Ion Exchange Resins Product List

Ion Exchange Resins Product List

Leading manufacturer of

UPS lon Exchange Resins

www.samyangtrilite.com

3Ion Exchange Resins Product List

No.1 Total Solution Provider

Samyang presents the full line-up of TRILITE Ion Exchange Resins from water treatment up to specialty

applications. Samyang develops Tailored resins optimized for customer needs and provides differentiated

technical services such as on-site visit for troubleshooting, technical seminars, process diagnosis, and design

consulting, etc. Also, Samyang IER Tech-center offers various analysis services for IERs and develops advanced

application technologies.

Locations (HQ, Plant, Tech-center of TRILITE)

Seoul (Head Office)

■ Technical sales force in 3 fields

- Demineralization/Ultrapure water /

Condensate polishing/Catalyst

- Food/Amino acids/Pharmaceuticals

- Wastewater/Chelating resins/

Purification

■ One Stop Service

- Analysis of IER

- Equipment diagnosis and design

support

- Technical seminars and trouble

shooting guides

Daejeon (Tech-center)

■ Analysis of IER

■ Recipe improvement of IER

■ New product development

- Tailored/Specialty resins

■ Application process development

- Pilot test

- Engineering data gathering

- Process proposal

Gunsan (UPS Resin Plant)

■ Samyang Fine Technology

(Joint venture with Mitsubishi

Chemicals)

■ Asia's largest manufacturing

capacity for UPS resins

■ Annual production capacity

- Cation 13,000㎘, Anion 7,000㎘

■ Product lines

- Uniform particle sized resins

- Chromatography resins

- Ultrapure water grade resins

(LCD, OLED)

Ulsan (UPW/Tailored/ Specialty Resin Plant)

■ Technology licensed by Mitsubishi

Chemicals & Self-development

■ Specialized production

of Tailored resins

■ Annual production capacity

- Cation 4,000㎘, Anion 3,000㎘

■ Product line

- Ultrapure water grade resins

(Semiconductor)

- Tailored resins : food, catalyst,

pharmaceuticals

- Specialty resins: chelating resins,

synthetic adsorbents, refining of

chemicals

Samyang Corporation Ion Exchange Resin Team

TEL : +82 2 740 7732~7

E-mail : [email protected]

http://www.samyangtrilite.com

Samyang Corporation is the history of Ion Exchange Resins in Korea

In 1976, Samyang Corporation successfully

initiated localized production of IER in South

Korea by technical cooperation with Mitsubishi

Chemical Corporation, Japan. In 2011, with

successful development of UPW (Ultrapure

water) grade resins, we are contributing to

enhancing national competitiveness in the

semiconductor and the display industries.

In 2016, Asia's largest UPS (Uniform Particle

Sized) specialized IER (Ion exchange resin)

plant; Samyang Fine Technology Corporation

was founded. TRILITE is being supplied to the

global market and is receiving rave reviews

from the users.

4 5Ion Exchange Resins Product List Ion Exchange Resins Product List

Uniformity of IER enlarges its Performance

TRILITE UPS resins are renowned in the industry for the consistent uniformity coefficient, which is directly

related to high performance. TRILITE UPS resins are manufactured under the strict quality control to ensure

optimized size of the resins, enabling extremely even reactions. UPS resins give an extremely even exhaustion

front of resins in the vessel, hence the operating capacity is enhanced. Also, it has outstanding mechanical and

chemical stability, leading to remarkably low crush rate even after long-term use.

Samyang TRILITE represents Next Generation Ion Exchange Resin

TRILITE UPS resin has adopted state-of-the-art Droplet generating technology for polymerization, differentiated

from the prevailing mechanical sieving of polymers and conventional polymerization technology. Premium grade

TRILITE Ion Exchange Resins are manufactured from the newest UPS IER plant in the world. TRILITE satisfies high

quality standards; Uniformity coefficient of TRILITE is under 1.1 with high mechanical and chemical stability.

Higher Operating Capacity, Reduction of Rinse Volume,

Longer Life Time of IER

Improved Kinetics, Fast Reaction Speed Excellent Physical & Chemical Strength+

(Raw Material Adjustment)

(Polymerization - Droplet Generator)

(Post-treatment – Functional group)

STM(Styrene Monomer)

DVB(Divinyl Benzene)

CH = CH₂ CH = CH₂

CH = CH₂

+

UPS(Uniform Particle Sized)Technology

(Raw Material Adjustment)

(Polymerization - Agitation)

(Post-treatment – Functional group)

STM(Styrene Monomer)

DVB(Divinyl Benzene)

CH = CH₂ CH = CH₂

CH = CH₂

+

Conventional Technology

Gaussian resin gives diffused

exhaustion front

UPS resin gives an extremely

even exhaustion front

Gaussian Resin

Next Generation IER, High Performance Low CostCutting-edge Technology Droplet Generator

(Packing)

60

50

40

30

20

10

0

UniformityCoefficient

1.1↓

200 400 600 800 1000

(Packing)

60

50

40

30

20

10

0200 400 600 800 1000

(%) (%)

(㎛) (㎛)

Lower Running Cost and Capital Expenditure

UPS Resin

UniformityCoefficient

1.6↓

Service Volume (Bed Volume)

UPS Resin (Mixed)

Gaussian Resin (Mixed)

30

25

20

15

10

5

0

0 10 20 30 40 50 60 70 80 90 100 110 120

Co

nd

uc

tivi

ty

(㎲/㎝

)

25 50 75 100 125 150

1.5

1.3

1.1

0.9

0.7

Op

era

tin

g C

ap

ac

ity

(eq

/ℓ-R

esi

n)

Specific Flow Rate (SV)

UPS Resin (SAC)

Gaussian Resin (SAC)

6 Ion Exchange Resins Product List

Classification of Ion Exchange Resin

SpecialtyAnion InertCation

SAC WAC SBA WBAChelating

resinsSynthetic adsorbents

For packed bed system,

mixed bed polisher

Functional Group

Mixing,

DryCatalyst

Nucleic Acid,

LysineUPW

Tailored Resin

UPS

(0.5 ~ 0.6mm)

Gaussian L-type(L)

(0.425 ~ 1.2mm)

Chromatography

(0.2 ~ 0.3mm)

Particle Distribution, Size

Gaussian

(0.3 ~ 1.2mm)

High

Crosslinkage

Crosslinkage

Low

Crosslinkage

* Crosslinkage : Divinylbenzeze versus total monomers in weight/weight (%)

Strongly acidic cation

Stronglybasic anion

Weakly acidic cation

Weaklybasic anion

Porous type

(Macropore)

Porosity

Gel type

(Micropore)

Micropore <100Å

Gel

Macropore 10Å<, <1000Å

Porous

Water treatment· Softening / Demineralization

· Condensate polishing

· Nuclear power

Ultrapure water

Catalyst

Chromatography separation

· Fructose / Glucose separation

· Amino acid separation / purification

· Acid purification

Food· Starch sugar refining

· Sugar refining

· Nucleic acid, Lysine separation / purification

Chelating resins· Secondary brine purification

· Wastewater treatment

Synthetic adsorbents

Ready to use mixed resins

Inert resins

Layered bed anion resins

EO/EG cycle water treatment

Contents


Various types of water treatment systems (softening, demineralization) are adaptable according to the types

of IERs, service/regeneration direction of solution and combination of IER towers. An appropriate system is

recommended under the conditions of raw water and required water quality.

TRILITE IER consists of the most efficient line-ups for various types of softening and demineralization of water.

It results in cost-effective, high performance of water treatment with remarkably high operating capacity and

high mechanical and chemical stability.

The Performance line-up realizes the high quality of performance, being manufactured from the

specialized UPS resin plant with state-of-the-art technology, Samyang Fine Technology Corporation.

The Basic line-up realizes the high-quality performance, being manufactured from the Samyang

Corporation Ulsan Plant.

The economy line-up proves the cost-effectiveness and the high quality, being manufactured

under the strict quality assurance system.

Water Treatment

Particle Size, Distribution, Uniformity Coefficient

Gaussian - Particle Size : 0.3 ~ 1.2mm

- Uniformity Coefficient : 1.6 ↓

Gaussian L-type(L) - Particle Size : 0.425 ~ 1.2mm


UPS - Particle Size : 0.5 ~ 0.6mm


Classification by regeneration system

Co-current regeneration

system

Counter-current regeneration system

Water blocking system

Packed bed

Upflow system Downflow system

Gaussian Gaussian or L-type UPS

Service Regeneration

IER

FreeboardMiddle Distributor

IER

Freeboard

IER

FreeboardIER

Freeboard

Classification by IER layer

Single

bed

Layered

bed

Mixed

bed

SAC WAC SBA WBA

SAC

WAC

SBA

WBA

SAC

SBA

TRILITE Water Treatment IER Line-up

UPS

Performance

Product Line

UPS(Samyang

Fine Technology)

1.1 ↓

Basic

Product Line

Gaussian(Samyang

Ulsan Plant)

1.3~1.6 ↓

Gaussian(OEM)

1.3~1.6 ↓

Economy

Product Line

UPS(OEM)

1.1~1.2 ↓

Type Weakly acidic cation resins (WAC) Weakly basic anion resins (WBA)

Gaussian, UPS Porous

WCA10L 4.2↑ 0.425~1.2

WBA

AW90 1.6↑ 0.50~0.60

UPSPorous

AW80 1.6↑ 0.40~0.60

GaussianPorous

AW30L 1.5↑ 0.425~1.2

Functionalgroup

(Polyacrylate+DVB) + Carboxylate (Polystyrene+DVB) + Tertiary Amine

Economy

Performance

Basic

Type

Strongly acidic cation resins (SAC) Strongly basic anion resins (SBA)

Gradename

TEC(eq/ℓ)

Particledistribution(㎜)

TypeGradename

TEC(eq/ℓ)

Particledistribution(㎜)

UPS Gel

MC-08 2.0↑ 0.55~0.65

Type1

MA-12 1.3↑ 0.53~0.63

MC-08H 1.8↑ 0.57~0.67 MA-12OH 1.0↑ 0.57~0.67

MC-10 2.2↑ 0.60~0.70 MA-10 1.35↑ 0.50~0.60

MC-10H 2.0↑ 0.61~0.71 MA-10OH 1.1↑ 0.54~0.64

MC-14 2.5↑0.60~0.70

MA-15 1.4↑ 0.55~0.65

MC-14H 2.4↑ MA-15OH 1.2↑ 0.58~0.68

Type2 MA-20 1.3↑ 0.53~0.63

Gaussian Gel

SCR-B 2.0↑

(General type)0.3~1.2(L-type)

0.425~1.2

Type1SAR10(MB) 1.3↑


0.425~1.2

SAR12 1.3↑

Type2 SAR20(MB) 1.3↑

UPS Gel UKC-08 2.0↑ 0.55~0.65 Type1 UKA-12 1.3↑ 0.55~0.65

UKC-10 2.2↑ 0.60~0.70

UKC-12 2.3↑ 0.60~0.70

Gaussian Gel

KC-07 1.9↑


0.425~1.2

Type1KA-10(MB) 1.3↑


0.425~1.2

KH-70 1.9↑ KA-12 1.3↑

KC-08 2.0↑ Type2 KA-20(MB) 1.3↑

KH-80 2.0↑

Functionalgroup

(Polystyrene+DVB) + Sulfonate(Polystyrene+DVB) +

Type1 : TMA, trimethylamineType2 : DMEA, dimethylethanolamine

Economy

Economy

Performance

Performance

Basic

Basic

※ Uniformity Coefficient : An unit measuring uniformity of IERs. A coefficient closer to 1.0, the particle size more uniform.


Demineralization system

Demineralization system LINE SAC SBA WAC WBA

2B2T (2Bed 2Tower) Cation Exchanger+ Anion Exchanger

2B3TCation Exchanger+ Degasifier+ Anion Exchanger

PerformanceMC-08MC-10

MA-12MA-20

Basic SCR-BSAR10SAR20

EconomyUKC-08UKC-10KC-08

UKA-12KA-12KA-20

Working MB (Mixed Bed)

Performance MC-08 MA-20P

Basic SCR-B SAR20MB

2B2T or 2B3T +MBP(Mixed Bed Polisher)

Performance MC-08MC-10

MA-10P

Basic SCR-B SAR10MB

3B3T + MBP


KA18LB AW90

Basic SCR-B KA18LB AW80

EconomyUKC-08UKC-10

KA18LB AW30L

4B3T + MBP


KA18LB WCA10L AW90

Basic SCR-B KA18LB WCA10L AW80

EconomyUKC-08

UKC-10KA18LB WCA10L AW30L

4B3T + MBP + CPP(Condensate Polishing)

Performance MC-10H

MC-14H

MA-10OH

MA-15OH

※ D : Degasifier ※ Anion grade name + (P), (MB) means the anti-clumping treatment. Anion resin used for MB or MBP requires anti-clumping

treatment that helps separation of cation and anion.

SAC SBA

SAC

SBA

SAC SBASAC

SBA

SAC SBAD※

SAC SBASAC

SBAD

SAC

WAC

SBA

WBA

SAC

SBAD

SACSBA

WBA

SAC

SBAD

SAC

WAC

SBA

WBA

SAC

SBA

SAC

SBAD Conden-

ser

Softening

NSF Test method

50 ㎖ of ion exchange resin is put into 100 ㎖ of water at 70℃ for 2 hours, and APHA(unit of chromaticity) is

measured with a visible spectrophotometer.

IER Grade Spec. Day 1 Day 2 Day 3 Day 4 Day 7

KH-80 Food < 25 12 13 13 13 14

SCR-B Tech - 145 149 153 160 183

SCR-BL Tech - 53 55 191 257 347

Food grade softening

When food grade softening is required, it is needed to select a suitable food grade ion exchange resin. Examples

are as follows.

Sodium hypochlorite(NaClO), Free chlorine(Cl2), Ozone(03)

When softeners are used with

oxidizing agents such as sodium

hypochlorite or free chlorine, it

is recommended to use highly

crossl inked strongly acidic

cation ion exchange resin with

high resistance to oxidation.

IER SelectionClO2

Concentration

Cl2 or O3

Concentration

MC-08

0.1ppm↓ 0.2ppm↓SCR-B

UKC-08, KC-07, KC-08

MC-100.15ppm↓ 0.3ppm↓

UKC-10

UKC-12 0.2ppm↓ 0.4ppm↓

Economy

Economy

Economy

Performance

Performance

Basic

Softening system Line SAC SBA WAC WBA

Softening(Industrial grade)

MC-08

MC-10

SCR-B

UKC-08

UKC-10, UKC-12

KC-07, KC-08

Softening

(Food grade)

KH-70

KH-80

Performance

Economy

Economy

BasicSAC

SAC

NSF certifiedTRILITE KH-80

KH-80 SCR-B SCR-BL


Typical power plant steam turbine loop and IER selection

Ion exchange resins for thermal power plant are classified by applications: Make-up system, condensate

polishing, etc. Various combinations of demineralization are adaptable for Make-up system for the power plant.

For condensate polishing plant (CPP), premium grade IERs are required with high operating capacity, high

operating temperature, and mechanical and chemical stability.

TRILITE IERs own various supply references to domestic and foreign thermal power plants hence contributing

to the competitive power supply for customers, with stable quality control and on-time delivery of resins.

Ion exchange resins for nuclear power plant are classified by applications: Make-up system, condensate

polishing and primary circuit for the nuclear power plant. For the primary circuit in the nuclear power plant,

IERs are exposed to radiation. Use of high crosslinkage IERs with low impurities, high mechanical and chemical

stability is highly recommended.

TRILITE IERs own various supply references to domestic and foreign nuclear power plants hence contributing

to the competitive power supply for customers, with stable quality control and on-time delivery of resins.

Pressurized water reactor type nuclear power plant steam turbine loop and IER selection

Power Plants - Thermal Power Plants - Nuclear

Classification

Nuclear grade resins for primary circuit


TypeGradename

TEC (eq/ℓ)Particle

distribution (㎜)Type

Gradename


distribution (㎜)

UPS

Gel MCN116K 2.4↑ 0.60~0.70 Gel type1 MAN210K 1.2↑ 0.58~0.65

MMN316K / Mixed Resin ratio = 1 : 1 as same equivalent (MCN116K : MAN210K)

Classification

Condensate polishing resins


TypeGradename


distribution (㎜)Type

Gradename


distribution (㎜)

GaussianPorous CMP28L 2.05↑

0.425~1.2Poroustype1

AMP18L 1.3↑0.425~1.2

CMP28LH 1.8↑ AMP18LOH 1.1↑

UPS Gel

MC-10 2.2↑ 0.60~0.70

Geltype1

MA-10 1.35↑ 0.50~0.60

MC-10H 2.0↑ 0.61~0.71 MA-10OH 1.1↑ 0.54~0.64

MC-14 2.5↑0.60~0.70

MA-15 1.4↑ 0.55~0.65

MC-14H 2.4↑ MA-15OH 1.2↑ 0.58~0.68

Storagetank

Condensate polisher

Conden-sate

storage

SAC(H form)

SAC

SBA

Containment structure

Condenser

LP Heater

DeaeratorHP

Heater

GeneratorLPTurbine

HPTurbine

Raw water

Make-up demineralization system

SAC

WAC

SBA

WBA

SAC

SBA

Conden-sate

storageSAC(Li form)

SBA(OH form)

Degasifier

Steam generator

Nuclear reactor

Primary circuit

Secondary circuit

Nuclear Grade

Containmentstructure

Conden-sate

storage

SAC

SBA

Condensate polisher

Boiler

Reheater2nd

Superheater

1st Superheater

Evaporator Tube

Condenser

LP HeaterDeaeratorHP Heater

GeneratorLPTurbine

IPTurbine

HPTurbine

Raw water

Make-up demineralization system

SAC

WAC

SBA

WBA

SAC

SBADegasifier

TRILITE condensate polishing resins enable stable operating of power plants with the superior hydralitic

properties and outstanding mechanical and chemical stability. TRILITE high crosslinkage nulear grade resins ensure optimal oulet water qulity with high ion exchange capacity

and low TOC leakage, also enable stable operating of power plants with the superior H+/OH- conversion rate

and low level of heavy metal ion impurities.


Performance

UPS Strongly Acidic Cation(SAC) Resins

Grade MC-04 MC-04H MC-08 MC-08H MC-10 MC-10H MC-14 MC-14H

Matrix Polystyrene + DVB (Gel type)

Functional group -SO₃-(Sulfonate)

Ionic form Na+ H+ Na+ H+ Na+ H+ Na+ H+

Specific gravity 1.16 1.13 1.28 1.20 1.32 1.22 1.36 1.32

Shipping weight (g/ℓ) 790 750 845 800 850 805 865 815

Moisture retention (%) 57~67 65~70 43~49 50~56 38~44 45~51 31~37 37~43

Total capacity (eq/ℓ) 1.3↑ 1.2↑ 2.0↑ 1.8↑ 2.2↑ 2.0↑ 2.5↑ 2.4↑

Uniformity coefficient 1.1↓

Average diameter (㎛) 500±50 500±30 600±50 620±50 650±50 660±50 650±50 650±50

Operating temp. (℃) 120↓

Operating pH range 0∼14

Swelling rate(Na＋ → H＋)

9% 9% 8% 7%

Remarks

Low Crosslinkage

Standard Crosslinkage

High Crosslinkage

Very High Crosslinkage

High crosslinkage resin features the high resistance against oxidizing agents, high exchange rate per apparent volume and less swelling rate. However, it adversely has less exchange rate for large molecules, less regeneration efficiency and vulnerable to organic fouling. Low crosslinkage resin features higher regeneration efficiency, high resistance against organic fouling and fast reaction rate. However, it adversely has low exchange capacity and vulnerable to oxidizing agents.

※ The data for Specific gravity/ Shipping weight/ Swelling rate is for reference.

Applications

TRILITE MC-04(H) TRILITE MC-04(H) is a low crosslinkage UPS SAC resin which features fast exchange reaction. It

is widely applied to various chemical reactions such as catalytic application (Bisphenol-A, etc),

separation and refining of nucleic acid and amino acid, etc.

TRILITE MC-08(H) TRILITE MC-08(H) is a standard crosslinkage UPS SAC resin. With its excellent regeneration

efficiency and less rinse volume consumption, high purity water can be produced economically.

It has outstanding mechanical and chemical stability, leading to low crush rate even after long-

term use. It is widely used for softening, demineralization and other applications such as lysine,

sugar and catalyst reaction.

TRILITE MC-10(H) TRILITE MC-10(H) is a high crosslinkage UPS SAC resin which features outstanding mechanical

and chemical stability. It is widely used for premium water treatments such as condensate

polishing and pretreatment for ultrapure water.

TRILITE MC-14(H) TRILITE MC-14(H) is a very high crosslinkage UPS SAC resin. It has outstanding mechanical and

chemical stability. It is widely used for premium application where extremely high exchange

capacity is required such as Primary circuit in nuclear power plants and etc.

Applications

TRILITE MA-12(OH) TRILITE MA-12(OH) is an UPS SBA resin (Gel Type 1) with TMA as functional group. It is

supplied either in Cl or OH forms. It features higher SiO2 removal and less ion leakage. With

the fast reaction rate, it is widely used for various applications such as MBP(Mixed bed

polisher) in demineralization, UPW and noble metal recovery.

TRILITE MA-10(OH) TRILITE MA-10(OH) is a high crosslinkage UPS SBA resin (Gel Type 1) with TMA as functional

group. It features outstanding mechanical and chemical stability, SiO2 removal and less ion

leakage. It is widely applied to Condensate polishing.

TRILITE MA-15(OH) TRILITE MA-15(OH) is a very high crosslinkage UPS SBA exchange resin (Gel Type 1) with TMA

as functional group. It features outstanding mechanical and chemical stability. It is widely

applied to premium water treatment applications such as Anion exchanger for UPW and

Condensate polishing.

TRILITE MA-20 TRILITE MA-20 is an UPS SBA resin (Gel Type 2) with DMEA as functional group. It features

very high regeneration efficiency and operating capacity. It shows outstanding performance

when used in packed bed system and pre-treatment single bed for demineralization.

UPS Strongly Basic Anion(SBA) Resins

Type Type 1 Type 2

Grade MA-12 MA-12OH MA-10 MA-10OH MA-15 MA-15OH MA-20


Functional group -N＋(CH₃)₃ (TMA, Trimethylammonium)

-N＋(CH₃)₂C₂H₄OH (DMEA,

Dimethylethanol-ammonium)

Ionic form Cl- OH- Cl- OH- Cl- OH- Cl-

Specific gravity 1.08 1.07 1.08 1.07 1.08 1.08 1.11

Shipping weight (g/ℓ) 670 660 675 665 705 670 700

Moisture retention (%) 49~55 62~70 43~49 59~65 39~45 54~62 45~51

Total capacity (eq/ℓ) 1.3↑ 1.0↑ 1.35↑ 1.1↑ 1.4↑ 1.2↑ 1.3↑


Average diameter (㎛) 580±50 620±50 550±50 590±50 600±50 630±50 590±50

Operating temp. (℃) 80↓ 60↓ 80↓ 60↓ 90↓ 70↓40↓ (OH- type)60↓ (Cl- type)


Swelling rate(Cl- → OH-)

24% 23% 22% 14%

Remarks Low Crosslinkage


High Crosslinkage



Performance


EconomyBasic

Applications

TRILITE SAR10(MB), TRILITE SAR10(MB), KA-10(MB) are the high crosslinkage Gaussian SBA resin

TRILITE KA-10(MB) (Gel type 1) with higher SiO2 removal and less ion leakage. It is widely used for Anion

exchanger and MBP for demineralization, and also catalyst application and recovery of

noble metals such as gold.

TRILITE SAR12, TRILITE SAR12, KA-12 features higher SiO2 removal and less ion leakage. These are

TRILITE KA-12 widely used for surface water treatment required for a large amount of organic contents

and water treatment for high pressure boilers.

TRILITE UKA-12 TRILITE UKA-12 is a UPS SBA resin which is widely used for surface water treatment required

for a large amount of organic contents and water treatment for high pressure boilers.

TRILITE SAR20(MB), TRILITE SAR20(MB), KA-20(MB) are the Gaussian SBA resin (Gel type 2), and features

TRILITE KA-20(MB) high regeneration efficiency and operating capacity. It is most widely used for water

treatment, noble metal recovery and other refining applications.

EconomyBasic

Applications

TRILITE KC-07 TRILITE KC-07 is widely used for industiral softening with the cost advantage.

TRILITE KC-08 TRILITE KC-08 ia a standard crosslinkage Gaussian SAC resin with the cost advantage which

is widely used for industrial softening.

TRILITE KH-70, TRILITE KH-70, KH-80 are the premium grade resins for domestic appliances and food

TRILITE KH-80 processing softening applications. Special post treatments reduce the colorants leakage

and the bad ordor at the initial stage of usage.

TRILITE SCR-B TRILITE SCR-B is a standard crosslinkage Gaussian SAC resin. It is widely applied to water

treatments like softening and demineralization and other applications such as refining of

sugar/starch sugar, amino acids separation, dehydration of organic solvents and catalyst for

various chemical reactions.

TRILITE UKC-08 TRILITE UKC-08 is a standard crosslinkage UPS SAC resin and it is widely used for industrial

softening and demineralization.

TRILITE UKC-10, TRILITE UKC-10, UKC-12 is the high crosslinkage UPS SAC resins which are widely used for

TRILITE UKC-12 industrial softening and demineralization.

Gaussian/UPS Strongly Acidic Cation(SAC) Resins

Grade KC-07 KH-70 KC-08 KH-80 SCR-B UKC-08 UKC-10 UKC-12


Functional group -SO3-(Sulfonate)

Ionic form Na＋

Specific gravity 1.25 1.27 1.25 1.29 1.29 1.28 1.31 1.34

Shipping weight (g/ℓ) 800 820 800 830 830 840 850 860

Moisture retention (%) 45~50 45~50 43~50 43~50 43∼50 42~47 41~45 39~44

Total capacity (eq/ℓ) 1.9↑ 1.9↑ 2.0↑ 2.0↑ 2.0↑ 2.0↑ 2.2↑ 2.3↑

Effective size (㎛) 400↑ UPS

Uniformity coefficient 1.6↓ 1.1↓

Particle size (㎛) 300~1,200 600±50 650±50



Swelling rate(Na+ → H+)

8~9% 9% 8% 7%

Remarks StandardCrosslinkage

High Crosslinkage


Gaussian/UPS Strongly Basic Anion(SBA) Resins

Type Type 1 Type 2

Grade KA-10(MB) SAR10(MB) KA-12 SAR12 UKA-12 KA-20(MB) SAR20(MB)


Functional group -N＋(CH3)3 (TMA, Trimethylammonium)-N＋(CH3)2C2H4OH

(DMEA, Dimethylethanolammonium)

Ionic form Cl-



Moisture retention (%) 43~47 43∼48 50~60 48∼55 49~55 40~50 39~45


Effective size (㎛) 400↑ 400↑ 400↑ 400↑ UPS 400↑ 400↑

Uniformity coefficient 1.6↓ 1.6↓ 1.6↓ 1.6↓ 1.1↓ 1.6↓ 1.6↓

Particle size (㎛) 300∼1,200 580±50 300∼1,200

Operating temp. (℃)60↓(OH- type)80↓(Cl- type)

40↓(OH- type)60↓(Cl- type)



24% 15% 12%



Condensate polishing & Nuclear grade Resins

Type Condensate polishing Nuclear grade

Grade MC-10H CMP28LH MA-10OH AMP18LOH MCN116K MAN210K MMN316K

Matrix Polystyrene + DVB

Functional group-SO3

-

(Sulfonate)-N＋(CH3)3

(TMA, Trimethylammonium)-SO3

-

(Sulfonate)

-N＋(CH3)3 (TMA,

Trimethyl-ammonium)

MCN116K+

MAN210K

Ionic form H+ OH- H+ OH-

Total capacity (eq/ℓ) 2.0↑ 1.9↑ 1.1↑ 1.1↑ 2.4↑ 1.2↑

Moisture retention (%) 45∼51 42~48 59~65 50~56 36~43 54~60

Shipping weight (g/ℓ) 805 780 665 680 810 660

Uniformity coefficient 1.1↓ 1.4↓ 1.1↓ 1.4↓ 1.1↓

Particle size (㎛) 660±50 400~1,200 590±50 400~1,200 650±50 600±50

Effective size (㎛) UPS 400↑ UPS 450↑ UPS UPS

△TOC (ppb) - - - - 10↓ 10↓ 10↓

Operating temp. (℃) 120↓ 120↓ 60↓ 50↓ 120↓ 60↓ 60↓


※ The data for Shipping weight is for reference.

Applications

TRILITE MC-10H TRILITE MC-10H is a high crosslinkage UPS SAC resin which features outstanding

mechanical and chemical stability. It is widely used for premium water treatments such

as condensate polishing and pretreatment for ultrapure water.

TRILITE MA-10OH TRILITE MA-10OH is a high crosslinkage UPS SBA resin (Gel Type 1) with TMA as

functional group. It features outstanding mechanical and chemical stability, SiO2 removal

and less ion leakage. It is widely applied to Condensate polishing.

TRILITE CMP28LH TRILITE CMP28LH is a very high crosslinkage Gaussian SAC resin, which features higher

stability against oxidizing agents. It is widely used for water treatment, metal removals

and condensate polishing.

TRILITE AMP18LOH TRILITE AMP18LOH is a high crosslinkage resin, which features outstanding SiO2 removal

capaicty and less ion leakage. It is widely used for water treatment containing large

amount of organic contents MBP application and the condenstate polishing.

TRILITE MCN116K TRILITE MCN116K is a high crosslinkage UPS SAC resin and has polystyrene-DVB matrix

withsulfonic acid as functional group. It features excellent mechanical and chemical

stability, and low crush rate after long term use. It is widely used for premium water

treatment such as primary circuit for nuclear power plant.

TRILITE MAN210K TRILITE MAN210K is a high crosslinkage UPS SBA resin (Gel type 1) and has polystyrene-

DVB matrix with TMA as functional group. It features excellent mechanical/ chemical

stability and low crush rate after long term use. It is widely used for anion tower for

nuclear power plant, and under the standard operating conditions, it maintains less than

△TOC 10ppb of outlet water quality.

TRILITE MMN316K TRILITE MMN316K is a mixed resin of MCN116K and MAN210K by 1:1 exchange capacity ratio.

Performance

Applications

TRILITE WCA10L TRILITE WCA10L is a Gaussian WAC resin. Due to excellent ion exchange capacity, high

purity water can be produced economically. It features high mechanical and chemical

stability leading to low crush rate after long term use. It has high exchange capacity and

regeneration efficiency. It is widely applied in layered bed of water treatment systems

combined with SAC resins, and also used for Electrodeposition of paints, etc.

TRILITE AW20 TRILITE AW20 doesn’t have natural salt splitting capacity but high exchange capacity and

regeneration efficiency. It is widely used for refining of organic solvents with excellent

chemical stability, heat resisting capacity and mechanical strength against attrition loss.

TRILITE AW30L TRILITE AW30L features outstanding chemical stability, high resistance against organic

fouling and superior decolonization capacity. It is widely applied in layered bed of water

treatment systems combined with SBA resins, and also used for starch sugar refining.

TRILITE AW80 TRILITE AW80 features an excellent chemical stability, high resistance against organic

fouling. It is widely used for Layered bed water treatment system combined with SBA resins.

TRILITE AW90 TRILITE AW90 is an UPS resin with high chemical stability, high resistance against organic

fouling and superior depolarization capacity. It is widely used for starch refining and Layered

bed water treatment system combined with SBA resins.

Performance Economy

Weakly Acidic Cation(WAC) / Weakly Basic Anion(WBA) Exchange Resins

TypeWeakly Acidic Cation

Exchange ResinsWeakly Basic Anion Exchange Resins

Grade WCA10L AW20 AW30L AW80 AW90

Matrix Polyacrylate + DVB Polystyrene + DVB

Functional groupCOOH

(Carboxylic acid)

Secondary

AmineTertiary Amine

Ionic form H+ Free Base

Specific gravity 1.19 1.07 1.05 1.04 1.04

Shipping weight (g/ℓ) 720 650 700 670 640

Moisture retention (%) 45~50 39~45 48~58 55~60 40~50

Total capacity (eq/ℓ) 4.2↑ 2.5↑ 1.5↑ 1.6↑ 1.6↑

Effective size (㎛) 500↑ 400↑ 400↑ UPS UPS

Uniformity coefficient 1.4↓ 1.6↓ 1.4↓ 1.2↓ 1.1↓

Particle size (㎛) 425~1,200 300~1,200 425~1,200 400~600 550±50

Operating temp. (℃) 120↓ 100↓ 60↓ 60↓ 60↓

Operating pH range 4~14 0~9 0~9 0~9 0~9

Swelling rate(H+ → Na+, FB → Cl-)

60% 30% 20% 23% 20%



※ Feed water : Industrial water, Electrical Conductivity : 200 μS/cm↓

Outlet condition of TRILITE UPW Resins

Mixed-bed(UPRM100U)

UV-OX,etc

Final Polisher(UPRM300U)

AnionPolisher

(UPRA200U)

RO,etc

FeedWater

Outletcondition

① Resistivity (MΩ·cm) ② TOC (ppb)

18.25

18.20

18.15

18.10

18.05

18.00

20

15

10

5

00.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0

(Mettler Toledo M300) hrs (Anatel A1000S20P) hrs

⑥ Particle (0.05㎛/㎖): None

(RION XP-L4W)

⑤ Metals (ppt)

Li Be Na Mg Al K Ca Ti Cr Mn Fe Co Ni Cu

< 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

Zn Ga As Sr Mo Ag Cd Sn Sb Ba Au Pb Bi

< 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

③ Total Silica (ppt) ④ Boron (ppt)

100

80

60

40

20

0

500

400

300

200

100

0

(HACH Series 5000 Silica Analyzer) hrs (Sievers UPW Boron Analyzer) hrs

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0

Ultrapure Water

The role of Ultrapure water(UPW) is increasing in electronic industries such as semiconductors and display

(LCD, OLED), etc. With the development of the relevant sectors, the quality control over the UPW has more

tightened up.

The following conditions are to be met necessarily to produce ultrapure water consistently.

- Low uniformity coefficient of resins (1.1↓)

- High conversion rate of resins (H+, OH-)

- Strict control over TOC (Total Organic Carbon) and trace metal-ion through post-treatment on resins.

TRILITE UPW resins own reliable supply reference to various ultrapure water systems from LCD(Samsung

Display, LG Display, etc.) to semiconductor(Samsung Electronics, SK Hynix, etc.) thus contributing to

competitiveness with customers with stable quality control and on time delivery.

TRILITE UPW resins are classified as: Primary application - UPR100 Series, Secondary application - UPR200

Series, and Final Polishing application – UPR300 Series.

Gradeseries

Representative products

Cationconversion rate

Anion conversion rateOutlet condition

H+(%) OH-(%) Cl-(%)

UPR100Series

UPRM100U 99.0↑ 95.0↑ 1.0↓

Guarantee) Resistivity > 17.0 MΩ·cm (in 10min.)

Actual) Resistivity > 18.0 MΩ·cm (in 10min.)

UPR200Series

UPRM200U 99.0↑ 95.0↑ 1.0↓Resistivity > 18.1 MΩ·cm (in 30min)

△TOC < 5ppb (in 120min)

UPR300Series

UPRM300U 99.9↑ 97.0↑ 0.1↓

Resistivity > 18.2MΩ·cm (in 30min)△TOC < 1ppb (in 180min)

Metal Impurity (ppm, as Dry Base)Na<1, Fe<1, Ca<1, Zn<0.5, Al<0.5, Cu<0.5

※ Feed water(100 Series) : Conductivity 10㎲/㎝ RO outlet, SV36Feed water(200, 300 Series) : Resistivity > 17.5㏁.㎝, TOC < 2ppb, SV30

RawWater

Point of Use

Typical UPW process and IER selection

Tank

Tank

TankHeat

Exchanger

Heat Exchanger

MF

UF

UV-ST

UV-OX

① CationExchanger

④ AnionPolisher

⑤ Final Polisher

① CationExchanger

Degasifier

RO

② AnionExchanger

③ Mixed Bed

MDGor

VDGPre-Treatment

System

① Cation Exchanger : MC-08, MC-10

② Anion Exchanger : MA-12, MA-10, MA-15, MA-20, AW80/AW90

③ Mixed Bed Tower : UPRC100U, UPRC120U, UPRA100U, UPRA120U

④ Anion Polisher : UPRA200U, UPRA220U, UPRA240U, UPRA300U, UPRA320U, UPRA340U

⑤ Final Polisher : UPRM200U, UPRM220U, UPRM240U, UPRM300U, UPRM320U, UPRM340U


Ultrapure water for final polishing UPR300 Series

Grade UPRC300U UPRA300U UPRC320U UPRA320U

Matrix

UPS SAC Gel type UPS SBA Gel type1 UPS SAC Gel type UPS SBA Gel type1


High Crosslinkage


Total capacity (eq/ℓ) 1.9↑ 1.0↑ 2.0↑ 1.1↑

Moisture retention (%) 50∼56 62∼70 45~51 59∼65

Average diameter (㎛) 620±50 620±50 660±50 590±50

Uniformity coefficient 1.1↓ 1.1↓ 1.1↓ 1.1↓

Ionic conversion rate

H+(%) 99.9↑ - 99.9↑ -

OH-(%) - 97.0↑ - 97.0↑

Cl-(%) - 0.1 ↓ - 0.1 ↓

Metal impurity(ppm, as Dry Base)

Na<1, Fe<1, Ca<1, Zn<0.5, Al<0.5, Cu<0.5

↓ ↓ ↓ ↓

Mixed ratio : 1:1 (Capacity ratio) Mixed ratio : 1:1 (Capacity ratio)

↓ ↓

Grade UPRM300U UPRM320U

Type Mixed resin

Outlet condition

Resitivity > 18.2 MΩ·cm (in 30min.)△TOC < 1ppb (in 180min.)

Resitivity > 18.2 MΩ·cm (in 30min.)△TOC < 1ppb (in 180min.)

Feed water : Resistivity > 17.5 MΩ·cm, TOC < 2ppb, SV30

Ultrapure water system

Ultrapure water for primary circuit UPR100 Series


Matrix



High Crosslinkage







H+(%) 99.0↑ - 99.0↑ -

OH-(%) - 95.0↑ - 95.0↑

Cl-(%) - 1.0 ↓ - 1.0 ↓

↓ ↓ ↓ ↓


↓ ↓


Type Mixed resin

Outlet condition1)

Guarantee) Resistivity > 17.0 MΩ·cm (in 10min.)Actual) Resistivity > 18.0 MΩ·cm (in 10min.)

Feed water : Conductivity 10㎲/㎝ RO outlet, SV36

Outlet condition2)Guarantee) Resistivity > 18.0 MΩ·cm (in 30min.)

Feed water : Resistivity > 17.5 MΩ·cm, SV30

Ultrapure water for secondary circuit UPR200 Series


Matrix



High Crosslinkage







H+(%) 99.0↑ - 99.0↑ -

OH-(%) - 95.0↑ - 95.0↑

Cl-(%) - 1.0 ↓ - 1.0 ↓

↓ ↓ ↓ ↓


↓ ↓


Type Mixed resin

Outlet condition

Resistivity > 18.1MΩ·cm (in 30min.)△TOC < 5ppb (in 120min.)

Resistivity > 18.1 MΩ·cm (in 30min.)△TOC < 5ppb (in 120min.)

Feed water : Resistivity > 17.5 MΩ·cm, TOC < 2ppb, SV30


Ion exchange resins are used as a catalyst for various chemical reactions and convert the Batch operation

into the Continuous operation. Based on the high conversion rate of IERs, the yield of the final product can be

maximized. The followings are the advantages of IERs used in the catalyst applications :

- Easily separable from the reaction system and cost-effective with the continuous reaction in the column reactor.

- Unnecessary for regeneration or re-concentration, high reaction selectivity and fewer byproducts produced.

- Easy to be selected with low corrosive to the system.

Also, the following disadvantage is taken care of disadvantages of catalyst IER for cation:

- Less heat stability compared to inorganic catalyst and slow reaction rate for macromolecules reactions.

TRILITE catalyst resin optimizes the catalytic reactions with the improved porosity and excellent ionic conversion

rate of resins. It shows a fast reaction rate with maximized surface area and remarkable internal diffusion speed,

resulting in efficient reactions even in the non-polar solvent. Also, it has outstanding mechanical and chemical

stability and excellent elasticity of polymers. Hence, the superior durability of resins can be achieved even under

the rapid volume changes and results in longer lifetime ultimately.

Catalyst

Application Reaction Catalytic resins Equivalent

Hydrolysis of

methyl acetateCH₃COOCH₃ + H₂O → CH₃COOH + CH₃OH

PCC40H,

MC-08H,

CMP08LH

Esterification

reactionRCOOH + ROH → RCOOR + H₂O

PCC40H, MC-08H,

CMP08LH,

SPC160H, SPC180H,

SPC400LH

Synthesis of

methyl

methacrylate

SPC180H

Alkylation of

phenol

SPC260H,

SPC320HAmberlyst15Wet

Synthesis of

bisphenol-A

PCC30H,

PCC40H

Methyl tertiary

butyl ether

(MTBE)

SPC280H Amberlyst35Wet

t-amyl methyl

ether(TAME)

SPC160H,

SPC180H

CH₂ = C CH₃OH → CH₂ = C H₂O

CH₃

COOH

CH₃

COOCH₃

+ +

H₂CCH₃

CH₃CH₃OH H₃C OMe

CH₃

CH₃

+

H₂CCH₂CH₃

CH₃CH₃OH H₃C OMe

CH₂CH₃

CH₃

+

OH OHHO+

O

H₃C CH₃H₃C CH₃

OH OH

+ H₂CR

H CH₃

R

H

Applications

TRILITE PCC30H, TRILITE PCC30H, PCC40H is a low crosslinkage SAC resin with high reaction rate and

TRILITE PCC40H mechanical and chemical stability, and widely used as a catalyst for Bisphenol-A.

TRILITE SPC260H TRILITE SPC260H is a porous type SAC resin with high exchange capacity and good

resistance against attrition loss. It is widely used for etherification catalyst. It features

strong selectivity even for a low-temperature with the excellent reaction rate.

TRILITE SPC280H TRILITE SPC280H features an enhanced exchange capacity (approximately 10%)

compared to TRILITE SPC260H.

Strongly Acidic Cation Resins for Catalyst

Grade PCC30H PCC40H SPC260H SPC280H

MatrixPolystyrene＋DVB

(Gel type)Polystyrene＋DVB

(Porous type)


Ionic form H＋(H Conversion rate 99.9%↑)

Shipping weight (g/ℓ) 750 780 800 800

Moisture retention (%) 60~70 57∼67 50~58 50~58

Total capacity (eq/kg) 4.5↑ 4.5↑ 4.7↑ 5.2↑


Effective size (㎛) 500↑ 400↑ 400↑


Particle size (㎛) 600∼1,250 General type : 300∼1,200, L-type : 425~1,200, XL-type : 700~1200

Operating temp. (℃) 120↓ 120↓ 120↓ 120↓

Operating pH range 0∼14 0∼14 0∼14 0∼14

Specific surface area (㎡/g) - - 40~70 40~50

Pore Volume (㎡/g) - - 0.30~0.50 0.35~0.40

Pore radius (Å) - - 200~500 380~450

Shrinkage Water → Phenol : 53% Water → Phenol : 51%

Water → Methanol : 5%Water → MTBE : 9%Water → Hexane : 20%Water → Dry : 36%

Water → Methanol : 5%Water → MTBE : 10%Water → Hexane : 20%Water → Dry : 40%


Chromatography

Ion Exchange Resins for chromatography separation efficiently separate useful materials in various applications

such as high-purity separation of sugar solutions, e.g. Fructose/Glucose separation and sucrose recovery from

molasses, and acid purification, etc.

The following characteristics are required to be IERs for chromatography separation.

- Outstanding uniformity and excellent separation capacity.

- Relatively small particle size for maximum separation efficiency with a larger surface area per volume unit of resins.

- A longer life time with mechanical and chemical stability.

TRILITE chromatography resins completely satisfy the above conditions, and enable the most efficient

separation capacity by the various degree of crosslinkages (%), ionic forms and particle sizes. The Following

tables show major applications of UPS gel type cation exchange resins and UPS gel type 1 & 2 anion exchange

resins, and the full line-up of TRILITE chromatography resins.

TypeIonic forms

Representativeproducts

Major application

UPS SAC Gel type

Na MCK-30Glucose/Oligosaccharide separation,

Maltose/Oligosaccharide separation

K MCK-22M Sucrose collection from Molasses

Ca MCK-55Fructose/Glucose separation, Fructose/Allulose separation,

Fructose/Galactose separation

UPS SBA

Gel

type 1 Cl MA-13J Bio diesel purification process

type 2 Cl MA-23F Acid purification

Lower Uniformity coefficient (1.05~1.10) than

other resins for chromatographic separation

→ Excellent separation efficiency

Higher physical & chemical strength

→ Longer life time+

Crosslinkage Ionic form

Average particle size

210~220㎛ 283~295㎛ 305~328㎛ 340~350㎛

5% KMCK-22M

(305㎛)

MCK-22K

(346㎛)

6%

NaMCK-30

(220㎛)

MCK-30J

(295㎛)

MCK-30L

(328㎛)

MCK-30K

(350㎛)

KMCK-32

(213㎛)

MCK-32J

(288㎛)

MCK-32L

(320㎛)

MCK-32K

(345㎛)

CaMCK-35

(210㎛)

MCK-35J

(283㎛)

MCK-35L

(315㎛)

MCK-35M

(305㎛)

MCK-35K

(340㎛)

8%

NaMCK-50

(215㎛)

KMCK-52

(215㎛)

CaMCK-55

(210㎛)

※ The data for average particle size and the crosslinkage is for reference.

Applications

TRILITE MC-04H TRILITE MC-04H is a low crosslinkage UPS SAC resin which features fast exchange

reaction. It is widely applied to various chemical reactions such as catalysitc application

(Bisphenol-A, etc), separation and refining of nucleic acid and amino acid, etc.

TRILITE CMP08H TRILITE CMP08H is a low crosslinkage Gaussian SAC resin and is widely used in water

treatments such as softening and demineralization and special refining such as acid

catalyst, organic chemical reactions.

TRILITE CMP28H TRILITE CMP28H is a very high crosslinkage Gaussian SAC resin, which features higher

stability against oxidizing agents. It is widely used for water treatment, metal removals and

condensate polishing.

TRILITE SPC160H TRILITE SPC160H has very high whole bead count, high uniformity, excellent mechanical

and chemical stability. It is widely used for etherification, e.g. Tetrahydrofuran(THF).

TRILITE SPC180H TRILITE SPC180H features stronger mechanical strength, higher surface area and higher

porosity than other resins. Its high diffusion rate into the inside of resins leads high reaction

performance. It is used for water treatment and catalyst applications such as alkylation

and etherification, e.g. 1,4-BDO, MMA.

TRILITE SPC320H TRILITE SPC320H has high exchange capacity, large specific surface area and high

porosity. It shows excellent adsorption and recovery capacity to metal ions such as Cu,

V2O5, etc.

Strongly Acidic Cation Resins for Catalyst

Grade MC-04H CMP08H CMP28H SPC400H SPC160H SPC180H SPC320H

MatrixPolystyrene

＋DVB(Gel type)

Polystyrene＋DVB(Porous type)

Functional group -SO₃-(Sulfonate)

Ionic form H＋(H Conversion rate 99.9%↑)


Moisture retention 65∼70 65~71 42~48 65∼75 54∼60 53∼60 42~48

Total capacity (eq/kg) 5.1↑ 4.9↑ 4.0↑ 4.9↑ 4.5↑ 4.5↑ 4.5↑


Effective size (㎛) UPS 400↑


Particle size (㎛) 500±30 General type : 300∼1,200, L-type : 425~1,200, XL-type : 700~1200





크로마토그래피 분리

MCK-22 Series (Chromatography cation resins)

Grade MCK-22M MCK-22K

Matrix, Functional group Polystyrene + DVB, -SO₃-(Sulfonate)

Ionic form K+ (K Conversion rate 98%↑)

Shipping weight (g/ℓ) 815

Moisture retention (%) 47~52 (K type), 59~64 (H type)

Total capacity (eq/ℓ) 1.6↑

Average diameter (㎛) 305±15 346±15



Grade MCK-30 MCK-30J MCK-30L MCK-30K


Ionic form Na+


Moisture retention (%) 52~56





Grade MCK-32 MCK-32J MCK-32L MCK-32K


Ionic form K+ (K Conversion rate 98%↑)







Fructose/Glucose separation by MCK-55

Isomerization of fructose by the use of enzyme produces glucose which features a higher sweetness (1.7 times

of sugar). The starch sugar is proved to be economically efficient and is substitutable to the use of sugar.

However, the enzyme reaction is a reversible reaction. The isomerization is limited up to 42% (equal to 90% of

sugar sweetness) due to reaction equilibrium. Hence, it is required to increase the glucose percentage up to

55%, with the IER technology.

A typical process to treat the fructose/glucose mixture with the Ca type ion exchange resin tower is described

as below. As the mixture passes through the IER layers, glucose moves faster than fructose which has a higher

affinity with Ca ion. In this principal, glucose elutes in before the fructose. The collection of glucose is sold as a

finished product, and the fructose is put to the previous process to react with the isomerization enzyme.

Fructose 90% ↑

Fructose/Glucose separation tower

Filtration, Concentration

Isomerization by enzyme

42% HFS

Activated carbon

Mixing

Ion exchanger

(for fructose)

55% HFS

Glucose (40~45%)

Fructose

Glucose

Fructose

Glucose Fructose

Glucose

MCK-55(Ca form)

High fructose syrup


Typical process of Starch sugar refining and Fructose/Glucose separation

CMP18

AMP24SCR-Bor

CMP18

AW30Lor

AW30C

Counter-current

pH 5~6

5㎲/㎝↓

CocurrentpH 8~9

20㎲/㎝↓

pH 4~6

2㎲/㎝↓

Bx 45

CV Max 0.05

2nd Ion exchanger(for fructose)

Concentration

Mixing

High fructose syrup

Activatedcarbon

Filtration

90~97% HFS

42% HFS

55% HFS

Isomerizationby enzyme

Concentration3rd Ion exchanger(for high fructose)

Fructose/Glucose Separation

CMP18

AMP24SCR-Bor

CMP18

AW30Lor

AW30C

Counter-current

pH 5~6

5㎲/㎝↓

CocurrentpH 8~9

20㎲/㎝↓

pH 4~6

2㎲/㎝↓

Bx 35~40

CV Max 0.05

Enzyme liquefaction, saccharification

Activated carbon1st Ion exchanger

(for glucose)

Corn syrup

Glucose

Emulsion of starch Filtration

ConcentrationConcentration

Starch(Corn)

The starch sugar refining is one of the primary food application for IERs. Unlike water treatment applications,

there are other variables affecting operation yields such as total organic contents or viscosity and adsorption

capacity to specific materials, hence customized Tailored resins optimized for specific operating conditions are

recommended.

Ion Exchange Resins used as food applications need for strict control and management of impurities and

foreign substances in the manufacturing process, and are registered as food grade between countries with

necessary permits as a Food additive. Also, Halal certificates are required for Islamic countries.

TRILITE food application IERs are optimized for various domestic and overseas food processes and contribute

to enhancing competitiveness to customers by continuous technical consultation and product improvements.

Porous type reins are recommended for starch sugar production with higher viscosity and less reactivity

of liquid rather than Gel type resins. TRILITE AW30C (WBA 99%↑) is recommended when the treated liquid

temperature is high (60℃↑) or there is worry about isomerization reaction.

TRILITE MCK-50 Series is receiving rave reviews from users with outstanding uniformity of resins and superior

mechanical and chemical stability to any other resins in the industry.

Food - Starch Sugar

Fructose(90~97%)

Glucose(80~90%)

Fructose (42%)

Glucose (52%)

Other sugars(6%)

pH 4~6

2㎲/㎝↓

Bx 40

CV Max 0.05

AW30C

AMP24

CMP18

(Mixture) (Separation)

MCK-55


Grade MCK-35 MCK-35J MCK-35M MCK-35L MCK-35K


Ionic form Ca2+ (Ca Conversion rate 98%↑)



Total capacity (eq/ℓ) 1.6↑ 1.7↑

Average diameter (㎛) 210±10 283±15 305±15 315±15 340±15



Grade MCK-50 MCK-52 MCK-55


Ionic form Na+ K+ (K Conversion rate 98%↑)

Ca²+ (Ca Conversion rate 98%↑)

Shipping weight (g/ℓ) 855 865 865

Moisture retention (%) 46~50 39~43 42~46

Total capacity (eq/ℓ) 1.9↑ 2.0↑ 2.0↑

Average diameter (㎛) 215±10 215±10 210±10


Strongly Basic Anion Resins for Chromatography

Type Type 1 Type 2

Grade MA-13J MA-13F MA-23F

Matrix, Functional group Polystyrene + DVB, TMAPolystyrene + DVB,

DMEA

Ionic form Cl-


Moisture retention (%) 43~53 47~51 42~46


Average diameter (㎛) 300±15 230±10 230±10



크로마토그래피 분리


Food - Sugar / Nucleic Acid / Lysine

Refined Sugar

White Sugar

Brown Sugar

Cane raw sugar refining process Sugar refining process with A/C Sugar refining process without A/C

Cane B Sugar (Raw sugar) C Sugar (Raw sugar)

Extraction Carbonation, Filtration Carbonation, Filtration

FiltrationDecolorization by IER(KA-11/SAR11 or AMP14)

Decolorizationby IER (2 steps)

(ASP10 + AMP14)

Crushing Affination, Melting Affination, Melting

Carbonation Activated carbon

Concentration,Crystallization

Concentration, Crystallization

Concentration, Crystallization

A Sugar B Sugar C SugarRefined Sugar

White Sugar

Brown Sugar

Typical process of nucleic acid

adsorption / elution processTypical process of lysine adsorption /

elution process

AMP26N MC-08LSNAC-4

orMC-04NH

AMP26N

Cultivation of microorganism

Cultivationof yeast

CrystallizationCrystallization

Broth withlysine

Extraction of nucleic acids

EvaporationEvaporation

Adsorption & separation

with IER

Decompositionof nucleic acids

Neutralization, Filtration

Adsorption & separation

with IER

Adsorptionof nucleic acids

Separationof GMP, IMP

Concentration Adsorption of lysine

2,000~3,000 I.U.

3,000~4,000 I.U.

800~1,000 I.U.

800~1,000 I.U.

300~400 I.U. 200~

300 I.U.100~150 I.U.

500~600 I.U. < 45 I.U. < 45 I.U.2,000~3,000 I.U.

< 100 I.U. < 100 I.U.3,000~4,000 I.U.

400~1,000 I.U. 400~1,000 I.U.

General sugar processes are classified into the production of raw sugar and refined sugar. The raw sugar

manufacturing process doesn’t need IERs, but refined sugar requires IERs necessarily. For refined sugar process,

it is also distinguished between the combination use of IERs & activation carbon and the use of two different

types of IERs. Without using activated carbon, there are a large number of colorants to be removed by IER. In

such a case, it is recommended to use the combination with TRILITE ASP10, which has the outstanding feature

of enhanced decolorization capacity and long lifetime with excellent resistance to organic fouling of resins.

Nucleic acids, one of the popular food additives, are

flavor enhancers and used as seasonings. IERs are

used for adsorption, separation, and concentration of

nucleic acids. TRILITE AMP26N and NAC-4 are Tailored

resins with high performance and long life cycle.

Ion Exchange Resins are used for separation and

purification of amino acids, constituents of protein.

Lysine as a feed nutrition additive is the most

commercialized amino acids. TRILITE MC-08LS is

a Tailored UPS resin with outstanding adsorption

capacity, mechanical and chemical stability.

※ GMP : Guanosine MonoPhosphate※ IMP : Inosine MonoPhosphate

※ Lysine : An essential amino acid

Starch sugar refining Resins

TypeSACGel

SAC Gel

SAC Porous

SBAPorous type 2

WBAPorous

WBAPorous

WBAPorous

Grade SCR-B MC-08 CMP18 AMP24 AW30L AW30C AW90

Matrix Polystyrene＋DVB


-N＋(CH3)2C2H4OH (DMEA)

Tertiary Amine

Ionic form Na＋ Cl- Free Base


Shipping weight (g/ℓ)

830 845 795 655 700 700 640

Moisture retention (%)

43∼50 43∼49 43∼50 54∼64 48~58 55~65 40~50


Effective size (㎛) 400↑ UPS 400↑ 400↑ 400↑ 400↑ UPS

Uniformity Coefficient

1.6↓ 1.1↓ 1.6↓ 1.6↓ 1.4↓ 1.6↓ 1.1↓

Particle size (㎛) 300~1,200 600±50 300~1,200 300~1,200 400~1,200 300~1,200 550±50

Operating ptemp. (℃)

120↓ 120↓ 120↓50↓ (OH- type) 70↓ (Cl- type)

60↓ 100↓ 60↓

Operating pH range

0∼14 0∼14 0∼14 0∼14 0~9 0~9 0~9

Swelling rate(Na+ → H+, FB → Cl-,

Cl- → OH-)

8% 9% 8% 14% 20% 20% 20%



Chelating Resins

CLR-08

Ca²+ 0.01ppm↓

Mg²+ 0.01ppm↓

Sr²+ 0.02ppm↓

Ba²+ 0.01ppm↓

In contrast to typical Ion exchange resins, the chelating resin selectively separates and removes a metal ion with

a functional group that can form a chelate (complex) with the metal ion. Chelating resins with various functional

groups are used in the following applications.

Grade Functional group Features Application

CLR-08 Iminodiacetate

- Much greater selectively for

multivalent ions (Ca²+, Mg²+, Sr²+, etc.)

from very highly concentrated

monovalent ions(Na+, etc.)

- Less leakage of multivalent ions

- Secondary brine purification

- Selective removal of bivalent ions

- Removal and recovery of heavy metals

/ rare metals from wastewater

CLR-09Aminomethyl

phosphonate

- slightly higher operating capacity than

CLR-08

- slightly more leakage of multivalent

ion than CLR-08

- Secondary brine purification

- Selective removal of bivalent ions

CLR-10 Thiouronium- Much greater selectivity for

mercury(Hg)- Mercury removal in wastewater

CLR-20 Polyamine

- Much greater selectivity for heavy

metals except alkali metal ions(Na+, K+,

etc) and alkaline earth metal ions(Ca2+,

Mg2+, etc)

- Separation of heavy metals from

alkali metal ions and alkaline earth

metal ions

CLR-B3 Glucamine- Much greater selectivity for boron(B)

from highly concentrated anions- Boron removal from wastewater

CLR-B3UP Glucamine- Much greater selectivity for boron(B)

and less TOC leakage(ΔTOC 5ppb↓)- Boron polisher for UPW

CLR-F Aminophosphonate- Much greater selectivity for fluoride(F)

even from low concentration- Fluoride removal in wastewater

CLR-N Triethylamine- Much greater selectivity for nitrate

than anion resins- Nitrate removal

TRILITE chelating resins are used for various applications and processes. Total solution service can be

provided by an optimized proposal for process retrofit and resin analysis. The professional consultation

can be provided; Preliminary technical review → Pilot plant test → Gathering engineering data → Optimized

design proposal → further Scale-up of the facility.

TRILITE chelating resins are being supplied to domestic and foreign customers especially for secondary brine

purification applicaton and proved the competitiveness to other equivalent resins.

Typical chloro-alkali process

Salt saturation

Dechlorination

Primary brine purification

Gas liquid separation

Secondary brine

purification

Ion exchange membrane

electrolysis cell

Vaporization

Salt

Chlorine

Hydrogen

Water

Secondary brine purification

50% NaOH

Sugar refining, Nucleic acid/Lysine adsorption Resins

TypeSugar refining resins

SBA Gel type 1 SBA Gel type 1 SBA Porous type 1 SBA Porous type

Grade SAR11 KA-11 AMP14 ASP10

Matrix Polystyrene＋DVB Polyacrylate + DVB

Functional group -N＋(CH3)3 (TMA, Trimethylammonium)Quaternary Ammonium

Ionic form Cl- Cl-


Moisture retention (%) 55~65 55~65 57~67 65~75


Effective size (㎛) 400

Uniformity Coefficient 1.6↓

Particle size (㎛) 300~1,200 400~1,250

Operating temp. (℃) 60↓ (OH- Type)80↓ (Cl- Type)

70↓ (OH- Type)90↓ (Cl- Type)

40↓ (OH- Type)80↓ (Cl- Type)

Operating pH range 0~14


35% 25% 25%

TypeNucleic acid adsorpion resins

Lysine adsorption resins

Gel SAC Porous type 2 UPS Gel SAC UPS Gel SAC

Grade NAC-4 AMP26N MC-04NH MC-08LS


Functional group -SO₃- (Sulfonate)-N+ (CH₃)₂C₂H₄OH

(DMEA)-SO₃- (Sulfonate) -SO₃- (Sulfonate)

Ionic form Na+ Cl- H+ Na+


Moisture retention (%) 57∼67 46∼52 65~70 43~49


Effective size (㎛) 450↑ 400↑ UPS UPS

Uniformity Coefficient 1.6↓ 1.1↓ 1.1↓

Particle size (㎛) 300∼1,200 500±50 600±50

Operating temp. (℃) 120↓ 50↓ (OH- Type)70↓ (Cl- Type)

120↓ 120↓

Operating pH range 0~14 0~14

Swelling rate(Na+ → H+, Cl- → OH-)

8% 13% 9% 9%

※ The data for Shipping weight/Swelling rate is for reference.


Synthetic Adsorbents

The reaction mechanism of synthetic adsorbents and experimental apparatuses

Synthetic adsorbents are non-functionalized resins with controlled pore size distribution and large surface area.

While the primary application of synthetic adsorbents is to adsorb various organics by Van der Waals forces,

it can be used in various applications such as decolorization of liquid chemical, separation, and purification of

proteins and antibiotics, purification of medical supplies and refining semiconductor chemicals.

The above diagram depicts the necessary test for the choice of Synthetic adsorbents. In general, the test is

preceded with TRILITE GSH-20 for adsorption and elution of target material first. To find out proper synthetic

adsorbent, re-test it with other types of synthetic adsorbents according to selectivity to M.W and elution rate of

the target material.

The following table shows the features of major TRILITE Synthetic adsorbents.

Type Product Feature

Aromatic standard type GSH-20

Relatively large pore radius, hence appropriate for

adsorption of large molecules (> 1,000mw). Easily elutes

and separates the target material.

Aromatic special type

GSP-25 Very large surface area and small pore radius, hence

appropriate for adsorption of small molecules (< 1,000mw)

and exclusion of large molecules.GSP-50

Aromatic chemically modified GSP-07

Substituted bromine turns out very high hydrophobicity

resulting very high selectivity to non-polar molecules.

Large amount of eluent may be required due to very high

adsorption force.

It can be can be used for solution with high density due to

high specific gravity.

The following table shows general tendency and guideline for choosing Synthetic Adsorbents.

Type Case and General Tendency Guideline

Selectivity

(molecular

weights)

Adsorption of all materials from solution containing

large amount of organics (mw > tens of thousands)GSH-20 > GSP-07 > GSP-25 > GSP-50

Adsorption of material from solution with large amount

of organic content (mw < 1,000)GSP-50 > GSP-25 > GSH-20 > GSP-07

Adsorption of materials (mw < several thousands) GSP-07 > GSP-50 > GSP-25 > GSH-20

ElutionElution tends to decrease with small pore radius and

large adsorption force.GSH-20 > GSP-25 > GSP-50 > GSP-07

Feeding solution

Eluent

Detector

Purewater

Regenerant

Fraction collector


Pure water

ColumnTarget

moleculesPore radius

(Å)

Specific surface

area(m2/g)

Typical process of removing heavy metal from waste water

The above diagram depicts a waste water treatment system with TRILITE chelating resins which selectively

removes metal ions. As the environmental regulations are more strictly controlled, there is tendency for the

increasing wastewater treatment cost. TRILITE chelating resins can be an alternative solution to the high cost of

wastewater treatment.

Waste water containing

various heavy metal

(If mercury is not present)

Waste water containing

various heavy metal

(If mercury is present)

CLR-10(Mercury removal)

Neutralization coagulationsettlement treatment

CLR-20(Heavy metal removal)

Type Chelating resins

Grade CLR-08 CLR-09 CLR-10 CLR-20 CLR-B3 CLR-B3UP CLR-F CLR-N


Functional group

Iminodia-cetate

Aminomethyl-phosphonate

Thiouronium Polyamine Glucamine GlucamineAmino-

phosphonateTriethylamine

Ionic form Na+ Na+ H+ OH- Free base Free base Al³+ Cl-

Total capacity (eq/ℓ)

Cu2+ 0.5↑

Ca2+ 0.4↑Ca2+ 0.6↑ 1.1↑

4mol↑as copper

0.6eq/ℓ↑as boron

0.6eq/ℓ↑as boron

11g↑ as fluorine

1.0↑

Particle size (㎛) 400~1,000 400~1,000 300~1,250 400~1,250 300~1,250 300~1,250 300~1,000 300~1,250

Equivalent

· Lewatit TP208

· Amberlite IRC748

· Diaion CR11· Purolite

S930

· Lewatit TP260

· Amberlite IRC747

· Purolite S940

· Eporous-Z7· Purolite

S924

· Diaion CR20

· Eporous MX-8C

· Diaion CRB03

· Amberlite IRA743

· Purolite S108

· Diaion CRBT03

· Eporous-K1· READ-F

· Amberlite IRA996

· Purolite A520E

CLR-10 (Optional)

CLR-20

Sandfilter

Activated carbon

filter

P

P

P

M M

Waste water

containing

heavy metal

Waste waterstorage pit

Neutralizingreaction pit

Clarifier

Dischargingor

recycling

pH adjusting pitChelating resin towerpH adjusting pit

Neutralizingagent

Neutralizingagent

Neutralizingagent

Coagulant

M


Ready to use Mixed Resins

Ready to use mixed resins produce high purity water in a more convenient way. Up to the usage of water

volume, they are widely used for cartridges or pressure vessels which do not require a complicated

regeneration process. The primary application for TRILITE SM200, SM210 is in Wire EDM applications. It features

an outstanding amount of treated water compared to other ready to use mixed resins in the market. TRILITE

SM300 used after RO(Reverse osmosis) in Make-up systems, results in treated water quality close to that of

Ultrapure water (Resistivity > 15.0MΩ·cm).

Type Ready to use mixed resins

Grade SM200 SM210 SM300


Functional group Mixed resin


Particle size (㎛) 300~1,200 (Uniformity Coefficient 1.6↓)


Ionic formH+ (H% 99%↑)

OH- (OH% 90%↑)H+ (H% 99%↑)

OH- (OH% 95%↑)H+ (H% 99%↑)

OH- (OH% 95%↑)

Mixed Ratio, Volume 45:55 45:55 40:60

Operating capacity (eq/ℓ)0.4↑ (Feed water :

Conductivity 150㎲/㎝Potable water, SV36)

0.5↑ (Feed water :Conductivity 150㎲/㎝Potable water, SV36)

0.5↑ (Feed water :Conductivity 10㎲/㎝

RO outlet, SV36)

Outlet conditionResistivity > 10.0MΩ·cm(Feed water : Tap water)

Resistivity > 10.0MΩ·cm(Feed water : Tap water)

Resistivity > 15.0MΩ·cm(Feed water : Post-RO)

※ The data for Specific gravity and Operating capacity is for reference.

Gradename

Feature & Application

Components Treated water quality

SM200

Simple production of pure water from tab water For Laboratories,Wire-cutting(EDM)

KC-08H(H+ 99.0%↑)KA-12OH(OH- 90.0%↑)

Mixed ratio(Volume) : 45:55

OutGuarantee) Resistivity > 10.0 MΩ·cm (in 10min.)


Feed Conductivity 150㎲/㎝ Potable water, SV36

SM210

Simple production of pure water from tab water For Laboratories,Wire-cutting(EDM)

SCR-BH(H+ 99.0%↑)SAR12OH(OH- 95.0%↑)




Feed Conductivity 150㎲/㎝ Potable water, SV36

SM300

High Resistivity andsuperb SiO2 removal ability MB for Post-RO and EDI

SCR-BH(H+ 99.0%↑)SAR12OH(OH- 95.0%↑)




Feed Conductivity 10㎲/㎝ RO outlet, SV36

UPRM100U(UPS)

Very high resistivity,Electronics GradeUltrapure water

UPRC100U(H+ 99.0%↑)UPRA100U(OH- 95.0%↑)

Mixed ratio(Capacity) : 50:50



Feed Conductivity 10㎲/㎝ RO outlet, SV36

UPRM200U(UPS)

Very high resistivity, Low ΔTOC level LCD, OLED Ultrapure water final polisher

UPRC200U(H+ 99.0%↑)UPRA200U(OH- 95.0%↑)


OutResistivity >18.1㏁·㎝ (in 30min.)

△TOC < 5ppb (in 120min.)

Feed Resistivity > 17.5㏁·㎝, TOC < 2ppb, SV30

UPRM300U(UPS)

Extremely high resistivity Extremely, low ΔTOC level Metal ion < 0.1pptSemiconductor Ultrapure water final polisher

UPRC300U(H+ 99.9%↑)UPRA300U(OH- 97.0%↑)


OutResistivity > 18.2㏁·㎝ (in 30min.)

△TOC < 1ppb (in 180min.)Metal ion < 0.1ppt

Feed Resistivity > 17.5㏁·㎝, TOC < 2ppb, SV30


Type Styrene TypeChemically Modified

Styrene Type

Grade GSH-20 GSP-25 GSP-50 GSP-07

Chemical structure

CH2－CH－

－CH₂－CH－CH₂－CH－

CH₂－CH－ Br

－CH₂－CH－CH₂－CH－

Specific surface area (㎡/g) 750↑ 1,100↑ 1,000↑ 600↑

Pore Volume (㎡/g) 1.0~1.5 1.2~1.6 0.9~1.1 0.8~1.0

Pore radius (Å) 50~80 45~55 30~50 50~70

Particle size (㎛) 315~1,250 250~700 250~700 250~700

Equivalent Diaion HP20 Diaion SP825 Diaion SP850 Diaion SP207

Applications

TRILITE GSH-20 Widely used in refining of pharmaceuticals and natural extracts, since these are suitable

for adsorbing large molecules because of their relatively large pore sizes and superior

adsorption/ desorption. GSH20 is widely used in various industrial applications, especially

adsorption, desalting and Decolorization of natural products and small proteins.

TRILITE GSP-25, These have much larger surface area and a narrower, more uniform pore-size distribution

TRILITE GSP-50 than GSH-20. They offer nearly one and half times the surface area of GSH-20. With large

surface area and narrower pore radius, it selectively adsorbs small molecules and excludes

larger molecules. This grade is recommended for adsorption, desalting and decolorization.

TRILITE GSP-07 With high hydrophobicity, TRILITE GSP-07 has higher selectivity for non-polar molecules

than standard aromatic adsorbents, due to its chemically bonded bromine to the aromatic

rings. It is suitable for upward flow and batch processes due to its high specific gravity but

also for treatment of heavy liquid such as purification of hydrogen peroxide in electric and

electronic industry.


EO/EG Cycle Water TreatmentInert resins

Anion resins for Layered Bed

Inert resins are non-fuctionalized polymers developed for use as an upper layer in packed bed system, and also

used to enhance separation of catoin and anion exchange resins prior to regeneration in Triobed system.

Type Inert resins

Grade TR70 TR30

Matrix Polyethylene Polystyrene＋DVB

Functional group None

Shipping weight (g/ℓ) 500 725

Particle size (㎛) 1,200~1,800 700~900

Operating temp. (℃) 90↓ 100↓

Remarks

The specific gravity islower than that of

water, it locates as top layer with in an IER tower, keeping the

layers compact, preventing any loss of active finer resins and improving the

regenerant distributionefficiency.

The specific gravity lies in the middle of that of cation resins

and anion resin. It forms a borderbetween them.

It eases separation of cation and anion resins, preventing

any counter regeneration hence improving the purity

of treated water.

NaOH

TRILITE TR70

IER

Freeboard

Regenerant

Service

Middle distributor

SAC

SBA

HCl

Packed bed Triobed

Freeboard

TRILITETR30

A layered bed water treatment system allows economical production of pure water through simultaneous

employment of Strongly Basic Anion(SBA) and Weakly Basic Anion(WBA) resins for an anion exchanger. Successive

regeneration of WBA resin with regeneration waste water of SBA resin enables high regeneration efficiency and ability

to cope with the change of raw water with a good resistance to organic fouling of resins.

TypeLayered bed anion resins

WBA SBA

Grade AW90LB KA18LB


(Porous type)Polystyrene＋DVB

(Gel type 1)

Functional group Tertiary Amine-N＋(CH3)3

(TMA, Trimethyl-ammonium)

Ionic form Free Base Cl-

Specific gravity 1.04 1.11

Shipping weight (g/ℓ) 640 675

Moisture retention (%) 40~50 43∼47

Total capacity (eq/ℓ) 1.6↑ 1.3↑


Particle size (㎛) 550±50 600~1,200

Operating temp. (℃) 60↓60↓ (OH- type)80↓ (Cl- type)

Operating pH range 0~9 0∼14

Swelling rate(FB → Cl-, Cl- → OH-)

20% 24%

Layered bed

Service

TRILITE KA18LB

TRILITE AW90LB

Freeboard

Regenerant

TRILITE KA18LB

TRILITE AW90LB

Freeboard

AW90LB

KA18LB



EO/EG

cycle water

EO(Ethylene oxide)/EG(Ethylene glycol) cycle water treatment is essential for MEG(Mono-ethylene glycol)

prodution. There occurs various types of impurities during the process, so the combination of several special

resins are being applied to remove them.

- Metal ion removal : Catalyst resin - SPC260EGH

- Aldehyde removal : Aldehyde removal resin(ARR) - AMP16EG

- Other organic acid removal : Weak base anion(WBA) resin - AW90EG

TypeEO/EG Cycle Water Treatment

SAC SBA WBA

Grade SPC260EGH AMP16EG AW90EG




(Porous type)


-N＋(CH3)3 (TMA, Trimethylammonium)

Tertiary Amine

Ionic form H＋ Cl- Free Base


Moisture retention (%) 50~58 49∼55 40~50


Effective size (㎛) 400↑ 400↑ UPS

Uniformity coefficient 1.6↓ 1.6↓ 1.1↓

Particle size (㎛) 300~1,200 550±50

Operating temp. (℃) 120↓ 70↓ (OH- type)90↓ (Cl- type)

60↓

Operating pH range 0∼14 0∼14 0~9


Ethylene+

O2

EO(Ethylene Oxide)

Stripping column

ScrubberGlycol

adsorption column

Evaporator

Dry column

MEG(Mono-ethylene

glycol)SAC WBASBAVacuum

degasifier

Sodium acetate

CO2

HCOOH

CH3COOH

Impurities in cycle water

ARRAldehyde

Removal Resin

Cationexchanger

Anionexchanger

With Silver Oxideas catalyst

NaOH(pH adjustme)

MEG process


COA (from DB)

Quality Assurance System (Self-manufacturing/OEM)

TRILITE Ion Exchange Resins assure strict quality management under ISO9001 Quality Assurance System.

TRILITE OEM products are being produced under the same quality assurance system, and through the pre-

shipment & on-arrival sample test, Samyang assures the trustworthy quality of the products.

Sampling

Customer

ISO9001

Shipping COA (from DB) Packing

Process Analysis

Keeping samples(for 4years)

Producthopper

DB

Y N

Periodical analysis

Osmotic shock stability Friability

Optional analysis

H/OH Conversion rate ResistivityΔTOC

Basic analysis

Bulk density Moisture retention Particle distributionExchange capacity Whole bead count

충전 역세 정치

눈금을 읽음

Qualitytest

Customer

Packing

① Production order

⑤ Product inspection

③ Product analysis

OEM Plant A OEM Plant B

1 2

Purchasing TRILITE means more than just a stable supply of high quality products . Our technical sales team

is subdivided into three specialized groups, and provides professional Total solutions as per the various

applications requested by customers. And, also Samyang IER Tech-center located in Daejeon provides analysis

service of resins with state-of-the-art facilities and other Pilot tests upon requests.

.exe

Kor/Chn/EngVersion Download

Samyang IER Tech-center located in Daejoen

provides resin analysis service for used resins and

resins for replacement . Multiperspective analysis

examines various fouling and performance of resins

for the most efficienct operation of facilities.

Ion exchange resin analysis

Samyang TriAngleTM is calculation software designing

water treatment system with ion exchange resins . User

friendly interface of the program supports economic

design of required resin quantity for the towers , as per

the various applications.

QR code scan or www.samyangtrilite.com

Ion exchange resin design program TriAngleTM

Samyang's professional engineers provide facility

diagnosis and optimised retofit proposals along with

trouble shooting guidelines for the problematic facility.

Facility diagnosisand retrofit proposalt

Samyang provides process development service for

various applications of IERs, including Lab. Test and

Pilot test.

Customised process developmentservices using various IERs

Analysis report

Applying for sample analysis

IER Analysis

ProcessConduct of analysis

Receiving of request

with sample

Inquiry to | Samyang Corporation | Ion Exchange Resin Team

· TEL : 02 740 7732~7 · E-mail : [email protected] · http://www.samyangtrilite.com

3 4

Technical Services

Performance

Economy

Basic

Shipback

Shipment

DB

Ulsan plant (UPW/Tailored/Specialty)

Seoul (HQ)

• Recipe supply

• Specification control

• Technical data analysis

• Product analysis

• Final product inspection

• Repacking & Shipping

• OEM contract• Production scheduling• Import processing

Process analysis

N

Y

Qualitytest

Qualitytest

N

Y

② Productio completion & sending samples by batch

④ Packing & shipping order

• Basic analysis

• Optional analysis

• Periodical analysis

Trucking, Shipping

Daejeon (Tech-center)

44 45Ion Exchange Resins Product List Ion Exchange Resins Product List 45Ion Exchange Resins Product List

1. Handling

Protective equipment must be used to protect eyes and skin, and resins must be handled in a place with good

ventilation. Eye-wash facilities are recommended at the work spot. When resins are spilled on the floor, they

are very slippery and may cause a person to fall. Avoid exposure to high temperature, sparks, flames, etc. Also,

avoid contact or mixing with oxidizing agents such as nitric acid because ion exchange resins can explode on

contact with nitric acid.

2. Storage

Resins should be stored in dry, cool and dark places where proper ventilation system is installed. The storage

container and bag of fiber drum should be tightly closed to prevent intrusion of impurities and drying of resins.

Do not store resins near oxidizing agents. At high temperature, rapid degradation of resins may occur, and

below 0℃, freezing of resins may occur which may cause physical breakage.

Factors affecting quality of resins in storage

Humidity

The ion exchange resin consists of about 50% water. When the dried resin comes in contact with moisture

again, the resins may crack due to osmotic shock.

Freeze and Defrost

Sudden freezing and defrosting of resins can take place and this may have a physical effect on the ion

exchange resin.

(Note: Freezing and defrosting should be avoided especially for Porous type.)

Abrupt temperature change

Sudden temperature changes can cause cracks on the surface of the ion exchange resin and cause

physical deterioration.

Physical shock

Over loading of resins on pallet for transport and storage should be avoided. Care should be taken as ion

exchange resins are susceptible to physical shock.

3. Disposal

Unused resins may be discarded in the landfill or by incineration following local regulations and the cautions

mentioned above. A suitable fitted furnace is necessary for incineration because SOX, NOX, COX and others will

be generated from the incineration.

Used resins may also be land-filled or incinerated as long as they contain no toxic or poisonous material such

as heavy metals. Resin can only be discarded, as above, after removal of poisonous material.

● The contents in this catalog might be changed without previous notice. March 2019 Edition

Cautions on Use of Ion Exchange ResinsQuality Certificates

Packing & Container Loading

TRILITE Ion Exchange Resins are supplied in various types of packaging, 25ℓ PE bag, 1,000ℓ bag (supersack),

5~7ft3 fiber drums and others to ensure customer preference when handling resins. Systematic manuals for

shipment and container loading assure minimization of any probable damage to products while transporting.

The work footages are shared with customers in real-time for customer satisfaction.

25ℓ PE bag1,000ℓ Ton bag

50ℓ Plastic drum

5 or 7ft3

Fiber Drum5ℓ

Vacuum Packing

Palletizing, Container Loading (1000ℓ)

Automatic Packing Manual Packing

HALAL Certificate

MUI JAKIMKMF

ISO9001 Certificate Veritas Certificate

Palletizing, Container Loading (25ℓ)

※ Bureau Ver i tas ( f rance) i s an institution which has the world wide experience and expertise to take on the quality certification of ion exchange resins for power plant applications.

TRILITE is being audited regularly to maintain ISO9001 Quality Assurance System and also being carried on

improvement of its QA & QC proceses. TRILITE is granted for its qualification in accordance with international

certificate authorities, Halal for Islamic countries and Veritas for power plants.

Contact us from your

mobile with messengers

WhatsApp+82 10-2790-4819

LineID : TRILITE

Kakao talkID : TRILITE

We chatID : TRILITEor Scan QR-code

Samyang Corporation Ion Exchange Resin Team

31, Jong-ro 33-gil, Jongno-gu, Seoul, Korea

TEL : +82 2 740 7732~7

E-mail : [email protected]

http://www.samyangtrilite.com

Date post:	12-Nov-2021
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