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Isomerization of M-xylene - docsdrive.comdocsdrive.com/pdfs/ansinet/jas/2005/236-248.pdf · Title:...

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  • H+

    H+

    CH3 First kinetic model for isomerization

    CH3

    CH3

    + H+ CH3

    H+

    CH3 H+

    +

    CH3

    CH3

    H+ H+ CH3

    H+

    CH3

    CH3 CH3 +

    kp

    ko

    Second kinetic model for disproportionation

    CH3

    CH3

    H+

    H+ +

    CH3

    CH3

    CH3

    CH3 CH3

    CH3

    H+

    CH3

    CH3

    H+ CH3

    CH3 H+

    CH3

    CH3

    CH3

    CH3 CH3

    CH3

    CH3 -H+

    CH3

    CH3

    CH3

    CH3

    CH3

    CH3 ki

    k-i

    ks

    C6H5CH3 C6H3(CH3)3

    ks

    Triangular model for isomerization and disproportionation

  • UntitledJAS.pdfPage 1

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