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Silicon Containing Hybrid Copolymers, First Edition. Edited by Chaobin He and Zibiao Li. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA. Published 2020 byWiley-VCH Verlag GmbH & Co. KGaA.

aadditive manufacturing (AM) 239,

240, 247, 260aerosol jet printing (AJP) 249–251amidation 87anchor zwitterionic polysiloxanes 109anionic polymerization 3, 7, 44, 50, 86,

91anionic ROP (AROP) 51, 81antibiofouling (AF) 1, 109anti‐corrosive 128, 137, 140anti‐fouling 1, 11, 15, 16, 109, 111,

119, 128, 137, 140, 148, 151, 163atom transfer radical polymerization

(ATRP) 7, 41, 45–46, 80, 103, 126, 148, 190

azobisisobutyronitrile (AIBN) 79

bbenzoyl peroxide (BPO) 32, 79bifunctional POSS

developing strategy 74–76special cases 73–74

9,10‐bis(phenylethynyl)‐anthracene (BPEA) 87

ccationic polymers 160, 161, 252chain transfer agents (CTAs) 80, 133click chemistry 2, 7, 42–43, 91, 173, 183coaxial 3D‐printing 245common linear polyorganosiloxane

copolymers 98

controlled radical polymerization (CRP) 45

atom transfer radical polymerization 45–46

methods 50reversible addition fragmentation

chain transfer polymerization 47–50

conventional organic chemistry 27, 68

conventional radical polymerization 43–44, 152

Co‐PDMS@PET fabrics 133, 140cyclic siloxane monomers 26, 99cyclic siloxanes 23, 25–27, 99cyclolinear polycarbosilanes 8

ddeposition of silicone influences 160digital light processing (DLP) 251,

252diglycidyl ether of bisphenol A

(DGEBA) 86, 220, 2541,1‐diphenyletylene (DPE) 87direct ink writing (DIW) 242

coaxial 3D‐printing 245embedded 3D printing 245–246rheology‐controlled shape

retention 242–244docetaxel (DTX) 11, 108double‐decker silsesquioxane

(DDSQ) 14, 76, 78doxorubicin (DOX) 11, 109, 153

Index

Index266

drug delivery micelles 108dye‐sensitized solar cells (DSSCs) 169

eelectrochromic device 182, 185, 187electrochromic polyamic acid 189electrochromic polymers 182embedded 3D printing 245–246epoxy resins 86, 202, 220–222, 224,

226, 227, 231, 233ethylene glycol dimethacrylate

(EGDMA) 111extrusion‐based printing

direct ink writing 242–246fused deposition

modelling 240–242types 240

ffabrication methods 119, 120field‐effect transistor (FET) 112flexible electronic systems 112free radical polymerization 2, 79, 121,

123, 252fused deposition modelling

(FDM) 240–242

gglycoproteins 155, 156

hhair care 159–160halogenated flame retardants 201highest occupied molecular orbitals

(HOMOs) 169hybrid copolymer, structures 97hydrosilation 178hydrosilylation 42, 66, 91, 178

polymerization 87

iimidazolium iodides 169, 188inkjet 3D‐printing (IJP) 247–249

jjetting‐based printing

aerosol jet printing 249–251inkjet 3D printing 247–249

llowest unoccupied molecular orbitals

(LUMOs) 169

mmacromers

block and graft copolymers 35–43crosslinking of functionalized

polysiloxanes 30–35modifying degree of

polymerization 30step‐growth polymerization 35–41

metallocene‐catalyzed polymerization 87

methacrylisobutyl POSS (MA‐POSS) 100, 104

methyl methacrylate (MMA) 44, 45, 79, 80, 104, 121

mono‐functional POSScorner capping of T7R7(OH)3 71–72substituents modification 73

nnitroxide‐mediated polymerization

(NMRP) 81

oocta‐functional POSS

hydrolysis and condensation from RSiX3 monomer 65–66

substituents modification 66–70octameric silsesquioxane 190octasilsesquioxanes (T8) 6, 63octavinylsilsesquioxane (OVS) 181,

193oil‐water separation

PDMS based superhydrophobic materials 129–135

POSS based superhydrophobic materials 135–136

organosilicon polymers 1–2application 10–17biomaterials application 10–12optical and electronic materials

application 13–15surface modification 15–18synthetic strategies 2

Index 267

organosilsesquioxanes 63oxidized polydimethylsiloxane

(ox‐PDMS) 112

pPEOXA‐b‐PDMS‐b‐PEOXA 105perylene diimide (PDIs)

derivatives 192PHEMPOSS‐b‐PMAA 105photo‐curable 3D printing 251

digital light processing 252photopolymerization

process 252–260stereolithography (SLA)

printing 252photo‐curable polymers 254photodynamic therapy (PDT) 99,

109–111photoinitiators 10, 253, 254photopolymerization process

photo‐curable polymers 254–260photoinitiator 253–254

physical reinforcement 211poly(propylene glycol) (PPG) 103polyamic acid 40, 189polycarbonate (PC) 41, 202, 206, 213,

240polycarbosilanes 7–10, 18polydimethylsiloxane (PDMS) 97–98,

109, 111, 120incorporated hybrid copolymer

materials 120–122self‐assembly 99–107

polyepoxides 86, 202, 220–233polyester 38, 41, 51, 78, 79, 83, 202,

216–220polyhedral oligomeric silsesquioxanes

(POSS) 97, 120, 168biomedical applications 107–109building block for electrochromic

material 181–189coating 111–112electroluminescent and

electrochromic materials 189incorporated hybrid copolymer

materials 122–128mono‐functional

corner capping of T7R7(OH)3 71–72

substituents modification 73octa‐functional

hydrolysis and condensation from RSiX3 monomer 65–66

substituents modification 66–70optical sensors 112–113organic electroluminescent

materials 171organic optoelectronic

materials 167–171photodynamic therapy 109–111self‐assembly 99–107structure 64synthetic protocols 76

preparation from monomers 78–87

preparation from polymers 87–91

synthetic strategiesbifunctional 73–76classes 64mono‐functional 71–73octa‐functional 65–70

polymeric materials 64, 171, 239, 240

polypropylene (PP) 17, 85, 147, 202–206

polysilanes 1, 7, 8, 10, 18polysilazanes 1, 2, 7, 9, 10, 18polysiloxanes 3, 7, 23

backbones 42click reaction 43with di‐functional terminals 25with functional side groups 27–29graft copolymers 41–42hydrosilylation 42–43macroinitiators 43–54macromers 30–43with mono‐functional

terminals 25side chains 41–42

polysilsesquioxanes 1, 3, 5–7, 10, 181polystyrene (PS) 45, 80, 100, 106, 120,

138, 202, 211–216polysulfone (PSf ) 41, 137

Index268

pyrene functionalized silsesquioxane cages (PySQ) 193, 194

pyridyldisulfanyl‐functionalized POSS (POSS‐PDS) 108

qquantum confinement effects 172quantum dots (QD) 98, 154, 172

Rradical polymerization

POSS functions as initiators 80–81POSS functions as

monomers 79–80reversible addition fragmentation chain

transfer (RAFT) polymerization 7, 41, 47–50, 80, 100, 123, 151

ring opening metathesis polymerization (ROMP) 41, 81, 87

ring opening polymerization (ROP) 50POSS functions as initiators 81–83POSS functions as monomers 81

sS‐heterocyclic PDI (SPDI) 192silicon based materials 18, 120, 239silicone copolymers

antibacterial effect 148–150antifouling effect 148based bio‐coating 150–152biomedical and healthcare

applications 145–156construction of artificial

cells 154–156drug delivery and

bioimaging 153–154personal care applications 157–162protein adsorption and cell

interaction 146self‐assembly 152–156surfactants 158–159tissue engineering 150

silicone oil emulsions 157–159, 161silsesquioxanes (SQ) 1, 5, 65, 74, 76,

78, 81, 122, 125, 168skin care applications 161–162small molecular semiconductors 167star shaped copolymers (SPP) 80, 87,

137step‐growth polymerization 35–41,

83–86stereolithography (SLA) printing 252,

256, 258superhydrophobicity 16, 111, 119–123,

125, 128, 135–137, 140, 244superhydrophobic materials and

surfaces 119application 128–140hybrid silicon copolymer

materials 120–128lotus effect 119

super‐hydrophobic POSSs 97

ttetraphenylporphyrin tetrasulfonic acid

hydrate (TPPS) 110thermoplastic urethane (TPU) 2413D printing 239

application 260–261extrusion‐based printing 240–246jetting‐based additive

techniques 247–251photo‐curable 3D printing 251–260

tissue engineering 12, 150, 163T7R7(OH)3 derivatives 71

uurethane reaction 91

vvat photopolymerization 251–260

zzwitterionic polymers 109