Installation Name & Address For inspection purposes only. · PDF fileA2-02 ESP Exhaust...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279

Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Report Written by

Patrick O'Brien

4th April 2016Report Date

TE1 TE2 TE3 TE4

Stack Emissions Testing Report Commissioned by

1st - 8th March 2016

Job Reference Number

CDU-0594

Installation Name & Address

Stack Reference

Irish EPA IPPC Licence: P0378-02

Signature of Report Approver

Version 1

MM 08 922MCERTS Level 2

Dates of the Monitoring Campaign

Team Leader

Team Leader

TE1 TE2 TE3 TE4MM 08 922

MCERTS Level 2

Patrick O'Brien

Report Approved by

Version

Exova Catalyst Ireland, Unit D8 North City Business Park, North Road, Finglas, Dublin 11T: +353 86 853 8247

E: [email protected] Exova Catalyst Ireland Contact: Nick Kenny (+353 86 853 8247)

BallyconnelScotchtown

Quinn Cement Ltd

County Cavan

Quinn Cement Ltd

A2-02 ESP Exhaust (Clinker Grate Cooler)

CAT-RT (Version BM)

CDU-0594 Quinn Cement A2-02 Dusdt Report

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TITLE PAGE

CONTENTS

Summary of Sampling Deviations

EXECUTIVE SUMMARY

Monitoring Objectives

Monitoring Results

Monitoring Dates & Times

Process Details

Monitoring & Analytical Methods

Sampling Location

Plant Photos / Sample Points

APPENDIX 1 - Monitoring Personnel & List of Equipment

APPENDIX 2 - Raw Data, Sampling Equations & Charts

4

2

7

CONTENTS

9

3

5

6

8

Opinions and interpretations expressed herein are outside the scope of

Exova Catalyst Ireland's ISO 17025 accreditation.

This test report shall not be reproduced, except in full, without the written

approval of Exova Catalyst Ireland.

The testing performed fully meets the technical requirements in Irish EPA

Guidance Note, AG2.

CAT-RT (Version BM)

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Job Number: CDU-0594, Version 1

Sample Date/s: 1st - 8th March 2016


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Overall Aim of the Monitoring Campaign

Special Requirements

Target Parameters



Quinn Cement Ltd, Ballyconnel

(Page 1 of 7)

Exova Catalyst Ireland were commissioned by Quinn Cement Ltd to carry out stack emissions testing on the A2-02 ESP Exhaust

(Clinker Grate Cooler) at Ballyconnel.

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the

Site's Licence.

There were no special requirements.

Total Particulate Matter

MONITORING OBJECTIVES

Executive Summary

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where MU = Measurement Uncertainty associated with the Result

Parameter

Total Particulate Matter ¹

Water Vapour

Stack Gas Temperature

Stack Gas Velocity

¹

- -

NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.

¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.

°C

Volumetric Flow Rate (ACTUAL)

(Page 2 of 7)

Volumetric Flow Rate (REF)

22712

0.14

494836

m³/hr

1.3

226478 10395

Executive Summary

Mass Emission

501.27

MONITORING RESULTS


-

Units

mg/m³ 5015.6

Result LimitMU



g/hr 368.622.15

+/-

Units Result

Concentration

MULimit

+/-

% v/v

18.8m/s

0.1

314.8

m³/hr

228700

-

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Parameter

R1 - -

R1

All results are expressed at the respective reference conditions.

mg/m³



5015.6

MONITORING DATE(S) & TIMES

mins


Units Concentration

08/03/2016

Sampling


Units

(Page 3 of 7)

22.1 14:20 - 14:52 32

Executive Summary

Sampling

Times

Velocity & Volumetric Flow Rate 08/03/2016 13:30 -14:15

Date(s)

Mass Emission

g/hr

Duration

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Standard Operating Conditions

Normal Operation



(Page 4 of 7)

Executive Summary

PROCESS DETAILS

Capacity (of 100%) and Tonnes / Hour

Continuous or Batch Process

N/A

Full Capacity

On

Continuous

Parameter

N/A

Fuel

Abatement System

Abatement System Running Status

Plume Appearance

ESP

Not Visible

Process Status


Value

Feedstock (if applicable)

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SUMMARY OF SAMPLING DEVIATIONS

Parameter Run Deviation

CAT-TP-03

TPM 1 There are no deviations associated with the sampling employed.

Pitot Tube and Thermocouple

(Page 5 of 7)

Testing


Executive Summary

MONITORING & ANALYTICAL METHODS

ANALYSIS LABORATORIES

Velocity & Vol. Flow Rate

(with short name reference as appears in the table above)

Exova Catalyst (CAT)

EN 16911-1 (MID) CAT-TP-41

EN 13284-1

Analysis

CAT Gravimetric

MCERTS

17025

Testing

0.2 mg/m³Yes

Analytical

Technique

Analytical

(Average)

ISOISO


Water Vapour


Standard

Lab

YesCAT-TP-01

Procedure

LOD

Yes

Lab

Monitoring

CAT

Parameter

Procedure

Technical

Testing

Analysis

CAT Yes

Yes 1.2 m/s

ISO 17025 Accreditation Number: 4279

CAT

CAT-TP-05 YesEN 14790 YesGravimetricCAT-TP-05

Yes

CAT 0.1 % v/v

17025 Analysis

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Duct Characteristics Location of Sampling Platform

Platform Details

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (from EN 15259)

Lowest Differential Pressure

Value

Easy Access Available

Depth

21.36

4" BSP

-

-

-

0.00

-

Highest Gas Velocity

Area

Yes

-

-

-

7.31

-

-

Orientation of Duct

Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements

Pa

-

-

Sample Port Size

There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.

121.0

Circular

Value

Safe Access Available

-

Vertical

Yes

Parameter

There are no obstructions present which hamper insertion of sampling equipment

-

0.000.00

-

8

0.00

Port Depth

-

Yes

Traverse 1

m/s

< 3 : 1Ratio of Above : 1 Yes

< 15°

No Local Negative Flow

Platform has vertical base boards (approx. 0.25m high)

> 5 Pa Yes

-

Yes

Yes

m

Lowest Gas Velocity

m/s

Yes

-

17.04

-

-

Required

-

Platform has chains / self closing gates at top of ladders

-18.81

Value

SUITABILITY OF SAMPLING LOCATION

Mean Velocity

Outside

Width

Compliant

-

(Page 6 of 7)

1.25

°

-

--

Units

Yes

19

Permanent / Temporary Platform

Inside / Outside

-

-

m²

m

The sampling location meets all the requirements specified in Irish EPA Guidance Note AG1 and EN 15259, and therefore there are

no improvement recommendations.

Yes

General Platform Information

Criteria in EN 15259

-

-

-

-

--m/s

Maximum Angle of Swirl

Executive Summary

cm

Yes

-

Permanent

Units

-

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

Yes

-

-

-

Sufficient working area to manipulate probe and operate the measuring instruments

Type

-

3.05

-

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Photo 3

Photo 2

SAMPLE POINTS

Executive Summary

PLANT PHOTOS

(Page 7 of 7)

Photo 1

Photo 4

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APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDICES

APPENDIX CONTENTS

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EPA Export 27-07-2016:01:29:55

CAT 3.93

Name

Donal O Faogain MCERTS Level 2

Equipment I.D.

STACK EMISSIONS MONITORING PERSONNEL

APPENDIX 1

MM131259

-

-

1m Heated Line (3)

Control Box DGM (1)

Equipment I.D.

Digital Manometer (1)SELECT Horiba Model (1)

Oven Box (2)

Miscellaneous Items

CAT 7.42

Equipment I.D.

-

Position

CAT-TP-05

CAT 3.27

CAT 14.67

-

S-Pitot (1)

L-Pitot

-

-

Laboratory Balance CAT 1.18 / 1.18a

Tape Measure CAT 16.94

Single Channel Heater Controller

CAT 23.30

Instrumental Analysers

S-Pitot (2) -

-

Equipment Type

CAT 4.540

Equipment Type

Technical Endorsements

Team Leader PatricO'Brien MCERTS Level 2

Team Leader

-

EN 13284-1

Technical ProcedureStandard

Heated Probe (1)

-

TE1 TE2 TE4

CAT-TP-01

Barometer

Digital Manometer (2)

Umbilical (1)

Box Thermocouples (2)

Box Thermocouples (1)

5m Heated Line (1) -

500g Check Weight

SELECT Heated Head

Stack Thermocouple (2)

-

-

-

CAT 3.103

-

Mass View (2)

EN 14790

Team Leader

-

-

Umbilical (2) Servomex 5200MP

Oven Box (1)

-

-


EN 16911-1 (MID) CAT-TP-41

Mass Flow Controller (2) -

Mass View (1) -

20m Heated Line (2)

Parameter


Bernath 3006 FID -

Water Vapour

- 1m Heated Line (2)

-

SELECT Logger 2 -

Dual Channel Heater Controller -1Kg Check Weight CAT 17.30

Last Impinger Arm -

Callipers

- 20m Heated Line (1)

-

METHODS & TECHNICAL PROCEDURES USED

Tubes Kit Thermocouple -

Stopwatch

15m Heated Line (1)

CAT 17.30

-

SELECT Gas Conditioning

CAT 13.2

Mass Flow Controller (1)

MCERTS Number

-

MCERTS Level 2 MM12 1194 TE1 TE2 TE3 TE4

Heated Probe (2)

-

ABB AO2020-URAS26

-

CAT 3.103

SELECT FTIR

SELECT Horiba Model (2)

Digital Temperature Meter

Heated Probe (3) -

-

Equipment Type

Conor Cooney

SELECT Logger 1

Control Box DGM (2)

Extractive Sampling

LIST OF EQUIPMENT

MCERTS Accreditation

MM08 922 TE1 TE2 TE3 TE4

Team Leader John Glennon MCERTS Level 2 MM101074 TE1 TE2 TE3 TE4

CAT 3.93-

-

CAT 21S.46


Gasmet Sampling SystemCAT 5.40 1m Heated Line (1)

Servomex 4900

-

Eco Physics CLD 822Mh

Velocity & Vol. Flow Rate

Bioaerosols Temperature Logger -

Electronic Refrigerator -

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EPA Export 27-07-2016:01:29:55

General Stack Details

Stack Gas Composition & Molecular Weights

CO₂ (Estimated)

O₂ (Estimated)

Moisture (H₂O)

Where: p = M / 22.41

pi = r x p

Calculation of Stack Gas Densities

Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)

P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)

P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)

P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flowrate, Q

Gas Volumetric Flowrate (Actual)

-0.0

-

1.2498

44.01

223509

Gas Volumetric Flowrate REF ¹

%

0.8037

Result

1.9635

-

-

0.2000

m³/hr

REF ¹

0.586

Dry Density (Actual), P Actual

m³/hr

Gas Volumetric Flowrate (STP, Dry)

kg/m³

Gas Volumetric Flowrate (STP, Wet)

Moisture

Conc

0.00118

Pa

0.06

314.8

99.8

% v/v

Units

1.31

kg/m³ 1.280

Duct gas flow conditions

226478

494836

0.589

Wet Density (STP), P STW

-

1.4277 0.28554-

Units

101.3

Temperature

N₂

-

Units

Average Pitot Tube Calibration Coefficient, Cp

ppm kg/m³

Average Stack Gas Pressure

Conc

1.31

Conc

M

Wet

r% v/v

kg/m³

m³/hr

Total Pressure

Average Wet Density (Actual), P ActualW

1.31

79.94 0.99913

1.286

78.89

Dry Density (STP), P STD

18.02

Determinand

0.0006

226478

kg/m³

kPa

0.0131

19.74

p pi

Mass

Component

m³/hr

Result

°C

kg/m³

0.7994 28.01

Fraction

Density

Dry

0.01053

20.00 32.00

Actual

0.06

Volume

148.1

Molar Conc

7.31Stack Area, A

APPENDIX 2

mStack Width, W

314.8

Average Barometric Pressure, Pb

m

Stack Details (from Traverse)

kPa

0.84

Value

3.05

100.0

Average Stack Gas Temperature, Ta

-0.173

m²

-

Units

PRELIMINARY STACK SURVEY: CALCULATIONS

Average Stack Static Pressure, Pstatic kPa

°C

Stack Diameter / Depth, D

Gas Volumetric Flowrate (from Traverse)

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EPA Export 27-07-2016:01:29:56

Parameter Parameter

Date of Survey Initial Pitot Leak Check

Time of Survey Final Pitot Leak Check

Atmospheric Pressure Orientation of Duct

Average Stack Static Pressure Pitot Tube, Cp

Result of Pitot Stagnation Test Number of Lines Available

Are Water Droplets Present? Number of Lines Used

Device Used

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

--

-

-

-

-

-

- -

-

--

-

- -

0.585

136.5

-

-- -

18.09

0.585

18.85

314.0

315.0

-

-

-

-

-

5.0

5.0

- -

-

-

-

-

-

-

-

-

-

- --

8.0

-

-

5.0182.0

--

-

7

315.0

-

121.0

136.0

0.586

8

315.0

314.0

150.0

18.59

162.0

159.6

0.585

314.6Mean

-

0.585

0.32

-

315.0

-

142.0

315.0

2.46

0.586

7.0

0.585

0.585

177.0

2.95

4.0

- -

18.98

151.0

143.020.90

3.0

3

6

19.72

- -

19.04

-

2.06

6.0144.0

17.52

7.0

6.0

0.585

315.0

- -

kg/m³Point °

314.0

4

6.0

-

17.04

315.0

17.92

17.18

315.0 0.585

5.0

315.0

18.46190.0

134.0

5.0

0.585

0.585

20.61

315.0 18.07

18.53

0.586

m/sPa

0.585

m

0.10

18.19

1

0.585

315.00.59

kg/m³

3.0

°C

7.0

°

128.0

148.0

m/s°C

-171.0

5

315.0

123.0 315.0

315.0

-174.0

Pass

VelocitySwirl

No

kPa

-

Wet Density

-

Swirl

Vertical

Pass

Traverse Depth

-

Velocity

Units

APPENDIX 2

7.0

138.0

21.36

19.53

STATIC (Units: Pa)

Value

∆P Temp

Sampling Line B

Pa

100.0

2.73

2

0.586

0.99

Temp

--

13:30 -14:15

Sampling Line A

0.585

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)

-

(1 of 1)

2

Pass

∆P

-

Wet Density

Pa

2

08/03/2016

Value

-

Units

-173 -

-

0.84

S-Type Pitot with KIMO MP 200 (500Pa)

0.585

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EPA Export 27-07-2016:01:29:56

Performance characteristics (Uncertainty Components) UnitsValueUncertainty

0.00053

-

u(k) 0.005

u(∆pi)

u(vi) 0.178

u(v) 0.073

Uc(v) 0.143

Uc,rel(v) 0.76

Standard Uncertainty on the coefficient of the Pitot Tube

Standard Uncertainty associated with the mean local dynamic pressures

- Resolution

- Calibration

- Drift

- Lack of Fit

- Overall corrections to dynamic measurements

Standard uncertainty associated with the molar mass of the gas

- φO₂,w

- φCO₂,w

- Oxygen, dry

- Carbon Dioxide, dry

- Water Vapour

- Oxygen, wet

- Carbon Dioxide, wet

-

Standard uncertainty associated with the mean velocity (95% Confidence)

Standard uncertainty associated with the mean velocity (95% Confidence), relative

Standard uncertainty associated with the volume flow rate (95% Confidence)

%

m/s

Pa

u(res) 0.00087

5.824

175.692

u(pstat) 1.847

u(ρ) 0.00316

%

Uc(qV,w)

0.00055

- #########

- 11587.8

Uc,rel(qV,w) 4.59

Standard uncertainty associated with the mean velocity

-

Standard uncertainty associated with the stack temperature

u(φH₂O) 0.067

u(φO₂,w) 0.604

-

Pa

m/s

-

u(φCO₂,d) 0.002

K

u(pc) 175.702 Pa

u(patm)

u(fit) 3.457

Standard uncertainty associated with the absolute pressure in the duct

- Atmospheric Pressure

u(drift) 0.083

- u(qV,w)

Standard uncertainty associated with the volume flow rate (95% Confidence), relative

u(M) 0.00003

- Static Pressure

Standard uncertainty associated with the density in the duct

Standard uncertainty associated with the local velocities

u(Cf)

u(cal) 2.283

2.612

u(Tc) 2.999

APPENDIX 2

22712.1 m³/hr

- u²(qV,w)

PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)

19.738

- 0.059

u(φO₂,d) 0.612

u(φCO₂,w) 0.002

- u²(a)/a²

- u²(qV,w)/q²V,w

-

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EPA Export 27-07-2016:01:29:56

Sample Runs

- -

- -

- -

- -

- -

- -

- -

- -

Blank Runs

- -

- -

General Sampling Information

FORMAT: Number Used / Number Required

FORMAT: Number Used / Number Required

Reference Conditions

Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.

g/hr 5015.6


Parameter

Concentration

22.15

Blank 1

Uncertainty

Filter Size and Material

Out Stack

Technical Procedure

Parameter Units

Uncertainty ±g/hr


Mean

1.31

Positioning of Filter

Number of Sampling Lines Used 2 / 2

Number of Sampling Points Used 16 / 16

Titanium

Filter Housing Material Borosilicate Glass

Probe Material

Parameter Units

Run 1

Water Vapour

Concentration

Mass Emission

Uncertainty ±mg/m³ 1.27 1.27

Units

TOTAL PARTICULATE MATTER: RESULTS SUMMARY

Mean

368.6

0.08 0.08

368.6

±% v/v

Standard

NOTE: Where the Balance Uncertainty / Limit of Detection is higher than the Blank concentration, the Balance Uncertainty / Limit of Detection concentration has

been reported.

47mm Glass Fibre

0.20

Parameter

EN 13284-1

Sample Point I.D.'s

1.31

CAT-TP-01

A1, A2, A3, A4, B1, B2, B3, B4, C1, C2, C3, C4, D1,

D2, D3, D4

% v/v

Value

APPENDIX 2

5015.6

mg/m³ 22.15

Run 1

Maximum

mg/m³ 0.20

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EPA Export 27-07-2016:01:29:56

Absolute pressure of stack gas, Ps

Volume of water vapour collected, Vwstd

Volume of gas metered dry, Vmstd

Moisture content, Bwo & Rwv

Bwo as a percentage

Reported Water Vapour, checked with Tables in EN 14790, Rwv

Volume of gas metered wet, Vmstw

Volume of gas metered at Oxygen Reference Conditions, Vmstd@X%O₂ & Vmstw@X%O₂

Molecular weight of dry gas stream, Md

CO₂ (Estimated)

O₂ (Estimated)

Molecular weight of stack gas (wet), Ms

Total flow of stack gas: Actual (Qa), Wet (Qstw), Dry (Qstd), Wet@O₂REF (QstwO₂), Dry@O₂REF (QstdO₂)

Percent isokinetic, %I

N/A

QstdO₂ = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) / (O₂REFd) m³/min N/A

Velocity pressure coefficient, Cp

Vmstw = (Vmstd)(100/(100 - Rwv))

Average square root of velocity heads, √∆P

Nozzle area, An mm²

% v/v

0.6943

APPENDIX 2

% v/v

mmH₂O

0.0092

Volume of gas sample through gas meter, Vm m³

Gas meter correction factor, Yd

0.5

109.8

m/s

-

Stack static pressure, Pstatic

m³/min

% v/v 1.31

QstwO₂ = ((Qa)(Ps)(Cf)) / ((Ts) + 273) / (O₂REFw)

%I = (4.6398E⁶)(Ts+273)(Vmstd) / (Ps)(Vs)(An)(q)(1 - (Rwv/100))

m³

Vwstd = (0.001246)(Vlc)

Average dry gas meter temperature, Tm °C 16.0

Vmstd = ((0.3592)(Vm)(Pb + (∆H/13.6))(Yd)) / (Tm + 273) m³

√mmH₂O

-17.1

7.4

Nozzle diameter, Dn

79.14

% oxygen reference condition, REF%O₂ % v/v N/A

% dry oxygen measured in gas stream, ACT%O₂d

O₂ Reference Factor dry (O₂REFd) = (21 - REF%O₂) / (21 - ACT%O₂d)

Vmstw@X%oxygen = (Vmstw) / (O₂REFw) m³ N/A

g

TOTAL PARTICULATE MATTER: ISOKINETIC SAMPLING CALCULATIONS

Test Units

Total mass collected in impingers (liquid trap)

mmH₂O

6.9

g

Total mass of liquid collected, Vlc

m³/min

Barometric pressure, Pb

0.84

O₂ Reference Factor wet (O₂REFw) = (21 - REF%O₂) / (21 - ACT%O₂w)

0.8940

1.31

Md = 0.44(%CO₂)+0.32(%O₂)+0.28(%N₂)

% v/v

0.7035

0.8282

Run 1

-

g

Average of velocity heads, ∆Pavg mmH₂O

Total sampling time, q

7.31

%

310.0

% v/v

-

min 32

% v/v

°C

Total

3868.3

Qstd = ((Qa)(Ps)(Cf)(1 - (Rwv/100))) / ((Ts) + 273) m³/min 3817.6

Ms = Md(1 - (Rwv/100)) + 18(Rwv/100)

N/A

Average stack gas temperature, Ts

15.63

3.95

37.83

m³/min

Vs = ((Kp)(Cp)(√∆P)(√Ts + 273)) / (√(Ms)(Ps)) 19.13

% v/v 20.86

mm

Qstw = ((Qa)(Ps)(Cf)) / ((Ts) + 273)

Conversion factor (K/mm.Hg), Cf

6.94

20.80

Ps = (Pb + (Pstatic / 13.6) mmHg

% wet oxygen measured in gas stream, ACT%O₂w

mmHg

N/A

Qa = (60)(As)(Vs)

Vmstd@X%oxygen = (Vmstd) / (O₂REFd)

Velocity of stack gas, Vs

N/A

N/A

-

m³

m³

Average pressure drop across orifice, ∆H

-

Total mass collected in impingers (silica trap)

Area of stack, As m²

% v/v

Bwo = Vwstd / (Vmstd + Vwstd) 0.0131

60.3

34.97

0.3592

750.0

m³

g/gmol 28.84

748.7

N₂

- N/A

No

Pitot tube velocity constant, Kp

g/gmol 28.70

-

0.06

8385.2

IED & Incinerates Hazardous Material? (Yes = no positive O₂ correction)

CAT-RT (Version BM)

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EPA Export 27-07-2016:01:29:56

Sample Runs

Filter I.D. Number

Probe Rinse I.D. Number

Where: ISO stands for Manual Isokinetic Sampling Train

Blank Runs

Filter I.D. Number

Probe Rinse I.D. Number

g

08/03/2016

g

g

2.83164

Total Mass Collected

Volume Sampled (REF) m³

0.00004

mg

g

g

-

Total Mass in Probe Rinse

Sampling Times

Blank 1

APPENDIX 2

-

End Probe Rinse Mass

2.96458

15.58

Average Volume Sampled (REF)

0.00010

Start Filter Mass

Total Mass in Probe Rinse

14:20 - 14:52

Sampling Dates -

End Probe Rinse Mass

g

0.14616

0.14900

Start Probe Rinse Mass

g

47-31325

47-31273

mg 0.14

0.20

Calculated Concentration

Total Mass Collected

End Filter Mass

-

Parameter

Parameter Units

m³

Balance Uncertainty / LOD

Calculated Concentration

08/03/2016

0.14518

Total Mass on Filter

PR-47-31325

mg/m³

g

g

0.7035

0.00284

-

End Filter Mass g

mg/m³

0.20

0.7035

Units

2.97732

g

0.14508

-

Blank Dates -

mg/m³

2.83168

Total Mass on Filter

TOTAL PARTICULATE MATTER: SAMPLING DETAILS

-

g

PR-47-31273

Start Filter Mass

22.15

0.20

Start Probe Rinse Mass

0.01274

Run 1

Sampling Device ISO

Balance Uncertainty / LOD mg/m³

CAT-RT (Version BM)

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Sample Runs

MU (Concurrent Water Vapour)

Run 1

-

Yes

APPENDIX 2

Pre-Conditioning Temperature °C

°C

mg/m³ 2.50

Water Droplets

%

Ambient Temperature Recorded? -

Overall Weighing Uncertainty

Less than 50% Faded

Units

Run 1

Units

Filter Temperatures

Units

Yes

Units Run 1

Pre-Sampling Leak Rate l/min 0.11

%

l/min 0.11

Allowable MU

(PAGE 1 OF 2)

Run 1

Run 1

Overall Weighing Uncertainty ± mg

20

°C

Isokinetic Criterion Compliance

Units

Measurement Uncertainty (MU)

-

Allowable Leak Rate

%

109.8%

Leak Test Results

Yes

0.38

120

Mean Sampling Rate l/min 23.14

%

Units

No

Isokinetic Variation

Yes

Run 1

Weighing Uncertainty Acceptable

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

Isokineticity Acceptable - Yes

-

Silica Gel (Concurrent Water Vapour) Units

Maximum Filter Temperature

Run 1

Post-Sampling Leak Rate

Are Water Droplets Present

l/min

Post-Conditioning Temperature

6.1

0.46

Leak Test Acceptable

ELV [Daily ELV for IED] mg/m³ 50.00

0.27

Run 1

Yes

± mg/m³

Weighing Uncertainty Criteria

160

Allowable Isokinetic Range %

MU Acceptable

Test Conditions Units

Allowable Weighing Uncertainty

95 - 115

180

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Blank Runs

Method Deviations

1

wx

- - - - -

- - - - -

- - - - -

- - - - -

- - - - -

l/min

-

Yes

Nature of Deviation

Expected Sampling Rate

Blank Acceptable

Blank Acceptable

Allowable Blank

mg/l

25.00

(x = deviation applies to the associated run, wx = deviation also applies to the concurrent water vapour run)

2.7

Blank 1

10

0.13

Post-Sampling Leak Rate l/min 11.00

Allowable Leak Rate

Acetone / Water Rinse Value

mg/m³

Validity of Blank vs ELV Units

5.0

l/min 0.50

l/min

(PAGE 2 OF 2)

There are no deviations associated with the sampling employed.

Acetone / Water Rinse Blank Units Blank

Allowable Blank

Leak Test Results

mg/l

-

Run Number

NoLeak Test Acceptable

Pre-Sampling Leak Rate

Units Blank 1

APPENDIX 2

TOTAL PARTICULATE MATTER: QUALITY ASSURANCE

- Yes

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Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Mass of Particulate

Uncollected Mass

Sampled Volume (Actual)

Sampled Gas Temperature

Sampled Gas Pressure

Sampled Gas Humidity

Leak

Mass of Particulate

Uncollected Mass

Sampled Volume (STP)

Leak

Mass of Particulate

Uncollected Mass

Sampled Volume (STP)

Leak

Mass of Particulate

Uncollected Mass

O₂ Correction Factor

Stack Gas O₂ Content

MU for O₂ Correction

Combined uncertainty

Expanded uncertainty (95% confidence), without Oxygen Correction

Expanded uncertainty (95% confidence), with Oxygen Correction

Expanded uncertainty (95% confidence), estimated with Method Deviations

Reported Uncertainty

Expanded uncertainty (95% confidence), without Oxygen Correction

Expanded uncertainty (95% confidence), with Oxygen Correction

Expanded uncertainty (95% confidence), estimated with Method Deviations

Reported Uncertainty

Units

289.0

ρm 99.8

Uncertainty in Result

mg/m³

mg/m³

0.14

UCM

L

Vm

% v/v

uρm

Tm uTm K 2.0

0.5

0.8282

Measured Quantities

uUCM mg -

≤1%

0.65

0.6943

% 0.40

Lr mg

uVm m³

≤1%

% 1.00

0.14

1.27

m³

0.0608

<5% of ELV

% 5.7

1.42

mg/m³ 1.27

0.69

%

Measured Quantities

%

uHm

0.0166

N/A

%

Run 1

2.00

Symbol Units Run 1

Run 1

-

Run 1 Requirement of Standard

mg/m³

Overall MU For O₂ Measurement

mg/m³ N/A

5.7

UCM

%

0.08

Uncertainty as a Percentage

N/A

Parameter

%

Symbol Units

mg/m³ 0.603

15.58

1.00

Units

mg

APPENDIX 2

TOTAL PARTICULATE MATTER: MEASUREMENT UNCERTAINTY CALCULATIONS

Value Standard uncertainty

Measured Quantities

- N/A

≤1%

mg/m³ 1.27

% 0.48

mg/m³

% N/A

Units

Run 1

31.90

mg/m³

Run 1

um

Vm

-uL %L 0.48

0.0Hm

kPa

m

≤2%

1.0

Measured Quantities Symbol

Uncertainty in Measurement Units Sensitivity Coefficient

%

Units Run 1

5.7

15.580

1.42

-

0.50

mg/m³

0.1990

0.061

0.1149

Run 1

≤2%

% v/v N/A

-

mg

%

Oxygen Correction Part of MU Budget

Measured Quantities

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