Oxygen Measurement in Nitrogen Blanketing INGOLD Leading Process Analytics Mettler-Toledo in situ amperometric oxygen analyzer provides well-priced alternative to costly paramagnetic system. The Mettler-Toledo amperometric in situ oxygen analyzer allows reliable oxygen measurement in operations where the presence of oxygen is undesirable. In these so called nitrogen Blanketing or inerting processes, it has proven it- self a worthy alternative for paramagnetic systems. Application Notes Background Storage, transportation and handling of flammable liquids and dust can create risk of explosion or fire. Especially milling operations or centrifuges that separate solids from organic solvents, are vulnerable to this threat. The rotating equipment generates heat or may cause electrostatic discharge which is all that is needed to ignite an explosive mixture. Nitrogen blanketing is therefore carried out to generate a non-combustible atmosphere with low oxygen contents. To achieve this, the centrifuge or tank is purged with a controlled stream of nitrogen to keep the oxygen level below the Limiting Oxygen Concentration (LOC). Efficient Control of LOC In order to prevent the oxygen concentration from exceeding the limiting oxygen concentration (LOC usually < 10%), the control loop initiates purging of the vessel when an upper intervention limit is exceeded. This threshold value is al- ways well below the limiting oxygen concentration (LOC). On the other hand the nitrogen consumption has to be controlled to reduce operating costs. The purging is therefore stopped when the Lower Intervention Limit is detected. This means that the inerting system keeps the consumption of nitrogen mini-
Transcript
Oxygen Measurement in Nitrogen Blanketing
INGOLDLeading Process Analytics
Mettler-Toledo in situ amperometric oxygen analyzer provides well-priced alternative to costly paramagneticsystem.The Mettler-Toledo amperometric in situ oxygen analyzerallows reliable oxygen measurement in operations wherethe presence of oxygen is undesirable. In these so callednitrogen Blanketing or inerting processes, it has proven it-self a worthy alternative for paramagnetic systems.Ap
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BackgroundStorage, transportation and handling of flammable liquids and dust cancreate risk of explosion or fire. Especially milling operations or centrifugesthat separate solids from organic solvents, are vulnerable to this threat. The rotating equipment generates heat or may cause electrostatic dischargewhich is all that is needed to ignite an explosive mixture.
Nitrogen blanketing is therefore carried out to generate a non-combustibleatmosphere with low oxygen contents. To achieve this, the centrifuge ortank is purged with a controlled stream of nitrogen to keep the oxygen levelbelow the Limiting Oxygen Concentration (LOC).
Efficient Control of LOCIn order to prevent the oxygen concentration from exceeding the limiting oxygenconcentration (LOC usually < 10%), the control loop initiates purging of thevessel when an upper intervention limit is exceeded. This threshold value is al-ways well below the limiting oxygen concentration (LOC). On the other handthe nitrogen consumption has to be controlled to reduce operating costs. The purging is therefore stopped when the Lower Intervention Limit is detected.This means that the inerting system keeps the consumption of nitrogen mini-
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Nitrogendischarge
Inert gas flowSolvent recovery
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Solvent drain
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Mettler-Toledo AG Process AnalyticsIm Hackacker 15CH-8902 UrdorfSwitzerland
mal while safe operation is ensured.Depending on individual processconditions and solvent concentration,the oxygen level is maintained bet-ween 1 and 9 vol%.
Disadvantages of the classical approachThe control loop usually consists ofan oxygen analyzer system, a pres-sure regulator, a control valve, a sa-fety relief valve etc.
A conventional analyzer system ty-pically consists of a paramagneticoxygen analyzer, a sample handlingsystem, a pump, a controller (PLC)and so on. Apart from all the peri-pherals needed, the analyzer itself isvery costly. Furthermore, a substan-
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tial amount of maintenance is re-quired. Faulty sample handling canlead to serious damage to the para-magnetic oxygen cell. This againwill lead to reduced capacity andproduction loss.
METTLER TOLEDO’s alternative With amperometric oxygen mea-surement, Mettler-Toledo offers acost efficient and reliable solution.The oxygen probe can be mounteddirectly into the nitrogen dischargepiping. If desired, a retractable sen-sor mounting assembly allows re-trieval of the sensor without inter-rupting the process. This enablesfully automated cleaning and calib-ration, with normal air used ascalibration gas. In very critical app-lications, the instrument can beequipped with redundant oxygenprobes.
Mettler-Toledo’s amperometric oxy-gen analyzer is characterized by robustness, fast response times andmoisture resistance. Of course bothanalog and digital communicationare available, whether it’s HART®,Foundation Fieldbus or Profibus®.
