2008.9English
I ndustr ia l Batter ies
Industrial Batteries
0
1
2
3
4
Volta
ge (V
)
0.1 1 10 100 1,000
Capacity (mAh)10,000 100,000 1,000,000
ICP(Li-ion)
ICP(Li-ion)ER
CR(Coin-Type)
CR(Cylindrical)
SRTC TC LR(AlkalineBattery)
MLMLTotalTotalCapacity Capacity TotalCapacity
TotalTotalCapacity Capacity TotalCapacity
TotalTotalCapacity Capacity TotalCapacity
Maxell supplies various battery lineups corresponding to application usage of diversified equipment, ranging from lithium ion batteries as the main power sources of portable information devices to backup power sources for various electronics devices.
Position of Maxell Batteries
� Application of Primary and Secondary Batteries
Tele-communications
IT Hardware
Imaging
Audio
Timepieces
Industrial
Automobiles
Other
SecondarySecondaryPrimary
Maxell batteries: Meeting a variety of energy needsCR/ER/SR/ICP/ML/TC Industrial Batteries
ICPSRERCR
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Mobile PhonesPHSOA Machines (Fax, Copiers, Printers)Notebook PCsDesktop PCsPDAsElectronic DictionariesCalculatorsCamcordersDigital Still CamerasFilm CamerasPortable CD/MD PlayersDigital Audio PlayersWatchesMedical Instruments, Cash Registers FA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors)Electronic Meters (Water, Gas, Electricity)Keyless Entry SystemsETC (Electronic Toll Collection System)Portable Game DevicesRemote Controllers
1
TotalCapacity
TotalCapacity
TotalCapacity
C O N T E N T S
CR2450 CR2430
CR2032H CR2032
CR2025 CR2016
CR2012 CR1620
CR1616 CR1220
CR1216 CR1025
With Terminals and Wire Connectors
&
&
&
&
&
&
� Coin Type
&
&
� Heat Resistant Coin Type
CR17450 CR17335
� Cylindrical Type
CR Lithium Manganese Dioxide Battery
ER18/50 ER17/50
ER6 ER6C
ER17/33 ER3
ER3S
With Terminals and Wire Connectors
&
&
&
ER Lithium Thionyl Chloride Battery
ML2032 ML2016
ML1220
With Terminals and Wire Connectors
&
ML Lithium Manganese Dioxide Rechargeable Battery
TC920S
TC Titanium Carbon Lithium Rechargeable Battery
Silver Oxide BatterySilver Oxide BatterySRLithium Ion Rechargeable BatteryICP
CR2450HR CR2450HR-Ex
3
5
7
8
9
10
11
12
13
15
16
17
18
19
24
25
26
27
28
37
41
42
43
45
49
29
33
Prim
ary
Se
co
nd
ary
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CRCR2450 / CR2430 / CR2032H / CR2032 / CR2025 / CR2016 /
CR2012 / CR1620 / CR1616 / CR1220 / CR1216 / CR1025 /
With Terminals and Wire Connectors
(CR2450 / CR2032 / CR2025 / CR1616 / CR1220)
Heat Resistant Coin Type
CR2450HR / CR2450HR-Ex
CR17450 / CR17335
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
Lithium Manganese Dioxide Battery (Li/MnO2)
3
4
Warnings Warnings Circuit Design for Back-up UseHandling
Safety InstructionsThis battery contains lithium, organic solvents, and other combustible materials. For this reason, improper handling of the battery could lead to distortion, leakage*, overheating, explosion, or fire, causing bodily injury or equipment trouble. Please observe the following instructions to prevent accidents.(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Warnings Disposal
�Never swallow.Always keep the battery out of the reach of infants and young children to prevent it from being swallowed. If swallowed, consult a physician immediately.
�Never charge.The battery is not designed to be charged by any other electrical source. Charging could generate gas and internal short-circuiting, leading to distortion, leakage, overheating, explosion, or fire.
�Never heat.Heating the battery to more than 100 deg. C* could increase the internal pressure, causing distortion, leakage, overheating, explosion, or fire. (* Consult Maxell regarding heat resistant coin type lithium manganese dioxide batteries.)
�Never expose to open flames.Exposing to flames could cause the lithium metal to melt, causing the battery to catch on fire and explode.
�Never disassemble the battery.Do not disassemble the battery, because the separator or gasket could be damaged, leading to distortion, leakage, overheating, explosion, or fire.
�Never reverse the positive and negative terminals when mounting.Improper mounting of the battery could lead to short-circuiting, charging or forced-discharging. This could cause distortion, leakage, overheating, explosion, or fire.
�Never short-circuit the battery.Do not allow the positive and negative terminals to short-circuit. Never carry or store the battery with metal objects such as a necklace or a hairpin. Do not take multiple batteries out of the package and pile or mix them when storing. Otherwise, this could lead to distortion, leakage, overheating, explosion, or fire.
�Never weld the terminals or weld a wire to the body of the battery directly.
The heat of welding or soldering could cause the lithium to melt, or cause damage to the insulating material in the battery. This could cause distortion, leakage, overheating, explosion, or fire. When soldering the battery directly to equipment, solder only the tabs or leads. Even then, the temperature of the soldering iron must be below 350 deg. C and the soldering time less than 5 seconds. Do not use a soldering bath, because the circuit board with battery attached could stop moving or the battery could drop into the bath. Moreover do not use excessive solder, because the solder could flow to unwanted portions of the board, leading to a short-circuit or charging of the battery.
�Never use different batteries together.Using different batteries together, i.e. different type or used and new or different manufacturer could cause distortion, leakage, overheating, explosion, or fire because of the differences in battery property. If using two or more batteries connected in series or in parallel even same batteries, please consult with Maxell before using.
�Never allow liquid leaking from the battery to get in your eyes or mouth.
Because this liquid could cause serious damage, if it does come in contact with your eyes, flush them immediately with plenty of water and consult a physician. Likewise, If the liquid gets in your mouth, rinse immediately with plenty of water and consult a physician.
�Keep leaking batteries away from fire.If leakage is suspected or you detect a strong odor, keep the battery away from fire, because the leaked liquid could catch on fire.
�Never touch the battery electrodes.Do not allow the battery electrodes to come in contact with your skin or fingers. Otherwise, the moisture from your skin could cause a discharge of the battery, which could produce certain chemical substances causing you to receive a chemical burns.
This is a primary battery and cannot be charged. If used in memory or RTC back-up applications, be sure to use diodes to prevent charging from the main power source or other batteries, and a protective resistor to regulate the current as shown in the figure below. Note that the points described below should be taken into careful consideration when selecting diodes and protective resistors.
�Supplied voltage to loadBecause a diode and a resistor generate the voltage drop on operating, please take into consideration these voltage drops for supplied voltage to load.
�Using diodes to prevent charging Please choose diodes with leak current as small as possible. Please keep the charged capacity due to leak current to within 1% of nominal capacity.
�Using and setting protective resistors
A protective resistor is used to prevent the battery from being charged by large surges of current during diode failure. Please set the resistor so that the maximum current shown in the right table is not exceeded. For example, say a CR2032 battery is used in sample circuit (A) in combination with a main power source 5 volt. Since the permitted charge current is 10mA and this battery’s voltage is 3V, let the resistor be R>=(5V-3V)/10mA=0.2k ohm, meaning that at least 0.2k ohm is required.
TypeCR2450CR2430
CR2032HCR2032CR2025CR2016CR2012CR1620CR1616CR1220CR1216CR1025
CR2450HRCR2450HR-Ex
CR17450CR17335
Maximum Current15mA15mA10mA10mA10mA10mA10mA4.0mA2.5mA3.0mA2.5mA2.5mA15mA15mA20mA20mA
The battery may be regulated by national or local regulation. Please follow the instructions of proper regulation. As electric capacity is left in a discarded battery and it comes into contact with other metals, it could lead to distortion, leakage, overheating, or explosion, so make sure to cover the (+) and (-) terminals with friction tape or some other insulator before disposal.
Load+5VDiode
Example (A)
Diode
Example (B)
Load+5VDiode
Protectiveresistor
Protectiveresistor
BatteryBattery
Diode
Diode
(Example of battery insulation)
Battery +
—
Tape Do not pile up or mix batteries.
Enlarged view
Electric current flows.
These batteries generate heat.
5
CR
The coin-type lithium manganese dioxide battery (CR battery) is a small, lightweight battery with an operating voltage of 3V and the ability to operate over a wide temperature range. It has a wide range of applications, both for powering devices such as wristwatches and electronic calculators and can be used in all types of electronic devices mainly as memory and RTC backup.
The coin-type lithium manganese dioxide battery uses manganese dioxide (MnO2) as its positive active material, lithium (Li) as its negative active material, and an organic electrolyte.
Overview
Construction Principle and Reactions
Products
�Battery Reactions
Positive reaction: MnO2�Li+�e–� MnOOLiNegative reaction: Li � Li+�e–
Total reaction: MnO2�Li � MnOOLi
Negative Cap
(–)
(+)
Negative Electrode (Lithium)
Separator
Gasket
Positive CanCollectorPositive Electrode
(Manganese Dioxide)
Example of Typical Construction
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.** Nominal capacity indicates duration until the voltage drops down to 2.0V when discharged at a nominal discharge current at 20 deg. C.***When using these batteries at temperatures outside the range of 0 to +40 deg. C, please consult Maxell in advance for conditions of use.• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
�Never expose the battery to ultrasonic sound.Exposing the battery to ultrasonic sound may cause short-circuiting because the inside material is broken into pieces, leading to distortion, leakage, overheating, explosion, or fire.�Never subject the battery to severe shock.Dropping, throwing or stomping on the battery may cause distortion, leakage, overheating, explosion, or fire.�Never short-circuit the battery while installing into
equipment.Please be careful when installing the battery not to short-circuit it with metal portions of the equipment.�Use the correct battery suitable for the equipment.The battery may not be suitable for the specific equipment due to the using conditions or type of equipment. Please select the suitable battery according to the handling instructions of the equipment.
�Never use or leave the battery in a hot place such as under the direct rays of the sun or in a car in hot weather.
If you do, this may cause distortion, leakage, overheating, explosion, or fire.�Never allow the battery to come in contact with water.If it does, this may cause the battery to rust or lead to distortion, leakage, overheating, explosion, or fire.�Never store the battery in a hot and highly humid
environment.Doing so may cause the performance of the battery to deteriorate. In certain environments, this may lead to distortion, leakage, overheating, explosion, or fire.�Keep contact pressure more than 2N.The battery voltage may be lower than intended value because of poor contact condition, please keep contact pressure more than 2N for suitable contact resistance.
Caution Handling/Storage
Model
Nominal Voltage (V)
Nominal Capacity (mAh)**
Nominal Discharge Current (mA)
Weight (g)*
Diameter (mm)
Height (mm)Dimensions*
CR2450
3
610
0.2
6.6
24.55.0
CR2430
3
290
0.2
4.6
24.53.0
CR2032H
3
240
0.2
20.0
3.0
3.2
CR2025
3
170
0.2
20.0
2.5
2.5
CR2016
3
90
0.1
20.0
1.7
1.6
CR2032
3
220
0.2
20.0
3.0
3.2
CR2012
3
50
0.1
Operating Temperature Range (deg. C)*** –20 to +85
20.0
1.4
1.2
CR1025
3
30
0.1
0.6
10.02.5
CR1216
3
25
0.1
0.6
12.51.6
CR1220
3
36
0.1
12.5
0.8
2.0
CR1616
3
55
0.1
16.0
1.1
1.6
CR1620
3
80
0.1
16.0
1.3
2.0
Coin Type Lithium Manganese Dioxide Battery
6
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
Fig. 1 Relationship between Discharge Current Consumption and Duration Time Fig. 2 Discharge Characteristics after Storage
Fig. 3 High Rate Discharge Characteristics
Optimum for Memory and RTC Backup (Fig. 1)Displays long-term stable operating voltage at low load discharge.
High 3 volt energy densityHigh energy density. At 3 volts (nominal voltage), it has about twice the voltage of alkaline button batteries and silver oxide batteries.
Stable discharge characteristics through low internal resistance and high operating voltage
Employs highly conductive electrolyte, lowering internal resistance and providing stable operating voltage. This allows stable power to be obtained, with little change in
operating voltage at room temperature as well as high and low temperatures.
Superior leakage resistance and excellent storage characteristics (Fig. 2)
Employs a leak-resistant organic electrolyte, giving it better leakage resistance than battery types using alkaline electrolytes. Furthermore, the high degree of seal of the seal structure and application of sealant keep self-discharge to about 1% per year.
Superior high rate discharge characteristics (Fig. 3)
Features
UL Recognized Components The coin-type lithium manganese dioxide battery is a UL (Underwriters Laboratories Inc.) recognized component.
Recognized models:CR2450, CR2430, CR2032, CR2032H,CR2025, CR2016, CR2012, CR1620, CR1616, CR1220, CR1216, CR1025 Certification Number: MH12568
Applications OA Machines (Fax, Copiers, Printers) Notebook PCs Desktop PCsPDAs Electronic Dictionaries Calculators Camcorders Digital Still Cameras Film Cameras Portable CD/MD Players Watches Medical Instruments, Cash Registers Electronic Meters (Water, Gas, Electricity) Keyless Entry Systems Portable Game Devices Remote ControllersFA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors)
1.5
1.7
1.9
2.1
2.3
2.5
2.7
2.9
3.1
3.3
3.5
0 200 400 600 800 1000 1200 1400
Discharge duration time (hours)
Vol
tage
(V)
After stored for 100 days at 60 deg. C(equivalent to storage at 20 deg. C for 5 years)
Initial
CR2032H
2.0
2.0
3.0
3.5
1.50 50 100 150 200 250
Discharge capacity (mAh)
Vol
tage
(V)
CR2032H
3.9k ohm
15k ohm
1k ohm
Discharge duration time (years)Dis
char
ge
curr
ent c
onsu
mpt
ion
(µA
)
10
10
10
10
Temperature : 20 deg. C
1 2 3 4 5 6 7 8 9 1010
10 2
10 1
10 0
-1
Discharge load : 15k ohmTemperature : 20 deg. CCR2450
CR2430
CR2032CR2025
CR2016CR1620CR1616CR2012CR1220CR1025CR1216
CR2032H
CR2430 (290mAh)
CR2450 (610mAh)
CR
7
15k� 300k�56k�150k�
300� 5 sec.
1 M� continuous
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
Discharge duration time (h)
Vol
tage
(V)
0 1000 2000 3000 4000
Discharge capacity (mAh)
0 100 200 300 400 500 600
Discharge load: 15 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 103
600
500
400
300
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
1M�
–10 deg. C0 deg. C
300� 5 sec.
45 deg. C
20 deg. C
–20 deg. C
–10 deg. C
20 deg. C45 deg. C
15k� 56k� 150k� 300k�
300� 5 sec.
1 M� continuous
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
Discharge duration time (h)
Vol
tage
(V)
0 200 400 600 800 1000 1200 1400 1600
Discharge capacity (mAh)
0 50 100 200 300150 250
Discharge load: 15 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 103150
250
200
300
350
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
1M�
–10 deg. C
0 deg. C
300� 5 sec.
45 deg. C
20 deg. C
–20 deg. C
–10 deg. C
20 deg. C45 deg. C
Coin Type Lithium Manganese Dioxide Battery
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
CR2032 (220mAh)
CR2032H (240mAh)
8
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Discharge duration time (h)
Vol
tage
(V)
Discharge capacity (mAh)
Discharge load: 15 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 103100
150
200
250
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
45 deg. C
–20 deg. C
–10 deg. C20 deg. C
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
300� 5 sec.
1 M� continuous
0 40 80 120 160 200 26024020 60 100 140 180 220
1M�
300� 5 sec.
15k� 1M�300k�150k�
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Discharge duration time (h)
Vol
tage
(V)
0 1400200 400 600 800 1000 1200
Discharge capacity (mAh)
0 40 80 120 160 200 24020 60 100 140 180 220
Discharge load: 15 k�
Temperature: 20 deg. C
Vol
tage
(V)
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
1M�
300� 5 sec.
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
300� 5sec
1 M� continuous
–10 deg. C
20 deg. C
60 deg. C
0 deg. C
20 deg. C
–10 deg. C
0 deg. C
60 deg. C
15kΩ 150kΩ 300kΩ1MΩ15k� 150k� 300k� 1M�
101 102 103 104100
150
200
25045 deg. C
20 deg. C
–20 deg. C
–10 deg. C
0 200 400 600 800 1000 1200 1400
0 deg. C
60 deg. C20 deg. C
–10 deg. C
CR2016 (90mAh)
CR2025 (170mAh)
CR� Discharge Characteristics
15k� 300k� 1M�150k�
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
1M� continuous
300� 5 sec.
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Discharge duration time (h)
Vol
tage
(V)
0 200 400 600 800 1000
Discharge capacity (mAh)
0 40 80 120 16020 60 100 140 180
Discharge load: 15 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 103
200
150
100
50
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
60 deg. C
� Pulse Discharge Characteristics
� Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
20 deg. C
–10 deg. C0 deg. C
45 deg. C
–10 deg. C–20 deg. C
1M�
300� 5 sec.
20 deg. C
300� 5 sec.
1 M� continuous
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Discharge duration time (h)
Vol
tage
(V)
0 100 200 50050 150 300250 400350 450
Discharge capacity (mAh)
0 20 40 60 80
Discharge load: 15 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 10340
60
80
100
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
1M�
–10 deg. C0 deg. C
300� 5 sec.
45 deg. C 20 deg. C
–20 deg. C–10 deg. C
20 deg. C45 deg. C
390k� 1M� 2.7M�39k�
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
Coin Type Lithium Manganese Dioxide Battery
9
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
CR1620 (80mAh)
CR2012 (50mAh)
10
300� 5 sec.
1 M� continuous
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Discharge duration time (h)
Vol
tage
(V)
0 100 200 300
Discharge capacity (mAh)
0 5040 1010
20
40
60
102 103302010 60
Discharge load: 15 k�
Temperature: 20 deg. C
Vol
tage
(V)
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
1M�
–10 deg. C 0 deg. C
300� 5 sec.
45 deg. C
20 deg. C
–10 deg. C
–20 deg. C
20 deg. C45 deg. C
56k� 560k� 1.8M�3.9M�
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
30k� 3M�1M�300k�
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5101 102 103 104 105 0 200 400 600 800 1000
0 20 40 60 80 10010 30 50 70 90
1M�
–10 deg. C 0 deg. C
300� 5 sec.
1 M� continuous
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
Discharge duration time (h)
Vol
tage
(V)
Discharge capacity (mAh)
Discharge load: 30 k�
Temperature: 20 deg. C
Vol
tage
(V)
300� 5 sec.
101 102 103
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
� Relationship between Discharge Current and Discharge Capacity
30
50
70
90
40
60
80
–20 deg. C–10 deg. C
20 deg. C45 deg. C
20 deg. C60 deg. C
CR1220 (36mAh)
CR1616 (55mAh)
CR
300� 5 sec.
1 M� continuous
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Discharge duration time (h)
Vol
tage
(V)
0 100 200 300 400 500 600
Discharge capacity (mAh)
0 10 30 5020 40 60
Discharge load: 30 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 1030
20
40
60
80
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
20 deg. C45 deg. C
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
1M�
–10 deg. C0 deg. C
300� 5 sec.
45 deg. C20 deg. C
–10 deg. C–20 deg. C
56k� 1.5M�560k� 3.9M�
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
1 M� continuous
3.5
3.0
2.5
2.0
1.5
4.0
3.0
2.0
1.0
Discharge duration time (h)
Vol
tage
(V)
0 100 200 300 400
Discharge capacity (mAh)
0 10 20 30 40
Discharge load: 30 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 10310
20
30
40
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
20 deg. C45 deg. C
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
–10 deg. C0 deg. C
1M�
300� 5 sec.
45 deg. C
20 deg. C
–20 deg. C–10 deg. C
300� 5 sec.
82k� 820k� 2.2M� 5.6M�
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
Coin Type Lithium Manganese Dioxide Battery
11
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
CR1025 (30mAh)
CR1216 (25mAh)
12
300� 5 sec.
1 M� continuous
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Discharge duration time (h)
Vol
tage
(V)
0 200 300100
Discharge capacity (mAh)
0 5 10 15 20 25 30
Discharge load: 30 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 1030
10
20
30
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
20 deg. C45 deg. C
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
–10 deg. C
1M�
300� 5 sec.
0 deg. C
20 deg. C45 deg. C
–20 deg. C–10 deg. C
120k� 1.2M� 3.6M�
3.5
3.0
2.5
2.0
1.5102101 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
600� 5 sec.
1 M� continuous
3.5
3.0
2.5
2.0
1.5
3.5
3.0
2.5
2.0
1.5
Duration (h)
Vol
tage
(V)
0 100 200
Discharge capacity (mAh)
0 10 20 30
Discharge load: 18 k�
Temperature: 20 deg. C
Vol
tage
(V)
101 102 1030
10
20
30
40
Discharge current (�A)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
20 deg. C45 deg. C
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
–10 deg. C
10 deg. C
1M�
600� 5 sec.
45 deg. C20 deg. C
–10 deg. C10 deg. C
100k� 1M� 2.2M� 6.8M�
3.5
3.0
2.5
2.0
1.5101 102 103 104 105
Discharge duration time (h)
Temperature: 20 deg. C
Vol
tage
(V)
ø20
3.0
4.0
1.8
7.45
4.0
5.0
(+)
(–)
Insulation sleeve
CR2032 T5
CR2032 T14
4 4.5
4
ø20
10.1
6
0.75
5.1
15.24
20.6
0.2(–) (+)
4.5
4
CR2032 T15
15.2
21
3 4
4.5
0.2
ø20
0.75
4
(+)(–)
Insulation sleeve
CR2032 T16
ø20
4.1
6.5
4.5
444.5
Insulation sleeve
214
0.75 200.2
0.75
4
(–) (+)
External Dimensions (unit : mm)CR2450 T25S
25
17.80.20.75
(–) (+)
10.64.0
ø24.
5
10.1
6
1.3
4
0.75
0.2
ø20
CR2032 T20
0.75
4.0
(–)
(–)
(+)
(+)4.0
0.75
4.0
10.1
6
3.0
10.1
6
6.5
Insulation sleeve
CR2032 T23
20.5
4.8 5
5.5
1.54
18.5
0.2
(–) (+)
0.2
ø20 3
4
5.5
5
CR2032 T33
5
5
(–)
(+)
7
1.5
ø20
4.2
3
CR2032 T25
4
0.75 0.2
17.8
20.3
4.5
(–) (+)
ø20
10.1
6
0.75
8.5
4
1.3
4
ø20
4.1
4.8
4.544.5
Insulation sleeve
214
0.75 20.50.2
1.8
4
(–) (+)
CR2032 T6 CR2032 T6LES
4.1
ø20
4.8
4 4.5
4.54
20.3
4
0.75 20.50.2
1.8
4
(–) (+)
CR2032 T19
(+)(–)
ø20
0.75
4
20.5 1.3
4.5
4
16
0.2
Actual appearance
Actual appearance
Actual appearance
CR Coin Type Lithium Manganese Dioxide Battery with Terminals and Wire Connectors
13
External Dimensions (unit : mm)CR2032 T34
Insulation sleeve
21 5
1.5
3.5 1.5
(+)
(–)
4
10.2
0.75
0.75
1.8
ø20
3.7
0.2
CR2032 T17
4.5 4
3
10.5
0.2 0.23.7
ø20
4 41.8 0.75
(–) (–)(+) (+)
Insulation sleeve
CR2032 T26
10.16
ø20
4
0.75 3.7
0.2
(+) (–)44.5 7.
5
Lead wire
34
35
20.2
4.5
12
12
(+)(–)
(–)(+)
(+)
(–)
Housing:Contact:Wire:
DF13-2S-1.25C (Hirose)DF13-2630SCF (Hirose)AWG28
Adhesive tape
Insulation sleeve
CR2032 WK13
34
180
20.2
4.5
12
(+)(–)
(–)(+)
(+)
(–)
12
Housing:Contact:Wire:
DF13-2S-1.25C (Hirose)DF13-2630SCF (Hirose)AWG28
Adhesive tape
Insulation sleeve
CR2032 WK12
Lead wire
34
70
20.2
4.5
12
(+)(–)
(–)(+)
(+)
(–)
12
Housing:Contact:Wire:
DF13-2S-1.25C (Hirose)DF13-2630SCF (Hirose)AWG28
Insulation sleeve
Adhesive tape
CR2032 WK11
Lead wire
CR2032 T7
Insulation sleeve
ø20
0.754
(–) (+)
0.23.76
24
CR2032 WK14
22
65
20.2 5
4.9
(+)(+)
(–)(–)
(+)
(–)
Housing:Contact:Wire:
DF3-4S-2C (Hirose)DF3-2428SCF (Hirose)AWG26
Insulation sleeve
Lead wire
: Tin plating: Horizontal & Through hole Type: Horizontal & Surface mounting Type: Vertical & Through hole Type: Wire connector Type
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
CR1616 T CR1220 T4
0.2
1.8
ø16
3
2.3
4
ø1.5
(+)
(+)
(–)
(–)
13
10
11.5
0.2 0.75
3.254
(+) (–)
(–) (+)
1.5
2.7
3.5
0.2
2.5
ø12.5
Insulation sleeve34
60
20.2
4.5
12
12
(+)(–)
(–)(+)
(+)
(–)
Housing:Contact:Wire:
DF13-2S-1.25C (Hirose)DF13-2630SCF (Hirose)AWG28
Insulation sleeve
Adhesive tape
CR2032 WK15
Lead wire
Actual appearance
14
15
Heat Resistant Coin Type Lithium Manganese Dioxide BatteryCR
Fig. 1 Storage Characteristics under High Temperatures
Fig. 3 High Rate Discharge Characteristics
Maxell’s original sealing technology and highly heat-resistant material expands operating temperature range remarkably, making the batteries supremely suitable for automobile applications — for powering TPMS (Tire Pressure Monitoring System) sensors, for example.
�Wide operating temperature range: -40 deg. C to +125 deg. CCR2450HR-Ex batteries can even be used at temperatures up to 150 deg. C, depending on other conditions*.�Superior leak-resistant characteristics even under high
temperature and acceleration.�Can be used even under 2000G, which is equivalent to
driving at 300km/h.�Electric characteristics are maintained after long
periods of exposure to high temperature and humidity.*When using CR2450HR and/or CR2450HR-Ex at temperatures exceeding 85 deg. C, please consult Maxell in advance for conditions of use.
Overview
Construction
Products
Features
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.** Nominal capacity indicates duration until the voltage drops down to 2.0V when discharged at a nominal discharge current at 20 deg. C.*** Equivalent to acceleration when driving at 300km/h, when attached to a 17-inch wheel• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
Fig. 2 Storage Characteristics under High Temperature/Humidity
ModelNominal Voltage (V)Nominal Capacity (mAh)**
Operating Temperature Range (deg. C)Acceleration Resistance
Weight (g)*
Diameter (mm)
Height (mm)Dimensions*
CR2450HR CR2450HR-Ex3
550
–40 to +125
3525
–40 to +125 (max.150)
Max. 2000G***
6.8
24.55.0
Negative Electrode (Lithium)Separator Gasket
Positive Electrode (MnO2)
Discharge duration time (h)
CR2450HR
Volta
ge (V
)
3.5
3.0
2.5
2.0
1.5
1.0
0.5
00 500 1000 1500 2000 2500 3000 3500
20 deg. C
1k� 3.9k� 15k�
120
100
80
60
40
20
0
1400
1200
1000
800
600
400
200
0
0
0 50 100 150 200
50 100 150 200Storage time (days, at 80 deg. C)
Other CR
Very little deterioration in capacity due to high storage temperature of 80 deg. C,compared to other CR batteries.
Very little deterioration in internal resistance due to high humidity (60 deg. C/90%RH), compared to other CR batteries.
Heat resistant CR (HR, HR-Ex)
Storage time (days, at 60 deg. C/90%)
Cal
cula
ted
DC
resi
stan
ce (%
)(C
ompa
red
to p
re-s
tora
ge)
Cap
acity
rete
ntio
n ra
tio (%
)
Other CR
Heat resistant CR (HR)
Heat resistant CR (HR-Ex)
Nominal Discharge Current (mA) 0.2 0.2
CR2450HR T43
φ24
.5
(0.2)1.8 20.5
3.5
- +
25
2.8
(5.0)
10.63.5
2-C0.5
Applications
� TPMS (Tire-Pressure Monitoring System) � ETC (Electronic Toll Collection System) � Set-Top Boxes � OA Machines (Fax, Copiers, Printers) � Notebook PCs � Desktop PCs � Medical Instruments, Cash Registers � FA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors) � Electronic Meters (Water, Gas, Electricity)
: Horizontal & Through hole Type
: Tin plating
External Dimensions (unit : mm)
16
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
CR2450HR-Ex (525mAh)
CR2450HR (550mAh)
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
101 102 103 104 105
Temperature: 20 deg. C
Discharge capacity (mAh)
Temperature: 20 deg. C
Vol
tage
(V)
Discharge current (mA)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
1M�
600
500
400
300
200
100
00.1 1 10
100 deg. C
3.5
3.0
2.5
2.0
1.5
Vol
tage
(V)
1
Discharge duration time (h)
3.9k� 15k� 150k� 300k�
3.5
3.3
3.1
2.9
2.7
2.5
2.3
2.1
1.9
1.7
1.50 50 100 150 200 250 300 350 400 450 500 550
300� 5 sec
1M� continuous
60 deg. C/80 deg. C
20 deg. C
–10 deg. C
Discharge duration time (h)
Vol
tage
(V)
Discharge load: 15 k�3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.00 500 1000 1500 2000 2500 3000 3500
20 deg. C60 deg. C
80 deg. C
100 deg. C
–10 deg. C
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Relationship between Discharge Current and Discharge Capacity
Discharge capacity (mAh)
Temperature: 20 deg. C
Vol
tage
(V)
Discharge current (mA)
Dis
char
ge c
apac
ity (m
Ah)
Final voltage: 2.0V
1M�
300� 5sec
600
500
400
300
200
100
00.1 1 10
–10 deg. C
20 deg. C
80 deg. C
60 deg. C
100 deg. C
3.5
3.0
2.5
2.0
1.5
Vol
tage
(V)
Temperature: 20 deg. C
Discharge duration time (h)
3.5
3.3
3.1
2.9
2.7
2.5
2.3
2.1
1.9
1.7
1.50 50 100 150 200 250 300 350 400 450 500 550
1M� continuous
300� 5sec
101 102 103 104 1051
3.9k� 15k� 150k� 300k�
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
Vol
tage
(V)
Discharge load: 15 k�
0 500 1000 1500 2000 2500 3000 3500
Discharge duration time (h)
60 deg. C 80 deg. C
100 deg. C–10 deg. C
20 deg. C
300� 5 sec
17
CR
The cylindrical lithium manganese dioxide battery (CR battery) features high capacity and excellent load characteristics due to Maxell’s unique winding method and improved electrical-conductivity structures. Because of its high-reliability, this battery is ideal for industrial use in, for example, security equipment and the power source of electronic meters.
�High capacity batteriesMaxell’s unique winding method and effective utilization of positive and negative electrodes realize high capacity.�Low self-discharge rate and long battery lifeA laser seal structure ensures air tightness. Minimized electrode surface areas reduce the self-discharge rate.�Superior storage characteristicsThe optimization of positive materials and employment of a high-reliability sealing structure stabilize pulse discharge characteristics over a wide usable temperature range after long-time storage or discharge.
The cylindrical lithium manganese dioxide battery uses manganese dioxide (MnO2) as its positive active material, and lithium (Li) as its negative active material.
Overview
Construction
Principle and Reactions
Products
Features
� Security Devices � Home Fire/Smoke Alarms
� Electronic Meters (Water, Gas, Electricity)� Memory Backup Power
Applications
�Battery Reactions
Positive reaction: MnO2�Li+�e– � MnOOLi
Negative reaction: Li � Li+�e–
Total reaction: MnO2�Li � MnOOLi
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.** Nominal capacity indicates duration until the voltage drops down to 2.0V when discharged at a nominal discharge current at 20 deg. C.
Model
Nominal Voltage (V)
Nominal Capacity (mAh)**
Nominal Discharge Current (mA)
Operating Temperature Range (deg. C)
Weight (g)*
Dimensions* Diameter (mm) X Height (mm)
CR17450
3
2600
5
–40 to +85
22
17 X 45
CR17335
3
1750
5
–40 to +85
16
17 X 33.5
Collector (Copper Foil)
Separator
Gas Release VentPositive Terminal
Collector
Gasket
Laser Seal
Negative Electrode(Lithium)
Positive Electrode(MnO2)
Negative Can
Cylindrical Lithium Manganese Dioxide Battery
0.75
4
4
( 45
)0.
30.
3
4.5
0.75
4
4
4.5
CR17335 WK 11
External Dimensions (unit : mm)CR17450 VO-T3 CR17450 WK 41 CR17335 VO-T3
50
48±
2
(−)(+)
ø17
Housing : PHR-2(JST)Contact : SPH-002T-P0.5S(JST)Lead Wire : AWG26
Insulation sleeve
( 33.
5 )
0.3
0.3
0.75
4
4
4.5
0.75
4
4
4.5
Insulation sleeve
36.5
50
(−)(+)
ø17
Housing : PHR-2(JST)Contact : SPH-002T-P0.5S(JST)Lead Wire : AWG26
: Tin plating : Wire connector Type: Horizontal & Through hole Type
18
L I T H I U M M A N G A N E S E D I O X I D E B A T T E R Y
CR17450 (2600mAh)
CR17335 (1750mAh)
2.0
2.2
2.4
2.6
2.8
3.0
3.2
3.4
Depth of discharge (%)
*After storage for 28 days at 80 deg. C **After storage for 57 days at 80 deg. C
2600 mAh: 100%
0 20 40 60 80
Minimum voltage for 0.1 second of 300 mA pulse discharge
Vol
tage
(V)
Discharge capacity (mAh)
Vol
tage
(V)
Discharge current: 5mA, Discharge temperature.: 20 deg.C
� Pulse Discharge Characteristics � Storage Characteristics
3.4
3.2
3.0
2.8
2.6
2.4
2.2
2.00 500 1000 1500 2000 2500 3000
Storage period 0 year 5 equivalent years* 10 equivalent years**
Temperature: 20 deg. C
� Discharge Characteristics � Temperature Characteristics
2.0
2.2
2.4
2.6
2.8
3.0
3.2
3.4
0 500 1000 1500 2000 2500 3000 0 500 1000 1500 2000 2500 3000
Discharge capacity (mAh)
Temperature: 20 deg. C
Vol
tage
(V)
2.0
2.2
2.4
2.6
2.8
3.0
3.2
3.4
Discharge capacity (mAh)
Continuous discharge at 40mA
Vol
tage
(V)
5mA
300mA
200mA
40mA 20 deg. C
100mA
50 deg. C
0 deg. C–10 deg. C
Batteries stored for10 equivalent years**
Batteries stored for4 equivalent years*
*After storage for 22 days at 80 deg. C, **After storage for 57 day's at 80 deg. C
Initial batteries
2.8
2.7
2.9
3.0
3.1
3.2
3.3
3.4
Depth of discharge (%)
*After storage for 28 days at 80 deg. C **After storage for 57 days at 80 deg. C
1750 mAh: 100%
0 20 40 60 80
Minimum voltage for 0.1 second of 30 mA pulse discharge
Vol
tage
(V)
Discharge capacity (mAh)
*After storage for 57 days at 80 deg. C
Vol
tage
(V)
Discharge current: 5mA, Discharge temperature.: 20 deg. C
� Pulse Discharge Characteristics
� Discharge Characteristics � Temperature Characteristics
� Storage Characteristics
2.0
2.2
2.4
2.6
2.8
3.0
3.2
3.4
0 500 1000 1500 2000Discharge capacity (mAh)
Temperature: 20 deg. C
Vol
tage
(V)
2.0
2.2
2.4
2.6
2.8
3.0
3.2
3.4
0 500 1000 1500 2000
Vol
tage
(V)
3.4
3.2
3.0
2.8
2.6
2.4
2.2
2.00 500 1000 1500 2000
Discharge capacity (mAh)
Continuous discharge at 30mA
5mA
100mA200mA
30mA
Temperature: 20 deg. C
Storage period 0 year 5 equivalent years* 10 equivalent years**
Initial
Batteries stored for10 equivalent years*
20 deg. C
0 deg. C–10 deg. C
ERLithium Thionyl Chloride Battery (Li/SOCI2)
With Terminals and Wire Connectors
(ER18/50 / ER17/50 / ER6 / ER6C / ER17/33 / ER3 / ER3S)
L I T H I U M T H I O N Y L C H L O R I D E B A T T E R Y
19
20
Warnings
�Never swallow.Always keep the battery out of the reach of infants and young children to prevent it from being swallowed. If swallowed, consult a physician immediately.
�Never apply an excessive force to the positive terminal.Because the positive terminal is sealed by a glass, subjecting this area to sudden jolts and excessive force (over 19.6 N) could destroy the glass seal. This could cause leakage and the generation of irritating/corrosive gases.
�Never drop.Dropping the battery could destroy the glass seal leading to leakage and the generation of irritating/corrosive gases.
�Never weld the terminals or weld a wire to the body of the battery directly.
The heat of welding or soldering could cause the lithium to melt, or cause damage to the insulating material in the battery, leading to possible distortion, leakage, overheating, explosion, or fire, or generation of irritating/corrosive gases. When soldering the battery directly to equipment, solder only the tabs or leads. Even then, the temperature of the soldering iron must be below 350 deg. C and the soldering time less than 5 seconds. Do not use a soldering bath, because the circuit board with battery attached could stop moving or the battery could drop into the bath. Moreover do not use excessive solder, because the solder could flow to unwanted portions of the board, leading to a short-circuit or charging of the battery.
�Never short-circuit the battery.Do not allow the positive and negative terminals to short-circuit. Never carry or store the battery with metal objects such as a necklace or a hairpin. Do not take multiple batteries out of the package and pile or mix them when storing. Otherwise, this could lead to distortion, leakage, overheating, and explosion of the battery.
�Never charge.The battery is not designed to be charged by any other electrical source. Charging could generate gas and internal short-circuiting, leading to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases.
�Never forcibly discharge.Forcibly discharging by an external power source or other batteries could cause the voltage to fall below 0V (reversing the poles), generating gas inside the battery and leading to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases.
�Never heat.Heating the battery to more than 100 deg. C could increase the internal pressure, causing distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases.
�Never expose to open flames.Exposing to flames could cause the lithium metal to melt, causing the battery to catch on fire and explode.
�Never disassemble the battery.Disassembly could generate the irritating/corrosive gases. In addition, the lithium metal inside the battery could overheat, leading to catch on fire.
�Never deform.Deforming could cause leakage, overheating, explosion, fire, or generation of irritating/corrosive gases.
�Never reverse the positive and negative terminals when mounting.
Improper mounting of the battery could lead to short-circuiting, charging or forced-discharging. This could cause distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases.
�Never use different batteries together.Using different batteries together, i.e. different type or used and new or different manufacturer could cause distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases because of the differences in battery property. If using two or more batteries connected in series or in parallel even same batteries, please consult with Maxell before using.
�Never allow liquid leaking from the battery to get in your eyes or mouth.
Because this liquid could cause serious damage, if it does come in contact with your eyes, flush them immediately with plenty of water and consult a physician. Likewise, If the liquid gets in your mouth, rinse immediately with plenty of water and consult a physician.
�Never touch the battery electrodes.Do not allow the battery electrodes to come in contact with your skin or fingers. Otherwise, the moisture from your skin could cause a discharge of the battery, which could produce certain chemical substances causing you to receive a chemical burns.
Warnings Circuit Design for Back-up Use
Handling
This is a primary battery and cannot be charged. If used in memory or RTC back-up applications, be sure to use diodes to prevent charging from the main power source or other batteries, and a protective resistor to regulate the current as shown in the figure below. Note that the points described below should be taken into careful consideration when selecting diodes and protective resistors.
�Supplied voltage to loadBecause a diode and a resistor generate the voltage drop on operating, please take into consideration these voltage drops for supplied voltage to load.
�Using diodes to prevent chargingPlease choose diodes with leak current of no more than 0.5μA.
Safety InstructionsThis battery is a high energy density sealed battery containing dangerous (Lithium) and deleterious (Thionyl Chloride) materials. For this reason, improper handling of the battery could lead to distortion, leakage*, overheating, explosion, fire, or generation of irritating/corrosive gases, causing bodily injury or equipment trouble. Please observe the following instructions to prevent accidents. For from your customers to your industrial waste processors (including recycled processor), please have them fully understand these instructions.(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Do not recharge
Load+5VDiode
Protective resistor
Battery
Example (A)
Diode
Example (B)
Load+5VDiode
Protectiveresistor
Battery
Diode
Diode
21
ER
�Using and setting protective resistorsA protective resistor is used to prevent the battery from being charged by large surges of current during diode failure. Please set the resistor so that the maximum current shown in the right table is not exceeded. For example, say an ER6 battery is used in sample circuit A in combination with a main power source 5 volt. Since the permitted charge current is 100μA and this battery’s voltage is 3.6V, let the resistor be R>= (5V-3.6V)/100μA=14k ohm, meaning that at least 14k ohm is required.
Note: If the diodes broke down, it is necessary for safety to replace them as soon as possible even though using a protective resistor. Considering the trouble of diodes and resistors, other safety measures should be incorporated in the circuit design.
Warnings Disposal
The battery may be regulated by national or local regulation. Please follow the instructions of proper regulation. As electric capacity is left in a discarded battery and it comes into contact with other metals, it could lead to distortion, leakage, overheating, or explosion, so make sure to cover the (+) and (-) terminals with friction tape or some other insulator before disposal.
Caution Handling
�Minimum transient voltage The various tests have shown that the minimum transient voltage is influenced greatly by the actual conditions of use and storage Therefore, please design your circuits using no more than the standard discharge current, taking into account the voltage drop due to the minimum transient voltage. Please consult with Maxell beforehand if you are unsure of anything.
�Installing, removing, and disposing of batteries1) When installing a battery in a device, make sure that the positive terminal is facing up, or at least to the side. As this battery uses liquid thionyl chloride as the positive active material, placing the positive terminal at the bottom will cause the thionyl chloride to become maldistributed, which could prevent the needed performance from being obtained when a large amount of current is used.2) Please have the installation, removal, and disposal of this battery performed by a technician with a thorough understanding of the Warnings and Cautions on handling.
�StorageAvoiding storing the battery in direct sunlight, or in excessively hot and humid locations, and store it out of the way of rainwater and other adverse environmental elements.
�Bundling When bundling the battery with a product, be sure to use cushioning and other packing to protect the battery (and especially the positive terminal) from jolts and shocks during transportation.
TypeER18/50ER17/50
ER6ER6C
ER17/33ER3
ER3S
Maximum Current125μA125μA100μA100μA70μA50μA40μA
(Example of battery insulation)
Tape
+
–
Tape
Lithium Thionyl Chloride Battery
L I T H I U M T H I O N Y L C H L O R I D E B A T T E R Y
22
The lithium thionyl chloride battery uses liquid thionyl chloride (SOCl2) as its positive active material, and lithium (Li) as its negative active material. The reactions of the battery are shown below.
Products
�Battery Reactions
Positive reaction: 2SOCl2+4Li++4e-�4LiCl+S+SO2
Negative reaction: Li�Li++e-
Total reaction: 2SOCl2+4Li�4LiCl+S+SO2
PositiveTerminal
(+)
(–)
Metal Lid
Metal Can
Top LidNegativeElectrode
PositiveElectrode
Separator
BottomInsulator
NegativeTerminal
Resin Seal
Melt Seal
Glass Seal
Positive Collector
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.** Nominal capacity indicates duration until the voltage drops down to 3.0V when discharged at a nominal discharge current at 20 deg. C.• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
This battery is ideal for such long-term applications as power for electronic devices and electric power, water, and gas meters, and especially as a backup power source for memory ICs.
The ER battery is for industrial use only.When replacement is necessary, please contact the manufacturer of your equipment.
Overview
�High 3.6-V voltageThe lithium thionyl chloride battery achieves a high voltage of 3.6 V.�Flat discharge characteristicsThe change of internal resistance during discharge is minimal, allowing for flat discharge voltage until end of discharge life.�High energy densityProvides high energy density of 970m Wh/cm3 with discharge current of 100μA (ER6 type).�Wide usable temperature rangeCan be used over a wide temperature range : - 55 deg. C to +85 deg. C (please consult with Maxell if using in temperatures of -40 deg. C or less).�Superior long-term reliabilityThe extremely low self-discharge, together with the use of a hermetic seal, allows for stable use over long periods.
Features
Principle and ReactionsConstruction
ER18/50 ER6 ER6C ER17/33 ER3 ER3SModel
3.6 3.6 3.6 3.6 3.6 3.6Nominal Voltage (V)
3,650 2,000 1,800 1,600 1,100 790Nominal Capacity (mAh)**
125 100 100 75 40 35Nominal Discharge Current (μA)
18 14.5 14.5 17.0 14.5 14.552.6 53.5 51 35 29.9 26Dimensions*
22
ER17/50
3.6
2,750
125
1752.6
20 15Weight (g)* 15 13 8 7
–55 to +85 –55 to +85 –55 to +85 –55 to +85 –55 to +85 –55 to +85Operating Temperature Range (deg. C) –55 to +85
Diameter (mm) Height (mm)
ER
23
Applications
� OA Machines (Fax, Copiers, Printers) � Desktop PCs � PDAs � Medical Instruments, Cash Registers � FA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors) � Electronic Meters (Water, Gas, Electricity) � ETC (Electronic Toll Collection System)
Storage CharacteristicsThe lithium thionyl chloride battery is made from chemically stable inorganic materials. Additionally, a sealing method employing a laser-welded seal structure and hermetic seal hinders the admittance of outside air. These features provide superior storage characteristics, holding down self-discharge to no more than 1% of capacity per year at normal temperatures.
Vo
ltag
e
Vo
ltag
e
Initial Usage
Minimum Transient VoltageTime
Time
Open Circuit
UL Recognized ComponentsThe lithium thionyl chloride battery is a UL (Underwriters Laboratories Inc.) recognized component. (Technician Replaceable)
Recognized models: ER18/50, ER17/50, ER6, ER6C, ER17/33, ER3, ER3S
Certification Number: MH12568
Relationship between Discharge Load and Operating VoltageThe operating voltage of a battery falls as the discharge load increases and temperature falls. In the case of initial use, an electric potential of at least 3 V will be maintained even at temperatures of -40 deg. C at discharge of less than 1 mA.
Minimum transient voltageThe lithium thionyl chloride battery has remarkably lower self-discharge when compared with conventional batteries. This is because a lithium chloride membrane is formed over the negative lithium surface, blocking reaction with the positive material. When first discharging after storage, resistance from this lithium chloride membrane may temporarily reduce the voltage at the initiation of discharge. The lowest voltage at this time is called minimum transient voltage, and the lower the temperature, and the larger the discharge current, the lower the voltage will be. Because minimum transient voltage is greatly influenced by storage time and conditions, it is necessary to take this into sufficient consideration when designing a device.
The figure above shows minimum transient voltage using a fresh battery.
103
4
3.5
3
2.5
2
1.5
1
0.5
0104
20 deg C–10 deg C–40 deg C
Min
imu
m T
ran
sien
t V
olt
age
(V)
Discharge load (ohm)
ER6
After 3 months at 20 deg. C
103 104
Op
erat
ing
Vo
ltag
e (V
)
Discharge load (ohm)
ER6
4
3
2
1
00 25 50 75 100
Discharge capac i ty (%)
Vo
lta
ge
(V
)
After stored for 200 days at 60 deg. C(equivalent to storage for 10 years at 20 deg. C)
ER6
Temp:20 deg.Cdischarge current: 100 μA
Init ia l
4
3.5
3
2.5
2
1.5
1
0.5
0
20 deg C–10 deg C–40 deg C
After 3 months at 20 deg. C
Lithium Thionyl Chloride Battery
L I T H I U M T H I O N Y L C H L O R I D E B A T T E R Y
ER18/50 (3650mAh)
ER17/50 (2750mAh)
24
200,000
100,000
70,000
50,000
20,000
10,000
7,000
5,000
2,00020 30 50 70 100 200 300 500
10
7
5
4
3
2
1
0.5
Year
60 deg. C
Dis
char
ge d
urat
ion
time
(h)
Discharge current (�A)
10 102 103 104 105 106
102 103 104 105 106
102 103 104 105 106
10
10
Discharge duration time (h)
Discharge duration time (h)
Discharge duration time (h)
1.2mA 120�A 24�A
1.2mA 120�A
1.2mA 1 20�A
24�A
4.0
3.0
2.0
4.0
3.0
2.0
4.0
3.0
2.0
Vol
tage
(V)
Vol
tage
(V)
Vol
tage
(V)
Temperature: 20 deg. C
Temperature: –40 deg. C
Temperature: 60 deg. C
0 1000 2000 3000
Discharge current: 1.2mA Temperature: 20 deg. C
Vol
tage
(V)
4.0
3.0
2.0
1.0
0
After stored for 200 days at 60 deg. C*
Discharge duration time (h)
(*Equivalent to storage at 20 deg. C for 10 years)
Initial
20 deg. C
� Relationship between Discharge Current and Duration Time
� Storage Characteristics
� Discharge Characteristics
10
7543
2
1
0.5
� Relationship between Discharge Current and Duration Time
Year
60 deg. C
Dis
char
ge d
urat
ion
time
(h)
Discharge current (�A)
10 102 103 104 105 106
102 103 104 105 106
102 103 104 105 106
10
10
Discharge duration time (h)
Discharge duration time (h)
Discharge duration time (h)
1.2mA 120�A 24�A
1.2mA 120�A
1.2mA 20�A
24�A
4.0
3.5
2.5
1.5
3.0
2.0
4.0
3.0
2.0
4.0
3.0
3.5
2.0
2.5
Vol
tage
(V)
Vol
tage
(V)
Vol
tage
(V)
Temperature: 20 deg. C
Temperature: –40 deg. C
Temperature: 60 deg. C
� Storage Characteristics
0 1000 2000 40003000
Discharge current: 1.2mA Temperature: 20 deg. CV
olta
ge (V
)4.0
3.0
2.0
1.0
0
After stored for 200 days at 60 deg. C*
Discharge duration time (h)
(*Equivalent to storage at 20 deg. C for 10 years)
Initial
20 deg. C
� Discharge Characteristics1,000,000
100,00070,00050,000
20,000
10,0007,000
5,000
2,000
1,00010 20 30 50 70 100 200 300 500 1000
ER6 (2000mAh)
ER6C (1800mAh)
ER
25
100,000
70,000
50,000
20,000
10,000
7,000
2,000
1,000
5,000
20 30 50 70 100 200 300 500
60 deg. C
Dis
char
ge d
urat
ion
time
(h)
Discharge current (μA)
Temperature: 20 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
Temperature: –40 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
Temperature: 60 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
1mA 100μA 20μA
1mA 100μA 20μA
1mA 100μA
20 deg. C
10
7
54
3
2
1
0.5
Year
0 800 1600 2400
4.0
3.0
2.0
1.0
0
Discharge current: 1mA Temperature: 20 deg. CV
olta
ge (V
)
(*Equivalent to storage at 20 deg. C for 10 years)
Discharge duration time (h)
InitialAfter stored for 200 days at 60 deg. C*
1 10 102 103 104 105
10 102 103 104 105
10 102 103 104 105
1
1
Discharge duration time (h)
Discharge duration time (h)
Discharge duration time (h)
Temperature: 20 deg. C
Temperature: –40 deg. C
Temperature: 60 deg. C
4.0
3.0
2.0
4.0
3.0
2.0
4.0
3.0
2.0
100 μ A1mA 20 μ A
100 μA
100 μ A
1mA
1mA
20 μ A
Vol
tage
(V)
Vol
tage
(V)
Vol
tage
(V)
100,000
70,000
50,000
20,000
10,000
7,000
2,000
1,000
5,000
20 30 50 70 100 200 300 500
Year
60 deg. C
Dis
char
ge d
urat
ion
time
(h)
0 800 1600 2400
4.0
3.0
2.0
1.0
0
Discharge current: 1mA Temperature: 20 deg. C
Vol
tage
(V)
After stored for 200 days at 60 deg. C*
Discharge duration time (h)
(*Equivalent to storage at 20 deg. C for 10 years)
Initial
Discharge current (μA)
107
54
3
2
1
0.5
20 deg. C
� Relationship between Discharge Current and Duration Time
� Storage Characteristics
� Discharge Characteristics
� Relationship between Discharge Current and Duration Time
� Storage Characteristics
� Discharge Characteristics
Lithium Thionyl Chloride Battery
L I T H I U M T H I O N Y L C H L O R I D E B A T T E R Y
ER17/33 (1600mAh)
ER3 (1100mAh)
26
100,000
70,000
50,000
20,000
10,000
7,000
2,000
1,000
5,000
20 30 50 70 100 200 300 500
20 deg. C
60 deg. C
Dis
char
ge d
urat
ion
time
(h)
Discharge current (�A)
0 800 1600 2400
4.0
3.0
2.0
1.0
0
Discharge current: 800μA Temperature: 20 deg. CV
olta
ge (V
)
Initial
Discharge duration time (h)
(*Equivalent to storage at 20 deg. C for 10 years)
Temperature: 20 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
Temperature: –40 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
Temperature: 60 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
80�A800�A 16�A
80�A800�A 16�A
80�A800�A
10
7
54
3
2
1
0.5
Year
After stored for 200 days at 60 deg. C*
0 1000 2000 3000
4.0
3.0
2.0
1.0
0
Discharge current: 400μA Temperature: 20 deg. C
Vol
tage
(V)
Discharge duration time (h)
(*Equivalent to storage at 20 deg. C for 10 years)
InitialAfter stored for 200 days at 60 deg. C*
Temperature: 20 deg. C
40μA
40μA
400μA
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
Temperature: 60 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
8μA
40μA400μA
400μA
8μA
Temperature: –40 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 106105
4.0
3.0
2.0
100,000
70,000
50,000
20,000
10,000
7,000
2,000
1,000
5,000
108 10030 50 200 300 500
60 deg. C
Dis
char
ge d
urat
ion
time
(h)
Discharge current (μA)
10
7
5
4
3
2
1
0.5
Year
20 deg. C
� Relationship between Discharge Current and Duration Time
� Storage Characteristics
� Discharge Characteristics
� Relationship between Discharge Current and Duration Time
� Storage Characteristics
� Discharge Characteristics
ER3S (790mAh)
ER
27
0 800 1600 2400
4.0
3.0
2.0
1.0
0
Discharge current: 400μA Temperature: 20 deg. CV
olta
ge (V
)
(*Equivalent to storage at 20 deg. C for 10 years)
Discharge duration time (h)
Initial
Temperature: 20 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
Temperature: –40 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
Temperature: 60 deg. C
Discharge duration time (h)
Vol
tage
(V)
1 10 102 103 104 105
4.0
3.0
2.0
100,000
70,000
50,000
20,000
10,000
7,000
2,000
1,000
5,000
108 30 50 70 100 200 300 500
60 deg. C
20 deg. C
Dis
char
ge d
urat
ion
time
(h)
Discharge current (μA)
10
7
5
4
3
2
1
0.5
Year
After stored for 200 days at 60 deg. C*
400μA 40μA 8μA
400μA 40μA 8μA
400μA 40μA
� Relationship between Discharge Current and Duration Time
� Storage Characteristics
� Discharge Characteristics
Lithium Thionyl Chloride Battery
External Dimensions (unit : mm)ER6 #2 PCER17/50 #2 PCER18/50 #2 PC
ø0.6
3
ø14.5
(53.
5)0.
75
0.25
7.5
7.5
47.654
.7
(+)
(–)
ø0.6
3
ø17 (52.
6)0.
75
0.25
6.5
47.7
53.8
(+)
(–)
6.5
ER6K-#17
Housing:Contact:Lead wire:
XHP-2 (JST)SXH-001GH-P0.6 (JST)AWG26
57.3 100
(+)1(–)2
LoopHook
1815
.2
ER6C #2 PC(2) ER6C WKP
ø0.6
3
ø14.5
(51)
0.75
0.25
7.5
7.5
44.552
(+)
(–)
1(+)2(–)
3.5
8.5
45.0
6.0
11.5
ø14.5 100
Plastic capInsulation sleeve
Housing:Contact:Lead wire:
HNC-2.5S-2 (Hirose)HNC-2.5S-C-B(0.3) (Hirose)AWG26
53.0
ER3S #2 PC ER3S WKP ER3SR #12
0.75
7.5
7.5
ø14.5
0.25
ø0.6
3
21.328
.5
(26)
(+)
(–)
ER17/33 #2 PC
ø0.6
3
ø17 (35)
0.75
0.25
6.5
6.5
30.1
36.2
(+)
(–)
ER17/33 WKP
36
8.5
30
5.2
ø17
MAX18.2
100
(+)
(–)
1(+)2(–)
Plastic cap
Insulation sleeve
Housing:Contact:Lead wire:
HNC2-2.5S-2 (Hirose)HNC-2.5S-C-B(03) (Hirose)AWG26
PKW 3RECP 2# 3RE
ø0.6
3
ø14.5 (29.
9)0.
75
0.25
7.5
7.5
2431.1
(+)
(–)
1(–)
2(+
)3.5
8.5
31.0
24.6
6.0
ø14.
9
11.5
55
MAX17
3.5
8.5
29.3
21.9
6.0
90
11.5
ø14.
9
MAX17.0
(+)
2(+
)1(
–)
Housing:Contact:Lead wire:
IL-2S-S3L-(N) (JAE)IL-C2-1-1000 (JAE)AWG24
Housing:Contact:Lead wire:
IL-S-2S-S2C2- SIL-S-C2-1-10000AWG26
Housing: 2695-02RPContact: 2759 GSLead wire: UL1007 AWG26
L I T H I U M T H I O N Y L C H L O R I D E B A T T E R Y
28
ø16.4 63
POS 1(–)POS 2(+)
ø0.6
3
ø18
0.75
6
6.5
47.7
53.8
(53.
6)
28
With Terminals and Wire Connectors
: Tin plating
: Horizontal & Through hole Type
: Wire connector Type
ICPLithium Ion Rechargeable Battery
L I T H I U M I O N R E C H A R G E A B L E B A T T E R Y
ICP403450AR / ICP463443SR / ICP463446AR / ICP463450AR /
ICP483640SR / ICP533640SR / ICP553443AR
ICP553446AR / ICP553450SR / ICP653047AS / ICP653443AR /
ICP653450AR / ICP783640SR / ICP803443AR
33
• Insulate (+) and (–) terminals with tape.• Do not remove coating.• Do not expose to rain or water.• Do not disassemble.• Do not leave under strong sunshine.• Store in rugged receptacle and cover with a lid.
Charge 0 deg. C to +45 deg. CDischarge -20 deg. C to +60 deg. CStorage (less than 30 days) -20 deg. C to +50 deg. CStorage (less than 90 days) -20 deg. C to +35 deg. C
Notes for treating used batteries
34
Danger
�Do not dip or wet the battery in water, seawater, or other liquid. Otherwise the battery may be shorted, which may generate heat or cause damage.
�Do not put the battery into a fire. Otherwise, the electrolyte may burn or cause an explosion.
�Do not heat the battery. Otherwise the electrolyte may boil and resin parts may melt, causing leakage, explosion or fire.
�The battery has a predetermined polarity. If the battery will not connect well to the charger or equipment, do not try to connect the battery forcefully. Check the polarity first. If the battery is connected in reverse, it will be charged in reverse and may cause leakage, heat generation, explosion or fire due to an abnormal chemical reaction.
�Do not connect the battery in reverse relation to the positive (+) and negative (-) terminals in the charger or equipment. If the battery is connected in reverse, it will be charged in reverse, discharge excessive current and may cause heat generation, explosion or fire due to an abnormal chemical reaction.
�Do not let the battery terminals (+ and -) come into contact with a wire or any metal (like a metal necklace or a hairpin) with which it is carried or stored. In such a case, the battery will be shorted and discharge excessive current, which may result in heat generation, explosion or fire.
�Do not apply any heavy impact to the battery, throw or drop it. Otherwise the battery may be shorted and result in heat generation, explosion or fire.
�Do not drive a nail into, hammer or stamp on the battery. Otherwise the battery may be shorted and result in heat generation, explosion or fire.
�Do not solder the battery directly. Heat applied during soldering may melt resin parts such as separator or gasket, and result in leakage, heat generation, explosion or fire.
�Do not disassemble or alter the battery. Otherwise the battery may be shorted and result in heat generation or fire.
�Do not use or leave the battery near fire, heaters, inside an automobile in hot weather or under strong sunshine. Such conditions of high temperature may damage the separator, and the battery may be shorted and result in heat generation, explosion or fire.
�When charging the battery, do not use any battery charger not specified by the manufacturer. Always follow the charge conditions specified by the manufacturer. If the battery is charged under other conditions (a high temperature, a high voltage/current or an altered charger) not specified by the manufacturer, the battery may cause heat generation, explosion or fire due to abnormal chemical reactions.
�Do not connect the battery directly to an electric outlet or cigarette lighter socket in a car. Applying a high voltage may generate an excessive current and cause an electric shock. In such a case, the battery may leak electrolyte, overheat, explode or cause fire.
Warnings�Do not put the battery in a microwave oven or a pressure cooker.
Sudden heat may damage the seal of the battery and may cause heat generation, explosion or fire.
�Do not use the battery together with a primary battery such as a dry battery or other battery of a different capacity, type and/or brand. In such a case, over-discharge during use or over-charge during charging may occur and abnormal chemical reactions may cause heat generation, explosion or fire from the battery.
�If you notice any unusual odor, heat, discoloration, deformation or any other characteristic apart from what you are used to while using, charging or storing the battery, then take it out of the equipment or charger, and avoid using it. Using it in such state may result in heat generation, explosion or fire.
�If the battery leaks or emits an unusual odor, remove it from the vicinity of any fire immediately. The electrolyte may catch fire, which may cause heat generation or explosion.
�Do not let leaked electrolyte come into contact with the eyes. In the event of such contact, flush the eyes with plenty of water immediately and consult a doctor. Otherwise prolonged contact may cause serious injury.
Caution�If the battery leaks and its electrolyte comes into contact with skin
or clothes, wash the contact area well with tap water or other clean water right away. Otherwise skin may break out in a rash.
�When the battery is expected not to be used for a long time, take the battery out of the equipment or device and store it in a less humid area.
�After long periods of storage without being used, the battery should be charged before it is used. Charge the battery every 6 months to the level specified by the manufacturer, even if the battery is not used.
�Do not leave the battery pack connected to the charger. It may cause the degradation of battery performance, such as a shortening of battery life.
�Turn off your equipment or device power switch after use.
�Do not use the battery in other than the following temperature ranges:
Safety InstructionsImproper use of the battery may cause heat, fire, explosion, damage or reduced battery capacity. Please read and follow the handling instructions for the battery before and during usage. The followings are general cautions and guidelines only and as such may not include every possible usage scenario. The manufacturer will not be liable for actions taken or accidents caused by any usage not documented below.
35
Maxell has concentrated its original technologies accumulated during the development of various products such as magnetic tapes, IC cards and memory cards, as well as its battery technology into Maxell’s lithium ion batteries. With Maxell’s unique manufacturing technology and quality control system, including carefully selected electrode materials, sealing technology, and micron-order accuracy control, Maxell has developed lithium ion batteries featuring various excellent characteristics and high reliability.
Overview
Products
Notes for Designers
Note
ICP
Start charge
Constant current, constant voltage charge• Current monitoring• Temperature monitoring• Time monitoring
Failed
Failed
Passed
Passed
Select the correct type of battery to match the operating conditions such as load current, etc.
�Charge ConditionsTo get the most out of lithium-ion batteries and use them safely, please read the following requirements carefully:
This brochure introduces lithium-ion cells only. Maxell offers these cells in battery pack format only, which include electronic circuits to prevent overcharge, overdischarge and so on. These battery packs are custom-developed and produced according to special requirements regarding operating conditions and specifications. As a result, a minimum number of units may apply to such customized orders from customers purchasing battery packs. For details, consult your nearest Maxell dealer or distributor.
�Charge Control Flowchart (sample)Refer to the following flowchart when designing constant current and constant voltage battery chargers.
Charge Mode Constant Current, Constant Voltage Charge
Charge Voltage 4.20V±0.05V / cell
Max. Charge Current 1C
Charge Time Approx. 3 hours
Charge Temperature 0 to +45 deg. C
Lithium Ion Rechargeable Battery
Check battery connection
Check battery temperature
Check battery voltage
Charge completion
Preliminary charge
Abnormal charge stop
Cell Type ICP403450AR ICP463443SR ICP463446AR ICP463450AR ICP483640SR ICP533640SR ICP553443AR
Dimensions*1Thickness 3.9±0.2 4.4±0.2 4.4±0.2 4.4±0.2 4.6±0.2 5.0±0.3 5.2±0.3
Width 33.7±0.2 33.8±0.2 33.8±0.2 33.8±0.2 35.8±0.2 35.8±0.2 33.8±0.2(mm)Height 49.7+0/-0.5 42.95+0/-0.5 46.0+0/-0.5 49.6+0/-0.5 40.0+0/-0.5 40.0+0/-0.5 42.8+0/-0.5
Weight (g)*2 16 15 16 18 17 18 18
Charge Max. Voltage (V) 4.2 4.2 4.2 4.2 4.2 4.2 4.2(CCCV) Max. Current (A) 0.80 0.79 0.82 0.92 0.82 0.90 0.92
Discharge End Voltage (V) 2.75 2.75 2.75 2.75 2.75 2.75 2.75(CC) Max. Current (A) 1.20 1.19 1.23 1.38 1.23 1.35 1.38
Nominal Voltage (V) 3.7 3.7 3.7 3.7 3.7 3.7 3.7
Minimum Capacity (mAh)*3 800 790 820 920 820 900 920
Cell Type ICP553446AR ICP553450SR ICP653047AS ICP653443AR ICP653450AR ICP783640SR ICP803443AR
Dimensions*1Thickness 5.2±0.3 5.2±0.3 6.2±0.3 6.2±0.3 6.2±0.3 7.5±0.3 7.7±0.3
Width 33.8±0.2 33.8±0.2 30.0±0.2 33.8±0.2 33.8±0.2 35.8±0.2 33.8±0.2(mm)Height 46.0+0/-0.5 49.6+0/-0.5 47.1+0/-0.5 42.6+0/-0.5 49.6+0/-0.5 40.0+0/-0.5 42.6+0/-0.5
Weight (g)*2 19 21 20 21 24 25 25
Charge Max. Voltage (V) 4.2 4.2 4.2 4.2 4.2 4.2 4.2(CCCV) Max. Current (A) 1.00 1.15 1.00 1.10 1.20 1.34 1.35
Discharge End Voltage (V) 2.75 2.75 2.75 2.75 2.75 2.75 2.75(CC) Max. Current (A) 1.50 1.73 1.50 1.65 1.80 2.01 2.03
Nominal Voltage (V) 3.7 3.7 3.7 3.7 3.7 3.7 3.7
Minimum Capacity (mAh)*3 1000 1150 1000 1100 1200 1340 1350
Positive electrode: Lithium cobalt dioxide, Negative electrode: Graphite*1: Dimensions of fresh cell without tube.*2: Approximate value*3: Capacity is according to the following conditions: Charge CCCV: 1C/4.2V/3h, Discharge 0.2C/E.V.=2.75V, Temperature 25 deg. CAbove specifications are subject to change without notice. For more detailed information and availability, please consult your Maxell representative.
36
Cell Structure
Features
�Charge Characteristics
Characteristics (ICP553450SR)
�Higher operating voltage of 3.7V and energy densityA lithium-ion battery delivers and maintains a stable operating voltage of over 3.7V until final discharge — three times as much voltage as a Ni-Cd or Ni-MH battery provides. It takes just 1/3 the number of lithium-ion batteries to provide the equivalent amount of voltage from Ni-Cd or Ni-MH batteries, so portable devices can be made much smaller and lighter.
�Higher discharge rate for more powerful devices Lithium-ion batteries are capable of outstanding rates of discharge sufficient to power a hard disk, a video camera’s motor and other devices.
�Stable discharge under various temperatures environmental conditions
Lithium-ion batteries provide stable discharge within a wide range of temperatures, from –20 deg. C to +60 deg. C.
�Superior storage characteristics and convenience including minimal self-discharge
Lithium-ion batteries limit self-discharge to less than 5% of the original capacity per month when batteries are stored at 20 deg. C.
�Excellent cost performanceSuperior recharging properties ensure a service life of about 500 charge/discharge cycles under normal usage conditions. The superior cost/performance ratio ensures that lithium-ion batteries are ultimately more economical than primary batteries.
L I T H I U M I O N R E C H A R G E A B L E B A T T E R Y
�Discharge Load Characteristics
�Discharge Temperature Characteristics
�Cycle Life Characteristics
� Mobile Phones � PHS � PDAs � Electronic Dictionaries � Camcorders � Digital Still Cameras � Digital Audio Players � Portable Game Devices
Applications
Laser Seal
Negative Terminal
Gas Release Vent
Positive Can
Separator
Positive Electrode
Negative Electrode
0 30 60 90 120 180150
4.5
4.0
3.5
3.0
2.5
2.0
Cel
l Vol
tage
(V)
Time (min)
100
80
60
40
20
0
1500
1200
900
600
300
0
Cha
rge
cap
acity
(%)
Cha
rge
curr
ent
(mA
)
Cell Voltage
Charge Current
Charge:1150mA(1C)/4.2V (CC-CV)Temperature: 25 deg. C
Charge Capacity
0 200 400 600 800 1000 1200
4.5
4.0
3.5
3.0
2.5
Cel
l vol
tage
(V)
Capacity (mAh)
Charge: 1150mA(1C)/4.2V(CC-CV)/2.5hDischarge: 0.2C, 0.5C,1C (E.V.=2.75V)Temperature: 25 deg. C
0.5C (575mA)
0.2C (230mA)
1C (1150mA)
0 200 400 600 800 1000 1200
4.5
4.0
3.5
3.0
2.5
Cel
l vol
tage
(V)
Capacity (mAh)
0 deg. C
Charge: 1150mA(1C)/4.2V(CC-CV)/2.5h/25 deg. CDischarge: 230mA(0.2C) (E.V.=2.75V)
25 deg. C60 deg. C-10 deg. C -20 deg. C
0 100 200 300 400 500Cycle number (cycle)
1200
1000
800
600
400
200
0
Cap
acity
(mA
h)
Charge: 1150mA(1C)/4.2V(CC-CV)/2.5hDischarge: 1150mA(1C) (E.V.=2.75V)Temperature: 25 deg. C
MLLITHIUM MANGANESE DIOXIDE RECHARGEABLE BATTERY
ML2032 / ML2016 / ML1220
With Terminals and Wire Connectors (ML2032 / ML2016 / ML1220)
L I T H I U M M A N G A N E S E D I O X I D E R E C H A R G E A B L E B A T T E R Y
37
38
Warnings
Warnings
�Never swallow.Always keep the battery out of the reach of infants and young children to prevent it from being swallowed. If wallowed, consult a physician immediately.
�Do not replace.Depending on the battery manufacturer, there might be major differences in performance even among the same types or models of batteries. If you are an equipment manufacturer and need to replace the battery, please use a new one of the same type and same model as the existing one. Because this is a rechargeable battery, its characteristics are completely different from a primary battery even though their shapes are alike. If a primary battery is installed in the circuit in place of a rechargeable battery, gas could be generated or the primary battery could be short-circuited by charging. This could lead to distortion, leakage, overheating, explosion, or fire. Please design your equipment so that the end user cannot replace the battery by mistake.
�Never use two or more batteries connected in series or in parallel.If batteries are connected together, it is very difficult to design a circuit to observe whether or not the batteries are charged at specified voltage or current as described in "Warning -Circuit Design".
�Never reverse the positive and negative terminals when mounting.
Improper mounting of the battery could lead to equipment trouble or short-circuiting. This could cause distortion, leakage, overheating, explosion, or fire.
�Never short-circuit the battery. Do not allow the positive and negative terminals to short-circuit. Never carry or store the battery with metal objects such as a necklace or a hairpin. Do not take multiple batteries out of the package and pile or mix them when storing. Please be careful when installing the battery not to short-circuit it with metal portions of the equipment. Otherwise, this could lead to distortion, leakage, overheating, explosion, or fire.
�Never heat. Heating the battery to more than 100 deg. C could increase the internal pressure, causing distortion, leakage, overheating, explosion, or fire.
�Never expose to open flames. Exposing to flames could cause the lithium metal to melt, causing the battery to catch on fire and explode.
�Never disassemble the battery.Do not disassemble the battery, because the separator or gasket could be damaged, leading to distortion, leakage, overheating, explosion, or fire.
�Never weld the terminals or weld a wire to the body of the battery directly.
The heat of welding or soldering could cause the lithium to melt, or cause damage to the insulating material in the battery, leading to possible distortion, leakage, overheating, explosion, or fire. When soldering the battery directly to equipment, solder only the tabs or leads. Even then, the temperature of the soldering iron must be below 350 deg. C and the soldering time less than 5 seconds. Do not use a soldering bath, because the circuit board with battery attached could stop moving or the battery could drop into the bath. Moreover do not use excessive solder, because the solder could flow to unwanted portions of the board, leading to a short-circuit or charging of the battery.
�Never allow liquid leaking from the battery to get in your eyes or mouth.
Because this liquid could cause serious damage, if it does come in contact with your eyes, flush them immediately with plenty of water and consult a physician. Likewise, if the liquid gets in your mouth, rinse immediately with plenty of water and consult a physician.
�Keep leaking batteries away from fire.If leakage is suspected or you detect a strong odor, keep the battery away from fire, because the leaked liquid could catch on fire.
�Never touch the battery electrodes.Do not allow the battery electrodes to come in contact with your skin or fingers. Otherwise, the moisture from your skin could cause a discharge of the battery, which could produce certain chemical substances causing you to receive a chemical burns.
�Never set the charge voltage above 3.3V.Charging at a higher voltage could cause the generation of gas, internal short-circuiting, or other malfunctions, leading to distortion, leakage, overheating, explosion, or fire. For details, see the recommended circuits in the figure below.
�Always charge at the nominal currents shown below.Large surges of current could degrade the battery’s characteristics, leading to distortion, leakage, overheating, explosion, or fire. To avoid excessive current at the initiation of charging, make sure to attach a protective resistor for current control. See the recommended circuits below.
�Recommended CircuitsPlease refer to the representative basic circuits shown below. If you have any questions about circuit design, please feel free to contact Maxell.
(How to select a protective resistor for the current control)The maximum charge current flows in the battery when charged at an end voltage of 2V. Therefore, the value of the resistor is calculated using this equation: (R) >= ((Output Voltage of Voltage Regulator) – 2) / (Nominal Charge Current)For example, the S-812C series, which has a maximum input voltage of 18V, or the S-817 series with a maximum input voltage of 10V (Seiko Instruments Inc.) can be used as a voltage regulator. Note 1: If the main power source voltage is stable, the charge voltage can be allotted from main power source divided by the combination of resistors.Note 2: Because the battery height must be changed by charge and discharge cycle, place a minimum of 1mm space between the battery and device or chassis.
Model
Table 1 Nominal Charge Current by Model
Charge Current
ML2032
2mA or lower
ML2016
2mA or lower
ML1220
1mA or lower
Safety InstructionsThis battery contains lithium, organic solvents, and other combustible materials. For this reason, improper handling of the battery could lead to distortion, leakage*, overheating, explosion, or fire, causing bodily injury or equipment trouble. Please observe the following instructions to prevent accidents.(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Handling
Circuit Design
D: Diode, R: Resistor
Load
(3.0-3.3V)
ML
R
D
–
+
GND
VoltageRegulator
To 16V
3.2V>600 ohm>600 ohm>1.2K ohm
3.1V>550 ohm>550 ohm>1.1K ohm
Model
ML2032ML2016ML1220
Output Voltage of Voltage Regulator
Table 2 Example of resistors
ML
39
Products
The coin-type lithium manganese dioxide rechargeable battery is a small, lightweight rechargeable battery. This battery employs specially treated manganese dioxide for the positive material and a lithium-aluminum compound for the negative material. A specially formulated organic electrolyte is also used, yielding excellent discharge characteristics with low self-discharge.
Overview
Construction The coin-type lithium manganese dioxide rechargeable battery is a 3V battery using specially treated manganese dioxide for the positive material, a lithium-aluminum compound for the negative material, and a specially formulated organic electrolyte.
Principle and Reactions
�Charge/Discharge Reactions
Collector
Collector
Negative ElectrodeNegativeCap
Separator
Gasket
Positive CanPositive Electrode
(–)
(+)
LiMnO2�AlMnO2�(Li-Al) Discharge
Charge
Warnings Disposal
The battery may be regulated by national or local regulation. Please follow the instructions of proper regulation. As electric capacity is left in a discarded battery and it comes into contact with other metals, it could lead to distortion, leakage, overheating, or explosion, so make sure to cover the (+) and (-) terminals with friction tape or some other insulator before disposal.
�Use within the rated temperature range of -20 to +60 deg. C.Otherwise the battery's charge and discharge characteristics may be reduced.
�Never expose the battery to ultrasonic sound.Exposing the battery to ultrasonic sound may cause short-circuiting because the inside material is broken into pieces, leading to distortion, leakage, overheating, explosion, or fire.�Never subject the battery to severe shock.Dropping, throwing or stomping on the battery may cause distortion, leakage, overheating, explosion, or fire.�Never use or leave the battery in a hot place such as
under the direct rays of the sun or in a car in hot weather. If you do, this may cause distortion, leakage, overheating, explosion, or fire.�Never allow the battery to come in contact with water.If it does, this may cause the battery to rust or lead to distortion, leakage, overheating, explosion, or fire.�Never store the battery in a hot and highly humid
environment.Doing so may cause the performance of the battery to deteriorate. In certain environments, this may lead to distortion, leakage, overheating, explosion, or fire
Caution Handling/Storage
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.** Nominal capacity indicates duration until the voltage drops down to 2.0V when discharged at a nominal discharge current at 20 deg. C.• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
(Example of battery insulation)
Battery +
–
Tape Do not pile up or mix batteries.
Enlarged view
Electric current flows.
These batteries generate heat.
Model
3Nominal Voltage (V)
25Nominal Capacity (mAh**)
200Nominal Discharge Current (μA)
Dimensions*20
1.6
Discharge Depth of 10%
Discharge Depth of 20%
Diameter (mm)
Height (mm)
Charge, DischargeCycle Lifetime
Weight (g)* 1.8
3
18
100
12.5
2.0
0.7
3
65
200
-20 to +60Operating Temperature Ranges (deg.C) -20 to +60-20 to +60
1,000 (6.5 mAh discharge)(total capacity 6,500 mAh) 300 (13 mAh discharge)
(total capacity 3,900 mAh)
1,500 (2.5 mAh discharge) (total capacity 3,750 mAh)
500 (5 mAh discharge) (total capacity 2,500 mAh)
1,500(1.8 mAh discharge)(total capacity 2,700 mAh)500 (3.6 mAh discharge)
(total capacity 1,800 mAh)
20
3.2
3.0
ML2032 ML2016 ML1220
Lithium Manganese Dioxide Rechargeable Battery
L I T H I U M M A N G A N E S E D I O X I D E R E C H A R G E A B L E B A T T E R Y
40
Fig. 1 Charge Property Fig. 2 Charge/Discharge Cycle Performance
Fig. 4 Overcharge CharacteristicsFig. 3 Low Self-discharge
Fig. 5 High Rate Discharge Characteristics
�Approx. 2.5V operating voltageThe operating voltage is about twice that of nickel cadmium rechargeable batteries. Displays a high discharge voltage of 2.8 V when at 10% of nominal capacity (depth of discharge is 10% or less), when charged at 3.0 to 3.3 V.�Superior charge/discharge cycle characteristics (Fig. 2)Achieves 1,000 cycles of discharging to 10% of nominal capacity (Depth of discharge = 10%). The total discharge capacity is quite high at 100 times nominal capacity.�Wide -20 deg. C to 60 deg. C usable temperature rangeDemonstrates stable operating voltage in temperatures as low as -20 deg. C and as high as 60 deg. C. �Low self-discharge and superior leakage resistance (Fig. 3)Self-discharge at 20 deg. C is no more than 2% per year. Supplies a nominal capacity of about 95% even when stored at 20 deg. C for roughly five years (according to accelerated test conducted by Maxell). And since organic electrolyte is used, the battery has superior leakage resistance (shipped fully charged).�Excellent floating characteristics (Fig. 4)A specially formulated organic electrolyte is employed to provide stable discharge characteristics even if charged for a year at 3.3 V at 20 deg. C (according to accelerated test conducted by Maxell). �Excellent high rate discharge characteristics (Fig. 5)
Features
� Mobile Phones � PHS � OA Machines (Fax, Copiers, Printers) � Notebook PCs � Desktop PCs � PDAs � Camcorders � Digital Still Cameras � Portable CD/MD Players � Watches � Medical Instruments, Cash Registers � FA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors) � Electronic Meters (Water, Gas, Electricity)
Applications
UL (Underwriters Laboratories Inc.) Recognized ComponentsRecognized models ML2032, ML2016, ML1220Certification Number: MH12568
Charge voltage (V)
Discharge duration time (h)
Discharge duration time (h)
Vol
tage
(V)
* equivalent to storage at 20 deg.C for 1 year
ML2032
ML2032
volta
ge (V
)
Depth of discharge (%)
Rec
harg
eab
le c
ycle
num
ber
/ c
ycle
s
Ava
ilab
le d
isch
arge
cap
acity
at
vario
us c
harg
ing
volta
ge (%
)
0
4
3
3.5
3.0
2.5
2.0
1.5
1.0
2
1
2.5 2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4 3.5 0101
102
103
104
20 40 60 80 100
20
40
60
80
100
Recommendedarea
Prohibitedarea
Temp: 20deg.CFV = 2.0V
Cut-off voltage of charge: 3.25VTemperature : 20 deg. C
ML2032
ML1220
ML2016
0 100
Initial
200 300 400 500
Discharge load:15 K�Discharge temperature: 20 deg. C
After charged at 60 deg. Cfor 20 days at 3.3V*
Storage time (days)
Cap
acity
ret
entio
n ra
tio(%
)
(when accelerating 20 days at 60 deg. C equivalent to 1 year at 20 deg.C)
ML2032
050
60
70
80
90
100
50 100 150 200 250
Temperature: 20 deg. C
1mA4mA 3mA 2mA0 10 20 30 40 50 60 70 80
Storage temperature: 60 deg. CDischarge temperature: 20 deg. CLoad: 15 K�
ML2032 (65mAh)
ML2016 (25mAh)
ML3.5
3.0
2.5
2.0
1.5
1.00 2010 30 40 50 60 70 80
Discharge capacity (mAh)
Volta
ge (V
)
Temperature: 20 deg. C
30k�
15k�
240k�
100k�
� Discharge Characteristics
3.5
3.0
2.5
2.0
1.5
1.00 100 200 300 400 500
Discharge duration time (h)
Volta
ge (V
)
Discharge load: 15 k�
–20 deg. C
0 deg. C
60 deg. C
20 deg. C
� Temperature Characteristics
104
103
102
101
100
100 101 102
Disc
harg
e du
ratio
n tim
e (d
ays)
Discharge final voltage: 2V Temperature: 20 deg. C
Discharge current (μA)
� Relationship between Discharge Current and Duration Time
Discharge duration time (h)
Volta
ge (V
)
1.0
1.5
2.0
2.5
3.0
3.5
0 10 20 30 40 50 60 70 80
Temperature: 20 deg. C
1mA2mA4mA 3mA
� High Rate Discharge Characteristics
� Over Charge Characteristics
1.5
2
2.5
3
3.5
0 100 200 300 400 500
Discharge duration time (h)
Volta
ge (V
)
Discharge load: 15 k� Temperature: 20˚C
Initial
After charged at 3.3V for20 days at 60 deg. C
3.5
3.0
2.5
2.0
1.5
1.0
Discharge duration time (h)
Volta
ge (V
)
0 100 200 300 400 500
After stored for 60 days at 60 deg. C
Discharge load: 15 k� Temperature: 20 deg. C
Initial
� Storage Characteristics
3.5
3.0
2.5
2.0
1.5
1.00 105 15 20 25 30
Discharge capacity (mAh)
Volta
ge (V
)
Temperature: 20 deg. C
30k�15k�
100k�
240k�
� Discharge Characteristics
3.5
3.0
2.5
2.0
1.5
1.06040200 80 100 120 140 160 180
Discharge duration time (h)
Volta
ge (V
)
Discharge load: 15k�
–20 deg. C0 deg. C
60 deg. C
20 deg. C
� Temperature Characteristics
Discharge current (μA)
100 101 102
Discharge final voltage: 2V Temperature: 20 deg. C
Disc
harg
e du
ratio
n tim
e (d
ays)
104
103
102
101
100
� Relationship between Discharge Current and Duration Time
3.5
3.0
2.5
2.0
1.5
1.00 5 10 15 20 25 30
Discharge duration time (h)
Volta
ge (V
)
4mA 1mA3mA 2mA
� High Rate Discharge Characteristics
Discharge load: 15 k� Temperature: 20 deg. C
� Over Charge Characteristics
1.5
2
2.5
3
3.5
0 50 100 150 200
Discharge duration time (h)
Volta
ge (V
)
Initial
After charged at 3.3V for20 days at 60 deg. C
3.5
3.0
2.5
2.0
1.5
1.00 604020 80 100 120 140 160 180
Discharge duration time (h)
Volta
ge (V
)
Discharge load: 15 k� Temperature: 20 deg. C
After stored for 60 days at 60 deg. C
Initial
� Storage Characteristics
Lithium Manganese Dioxide Rechargeable Battery
41
ML1220 (18mAh)
L I T H I U M M A N G A N E S E D I O X I D E R E C H A R G E A B L E B A T T E R Y
42
3.5
3.0
2.5
2.0
1.5
1.00 4 8 12 162 6 10 14 18 20
Discharge capacity (mAh)
Temperature: 20 deg. C
Volta
ge (V
)
100k�
30k�
� Discharge Characteristics � Temperature Characteristics
3.5
3.0
2.5
2.0
1.5
1.0
Discharge duration time (h)
Volta
ge (V
)
0 40 80 120 160 200 24020 60 100 140 180 220 260
Discharge load: 30 k�
60 deg. C
20 deg. C
–20 deg. C
0 deg. C
Discharge current (μA)
104
103
102
101
100
Discharge final voltage: 2V Temperature: 20 deg. C
Disc
harg
e du
ratio
n tim
e (d
ays)
� Relationship between Discharge Current and Duration Time
1 101 102
1mA
2mA
3mA
4mA
1614121086420
3.5
3.0
2.5
2.0
1.5
1.0
Discharge duration time (h)
Volta
ge (V
)
Temperature: 20 deg. C
� High Rate Discharge Characteristics
� Over Charge CharacteristicsDischarge load: 30 k� Temperature: 20 deg. C
1.5
2
2.5
3
3.5
0 50 100 150 200 300250
Discharge duration time (h)
Volta
ge (V
)
Initial
After charged at 3.3V for20 days at 60 deg. C
3.5
3.0
2.5
2.0
1.5
1.0
Discharge duration time (h)
Volta
ge (V
)
0 50 100 150 200 250
After stored for 60 days at 60 deg. C
Discharge load: 30 k� Temperature: 20 deg. C
Initial
� Storage Characteristics
External Dimensions (unit : mm)
ML2016 T6 ML2016 T17ML2016 T25ML2032 WK2
ML2032 T26ML2032 T32 ML2032 WK
ML2032 T25ML2032 T14ML2032 T6 TUBE
ML2032 T17
ML2032 T6
Insulation sleeve
ø20
0.2
(–)(+)
(+)
(–)
3.70.75
4.0
4.0
4.5 7.
5
Insulation sleeve Insulation sleeve
40.
75
ø20
0.2
4.8 4
(+)(–)
25.4
20.2
7.5
22
Hook Loop(+)
(–)
Lead wire
80
20.2
34
65
(+)(–)
(–)
(+)
(+)
(–)
Lead wire
(+)
(–)
(+)(–)
4.5
ø20
0.75
10.1
6
20.3
0.218.05
0.754
4 4
1.3
8.5
(–)(+)0.20.2
3.7
ø20
10.5
0.7544
1.8
43
4.5
Insulation sleeve
(+) (–)
4 4.5
4
ø20
10.1
6
0.75
5.1
15.24
20.6
0.2(–) (+)
4.5
4
ø20
4.8
4.5
4.1
4
4.54 4
20.5
20.3
0.750.2 1.8
4
(–) (+)
ø20
10.5
0.7544
1.8
43
4.5
0.20.2(–)(+)
Insulation sleeve Insulation sleeve
ø20
0.75
(–) (+)
20.5 0.2
4 421
4.5
4.52.
5
43.
2
1.8
20.3
(–) (+)
0.2
18.050.75
4 4
2.9
8.8
4.5
0.75
10.1
6
ø20
Housing:Contact:Lead wire:
HNC2-2.5S-4 (Hirose)HNC2.5S-C-B (02) (Hirose)AWG26
Housing:Contact:Lead wire:
ZHR-2 (JST)SZH-002T-P0.5 (JST)AWG26
10.16
2.1
4
ø20
4.8
4.5
4.1
4
4.54 4
20.5
21
Insulation sleeve
0.750.2 1.8
4
(–) (+)
ML
Actual appearance Actual appearance
Actual appearance
Actual appearance
Lithium Manganese Dioxide Rechargeable Batterywith Terminals and Wire Connectors
43
L I T H I U M M A N G A N E S E D I O X I D E R E C H A R G E A B L E B A T T E R Y
External Dimensions (unit : mm)
ML1220 T13
ML1220 T10ML1220 T9 ML1220 T12ML2016 T26
ø20
0.75
4
44.5
10.16
(+)
(–)
Insulation sleeve
2.1
0.27.5
ø12.5
0.75 0.75
3.25
(+)
(+)(–)
(–)
16.2
5
3.0
3.75
Insulation sleeve
2.7
0.2
ø12.5
0.75 0.75
3.8
(+) (–)
(–)(+)
3.0
3.5
Insulation sleeve
2.7
0.2
ø12.5
0.75 0.75
3.25
(+) (–)
(–)(+)
3.0
3.5
Insulation sleeve
2.7
0.2
3.3 3.3ø12.5
0.75
2.1
2.7
Insulation sleeve
0.75
4(–) (+)
(+) (–)
Actual appearance
: Tin plating: Horizontal & Through hole Type: Horizontal & Surface mounting Type: Vertical & Through hole Type: Wire connector Type
44
TCTITANIUM CARBON LITHIUMRECHARGEABLE BATTERY
TC920S
T I T A N I U M C A R B O N L I T H I U MR E C H A R G E A B L E B A T T E R Y
45
46
Warnings
Warnings
�Never swallow.Always keep the battery out of the reach of infants and young children to prevent it from being swallowed. If swallowed, consult a physician immediately.
�Do not replace.Depending on the battery manufacturer, there might be major differences in performance even among the same types or models of batteries. If you are an equipment manufacturer and need to replace the battery, please use a new one of the same type and same model as the existing one. Because this is a rechargeable battery, its characteristics are completely different from a primary battery even though their shapes are alike. If a primary battery is installed in the circuit in place of a rechargeable battery, gas could be generated or the primary battery could be short-circuited by charging. This could lead to distortion, leakage, overheating, explosion, or fire. Please design your equipment so that the end user cannot replace the battery by mistake.
�Never use two or more batteries connected in series or in parallel.If batteries are connected together, it is very difficult to design a circuit to observe whether or not the batteries are charged at specified voltage or current as described in "Warning -Circuit Design".
�Never reverse the positive and negative terminals when mounting.
Improper mounting of the battery could lead to equipment trouble or short-circuiting. This could cause distortion, leakage, overheating, explosion, or fire.
�Never short-circuit the battery.Do not allow the positive and negative terminals to short-circuit. Never carry or store the battery with metal objects such as a necklace or a hairpin. Do not take multiple batteries out of the package and pile or mix them when storing. Please be careful when installing the battery not to short-circuit it with metal portions of the equipment. Otherwise this could lead to distortion, leakage, overheating, explosion, or fire.
�Never heat. Heating the battery to more than 100 deg. C could increase the internal pressure, causing distortion, leakage, overheating, explosion, or fire.
�Never expose to open flames. Exposing to flames could cause the battery to catch on fire and explode.
�Never disassemble the battery. Do not disassemble the battery, because the separator or gasket could be damaged, leading to distortion, leakage, overheating, explosion, or fire.
�Never weld the terminals or weld a wire to the body of the battery directly.
The heat of welding or soldering could cause the lithium to melt, or cause damage to the insulating material in the battery, leading to possible distortion, leakage, overheating, explosion, or fire. When soldering the battery directly to equipment, solder only the tabs or leads. Even then, the temperature of the soldering iron must be below 350 deg. C and the soldering time less than 5 seconds. Do not use a soldering bath, because the circuit board with battery attached could stop moving or the battery could drop into the bath. Moreover do not use excessive solder, because the solder could flow to unwanted portions of the board, leading to a short-circuit or charging of the battery.
�Never allow liquid leaking from the battery to get in your eyes or mouth.
Because this liquid could cause serious damage, if it does come in contact with your eyes, flush them immediately with plenty of water and consult a physician. Likewise, if the liquid gets in your mouth, rinse immediately with plenty of water and consult a physician..
�Keep leaking batteries away from fire.If leakage is suspected or you detect a strong odor, keep the battery away from fire, because the leaked liquid could catch on fire.
�Never touch the battery electrodes.Do not allow the battery electrodes to come in contact with your skin or fingers. Otherwise, the moisture from your skin could cause a discharge of the battery, which could produce certain chemical substances causing you to receive a chemical burns.
Safety InstructionsThis battery contains organic solvents, and other combustible materials. For this reason, improper handling of the battery could lead to distortion, leakage*, overheating, explosion, or fire, causing bodily injury or equipment trouble. Please observe the following instructions to prevent accidents.(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Handling
Circuit Design
Table 1 Nominal Charge Current by Model
�Never set the charge voltage above 3.15V.Charging at a higher voltage could cause the generation of gas, internal short-circuiting, or other malfunctions, leading to distortion, leakage, overheating, explosion, or fire. For details, see the recommended circuits in the figure below.
�Always charge at the nominal currents shown below.Large surges of current could degrade the battery’s characteristics, leading to distortion, leakage, overheating, explosion, or fire. To avoid excessive current at the initiation of charging, make sure to attach a protective resistor for current control. See the recommended circuits below.
�Recommended CircuitsPlease refer to the representative basic circuits shown below. If you have any questions about circuit design, please feel free to contact Maxell.
(How to select a protective resistor for the current control)The maximum charge current flows in the battery when charged at an end voltage of 1.0V. Therefore the value of the resistor is calculated using this equation:(R) >= ((Charge voltage* –1) / (Nominal Charge Current) * Charge voltage (A): Voltage of main power source (B): Output voltage of regulator
For example, the S-812C series, which has a maximum input voltage of 18V, or the S-817 series with a maximum input voltage of 10V (Seiko Instruments Inc.) can be used as a voltage regulator.
2.5V>300 ohm
1.8V>160 ohm
Model
TC920S
Charge voltage*
Table 2 Example of resistor
(A) Main power source of 1.6 to 3.15V (B) Other main power source
D: Diode; R: Resistor
(1.6 to 3.15V)
TC
R
D
–
+
Load Load
TC
R
D
–
+
GND
(1.6 to 3.15V)
D: Diode; R: Resistor
VoltageRegulator
1.6 to 3.15V To 16V
Model
Charge Current
TC920S
5mA or lower
47
TC
Products
Construction The button-type titanium carbon lithium ion rechargeable battery uses lithium titanium oxide as the positive material, carbon as the negative material, and organic electrolyte.
Principle and Reactions
�Charge/Discharge ReactionsPositive Electrode
Negative Electrode
Negative Cap
Gasket
Separator
Positive CanCharge
Discharge LixTiyO4+LizC6 Lix+�TiyO4+Liz-�C6
* Nominal capacity indicates duration until the voltage drops down to 1.0V when discharged at a nominal discharge current at 20 deg. C.• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
The button-type titanium carbon lithium ion rechargeable battery is a small rechargeable battery developed as a backup power source for real-time clocks and SRAM like digital cameras and mobile phones. It provides fully 10 times the capacity of a capacitor of the same size.
Overview
Warnings Disposal
The battery may be regulated by national or local regulation. Please follow the instructions of proper regulation. As electric capacity is left in a discarded battery and it comes into contact with other metals, it could lead to distortion, leakage, overheating, or explosion, so make sure to cover the (+) and (-) terminals with friction tape or some other insulator before disposal.
�Use within the rated temperature range (-20 to 60 deg. C).Otherwise the battery’s charge and discharge characteristics may be reduced.
�Never expose the battery to ultrasonic sound.Exposing the battery to ultrasonic sound may cause short-circuiting because the inside material is broken into pieces, leading to distortion, leakage, overheating, explosion, or fire.�Never subject the battery to severe shock.Dropping, throwing or stomping on the battery may cause distortion, leakage, overheating, explosion, or fire.�Never use or leave the battery in a hot place such as
under the direct rays of the sun or in a car in hot weather.
If you do, this may cause distortion, leakage, overheating, explosion, or fire.�Never allow the battery to come in contact with water.If it does, this may cause the battery to rust or lead to distortion, leakage, overheating, explosion, or fire.�Never store the battery in a hot and highly humid
environment.Doing so may cause the performance of the battery to deteriorate. In certain environments, this may lead to distortion, leakage, overheating, explosion, or fire.
Caution Handling/Storage
(Example of battery insulation)
Battery +
–
Tape Do not pile up or mix batteries.
Enlarged view
Electric current flows.
These batteries generate heat.
Model
Nominal Voltage (V)
Nominal Capacity (mAh)*
Nominal Discharge Current (μA)
Dimensions
Weight (g)*
Diameter(mm)
Height(mm)
Charge/Discharge Cycle
TC 920S
1.5
3.5
500
Operating Temperature Range (deg. C) -20 to +60
9.5
2.05
0.43
100
Titanium Carbon Lithium Rechargeable Battery
48
T I T A N I U M C A R B O N L I T H I U M R E C H A R G E A B L E B A T T E R Y
Applications
�Approx. 1.5V operating voltageThe operating voltage is about 1 to 1.5V the same as the SR, LR battery.�Wide range charging voltage (Fig. 1)Charging voltage is 1.6 to 3.15V.�Excellent cycle performance (Fig. 2)500 charge/discharge cycles is archived because by utilizing lithium ion.�Wide temperature characteristics (Fig. 3)Usable in a wide temperature range of-20 to 60 deg. C.
�Excellent overcharge characteristicsA special formulated organic electrolyte is employed to provide stable discharge characteristics even if charged for 10 years at 3.15V at 20 deg. C. (under accelerated test conditions conducted by Maxell)�Superior leakage resistanceLeakage resistance can withstand over 1,200 heat shock cycles between 60 deg. C and-10 deg. C.
Features
Discharge capacity (mAh)
Vo
ltag
e (V
)
0
20
40
60
80
100
Charge voltage (V)
Recommended area1.6V—3.15V
Rec
over
able
rat
io (%
)
1.5 2.0 2.5 3.0 3.5
Prohibited areaFV=1.0V
Charge/discharge cycle (Numbers)
Dis
char
ge
cap
acit
y (m
Ah)
� Mobile Phones � PHS � Camcorders � Digital Still Cameras � Portable CD/MD Players � Watches
1.5
2.0
2.5
3.0
3.5
4.0
4.5
0 200100 300 400 500
FIg. 1 Charge Property
Fig. 3 Temperature Characteristics
Fig. 2 Charge/Discharge Cycle Performance
20 deg. C
Charge voltage: 2.4VProtective resistor: 300�Charge time: 6hr
Discharge load: 1k�Discharge time: 6hr
0
0.5
1.0
1.5
2.0
2.5
0 3.02.01.0 4.0 5.0 6.0
–20 deg. C
20 deg. C
Discharge load: 15k�
TC920S (3.5mAh)
TC
49
� Charge/Discharge Curves �Temperature Characteristics
�Over Charge Characteristics �Overdischarge Characteristics
Discharge capacity (mAh)
Vol
tage
(V)
0
0.5
1.0
1.5
2.0
2.5
0 1.0 2.0 3.0 4.0 5.0 6.0 7.0
Discharge capacity (mAh)
Vol
tage
(V)
0
0.5
1.0
1.5
2.0
2.5
0 1.0 2.0 3.0 4.0 5.0 6.0
Discharge
Charge
Initial Initial
Charge voltage: 2.4VProtective resistor: 300�Charge time: 24 hrs
Discharge load: 15k�Final voltage: 0.5V
20 deg. C
–20 deg. C
Discharge load: 15k�Temperature: 20 deg. C
Discharge capacity (mAh)
Vol
tage
(V)
0
0.5
1.0
1.5
2.0
2.5
0 1.0 2.0 3.0 4.0 5.0 6.0 0 1.0 2.0 3.0 4.0 5.0 6.0
Discharge capacity (mAh)
Vol
tage
(V)
0
0.5
1.0
1.5
2.0
2.5Discharge load: 15k� Temperature: 20 deg. C
After charged at 2.4V for 80 days at 60 deg. C After discharged at 0V for 80 days at 60 deg. C
Discharge load: 15k� Temperature: 20 deg. C
Titanium Carbon Lithium Rechargeable Battery
Scope of Registration: The design/developmentand the manufacture of cylindrical alkaline battery, silver oxide battery, alkaline button battery, manganese dioxide lithium battery (coin type and cylindrical type), thionyl chloridelithium battery, manganese dioxide lithium rechargeablebattery and titanium carbon lithium ion rechargeable battery.
Scope of Registration: The design/development and manufacture of manganese dioxide lithium battery (coin type) for automobile use.
ISO14001Hitachi Maxell, Ltd., Osaka-Ono SiteCertificate Number: EC97J1166Certificate Expiry: 25/Dec/2008Registration Date: 26/Jan/1998Issue Date: 26/Dec/2005
Factories producing these products conform to the ISO 14001 standards.
ISO14001Hitachi Maxell, Ltd., Kyoto SiteCertificate Number: EC97J1188Certificate Expiry: 22/Feb/2010Registration Date: 23/Feb/1998Issue Date: 23/Feb/2007
ISO9001
ISO 14001
ISO9001Hitachi Maxell, Ltd.Energy Solution Business GroupPrimary Battery DivisionCertificate Number : JQA-0986Registration Date: September 29, 1995Last Renewal Date: December 19, 2006Expiry Date: December 18, 2009
JQA-0986
JQA-AU0078
ISO/TS16949Hitachi Maxell, Ltd.Energy Solution Business GroupPrimary Battery Division, Ono WorksCertificate Number : JQA-AU0078Registration Date: January 7, 2005Last Renewal Date: January 7, 2008Expiry Date: January 6, 2011
JQA-3029
Scope of Registration: The design/development and manufacture of lithium ion rechargeable battery.
ISO9001Hitachi Maxell, Ltd.Rechargeable Battery DivisionCertificate Number: JQA-3029Registration Date: January 29, 1999Last Renewal Date: December 27, 2005Expiry Date: December 26, 2008
EMS AccreditationRE 009
QS AccreditationR009
50
ISO/TS 16949
Catalog contents accurate as of September, 2008.Data and dimensions are just reference values.Contents on this catalog are subject to change without notice. Committed to the highest quality assurance management standards as well as responsibility to the environment, Maxell's Batteries production facilities are accredited with both ISO 9001 and ISO 14001 certifications.
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