INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP) INTERNATIONAL COLLABORATIVE EXERCISES ... ·...

INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)

INTERNATIONAL COLLABORATIVE EXERCISES (ICE)

Summary ReportSEIZED MATERIAL

2013/2

This report contains the data received from laboratories participating in the current exercise. The results compiled in this report are not intended to be an overview of the quality of work and cannot be interpreted as such. These comments do not reflect the general state of the art within the profession.

Participant results are reported using a randomly assigned "WebCode". This code maintains participant's anonymity, provides linking of the various report sections, and will change with every report.

Samples Substances Concentrations Comments on substances

Sample 1 Heroin 38.6 %

Sample 2 Caffeine 0 %

Amfetamine 4.9 %

Sample 3 1-(3-Chlorophenyl)piperazine 82.1 %

Sample 4 Lactose 0 %

Test Samples Information

Samples Comments on samples

Sample 1 SM-1 was prepared from a seizure containing 38.6% w/w heroin base.The seizure also contained acetyl codeine,6-monoacetylmorphine glucose and trace amounts of codeine and morphine

Sample 2 SM-2 was prepared from a seizure containing 4.9% w/w amphetamine base.The seizure also contained caffeine and creatinine.

Sample 3 SM-3 was prepared from a seizure containing 82.1% w/w 1-(3-chlorophenyl)piperazine base.The seizure also contained trace amounts of codeine and morphine.

Sample 4 SM-4 was prepared from the diluent lactose

2013/2-SM Copyright (c) 2014 UNODC

INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)

Table of contents Introduction Page 2 Comments from the International Panel of Forensic Experts Page 2

Codes and Abbreviations Page 4 Sample 1 Analysis Page 6 Identified substances Page 6

Statement of findings Page 10 Identification methods Page 19

Summary Page 23 Z-Scores Page 24 Sample 2 Analysis Page 27 Identified substances Page 27

Statement of findings Page 30 Identification methods Page 39

Summary Page 43 Z-Scores Page 44 Sample 3 Analysis Page 46

Identified substances Page 46 Statement of findings Page 49 Identification methods Page 57 Summary Page 62

Z-Scores Page 63 Sample 4 Analysis Page 65

Identified substances Page 65 Statement of findings Page 66 Identification methods Page 74 Summary Page 78

Introduction An important element of the UNODC International Quality Assurance Programme (IQAP) is the implementation of the International Collaborative Exercises (ICE). The exercises allow laboratories, from both developing and developed countries, to continuously monitor their performance in drug testing on a truly global scale. This report provides information on analytical results of laboratories participating in the Seized Materials (SM) group. In order to maintain confidentiality, the participating laboratories have been assigned random “Web Codes”, which change every round. Two rounds are offered per year with each round presenting participants with four different test samples for analysis. The analytical results returned by laboratories participating in ICE are evaluated by UNODC and a confidential report is provided to each laboratory on its own performance. The overall analytical results are reviewed by the UNODC’s International Panel of Forensic Experts which oversees the implementation of these exercises, and offers guidance and support in addressing relevant quality issues. The exercises provide an overview of the performance and capacity of participating laboratories and enable UNODC to tailor technical support in the laboratory sector for greatest impact.

Comments from the International Panel of Forensic Experts Participation of Laboratories Samples within both the Seized Materials (SM) and Biological Specimens (BS) test groups were sent to 165 laboratories in 59 countries. Within the SM test group, samples were sent to 136 laboratories and 131 laboratories (96%) submitted the results of their analysis in time for inclusion in the summary report, with 128 (98%) using the ICE portal for return of results.. Qualitative Analysis The results for the qualitative identification of the ICE menu substances were good for all test samples in the SM group. 98% and 95 % of participants correctly identified the heroin and amphetamine in SM-1 and SM-2 respectively. It is encouraging to note that 94% of participants identified the 1-(3-chlorophenyl)piperazine in SM-3, indicating an excellent level of awareness of participants in the identification of this New Psychoactive Substance (NPS). As the ICE programme develops, UNODC will include further examples of representative NPS in the ICE menu to assist participants in their analysis and detection of emerging substances. ICE participants are encouraged to use the UNODC Early Warning Advisory on New Psychoactive Substances http://www.unodc.org/nps, to report NPS detected in their laboratories. This information will greatly assist UNODC to further target its technical assistance to ICE participants. SM-4 was a blank test sample containing no substances in the ICE menu. Overall, 90% of participants overall used GC-MS for the qualitative analysis indicating wide access to this technique which is one of the most commonly used tandem techniques for the confirmation of controlled substances. It is encouraging to note that only 15 false positive results were reported for the four test samples in the SM group, while there were also only 9 false negative results. The detection limits of the different analytical techniques are taken into consideration when ascribing false positive results and as such laboratories who detected the trace amounts of morphine in SM-1 and morphine and/or Codeine in SM-3 should not consider their results as false positives. Quantitative Analysis A modified Z-score was used for the statistical examination of the quantitative results, as it is a robust method based on absolute deviations from the median of all participant values and is relatively insensitive to outliers. Test samples in the previous three successive rounds of ICE have contained heroin and the percentages of laboratories performing quantification for this substance has remained stable at 68% for ICE 2012/1, 70% for ICE 2012/2, 68% for ICE 2013/1 and 71% for this current round. As 1-(3-chlorophenyl)piperazine is a new substance on the ICE test samples for this current round, it is encouraging to see 29% of laboratories already performing quantitative analysis for this drug. It is understood that quantitative analysis of controlled substances is often governed by local legislation and the requirements of prosecution. Analysis of the Z-scores showed that 83 out of 93 (89%) of participants provided acceptable quantitative results with Z-scores within 3.5 for heroin in SM-1, 69 out of 75 (92%) for amphetamine in SM-2 and 29 out of 37 (78%) laboratories for 1-(3-chlorophenyl)piperazine in SM-3. Participants with Z-scores outside acceptable limits should review their quantification procedures.


http://www.unodc.org/nps

71% of participants in this round quantified at least one test sample and 27% quantified all three test samples. The predominant analytical techniques used by participants for quantification within the SM test group were GC-FID (51%), followed by HPLC (24%). Z-score values obtained from quantitative analysis assist participating laboratories in evaluating their performance and Z-scores should be monitored over time as part of each laboratory’s quality assurance programme.


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Codes and Abbreviations

Tech Code Name

140 Colorimetric reactions

141 Marquis reagent (sulphuric acid, formaldehyde)

142 Cobalt thiocyanate

150 Thin Layer Chromatography

160 High/Ultra High Performance Liquid Chromatography

161 High Performance Liquid Chromatography with diode array detection

170 Gas Chromatography NPD

171 Gas Chromatography FID

172 Gas Chromatography ECD

180 Gas Chromatography/Mass Spectrometry

190 Fourier Transform Infrared Spectrometry

200 Spectrophotometry (visible, UV)

210 Others (specify)

211 NMR

220 Microcrystal test

230 Liquid chromatography/mass spectrometry

231 Liquid chromatography/tandem mass spectrometry

(+) “positive”: Indicates that the analyte is identified; for presumptive tests (e.g. colour reactions), indicates that a positive reaction was obtained.

(-) “negative”: Indicates that the analyte is not identified.

(ANP): Analysis not performed.

2013/2-SM Copyright (c) 2014 UNODC(5)


Identified substances for Test Sample 1

Code Identified Substances0DA6JO HEROÍNA + CANABIDIOL

0NNGO4 Heroin

0YFLNL Heroin

144FAB diamorphine hydrochloride

192GH2 Heroin

28NZ22 Heroin

2EQC6Q Heroin

2UUUXU Heroin

3DVBVE Heroin

3LN2N9 Heroine

44VN4T Heroin Hydrochloride

4CVIID Heroin

4Y4BMB Heroin

5AKBA5 heroin chlorhydrate

5DMOWW Heroïn

5OHSAB DIACETYLMORPHINE

5V2K55 heroine, 6-MAM, Acetylcodeine

66P66H eroina

6AAAIA Heroin, 6-MAM, Acetylcodeine

7JPM7K heroin

7NMYY7 Heroin

815B51 HEROINA

9999JM heroin

9AT7DN Heroin & Morphine (trazes)

9S9R99 Heroin

A4DVDD Heroin

AC6AA0 Heroin

ARRBBM Heroine

AXAVAA heroin

B11A58 Heroine,HCl

BR66FX Heroin

C6UZN1 heroin

CFILQS heroin hydrochloride

CITDQT Acetylcodeine, 6-Monoacetylmorphine, Codeine, Morphine and Delta-9-THC

CMQISC heroin

CPCFME Heroin

DFLETW Heroin

DGEIFI Diamorphine HCl

DWGQZS héroine

E4AF6Q Heroin

Sample 1 Analysis



Code Identified SubstancesE5B6AC Morphine

EOZOOO Heroin, monoacetylmorphines and codeine

G7GGCR heroin

GGWXWW Diamorphine (Heroin)

GULHNN Heroin, Monoacetylmorphines

GZDUQM Heroin

HBHUNI Heroine+Acetlcodeine+6MAM

HE2TG2 Heroin

HHHHU5 DIAMORPHINE HYDROCHLORIDE

HHRTHH Heroin

HVXZXL Heroin/Morphine

HWGQ3X Heroin, Acetylcodeine, 6-Monoacetylmorphine

I5IP07 HEROIN

IAWA6A heroin

IBOQKX Heroin

II8JO4 Heroin

IP12QF Heroin

JDDD6D Heroin

JJRRVN heroin

JKBKRK Heroin

JPIPOT Heroine

JRLS5J heroin, morphine

JSHHOS Diamorphine

JSZMHJ Base Heroin

JYDFMU heroin

KKQS2K heroin

LLCQXL 6-Monoacetylmorphine and Heroin

LQEYRY heroin, morphine, codein, 6-acethylcodein, 6-acethylmorphine

N0TYZE Heroin

NBNVJG HEROIN

NNVNSC heroin

NRVAVR HEROIN

NVUXXR Heroin

NZMVTG Diamorphine

O0NJNN Diacetyl morphine

ODFBYE HEROIN 36%, MORPHINE 2,6% , 6-MONOACETYLMORPHINE

OF0Q00 Heroin

OOAION Heroin, Morphine

OOIOUO Heroin, Acetyl Codeine, Mono Acetyl Morphine and Morphine

P04CR4 Heroin

PCR99G heroin and 6-monoacetylmorphine

PDMMHM HEROIN

PWYKZQ Heroin

QMG6MM Heroïn



Code Identified SubstancesQPEFZE Heroin

QRPRRR heroin hydrochloride

QXZKSQ Heroin

R21VX8 Heroin

RBFBBM Heroin, Acetylcodeine, 6-Monoacetylmorphine

RRR6HI HEROIN

RSNKH3 heroin

SL61P0 Heroin

SLJETI heroin

SUA1EC heroin

SZT4VF heroine

SZVCHI heroin

T3A33W Heroin

UBJZMK Heroin

UGGGBT heroin

UOBROB Heroina

UVIZDN Heroin,Morphine

UY78GL HEROÍNA

UYAC2L Heroin

VDZ8NV Heroína

VWU2B0 heroin

W4B4QT Heroin

WABFAA heroin

WEEH53 heroin

WELQMQ heroin

WLPRZL heroin

WLZJLF Heroína y Acetilcodeína

WM8MGO HEROÍN

WTCTPT Heroin

WUAUUU heroin

WVBNU6 heroin, ACETILCODEINE

WWWH4N Heroin HCl

X3UUYH heroine,6-monoacetylmorphine,Acetylcodeine

X8WVVF heroin, monoacetylmorphine

XDOWHP heroin

XLL0OS heroine

XNSNEU Heroin

XPOMU1 HEROIN

XSNG6F Heroin

XXR4ZM Heroin

Y6T66I heroine

YXMHT9 heroin HCl

YXXRY9 Heroin

Z0BIZI Heroin



Code Identified SubstancesZ1SAXE heroin

ZLFXWZ Heroin



Code Heroin

0DA6JO +

De los análisis realizados se concluye que el polvo blanco se trata de una mezcla que contiene heroína y canabidiol.

0NNGO4 +

0YFLNL +1 glass bottle containing 0.23 grammes of a mixture containing 0.08 grammes of heroin hydrochloride (being a salt of heroin).

144FAB +

A white powder containing an average of 41% of diamorphine hydrochloride

192GH2 +The sample contains heroin, 6MAM, acetyl codeine and dextrose.

28NZ22 +

The sample contains heroin (36.1%), acetylcodeine and 6-monoacetylmorphine.

2EQC6Q +

The sample also contained acetylcodeine, 6-monoacetylmorphine.

2UUUXU +

After analysing the sample with colourimetric tests, MSD confirmation and subsequent quantification by chromatography with FID detector, we are confident that the SM-1 sample contains 29.59 % heroin base

3DVBVE +

3LN2N9 +

contained heroine, acetylcodeine and 6-monoacetylmorphine

44VN4T +

Heroin hydrochloride and dextrose confirmed in one unit tested of one unit recieved.

4CVIID +

In the test sample 2013/2/SM-1 were detected heroin, 6-monoacetylmorphine and acetylcodeine

4Y4BMB +

acetyl-codeine

5AKBA5 +

glucose, acetylcodeine, monoacetylmorphine

5DMOWW +

Find also acetylcodeine and glucose. Heroïn is a drug of abuse. Acetylcodeine comes from acetylation of codeine coming from opium. Glucose is a sugar

5OHSAB +

Was found too ACETYLCODEINE

Statement of findings for Test Sample 1



Code Heroin

5V2K55 +

66P66H +

6AAAIA +

Illegal substances on the basis of the italian law DPR 309/90

7JPM7K +

7NMYY7 +

815B51 +

LA MUESTRA DE POLVO BLANCO ES UNA MEZCLA DE HEROINA Y LACTOSA

9999JM +

Sample contains 36.4 ± 2.2 w/w heroin base in HCL salt form. 6-MAM and acetyl-codeine were also detected.

9AT7DN +

It was also detected: 6-MAM, acetylcodeine and codeine. However, it wasn't detected noscapine and papaverine, natural opiates found in Papaver somniferum. No adulterants were found.

9S9R99 +

We found heroin in SM-1 as controlled drugs

A4DVDD +

The sample 2013/2/SM-1 contains Heroin detected by GC-MS. The percentage by weight of Heroin is 35.8%.detected by GC-FID.

AC6AA0 +

Heroin was identified by TLC and GC/MS

ARRBBM +

AXAVAA +

B11A58 +the powder contains heroine chlorhydrate with glucose

BR66FX +

The sample contains heroin. The percentage by weight of heroin (as base) is 34.3%.

C6UZN1 +

6-monoacetylmorphine, acetylcodeine



Code Heroin

CFILQS +

sample 1 contains Heroin HCl (35,5% as base) cut with glucose. We also identify o-6 MAM, acetylcodeine and codeine.

CITDQT -

Major compounds detected are Acetylcodeine and 6-Monoacetylmorphine. No quantitation performed.

CMQISC +

CPCFME +

On analysis, I found the sample to contain diamorphine. (Under Irish legislation, heroin is controlled as diamorphine)

DFLETW +

DGEIFI +

This powder contained an average of 36% DIAMORPHINE (commonly known as 'heroin') together with the adulterant glucose.

DWGQZS +

acétyl codéine, 6-mono acetylmorphine, dextrose

E4AF6Q +

Heroin, acetylcodein, monoacetylmorphine and glucose

E5B6AC -

Marquis reagent have been apllied, TLC (Thin Layer Chromatography) for opiaces, cocaine and the GC/FID

EOZOOO +

Based on the above analysis, the sample was found to contain 36.3 % heroin. The sample also found to contain monoacetylmorphines, acetylcodeine and codeine.

G7GGCR +

glucose

GGWXWW +

The powder was analysed and found to contain Diamorphine. A portion of the powder was further analysed and found to contain Diamorphine.

GULHNN +

On analysis, I found the substance to contain 37.1% of Heroin

GZDUQM +

Sample 2013/2/SM-1 consists of white powder. Heroin, a prohibited substance included in the National Law for Narcotics, is found to be present in this sample. The seizure also contains acetylcodeine, 6-mono-acetyl-morphine and traces of morphine.

HBHUNI +

Powder containg Heroine, Acetylcodeine and 6MAM

HE2TG2 +

Presence of chlorides



Code Heroin

HHHHU5 +

Test Sample 2013/2/SM-1 - one vial containing off-white powder. This powder contained an average of 44% DIAMORPHINE HYDROCHLORIDE.

HHRTHH +

SM1 contain Heroin.HCl

HVXZXL +

Heroin and morphine detected in SM-1.Heroin content is 34.18% and morphine content is 0.61%.

HWGQ3X +

Color Test: Marquis' --> violet; Mecke --> deep green; Froehde---> purpleTLC & GCMS: Heroin, Acetylcodeine, 6-MonoacetylmorphineGC: Heroin Base 36.83%

I5IP07 +

HEROINE HYDROCHLORIDE 36.4 %( as BASE ), GLUCOSE

IAWA6A +

acetyl-codeine and 6-MAM

IBOQKX +

This sample is heroin.

II8JO4 +

Powder was found to contain diamorphine at a concentration of 37%. Diamorphine is controlled by the Misuse of Drugs Act 1971 (as amended) as a Class A drug.

IP12QF +

The sample is a preparation that contains heroin.

JDDD6D +

The test sample 2013/2/SM-1 was analysed by colour test and Thin layer Chromatography techniques and found to contain Heroin.

JJRRVN +

The sample was found to contain heroin.

JKBKRK +

0.234grams of a powder containing 41% Diamorphine. Diamorphine is a Class A controlled drug under the provisions of the Misuse of Drugs Act 1971.

JPIPOT +

The sample SM1 contained 36.5 % calculated as a base. In the sample was identified glucose and codeine.

JRLS5J +

The sample contains heroin, morphine and codeine which are scheduled as illicit drugs in France. Glucose is a cutting agent.

JSHHOS +

The powder was analysed and found to contain diamorphine.

JSZMHJ +

Base Heroin 37,11+/- 4,31 % (w/w), Acetylcodeine; 6-momoacetylmorphine and Glucose



Code Heroin

JYDFMU +

acetylcodein, mono acetylmorphin, glucose

KKQS2K +

acetylcodein, 6-monoacetylmorphine

LLCQXL +

On analysis, I found the substance to contain 6-Monoacetylmorphine and Heroin. Quantitative analysis was not carried out to determine the weight of the drugs.

LQEYRY +

We also found glucose

N0TYZE +

NBNVJG +

ACETILCODEINA Y 6-MONOACETILMORFINA

NNVNSC +

heroin with glucose

NRVAVR +

The sample 2013/2/SM-1 was found to contain Heroin.

NVUXXR +

Narcotics: Heroin (I) (the number refers to legislation)Concentration: 41 % heroinhydrochlorideAmount: 0,2 gram

NZMVTG +

The sample was found to contain 37.7% of diamorphine (as base).

O0NJNN +

Test sample 2013/2/SM1 was found to contain Heroin which is a controlled drug.

ODFBYE +ACETYLCODEINE, CODEINE

OF0Q00 +

The sample contain heroin. The dample contain traces of acetyl-codeine and 6-monoacetyl-morphine

OOAION +-

OOIOUO +

Examination revealed the presence of illicit heroin

OQ2JQM +



Code Heroin

P04CR4 +

-The sample obtains with the positive result with Marquis reagent.- TLC: The Rf sample obtain with the same Rf Heroin Standard.- GC: The Rt sample obtain with the same Rt Heroin Standard.

PCR99G +

the sample also contains heroin, 6-monoacetylmorphine and acetylcodeine

PDMMHM +

TRACES OF CODEINE, MORPHINE, ACETYLCODEINE AND 6-MAM WERE IDENTIFIED

PWYKZQ +

Acetylcodeine and 6-monoacetylmorphine

QMG6MM +

QPEFZE +

QRPRRR +

the presence of drug confirmed by GC-MS and FTIR analysis, the hydrochloride form confirmed by the anion analysis

QXZKSQ +

The sample contains heroin which is listed as a controlled drug according to french order, appendix I of February 22nd 1990.

R21VX8 +

GC MS AND NPD

RBFBBM +

RRR6HI +

HEROIN as base 35.7% - GLUCOSE

RSNKH3 +

White powder containing Heroin (38%ww) and 6-monoacetylmorphine (0.9%ww) controlled by national law. In addition also acetylcodeine is present

SL61P0 +

Acetylcodeine, Monoacetylmorphine (MAM)

SLJETI +

SUA1EC +

6-MAM, acetil-kodein

SZT4VF +sample contains heroine hydrochloride (30,64% of heroine base)



Code Heroin

SZVCHI +

positive to marquis reagent: violetretention time as our pattern of heroin

T3A33W +

UBJZMK +

Heroin (diacetylmorphine) was detected at 35.61%

UGGGBT +

the sample was performed by UV, tlc, Gc ms and also contains 6 Monoacetyl morphine and acetyl codeine

UOBROB +

UVIZDN +

In this sample contain five substance .Heroin,Morphine,6monoacetylmorphine,Acetylcodeine and Glucose

UY78GL +

LA MUESTRA AL SER ANALIZADA SE ENCONTRO QUE CONTIENE HEROÍNA

UYAC2L +

Heroin and lactose

VDZ8NV +

se le realizó pruebas de marquis, scott, lieberman´s, Mad4linn´s, también microcristales con cloruro de mercurio al 2%, FT-IR, UV

VWU2B0 +

W4B4QT +

Heroin + acetylcodeine. Heroin=38% +-4% as free base

WABFAA +

heroin, morphinan, 6-monoacethylmorphin

WEEH53 +

white powder containing 35.7%ww of heroin

WELQMQ +

WLPRZL +

the result of TLC and IR of test sample was shown same as those of the reference substance of heroin.

WLZJLF +



Code Heroin

WM8MGO +

The results of the tests of the SM1 (81) received confirmed that the mentioned sample contains heroin with 35.1percentage by weight (35.1%)

WTCTPT +

Heroin is controlled by law (KB 31/12/1930, changed by KB 8/10/1963)

WUAUUU +

white powder, other alkaloid acetylcodeine, glucose (dextrose) as diluent ingredient

WVBNU6 +

WWWH4N +

SM 1 contains: Acetylcodeine, 6-monoacetylmorphine, Glucose.Trace amounts of Morphine could be detected

X3UUYH +

X8WVVF +

white powder containing 34.8%ww heroin and 5.8%pp monoacetylmorphine (MAM). Acetylcodeine and glucose are present.

XDOWHP +

the powdre is a mixture of heroin, other opiates and glucose. The concentration of heroin in the sample is 37.5% by weight

XLL0OS +

acetylcodeine, 06-monoacetylmorphine and lactose

XNSNEU +

Presence of heroin hydrochloride, acetilcodeine and glucose was detected in the sample.

XPOMU1 +

XSNG6F +

Sample 2013/2/SM-1 was found to contain Heroin a Schedule I drug under the Single Convention on Narcotic Drugs. The sample was also found to contain Acetylcodeine.

XXR4ZM +

Sample 2013/2/SM-1,a white odorless powder, was found to contain Heroin, a controlled substance under National Law.

Y6T66I +

The sample also contains acetylcodeine, 6-monoacethylmorphine

YXMHT9 +

acetylcodeine

YXXRY9 +

White powder containing Heroin and traces of Acetyl-codeine, Monoacetylmorphine and Morphine



Code Heroin

Z0BIZI +

Z1SAXE +

found heroin 39.9%ww, 6-monoacetylmorphine and 6-acetylcodeine

ZLFXWZ +

On analysis, I found the substance to contain 36.4% Heroin



Identification methods for Test Sample 1

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

0DA6JO S S S I SI Ion Mobility Spectrometry

0NNGO4 S I I

0YFLNL S S SI I

144FAB S S I I

192GH2 S S I I

28NZ22 S S S I I

2EQC6Q SI I

2UUUXU S I

3DVBVE S I I

3LN2N9 SI

44VN4T I SI I I

4CVIID I I I

4Y4BMB S I I

5AKBA5 SI

5DMOWW

I SI I

5OHSAB S S S I I

5V2K55 I SI

66P66H SI SI

6AAAIA I I

7JPM7K I

7NMYY7 SI S I

815B51 S I I I ESPECTROMETRIA DE MASAS/INSERCION DIRECTA

9999JM I S I SI SI

9AT7DN I SI I I

9S9R99 S I I

A4DVDD SI I

AC6AA0 S S S I I

ARRBBM SI I

AXAVAA S S S SI

B11A58 I SI I

BR66FX SI I I

C6UZN1 S SI I I

CFILQS S S I I

Analytical Technique Codes

Legend: S ... used for Screening I ... used for Identification SI ... used for both



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

CITDQT S I S Simon's

CMQISC S I I

CPCFME I SI

DFLETW I SI

DGEIFI S S I I

DWGQZS SI I

E4AF6Q S I

E5B6AC SI S S I I

EOZOOO S I I

G7GGCR S S S I I I

GGWXWW

S I

GULHNN S I I

GZDUQM S S I I I I

HBHUNI SI I I

HE2TG2 S S SI I

HHHHU5 S S I I

HHRTHH S S S I

HVXZXL I I I S colloidal gold

HWGQ3X S S I I I

I5IP07 S S I I

IAWA6A I SI I

IBOQKX S I I

II8JO4 S S I I

IP12QF I S I

JDDD6D S S I I A

JJRRVN S I I

JKBKRK S S I I

JPIPOT I I

JRLS5J S S I I

JSHHOS S S I I

JSZMHJ S I I I XRD

JYDFMU SI SI

KKQS2K S I S

LLCQXL S I

LQEYRY SI I

N0TYZE SI

NBNVJG S I I

NNVNSC I I

NRVAVR S S S I I



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

NVUXXR SI I

NZMVTG SI I LC/ELSD

O0NJNN SI

ODFBYE SI SI SI I I I

OF0Q00 SI ASAP-TOF

OOAION SI

OOIOUO S SI

OQ2JQM S S S I I

P04CR4 S S S I I

PCR99G S S I I

PDMMHM I SI I

PWYKZQ I SI

QMG6MM I SI SI

QPEFZE S S S I I I S

QRPRRR S S I I I

QXZKSQ I I

R21VX8 I SI

RBFBBM S I I

RRR6HI S S S I I I

RSNKH3 I SI

SL61P0 I SI

SLJETI SI

SUA1EC S SI I I

SZT4VF S SI I I I I

SZVCHI S I

T3A33W S S I I SI

UBJZMK S S I I

UGGGBT S I I

UOBROB S I I

UVIZDN S S S I I

UY78GL S I I

UYAC2L SI I

VDZ8NV S S S I I I I

VWU2B0 SI S S I I

W4B4QT S S I I

WABFAA SI SI I I I

WEEH53 I SI

WELQMQ SI I

WLPRZL I I SI



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

WLZJLF S SI S I I

WM8MGO

SI SI SI I

WTCTPT I S

WUAUUU SI I

WVBNU6 SI SI I I

WWWH4N

I S I I

X3UUYH S S S I I

X8WVVF I SI

XDOWHP I I I SI I I xrd

XLL0OS SI SI I I I

XNSNEU S S S S I I I

XPOMU1 I I SI FPIA

XSNG6F S I

XXR4ZM S S I I

Y6T66I S I I I

YXMHT9 I I S ATR

YXXRY9 S I SI SI I

Z0BIZI S I I

Z1SAXE SI

ZLFXWZ S I I





Frequency of use of screening and identification techniques:

Summary for test sample 1The response summary of all 130 participating laboratories for the identification of SM-1, frequency of use of screening andidentification techniques and false positives and negatives:

Identification of test sample 1:

False positives for Test Sample 1

Code Name Technique

180

Response SummaryParticipants: 131

Heroin: 129

142 150 160 161 170

Response Summary Participants: 130

0DA6JO Cannabidiol Ion mobility spec

CITDQT ∆-9-THC

False negatives for SM-1 (techinque(s) used or ANP)

Code: CITDQT (180) E5B6AC (171)

Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 43 54 39 16 0 2 0 2 41 8 1 0 0 0 6

32.8% 41.2% 29.8% 12.2% 0.0% 1.5% 0.0% 1.5% 31.3% 6.1% 0.8% 0.0% 0.0% 0.0% 4.6%

Identification 12 6 3 30 6 15 3 20 118 70 2 3 2 3 9

9.2% 4.6% 2.3% 22.9% 4.6% 11.5% 2.3% 15.3% 90.1% 53.4% 1.5% 2.3% 1.5% 2.3% 6.9%

# labs using this technique

48 54 40 39 6 16 3 21 118 73 3 3 2 3 11

36.6% 41.2% 30.5% 29.8% 4.6% 12.2% 2.3% 16.0% 90.1% 55.7% 2.3% 2.3% 1.5% 2.3% 8.4%


Z-Scores for Test Sample 1

CODEHeroinMAD: 1.5

Conc. * AbsDev ZScore

0YFLNL 32.4 4.1 1.9

144FAB 35.0 1.5 0.7

192GH2 44.3 7.8 3.7

28NZ22 36.1 0.4 0.2

2EQC6Q 37.3 0.8 0.4

2UUUXU 35.2 1.3 0.6

3DVBVE 34.2 2.3 1.1

3LN2N9 37.2 0.8 0.3

44VN4T 35.2 1.3 0.6

4CVIID 37.0 0.5 0.3

4Y4BMB 34.7 1.8 0.8

5AKBA5 35.0 1.5 0.7

5DMOWW 22.4 14.1 6.5

5V2K55 37.9 1.5 0.7

66P66H 19.0 17.5 8.1

6AAAIA 30.7 5.8 2.7

7NMYY7 32.9 3.6 1.7

9999JM 36.4 0.1 0.0

9AT7DN 32.7 3.7 1.7

A4DVDD 35.8 0.7 0.3

AC6AA0 35.6 0.9 0.4

AXAVAA 40.7 4.3 2.0

B11A58 36.6 0.1 0.1

BR66FX 34.3 2.2 1.0

CFILQS 35.5 1.0 0.4

CPCFME 33.6 2.9 1.3

DFLETW 38.4 2.0 0.9

DGEIFI 36.0 0.5 0.2

DWGQZS 37.8 1.3 0.6

E4AF6Q 39.3 2.8 1.3

EOZOOO 36.3 0.2 0.1

G7GGCR 39.4 3.0 1.4

GGWXWW 36.0 0.5 0.2

GULHNN 37.1 0.6 0.3

HHHHU5 38.0 1.6 0.7

HHRTHH 41.3 4.8 2.3

HVXZXL 34.2 2.3 1.1

HWGQ3X 36.8 0.4 0.2

I5IP07 36.4 0.1 0.0

IBOQKX 36.7 0.2 0.1

II8JO4 37.0 0.5 0.3

2013/2-SM


CODEHeroinMAD: 1.5


IP12QF 24.5 12.0 5.6

JJRRVN 35.7 0.8 0.3

JKBKRK 41.0 4.6 2.1

JPIPOT 36.5 0.0 0.0

JRLS5J 38.0 1.6 0.7

JSZMHJ 37.1 0.7 0.3

JYDFMU 52.2 15.8 7.3

LQEYRY 38.9 2.4 1.1

N0TYZE 29.0 7.5 3.5

NNVNSC 37.3 0.8 0.4

NVUXXR 37.0 0.5 0.3

NZMVTG 37.7 1.3 0.6

ODFBYE 36.0 0.5 0.2

OOAION 41.5 5.1 2.4

OOIOUO 35.4 1.1 0.5

P04CR4 57.0 20.5 9.6

PCR99G 40.3 3.8 1.8

PDMMHM 36.7 0.3 0.1

PWYKZQ 34.6 1.9 0.9

QMG6MM 37.3 0.8 0.4

QPEFZE 67.0 30.6 14.2

QRPRRR 33.2 3.3 1.5

QXZKSQ 37.1 0.6 0.3

RBFBBM 35.4 1.1 0.5

RRR6HI 35.7 0.8 0.4

RSNKH3 38.0 1.6 0.7

SL61P0 35.5 1.0 0.4

SZT4VF 30.6 5.8 2.7

SZVCHI 35.0 1.4 0.7

UBJZMK 35.6 0.8 0.4

VDZ8NV 65.7 29.2 13.6

VWU2B0 36.0 0.5 0.2

W4B4QT 38.0 1.6 0.7

WABFAA 38.0 1.6 0.7

WEEH53 35.7 0.8 0.3

WELQMQ 54.2 17.8 8.3

WLPRZL 46.0 9.6 4.4

WM8MGO 32.7 3.8 1.7

WTCTPT 36.6 0.1 0.1

WUAUUU 38.0 1.6 0.7

WWWH4N 35.9 0.6 0.3

X3UUYH 37.0 0.5 0.3

(24)

CODEHeroinMAD: 1.5


X8WVVF 34.8 1.7 0.8

XDOWHP 37.5 1.1 0.5

XLL0OS 38.0 1.6 0.7

XNSNEU 30.0 6.5 3.0

XSNG6F 36.0 0.5 0.2

XXR4ZM 29.1 7.4 3.4

Y6T66I 36.2 0.3 0.1

YXMHT9 39.0 2.6 1.2

Z1SAXE 39.9 3.5 1.6

ZLFXWZ 36.4 0.1 0.0

*) Concentration: w/w %

Z-Score has been calculated as modified Z-Score as it is a robust method and therefore relatively insensitive to outliers.Modified Z-Score = 0.6745 * AbsDev/MADAbsDev = Absolute value of the difference between a laboratory value and the median of all the laboratory values for the given drug;MAD = median absolute deviation about the median.Modified Z-scores with an absolute value of greater than 3.5 should be considered as potential outliers.Reference:Iglewicz, B. and Hoaglin, D. C.: 1993 How to Detect and Handle Outliers, American Society for Quality Control, Milwaukee, WI

2013/2-SM Copyright (c) 2014 UNODC


(25)

Substance: SM-1/Heroin 1.5MAD =Median =UNODC value = 38.6

36.4

Round: 2013/2


Z-Score Report per Sample per Substance

(26)


Code Identified Substances0DA6JO ANFETAMINA

0NNGO4 caffeine

0YFLNL Amphetamine

144FAB amphetamine

192GH2 Amphetamine

28NZ22 Amfetamine

2EQC6Q Amfetamine

2UUUXU Amhetamine

3DVBVE Amphetamine

3LN2N9 amfetamine

44VN4T d,l-amphetamine

4CVIID Amfetamine

4Y4BMB amphetamine

5AKBA5 amphetamine sulfate

5DMOWW amfetamine sulfate

5OHSAB Benzeneethanamine, N-methyl; N-acetylamphetamine

5V2K55 Amphetamine

66P66H amfetamina

6AAAIA Amphetamine

7JPM7K amphetamine

7NMYY7 Amfetamine

815B51 ANFETAMINA - CAFEÍNA

9999JM amphetamine

9AT7DN Amfetamine

9S9R99 amphetamine

A4DVDD Amfetamine and Caffeine

AC6AA0 Amphetamine

ARRBBM Amphetamine

AXAVAA amphetamine

B11A58 Amphétamine

BR66FX Amphetamine

C6UZN1 amphetamine

CFILQS Amfetamine sulfate

CITDQT Amphetamine

CMQISC amfetamine

CPCFME Amphetamine

DFLETW Amfetamine

DGEIFI Amphetamine and caffeine

DWGQZS éthylamphétamine

E4AF6Q Amphetamine

Sample 2 Analysis



Code Identified SubstancesE5B6AC Caffeine and derivates amphetamines

EOZOOO Amphetamine

G7GGCR amfetamine

GGWXWW Amphetamine

GULHNN Amphetamine

GZDUQM Amfetamine

HBHUNI Amfetamine

HE2TG2 Amphetamine, caffeine

HHHHU5 AMPHETAMINE

HHRTHH Amphetamine

HVXZXL Amfetamine/Caffeine

HWGQ3X Amphetamine Sulfate

I5IP07 AMPHETAMIN

IAWA6A amphetamine

IBOQKX Amphetamine

II8JO4 Amphetamine

IP12QF amphetamine, caffeine

JDDD6D Amfetamine and Caffeine

JJRRVN amfetamine

JKBKRK Amfetamine

JPIPOT Amphetamine

JRLS5J amfetamine, caffeine

JSHHOS Amphetamine

JSZMHJ Amfetamine sulphate

JYDFMU amphetamine

KKQS2K amfetamine

LLCQXL Amphetamine and caffeine.

LQEYRY caffein and amphetamine

NBNVJG ANFETAMINA

NNVNSC amfetamine

NRVAVR Amfetamine. Caffeine.

NVUXXR Amphetamine

NZMVTG Amphetamine

O0NJNN Caffeine

ODFBYE AMPHETAMINE 4,4% AND CAFFEINE

OF0Q00 Amphetamine

OOAION Amfetamine

OOIOUO Amphetamine

P04CR4 Amphetamine

PCR99G amphetamine

PDMMHM AMPHETAMINE

PWYKZQ Amfetamine

QMG6MM Amfetamine

QPEFZE Amfetamine



Code Identified SubstancesQRPRRR amphetamine sulphate

QXZKSQ Amfetamine

R21VX8 Amfetamine ,Caffeine

RBFBBM Caffeine

RRR6HI AMPHETAMINE

RSNKH3 amphetamine

SL61P0 Amphetamine

SLJETI amphetamine

SUA1EC ampetamine

SZT4VF amphetamine

SZVCHI amfetamine

T3A33W Amphetamine

UBJZMK Amfetamine

UGGGBT amphetamine

UOBROB Anfetamina

UVIZDN Amphetamine

UY78GL ANFETAMINA, CAFEINA

UYAC2L Amfetamine

VDZ8NV cafeína

VWU2B0 amfetamine

W4B4QT amphetamine

WABFAA amfetamine

WEEH53 amfetamine

WELQMQ A

WLZJLF Anfetamina

WM8MGO AMPHETAMINE

WTCTPT amphetamine

WUAUUU amphetamine

WVBNU6 CAFEINE

WWWH4N Amphetamine sulphate

X3UUYH Amfetamine

X8WVVF amphetamine

XDOWHP amphetamine

XLL0OS amphetamine

XNSNEU Amfetamine

XPOMU1 AMPHETAMINE

XSNG6F Amphetamine

XXR4ZM Amphetamine

Y6T66I amphethamine

YXMHT9 amphetamine sulfate

YXXRY9 Amphetamine

Z0BIZI Amfetamine

Z1SAXE amfetamine

ZLFXWZ Amphetamine



Code Amfetamine Caffeine

0DA6JO + ANP

De los análisis realizados se concluye que el polvo blanco se trata de anfetamina.

0NNGO4 - -

0YFLNL + +

1 glass bottle containing 0.23 grammes of a powder containing 0.01 grammes of amphetamine.

144FAB + +

A white powder containing an average of 7% of amphetamine (calculated as sulphate salt)

192GH2 + +

The sample contains amphetamine, caffeine and creatine.

28NZ22 + +

The sample contains amfetamine (5.4%) and caffeine.

2EQC6Q + +

The sample also contained caffeine.

2UUUXU + ANP

After analysing the sample with colourimetric tests, MSD confirmation and subsequent quantification by chromatography with FID detector, we are confident that the SM-2 sample contains 6.52 % amphetamine base. caffeine is detected too.

3DVBVE + +

3LN2N9 + +

contained amfetamine and coffeine

44VN4T + +

d,l-amphetamine (salt form not determined), caffeine, and creatine confirmed in one unit tested of one unit recieved.

4CVIID + +

In the test sample 2013/2/SM-2 were detected amfetamine and caffeine

4Y4BMB + +

caffeine as adulterant

5AKBA5 + +

caffeine, creatine

5DMOWW + -

Find also caffeine 29.7%

5OHSAB + +





5V2K55 + -

66P66H + +

caffeina

6AAAIA + +

Illegal substances on the basis of the italian law DPR 309/90

7JPM7K + ANP

7NMYY7 + +

815B51 + +

LA MUESTRA DE POLVO BLANCO ES UNA MEZCLA DE ANFETAMINA Y CAFEINA

9999JM + +

Sample contains 5.85 ± 0.47 w/w amphetamin base. The sample also contain caffeine and creatinine.

9AT7DN + +

It was also detected caffeine, usually found as adulterant in amfetamine' seizures

9S9R99 + +

we found amphetamine in SM-2 as controlled drugs and we also found caffein in SM-2 as adulterant

A4DVDD + +

The sample 2013/2/SM-2 contains Amfetamine and Caffeine detected by GC-MS. The percentage by weight of Amfetamine is 5.8%.

AC6AA0 + +

Amphetamine was identified by TLC and GC/MSCaffeine was also Identified by TLC and GC/MS

ARRBBM + +

AXAVAA + +

B11A58 + +

The powder contains amphétamine with caféine and creatine

BR66FX + +

The sample contains amphetamine and caffeine. The percentage by weight of amphetamine (as base) is 6.2%

C6UZN1 + +

caffeine, creatine monohydrate

CFILQS + +

sample 2 contains amfetamine sulfate (5.5 % as base) cut with caffeine (29.0 %) and creatine




CITDQT + +

Also detected Creatinine and Caffeine. No quantitation performed.

CMQISC + +

CPCFME + +

On analysis, I found the sample to contain amphetamine.

DFLETW + +

DGEIFI + +

This powder contained an average of 5% AMPHETAMINE together with the adulterants caffeine and creatine monohydrate.

DWGQZS + +

caféine

E4AF6Q + +

Amphetamine and Caffein

E5B6AC + +


EOZOOO + +

Based on the above analysis, the sample was found to contain amphetamine and caffeine.

G7GGCR + +

caffein

GGWXWW + ANP

The powder was analysed and found to contain Amphetamine.

GULHNN + +On analysis, I found the substance to contain 5.0% of Amphetamine.

GZDUQM + +

Sample 2013/2/SM-2 consists of white powder. Amfetamine, a prohibited substance included in the National Law for Narcotics, is found to be present in this sample. The seizure also contains caffeine and lactose.

HBHUNI + +Powder containing Amfetamine with cafeine as cutting agent

HE2TG2 + +

Presence of Sulfates

HHHHU5 + +

Test Sample 2013/2/SM-2 - one vial containing off-white powder. This powder contained an average of 5% AMPHETAMINE, together with the adulterant caffeine.




HHRTHH + +

SM2 contain Amphetamine. Caffeine was detected also.

HVXZXL + +

Amfetamine and caffeine detected in SM-2.Amfetamine content is 6.31%.

HWGQ3X + +

Color Test: Marquis'--> orange then change to brown, Simon --> pink to cherry-redTLC and GCMS: Amphetamine, CaffeineGC: Amphetamine base 5.64%, Caffeine 28.06%

I5IP07 + +

AMPHETAMINE , CAFEINE

IAWA6A + +

caffeine

IBOQKX + +

This sample is amphetamine.

II8JO4 + +

Powder was found to contain amphetamine at a concentration of less than 5%. Amphetamine is controlled by the Misuse of Drugs Act 1971 (as amended) as a Class B drug.

IP12QF + +

The sample is a preparation that contains amphetamine.

JDDD6D + +

The test sample 2013/2/SM-2 was analysed by colour test and Thin layer Chromatography techniques and found to contain Amfetamine and Caffeine.

JJRRVN + ANP

The sample was found to contain amfetamine

JKBKRK + ANP

0.238grams of a powder containing 5% Amfetamine. Amfetamine is a Class B controlled drug under the provisions of the Misuse of Drugs Act 1971.

JPIPOT + +

The sample SM2 contained 5.1 % calculated as a base. In the sample was identified caffeine and creatine.

JRLS5J + +

The sample contains amfetamine which is scheduled as illicit drug in France. Caffeine and creatine are cutting agent.

JSHHOS + +

The powder was analysed and found to contain amphetamine.

JSZMHJ + +

Base Anfetamina 6,97% ,Caffeine and Creatine hydrate

JYDFMU + +

caffeine, creatine




KKQS2K + +

caffein

LLCQXL + +

On analysis, I found the substance to contain Amphetamine and caffeine. Quantitative analysis was not carried out to determine the weight of the amphetamine drug.

LQEYRY + +

N0TYZE - +

NBNVJG + +

CAFEINA

NNVNSC + +

amfetamine with caffeine and creatine

NRVAVR + +

The sample 2013/2/SM-2 was found to contain Amfetamine and caffeine.

NVUXXR + +

Narcotics: Amphetamine (II) (the number refers to legislation)Concentration: 8 % amphetamine sulphateAmount: 0,2 gram

NZMVTG + +

The sample was found to contain amphetamine.

O0NJNN - +

Test sample 2013/2/SM2 was found to contain caffeine which is a stimulant.

ODFBYE + +

OF0Q00 + +The sample contain amphetamine. The sample contain also caffeine

OOAION + +

-

OOIOUO + -

Examination revealed the presence of Amphetamine

OQ2JQM + -

P04CR4 + +

-The sample obtains with the positive result with Marquis reagent.- TLC: The Rf sample obtain with the same Rf Amphetamine Standard.- GC: The Rt sample obtain with the same Rt Amphetamine Standard.




PCR99G + +

the sample also contains caffeine

PDMMHM + +

CAFFEINE AND CREATINE WERE IDENTIFIED

PWYKZQ + +

Caffeine

QMG6MM + +

QPEFZE + +

QRPRRR + +

the presence of drug confirmed by GC-MS and FTIR analysis, the sulphate form of amphetamine confirmed by the anion analysis

QXZKSQ + +

The sample contains amfetamine which is listed as a controlled drug according to french order, appendix III of February 22nd 1990.

R21VX8 + +

GC MS NPD

RBFBBM - +

RRR6HI + +

AMPHETAMINE SULFATE (6.1% as base) - CAFFEINE - CREATINE

RSNKH3 + +

white powder containing amphetamine (6.1%ww) controlled by national law. In addition also caffeine was detected.

SL61P0 + +

Caffein, Ritalin (Methylphenidate)

SLJETI + +

SUA1EC + +caffein, creatin-monohidrát

SZT4VF + +

sample contains amphetamine hydrochloride (2,28% of amphetamine base)

SZVCHI + ANP

positive to marquis reagent: orangepositive to scott reagent

retention time as our pattern of amfetamine




T3A33W + +

caffeine

UBJZMK + +

White powder containing Amfetamine at 7.07% and also caffeine.

UGGGBT + +

the sampke was confirmed by GC ms and also contains caffeine

UOBROB + +

UVIZDN + +

In this sample contain Tow substance Amphetamine and Caffeine

UY78GL + +

LA MUESTRA DOS ADEMAS DE ANFETAMINA CONTIENE CAFEINA

UYAC2L + +

Amfetamine and Caffeine

VDZ8NV ANP +

Marquis, ácido amalico, solubilidad, UV, FT-IR y HPLC-DAD

VWU2B0 + ANP

W4B4QT + +amphetamine + cafeine

WABFAA + +

amfetamine, caffeine

WEEH53 + +

white powder containing 6.3%ww of amphetamine

WELQMQ + ANP

WLPRZL - +

the result of TLC of test sample and reference substance was same as caffeine. the peak of IR of test sample was shown same as caffeine.

WLZJLF + +

La muestra contiene Cafeina y Anfetamina

WM8MGO + +

The results of the tests of the SM2 (94) received confirmed that the mentioned sample contains amphetamine but we are not able to give a cuantification result because we can not do it with our gas chromatography-gas spectometer and we have not got a gas chromatography FID which is the suitable analytical technique.The sample 2 also contains caffein as not controlled drug.




WTCTPT + +

Amphetamine is controlled by law (KB 22/01/1998)

WUAUUU + +

white powder, mixture of the amphetamine, caffeine and creatine

WVBNU6 - +

WWWH4N + +

SM2 contains also Coffeine and Creatinine

X3UUYH + +

X8WVVF + +

whitepowder containing 4.9%ww amphetamine. Caffeine is present.

XDOWHP + +

the powder is a mixture of caffeine and amphetamine. The concentration of the amphetamine in the sample is 5.4% by weight

XLL0OS + +

coffeine

XNSNEU + +

Presence of amfetamine sulphate, caffeine and lactose was detected in the sample.

XPOMU1 + +

ALSO CAFFEINE

XSNG6F + +

Sample 2013/2/SM-2 was found to contain Amphetamine a Schedule II drug under the United Nation Convention on Psycotropic Substances. The sample was also found to contain Caffeine.

XXR4ZM + +Sample 2013/2/SM-2,a creamy white powder, was found to contain amphetamine, a controlled substance under National Law.

Y6T66I + -

The sample also contains caffeine and creatinine

YXMHT9 + +caffeine, creatine

YXXRY9 + +

White powder containing Amphetamine and Caffeine

Z0BIZI + +

Diluted with Caffeine

Z1SAXE + +

found amfetamine 6.1%ww and caffeine




ZLFXWZ + +

On analysis, I found the substance to contain Amphetamine




Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


0NNGO4 S I I

0YFLNL S S SI I

144FAB S S I I

192GH2 S S I I

28NZ22 S S S I I

2EQC6Q SI I

2UUUXU S I

3DVBVE S I I

3LN2N9 SI

44VN4T I SI I I

4CVIID I I I

4Y4BMB S I I

5AKBA5 SI

5DMOWW

I SI I

5OHSAB S S S I I

5V2K55 I SI

66P66H SI SI

6AAAIA I I

7JPM7K I

7NMYY7 SI S I


9999JM I S I SI SI

9AT7DN I SI I I

9S9R99 S I I

A4DVDD SI I

AC6AA0 S S S I I

ARRBBM SI I

AXAVAA S S S SI

B11A58 I SI I

BR66FX SI I I

C6UZN1 S SI I I

CFILQS S S I I





Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


CMQISC S I I

CPCFME I SI

DFLETW I SI

DGEIFI S S I I

DWGQZS SI I

E4AF6Q S I

E5B6AC SI S S I I

EOZOOO S I I

G7GGCR S S S I I I

GGWXWW

S I

GULHNN S I I

GZDUQM S S I I I I

HBHUNI SI I I

HE2TG2 S S SI I

HHHHU5 S S I I

HHRTHH S S S I


HWGQ3X S S I I I

I5IP07 S S I I

IAWA6A I SI I

IBOQKX S I I

II8JO4 S S I I

IP12QF I S I

JDDD6D S S I I A

JJRRVN S I I

JKBKRK S S I I

JPIPOT I I

JRLS5J S S I I

JSHHOS S S I I

JSZMHJ S I I I XRD

JYDFMU SI SI

KKQS2K S I S

LLCQXL S I

LQEYRY SI I

N0TYZE SI

NBNVJG S I I

NNVNSC I I

NRVAVR S S S I I



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

NVUXXR SI I

NZMVTG SI I LC/ELSD

O0NJNN SI


OF0Q00 SI ASAP-TOF

OOAION SI

OOIOUO S SI

OQ2JQM S S S I I

P04CR4 S S S I I

PCR99G S S I I

PDMMHM I SI I

PWYKZQ I SI

QMG6MM I SI SI


QRPRRR S S I I I

QXZKSQ I I

R21VX8 I SI

RBFBBM S I I

RRR6HI S S S I I I

RSNKH3 I SI

SL61P0 I SI

SLJETI SI

SUA1EC S SI I I

SZT4VF S SI I I I I

SZVCHI S I

T3A33W S S I I SI

UBJZMK S S I I

UGGGBT S I I

UOBROB S I I

UVIZDN S S S I I

UY78GL S I I

UYAC2L SI I


VWU2B0 SI S S I I

W4B4QT S S I I

WABFAA SI SI I I I

WEEH53 I SI

WELQMQ SI I

WLPRZL I I SI



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

WLZJLF S SI S I I

WM8MGO

SI SI SI I

WTCTPT I S

WUAUUU SI I

WVBNU6 SI SI I I

WWWH4N

I S I I

X3UUYH S S S I I

X8WVVF I SI


XLL0OS SI SI I I I


XPOMU1 I I SI FPIA

XSNG6F S I

XXR4ZM S S I I

Y6T66I S I I I

YXMHT9 I I S ATR

YXXRY9 S I SI SI I

Z0BIZI S I I

Z1SAXE SI

ZLFXWZ S I I









Code Name Technique

DWGQZS Ethylamphetamine 180/190

5OHSAB Benzenethanamine 180/190

5OHSAB N-Methyl; N-acetylamphetamine 180/190

SL61P0 Methylphenidate 180



Amfetamine: 124

Caffeine: 116

5OHSAB Metamfetamine 180/190

5V2K55 Ketamine 180

Response Summary Participan


Code: 0NNGO4(180) N0TYZE (180), O0NJNN (180), RBFBBM (180/231 WLPRZL (150/190), WVBNUS (180), VDZ8NV( ANP)

Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 43 54 39 16 0 2 0 2 41 8 1 0 0 0 6

32.8% 41.2% 29.8% 12.2% 0.0% 1.5% 0.0% 1.5% 31.3% 6.1% 0.8% 0.0% 0.0% 0.0% 4.6%

Identification 12 6 3 30 6 15 3 20 118 70 2 3 2 3 9

9.2% 4.6% 2.3% 22.9% 4.6% 11.5% 2.3% 15.3% 90.1% 53.4% 1.5% 2.3% 1.5% 2.3% 6.9%


48 54 40 39 6 16 3 21 118 73 3 3 2 3 11

36.6% 41.2% 30.5% 29.8% 4.6% 12.2% 2.3% 16.0% 90.1% 55.7% 2.3% 2.3% 1.5% 2.3% 8.4%



CODEAmfetamineMAD: 0.5


0YFLNL 5.5 0.1 0.1

144FAB 5.0 0.5 0.7

192GH2 46.0 40.5 58.2

28NZ22 5.4 0.1 0.1

2EQC6Q 5.5 0.0 0.0

2UUUXU 6.5 1.1 1.5

3DVBVE 5.5 0.1 0.1

3LN2N9 5.2 0.3 0.4

44VN4T 5.6 0.1 0.2

4CVIID 6.2 0.7 1.0

4Y4BMB 5.6 0.1 0.2

5AKBA5 5.5 0.0 0.0

5DMOWW 2.6 2.9 4.1

5V2K55 5.1 0.4 0.5

66P66H 5.0 0.5 0.7

6AAAIA 2.8 2.7 3.8

7NMYY7 5.1 0.4 0.5

9999JM 5.9 0.4 0.5

9AT7DN 5.0 0.4 0.6

A4DVDD 5.9 0.4 0.6

AC6AA0 3.2 2.3 3.3

AXAVAA 6.0 0.5 0.8

BR66FX 6.2 0.7 1.0

CFILQS 5.5 0.0 0.0

CPCFME 5.6 0.1 0.2

DFLETW 5.0 0.5 0.7

DGEIFI 5.0 0.5 0.7

E4AF6Q 5.7 0.2 0.3

G7GGCR 4.2 1.3 1.9

GULHNN 5.0 0.5 0.7

HHHHU5 5.0 0.5 0.7

HHRTHH 21.6 16.1 23.2

HVXZXL 6.3 0.8 1.2

HWGQ3X 5.6 0.2 0.2

IBOQKX 5.6 0.1 0.2

II8JO4 4.0 1.5 2.1

IP12QF 5.4 0.1 0.1

JKBKRK 5.0 0.5 0.7

JPIPOT 5.1 0.4 0.5

JRLS5J 5.0 0.5 0.7

JSZMHJ 7.0 1.5 2.2



CODEAmfetamineMAD: 0.5


JYDFMU 5.4 0.1 0.1

LQEYRY 5.1 0.4 0.5

NNVNSC 5.4 0.1 0.1

NVUXXR 5.6 0.1 0.2

ODFBYE 4.4 1.1 1.5

OOAION 6.1 0.6 0.9

P04CR4 10.7 5.2 7.5

PDMMHM 5.5 0.0 0.0

PWYKZQ 5.8 0.4 0.5

QPEFZE 4.8 0.7 1.0

QRPRRR 5.6 0.2 0.2

QXZKSQ 5.4 0.1 0.1

RRR6HI 6.2 0.7 1.0

RSNKH3 6.1 0.6 0.9

SL61P0 5.3 0.2 0.2

SZT4VF 2.3 3.2 4.6

SZVCHI 4.3 1.2 1.8

UBJZMK 7.1 1.6 2.3

WABFAA 5.0 0.5 0.7

WEEH53 6.3 0.8 1.2

WELQMQ 6.7 1.2 1.8

WTCTPT 5.7 0.2 0.3

WUAUUU 5.0 0.5 0.7

WWWH4N 3.9 1.6 2.3

X3UUYH 4.7 0.8 1.1

X8WVVF 4.9 0.6 0.8

XDOWHP 5.4 0.1 0.1

XLL0OS 6.0 0.5 0.8

XNSNEU 5.5 0.0 0.0

XSNG6F 5.7 0.2 0.3

XXR4ZM 7.9 2.4 3.5

Y6T66I 5.3 0.2 0.2

YXMHT9 6.0 0.5 0.8

Z1SAXE 6.1 0.6 0.9

Substance: SM-2/Amfetamine 0.5MAD =Median =UNODC value = 4.9

5.5

Round: 2013/2



(45)


Code Identified Substances0DA6JO MDMA

0NNGO4 1-(3-Chlorophenyl)piperazine

0YFLNL 1-(3-Chlorophenyl)piperazine

144FAB 1-(3-chlorophenyl)piperazine

192GH2 Morfine

28NZ22 1-(3-Chlorophenyl)piperazine

2EQC6Q 1-(3-Chlorophenyl)piperazine

2UUUXU 1-(3-chlorophenyl)piperazine

3DVBVE 1-(3-Chlorophenyl)piperazine

3LN2N9 1-(3-Chlorophenyl)piperazine

44VN4T 1-(3-chlorophenyl)piperazine mono-hydrochloride, morphine, and codeine

4CVIID 1-(3-chlorophenyl)piperazine

4Y4BMB 1-(4-Chlorophenyl)piperazine

5OHSAB 1-(3-CLOROFENIL) PIPERAZINA

5V2K55 1-(3-Clorphenyl)piperazine (mCPP)

66P66H 1-(3-Clorophenyl)piperazine

6AAAIA 1-(3-Chlorophenyl)piperazine

7NMYY7 1-(3-Chlorophenyl)piperazine

815B51 1-(3-CLOROFENIL)PIPERAZINA - MORFINA - CODEINA

9999JM 1-(3-Chlorophenyl)piperazine

9AT7DN 1-(3-chlorophenyl)piperazine

9S9R99 1-(3-chlorophenyl)piperazine

A4DVDD 1-(3-Chlorophenyl)piperazine

AC6AA0 1-(3-Chlorophenyl)piperazine

ARRBBM Piperazine, 1-(3-chlorophenyl-)

AXAVAA 1 3 chlorophenyl piperazine

BR66FX 1-(3-Chlorophenyl)piperazine

C6UZN1 mCPP 1-(3-Chlorophenyl)piperazine

CFILQS 1-(3 chlorophényl)pipérazine hydrochloride, morphine

CITDQT 1-(3-chlorophenyl) piperazine, Codeine and Morphine.

CMQISC 1-(3-Chlorophenyl)piperazine

CPCFME 1-(3-Chlorophenyl)piperazine

DFLETW 1-(3-Chlorophenyl)piperazine

DGEIFI Morphine and 1-(3-chlorophenyl)piperazine

DWGQZS m CCP

E4AF6Q 1-(3-Chlorophenyl)piperazine

E5B6AC HEROINE, m- CPP - HCl, PARACETAMOL, KETAMINE

EOZOOO Codeine and morphine

G7GGCR 1-(3-Chlorophenyl)piperazine

GGWXWW MCPP (1-(3-chlorophenyl)piperazine, Codeine and Morphine.

Sample 3 Analysis



Code Identified SubstancesGZDUQM Morphine

HBHUNI mCPP

HE2TG2 m-CPP, morphine

HHHHU5 CHLOROPHENYLPIPERAZINE, MORPHINE, CODEINE

HHRTHH m-CPP

HVXZXL 1-(3-Chlorophenyl)piperazine/Morphine

HWGQ3X 1-(3-Chlorophenyl) piperazine, Morphine,Codeine

I5IP07 mCPP ( 1,3 chlorophenylpiperazine)

IAWA6A m-CPP

IBOQKX mCPP, morphine

II8JO4 1-(3-chlorophenyl)piperazine

IP12QF m-chlorophenylpiperazine

JDDD6D Piperazine

JJRRVN 1-(3-chlorophenyl)piperazine

JKBKRK 1-(3-chlorophenyl)piperazine

JPIPOT m-CPP

JRLS5J morphine, 1-(3-Chlorophenyl)piperazine

JSHHOS Chlorophenylpiperazine

JSZMHJ 1-(3-chlorophenyl)piperazine

JYDFMU meta-chlorophenylpiperazine

KKQS2K 1-(3-chlorophenyl)piperazine

LLCQXL 1-(3-Chlorophenyl)piperazine

LQEYRY 1-(3-Chlorophenyl)piperazine, morphine

N0TYZE Clorophenylpiperazine

NBNVJG 1,3-CLOROFENILPIPERAZINA

NNVNSC 1-(3-Chlorophenyl)piperazine

NRVAVR 1-(3-Chlorophenyl)piperazine.

NVUXXR mCPP

NZMVTG mCPP and Morphine

O0NJNN 1-(3-Chlorophenyl) piperazine

ODFBYE 1-(3-CHLOROPHENYL)PIPERAZINE

OF0Q00 m-CPP

OOAION 1-(3-Chlorophenyl)piperazine, Morphine

OOIOUO 1-(3-Chlorophenyl)piperazine and Codeine

PCR99G morphine and codeine

PDMMHM 1-(3-CHLOROPHENYL)PIPERAZINE

PWYKZQ Morphine and Codeine

QMG6MM Morphin; codein; (mCPP)

QPEFZE 1-(3-chlorophenyl)piperazine, morphine

QRPRRR 1-(3-Chlorophenyl)piperazine hydrochloride

R21VX8 1-(3-Chlorophenyl)piperazine

RBFBBM 1-(3-Chlorophenyl)piperazine

RRR6HI 1,3 CHLOROPHENYLPIPERAZINE

RSNKH3 1-(3-chlorophenyl)piperazine and morphine



Code Identified SubstancesSL61P0 mCPP

SLJETI piprazine

SUA1EC mCPP(1-(3-clorophenil)-piperazin)

SZT4VF 1-(3-chlorphenyl)piperazine

SZVCHI not identified

T3A33W mCPP

UBJZMK 1-(3-Chlorophenyl)piperazine

UGGGBT MCPP 1-3 cholorphenyl piperazine

UOBROB 1-(3 Clorofenil) Piperazina

UVIZDN Morphine

UY78GL 1-(3- CLOROFENIL)PIPERAZINA

UYAC2L CPP

VDZ8NV morfina

VWU2B0 morphine

W4B4QT 1-(3-clorophenyl)piperazine

WABFAA 1,3-chlorophenylpiperazine

WELQMQ morphine, mCPP

WLPRZL 1-(3-chlorphenyl) piperazine

WLZJLF Piperazina

WM8MGO 1-(4-clorophenyl)piperazine

WTCTPT 1-(3-chlorophenyl)piperazine

WUAUUU mCPP

WVBNU6 1-3 CLOROFENILPIPERAZINE

WWWH4N 1-(3-chlorophenyl)piperazine

X3UUYH 1-(3-Chlorophenyl)piperazine

X8WVVF 1-(3-clorophenyl)piperazine (m-cpp))

XLL0OS 1-(3-chlorophenyl) piperazine

XNSNEU 1-(3-chlorophenyl)piperazine

XPOMU1 MORPHINE, 1-(3-CHLOROPHENYL) PIPERAZINE

XSNG6F 1-(3-Chlorophenyl)piperazine

XXR4ZM 1-(3-Chlorophenyl)piperazine

Y6T66I 1-(3-chlorphenyl)piperazine

YXMHT9 mCPP HCl (1-(3-chlorophenyl)piperazine HCl)

YXXRY9 mCPP, 1-(3-chlorophenyl)piperazine

Z0BIZI 1-(3-Chlorophenyl)piperazine

Z1SAXE 1-(3-chlorophenyl)piperazine and morphine



Code 1-(3-Chlorophenyl)piperazine

0DA6JO ANP

De los análisis realizados se concluye que el polvo blanco se trata de 3,4 metilendioximetanfetamina

0NNGO4 +

0YFLNL +

1 glass bottle containing 0.20 grammes of a powder containing 0.16 grammes of chlorophenylpiperazine, being a compound structurally dervied from 1-phenylpiperazine by substitution in the aromatic ring with haloalkyl substituent.

144FAB +

A white powder containing 1-(3-chlorophenyl) piperazine

192GH2 +

The sample contains mCPP, codeine and morphine.

28NZ22 +

The sample contains 1-(3-Chlorophenyl)piperazine (not quantified).

2EQC6Q +

2UUUXU +

After analysing the sample with colourimetric tests, MSD confirmation we are confident that the SM-3 samples is mCPP 1-(3-chlorophenyl)piperazine base. no quantification

3DVBVE +

3LN2N9 +

1-(3-Chlorophenyl)piperazine

44VN4T +

1-(3-chlorophenyl)piperazine mono-hydrochloride, morphine (salt form not determined), and codeine (salt form not determined) confirmed in one unit tested of one unit recieved.

4CVIID +

In the test sample 2013/2/SM-3 was detected 1-(3-chlorophenyl)piperazine

4Y4BMB +

We found 1-(4-Chlorophenyl)piperazine instead 1-(3-Chlorophenyl)piperazine

5AKBA5 +

mCPP

5DMOWW +mCPP chlorophenylpiperazine is not quantified routinely in our laboratory. It's not a controlled drug in France.





5OHSAB +

Was found too CODEINE

5V2K55 +

66P66H +

non è stato possibile quantificare perché non abbiamo standard

6AAAIA +

7JPM7K ANP

7NMYY7 +

815B51 +

LA MUESTRA DE POLVO BLANCO ES UNA MEZCLA DE 1-(3-CLOROFENIL)PIPERAZINA, MORFINA Y CODEINA; TODAS CONSIDERADAS COMO DROGAS ILEGALES EN MEXICO

9999JM +

Sample contains 82.0 ± 3.7 w/w 1-(3-Chlorophenyl)piperazine base in HCL salt form.Trace amount of morphine and codeine were also detected by GC/MS.

9AT7DN +

Quantitative results were no reported due to the lack of the appropiate analytical standard.

9S9R99 +

We found 1-(3-chlorophenyl)piperazine as uncontrolled drugs

A4DVDD +

The sample 2013/2/SM-3 contains 1-(3-Chlorophenyl)piperazine detected by GC-MS. The percentage by weight of 1-(3-Chlorophenyl)piperazine is 31.1%.

AC6AA0 +

1-(3-Chlorophenyl)piperazine was identified by TLC and GC/MS

ARRBBM +

AXAVAA +

which is not narcotic in Albania

B11A58 +

The powder contains M-CPP ( 1-(3-chlorophenyl)piperazine )M-CPP is not a drug in France

BR66FX +

The sample contains 1-(3-Chlorophenyl)piperazine. The percentage by weight of1-(3-Chlorophenyl)piperazine (as base) is 84.4%.




C6UZN1 +

morphine

CFILQS +

sample 3 contains 1-(3 chlorophényl)pipérazine hydrochloride (81.5 % as base), morphine and codéine (not quantified)

CITDQT +

No quantitation performed.

CMQISC +

morphine, codeine

CPCFME +

On analysis, I found the sample to contain 1-(3-chlorophenyl)piperazine(also known as mCPP).

DFLETW +

DGEIFI +This powder contained 1-(3-CHLOROPHENYL)PIPERAZINE (CPP).

(I would not include in my statement the presence of morphine in the powder as it is at such low levels and I am satisfied in my opinion it is below 0.2% and would therefore not be controlled under the Misuse of Drugs Act 1971).

DWGQZS +

E4AF6Q +1-(3-Chlorophenyl)piperazine

E5B6AC +


EOZOOO +

Based on the above analysis, the sample was found to contain codeine, morphine and 1-(3-chlorophenyl)piperazine.

G7GGCR +

GGWXWW +

The powder was analysed and found to contain MCPP (1-(3-chlorophenyl)piperazine, Codeine and Morphine.

GULHNN +

On analysis, I found the substance to contain 1-(3-Chlorophenyl)piperazine

GZDUQM ANP

Sample 2013/2/SM-3 consists of white powder. Morphine, a prohibited substance included in the National Law for Narcotics, is found to be present in this sample. The seizure also contains codeine and paracetamol.




HBHUNI +

Powder containig mCPP

HE2TG2 +

Presence of Chlorides

HHHHU5 +

Test Sample 2013/2/SM-3 - one vial containing off-white powder. This powder contained CHLOROPHENYLPIPERAZINE, together with MORPHINE and CODEINE.

Note: The morphine and codeine in this powder were present in relatively small amounts when compared to the chlorophenylpiperazine. The amount of morphine and codeine contained in this powder have not been accurately determine as part of this submission.

HHRTHH +

SM3 contain m-CPP.HCl

HVXZXL +

1-(3-Chlorophenyl)piperazine and morphine detected in SM-3.Morphine content is 1.74%.

HWGQ3X +

Color Test: Marquis, Mecke, Froehde --> negative; Simon --> Blue then slowly change to yellowTLC: 1-(3-Chlorophenyl) piperazineGCMS: 1-(3-Chlorophenyl) piperazine, Morphine,CodeineGC: 1-(3-Chlorophenyl) piperazine base 83.17%, Morphine base 1.54%, Codeine (trace)

I5IP07 +

IAWA6A +

codein and morphine (contamination)

IBOQKX +This sample is mCPP wtih traces of morphine.

II8JO4 +

Powder was found to contain chlorophenylpiperazine. Chlorophenylpiperazine is controlled by the Misuse of Drugs Act 1971 (as amended) as a Class C drug.

IP12QF +The sample is a preparation that contains the new phsycoactive drug m-chlorophenylpiperazine

JDDD6D +

The test sample 2013/2/SM-3 was analysed by colour test and Thin layer Chromatography techniques and found to contain Piperazine.

JJRRVN +

the sample was found to contain 1-(3-chlorophenyl)piperazine

JKBKRK +

0.206grams of a powder containing Chlorophenylpiperazine. Chlorophenylpiperazine is a Class C drug under the provisions of the Misuse of Drugs Act 1971.




JPIPOT +

The sample SM3 contained 80.1 % calculated as a base.

JRLS5J +

The sample contains morphine and codeine which are scheduled as illicit drugs in France. 1-(3-Chlorophenyl)piperazine is not scheduled as illicit drug in France.

JSHHOS +

The powder was analysed and found to contain amphetamine.

JSZMHJ +

1-(3-chlorophenyl)piperazine hidrochloride

JYDFMU +

KKQS2K +

LLCQXL +On analysis, I found the substance to contain 1-(3-Chlorophenyl) piperazine.

LQEYRY +

We also found traces (very small amount) of codein

N0TYZE +

NBNVJG +

NNVNSC +


NRVAVR +

The sample 2013/2/SM-3 was found 1-(3-Chlorophenyl)Piperazine.

NVUXXR +

Identified substance: mCPPAmount: 0,2 gramThe substance identified is whit it´s chemical structure a piperazine

NZMVTG +

The sample was found to contain 1-(3-chlorophenyl)piperazine and morphine (trace amounts).

O0NJNN +

Test sample 2013/2/SM3 was found to contain 1-(3-Chlorophenyl) piperazine which is a controlled drug.

ODFBYE +




OF0Q00 +

The sample contain a piperazine derived designer drug 1-(3-chlorophenyl)-piperazine.

OOAION +

-

OOIOUO +

Examination revealed the presence of piperazine and Codeine

OQ2JQM +

P04CR4 ANP

PCR99G +

the sample also contains 1-3(chlorophenyl) piperazine

PDMMHM +

TRACES OF TFMPP, MORPHINE AND CODEINE WERE IDENTIFIED

PWYKZQ +

1-(3-Cholorophenyl)piperazine

QMG6MM +

mCPP : is not considerated as a drug in France .

QPEFZE +

QRPRRR +

the presence of drug confirmed by GC-MS and FTIR analysis, the hydrochloride form confirmed by the anion analysis

QXZKSQ +

The analysis did not reveal any controlled drug according to french order, decree of February 22nd 1990.

R21VX8 +

GC MS (NO STANDARD BASED ON LIBRARY)

RBFBBM +

RRR6HI +

1,3 CHLOROPHENYLPIPERAZINE CHLORYDRATE (84,8% as base)

RSNKH3 +

White powder containing morphine (2.1%ww) and mCPP, which are controlled drugs. The amount of mCPP was not determined because the lack of reference material. In addition was detected codeine.




SL61P0 +

SLJETI +

SUA1EC +

morphin, codeine (contamination)

SZT4VF +

sample contains 1-(3-chlorphenyl)piperazine

SZVCHI ANPpositive to marquis reagent: violet. retention time unknown

T3A33W +

The sample contain trace morphine and codeine

UBJZMK +White powder containing 1-(3-Chlorophenyl)piperazine at 59.63%

UGGGBT +

the sample was confirmed by GC MS and laso contains trace of caffeine

UOBROB +

UVIZDN +

In this sample contain tow substance Morphine and MCPP(piprazin)

UY78GL +

EL ANALISIS POR CROMATOGRAFIA GC/MZ DIO COMO RESULTADO QUE LA MUESTRA CONTIENE 1-(3- CLOROFENIL)PIPERAZINA

UYAC2L +


VDZ8NV ANP

Se le realizó pruebas de marquis, scott, HPLC-dad, FT-IR, UV

VWU2B0 ANP

W4B4QT +

1-(3-clorophenyl)piperazine

WABFAA +

1,3-chlorophenylpiperazine

WEEH53 +

white powder containing 1-(3-chlorophenyl)piperazine (mcpp) potential hazard substance




WELQMQ +

WLPRZL +

the peak of IR of test sample was same as 1-(3-chlorphenyl) piperazine

WLZJLF +

WM8MGO -

The results of the tests of the SM3 (81) received confirmed that the mentioned sample contains 1(4 chlorophenyl)piperazine but this is a not controlled substance yet

WTCTPT +

1-(3-chlorophenyl)piperazine is controlled by law (KB 22/01/1998 changed by KB 22/10/2006)

WUAUUU +

white powder, no other compound

WVBNU6 +

WWWH4N +

SM3 contanis also trace amount of Morphine and Codeine

X3UUYH +

X8WVVF +

white powder containing m-cpp (not quantified)

XDOWHP +

the powder contains 1-(3-chlorophenyl)piperazine also known as mCPP. It also contains a very little amount of codeine (traces)

XLL0OS +

XNSNEU +

Presence of 1-(3-chlorophenyl)piperazine hydrochloride was detected in the sample.

XPOMU1 +

ALSO CODEINE

XSNG6F +

Sample 2013/2/SM-3 was found to contain 1-(3-Chlorophenyl)piperazine not scheduled under the Single Convention on Narcotic Drugs or the United Nation Convention on Psycotropic Substances.

XXR4ZM +

Sample 2013/2/SM-3,a white,flaky, odorless powder, was found to contain CPP [1-(3-Chlorophenyl)piperazine], a controlled substance under National Law.




Y6T66I +

YXMHT9 +

mCPP HCl - not under control in Polish law

YXXRY9 +

Off-white powder containing mCPP and traces of Morphine and Codeine

Z0BIZI +

Z1SAXE +found 1-(3-chlorophenyl)piperazine (mcpp) 96.2%ww , morphine 2.2%ww , and codeine.

ZLFXWZ +

On analysis, I found the substance to contain 1-(3-chrorophenyl)piperazine.




Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


0NNGO4 S I I

0YFLNL S S SI I

144FAB S S I I

192GH2 S S I I

28NZ22 S S S I I

2EQC6Q SI I

2UUUXU S I

3DVBVE S I I

3LN2N9 SI

44VN4T I SI I I

4CVIID I I I

4Y4BMB S I I

5AKBA5 SI

5DMOWW

I SI I

5OHSAB S S S I I

5V2K55 I SI

66P66H SI SI

6AAAIA I I

7JPM7K I

7NMYY7 SI S I


9999JM I S I SI SI

9AT7DN I SI I I

9S9R99 S I I

A4DVDD SI I

AC6AA0 S S S I I

ARRBBM SI I

AXAVAA S S S SI

B11A58 I SI I

BR66FX SI I I

C6UZN1 S SI I I

CFILQS S S I I





Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


CMQISC S I I

CPCFME I SI

DFLETW I SI

DGEIFI S S I I

DWGQZS SI I

E4AF6Q S I

E5B6AC SI S S I I

EOZOOO S I I

G7GGCR S S S I I I

GGWXWW

S I

GULHNN S I I

GZDUQM S S I I I I

HBHUNI SI I I

HE2TG2 S S SI I

HHHHU5 S S I I

HHRTHH S S S I


HWGQ3X S S I I I

I5IP07 S S I I

IAWA6A I SI I

IBOQKX S I I

II8JO4 S S I I

IP12QF I S I

JDDD6D S S I I A

JJRRVN S I I

JKBKRK S S I I

JPIPOT I I

JRLS5J S S I I

JSHHOS S S I I

JSZMHJ S I I I XRD

JYDFMU SI SI

KKQS2K S I S

LLCQXL S I

LQEYRY SI I

N0TYZE SI

NBNVJG S I I

NNVNSC I I

NRVAVR S S S I I



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

NVUXXR SI I

NZMVTG SI I LC/ELSD

O0NJNN SI


OF0Q00 SI ASAP-TOF

OOAION SI

OOIOUO S SI

OQ2JQM S S S I I

P04CR4 S S S I I

PCR99G S S I I

PDMMHM I SI I

PWYKZQ I SI

QMG6MM I SI SI


QRPRRR S S I I I

QXZKSQ I I

R21VX8 I SI

RBFBBM S I I

RRR6HI S S S I I I

RSNKH3 I SI

SL61P0 I SI

SLJETI SI

SUA1EC S SI I I

SZT4VF S SI I I I I

SZVCHI S I

T3A33W S S I I SI

UBJZMK S S I I

UGGGBT S I I

UOBROB S I I

UVIZDN S S S I I

UY78GL S I I

UYAC2L SI I


VWU2B0 SI S S I I

W4B4QT S S I I

WABFAA SI SI I I I

WEEH53 I SI

WELQMQ SI I

WLPRZL I I SI



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

WLZJLF S SI S I I

WM8MGO

SI SI SI I

WTCTPT I S

WUAUUU SI I

WVBNU6 SI SI I I

WWWH4N

I S I I

X3UUYH S S S I I

X8WVVF I SI


XLL0OS SI SI I I I


XPOMU1 I I SI FPIA

XSNG6F S I

XXR4ZM S S I I

Y6T66I S I I I

YXMHT9 I I S ATR

YXXRY9 S I SI SI I

Z0BIZI S I I

Z1SAXE SI

ZLFXWZ S I I









Code Name Technique

JSHHOS Amphetamine 180/190

PDMMHM TFMPP 180/161

GZDUQM Paracetamol 170


Response Summary Participants: 131 140 141 142 150 160 161 170 171 211 230


1-(3-Chlorophenyl)piperazine: 123

0DA6JO MDMA 190/210 E5B6AC Ketamine, Heroin, Paracetamol 150/171


Code: WM8MGO (180/141) 0DA6J0 (ANP), 7JPM7K (ANP), GZZDUQM (ANP) P04CR4 (ANP), SZVCHI (ANP), VDZ8NV (ANP), VWU2BO (ANP)

Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 43 54 39 16 0 2 0 2 41 8 1 0 0 0 6

32.8% 41.2% 29.8% 12.2% 0.0% 1.5% 0.0% 1.5% 31.3% 6.1% 0.8% 0.0% 0.0% 0.0% 4.6%

Identification 12 6 3 30 6 15 3 20 118 70 2 3 2 3 9

9.2% 4.6% 2.3% 22.9% 4.6% 11.5% 2.3% 15.3% 90.1% 53.4% 1.5% 2.3% 1.5% 2.3% 6.9%


48 54 40 39 6 16 3 21 118 73 3 3 2 3 11

36.6% 41.2% 30.5% 29.8% 4.6% 12.2% 2.3% 16.0% 90.1% 55.7% 2.3% 2.3% 1.5% 2.3% 8.4%



CODE

1-(3-Chlorophenyl)piperazineMAD: 2.3


0YFLNL 80.5 2.0 0.6

2EQC6Q 80.5 2.0 0.6

3DVBVE 80.8 1.7 0.5

3LN2N9 84.2 1.7 0.5

44VN4T 79.6 2.9 0.9

4CVIID 82.0 0.5 0.1

5V2K55 83.3 0.8 0.2

9999JM 82.0 0.5 0.1

A4DVDD 31.1 51.4 15.1

AC6AA0 82.7 0.2 0.1

BR66FX 84.4 1.9 0.6

CFILQS 81.5 1.0 0.3

DFLETW 82.5 0.0 0.0

HHRTHH 85.6 3.1 0.9

HWGQ3X 83.2 0.7 0.2

IBOQKX 85.4 2.9 0.9

JPIPOT 80.1 2.4 0.7

JYDFMU 100.0 17.5 5.1

LQEYRY 98.3 15.8 4.6

NNVNSC 80.4 2.1 0.6

OOAION 74.4 8.2 2.4

QPEFZE 53.0 29.5 8.7

QRPRRR 83.5 1.0 0.3

RBFBBM 83.0 0.5 0.1

RRR6HI 84.8 2.3 0.7

UBJZMK 59.6 22.9 6.7

WABFAA 95.0 12.5 3.7

WELQMQ 90.3 7.8 2.3

WLPRZL 96.8 14.3 4.2

WTCTPT 80.5 2.0 0.6

WUAUUU 76.0 6.5 1.9

WWWH4N 79.8 2.7 0.8

X3UUYH 83.8 1.3 0.4

XLL0OS 73.1 9.4 2.8

XNSNEU 77.5 5.0 1.5

Y6T66I 82.5 0.0 0.0

Z1SAXE 96.2 13.7 4.0

*) Concentration: w/w %



Substance: SM-3/1-(3-Chlorophenyl)piperazine 2.3MAD =Median =UNODC value = 82.1

82.5

Round: 2013/2



(64)


Code Identified Substances0NNGO4 Lactose

9AT7DN None

9S9R99 -

E4AF6Q None

EOZOOO None

HE2TG2 Lactose

HHRTHH BLANK

HVXZXL Lactose

HWGQ3X None

II8JO4 None

JDDD6D Lactose Monohydrate

JJRRVN lactose

JPIPOT Lactose

JRLS5J lactose

NZMVTG No common controlled drugs

O0NJNN None

OF0Q00 Amphetamine

OOAION -

QMG6MM No drug

RBFBBM no drugs

RRR6HI LACTOSE

SLJETI spice (oleamide)

SZT4VF /

SZVCHI none

UGGGBT not detected for drugs

UVIZDN No controlled drugs

UY78GL NA

UYAC2L -

W4B4QT NOT drugs found

WABFAA -

WLPRZL Lactose

WM8MGO NONE

WVBNU6 LACTOSA

Sample 4 Analysis



Code Lactose

0DA6JO +De los análisis realizados se concluye que el polvo blanco se trata de lactosa.

0NNGO4 +

0YFLNL +

1 glass bottle containing 0.23 grammes of a powder which did not contain any substances controlled under the Dangerous Drugs Ordinance (Cap.134).

144FAB +

A white powder containing lactose

192GH2 +

The sample is lactose.

28NZ22 -

No controlled drugs detected.

2EQC6Q +

The sample contained lactose.

2UUUXU ANP

After analysing the sample with colourimetric tests, MSD chromatography (several methods) we are confident that SM-4 sample is not drugs-negative

3DVBVE +

3LN2N9 ANP

not detected substances by method GC/MS

44VN4T +

Lactose confirmed in one unit tested of one unit recieved.

4CVIID +

In the test sample 2013/2/SM-4 was detected lactose

4Y4BMB +

Lactose

5AKBA5 +Lactose

5DMOWW +

Ose

5OHSAB +

LACTOSA,4-TETRAMETHYLENEAZIRIDINE




Code Lactose

5V2K55 ANP

66P66H +

lattosio

6AAAIA +

7JPM7K ANP

7NMYY7 -

815B51 +

LA MUESTRA DE POLVO BLANCO CORRESPONDE A LACTOSA

9999JM +

The sample contains lactose.

9AT7DN +

Lactose, usual diluent, was found in this sample

9S9R99 +

We found alpha-lactose monohydrate in SM-4

A4DVDD +The sample 2013/2/SM-4 does not contain any drug in the menu of ICE programme.

AC6AA0 +

Lactose was identified by TLC

ARRBBM ANP

AXAVAA ANP

B11A58 +

the powder contains lactose

BR66FX +

The sample contains lactose.

C6UZN1 +

lactose

CFILQS +

sample 4 contains lactose



Code Lactose

CITDQT -

CMQISC +

CPCFME ANP

On analysis of the sample, no controlled drugs were detected.

DFLETW +

DGEIFI +

No controlled drugs were detected in this powder, which contained lactose.

DWGQZS +

Lactose

E4AF6Q +

Lactose

E5B6AC +Marquis reagent have been apllied, TLC (Thin Layer Chromatography) for opiaces, cocaine and the GC/FID

EOZOOO +

Based on the above analysis, the sample was found to contain lactose.

G7GGCR +lactose

GGWXWW ANP

The powder was analysed for the presence of drugs controlled within the provisions of the Misuse of Drugs Act 1971 with a negative result.

GULHNN +On analysis, I found the substance to contain lactose

GZDUQM +

Sample 2013/2/SM-4 consists of white powder. No prohibited substances included in the National Law for Narcotics, are found to be present in this sample. The sample contains paracetamol and lactose.

HBHUNI ANP

HE2TG2 +

HHHHU5 +

Test Sample 2013/2/SM-4 - one vial containing white powder. No controlled drugs were detected in this powder which contained lactose.



Code Lactose

HHRTHH -

SM4 was free of drugs

HVXZXL +

Lactose detected in SM-4.

HWGQ3X +

Color test: negativeTLC and GCMS: drug not foundGC: no peakFT-IR: Lactose

I5IP07 +

LACTOSE

IAWA6A +

lactose

IBOQKX +

This sample is lactose.

II8JO4 +

No controlled drugs detected. Results indicated the powder to be lactose.

IP12QF +

It is detected the presence of lactose in the sample.

JDDD6D +

The test sample 2013/2/SM-4 was analysed by colour test and Thin layer Chromatography techniques and found to contain Lactose Monohydrate.

JJRRVN +

the sample was found to contain lactose

JKBKRK +

No controlled drugs were detected.

JPIPOT +The sample SM4 contained lactose.

JRLS5J +

The lactose is not scheduled as illlicit drug in France, it's a cutting agent.

JSHHOS +

The powder was analysed and found to contain no controlled substances.

JSZMHJ +

Lactose

JYDFMU +

lactose 100%



Code Lactose

KKQS2K ANP

LLCQXL ANP

On analysis, I did not detect drug in "2013/2/SM-4" sample.

LQEYRY +

We only found lactose

N0TYZE -

NBNVJG +

LACTOSA

NNVNSC +

lactose

NRVAVR ANP

The sample 2013/2/SM-4 did not contain any of the drugs tested for.

NVUXXR +

Possibly sugarAmount: 0,2 gram

NZMVTG +

The sample was found to contain no common controlled drugs.

O0NJNN -

Controlled drugs were not detected in test sample 2013/2/SM4.

ODFBYE -

OF0Q00 ANPThe sample contain amphetamine.

OOAION ANP

-

OOIOUO ANP

None detected

OQ2JQM ANP

P04CR4 ANP

PCR99G +

the sample contains lactose



Code Lactose

PDMMHM +

LACTOSE WAS IDENTIFIED

PWYKZQ ANP

negative

QMG6MM +

QPEFZE +

SM-4 contains lactose

QRPRRR +

QXZKSQ +

The analysis did not reveal any controlled drug according to french order, decree of February 22nd 1990.

R21VX8 +

LACTOSE POSITIVE

RBFBBM +

Lactose

RRR6HI +

LACTOSE

RSNKH3 ANP

SL61P0 -

SLJETI ANP

SUA1EC +

lactose

SZT4VF +

sample contains lactose

SZVCHI ANP

negative to marquis reagentnegative to scott reagentthere is not signal in our chromatogram

T3A33W +

lactose

UBJZMK +

White powder containing lactose, NO illegal drugs where detected.



Code Lactose

UGGGBT ANP

the sample was performed by TLC , UV and GC MS and no illicit or psycotric drugs were found neither

UOBROB +

UVIZDN +

We find in this Sample Lactose

UY78GL +

DE ACUERDO AL ESPECTRO IR LA MUESTRA CORRESPONDE A LACTOSA

UYAC2L +

Lactose

VDZ8NV +

se le realizó marquis, scott, chen cao, lieberman y FT-IR

VWU2B0 ANP

W4B4QT +

NOt identified any regulated substance, we identified Lactose

WABFAA -

-

WEEH53 ANP

WELQMQ ANP

WLPRZL +

The result of TLC and IR of test sample was same as Lactose

WLZJLF -

La muestra es Lactosa

WM8MGO -

we have not found any controlled drug in the SM 4

WTCTPT ANP

Samples contains lactose (screening with FT-IR)

WUAUUU +

white powder identified as lactose

WVBNU6 +



Code Lactose

WWWH4N +

SM4 contains Lactose

X3UUYH ANP

X8WVVF +

white powder containing lactose

XDOWHP +

powder containing lactose.

XLL0OS +

lactose

XNSNEU +

Presence of lactose was detected in the sample.

XPOMU1 ANP

XSNG6F +

XXR4ZM ANP

Sample 2013/2/SM-4,a white odorless powder, was not found to contain any controlled substance under National Law.

Y6T66I +

The sample contains lactose

YXMHT9 +

lactose

YXXRY9 ANPWhite powder, negative

Z0BIZI +

Lactose

Z1SAXE ANP

ZLFXWZ +

On analysis, I found the substance to contain Lactose




Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


0NNGO4 S I I

0YFLNL S S SI I

144FAB S S I I

192GH2 S S I I

28NZ22 S S S I I

2EQC6Q SI I

2UUUXU S I

3DVBVE S I I

3LN2N9 SI

44VN4T I SI I I

4CVIID I I I

4Y4BMB S I I

5AKBA5 SI

5DMOWW

I SI I

5OHSAB S S S I I

5V2K55 I SI

66P66H SI SI

6AAAIA I I

7JPM7K I

7NMYY7 SI S I


9999JM I S I SI SI

9AT7DN I SI I I

9S9R99 S I I

A4DVDD SI I

AC6AA0 S S S I I

ARRBBM SI I

AXAVAA S S S SI

B11A58 I SI I

BR66FX SI I I

C6UZN1 S SI I I

CFILQS S S I I





Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


CMQISC S I I

CPCFME I SI

DFLETW I SI

DGEIFI S S I I

DWGQZS SI I

E4AF6Q S I

E5B6AC SI S S I I

EOZOOO S I I

G7GGCR S S S I I I

GGWXWW

S I

GULHNN S I I

GZDUQM S S I I I I

HBHUNI SI I I

HE2TG2 S S SI I

HHHHU5 S S I I

HHRTHH S S S I


HWGQ3X S S I I I

I5IP07 S S I I

IAWA6A I SI I

IBOQKX S I I

II8JO4 S S I I

IP12QF I S I

JDDD6D S S I I A

JJRRVN S I I

JKBKRK S S I I

JPIPOT I I

JRLS5J S S I I

JSHHOS S S I I

JSZMHJ S I I I XRD

JYDFMU SI SI

KKQS2K S I S

LLCQXL S I

LQEYRY SI I

N0TYZE SI

NBNVJG S I I

NNVNSC I I

NRVAVR S S S I I



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

NVUXXR SI I

NZMVTG SI I LC/ELSD

O0NJNN SI


OF0Q00 SI ASAP-TOF

OOAION SI

OOIOUO S SI

OQ2JQM S S S I I

P04CR4 S S S I I

PCR99G S S I I

PDMMHM I SI I

PWYKZQ I SI

QMG6MM I SI SI


QRPRRR S S I I I

QXZKSQ I I

R21VX8 I SI

RBFBBM S I I

RRR6HI S S S I I I

RSNKH3 I SI

SL61P0 I SI

SLJETI SI

SUA1EC S SI I I

SZT4VF S SI I I I I

SZVCHI S I

T3A33W S S I I SI

UBJZMK S S I I

UGGGBT S I I

UOBROB S I I

UVIZDN S S S I I

UY78GL S I I

UYAC2L SI I


VWU2B0 SI S S I I

W4B4QT S S I I

WABFAA SI SI I I I

WEEH53 I SI

WELQMQ SI I

WLPRZL I I SI



Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

WLZJLF S SI S I I

WM8MGO

SI SI SI I

WTCTPT I S

WUAUUU SI I

WVBNU6 SI SI I I

WWWH4N

I S I I

X3UUYH S S S I I

X8WVVF I SI


XLL0OS SI SI I I I


XPOMU1 I I SI FPIA

XSNG6F S I

XXR4ZM S S I I

Y6T66I S I I I

YXMHT9 I I S ATR

YXXRY9 S I SI SI I

Z0BIZI S I I

Z1SAXE SI

ZLFXWZ S I I









Code Name Technique

GZDUQM

Response Summary Participants: 131 Section 140 141 142 150


OF0Q00 Amfetamine 190 (ASAP-TOF MS)


Lactose: 89

Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 43 54 39 16 0 2 0 2 41 8 1 0 0 0 6

32.8% 41.2% 29.8% 12.2% 0.0% 1.5% 0.0% 1.5% 31.3% 6.1% 0.8% 0.0% 0.0% 0.0% 4.6%

Identification 12 6 3 30 6 15 3 20 118 70 2 3 2 3 9

9.2% 4.6% 2.3% 22.9% 4.6% 11.5% 2.3% 15.3% 90.1% 53.4% 1.5% 2.3% 1.5% 2.3% 6.9%


48 54 40 39 6 16 3 21 118 73 3 3 2 3 11

36.6% 41.2% 30.5% 29.8% 4.6% 12.2% 2.3% 16.0% 90.1% 55.7% 2.3% 2.3% 1.5% 2.3% 8.4%


Paracetamol (Acetaminophen) 170

The Laboratory and Scientific SectionUNODC, International CentreWagramer Strasse 5, P.O. Box 500A-1400, Vienna, AUSTRIAEmail: [email protected]



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