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Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate School of Pure and Applied Sciences, University of Tsukuba November 2018 in OSHIO Lab, Tsukuba City, Japan Supervised by: Professor Rachid TOUZANI Professor Hiroki OSHIO Professor Takuya SHIGHA ACKNOWLEDGMENTS First, I am thankful and grateful to Almighty Allah for the good health, compassionate, wellbeing and helping that were necessary to complete this internship at OSHIO Lab at Tsukuba University, Tsukuba City a lovely city. I would like to express my deepest gratitude to Prof. Hiroki OSHIO, for his excellent guidance, encouraging and for providing me with an excellent atmosphere for doing research. I place on record, my sincere thanks to my supervisor Prof. Rachid Touzani, for assisting in numerous ways, valuable pieces of advice and help. Special Thanks to Prof Takuya SHIGHA for quality for their encouragement, support, and guidance, which helped us in successfully completing this internship. My sincere thanks go also to Prof Smaail Radi, dean of faculty of science at Mohamed First University (Oujda Morocco) and Prof Hammouti for valuable advice and help. My sincere thanks also goes to Prof OUSSAID Adyl for his help. I am extremely grateful to all the worthy staff members of OSHIO Lab, for their helpful attitude and constant support, especially, Doc. WEI Rong Jia, JSPS Foreign Researcher, Masayuki NIHEI. I would like to extend our sincere esteems to all staff in a laboratory for their timely support during my internship, Prof. Rie MIURA, Secretary, and all PhD and Master Students.
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Page 1: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Internship report

Training of Abderrahim TITI in Coordination chemistry laboratory

Graduate School of Pure and Applied Sciences, University of Tsukuba

November 2018 in OSHIO Lab, Tsukuba City, Japan

Supervised by: Professor Rachid TOUZANI

Professor Hiroki OSHIO

Professor Takuya SHIGHA

ACKNOWLEDGMENTS

First, I am thankful and grateful to Almighty Allah for the good health, compassionate,

wellbeing and helping that were necessary to complete this internship at OSHIO Lab at

Tsukuba University, Tsukuba City a lovely city.

I would like to express my deepest gratitude to Prof. Hiroki OSHIO, for his excellent

guidance, encouraging and for providing me with an excellent atmosphere for doing research.

I place on record, my sincere thanks to my supervisor Prof. Rachid Touzani, for assisting in

numerous ways, valuable pieces of advice and help.

Special Thanks to Prof Takuya SHIGHA for quality for their encouragement, support, and

guidance, which helped us in successfully completing this internship.

My sincere thanks go also to Prof Smaail Radi, dean of faculty of science at Mohamed First

University (Oujda Morocco) and Prof Hammouti for valuable advice and help.

My sincere thanks also goes to Prof OUSSAID Adyl for his help.

I am extremely grateful to all the worthy staff members of OSHIO Lab, for their helpful

attitude and constant support, especially, Doc. WEI Rong Jia, JSPS Foreign Researcher,

Masayuki NIHEI.

I would like to extend our sincere esteems to all staff in a laboratory for their timely support

during my internship, Prof. Rie MIURA, Secretary, and all PhD and Master Students.

Page 2: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

OSHIO Lab

The Oshio lab is a complex systems and coordination chemistry group based at the

University of Tsukuba, Japan. The group is involved in a wide range of areas, which can be

broadly grouped as ‘Responsive Molecular Systems’, ‘Coordination Architectures’ and

‘Functional Molecular Oxides’. A bistable system can rest in two stable phases, at free energy

minima, and switching between the phases can be achieved by the application of external

stimuli such as temperature/light/pressure/host-guest interactions... Bistable molecules have,

therefore, attracted intense research interest due to their potential applications in molecular

switches and memory devices, for which spin-crossover (SCO) and electron transfer–active

chromophores are promising building blocks. Multi-component materials, in which each

component exhibits different bistability, can be expected to show synergistic properties, such

as stepped phase transition and selective excitation to meta-stable states and may function as

multibistable molecular switching systems.

Group

Hiroki OSHIO, Professor Ph.D 1982, Kyushu Univ. Laboratory of Advanced Research B606 oshio_atto_chem.tsukuba.ac.jp tel : +81-29-853-423

fax : +81-29-853-4238

Page 3: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Hiroki Oshio graduated from Kyushu University in 1977 and obtained his Ph.D. in 1982.

After a postdoctoral fellowship at Marquette University between 1982 and 1984, he was

appointed as a research associate at the Institute for Molecular Science (Okazaki, Japan) in

1985. In 1992 he moved to Tohoku University as an Associate Professor, before he was

appointed as a Professor at the University of Tsukuba in the Graduate School of Pure and

Applied Sciences in 2001. His research has focused on molecular magnetism, including

bistable and spin-crossover systems. He received the CSJ Award for Creative Work (2005)

and has accumulated over 200 peer-reviewed research publications.

Rsearch Fieds Coordination Chemistry

Inorganic Chemistry

Academic Society

Chemical Society of Coordination Chemistry

Award

2016/06 Japan Society of Coordination Chemistry Award for 2016 2006/03

the Chemical Society of Japan Award for Creative Work for 2005

Masayuki NIHEI, Assoc. Prof. Ph.D 2002, Tokyo Univ. nihei_atto_chem.tsukuba.ac.jp tel : +81-29-853-4426

fax : +81-29-853-4426

Takuya SHIGA, Assist. Prof. Ph.D 2004, Kyushu Univ. shiga_atto_chem.tsukuba.ac.jp tel : +81-29-853-5923

fax : +81-29-853-4426

WEI Rong Jia, JSPS Foreign Researcher Laboratory of Advanced Research B622 rongjwei_atto_chem.tsukuba.ac.jp tel : +81-29-853-4426

fax : +81-29-853-4426

Page 4: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Lab Information

Transition Metal Complexes...

The assembly of designable organic

ligands and transition metal ions

with variable electronic states

Research Areas

Responsive Molecular Systems

Coordination Architectures

Functional Molecular Oxides

Experimental Facilities X-ray Bruker APEX I

X-ray Bruker APEX II

SQUID Magnetometor MPMS 5XL

iHe3 Low temperature unit

Physical Property Measurement System PPMS

Mossbauer Spectrometer

UV-Vis-NIR Spectrometer Shimadzu

FT-IR Spectrometer Shimadzu

Electrochemical Property Measurement System BAS

Thermogravimetry measurement System Perkin-Elmer TG

Glovebox

Multiple Fume cupboards

Experimental room

Page 5: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Training :

Synthesis of a series of polynuclear materials (clusters

mono and bimetallic)

Measurements of infrared spectra

Measurements of single crystal of X-ray diffraction

Some Papers

Synthesis of novel Cl2Co4L6 cluster using 1-hydroxymethyl-3,5-

dimethylpyrazole (LH) ligand: Crystal structure, spectral, thermal,

Hirschfeld surface analysis and catalytic oxidation evaluation Abderrahim Titia, Takuya Shigab, Hiroki Oshiob,*, Rachid Touzania, Belkheir

Hammoutic, Messali Mouslimd, Ismail Warade,f

https://doi.org/10.1016/j.molstruc.2019.126995

Synthesis, characterization, X-Ray crystal study and bioctivities of pyrazole

derivatives: Identification of antitumor, antifungal and antibacterial

pharmacophore sites

AbderrahimTitia,MouslimMessalib,BakhetA.Alqurashyc,RachidTouzania,TakuyaShigad,

Hirok iOshiod,MohammedFettouhie,MehdiRajabif,Faisal, A.Almalkig,TaibiBen Haddaa,g

aLaboratory of Applied and Environmental Chemistry, Mohammed First University, (LCAE), Oujda, Morocco

bDepartment of Chemistry, Taibah University, 30002, Al-Madina Al-Mounawara, Saudi Arabia

cDepartment of Basic Science and Technologies Community Faculty, Taibah University, 30002, Al-Madina Al-

Mounawara, Saudi Arabia

dGraduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki, 305

8571, Japan

eDepartment of Chemistry, King Fahd University of Petroleum and Minerals, P.O. Box 5048, Dhahran, 31261,

Saudi Arabia

fSchool of Sciences, University of Louisiana at Monroe, 700 University Ave, Monroe, LA, 71209, USA

gDepartment of Pharmaceutical Chemistry, Faculty of Pharmacy, Umm Al-Qura University, Makkah

Almukkarramah, Saudi Arabia

https://doi.org/10.1016/j.molstruc.2019.127625

Synthesis and XRD of novel Ni4(µ3-O)4 twist cubane cluster using three

NNO mixed ligands: Hirshfeld, spectral, thermal and oxidation properties

Abderrahim Titia*, Hiroki Oshiob, Rachid Touzania, Messali Mouslimc, Abdelkader

Zarroukd, Belkheir Hammouti,a Nabil Al-Zaqrie, Ali Alsalmee, Ismail Waradf,h*

aLaboratory of Applied and Environmental Chemistry (LCAE), Mohammed first University, Oujda, Morocco. bGraduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-

8571, Japan.

Page 6: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

cDepartment of Chemistry, Faculty of Science, Taibah University, Al-madinah Al-munawarah, Saudi Arabia. dLaboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University, Av.

Ibn Battouta, Box 1014 Agdal-Rabat, Morocco eDepartment of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi

Arabia fDepartment of Chemistry and Earth Sciences, PO Box 2713, Qatar University, Doha, Qatar. hDepartment of Chemistry, Science College, An Najah National University, P.O. Box 7, Nablus, Palestine

under soumission

Some nice of Clusters Structures of Single X-Ray Analysis.

Page 7: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Some nice pictures at Tsukuba University

University of Tsukuba – Entrance

Oshio Lab is inside this building

University of Sciences

Page 8: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Picture at the Center of Tsukuba University

Working inside Oshio lab

Page 9: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

An invite to a Sushi meal from Mr. Oshio Hiroki

Page 10: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Memorable moments at Fish market and Sushi bar Ōarai,

Ibaraki with Group Oshio Lab

Page 11: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate
Page 12: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate
Page 13: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Pictures Taken During my Visit to Tsukuba Space Center

Page 14: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

Finally, I share with you some Pictures of this Beautiful City.

Page 15: Internship report - jmaterenvironsci.comjmaterenvironsci.com/Document/Report of japan.pdf · Internship report Training of Abderrahim TITI in Coordination chemistry laboratory Graduate

During my stay at the laboratory of Oshio in the

Japanese University of Tsukuba, I have benefited

greatly from their expertise in the field of Chemistry;

specifically, in Organometallic chemistry. Moreover, I

have had the pleasure to receive a personal training in

Apex II, the machine that measures single crystal of

X-ray diffraction. My findings allowed me to produce

more than three scientific papers. Furthermore, I have

got to experience and discover the Japanese culture,

its values, its kitchen and its heritage.


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