Page 1
Solid Oxide Fuel Cells 10
(SOFC-X) - Pari 1
Editors:
K. EfluchiKyoto UniversityKyoto, Japan
S. C. SinghalPacific Northwest National LaboratoryRichland, Washington, USA
H. Yokokawa
National Institute of Advanced Industrial Science and Technology
Tsukuba, Japan
J. Mizusaki
Tohoku UniversitySendai, Japan
Published by
The Electrochemical Society65 South Main Street, BuildtfTg-B1Pennington, NJ 08534-2830, USA
tel 609 737 1902
fax609 737 2743
www.electrochem.org
^transactions
TECHNISCHE V°fcl7 N°" 1
INFORIMTiG^oBKiUO^fR"1"58877-884"0
university. --/LIOTHEK
Page 2
ECS Transactions, Volume 7, Issue 1
Solid Oxide Fuel Cells 10 (SOFC-X)
Table of Contents
PART ONE
Preface iii
Chapter 1
Plenary Papers
Status ofNational Projectfor SOFC Development in Japan 3
T. Ujii
U.S. DOE Fossil Energy Fuel Cell Program 11
W. Surdoval
SOFC Related Research and Development within the Framework Programme 17
ofthe European Union
B. Rietveld
Chapter 2
Stack and Systems
Development of SOFC Residential Cogeneration System at Osaka Gas and 27
KyoceraM. Suzuki, T. Sogi, K, Higaki, T. Ono, N. Takahashi, K. Shimazu andT.
Shigehisa
Solid Oxide Fuel Cell Development at Topsoe Fuel Cell A/S and Ris0 31
National LaboratoryN. Christiansen, J. B. Hansen, H. H. Larsen, S. Linderoth, P. H. Larsen,P. V. Hendriksen andA. Hagen
Development of 25kW Class SOFC Module 39
K. Ikeda, N. Hisatome, K, Nagata, D. Tsukamoto, Y. Kawaguchi, K.
Kosaka, N. Matake, H. Sasatsu, Y. Takahashi andK. Konishi
Coal Based Solid Oxide Fuel Cell Technology Development 45
N. Minh
Page 3
Support Structures for SOFCs Operating at High Power Density and Fuel 51
Utilization
S. Aruliah, S. Amarasinghe, J. Love, R. Ratnaraj, A. Summergreene and
M. Watts
Solid Oxide Fuel Cell Development: Latest Results 59
S. Mukerjee, K. Haltiner, R. Kerr, L. Chick, V. Sprenkle, K. Meinhardt, C.
Lit, J. Y. Kim crndK. Weil
Real-SOFC - A JointEuropean Effort in Understanding SOFC Degradation 67
R. Steinberger-Wilckens, F. Tietz, M. J. Smith, J. Mougin, B, Rietveld, O.
Bucheli, J. van Eerie, R. Rosenberg, M. ZahidandP. Holtappels
Development ofIntermediate-temperature SOFC Modules and Systems 77
M. Shibata, N. Murakami, T. Akbay, H. Eto, K, Hosoi, H. Nakajima, J.
Kano, F. Nishiv/aki, T. Inagaki andS. Yamasaki
Characterization ofSOFC Short Stacks and Stacks for Mobile Applications 85
M. Lang, C. Auer, A. Eismann, G, Schiller andP. Szabo
Stack Testing Summary - Versa Power Systems 95
/ Dueck, S. Benhaddad, C. Brown, O. Grande, J. Kelsall, T. Machacek, J.
Nelson, S. Thompson and T. Wood
The Components ofa Rolls-Royce 1 MW SOFC System 105
G. D. Agmw, R. D. Collins, M. 3. Jorger, S. H. Pyke andR. Travis
Operational Experience ofan IT-SOFC / Battery Hybrid System for 113
Automotive ApplicationsD. J. Brett, P. Aguiar, N. P. Brandon, I. Coop, J. Dueck, R. C. Galloway,0. Grande, G. W. Hayes, K. Lillie, C. Mellors, S. Thompson, R. Tilley and
T. Wood
Design of 500 W Class SOFC Stack with Homogeneous Cell Performance 123
0. Bucheli, M. Molinelli, T. Zahringer, E. Thorn, S. Diethelm, Z,
Wtiittemin, A. Nakajo, N. Autissier andJ, van Eerie
Investigation on Degradation in Long-Term Operations ofFour Different 133
Stack/Modules
E Yokokawa, T. Watanahe, A. Ueno andK. Hoshino
Development Status ofa Planer Type of 1 kW Class SOFC System 141
J. Shimano, H. Yamazaki, Y. Mizutani, K. Eisada, K. Ukai, M. Yokoyama,K. Nagai, S. Kashima, H. Orishima, S. Nakatsuka, H. Uwani andM.
Eirakawa
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Development of High Power Density Seal-Less SOFCsS. Vora
149
Development of SOFC-Micro Gas Turbine Combined Cycle System 155
M. Nishiura, S. Koga, T. Kabata, N. Eisaiome, K. Kosaka, Y. Ando and Y.
Kobayashi
JPOWER's Prototype 150kW-Class SOFC Cogeneration System 161
Development (SOFIT)H. Nakatomi, N. Komiyama, Y, Takahashi, K. Omata, T. Haga, T. Kikuchi
andH. Sasatsu
GE SECA Prototype System Development and Testing 167
Q. Zhou, J. Goodman, J. Powers and T. Campbell
Improvement ofTubular Type Cell Stack 173
K. Tomida, T, Kabata, N. Hisatome, A. Yamashita, E. Tsukuda, S.
Ohkuma and T. Kiyabu
Long-Term Operations Test and Investigation on Stack Performance of 181
Tubular-type SOFC Stacks
T Yamamoto, Y. Etori, H. Morita, Y. Mugikura, T, Watanabe andA,
Yamashita
Development of Anode Supported Micro-Tubular SOFC Stack for APU 187
ApplicationS. Lee, K. Yun, T. Lim, R. Song andD. Shin
Operating Characteristics of Advanced 500W Class Anode-supported Flat 193
Tubular SOFC stack in KIER
T. Lim, G. Kim, J. Park, R. Song, S. Lee andD, Shin
Development of 1 kW Class SOFC System at KEPRI 199
T. Lee, J. Park, J. Oh, Y. Yoo, J. Bae, J. Park and J. Kim
The Electrical Performance ofa 5-Cell Planar SOFC Stack 205
G. DiGiuseppe
Planar LT-SOFC, Stack and Fuel ProcessorDevelopment at IPPE 215
V. Ruzhnikov, N. Khramushin, A. Gulevich and V, Privezentsev
Development ofAutothermal Reforming Catalyst for SOFC System Powered 221
by Kerosene
Y. Sugiura, Y. Mizuno, 0. Sadakane and I. Anzai
vil
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Chapter 3
Cell Design, Processing, and Performance
Development of Anode-supported Planar SOFC using Inexpensive and 227
Simple Processing TechniqueR. Basu, A. Das Sharma, A. Dutta, J. Mukhopadhyay andH. S. Maiti
Development of Segmented-in-series Cell-stacks with Flat-tubular Substrates 235
M. Koi, S. Yamashita andY. Matsuzaki
Characterization of Cathode Chromium Incorporation during Mid-Term 245
Stack Operation under Various Operational Conditions
N. H. Menzler, L. G. de Haart andD. Sebold
Development ofAnode Supported Solid Oxide Fuel Cells using LaNi(Fe)03 255for Cathodes.
H. Orui, K. Nozawa, R. Chiba, T, Komatsu, K. Watanabe, S. Sugita, H.
Aral andM. Arakawa
Strategy ofthe Development of Cr-tolerant Cathodes of Solid Oxide Fuel 263
Cells
Y. Zhen, S. Jiang andA. Tok
Development of Novel Cell Components for Low-temperature SOFC 271
Y. Zhang-Steenwinkel, M. M. van Tuel, F. P. vanBerkelandB. Rietveld
Metal Supported SOFCs 279M. Tucker, G. Lau, C. P. Jacobson, L. C. DeJonghe andS. J. Visco
Development Status ofSOFC Cell and Stack Technology at NRC-IFCI 285A. Tuck, X. Zhang, R. Hui, W. Qu, C. Deces-Petit, Y. Xie, J. Roller, K.
Min, M. Robertson, S. Yick, R. Marie andD. Ghosh
Performance and Reliability Improvement ofPlanar SOFC Stack with 295Advanced Design ofUnit Cell and Sealing
J. Lee, E. Kim, H. Kim, J. Son, J. Kim, H. Lee andE. Song
Anode Supported Solid Oxide Fuel Cells - Deconvolution ofDegradation 301
into Cathode andAnode Contributions
A. Hagen, Y. L. Liu, R. BarfodandP. V. Hendriksen
Fabrication and Performance Evaluation ofMulti-Cell Arrayed Planar SOFC 311Stack
E Kim, H. Jung, H. Jung, J. Kim, J. Lee, H. Lee andH. Song
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Manufacturing ofAnode-Supported SOFC's: Processing Parameters and their 317
Influence
S. Ramousse, M. Menon, K. Brodersen, J. Knudsen, U. RahbekandP. H.
Larsen
Electrocatalytic Properties ofIntermediate Temeprature-SOFC 329
Cathode/LSGMC Interfaces
Y. G. Qin, X. Lu, J. Brouwer andD. R. Mumm
New High Efficient Thermal Spray Solutions for Perovskite Coatings and 339
Dense Thin Electrolytes Using TriplexPro-200 APS and LPPS-Thin Film
TechnologyE Eoehle, A. Refke andM. Gindrat
Comparison ofthe Numerical Calculations on Cell Performance Between 347
Ordinary Planar Cell and Segmented Cell
H. Yakabe
Operation of High Temperature Steam Electrolyzer Module 357
J. J. Hartvigsen, S. Elangovan, J. E. O'Brien, C. M. Stoots and J. S.
Herring
Double Layer-Type Electrodes for Reversible Solid Oxide Fuel Cells 365
E Uchida, S. Watanabe, Y. Tao, N. Osada and M. Watanabe
Regeneration ofAnodes Exposed to Sulfur 373
A. J. McEvoy and M. J. Smith
Long-term and Redox Stability ofElectrolyte Supported Solid Oxide Fuel 381
Cells Under Various Operating Conditions -n
S. Mosch, N. Trofimenko, M. Kusnezoff, T. Betz andM. Kellner
Degradation Behavior at Interface of LSCF Cathodes and Rare Earth Doped 389
Ceria
N. Sakai, H. Kishimoto, K. Yamaji, T. Horita, M. E. Brito andH.
Yokokawa
Refractory Cathode Investigation for Single-Step Co-fired Solid Oxide Fuel 399
Cells
P. Zink, K. J. Yoon, W. Huang, U. B. Pal and S. Gopalan
Performance Degradation of Solid Oxide Fuel Cells with Metallic 405
Interconnects
J, Guan, S. Zecevic, Y. Liu, P. Lam, R. King, M. Alinger, S. Taylor, B.
Ramamurthi, R. Sarrqfl-Nour andS. Renou
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Fracture Mechanics Experiments to Characterize the Failure of 413
Ceramic/Metal Joints in SOFC Stacks
B Kuhn, F J Wetzel, J Makbender, R W Stembiech andL Smgheiser
Micro-Hotplate Devices for Micro-SOFC 421
D Beckel, B Damck, J Courbat, A Bieberle-Hutter, N F deRooij and
L J Gauckler
Residual Stress Analysis in Lanthanum Gallate-based Cell before and after 429
Fuel Cell OperationH Yoshida, H Deguchi, T Inagaki, K Hashino, M Kawano, K Hosoi
andM Horiuch
High Power SOFC using LaGa03 Based Oxide Electrolyte Film Prepaied on 435
Porous Metal Substrate
T Ishhara, J Yan andH Matsumoto
A Model for Solid Oxide Fuel Cell (SOFC) Stack Degradation 443
A Virkat
Reliability Evaluation ofSOFC under Simulated Operating Condition 455
K Sato, N Imanaka, K Fukui, M Numao, S Kyotani, K Yashn o, T
Kawada, T Hashida andJ Mizusah
Influence ofFuel Contaminants on SOFC Operation Effect on Performance 459
and Degradation MechanismsJ Mougm, S Ravel, E de Vito andM Petijean
Multiphysics Concepts and Foundations for Durability and Accelerated 469Characterization ofSolid Oxide Fuel Cells
K Reifsmder, G Ju andX Huang
Fabrication ofMicio-Tubular SOFC Stack Using Ceramic Manifold 477T Suzuki, Y Funahashi, T Yamaguchi, Y Fujishno andM Awano
Portable Propane Micro-Tubular SOFC System Development 483
C Finnerty, C Robinson, S Andiews, Y Du, P Cheekatamai la, P
DeWald, Y Lit and T Schwartz
Robust and Reliable Cells for an Easy Stack Operation 493
R Ihringer
x
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Development ofthe Stacked Micro SOFC Modules using New Approaches of 497
Ceramic Processing Technology.Y. Fujishiro, M. Awano, T. Suzuki, T. Yamaguchi, K. Arihara, Y.
Funahashi, S. Shimizu, A. M. El-Toni andS. Sakuragi
SOFC Cells and Stacks for Complex Fuels 503
E. M. Sabolsky, M. Seabaugh, K. Sabolsky, S. A. Ibanez andZ. Zhong
Anode Supported Tubular Cell Fabrication and Performance 511
W. A. McPhee, P. D. Menard, N. S. Gatto, N. M. Sammes andK.
Reifsnider
Evaluation and Modelling ofthe Cell Resistance in Anode Supported Solid 521
Oxide Fuel Cells
A. Leonide, V. Sonn, A. Weber andE. Ivers-Tiffee
Improvement in Mechanical Properties ofAnode-Supported Planar SOFC 533
R. Basu, S. S. Kumar, A. K. Mukhopadhyay andH. S. Maiti
Effect ofAnode Support Thickness on the Performance ofTubular SOFCs 543
H Son, T. Lim, S. Lee, D. Shin, R. Song andS. Kim
Effect ofGDC Electrolyte Thickness on the Performance ofAnode 551
Supported Micro Tubular SOFC
T. Otake, M. Yokoyama, K. Nagai, K. Ukai and Y. Mizutani
Direct-Flame Solid-Oxide Fuel Cell (DFFC): A Thermally Self-Sustained, 555
Air Self- Breathing, Hydrocarbon-Operated SOFC System in a Simple, No-
Chamber SetupM. Vogler, D. Barzan, H. Kronemayer, C. Schulz, M. Horiuchi, S.
Suganuma, Y. Tokutake, J. Wamatz and W. G. Bessler
Anode Polarization Effects in Single Step Co-fired Solid Oxide Fuel Cells 565
K. J. Yoon, S. Gopalan and U. B. Pal
Electrochemical Study ofIT-SOFC Unit Cell Prepared By Tape Casting 573
Process and Co-sinteringH Kim, J. Song, S. Park, S. Oh andD. Chang
High Performance Low Cost Co-Fired Solid Oxide Fuel Cells 579
K. J. Yoon, P. Zink, U. B. Pal, S- Gopalan andD. Seccombe
Geometric Effects on Tubular Solid Oxide Fuel Cells 589
C. Finnerty, Y. Du, B. J. Emley, P. Cheekatamarla, W. Zhu, J. Cai andR.
Sharp
XI
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Cell Performance ofMicrotubular SOFCs with Sc-Doped Zircoma 597
Electrolyte under Pressurized Conditions
H Nishino, S Hashimoto, Y Liu, K Asano, M Mori, Y Funahashi and Y
Fujishiro
TubularMicro-Solid Oxide Fuel Cell for Remote Power Applications 603
P Sarkai,L YamarieandL Johanson
Polarization Properties ofan Intermediate Temperature Operated Ceramic 609
Reactor in Power Generating ModeS Hashimoto, H Nishino, Y Liu, K Asano, K Takei, M Mon, Y
Funahashi and Y Fujishiro
Development of Micro-Tubular SOFCs with an Improved Performance via 615
Nano-Ag Impregnation for Intermediate Temperature OperationY Liu, S Eashimoto, E Nishino, M Mori, Y Funahashi, Y Fijishiro, A
Hirano, N Imamshi and Y Takeda
Electrochemical Testing of Solid Oxide Fuel Cells with Sol Gel Impregnated 623
Plasma Sprayed ElectrolytesL Rose, O Kesler, Z Tang andA Burgess
An Electrolyte-supported SOFC Stack Fabricated by Slip Casting Technique 633
J Sui andJ Liu
Fabrication and Characterization of Stacked SOFCs Using Rapid Fabrication 639
TechniqueK Anhara, Y Fujishiro andM Awano
Optimization of Configuration for Cube-Shaped SOFC Bundles 643
Y Funahashi, T Suzuki, Y Fujishiro, T Shimamoi i and M Awano
Fabrication and Properties ofHoneycomb-type SOFCs Accumulated with 651
Multi Micro-cells
S Shimizu, T Yamaguchi, T Suzuki, Y Fujishiro andM Awano
Development of Honeycomb-type SOFCs with Accumulated Multi Micro- 657
cells
T Yamaguchi, S Shimizu, T Suzuki, Y Fujishiro and M Awano
Two-cell Stack Test ofHoneycomb SOFCs with Air Preheating Channels 663
S Shimizu, Z Wang, S Kobuna and Y Yamazaki
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Power Generating Performance ofHoneycomb-type Solid Oxide Fuel Cell 669
Consisting ofLaGa03 Based Oxide ElectrolyteH. Zhong, H. Matsumoto, T. Lshihara andA. Toriyama
A Numerical Approach to Predict the SOFC Fracture: The Case of an Anode 677
Supported Cell
J. Laurencin, G. Delette, M. Dupeux andF. Lefebvre-Joud
An Aging Study ofSolid Oxide Fuel Cells for Intermediate Temperature 687
OperationT. L. Reitz, H Xiao, M. Rottmayer andA. Seibert
Development ofEstimation of SOFC System Performance 697
F. Yoshiba, T. Yamamoto, M. Yoshikawa, Y. Mugikura and T. Watanabe
Development of Tubular Solid Oxide Fuel Cells Composed ofNi-YSZ 703
Supported SSZ Electrolyte Film and Cobaltile Electrodes for Reduced-
Temperature Operating SOFCs
T. T. Nguyen, T Kato, T. Honda, Y. Tanaka, A. Negishi, K Kato, S.
Tanaka and Y. Iimura
Performance of Single Cells with Anode Functional Layer based on Ni-YSZ, 713
ScSZ and SDC for IT-SOFCs
J. Park, S. Yang, T. Lee, T. Park and Y. Yoo
Power Generation Experiment ofSingle Planar SOFC with Segmented 719
Electrodes
H. Iwai, R. Yasutomi, Y. Okumura, M. Saito, E. Yoshida, K. Kodani and
K. Yoshikata
Development of Small Planar Cells (Ni-YSZ|YSZ|LSM) and Automatic 727
Evaluation ofPerformance and Deterioration ofSOFC
M. Yoshida, T. Gomoto andK. Eguchi
Fabrication and Characterization ofthe Gas Channel Integrated SOFC Cells 735
T. Ryu, T. Okamoto, C. Chen, S. Ito, K. Matsuda, T. Kuno and T. Ichigi
Fabrication and Characterization of Miniaturized SOFC by Colloidal Process 743
E. Oh, H Kim, D. Baek, J. Park, H. Kim, J. Lee, H. Lee, C. Whang and J.
Son
Synthesis, Structure and Electrochemical Properties ofEpitaxial Perovskite 749
Films Deposited on YSZ Substrate
D. Mori, E. Oka, Y. Suzuki, A. Yamada, R. Kanno, N. Imanishi andY.
Takeda
xm
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Characteristics and Performance of Electrolyte Supported Single Solid Oxide 757
Fuel Cells using Ethanol and HydrogenD. Zanetti de Florio, F. C. Fonseca, E. N. Muccillo andR. Muccillo
Metal-supported Solid Oxide Fuel Cell Operated at 400~600°C 763
S. R. Hui, D. Yang, Z. Wang, S. Yick, C. Deces-Petit, W. Qu, A. Tuck, R.
Marie andD. Ghosh
Ceramic Diffusion Barrier Layers for Metal Supported SOFCs 771
T Franco, K. Schibinger, Z. Ilhan, G. Schiller andA. Venskutonis
Fabrication ofa Metal-Supported Ceria Cell by Wet Powder Spray and its 781
Characterization at Intermediate Temperatures
N. Oishi, Y. Yoo andI. Davidson
Spray Pyrolysis Deposition ofElectrolyte and Anode for Metal Supported 787
Solid Oxide Fuel Cell
Y. Xie, R Neagu, C. Esu, X. Zhang andC. Deces-Petit
Stability Analysis ofthe Interface Between Electrical Contact Layers and 795
Metal Interconnects in Solid Oxide Fuel Cells
S. Shim andD. R. Mumm
Measurement of Concentration Profile of Gaseous Species in Seal-less Disc- 805
type SOFC Anode Operating on Reformed Fuel
A. Momma, K. Takano, Y. Tanaka, A. Negishi, K. Kato, M. Amano, K.
Nozaki, T. Kato, T. Lnagaki, M. Kawano, K. Hosoi, K. Hoshino, M.
Shibata, T. Akbay, J. Akikusa andN. Chitose
Liquid-Hydrocarbon Internal Reforming In Catalyst-Assisted SOFCs 815
I. Kim, M. R. Pillai andS. A. Bamett
Improving Reliability ofMicrotubular SOFCs for Direct Use on Methane 823
A. Dhir andK. Kendall
Carbon Content in a Direct Carbon Fuel Cell 829
S. Jain, B. Lakeman, K. D. Pointon andJ. T. Irvine
Enhancing Cathode Performance and Anode Sulfur/Carbon Tolerance of 837
SOFCs by Nano-Infiltration
T. Sholklapper, H Kurokawa, C. P. Jacobson, S. J. Visco andL. C. De
Jonghe
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Influence ofH2S Poisoning on Anode Layer ofSOFC 845
A. Ishikura, S. Sakuno, N. Komiyama, E. Sasatsu, N. Masuyama, E. Itoh
andK. Yasumoto
Electrode Polarization Characteristics of Solid Oxide Fuel Cells Under 851
Pressurized Conditions
T. Matsui, M. Futamura, R. Kikuchi andK. Eguchi
High-temperature Reactions between Scandia-doped Zirconia (ScSZ) and 859
Cathode Materials
/. Wackerl, T. Markus, D. Peck, S. Woo andL. Singheiser
Influence ofPolymeric Resin-Derived LSM Coated YSZ Composites on 869
Cathodic Performance and Durability in SOFCs
H. Song, S. Hyun andJ. Moon
In-situ Observation on the Active Reaction Sites for the OxygenReduction in 875
Solid Oxide Fuel Cells
W. Wang andS. Jiang
Growth ofThin Film Electrodes of SOFC by PLD Method 881
S. Tsukui, M. Otani, K. Yoshida, K. Sagara and T. Oka
ONEBAT: Micro-Solid Oxide Fuel Cells for Battery Replacement in 887
Portables
J. Rupp, U. P. Muecke, D. Beckel, A. Bieberle-Hiitter, A. Infortuna andL.
J. Gauckler
Ceria-Based Thin Film Hetero-structure Growth and Characterization for 891
SOFC ApplicationsV. Esposito, D. Pergolesi, S. Sanna, A. Tebano, P. Medaglia, S. Licoccia,G, Balestrino andE. Traversa
Fabrication and Characterization of Cermet Supported Cell with SDC 899
ElectrolyteX. Zhang, M. Robertson, C. Deces-Petit, W. Qu, M. Kyong-Bok, A. Tuck,Y. Xie, R. Hui, 0. Kesler, R. Marie andD. Ghosh
Materials for Symmetrical Solid Oxide Fuel Cells 905
J. Ruiz-Morales, J. Canales-Vazquez, C. Savaniu, J. T. Irvine andP.
Nunez
Manufacture ofLSM and GDC ThickFilm Pastes for SOFCs in an ISO 9001 913
Environment
A. E Feingold, P. Palanisamy, K. Takarabe, Z. Topka andR. S. Webb
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Properties ofNickel Products for SOFC ApplicationsL. Renny, Q- Yang, E. Wasmund, J. Bartout andS. Corbin
917
Development ofHigh-Performance Current Collectors via Novel Metal 927
Coating for Micro-Tubular Cells
Y. Liu, S. Hashimoto, H. Nishino, K. Takei, M. Mori and Y. Funahashi
Solid Oxide Electrolyzers for Efficient Hydrogen Production 933
J. P. Ouweltjes, M. V. Tuel, F. P. van BerkelandB. Rietveld
Fabrication of Tubular Solid Oxide Electrolysis Cells for Hydrogen 941
Production
T. Kato, T. T. Nguyen, T. Honda, Y. Tanaka, A. Negishi, S. Tanaka, M.
Amano, A. Momma, K. Kato and Y. Iimura
Single-Chamber Mini-Solid Oxide Fuel Cells Operated at a Lower 947
TemperatureJ. Min, S. Ahn, J. Moon, J. Kim andH Lee
Performance of Single-Chamber Intermediate-Temperature SOFCs Operated 955
in Methane/Air Mixtures using PdO/NiO/Ce02-Sm203 AnodesM. D. Cabezas, D. G. Lamas, M. G. Bellino, R. 0. Fuentes andN. E.
Walsoe de Reca
NiO/Zr02-Ce02 Anodes for Single-Chamber Solid-Oxide Fuel Cells 961
Operating on Methane/Air Mixtures
D. G. Lamas, M. D. Cabezas, I. O. Fdbregas, N. E. Walsoe de Reca, G. E.
Lascalea, A. Kodjaian, M. A. Vidal, N. E. Amadeo andS. A. Larrondo
Single-Chamber SOFC Operating with Hydrocarbon-Air and Hydrogen- 971
Oxygen Gas Mixtures
/. Kellogg, F. Dogan, T. Suzuki, U. O. Koylu, II. U. Anderson and V.
Petrovsky
Architectures and Performance of High-Voltage, Microscale Single-Chamber 981
Solid Oxide Fuel Cell Stacks
E. J. Crumlin, G. La O'andY. Shao-Horn
SOFC Based on Proton Conductors 987U. Balachandran, T. E. Lee and S. E. Dorris
Anode Performance ofa Dense Pd Film for IT-SOFCs using 993BaCe0.8Y0.2O3-a as an Electrolyte
K. Asano, M. Kawakami, Y. Mugikura and T. Watanabe
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Chapter 4
Cathode Materials, Processing, and Performance
Characterisation of Combinatorial Libraries of Perovskite Materials for 1005
SOFC Cathode ApplicationsJ. Rossiny, S. Fearn, J. A. Kilner, Y. Zhang, L. Chen, S. Yang, J. R. Evans,T Zhang, K. Yates andL. F. Cohen
(BaxSrl-x)(CoyFel-y)03-5 Perovskites as SOFC Cathode Material: 1015
Electrode-Electrolyte Reactions and Electrochemical Characterisation
L. Wang, R. Merkle, F. Baumann, J. Fleig and J. Maier
Characterisation ofMixed Conducting La-Sr-Fe Perovskites for Application 1025
in Solid Oxide Fuel Cells
P. Holtappels, A. Braun, M. Thiinemann and U. Vogt
Long-Term Stability ofComposite Cathode at High Current Densities 1033
M. Kusnezoff, N. Trofimenko, S. Mosch, W. Beckert, A. GraffandF.
Altmann
Impedance Studies ofThin-film and Patterned Sr-doped LaMn03 on Yttria- 1041
Stabilized Zirconia to Probe Oxygen Reduction Kinetics
G La O'and Y. Shao-Hom
Deconvolution ofSOFC Cathode Polarization 1051
E. Wachsman
Promotion ofOxygen Surface Reaction at the Hetero-Interface of 1055
(La,Sr)Co03 / (La,Sr)2Co04M. Sase, F. Eermes, T. Nakamura, K. Yashiro, K. Sato, J. Mizusaki, T.
Kawada, N. Sakai, K. Yamaji, T. Horita andH. Yokokawa
Mechanisms and Rate Laws for Oxygen Exchange on Mixed-Conducting 1061
Oxide Surfaces
S. Adler, X. Y. Chen andJ. R. Wilson
Influence ofCathode Porosity and Potential on Oxygen Reduction Kinetics at 1071
Intermediate Temperature SOFCs Cathodes
E. Lust, I. Kivi, G. Nurk, P. Moller, S. Kallip, V. Grozovski andH. Kurig
Development of (La0.75Sr0.25)(Cr0.5Mn0.5)O3 Cathodes of Solid Oxide 1081
Fuel Cells by Gelcasting TechniqueS. Jiang, L. Zhang, C. Cheng andL. Zhang
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Studies of Oxygen Exchange on Thin-Film La0.6Sr0.4CoO3-8 Using 1089
Nonlinear Electrochemical Impedance Spectroscopy (NLEIS)J. R. Wilson, M. Sase, T. Kawada and S. Adler
Improving LSM Cathode Performance Using (Cu,Mn)304 Spinel Coated 1097
UNS430 Ferritic Stainless Steel SOFC Interconnects
S. Paulson, M. R. Bateni, P. Wei, A. Petric and V. Birss
Electrochemical Characterization ofAir Plasma Sprayed LSM/YSZ 1107
Composite Cathodes onMetallic Interconnects
B. White, O. KeslerandL. Rose
Dry Coating Technique for Nanosized La0.8Sr0.2MnO3 Powder for SOFC 1115
Cathode
E Abe, E. Shimoda, K. Sato andM. Naito
Microstructure Control Using Impregnation of LSM in a Thin Porous 1119
Electrolyte LayerE. Shimada, K. Takizawa, H Michibata andA. Hagiwara
Alanine Assisted Low-Temperature Synthesis and Characterization of 1129
Nanocrystalline SOFC Cathodes
R. Basu, P. Pal, M. W. Raja, J. Mukhopadhyay, A. Dutta, S. Mahanty and
H. S. Maiti
LSCF Thin Film Cathodes Deposited by Spray Pyrolysis for Micro-SOFC 1139
D. Beckel, U. P. Muecke, G. Florey, T. Gyger, A. Dubach, A. InfortunaandL. J. Gauckler
Performance of Ln0.7Sr0.3Fe0.8Co0.2O3-5 (Ln = Pr, La, Gd) Cathodes for 1147
Intermediate-Temperature SOFCs Synthesized by a Novel Gel-Combustion
Route
I. Ruiz de Larramendi, D. G. Lamas, A. Fernandez, J. I Ruiz de
Larramendi, T. Rojo andN. E. Walsoe de Reca
Synthesis and Performance ofLa0.6Ca0.4Fe0.8Ni0.2O3-5 Material for 1157
Intermediate-Temperature SOFC Cathode
/. Rub de Larramendi, N. Ortiz, J. I. Ruiz de Larramendiand T. Rojo
Correlation ofLa0.8Sr0.2MnO3-5 Powder Synthesis Routes and High 1165
Temperature Electrical PropertiesM. J. Creedon, Y. Yang, C. S. Khadilkar andA. Shaikh
Evaluation ofLa0.8Sr0.2Cul-xMnxOd Double Perovskite forUse in SOFCs 1173
A. Berenov, H. WoodandA. Atkinson
xvtu
Page 16
Thermochemical Stability and Polarization Resistance of La(Ni0.6Fe0.4)O3 1183
Cathode
P. Sornthummalee, K. Sato, T. Komatsu, H. Oriti, R. Chiba andM.
Arakawa
LaNi0.6Fe0.4O3 - Ceria Composite Cathode for SOFCs Operating at 1191
Intermediate TemperaturesR. Chiba, H. Orui, T. Komatsu, Y. Tabata, K. Nozawa, H Arai, M.
Arakawa andK. Sato
Properties ofGd Substituted Lanthanum Cobalt Iron Oxide as Cathode for 1201
IT-SOFCs
P. Limthongkul, H. Tsuchiya, K. Somroop, M. Sansernnivet, K. Sato andS.
Charojrochkul
A-Site Deficiency and Phase Purity of Lanthanum Strontium Ferrite Powders 1207
T. Striker, J. A. Ruud, W. J. Heward, Y. Gao and C. Steinbruchel
Characterisation of La0.6Sr0.4Co0.2Fe0.8O3-d and 1217
Ba0.5Sr0.5Co0.8Fe0.2O3-d as Cathode Materials for the Application in
Intermediate Temperature Fuel Cells
P. Ried, E. Bucher, W. Preis, W. Sitte and P. Hollappels
Bal-xSrxCol-yFey03-5 Perovskites Bulk and Thin Films: Phase 1225
Compositions and Electrical ConductivityZ. Yang, A. Inforttma, A. Harvey andL. J. Gauckler 1
Lanthanum Doped Barium Cobaltite as a Novel Cathode for Intermediate- 1229
temperature SOFC Using Lanthanum Gallate ElectrolyteM. Kawasaki, N. Chitose, J. Akikusa, T. Akbay, H. Eto, T. Inagaki andT.
Ishihara
Initial Characterisation ofCerium Doped Neodymium Cuprates for Solid 1235
Oxide Fuel Cell ApplicationsM. Cassidy andJ. T. Iiyine
Passivation and Activation of SOFC Nanostructured Cathodes 1243
W. Wang, J. Bentzen, S. H. Jensen, N. Bonanos, P. V. Hendriksen andM.
Mogensen
Activation Process of Solid Oxide Fuel Cells under Polarization Conditions 1251
R. Kikuchi, K. Murakami, M. Futamura, T. Matsui andK. Eguchi
Electrochemical Impedance Studies ofSOFC Cathodes 1261
J. Hjelm, M. Segaard, M. Wandel, M. Menon, M. Mogensen andA. Hagen
xix
Page 17
Impedance Spectroscopy Studies of Oxygen Reduction Reaction on Thin 1271
Film Platinum Microelectrodes Supported on YSZ
S. Koc, G. La 0', T. Golflnopoulos and Y. Shao-Eorn
Electronic Structure Studies of Lal-xSrxCo03-5 Using High Temperature 1279
Magnetization Measurements
D. Baskar andS. Adler
Electrode Performance at Hetero-interface ofPerovskite-related Oxides, (La, 1287
Sr)Co03-8 / (La, Sr)2Co04-8K. Yashiro, T. Nakamura, M. Sase, F. Hermes, K. Sato, T. Kawada andJ.
Mizusaki
Combination of Electrochemical Impedance Spectroscopy and Cyclic 1293
Voltammetry to Investigate Oxygen Ion Transport in YSZ Electrolyte of
SOFC
W. Boonjob, N. Punbusayakid, R. Beckett, M. Masomtub, K. Wongtidad, S.
Charojrochkul and W. Veerasai
Performance ofAg/La0.6Sr0.4Col-xFexO3 (x = 0 - 0.8) Nanotube 1299
Composite Cathodes for IT-SOFCs
M. G. Bellino, J. G. Sacanell, D. G. Lamas, A. G. Leyva andN. E. Walsoe
de Reca
LSCF-Ag Composite Cathode for Reduced-temperature SOFCs 1305
Y. Sakitou, A. Hirano, K. Eanai, T. Matsumura, N. Imanishi and Y.
Takeda
Ag Thin Film Cathode for LSGM Electrolyte LT-SOFCs 1311
K. Sasaki, M. Muranaka, A. Suzuki andM. Terai
Electrophoretically Coated Wire Meshes as Current Collectors for Solid 1319
Oxide Fuel Cell
Y. Itagaki, F. Matsubara, M. Asamoto, E. Yamaura, E. Yahiro and Y.
Sadaoka
xx
Page 18
PARTTWO
Chapter 5Anode Materials Processing, and Performance
A Critical Review of Models ofthe H2/H20/Ni/SZ Electrode Kinetics 1329
M. Mogensen, J. Hogh, K. V. Eansen and T Jacobsen
SOFC Anode Performance Enhancement through Precipitation of Nanoscale 1339
CatalystsB. D. Madsen, W. Kobsiriphat, Y. Wang, L. D. Marks andS. Barnett
Multilayer High Performance Ceramic Anodes 1349
M. Gross, R. Gorte andJ. Vohs
Morphology Control ofNi-GDC Cermet Anode for Lower Temperature 1355
SOFC
T Misono, K. Murata, J. Yin and T. Fitkui
Towards Understanding the Impedance Response of Ni/YSZ Anodes 1363
V. Sonn, A. Leonide andE. Ivers-Tijfee
Microstructural Changes ofNi/YSZ Cermet under Repeated RedoxReaction 1373
in Environmental Scanning Electron Microscope (ESEM)Y. Nakagawa, K Yashiro, K. Sato, T. Kawada and J. Mizusaki
Reaction Compounds in the Vicinity ofNi-SDC/LSGM Interface and 1381
Performance of SOFC Single Cells with DifferentAnode Thickness
K. Kawahara, S. Suda, M. Suzuki, M. Kawano, H. Yoshida and T. Inagaki
Anode Polarization in Liquid Tin Anode Solid Oxide Fuel Cell 1389
T. Tao, M. Slaney, L. Bateman andJ. Bentley
Preparation ofStandard Gas and Precise Analysis ofReformate Gas 1399
Y. Tanaka, K. Kato, A. Negishi, T Kato andK. Nozaki
Mechanical Properties ofAnode-Supported Micro-Tubular Solid Oxide Fuel 1409
Cells
A. Mohammadia, J. Pusz, A. L. Smirnova andN. M. Sammes
Modeling Approach ofa New Anode Concept for Gradual Internal 1419
ReformingJ. Klein, Y. Bultel, S. Georges andM. Pons
xxi
Page 19
Coke Formation in Hydrocarbons-Containing Fuel Gas and Effects on SOFC 1429
Degradation Phenomena
E Timmermann, W Sawady, D Campbell, A Weber, R Reimert andE
Ivers-Tiffee
Behavior of Carbon Deposition on Fuel Electrode and Subsequent 1437
Deterioration ofCell Performance During Internal Reforming Operation of
SOFCs
T Matsui, T hda, M Kawano, T Inagaki, R Kikuchi andK Eguchi
Al-Doped (La,Sr)Ti03+5 Anodes for the Direct Oxidation of Methane in 1447
SOFCs
D Miller andJ T Irvine
Direct Internal Steam Reforming at SOFC with Anode Prepaied Usmg NiO- 1455
SDC Composite Particles
M Kawano, T Matsui, R Kikuchi, E Yoshida, T Inagaki andK Eguchi
Conversion ofSimulated Biogas in a SOFC The Effect of Organic 1465
CompoundsN Dekker, J P Ouweltjes andB Rietveld
Performance Assessment ofBioethanol-Fed Solid Oxide Fuel Cell System 1475
Integrated with Distillation Column
W Jamsak, S Assabumrungrat, P L Douglas, E Croiset, N
Laosiripojana, R Suwanwarangkul and S Charoji ochkul
High Tolerant to Carbon DepositionNi-based Electrodes underInternal 1483
Steam Reforming Conditions
I Gavrielatos andS Neophytides
On the Redox Cycling of Anode-Supported SOFCs Mechanical Properties 1491
and Damage Mechanisms
D Sarantaridis, R A Rudkin andA Atkinson
Dimensional Behaviour ofNi-YSZ Anode Supports for SOFC Under RedOx 1501
Cycling Conditions
M Pihlahe, A Kaisei, P H Larsen andM Mogensen
Understanding Nickel Oxidation and Reduction Processes in SOFC Systems 1511
J L Young, V Vedahaia, S Kung, S Xia and V Birss
Comparative Analysis ofThermal and Redox Cycling for Microtubular 1521
SOFCs
K Kendall, C M Dikwal and W Bujalski
xxn
Page 20
Microstructure and Effective Thickness of Cermet Anode for SOFC 1527H Fukunaga, T Ohno, C Aral, T Takatsuka andK Yamada
Microstructural and Electrochemical Study of Charge Transport and Reaction 1533
Mechanisms m Ni/YSZ Anode
I Bredikhin, V Simtsyn, A Aronin, I Kuritsyna andS Bredikhin
Effect ofGraded Porous Structure on Ni-YSZ Anode Performance 1541
K Jono, S Suda andM Eattori
Electrochemical and Microstructural Characterization of the Solid Oxide Fuel 1547
Cell Anode Prepared by Co-precipitationS Mosch, N Troflmenko, M Kusnezoff, T Betz andM Kellner
Influence ofComposite Structure on Electrochemical and Mechanical 1555
Properties of Thick Ni-YSZ Anode
K Sato, G Okamoto, H Abe andM Naito
Development ofFunctional SOFC Anode 1563
R Basu, J Mukhopadhyay, M Banerjee, A Das Sharma andE S Maiti
Experimental and Modeling Study of the Impedance ofNi/YSZ Cermet 1573
Anodes
S Gewies, W G Bessler, V Sonn andE Iveis-Tiffee
Nano-metal Dispersed Anode ofIntermediate-temperature SOFC for High 1583
Power Density OperationS Awatsu, E Iwasaki, K Isono, N Chitose, G Uozumi, T Inagaki and T
Ishihara
Investigation ofH2 and CO Oxidation on Ni-Ce02 Electrodes Using a 1591
Specially Designed Three-Electrode ConfigurationM Cimenti andJ M Eill
Electrochemical Behaviors ofMixed Conducting Oxide Anodes for SOFC 1601
T Nakamura, T Kobayashi, K Yashiro, K Sato, T Kawada andJ
Mizusaki
Influence of Mesoporosity ofthe Anode on the Characteristics of 1609
Mediumtemperature SOFC Single Cells
G Nurk, R Kungas, I Kivi, H Kurig, V Grozovsh, S Kallip andE Lust
xxin
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Electrochemical Performance ofNi-CGO Nano-Grained Thin Film Anodes 1617
for Micro SOFCs
U P Muecke, K Abba, T Salkus, N Stus and G J Ludwig
Synthesis and Electrical Characterization of the Ceramic Anode Lai- 1623
xSrxMnO 5Cr0 503
F C Fonseca, D Z de Floi to, E N Muccillo andR Muccillo
Synthesis and Study ofTi-0 Based Materials for SOFC Anode Application 1631
V Kozhukharov, Y V Tsvetkova, S Bebelis and V Kournoutis
Electrical Properties ofNb-Doped SrTi03 Ceramics with Excess Ti02 for 1639
Anodes and Interconnects of SOFCs
F Eorikiri, L Q Han, N Iizawa, K Sato, K Yashiro, T Kawada andJ
Mizusaki
A Novel Three Electrode Design for Electrochemical Investigations of an 1645
Intermediate Temperature SOFC
G Offer, D J Brett andN P Brandon
Effect ofEthene Impurity on Performance ofSolid Oxide Fuel Cell 1653
A Aarva, M Noponen andJ Kiviaho
Stability ofNickel-based Cermet Anode for Carbon Deposition during Cell 1661
Operation with Slightly Humidified Gaseous Hydrocarbon Fuels
K Yamaji, H Kishimoto, X Yueping, T Horita, N Sakai, M E Brito and
H Yokokawa
Direct Feeding ofLiquid Fuel m SOFC 1669
E Kishimoto, Y Xiong, K Yamaji, T Hoi ita, N Sakai, M E Bi ito andH
Yokokawa
Fuel Impurity Tolerance of Solid Oxide Fuel Cells 1675
K Sasaki, S Adachi, K Eaga, M Uchikawa, J Yamamoto, A Iyoshi, J
Chou, Y Shiratori andK I/oh
Recent Advances on the Development ofNiCu Alloy Catalysts for IT-SOFCs 1685
D LaRosa, M LoFaro, G Monfoite, V Antonucci, A Arico andA Sin
Electrochemical Activity of Ni 1-XCoX-Based Cermet Anode for Methane 1695
Oxidation
W Weerapakkaioon, K OgasaandK Sato
xxiv
Page 22
Microstructure and Electrochemical Properties ofNil-xMgxO-ScSZ Cermet 1701
Anodes for Biogas Fueled SOFCs
Y. Shiratori andK. Sasaki
Anode Performance ofNi/(Ce02)l-x(Ln01.5)x (Ln: Lanthanoids) in SOFCs 1711
Using Hydrocarbon Fuels
M. Asamoto, S. Miyake, A. Saito, H. Yamaura, H. Yahiro, Y. Itagaki and Y.
Sadaoka
Steam Reforming ofEthanol over Ni on High Surface Area Ceria Support: 1717
Influence ofRedox Properties on the Catalyst Stability and Product
Selectivities
N. Laosiripojana, S. Assabumnmgrat andS. Charojrochkul
SOFC Anodes for Direct Oxidation ofAlcohols at Intermediate Temperatures 1725
M. Cancellier, A. Sin, M. Morrone, P. Caracino, P. Sarkar, L. Yamarte, J.
Lome, M. Liu, E. Barker-Eemings, A. Caligiuri and C. Cavallotti
Power Generations ofRechargeable Direct Carbon Fuel Cells with Ni/GDC 1733
Anodes and Ni/ScSZ Anodes
M. Ihara, S. Hasegawa, H. Saito and Y. Jin
Development of Solid Oxide Fuel Cell Operated at Intermediate Temperature 1741for Direct Utilization of Dimethylether Fuel - Investigation ofAnode
CatalystsK. Takeuchi, Y. Ishida, R. Tai, K. Ui, N. Koura andH. Koyanaka
Effect of Steam on Direct Oxidation ofMethane over Pd-Ni Electrocatalyst 1745
Supported on Lanthanum Chromite Anode
I. Yamanaka, T. Ito, Y. Nabae andM. Hatano
Electrochemical Characteristics ofAnode with SrZr0,95Y0.05O3-a for 1753
SOFC in Dry Methane Fuel
Y. Jin, C. Levy, H. Saito, S. Hasegawa, K. Yamahara, K. Hanamura and
M. Ihara
Investigation ofComposite Ni-Doped Perovskite Anode for Direct Oxidation 1761
ofHydrocarbonsL. Massimiliano, D. La Rosa, G. Brunaccini, M. Minutoli, V. Antonucci
andA. Arico
Effect ofSpecific Surface Area and Zr Doping Content on Oxygen Storage 1769
Capacity (OSC) and Methane Steam Reforming Reactivity ofCeO2-Zr02
W. Sutthisripok, N. Laosiripojana andL. Sikong
XXV
Page 23
Chapter 6
Cell, Stack, and System Modeling
SOFC-MGT Hybrid System Using Natural Gas Mixed with Biomass Gasified 1781
Fuel
M. Sucipta, S. Kimijima andK. Suzuki
Electrical Interaction Model of Planar SOFC Stack Fed with Natural Gas 1791
Y. Bultel, L. Gautier, M Zahid, P. Stevens andJ. Klein
A New Approach for Elementary-Kinetic Modeling ofmtemal-Reforming 1801
SOFCs
W. G Bessler, S. Gewies andM. Vogler
Thermodynamic Analysis of a SOFC Aystem for CHP Applications: 1811
Influence ofOperation Parameters on Global EfficiencyA. Corradetti, U. Desideri, P. Lunghi andP. Lisbona
Dynamic Simulation Tool APROS in SOFC Power Plant Modeling at 1821
Wiirtsila and VTT
T Ollikainen, J. Saarinen, M. Halinen, T. Hottinen, M. Noponen, E.
Fontell and J. Kiviaho
Experiences with a CFD Based Two Stage SOFC Stack Modeling Concept 1831
and Its ApplicationD. Froning, L. Blum, A. Gubner, L. G. de Haart, M. Spiller andD. Stolten
Investigation of Locally Resolved SOFC Characteristics along the Flow Path 1841
P. Metzger, K. Friedrich, G. Schiller andH. Muller-Steinhagen
Experimental and Numerical Studies on Flow Uniformity in Interconnects 1849
and its Influence on a Single Planar Solid Oxide Fuel Cell
C. Huang, S. Shy andC. Lee
Numerical Study ofHeterogeneous Reactions in an SOFC Anode With 1859
Oxygen Addition
Y. Hao andD. G. Goodwin
Modeling Distributed Charge-Transfer Processes in Membrane Electrode 1869
Assemblies with Mixed-Conducting Composite Electrodes
H. Zhu andR. Kee
XXVI
Page 24
Three Dimensional Reconstruction ofSolid Oxide Fuel Cell Electrodes Using 1879
Focused Ion Beam - Scanning Electron MicroscopyJ. Wilson, W. Kobsiriphat, R. Mendoza, H. Chen, T. Hines, J. Hitter, D.
Miller, K. Thornton, P. Voorhees, S. Adler, D. R. Mumm andS. Barnett
A General Approach for Electrochemical Impedance Spectroscopy 1889
Simulation using Transient Mechanistic SOFC Model
Y. Shi, N Cai, C. Li, C. Bao, E. Croiset, J. Qian, Q. Hu andS. Wang
Numerical Simulation ofElectrochemical and TransportProcesses in Solid 1901
Oxide Fuel Cells
T. X. Ho, P. Kosinski, A. C. Hoffmann, I. Wmrnhus andA. Vik
Parameter Effects on Transport Phenomena in Conjunction with Internal 1909
Reforming Reactions in Intermediate Temperature SOFCs
J. Yuan and W. Wang
Numerical Analysis ofOutput Characteristics ofa Tubular SOFC with 1919
Different Fuel Compositions and Mass Flow Rates
Y. Barzi, M. Ghassemi, M. Hamedi andE. Afshari
A Neural Network Model in LaNixAH-x03 Catalyst for Methane Reforming 1929
in SOFC
S. Ciou, Y. Jhang, Y. Lai, F. Kuan-Zong, M. Hung andK. Chiang
Efficiency Analysis ofPlanar Solid Oxide Fuel Cell at Direct Internal 1939
Reforming Conditions
V. M. Janardhanan and O. Deutschmann
Simulation and Modeling Study of Anode-Supported Planar SOFC Operating 1945
with Synthesis Gas
R. Suwanwarangkul, K. Wattana, S. Charojrochkul, E. Croiset, P. L.
Douglas andE. Entchev
Modeling and Analysis of a Micro-Tubular Solid Oxide Fuel Cell (SOFC) 1955
Operating at Intermediate TemperaturesM. Serincan, A. L. Smirnova andN. M. Sammes
Analysis ofPerformance Characteristics of Intermediate-Temperature Disk 1967
Type SOFC Using Pure HydrogenT. Tanaka, T. Kanno, T. Nakamura, Y. Inui, N. Chitose, T. Miyazawa and
T. Akbay
Finite Element Analysis ofThermal Stress Distribution in Planar SOFC 1977
C. Lin, T. Chen, A. Chen, Y. Chyou andL. Chiang
xxvu
Page 25
A Simple Model for Prediction ofPolarization Loss Phenomena in a SOFC 1987
Stack
M. P. Heddrich, L. Dorrer, R. Dietrich, G. Borchardt and C. Argirusis
Oriented-Control Lumped Model ofa SOFC Stack: Thermal and 1995
Electrochemical Response to External Perturbations
A. Baratella, A. Corradetti, U. Desideri, P. Lisbona andP. Lunghi
Non-reacting Flow Distributions under Various SOFC Stack Configurations 2005
W. Wattana, J. Charoensuk, N. Phoocharoen andS. Charojrochkul
Numerical Modelling of Radiative Heat Transfer in an SOFC System 2013
G. Brus andJ. Szmyd
Reversible SOFC Model as a Base ofDesign and Testing 2021
W. Winkler
3-D Simulations ofCharge and Mass Distribution in Tubular SOEC 2031
J. Deseure, J. Klein, Y. Bultel andL. Dessemond
Micro-structural Modelling of SOFC Anodes 2041
J. Golbert, C. Adjiman andN. P. Brandon
Modeling ofSOFC Anodes Based on the Stochastic Reconstruction Scheme 2049
Y. Suzue, N Shikazono andN. Kasagi
Development ofThree-Dimensional Porous Structure Simulator for 2057
Optimizing Microstruclure ofSOFC Anode
M. Koyama, H. Tsuboi, N Hatakeyama, A. Endou, H. Takaba, M. Kubo,
C. A. Del Carpio andA. Miyamoto
3D-Modelling and Performance Evaluation of Mixed Conducting (MIEC) 2065
Cathodes
B. Riiger, A. Weber andE. Ivers-Tiffee
Non Linear Modeling ofMixed Ionic Electronic Conductors 2075
F. Gucci andD. G. Goodwin
Chapter 7
Electrolyte, Interconnection, and Sealing
Properties ofYttria Doped Zirconia Composites for Solid Oxide Fuel Cells 2085
S. Charojrochkul, S. Wannakitti, P. Limthongkul, J. Ueda andK Sato
xxvin
Page 26
Fabrication of Ccl-xGdxO2-0.5x Electrolytes with Tunable Dense 2093
Microstructures for 1T-SOFC ApplicationsV. Esposito, F. C. Fonseca, D. Z. De Florio, M. Zunic, R. Muccillo andE.
Traversa
Novel Design of Compressed Seal Gasket with Higher Thermo-Mechanical 2103
StabilityH. Lee, S. Kim, H. Kim, H. Jung, H. Jung, J. Lee, H. Song andJ. Lee
P/M Processing and Coating Technologies for Fabrication ofInterconnect for 2109
Stationary and Mobile SOFC ApplicationsA. Venskutonis, G. Runscherl, E. Mueller andH, Hoehle
Stability of Oxidation Resistance of Ferritic Fe-Cr Alloy for SOFC 2117
Interconnects
A. TojiandT. Uehara
Evaluation of Selected Interconnect Alloys at Versa Power Systems: 2125
Laboratory Screening and In-stack TestingS. Benhaddad, J. Protkova, W. Dueck and S. Sherman
Oxidation Behavior and Conductivity ofUNS 430 Stainless Steel and Crofer 2135
22 APU with Spinel CoatingsP. Wei, X. Deng, M. R. Bateni andA. Petrk
Initiation and Performance of a Coating for Countering Chromium Poisoning 2145in a SOFC-stack
K. Nielsen, A. Persson, D. Beeaff J. Hagh, L. Mikkelsen andP. V.
Hendriksen
Study on the Ohmic Resistance of Solid Oxide Fuel Cells Based on YSZ 2155
Membrane Fabricated by Slurry Spin CoalingZ M J. Wang, K. Chen, X. Huang, N. Ai, R. Zhu and W. Sit
Composition Effects in YSZ Electrolyte Tapes for Solid Oxide Fuel Cells 2161
Fabricated By Tape CastingC. Chen, L. Liau, G. Jung andS. H. Chan
Sol Gel Synthesis of Nano-Sized Powder Precursors for Y203-HfO2-ZrO2 2167
Ceramics
S. Vladimirovich, E. A, Ivanovo and V. G. Konakov
Sintering of Thin Zirconia SOFC Electrolyte Films 2175
R. Milcke, N. H. Menzler, II. Buchkremer andD. Stoever
xxix
Page 27
Fabrication of Porous Structure with Scandia Stabilized Zirconia Electrolyte 2187
for Solid Oxide Fuel Cell
D. Peck, Y. Choi, S. Woo, R. Song, J. Wackerl and T. Markus
Synthesis ofZr02-Sc203 Nanopowders by Gel-Combustion Routes 2197
P. M Abdala, R. KempfandD. G. Lamas
Processing and Properties of Scandia-doped Zirconia Electrolyte for 2207
Intermediate Temperature SOFC
R. Singh andS. B. Chavan
A Comparison and Characterization ofCe02-doped and Bi203-doped 2213
Scandia Stabilized Zirconia as IT-SOFC ElectrolytesB. Bai, W. A. McPhee, A. L. Smirnova andN. M. Sammes
High Sinterability Doped Scandia Zirconia Powders 2223
E. de Carvalho andJ. T Irvine
Mechanical Properties of Ceria-doped Scandia-stabilized Zirconia Electrolyte 2233
Coatings for SOFCs
X. Zhang, A. L. Smirnova, N. M Sammes, E. Brodnikovskii and O.
Vasylyev
Microstructure and Electrical Conductivity of Ce0.85Y0.15-xRExO2-/ 2239
(RE=Pr,Tb)S. K. Tadokoro andE. N Muccillo
Study ofPr-doped Ceria-based Electrolytes for IT-SOFC 2245
M. Chen, S. Cheng, F. Wang, J. Lee andY. Tai
Nano-scale Analysis of Low Temperature Solid Oxide Fuel Cell Electrolytes 2253
S. Lee, C. Cheng, W. Chen and C. Hong
Structural and Electrical Properties ofGadolinia-doped Ceria Mixed with 2261
Alkali Earth Carbonates for SOFC ApplicationsM. Benamira, V. Albin, A. Ringuede, R. Vannier, A. Boden, C. LagergrenandM Cassir
Sintering Mechanism ofCuO-doped Ce0.8Gd0.2O2-5 Ceramics 2269
P. Mangifesta, A. Sanson andE. Roncari
Effect ofSintering Aids on the Formation of Zirconia-Ceria Solid Solution 2277
C. Deces-Petit, X. Zhang andR. Marie
xxx
Page 28
Ionic Conductivity in Lanthanoid Ion-doped BaCe03 Electrolytes 2283J. Kikuchi, S. Koga, K. Kishi, M. Saito and J. Kuwano
Development of Proton Conducting Thin Films from Nanoparticulate 2291Precursors
G. Taillades, M. Jacquin, Z. Khani, D. Jones, M. Marrony andJ. Roziere
Ceramic Protonic Electrolyte Supported Fuel Cell for Operationwith 2299Methane and Ethanol
R. Muccillo, 0. R. Oliveira, E. dos Santos, D. Z. de Florio, F. C. Fonseca
andE. N. Muccillo
Fabrication ofAnode Supported Direct Ammonia Solid Oxide Fuel Cells 2305Based on Proton Conducting Y-doped BaCe03 Electrolyte
Y. Yoo, M. Tuck, N. Lim, A. McFarlan andN Maffei
SrZrl-xYx03 Coatings Elaborated by DC Magnetron Sputtering 2313
A. Pour Yazdi Mohammad, P. Briois, F. Lapostolle andA. Billard
Improvement in Sintering of Barium Zirconate by Doping with Scandium 2321
S. Imashuku, T. Udaand Y. Awakura
Performance of BaZr03 based Proton Conductors as an Electrolyte for 2331
Intermediate Temperature Operating SOFC
F. Iguchi, T. Tokikawa, T. Miyoshi, T Tsurui, Y. Nagao, N Saia andH.
Yugami
BaZrxYl-x03-d and BaCel-x-zZrxYz03-d Proton Conductors For 2337
Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFCs)A. DEpifanio, E. Fabbri, E. DiBartolomeo, S. Licoccia andE. Traversa
Design and Evaluation ofSOFC Based on BaIn0.3Ti0.7O2.85 Electrolyte 2343
and Ni/BaIn0.3Ti0.7O2.85 Cermet Anode
D. Prakash, T. Delahaye, O. Joubert, M. Caldes, Y. PiffardandP. Stevens
Synthesis of Lanthanum Silicates Electrolyte for Intermediate Temperature 2351
SOFC
W. Gao, C. Zhang, F. Lapostolle, H. Liao, V. Ji andC. Codden
Effect ofY203 Addition on Crystal Structure and Electrical Conductivity of 2357
W03 Doped B1203 Solid ElectrolyteC. Hsieh andK. Fung
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Oxide Scales ofModified Fe-Cr Alloy (Low Si and Al Concentrations) m 2363
Reducing AtmospheresT Horita, Y Katsuhiko, N Sakai, H Yokokawa, A Toji, T Uehara, T
Seo, K Ogasawara, H Kameda, Y Matsuzaki andS Yamashita
Carbunzation Resistance ofNb Added-16Cr Alloy at 1073 K 2371
T Ito, M Veda, K Kawamttra andT Mantyama
Oxidation Studies on Crofer 22 APU Alloy Under Simulated SOFC 2379
Operating Conditions
W Huang, S Gopalan, U B Pal andS N Basu
Effects of REM Coatings on Electrical Conductivity of Ferntic Stainless 2385
Steels for SOFC Interconnect ApplicationsJ Jun, D Kim andJ Jun
Electrodeposition of Cena on Stainless Steel for SOFC Interconnect 2391
ApplicationsH Elbelghiti, V Lair, A Rmguede and M Cassir
Use ofSOFC Metallic Interconnect Coated with Spinel Protective Layers 2399
using the APS TechnologyM Vargas, M Zahid, F Tietz andA Aslamdes
Ceramic PVD Coatings as Dense/Thm Barrier Layers on Interconnect 2407
Components for SOFC ApplicationsG Kunschett, S Schhchtherle, G N Stiauss andK Kailer
Analysis ofStructural Phase Transition Behavior ofLal-x-yCaxSryCr03 2417
A Mitsui, K Homma, Y Kumekawa, F Nakamura, N Ohba and T
Hashimoto
Investigation of Electrical Conductivity and Oxidation Behavior ofTiC and 2427
TiN Based Cermets for SOFC Interconnect ApplicationY Pang, H Xie andR Koc
Development of Insulating and Conductive Seals for Controlled Conduction 2437
Paths
S Suda, K Kawahaia andK Jono
Tailor-made BaO-CaO-A1203-Si02-based Glass Sealant for Anode- 2443
supported Planar SOFC
R Basu, S Ghosh, A Das Sharma, P Kundu andII S Maiii
Author Index 2453
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