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Fragrances,Flavors, & Food
AdditivesNINA TINAJA
JASMIN ESTELEYDES
CHE 3202
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FRAGRANCES
• The manufacture of erfume! co"o#ne! to$"ette %ater&
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'ERF(MEIND(STRY
Dra)t$c chan#e) *ue to+
• Increa)e $n the num,er of a-a$"a,"e ra% mater$a"$n#re*$ent)
•
A -ar$et. of ne% t.e) of ro*uct) re/u$r$n#fra#rance)
• Inno-at$on) $n aca#$n#
• 1roa*ene* channe") an* metho*) of *$)tr$,ut$on
• Gro%th $n men) to$"etr$e)
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Ma$n chan#e) $n the $n*u)tr.+
• Intro*uct$on of ).nthet$c)
• Imro-e* metho*) of o,ta$n$n# true o$")
'ERF(MEIND(STRY
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'ERF(ME
• Lat$n %or* perfumare
• to 4"" %$th )moe5
• 'erfume 6 m$7ture of fra#rant e))ent$a" o$") an* aroma
comoun*)! 47at$-e)! an* )o"-ent)! u)e* to #$-e thehuman ,o*.! o,8ect) an* "$-$n# )ace) a "ea)ant)me""&
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1AC9 HIST:RY
• Ear". $ncen)e) 6 m$7utre of 4ne".#roun* )$ce) %$th m.rrh or)tora7
• D$)co-ere* o$ntment)
• Avicenna! the Ara,$an
h.)$c$an! *$)co-ere* the )team*$)t$""at$on of -o"at$"e o$")&
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M:DERNERA
• The manufactur$n# roce)) un*er#one *ra)t$cchan#e)
• F$ne)t mo*ern erfume) are ne$ther %ho"". ).nthet$c
or com"ete". natura"& – to re*uce the r$ce! an*
– to $ntro*uce fra#rance) $nto the enchant$n# #amutat re)ent a-a$"a,"e
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'ERF(MES
• Con)t$tuent) of erfume) are+
– -eh$c"e) or )o"-ent)
– the 47at$-e)! an*
–
o*or$ferou) e"ement)
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'ERF(ME;EHICLES
• So"-ent) u)e* for ,"en*$n# an* ho"*$n# erfumemater$a")
– e&! eth." a"coho" an* %ater at *$
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• F$7at$-e) ma. ,e *e4ne* a) )u,)tance) of lowervolatility of the erfume o$")! %h$ch retard and evenup the rate of evaporation of the -ar$ou) o*orou)con)t$tuent)
– an$ma" )ecret$on)
– re)$nou) ro*uct)
– e))ent$a" o$")! an*
– ).nthet$c chem$ca")
'ERF(MEFI=ATI;ES
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ANIMAL FI=ATI;ES
– Civet 6)oft fatt. ac$* )ecret$on of the er$nea"#"an* of c$-et cat
– Musk 6 *r$e* )ecret$on of the reut$a" #"an*)of ma"e mu) *eer foun* $n Himalayas
– Ambergris 6 ca"cu"u)! or )ecret$on! *e-e"oe*,. certa$n %ha"e)
– Musc zibata 6 e7tracte* from #"an*) ofLou$)$ana mu)rat& A,out >0? of the
un)aon$4a,"e mater$a") $n the mu)rat #"an*con)$)t) of "ar#e! o*or"e)) c.c"$c acoho")! %h$chare con-erte* to etone)&
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RESIN:(S FI=ATI;ES
• Norma" or atho"o#$ca" e7u*ate)from certa$n "ant) – Har* re)$n) 6 ,en@o$n an* #um)
– Soft re)$n) 6 m.rrh an* "a,*anum
– Mo*erate". )oft ,a")am)B 6 'eru,a")am! to"u ,a")am! co$a,a an* )tora7
– :$". mater$a") o"eore)$n)B 6 terene)
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ESSENTIAL :IL FI=ATI;ES
• A fe% e))ent$a" o$" are u)e* for the$r47at$-e roert$e) a) %e"" a) the$ro*or – C"ar. )a#e
– ;et$-er
– 'atchou"$
– :rr$) – San*a"%oo*
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SYNTHETIC FI=ATI;ES
• H$#h,o$"$n# an* comarat$-e". o*our"e)) e)ter)
• Some e7am"e)+ – G".cer." *$acetate –
Eth." htha"ate – 1en@." ,en@oate – Am." ,en@oate – C$nnam$c a"coho" e)ter) – C$nnam$c ac$* e)ter) –
Mu) etone – Mu) am,rette – ;an$""$n – Courmar$n
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• E))ent$a" o$")
• I)o"ate)
• S.nthet$c or Sem$).nthet$c chem$ca")
'ERF(ME:D:R:(S S(1STANCE
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ESSENTIAL :IL
• ;o"at$"e! o*or$ferou) o$") of "ant or$#$n&
• Connecte* %$th meta,o"$)m! fert$"$@at$on! or rotect$onfrom enem$e)&
•
It foun* $n ,u*)! o%er)! "ea-e)! ,ar! )tem)! fru$t)!)ee*)! %oo*! root) an* rh$@ome)&
• In )ome tree) $n oleoresinous exudates.
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• In)o"u,"e $n %ater an* )o"u,"e $n or#an$c )o"-ent)
• Enou#h of the o$" ma. *$))o"-e $n %ater to #$-e an$nten)e o*or to the )o"ut$on!
e&! ro)e %ater or oran#e a-or %ater&
ESSENTIAL :IL
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ESSENTIAL :IL
The comoun*) occur$n# $n e))ent$a" o$") are
& E)ter) 6 ma$n". of ,en@o$c! )a"$c."$c! acet$c an* c$nnam$cac$*)
2& A"coho") 6 L$na"oo"! #eran$o"! c$trone""o"! ter$no"! mentho"!,orneo"
3& A"*eh.*e) 6 c$tra"! c$trone""o"! ,en@a"*eh.*e!c$nnama"*eh.*e! -an$""$n
& Ac$*) 6 ,en@o$c! c$nnam$c! m.r$)t$c! $)o-a"er$c $n the free)tate
& 'heno") 6 eu#eno"! th.mo"! car-acro"
& 9etone) 6 car-one! menthone! u"e#one! $rone! camhor!meth." non." etone! meth." heten$ne
& E)ter) 6 c$neo"e! $nterna" ether euca".to"eB! anetho"e!)afro"e
& Lactone) 6 coumar$n
>& Terene) 6 camhene! $nene! "$monene! he""an*rene!ce*rene
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IS:LATES
'ure chem$ca" comoun* %ho)e )ource $) an e))ent$a" o$" orother natura" erfume mater$a"&
e#& Eu#eno" from c"o-e o$"
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E=TRACTI:N'R:CESS
:FESSENTIAL:ILS
• E7re))$on
• D$)t$""at$on
• E7tract$on %$th -o"at$"e )o"-ent)
• Eneura#e
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E='RESSI:N
• cold pressed5 metho* $) referre* to $n themanufacture of e))ent$a" o$")! $t ,a)$ca"". refer) to thee7re))$on metho*! )$nce no heat $) $n-o"-e* $n th$)metho*&
• It $) the metho* u)e* commerc$a"".
• 'ro*uce* the h$#he)t /ua"$t. o$"
• :$" $) force* from the mater$a" un*er h$#h mechan$ca"
re))ure
• A )$m"e techn$/ue %here fru$t) are co"* re))e* toe7tract the$r e))ent$a" o$") u)$n# ro""er) or )on#e)&
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DISTILLATI:N
• Ma8or$t. of o$") are o,ta$ne* %$th *$)t$""at$on! u)ua"".%$th )team
• Con-ert) the -o"at$"e "$/u$* the e))ent$a" o$")B $nto a-aor an* then con*en)e) the -aor ,ac $nto a "$/u$*
• It $) the mo)t ou"ar! an* co)t e
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DISTILLATI:N
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ENFLE(RAGE
• A co"*fat e7tract$on roce))
• De"$cate o%er) Ja)m$ne! tu,ero)e! -$o"et! etc&B
• Fat or ,a)e! con)$)t) of h$#h". ur$4e* m$7ture of art ta""o% to 2 art) "ar*! %$th 0&? ,en@o$n a**e* a)
re)er-at$-e)• Y$e"*) no *$rect o$" on *$)t$""at$on
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E=TRACTI:N KITH ;:LATILES:L;ENTS
• Maceration/olvent !xtraction
• For "ant mater$a") conta$n too -o"at$"e o$" to un*er#oe7re))$on
• :r chem$ca" comonent) too *e"$cate an* ea)$".*enature* ,. h$#h heat u)e* $n )team *$)t$""at$on
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MAN(FACT(RING'R:CESS
1
2
3
4
COLLECTION
EXTACTION
!LEN"IN#
A#IN#
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TY'ES:F'ERF(MES
Aro$aticCo$po%nd
Concentration
'(
)er*%$ee+tract
60? 20?
Esprit de)ar*%$
630?
Ea% de)ar*%$
0620? ?
Ea% deToilette
6? 0?
Ea% de
Cologne
36? ?
)er*%$e $ist 6
•!ased on t.e concentration o* aro$atic co$po%ndsessential oil, per*%$e oil(
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FRAGRANCEN:TES
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C.e$istr/ o* Flavors- is the sensory impression of a food or
other substance,and is determined mainly by the chemical
senses
of taste and smell.
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KHAT IS FLA;:R
• aroma! ta)te an*
cheme)tet$c
re)on)e)ton#ue!
mouth! "$)!
throat! o"factor.re#$onB
• com"e7
$nteract$on ofta)te!)me""!aearance!fee"$n#! e7o)ure!
etc&
• $n the a)t • no%
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FLA;:R ENHANCERS
*oe) not $t)e"f ,r$n# a-or to a *$)h$n)tea*
$t act) to he$#hten) the *$ner)ercet$on of
a-or &
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T/pe "escription
Natura" a-or$n# )u,)tance) F"a-or$n# )u,)tance) o,ta$ne*
from "ant or an. ra%mater$a")! ,. h.)$ca"!m$cro,$o"o#$ca" or [email protected]$croce))e*&
Nature$*ent$ca" a-or$n#
)u,)tance)
F"a-or$n#)u,)tance) that are
o,ta$ne* ,. ).nthe)$) or$)o"ate* throu#h chem$ca"roce))e)&
Art$4c$a" a-or$n# )u,)tance) The)e are t.$ca"". ro*uce* ,.fract$ona" *$)t$""at$on an*a**$t$ona" chem$ca"
man$u"at$on of natura"".)ource* chem$ca")! cru*e o$" orcoa" tar
http://en.wikipedia.org/wiki/Crude_oilhttp://en.wikipedia.org/wiki/Coal_tarhttp://en.wikipedia.org/wiki/Coal_tarhttp://en.wikipedia.org/wiki/Crude_oil
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Taste
-0eet
-alt/
!itter -o%r
E+ )ol/.idro+/co$po%nd, sacc.arin E+ NaCl, LiCl
E+ Lean $eat →creatine
Coffee, cocoa →caffeine E+, acetic acid, lacticacid
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SKEETNESS•
S%eetne)) $) foun* $n man. t.e) ofmo"ecu"e) not 8u)t )u#ar)B! an*re"at$-e )%eetne)) $) norma"".comare* to )ucro)e
• Natura" )u#ar) 6 )ucro)e &0B!#"uco)e 0&B! fructo)e &2B
• A")o art$4c$a" )%eetener) 6 )o*$um
c.c"amate 30B ace)u"ham90Ba)artame200B )acchar$n 30Bnroo7.2am$non$tro,en@ene
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S:(RNESS
• Sourne)) $) a))ume* to ,e "$ne*%$th ac$*$c )o"ut$on)
• C$tr$c! ma"$c! tartar$c#raeB!$)oc$tr$c! o7a"$c! acet$c! "act$c ac$*&
• C$tr$c ac$* %a) 8u*#e* the mo)t)our! fumar$c an* tartar$c a,out
e/ua" an* a*$$c "ea)t )our &
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SALTINESS•
The )a"t. ta)te $) ,e)t e7h$,$te*,. NaC"
• The ta)te of )a"t) *een*) on the
nature of ,oth cat$on an* an$on• Sa"t )u,)t$tute) ,a)e* on
ota))$um ch"or$*e *o not
enhance mouthfee" or ,a"ancean* $ncrea)e ,$tter or meta""$co
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1ITTERNESS•
Taste %ds at ac o* tong%e responsive to- Grou an* 2 ha"$*e )a"t)
- Certa$n heno"$c)
• 5!r is ot. salt/ and ittter
• ha"$*e )a"t) %$th the )um of the$r $on$c *$ameter)O 9,r are ,$tter! $f the )um $) "e)) then the. are)a"t.
• 6an/ plants contain $olec%les 0.ic. 0e
perceive as ver/ itter• n$cot$ne! atro$ne! emet$ne
• /u$n$ne a a-or comonent of ton$c %ater an*,$tter "emon
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Chem$ca" )tructure) an*funct$ona"
#rou) re)on)$,"e for a-our
ro*uct$on $n foo*)tu
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'R:D(CTI:N :F J(ICE ANDC:NCENTRATE
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FR(IT FLA;:R
• A"$hat$c am$no ac$*) →alcohols+acids→esters (fruity)
• Aromatic amino acids →aromatic aldehydes
(spicy)
• Fat →free fatty acids →acids + alcohols→esters
• Terpenes (glycosidically bound) .
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E=AM'LE :F FLA;:RS
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;ANILLA H.*ro7.3metho7.,en@o"a"*eh.*eB
• The -an$""a ,ean $) the$mmature fru$t of the orch$*;an$""a "an$fo"$a&
•
The #reen o*) un*er#otreatment from 3 to month)&
• The #"uco)$*e #"uco-an$""$n
re)ent $n the ,ean ha),een acte* ,. a fermentan* )"$t $nto #"uco)e!-an$""$n an* other aromat$c)
CHO
OH
OCH3
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C7OCOLATE AN" COCOA
• The cacao ,ean! the)ee* of theo,roma cacaoL& #ro%) $n e/uator$a"
area) on the three $no*) from 30 to 0,ean)
•
'reare* ,. ferment$onfrom 2 to *a.) !*r$e*an* heate* ,et%een 0an* 20˚, cooled and thendehus!ed
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'R:D(CTI:N :F
CH:C:LATE
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Su,)tance) other than ,a)$c foo* )tu
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Mono)o*$um G"utamate MSGB,COO7C72(2C7N72(COONa
5i%nae Ieda, Jaane)e ,$ochem$)t! %ho%a) )ee$n# to $)o"ate an* *u"$cate the)a-our. ta)te of om,u! an e*$,"e )ea%ee*
u)e* a) a ,a)e for man. Jaane)e )ou)&)o*$um )a"t of an am$no ac$* ca""e* #"utam$cac$*
%a) often manufacture* from %heat #"uten or
corn rote$n ,ut to*a. $t $) u)ua"". ma*e $n afermentat$on roce)) that )tart) %$th mo"a))e)
http://en.wikipedia.org/wiki/Kikunae_Ikedahttp://en.wikipedia.org/wiki/Kikunae_Ikedahttp://en.wikipedia.org/wiki/Kombuhttp://en.wikipedia.org/wiki/Kombuhttp://en.wikipedia.org/wiki/Kikunae_Ikedahttp://en.wikipedia.org/wiki/Kikunae_Ikeda
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• To reare Eau De Co"o#ne! 00# of *$"utee))ent$a" o$" conta$n$n# 20? o$" $) m$7e* %$th a200# )o"ut$on of 0? a"coho"& Khat %$"" the 4na"como)$t$on ,e