Improvement of Energy Linearity in Kinetic Energy Measurement with Superconducting Detectors for TOF-MS
Yiner Chen, Masahiro Ukibe, and Masataka OhkuboNational Institute of Advanced Industrial Science and Technology (AIST), Umezono, Tsukuba, Ibaraki 305-8568, Japan
Simplified Schematic TOF experiment of mass spectroscopy
✰ Cryogenic Nb-based proximized STJ detectors with 100 elements of 200×200 µm2 was fabricated successfully. ✰ The STJ elements show good tunnel junction performance at 0.3K (extremely low leakage current ~ a few nA).✰ The kinetic energy spectrum of TOF-MS experiment for polystyrene of 100KDa proved that the detector has a 100% detection efficiency independent on
molecular weight up to 2MDa.✰ Energy non-linearity has been observed. The fabrication to obtain a good energy linearity is under progress.
Conclusions
MP09-171
(1). Fabrication of large-array cryogenic tunnel junction (STJ) detectors by photolithographic techniques, DC magnetron sputtering, reaction ion etching (RIE), and wet-etching processes.
(2). Good tunnel junction property.(3). 100% detection efficiency independent on
molecular weight.
Overview(1). STJ detectors have a faster time resolution of a few 10 ns, which is
advantageous for a high mass resolution, than other cryogenic detectors such as calorimeters of which time resolution is about 1 µs.
(2). Problem of STJ detectors to be solved is small active area (currently<200μm). In this study, array of one-hundred STJ elements with a size of 200×200 µm2 have been fabricated and tested.
(3). Advantage for TOF-MS comes from 100% detection efficiency for a wide mass range, no noise, and kinetic energy measurement.
Introduction UV laser17.5kV high voltage
Analyte in matrix
field free regionSTJ
detector
+ion
Scheme of STJ detector structure
Experimental Methods
photolithographic equipmentsputtering apparatus
with six targetscryostat apparatus
Experimental Results
Kinetic energy spectrum of TOF-MS experiment for polystyrene of 100kDa
-8
-6
-4
-2
0
2
4
6
8
-0 . 4 -0 . 2 0 0 . 2 0 . 4
V [mV]
I [n
A]
Image of Nb-based STJ array with 100elements of 200×200 µm2
enlarged
Bottom (Nb)Upper (Nb)
Nb/Al/AlOx/Al/Nb
Substrate(Si)
Isolation (SiO2)
k Da/zk Da/z
Mass spectrum of BSA(66.4kDa)
k Da/z1cm
I-V curve at 0.3KI-V curves at different temperatures Mass vs. kinetic energy plot
k Da/z
Kinetic energy spectrum of BSA+
(17.5 keV) and BSA++ (35keV)
Non-linearityshould be improved
molecular impact
✰ Normal resistance RN: ~0.4 Ω; Quality factor (Rd/RN): ~106 at 0.3K. ✰ 25% elements have good superconducting performance.
100% detection efficiency
(independent on molecular weight)