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Inorganic Polymer

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    Group 1:

    Kien Thi Thuy Linh Nguyen Thi Yen Nhi Nguyen Hoang AnhLe Trung Hieu

    Teacher:

    Luu Thuy Quyen

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    Outline

    Introduction Cement Silicates

    Asbestos Carbon C

    eramics Superconductors Zeolite

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    S ilicon dioxide

    The repeating general structural of rock, sand, dirt, SiO2 can be described as a three-dimensional network

    constructed from tetrahedral cells, with four oxygen atoms

    surrounding a silicon atom

    Figure . S tructure of S iO2

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    Two forms: Amorphous Quartz

    S ilicon dioxide

    Figure . Network of S iO2

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    G lass

    G lass is amorphous silicate, usual mixedimpurities to control desire property.

    G lass is transparent.Thermal and electric conduction depend onimpurity levels.

    Thermal stable and high hardness.

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    G lass is made by heating silica sand and powder additives in aspecified manner

    M elting point of S iO2 : 2.000 C (3.632 F). In processing of G lass, addition of compound to reduce Tm.

    Additives are usual : Na2C

    O3; K2C

    O3.C

    aC

    O3 to recover dissoluble of Na2 C O3

    G lass

    Form oxides which become

    intergrate into the S iliconstructure

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    G lass

    Why Glass is amorphous ??? G lass: short- range order & long-range disorder .

    The impurities encourage the glass to cool to an amorphousstructure since the different-size of metal ions

    Figure .S

    tructure of G

    lass

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    G lass

    Silica sand 72% Soda Ash 15%

    Lime 9%Other 4%

    P r tag f I gr i ts i G lass

    sili a sas a ashlim

    th r i gr i ts72%

    15%4%

    9%

    Figure . Ingredient of S oda-lime glass

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    M ixing and weightinginto proper proportion

    Send to furnaces inhoppers

    operated by natural gas heat the mixture at 1300-

    1600 degrees C elsius into

    soften or molten state

    Glass

    Figure . Process of manufacture glass

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    G lassMoldin --- molten glass flows to forming machine to moldinto desire shapes

    Annealin --- reheating the glass in an oven to ensure even cooling of glass for strengthening of the products

    Coolin p ocess --- C ool for 30 min to an hour for safe tohandle.

    G lass p oducts are then decorated, inspected again andfinally packaged and shipped to our customers.

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    Applications o G lass

    Figure . Application of G lass

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    Q ua tz Is a kind of silicon crystallizes, a major components of

    ingenous rocksThree mainly forms- quartz, tridymite,cristobalite. Depend ontemp, it exist in different formsQuartz exhibitz an important property called the piezoelectriceffect.

    Figure . Quartz

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    The unit cell of crystal silicon dioxide

    -

    +

    +

    -

    +

    -

    + = S ilicon

    - = Oxygen

    By definition : A unit cell is the s mallest parallele pi ped(6 sided parallelo gram) that will descri be the molecule .

    Q ua tz

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    -

    +

    +

    -

    +

    -

    U nit C ell at Rest-

    +

    +

    -

    +

    -

    Ne utral Charg e

    U nit C ell U nder M echanicalC ompression ( pushing force):Electrical polarity as shown

    -

    +

    +--

    U nit C ell U nder mechanicalTension ( pulling force):Electrical polarity reverses.

    + + +

    - - -

    + + +

    - - -

    +

    Q ua tz

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    -

    +

    +

    -

    +

    -

    -

    +

    +

    -

    +

    -

    + + +

    - - -

    U nit C ell at Rest

    Ne utral Charg e N ot caus e e l e ctric ene rgy

    2 compression forces inopposite directions...

    Will also r e sult i n e l e ctrical ene rgy!

    Q ua tz

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    Application o Q ua tz

    Figure . Application of Quartz

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    S ilicon c ips1958,"The C hip" was invented by both Jack

    Kilby and Robert Noyce.

    It is an intergrate circuit that is design to

    work for an funtion or diferent purpose

    Figure . S ilicon chips

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    S ilicon c ips

    Figure . Process of manufacture C hips

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    S ilicon c ips

    S iO2 + C S i + CO2

    D esign Wafer:

    I t is pure silic, purity

    above 99,9999%

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    S ilicon c ips

    Treat Wafer Wet process: C lean wafers bychemical solutions. Ex:AP M (NH4OH/H2O2/H2O);HP M

    (HC l/H2O2/H2O)

    Oxidation: formthin layer of S iO2 ( 1-2nm)

    Ion implantation :V ary the impurities.Ex: ion As to form

    n+ layer

    P hotolithography Sputtering

    Anealing Treat surface

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    Process of manufacture chip is multistepsThe purity is above 99,9999% or impurity

    level is 1ppb

    S ilicon c ips


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