JOAN D. WILLEY Personal Married, with children Telephone Number: 910-962-3459; Fax: 910-962-3013; e mail: willeyj@uncw.edu Education Duke University, North Carolina, 1965-1969, B.Sc. in Chemistry Duke University, Marine Laboratory, summers of 1968 and 1969 Dalhousie University, Nova Scotia, 1969-1975, Ph.D. in Chemical Oceanography Scholarships, Fellowships and Awards National Science Foundation Predoctoral Award, summer 1969 Dalhousie University Fellowship, 1969 to January of 1974 Memorial University of Newfoundland Post-doctoral Fellowship, February 1974 to September 1975 National Research Council of Canada Post-doctoral Fellowship, January 1976 to August 1977 DeLoach Professor of Chemistry, July 1991 - June 1996 University of North Carolina at Wilmington Award for Faculty Scholarship, 1994 Research Reassignment, August 1995 - May 1996, Guest Investigator at the Woods Hole Oceanographic

Institution and at the Graduate School of Oceanography, University of Rhode Island Camille and Henry Dreyfus Scholar University of North Carolina at Wilmington Graduate Mentor Award, 2004 Exemplary Rating, UNCW Five Year Post Tenure Review, 2001 and 2006 External Examiner, Ph.D. Candidate, University of Utrecht, the Netherlands 2009 Pi Delta Phi, Nu Kappa Chapter, Honorary Member (French Honor Society) 2011 Employment History Analytical chemist, Humble Oil and Refining Company, Lubricants Testing Laboratory, Pittsburgh, Pennsylvania,

summers of 1966 through 1968 Geochemist, Duke University Marine Laboratory, Sedimentology Laboratory, Beaufort, North Carolina, l969 Post-doctoral Fellow, Department of Geology, Memorial University of Newfoundland, St. John's Newfoundland,

l974-1975 Visiting Scientist, Environmental Marine Geology, Atlantic Geoscience Centre, Bedford Institute of

Oceanography, Dartmouth, Nova Scotia, 1975-1977 Assistant Professor, Division of Chemistry, University of North Carolina at Wilmington, l977-1982 Associate Professor, Division of Chemistry, University of North Carolina at Wilmington, 1982-1986 Professor, Department of Chemistry, University of North Carolina at Wilmington, 1986-present, Graduate Coordinator, Department of Chemistry, University of North Carolina at Wilmington, 1988-1994 Oceanography Program Coordinator, University of North Carolina at Wilmington Center for Marine Science

Research, 1989-1994 Adjunct Graduate Faculty, Department of Marine, Earth and Atmospheric Sciences, North Carolina State

University, 1990-present Adjunct Faculty, Department of Marine Sciences, University of North Carolina at Chapel Hill, 1994-present Interim Dean of the Graduate School, University of North Carolina at Wilmington, July 1, 1994-June 30, 1995 Assistant Chair, Department of Chemistry, University of North Carolina at Wilmington, 1997-1998 Associate Director for Education, Center for Marine Science, University of North Carolina at Wilmington, 1999-

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present Representative Professional Activities Participant, RV "Eastward" cruises in 1968, 1969, and 1980, and RV "Cape Hatteras" cruises in 1982, 1984,

1987, 1991, 1993, 1994, 1995, 2008; RV "Edwin Link" cruise and "Sea Link" submersible dive in 1989; RV "Seward Johnson" cruise in 1991, RV “Endeavor” cruise in 2000

Scientist, RV "Dawson" cruises to Bermuda and the North Atlantic, 1970-1974 Co-Chief Scientist, RV "Rita Maxwell" cruises in Placentia Bay, Newfoundland, Canada, 1974-1975 Scientist, Multidisciplinary Sampling Program, Miramichi Estuary, New Brunswick, Canada, 1975-1977 University Committee Service, 1978-present: Continuing Education, Research, Arts and Sciences Curriculum, Faculty Hearings, Promotion and Tenure, Marine Science Research Advisory Board, University Planning Committee, Buildings and Grounds Committee (chair 1992-1994), Arboretum Task Force, College of Arts and Sciences Planning Committee, Athletics Committee, Graduate Council, Professional Relations Committee, Hurricane Committee , CMS Internal Advisory Committee, CMS Center Research Investigators Strategic Planning Committee, CMS Education Committee (chair 1998 – present), CMS External Advisory Committee. Journal reviewer (Atmospheric Environment, Global Biogeochemical Cycles, Journal of Geophysical Research,

Geochimica et Cosmochimica Acta, Geophysical Research Letters, Global and Planetary Change, Estuarine, Coastal and Shelf Science, Environmental Science and Technology, Journal of Atmospheric Chemistry, Estuaries, Marine Ecology Progress Series, Nature, Science of the Total Environment, Sedimentary Geology, Marine Chemistry, Kuwait Journal of Science and Technology, Biogeochemistry), 1979-present

Proposal reviewer for the National Science Foundation, Sea Grant and many other agencies, 1985-present General College Advisor, 1980-1981 Associate Editor, Journal of the North Carolina Academy of Science, 1980-1982 Editorial Board, Marine Chemistry, 1983 - 1992 Duke-UNC Oceanographic Consortium Program Advisory Committee, 1990-1996, 1999-2002 University of North Carolina System Graduate Council 1999 - 2001 North Carolina Water Quality Workgroup (UNC System and NC Department of Environment and Natural

Resources) 1999-2005 Co-convener session: Atmospheric Wet Deposition, Aqueous Phase Photochemistry, and Potential

Impacts on Biogeochemical Cycles, AGU Fall Meeting San Francisco, CA. Dec. 5-9, 2011

Membership in Professional Societies American Chemical Society, Geochemistry Section American Geophysical Union, Oceanography Section American Society of Limnology and Oceanography North Carolina Academy of Science Phi Kappa Phi National Honor Society Sigma Phi Sigma (National Physics Honor Society) Sigma Xi (Scientific Research Society) The Oceanographic Society Research Grants North Carolina Marine Science Council Grants, $4,000 in 1978 and $3,780 in 1979

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American Chemical Society Travel Grants, $100 per year, 1979 and 1980 Philadelphia Quartz Corporation (PQ) Honorarium, $256, 1981 University of North Carolina at Wilmington Faculty Development Grant, $550, 1982 National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, $29,800,

1985 National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, $35,867,

1988 National Science Foundation Research Experience for Undergraduates Grant, Atmospheric Chemistry, $4000,

1990 Duke/UNC Oceanographic Consortium Shiptime, 8 days shiptime plus $1,000, 1993 (with R. J. Kieber, and P. J.

Seaton) National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, with R. J.

Kieber, $135,000, 1994-1996 North Carolina Federation of the Environment Grant, with Marc J. Alperin (UNCCH) and Hans W. Paerl

(IMS-UNCCH), $10,000, 1995 National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, with R. J.

Kieber, $236,465, 1996-1998 Camille and Henry Dreyfus Foundation Scholar/Fellow Program for Undergraduate Institutions, $60,000, 1997-

1999 National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, with R. J.

Kieber , $297,833, 1998-2001 National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, with R. J.

Kieber and S. A. Skrabal , $414,775, 2001-2004. Sea Grant, R. J. Kieber and S. A. Skrabal, $111,720, 2002-2004. Sea Grant, R. J. Kieber and S. A. Skrabal, $203,000, 2004-2006 National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, with R. J.

Kieber and R.F. Whitehead, $499,189, 2004-2007. National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, with R. J.

Kieber, G.B. Avery and R.F. Whitehead, $532,752, 2007-2010. National Science Foundation REU Supplement, Atmospheric Chemistry, with R. J. Kieber and M. W. Southwell, $6,830.00, June 1, 2008 - August 31, 2010. Duke UNC Oceanographic Consortium, with R. N. Mead (Principal), G. B. Avery, R. J. Kieber, S. A. Skrabal, B.

K. Song, and C. R. Tobias, $78,000, June 1, 2008 - June 10, 2008. National Science Foundation Major Research Instrument, with P. J. Seaton (Principal), J. B. Morgan, S,

Varadarajan, C. J. Halkides, P. F. Almeida, R. J. Kieber, G. B. Avery, S. T. Kinsey, J. L. Wright, $700,000, August 1, 2009 - Present.

National Science Foundation Research at Undergraduate Institutions Grant, Atmospheric Chemistry, with R. J. Kieber, G. B. Avery and R. N. Mead, $622,400, 2010-2013.

National Science Foundation, Chemical Oceanography and International Office for Science and Engineering, with S. A. Skrabal and P. J. Statham (Southampton University, UK), $559,094, submitted February 15, 2012. PENDING.

Teaching Experience Graduate courses taught: Introduction to Chemical Research, Global Environmental Problems, Aquatic

Chemistry, Chemical Oceanography, Chemical Analysis of Natural Waters, Cruise and Field Sampling, Seminar in Marine Science

Undergraduate courses taught: Introduction to Chemical Research, Environmental Chemistry, Environmental Chemistry Laboratory, Chemical Oceanography, Analytical Chemistry Laboratory, General Chemistry,

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Senior Seminar Other teaching interests: Atmospheric Chemistry, Marine Geochemistry, Estuarine Chemistry Research Interests Rainwater composition and impact on coastal and open ocean seawater, trace metal speciation in rain and coastal

waters (Fe, Cr, Cu, Hg, Mn, Zn), redox chemistry of rain, silica geochemistry, chemical reactions during estuarine mixing, sediment-seawater interactions, photochemical reactions in natural waters

Since 1978, seventy-five undergraduate students have worked on various research projects with Dr. Willey,

eighteen of whom were honor students. Dr. Willey has supervised forty master's degree students, one doctoral student and six post-doctoral fellows. All students have given presentations on their research; the honor’s, master’s and Ph.D. students also wrote theses.

Refereed Publications Willey, Joan D., "The Effect of Pressure on the Solubility of Amorphous Silica in Seawater at Oo C," Marine

Chemistry 2:239-250 (1974). Willey, Joan D., "Reactions Which Remove Dissolved Alumina From Seawater," Marine Chemistry, 3:227-240

(1975). Willey, Joan D., "Silica-alumina Interactions in Seawater," Marine Chemistry, 3:241-251 (1975). Willey, Joan D., "Geochemistry and Environmental Implications of the Surficial Sediments in Northern Placentia

Bay, Newfoundland," Canadian Journal of Earth Sciences 13(10):1393-1410 (1976). Willey, Joan D., "Seasonal Variations in the Oceanography and Sediment Geochemistry in the Miramichi

Estuary, New Brunswick: A Preliminary Report," Geological Survey of Canada, Paper 76-1C, pp 47-50 (1976).

Willey, Joan D., "Reactions Which Remove Trace Metals From Seawater: Preliminary Observations," Geological

Survey of Canada, Paper 76-1C, p. 71 (1976). Duedall,I. W., Ramesh Dayal and Joan D. Willey, "The Partial Molal Volume of Silicic Acid in 0.725 m NaCl

and in Seawater," Geochimica et Cosmochimica Acta 40:1185-1189 (1976). Willey, Joan D., "Coprecipitation of Dissolved Silica With Zinc in Seawater," Marine Chemistry, 5:267-290

(1977). Willey, Joan D., "Release and Uptake of Dissolved Silica in Seawater by Marine Sediments," Marine Chemistry,

7:53-65 (1978). Willey, Joan D., "Effects of Aging on Silica Solubility: A Laboratory Study," Geochimica et Cosmochimica

Acta, 44:573-578 (1980). Willey, Joan D. and Robert A. Fitzgerald, "Trace Metal Geochemistry in Sediments from the Miramichi Estuary,

New Brunswick," Canadian Journal of Earth Sciences 17(2):254-265 (1980).

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Willey, Joan D. and Larry P. Atkinson, "Natural Fluorescence as a Tracer for Distinguishing Between Piedmont and Coastal Plain River Water in the Nearshore Waters of Georgia and North Carolina," Estuarine and Coastal Marine Science (14):49-59 (1982).

Willey, Joan D., "Aging of Amorphous Silica in Salt Water Solutions," Soluble Silicates, Advances in Chemistry

Series, American Chemical Society, Washington, D. C., pp. l49-164 (1982). Willey, Joan D., "Partial Molal Volume Calculations for the Dissolution of Aged Amorphous Silica in Salt Water

and Seawater at 0-2o," Geochimica et Cosmochimica Acta 46:1307-1310 (1982). Willey, Joan D., "Solvent-ion Interactions in Salt Water: A Simple Experiment," Journal of Chemical Education

61:727-728 (1984). Willey, Joan D., "The effect of seawater magnesium on natural fluorescence during estuarine mixing, and

implications for tracer applications," Marine Chemistry 15:19-45 (1984). Paerl, H. W., and Joan D. Willey, "Deposition and Effects in Coastal Areas," in Acid Rain in North Carolina, The

Acid Rain Foundation, Inc., Minnesota, 1986. Willey, Joan D., Ramona I. Bennett, Jeanne M. Williams, Robert K. Denne, Cynthia R. Kornegay, Mark S.

Perlotto and Beth M. Moore, "Effect of Storm Type on Rainwater Composition in Southeastern North Carolina," Environmental Science and Technology 22(1):41-46 (1988).

Willey, Joan D., John R. Kucklick, and G. Brooks Avery, Jr., "Rainwater-SurfaceWater Interactions in

Southeastern North Carolina," in: Carolina Coastal Oceanography, R.Y. George and A.W. Hulbert, editors, National Undersea Research Program Research Report 89-2 (1989).

Willey, Joan D. and Rudi H. Kiefer, "A Contrast in Winter Rainwater Composition: Maritime versus Continental

Rain in Eastern North Carolina," Monthly Weather Review (The Journal of the American Meteorological Society) 118(2):488-494 (1990).

Willey, Joan D. and Lawrence B. Cahoon, "Enhancement of Chlorophyll a Production in Gulf Stream Surface

Seawater by Rainwater Nitrate," Marine Chemistry, 34:63-75 (1991). Willey, Joan D. and John H. Hackney, "Chemical Interactions Between Acid Rain and Dogwood Leaves," Journal

of the Elisha Mitchell Scientific Society, 107(2): 83-88 (1991). Avery, G. B., Jr., Joan D. Willey and Carol A. Wilson, "Formic and Acetic Acids in Coastal North Carolina

Rainwater," Environmental Science and Technology, 25: 1875-1880 (1991). Willey, Joan D. and G. Brooks Avery, Jr., Responses to Comments on "Formic and Acetic Acids in Coastal North

Carolina Rainwater," Environmental Science and Technology, 26: 1260 and 1666-1667 (1992). Willey, Joan D. and Carol A. Wilson, "Formic and Acetic Acids in Atmospheric Condensate in Wilmington,

North Carolina," Journal of Atmospheric Chemistry, 16: 123-133 (1993). Willey, Joan D. and Hans W. Paerl, "Enhancement of Chlorophyll a Production in Gulf Stream Surface Seawater

by Synthetic Versus Natural Rain," Marine Biology, 116: 329-334 (1993).

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Willey, Joan D. and Rudi H. Kiefer, "Atmospheric Deposition in Southeastern North Carolina: Composition and Quantity," Journal of the Elisha Mitchell Scientific Society, 109 (1): 1-19 (1993).

Cahoon, L. B., John R. Kucklick, Rudi H. Kiefer and Joan D. Willey, "The Effects of Chemical Weathering on

Limestone Dissolution and Phosphate Release into Lake Waccamaw, North Carolina," Journal of the Elisha Mitchell Scientific Society, 109 (3): 123-134 (1993).

Willey, Joan D., "A Decade of Rainwater Research," UNCW Discovery 5(1): 2-4 (1994). Wagoner, David B., Lawrence B. Cahoon, and Joan D. Willey, “A Trophic State Evaluation of Trask’s Pond and

Bluethenthal Wildflower Preserve Pond, Wilmington, North Carolina,” CANCAS, Collegiate Academy of the North Carolina Academy of Science, 40 (1):101-119 (1994).

Willey, Joan D., Robert J. Kieber, and Richard D. Lancaster, “Coastal Rainwater Hydrogen Peroxide:

Concentration and Deposition,” J. Atmospheric Chemistry, 25: 149-165 (1996). Willey, Joan D. and Arthur Spivack, "Dissolved Silica Concentrations and Reactions in Pore Waters from

Continental Slope Sediments Offshore from Cape Hatteras, North Carolina, USA," Marine Chemistry, 56: 227-238 (1997).

DeForest, Cindy L., Robert J. Kieber, and Joan D. Willey, "Comparison of Stripping Coil and Condensate

Techniques for the Collection of Gas Phase Hydrogen Peroxide, with Applications of Condensate Collection in and off the Coast of North Carolina, USA", Environmental Science and Technology, 31(11): 3068-3073 (1997).

Kieber, R. J., Kris A. Rudolph, Sybil K. Burgess and Joan D. Willey, “Effect of Acid Rain on Alkalinity and

Calcium Carbonate Dissolution in the Albemarle Sound of North Carolina, USA,” Journal of the Elisha Mitchell Scientific Society, 114(2): 63-71 (1998).

Willey, Joan D., Hans W. Paerl, and Malia Go. “Impact of Rainwater Hydrogen Peroxide on Chlorophyll a

Content of Surface Gulf Stream Seawater off North Carolina, USA,” Marine Ecology Progress Series, 178, 145-150 (1999).

Willey, Joan D., Joan D. Willey, Malia Go, Benjamin L. Peirels, James L. Pinckney, and Marilyn L. Fogel.

“Rainfall Stimulation of Primary Production in Western Atlantic Ocean Waters: Roles of Different Nitrogen Sources and Co-limiting Nutrients,” Marine Ecology Progress Series, 176, 205-214 (1999).

.Fogel, M. L., Carmen Aguilar, Russell Cuhel, David J. Hollander, Joan D. Willey, and Hans W. Paerl.

“Biological and Isotopic Changes in Coastal Waters Induced by Hurricane Gordon,” Limnology and Oceanography 44(6), 1359-1369 (1999).

Kieber, R. J., Matthew F. Rhines, Joan D. Willey, and G. Brooks Avery. "Nitrite Variability in Coastal North

Carolina Rainwater and its Impact on the Nitrogen Cycle in Rain," Environ. Sci. Technol. 33(3), 373-377 (1999)

Kieber, R. J., Matthew F. Rhines, Joan D. Willey, and G. Brooks Avery. "Rainwater Formaldehyde:

Concentration, Deposition and Photochemical Formation," Atmos. Environ. 33(22),3659-3667 (1999). Willey, Joan D., G. Brooks Avery, John J. Manock, Stephen A. Skrabal, and Charles F. Stehman. “Chemical

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Analysis of Soils: An Environmental Chemistry Laboratory for Undergraduate Science Majors,” J. Chem. Ed., 76, 1693-1694 (1999).

Willey, Joan D., Robert J. Kieber, Mary S. Eyman, and G. Brooks Avery. “Rainwater Dissolved Organic Carbon:

Concentrations and Global Flux,” Global Biogeochemical Cycles, 14(1): 139-148 (2000). Willey, Joan D., Robert J. Kieber, Kelly H. Williams, Jamie S. Crozier, Stephen A. Skrabal and G. Brooks Avery.

“Temporal Variability of Iron Speciation in Coastal Rainwater,” J. Atmos. Chem. 37, 185-205 (2000). Kieber, R. J., Kelly H. Williams, Joan D. Willey, Stephen A. Skrabal and G. Brooks Avery.“Iron Speciation in

Coastal Rainwater: Concentration and Deposition to Seawater,” Mar. Chem., 73, 83-95 (2001) Kieber, R. J., William J. Cooper, Joan D. Willey and G. Brooks Avery. “Hydrogen Peroxide at the Bermuda

Atlantic Time Series Station. Part 1: Temporal Variability of Atmospheric Hydrogen Peroxide and its Influence on Seawater Concentrations” J. Atmos. Chem. 39, 1-13 (2001)

Kieber, R. J., Barrie Peake, Joan D. Willey and Bethany Jacobs. “Iron Speciation and Hydrogen Peroxide

Concentrations in New Zealand Rainwater,” Atmos. Environ. 35:6041-6048 (2001). Avery, G. B., Joan D. Willey, and Robert J. Kieber. “Diurnal Variations in Major Rainwater Components at a

Coastal Site in North Carolina,” Atmos. Environ. 35:3927-3933 (2001). Avery, G. B., Yan Tang, Robert J. Kieber and Joan D. Willey. “Impact of Recent Urbanization on Formic and

Acetic Acid Concentrations in Coastal North Carolina Rainwater” Atmos. Environ, 35(19), 3353-3359 (2001).

Kieber, R. J., Barrie Peake, Joan D. Willey and G. Brooks Avery. “Dissolved Organic Carbon and Organic Acids

in Coastal New Zealand Rainwater,” Atmos. Environ. vol. 36, p. 3557- 3563 (2002). Peake, B. M.,S. J. Collett, P. Labadie, L. M. Mosley, R.J Kieber and J. D. Willey. “UV Radiation And The

Production of Reactive Oxygen Species (ROS) in Aquatic Environments.” p. 70-72 In: UV Radiation and its Effects - An Update 2002, RSNZ Miscellaneous Series 60, Royal Society of New Zealand, Wellington, pp126, 2002.

Kieber, R. J., Joan D. Willey and Suzanne D. Zvalaren. “Chromium Speciation in Coastal Rainwater: Temporal

Variability and Atmospheric Deposition,” Environ. Sci. Technol. Vol 36, p. 5321-5327 (2002). Kieber, R. J., D.R. Hardison, R.F. Whitehead and J.D. Willey. “Photochemical Production of Fe(II) in

Rainwater,” Environ. Sci. Technol. 37, 4610-4616 (2003). Avery, G. B., J.D. Willey, R.J. Kieber, G.C. Shank and R.F. Whitehead. “The Flux and Bioavailability of Cape

Fear River and Rainwater Dissolved Organic Carbon to Long Bay, Southeastern United States” Global. Biogeochem. Cycles 17(2), 11-1 to 11-6 (2003).

R.J. Kieber, J.D. Willey and G.B. Avery. “Temporal Variability of Rainwater Iron Speciation at the Bermuda

Atlantic Time Series Station” J. Geophys. Res. 108 (C8), 33-1 to 33-7 (2003).

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Willey, Joan D., R.J. Kieber and G.B. Avery. "Effects of Rainwater Iron and Hydrogen Peroxide on Iron Speciation and Phytoplankton Growth in Seawater near Bermuda"", J. Atmospheric Chemistry, 47, 209-222 (2004).

Kieber, R. J., S.A. Skrabal, C. R. Smith and J.D. Willey. "Redox Speciation of Copper in Rainwater: Temporal

Variability and Atmospheric Deposition", Environ. Sci.Technol, 38, 3587-3594 (2004). Willey, Joan D.. “The Effect of Ionic Strength on the Solubility of an Electrolyte” J. Chem Ed., 81,1644-1646 (2004). Avery, G. B., R.J. Kieber, J. D. Willey, G. C. Shank, and R. F. Whitehead, “Impact of Hurricanes on the Flux of Rainwater and Cape Fear River Water Dissolved Organic Carbon to Long Bay, Southeastern United States,” Global Biogeochemical Cycles 18(3), GB 3015 (2004). Kieber, R. J., S.A. Skrabal, B.J. Smith and J.D. Willey, “Organic Complexation of Fe(II) and its Impact on the Redox Cycling of Iron in Rain” Environ. Sci. Technol. 39, 1576-1583 (2005). Willey, J. D., R.F. Whitehead, R.J. Kieber and D.R. Hardison, “Oxidation of Fe(II) in Rainwater,” Environ. Sci. Technol. 39, 2579-2585 (2005). Kieber, R. J.,M.S. Long and J.D. Willey, “Factors Influencing Nitrogen Speciation in Coastal Rainwater,” J. Atmos. Chem., 52, 81-99 (2005). Avery,G. B. Jr., W.J. Cooper, R.J. Kieber and J.D. Willey, “Hydrogen Peroxide at the Bermuda Atlantic Time Series Station: Temporal Variability of Seawater Hydrogen Peroxide,” Marine Chemistry, 97, 236-244 (2005). Avery, G.B., Kieber, R.J., Witt, M. and Willey, J.D. “Rainwater Monocarboxylic and Dicarboxylic Acid Concentrations in Southeastern North Carolina, USA as a Function of Air-Mass Back Trajectory” Atmos. Environ. 40, 1683-1693 (2006). R.J. Kieber, R.F. Whitehead, S.N. Reid, S.N., J.D. Willey and P.J. Seaton, P.J. “Chromophoric Dissolved Organic Matter (CDOM) in Rainwater Collected in Southeastern North Carolina, USA” J.Atmos. Chem.,54, 21-41 (2006). Avery, G. B.; Willey, J. D.; and Kieber, R. J. “Carbon Isotopic Characterization Of Dissolved Organic Carbon In Rainwater: Terrestrial And Marine Influences” Atmos. Environ. 40(39), 7539-7545 (2006).

Willey, J. D., Kieber, R.J. and G. Brooks Avery, Jr. “The Changing Chemical Composition of Rainwater in the Continental USA” Environmental Science and Technology 40, 5675-5680 (2006). Jenkins, S.B., Gamble, D.W., Benedetti, M.M. and Willey, J.D., “The Effects of Local Weather Patterns on

Nitrate and Sulfate Rainwater Concentrations in Wilmington, North Carolina” The North Carolina Geographer 41, 31-39 (2006).

Witt, M., Skrabal, S.A., Kieber, R.J. and Willey, J.D. “Copper Complexation in Coastal Rainwater in Southeastern USA” Atmos. Environ. 41, 3619-3630 (2007).

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Witt, M., Skrabal, S.A., Kieber, R.J. and Willey, J.D. “Photochemistry of Cu Complexed with Chromophoric Dissolved Organic Matter: Implications for Cu Speciation in Rainwater” J. Atmos. Chem. 58, 89-109 (2007).

Kieber, R.J., Whitehead, R.F., Reid, S.N. and Willey, J.D. “Photochemistry of Chromophoric Dissolved Organic matter (CDOM) in Rainwater” J. Atmos. Chem. 58:219–235 (2007) DOI 10.1007/s10874-007-9089-3 Miller, C., Willey, J.D. and Kieber, R.J. “Changes in Rainwater Composition During Tropical Storm Ernesto”

Atmos. Environ. 42(5), 846-855 (2008). Willey, J.D., Kieber, R.J., Seaton, P.J. and Miller, C. “Rainwater as a Source of Fe(II)-Stabilizing Ligands to Seawater” Limnology and Oceanography, 53(4), 1678- 1684 (2008). Kieber, R.J., Parler, N.E., Skrabal, S.A. and Willey, J.D. “Speciation and Photochemistry of Mercury in Rainwater” J. Atmos. Chem. 60, 153 – 168 (2008). Miller, C, Gordon, K.G., Kieber, R.J., Willey, J.D. and Seaton, P.J. “Chemical Characteristics of Chromophoric Dissolved Organic Matter in Rainwater” Atmos. Environ. 43, 2497:2502 (2009). Avery, G.B., Dickson Brown, J.L., Willey, J.D. and Kieber, R.J. “Assessment of Rainwater Volatile Organic

Carbon in Southeastern North Carolina, USA” Atmos. Environ. 43(16), 2678-2681 (2009). Willey, J.D., Kieber, R.J. and Yavari, J.R. “Fe(II) in Coastal Rainwater: Changing Stability and Concentrations” Aquatic Sciences 71(2), 144-150 (2009). Mead, R.N., Morgan, J.B., Avery, G.B., Kieber, R.J., Kirk, A., Skrabal, S.A., and Willey, J.D. “Occurrence of

the Artificial Sweetener Sucralose in Coastal and Marine Waters of the United States” Mar. Chem. 116, 13-17 (2009).

Willey, J.D., Inscore, M.T., Kieber, R.J. and Skrabal, S.A. “Manganese in Coastal Rainwater: Speciation, Cycling

and Deposition to Seawater” J. Atmospheric Chem. 62:31-43 (2009). Southwell, M.W., Smith, J.D., Kieber, R.J. and Willey, J.D. (2010). Photochemical Production of Formaldehyde from

Rainwater Dissolved Organic Matter. 44. Atmos. Environ., 44. 3638. Kieber, R.J., Smith, J., Mullaugh, K.M., Southwell, M.W., Avery Jr., G.B. and Willey, J.D. “Influence of

Dissolved Organic Carbon on Photochemically Mediated Cycling of Hydrogen Peroxide in Rainwater” J. Atmos.Chem. (2010), 64:149-158 DOI 101.1007/s10874-010-9174-x.

Willey, J.D., Glinski, D.A., Southwell, M., Long, M.S., Avery Jr., G.B. and Kieber, R.J. “Decadal Variations Of

Rainwater Formic and Acetic Acid Concentrations in Wilmington, NC, USA” Atmos. Environ. 45:1010-1014 (2011). doi:10.1016/j.atmosenv.2010.10.047.

Mullaugh, K.M., Kieber, R.J., Willey, J.D. and Avery, G.B. “Long Term Temporal Variability in Hydrogen

Peroxide Concentrations in Wilmington, North Carolina USA Rainwater” Environ. Sci. Technol. 45:9538-9542 (2011).

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Kieber, R.J., Adams, M.B., Willey, J.D., Whitehead, R.F., Avery, G.B., Mullaugh, K.M. and Mead, R.N. “Short Term Temporal Variability in the Photochemically Mediated Alteration of Chromophoric Dissolved Organic Matter (CDOM) in Rainwater” Atmos. Environ. 50:112-119 (2012).

Avery, G. B, Karabi, B. Southwell, M., Mead, R., Kieber, R. J. , and J. D. Willey. “Carbon Isotopic Composition of Hydrophobic Organic Material in Rainwater” Atmospheric Environment, 68:230-234 (2013). http://dx.doi.org/10.1016/j.atmosenv.2012.11.054 Willey, J.D., Mullaugh, K. M., Kieber, R. J., Avery, G. B., Mead, R. N. (2012) “Controls on the Redox Potential

of Rainwater” Environmental Science and Technology, 46 (24): 13103-13111, http://dx.doi.org/10.1021/es302569j.

Mead, R. N., Mullaugh, K. M., Avery, G. B., Kieber, R. J., Willey, J. D., and Podgorski, D. C. (2012)“Insights Into Dissolved Organic Matter Complexity in Rainwater from Continental and Coastal Storms by Ultrahigh Resolution Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Atmospheric Chemistry Physics Discussion, 12, 31413-31438, doi:10.5194/acpd-12-31413-2012. Mullaugh, K., Willey, J. D., Kieber, R. J., Mead, R. N., Avery, G. B. (2013). “Dynamics of the Chemical

Composition of Rainwater throughout Hurricane Irene”. Atmospheric Chemistry and Physics. (vol. 13, pp. 2321-2330).

Kieber, R. J., Guy, A., Mead, R. N., Roebuck, A., Carroll, A., Jones, S. B., Giubbina, F., Campos, M., Willey, J.

D., Avery, G. B. (2013). “Determination of Ambient Ethanol Concentrations in Aqueous Environmental Matrixes by Two Independent Analyses”. Analytical Chemistry(10.1021/ac400974m).

Seaton, P. J., Kieber, R. J., Willey, J. D., Avery, G. B., Dixon, J. (2013). “Seasonal and Temporal

Characterization of Dissolved Organic Matter in Rainwater by Proton Nuclear Magnetic Resonance Spectroscopy. “Atmospheric Environment, 65, 52-60.

 Felix, J.D., Jones, S.B., Avery, G.B., Willey, J.D., Meade, R.N. and Kieber, R.J. (2014) “Temporal Variations in

Rainwater Methanol” Atmos. Chem. Phys. 14, 1-9, doi:10.5194/acpd-14-1-2014 Kieber, R.J., Tatum, S.K., Willey, J.D., Avery, G.B. and Mead, R.N. (2014) “Variability of Ethanol and

Acetaldehyde Concentrations in Rainwater” Atmos. Environ. 84c, 172-177. Mullaugh, K. M.; Byrd, J. N.; Avery, G. B.; Mead R. N.; Willey, J. D.; Kieber, R. J. "Characterization of

Carbohydrates in Rainwater from Southeastern North Carolina.” (2014) Chemosphere, 2014, 107: 51-57. Hopwood, M.J., Statham, P. J., Skrabal, S.A.,Willey, J.D. and van den Berg, C.M.G., “Dissolved Fe(II) Biogeochemistry in River and Estuarine Waters”, in press 2014, Marine Chemistry. Felix, J.D., Elliot, E.M., Avery, G.B., Kieber, R.J., Mead, R.N., Willey, J.D. and Mullaugh, K.M. (2014).”

Isotopic Composition of Nitrate in Sequential Hurricane Irene Precipitation Samples: Implications for Changing NOx Sources”. Atmos. Environ.. Submitted.

Felix, J.D., Roebuck, A., Avery, G.B., Willey, J.D., Meade, R.N. and Kieber, R.J. (2014). Methanol and Ethanol

Record in a Greenland Ice Core: Implications for Source Changes and Atmospheric Oxidation Chemistry. Geophys. Res. Letters. Under Review.

11

Mead, R. N., Felix, J. D., Avery, G. B., Kieber, R. J., Willey, J. D. and Podgorski, D. C. “Characterization of CHOS Compounds in Rainwater from Continental and Coastal Storms by Ultrahigh Resolution Mass Spectrometry,” Submitted to Atmospheric Environment September 9, 2014. Willey, J.D., Kieber, R.J., Humphreys, J., Rice, B.C., Hopwood, M.J., Avery, G.B. and Mead, R.N. (2014). The

Role of Fossil Fuel Combustion on the Stability of Dissolved Iron in Rainwater. Atmospheric Environment, submitted November 10, 2014.

Theses and Technical Reports Joan D. Willey, "The Physical Chemistry of Silica in Seawater and Marine Sediments," Ph.D. Thesis, Dalhousie

University, Halifax, Nova Scotia, 195 pp (1975). Joan D. Willey, "Placentia Bay Hydrographic Data Report," unpublished manuscript, 22pp (1975). Malcolm MacIntosh, Joan D. Willey, and Carrone Courneya, "A Compendium of Sampling and Analytical

Techniques Used by the Environmental Marine Geology Subdivision," Atlantic Geoscience Centre, Bedford Institute of Oceanography, Dartmouth, Nova Scotia. Geological Survey of Canada Open File Report No. 397, 70pp (1980).

Joan D. Willey, "Amorphous Silica," Kirk-Othmer Encyclopedoa of Chemical Technology, Volume 20, John

Wiley and Sons, Inc., New York, pp. 766-781 (l982). Invited contribution. Joan D. Willey, Book Review of Equilibria, Nonequilibria and Natural Waters, Volumes I and II by R. M.

Pytkowicz. Journal of the American Chemical Society 106(16):4652 (1984). Joan D. Willey, "Amorphous Silica," Kirk-Othmer Concise Encyclopedia ofl Chemical Technology, John Wiley

and Sons, Inc., New York, 1054-1055 (1985). Joan D. Willey, "Amorphous Silica," Kirk-Othmer Encyclopedia of Glass, Ceramics, Clay and Cement, John

Wiley and Sons, Inc., New York, 796-811 (1985). Christina R. Bode and Joan D. Willey, "Graduate Teaching Assistant Resource Manual," unpublished UNCW

Graduate School document, 24 pp (1994). Joan D. Willey, Alnita C. Hannible and Christina R. Bode, "Guidelines for Thesis Preparation," unpublished

UNCW Graduate School document, 22 pp (1995). Joan D. Willey, Catarina De Carvalho and Matthew Dawson, “Master of Science in Marine Science Graduate

Student Handbook,” unpublished UNCW document, 41 pp. (2010). Published Abstracts of Papers Presented at Scientific Meetings Atkinson, L. P., M. Kelly, and Joan D. Willey, "Chemical Tracers of Southeastern United States Rivers in Coastal

Waters," Southeastern Section of the American Chemical Society Meeting, Savannah, Georgia, Abstract No. 193 (1978).

Willey, J.D., "Cape Fear Estuary Sediment Geochemistry," Journal of the Elisha Mitchell Scientific Society.

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Reports from the North Carolina Academy of Science Meeting, Greensboro, N. C. (1979). Willey, J.D., "Zinc in Sediments from the Cape Fear Estuary, North Carolina," Journal of Elisha Mitchell

Scientific Society. Reports from the North Carolina Academy of Science Meeting, Greenville, North Carolina (1980).

Willey, J.D.and R. Dayal, "Aging of Amorphous Silica in Salt Water Solutions," National American Chemical

Society Meeting, New York, New York (1981). Session chair. Willey, J.D.and Larry P. Atkinson, "Natural Fluorescence in Southeastern U. S. Rivers," 32nd Annual Meeting of

the Southeastern Section of the Geological Society of America, Abstract No. 21424 (1983). Session chair. Willey, J.D., "Sources of Rainwater Acidity in Southeastern North Carolina," 36th Southeastern Regional

Meeting of the American Chemical Society, Abstract No. 239 (l984). Willey, J.D., T. V. Sams, B. J. Devereux, D. C. Coleman, M. E. Bowers, and R. I. Bennett, "Rainwater

Composition in Eastern North Carolina," Journal of the Elisha Mitchell Society, Reports from the North Carolina Academy of Science Meeting, Greenville, NC (1986).

Willey, J.D., John R. Kucklick, and G. Brooks Avery, Jr., "Rainwater-Surface Water Interactions in Southeastern

North Carolina," 39th Southeast Regional Meeting of the American Chemical Society, Orlando, Florida, Abstract No. 243 (1987).

Willey, J.D., G. Brooks Avery, Jr., and John R. Kucklick, "Intrastorm Variation in the Composition of Rain in

Wilmington, North Carolina," Proceedings of the Fifth Annual Gatlinburg Acid Rain Conference, p. 39 (1988).

Kucklick, J. R., and Joan D. Willey, "Atmospheric Deposition as a Nutrient Source to Lake Waccamaw, North

Carolina," Proceedings of the Fifth Annual Gatlinburg Acid Rain Conference, p. 27 (1988). Martens, C. S., J. P. Chanton, J. V. Klump, L. K. Benninger, P. M. Krill, R.I. Haddad, D. B. Albert, C. A. Kelley,

M. J. Alperin, J. D. Willey, and N. E. Blair, "Biogeochemical Processes Dominating Upper Slope Sediments along a 36o20'N Transect off North Carolina, USA," EOS, Transactions of the American Geophysical Union 70(15):369 (1989).

Kucklick, J. R., Joan D. Willey, and Lawrence B. Cahoon, “Wet and Dry Deposition as a Source of Nitrogen to

Lake Waccamaw, North Carolina,” SETAC 10th Annual Meeting (1989). Willey, J.D., "Sulfite in Winter Rainwater in Wilmington, North Carolina," EOS, Transactions of the American

Geophysical Union 71(2):165 (1990). Willey, J.D.and Hans W. Paerl, "Atmospheric Deposition of Nutrients to Gulf Stream Surface Seawater and to

Shallow Lakes in Eastern North Carolina," EOS, Transactions of the American Geophysical Union 74(16): 79 (1993).

Lancaster, R. D., Joan Willey and Robert Kieber, "Hydrogen Peroxide in Coastal North Carolina Rainwater and

Contribution of Rain to Surface Water Hydrogen Peroxide Concentration. Journal of the Elisha Mitchell Society, vol. 109(4), 1993, Reports from the Ninetieth North Carolina Academy of Science AnnualMeeting, Wilmington, North Carolina, Abstract 27, p. 236 (1993).

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Kieber, R. J., R.D. Lancaster and J.D. Willey, “Variations in Hydrogen Peroxide Concentrations in Coastal North

Carolina Rainwater,” Environmental Chemistry Division of the American Chemical Society, National Meeting, Chicago, IL (1995).

Willey, J.D., Robert J. Kieber, Richard D. Lancaster and Cindy L. DeForest, “Flux 0f Rainwater and Gas Phase

Hydrogen Peroxide to Lakes, Coastal Waters, the Gulf Stream and the Sargasso Sea off Eastern North Carolina, USA,” EOS, Transactions of the American Geophysical Union, 1996 Ocean Sciences Meeting, San Diego, CA. (1996).

Willey, J. D., Kieber, R. J., Lancaster, R. D., Paerl, H. W., and Go, M. " Rainwater Deposition of Hydrogen

Peroxide to Coastal North Carolina Waters: Effect on the Bioavailability of Iron in Seawater," American Society of Limnology and Oceanography, Aquatic Sciences Meeting Abstracts, Santa Fe, New Mexico, p. 344 (1997).

Willey, J. D., Kieber, R. J., Eyman, M. S., and Avery, G. B. “Rainwater Dissolved Organic Carbon as a Part of

the Global Carbon Budget,” American Society of Limnology and Oceanography, Santa Fe, New Mexico, p. 190 (1999).

Willey, Joan D., Kieber, Robert J., Cooper, W. and Avery, G. Brooks. “Photochemical production and

atmospheric deposition of hydrogen peroxide at the Bermuda Atlantic Time Series Station,” American Chemical Society Pacificchem meeting, Honolulu, Hawaii (2000).

Kieber, R.J, Willey, J.D. and Skrabal. S.A.. “The effect of photochemical reactions on the lifetime of

atmospherically deposited iron in seawater,” American Chemical Society Pacificchem meeting, Honolulu, Hawaii (2000).

Skrabal, S., Kieber. R.J., Willey, J.D. “Redox Active Trace Metals in Rain and Surface Waters: Speciation and

Photochemical Effects,” American Chemical Society Pacificchem meeting, Honolulu, Hawaii (2000). Willey, J.D., Kieber, R.J. and Avery, G.B. “Effects of Rainwater Fe(II), Fe(III) and Hydrogen Peroxide on

Chlorophyll a in Bermuda Atlantic Time Series Station Bioassays: A Delicate Balance,” American Society of Limnology and Oceanography meeting, Albuquerque, New Mexico (2001).

Kieber, R.J., Willey, J.D., and Cooper, W.J. “Temporal Variability of Iron Speciation and Hydrogen Peroxide

Concentrations at BATS: Atmospheric Influences on Seawater Concentrations,” American Society of Limnology and Oceanography meeting, Albuquerque, New Mexico (2001).

Avery, G.B., Kieber, R.J. and Willey, J.D. “Rainwater Flux of Fossil Fuel Derived DOC Determined Via 14C

Analysis,” American Society of Limnology and Oceanography American Geophysical Union Ocean Sciences Meeting, Honolulu, Hawaii (2002).

Willey, J. D. and Kieber, R.J. “Decrease in Iron Availability to Phytoplankton in Oligotrophic Seawater Caused

by Rainwater Hydrogen Peroxide,” American Society of Limnology and Oceanography meeting, Victoria, British Columbia (2002).

Zvalaren, S.D., Willey, J. D. and Kieber, R. J. “Chromium Speciation in Coastal Rainwater,” American Society of

Limnology and Oceanography meeting, Victoria, British Columbia (2002).

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Willey, J. D., Kieber, R.J., Hardison, D.R. and Avery, G.B. “Effects of Rainwater Fe(II), Fe(III) and Hydrogen Peroxide on Chlorophyll a Production in Sargasso Seawater Bioassays: A Delicate Balance,” Joint Assembly of the European Geophysical Society, the American Geophysical Union and the European Union of Geosciences, Nice, France (2003).

Kieber, R.J., Hardison, D.R., Whitehead, R.F. and Willey, J.D. “Photochemical Production of Fe(II) in

Rainwater,” American Chemical Society National Meeting, New Orleans LA. (2003). Witt, M., Jickells, T. D.,Kieber, R. J. , Skrabal, S., and Willey. J., “Organic Complexation of Copper in Rain,”

ASLO 2004 Summer Meeting, Savannah, GA (2004). Bradshaw, L.C., Skrabal, S.A., Kieber, R.J., Willey, J.D., and Cahoon, L.B., “Ammonium in the Cape Fear River

Estuary; The Role of Particle-Water Interactions,” ASLO 2004 Summer Meeting, Savannah, GA (2004). Zvalaren, S. D., Willey, J.D., Skrabal, S.A., and Kieber, R.J. “Mercury Speciation in the Organic Rich Cape Fear

River, North Carolina, USA,” ASLO 2004 Summer Meeting, Savannah, GA (2004). Kieber, R. J., Bradshaw, L.C., Long, M.S., Skrabal, S. A., and Willey, J. D. “Increasing ammonium in the Cape

Fear River Estuary: Where is it coming from?” American Society of Limnology and Oceanography/The Oceanographic Society Ocean Research Conference, Honolulu, Hawaii (2004).

Whitehead, R. F., Reid, S., Kieber, R.J., and Willey, J.D. “Rainwater chromophoric dissolved organic matter:

Characteristics and photoreactivity,” ASLO/TOS Ocean Research Conference, Honolulu, Hawaii (2004). Avery, G. B., Kieber, R. J., Willey, J. D., Shank, G. C., and Whitehead, R. F. “The impact of hurricanes on the

flux of rainwater and Cape Fear River Water dissolved organic carbon to Long Bay Southeastern US’” ASLO/TOS Ocean Research Conference, Honolulu, Hawaii (2004).

Willey, J., Kieber, R.J. Skrabal, S.A., and Smith, B.J. “Stability of organically complexed Fe(II) in rainwater

before and after deposition to surface seawater, Surface Ocean Lower Atmosphere Study (SOLAS) Meeting, Halifax, Nova Scotia (2004).

Zvalaren, S.D., Willey, J.D., Skrabal, S.A. and Kieber, R.J. “Mercury Speciation in the Organic Rich Cape Fear

River” 102nd North Carolina Academy of Science Meeting, Raleigh, North Carolina, 2005. Resetar, L., Kieber, R.J., Whitehead, R.F, and Willey, J.D. “Organic Complexation of Fe by CDOM in Rainwater

and Its Impact on Fe Speciation in Seawater” 102nd North Carolina Academy of Science Meeting, Raleigh, North Carolina, 2005.

Bradshaw, L.C., Skrabal, S.A., Kieber, R.J., Willey, J.D. and Cahoon, L.B. “ Sources and Sinks of Nitrogen in the

Cape Fear River Estuary, Southeastern North Carolina” Mercury Speciation in the Organic Rich Cape Fear River” 102nd North Carolina Academy of Science Meeting, Raleigh, North Carolina, 2005.

Kieber, R. J., Willey, J.D., Whitehead, R.F., Resetar, L.A. and Skrabal, S. A. “Organic Complexation of Fe by

CDOM in Rainwater and its Impact on Iron Speciation in Seawater” American Society of Limnology and Oceanography Summer Meeting, Santiago de Compostela, Spain, 2005.

Kieber, R.J., Skrabal, S.A., Willey, J.D. and Bradshaw, L. “Nitrogen Inputs into the Cape Fear River Estuary: A System-Wide Approach” 18th Biennial Conference of the Estuarine Research Federation, Norfolk, VA,

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2005. Avery, G.B., Kieber, R.J., Willey, J.D., Shank, G.C. and Whitehead, R.F. “The Impact of hurricanes on the flux of rainwater and Cape Fear River Water dissolved organic carbon to Long Bay, Southeastern United States” 18th Biennial Conference of The Estuarine Research Federation, Norfolk, VA, 2005. Kieber, R.J., Willey, J.D., Whitehead, R.F., Skrabal, S.A. and Resetar, L. “Photodegradation of chromophoric dissolved organic matter (CDOM) in rainwater and its influence on the redox chemistry of the troposphere” American Chemical Society Pacificchem meeting, Honolulu, Hawaii, 2005. Whitehead, R.F., Kieber, R.J., Willey, J.D. and Skrabal, S.A. “Photochemical reactivity of chromophoric dissolved organic matter in rainwater” American Geophysical Union Ocean Research Conference, Honolulu, Hawaii, 2006. Willey, J. D., Skrabal, S. A., Parler, N. E., and Kieber, R. J. “Redox speciation of mercury in coastal rainwater,

Wilmington, NC, USA” 231st National Meeting, American Chemical Society, Atlanta, Georgia, 2006, Abstract GEOC 80.

Zvalaren, S.D., Willey, J.D., Skrabal, S.A., and Kieber, R.J. “ Distribution of Mercury Species in the Cape Fear

River Estuary, North Carolina” 231st National Meeting, American Chemical Society, Atlanta, Georgia, 2006, Abstract GEOC 81.

Willey, J.D., Skrabal, S.A., Parler, N.E., and Kieber, R.J. “Rainwater as a Source of Dissolved Gaseous Mercury

DGHg(0) to Seawater,” ASLO Aquatic Sciences Meeting 2007, Santa Fe, NM, p. 194. Kieber, R.J., Willey, J.D., Whitehead, R.F., Miller, C. and Avery, G.B. “Photodegradation of chromophoric dissolved organic matter (CDOM) in atmospheric waters and its influence on the redox chemistry of the troposphere” American Geophysical Union Joint Assembly Meeting, 2007, Acapulco Mexico. Avery, G.B., Kieber, R.J., Willey, J.D., Miller, C. and Seaton, P.J. “Chemical and isotopic characterization of rainwater dissolved organic carbon and chromophoric dissolved organic matter” American Geophysical Union Joint Assembly Meeting 2007, Acapulco, Mexico. Zvaleren, S., Willey, J.D. Kieber, R.J. “Distribution of mercury species in the Cape Fear River Estuary, North Carolina” American Society of Limnology and Oceanography, 2008, Orlando, FL. Willey, J.D., Kieber, R.J., Seaton, P.J. and Miller, C. “Rainwater as a source of Fe(II) stabilizing ligands to

seawater,” ASLO Summer Meeting 2008, St. John’s, Newfoundland, Canada, June 9-13, 2008. Willey, J.D., Kieber, R.J. and Yavari, J.R. “Rainwater: A Dynamic Episodic Source of Fe(II) to Surface Seawater” American Society of Limnology and Oceanography Aquatic Sciences Meeting, Nice, France, 2009. Southwell, M.W., Kieber, R.J., Smith, J.D., Rice, B. C. and Willey, J.D. “Photochemical Alteration of Rainwater Dissolved Organic Matter: Implications for Bioavailability of Nutrients and Organic Matter” American Society of Limnology and Oceanography Aquatic Sciences Meeting, Nice, France, 2009. Kirk, A., Mead, R.N., Avery, G.B., Kieber, R.J., Morgan, J.B., Skrabal, S.A., and Willey, J.D. “Occurrence of the Artificial Sweetener Sucralose in Marine Waters” 238th National American Chemical Society Meeting,

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Washington DC, 2009. Kieber, R. J., Willey, J. D., Mead, R. N., Jones, S. B., Avery, G. B., Mullaugh, K. M., Kinney, S. M.* “Ethanol

Variability in Coastal North Carolina, USA Rainwater and its Impact on the Atmospheric Carbon Cycle” American Geophysical Union Meeting of the Americas, Brazil, Eos Trans. AGU, 91(26), Meet. Am. Suppl., Abstract GC13D-07. 2010.

Whitehead, R. F., Kieber, R. J., Willey, J. D., Avery, G. B., Mead, R. N., Adams, B., Smith, J. and Mullaugh, K.

M. “Photo-mediated Changes in Rainwater Chromophoric Dissolved Organic Matter.” Pacifichem Conference, Honolulu, HI, 2010.

Mullaugh, K. M.; Kieber, R. J.; Willey, J. D.; Mead, R. N.; Jones, S. B.; Avery, G. B.; Kinney, S. M.* “Ethanol

Variability in Coastal North Carolina, USA Rainwater and its Impact on the Atmospheric Carbon Cycle.” Pacifichem Conference, Honolulu, HI, 2010.

Hatzakis, E., Carter, B.*, Seaton, P. J., Kieber, R. J., Willey, J. D., Avery, G. B. and Mead, R. N.

“Characterization of Rain Water by 1D, 2D and Diffusion NMR Spectroscopy” PittCon, Atlanta, GA, March 2011.

Willey J.D., Mullaugh, K.M., Kieber, R.F., Avery, G.B., Mead R.N. The Redox Chemistry of Rainwater, presented at 2011 Fall Meeting, AGU, San Francisco, Calif., 5-9 Dec., 2011.

Kieber R.J., Avery, G.B., Willey, J.D., Mead R.N., Kinney, S. Ethanol Variability in Coastal North Carolina,

USA Rainwater and its Impact on the Atmospheric Carbon Cycle. presented at 2011 Fall Meeting, AGU, San Francisco, Calif., 5-9 Dec., 2011.

Mullaugh, K.M., Kieber, R.J., Willey, J.D., Avery G.B., Effect of Reduced Sulfur Dioxide Emissions on

Hydrogen Peroxide Concentrations in Wilmington, NC, USA Rainwater. presented at 2011 Fall Meeting, AGU, San Francisco, Calif., 5-9 Dec., 2011.

G.B. Avery, Jr. Farhana, B.K., Southwell M., Kieber, R.J., Willey, J.D., Mead, R.N., Mullaugh K.M Carbon

Isotopic Composition of Rainwater Chromophoric Dissolved Organic Material presented at 2011 Fall Meeting, AGU, San Francisco, Calif., 5-9 Dec., 2011

Mead, R.N., Podgorski, D.C., Mullaugh, K.M., Avery, G.B., Kieber, R.J., Willey, J.D., Cooper, W.T.

Characterization of Rainwater Dissolved Organic Matter by Ultrahigh Resolution Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. presented at 2011 Fall Meeting, AGU, San Francisco, Calif., 5-9 Dec., 2011.

Byrd, N., Mullaugh, K., Avery, G. B., Kieber, R. J., Mead, R. N., Willey, J. D., Helms, J. Raleigh, NC, "Chemical characterization of rainwater carbohydrates from the southeastern United States", Southeastern Meeting of the American Chemical Society, Raleigh, NC. (November 17, 2012).

Carroll, A. L.; Avery, G. B.; Kieber, R. J.; Willey, J. D.; Mead, R. N.; Mullaugh, K. M. “Variations in Gas Phase Concentrations of Formaldehyde, Acetaldehyde, Methanol and Ethanol.” Poster presented at the South Eastern Regional Meeting of the American Chemical Society, Raleigh, NC, November 17, 2012.

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Rice, B., Willey, J. D., Kieber, R. J., Avery, G. B., Mead, R. N., "Changes in Fe(II) concentration and stability in rain water in Wilmington, NC.", Southeastern Meeting of the American Chemical Society, Raleigh, NC. (November 17, 2012).

Seaton, P. J., Opanasenko, B., Hatzakis, E., Kieber, R. J., Willey, J. D., Avery, G. B. “Characterization of

Rainwater DOC by 1D and 2D NMR Techniques”. (2012) 64th Southeastern Regional Meeting of the American Chemical Society,, SERMACS, Raleigh NC.,

Willey, J.D., Rice, B., Humphreys, J., Kieber, R.J., Helms, J., Avery, G.B. and Mead, R.N. (2013). Temporal Variability Of Rainwater Fe(II) Concentrations And Wet Deposition To Surface Seawater. Goldschmidt Conference. Florence, Italy. Invited.

Kieber, R.J., Willey, J.D., Avery, G.B., Mead, R.N., Giubbina, F. and Campos L. (2013). Ethanol Variability In

Rainwater And Its Impact On The Chemistry Of The Troposphere. Goldschmidt Conference. Florence, Italy.

M.J. Hopwood, P.J. Statham, J.D. Willey and S.A. Skrabal (2014) Estuarine FeII Ligands And Their Export To Coastal Waters, Ocean Sciences meeting, Hawaii. Presentations Without Published Abstracts, Last Ten Years Willey, J.D., Skrabal, S.A., Smith, C., Sutton, A., and Kieber, R.J. “Copper (I) and Copper(II) Speciation in

Coastal Rain,” Gordon Conference on Chemical Oceanography, Tilton, NH, poster presentation, 2001. Willey, J.D. “Reduced Metals in Coastal Rain,” Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC,

2001. Willey, Joan D., Kieber, Robert J., Cooper, W. and Avery, G. Brooks. “Photochemical production and

atmospheric deposition of hydrogen peroxide at the Bermuda Atlantic Time Series Station,” 5th UNCW Symposium on Chemistry and Biochemistry, Wilmington NC, poster presentation. 2001.

Kieber, R.J., Willey, J.D. and Skrabal, S. “The Effect of Photochemical Reactions on the Lifetime of

Atmospherically Deposited Iron in Seawater,” 5th UNCW Symposium on Chemistry and Biochemistry, Wilmington, NC, poster presentation. 2001.

Skrabal,S., Kieber. R.J., Willey, J.D. “Redox Active Trace Metals in Rain and Surface Waters: Speciation and

Photochemical Effects,” 5th UNCW Symposium on Chemistry and Biochemistry, Wilmington, NC, poster presentation. 2001.

Willey, J.D., Skrabal, S.A., Smith, C., Sutton, A., and Kieber, R.J. “Copper Speciation in Coastal Rain,” 6th

UNCW Symposium on Chemistry and Biochemistry, Wilmington NC, poster presentation. 2002. Willey, J.D. “Iron Addition Experiments at the Bermuda Atlantic Times Series (BATS) Station,” 16th Annual

Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC, 2002. Avery, G.B. Jr, Keiber, R.J. and Willey, J.D. “Rainwater as a Removal Mechanism for Fossil Fuel Derived Dissolved Organic Carbon” Ocean Sciences Meeting, Honolulu Hawaii, February 2002.

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Willey, J.D. “Oxidation of Fe(II) in rain and coastal seawater,” 17th Annual Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC. 2003.

Zvalaren, S.D., Skrabal, S.A., Kieber, R.J. and Willey, J.D. “Mercury Speciation in the Organic Rich Cape Fear

River,” 7th UNCW Symposium on Chemistry and Biochemistry, Wilmington NC, poster presentation. 2004.

Bradshaw, L.C., Skrabal, S.A., Kieber, R.J. and Willey, J.D. “Ammonium in the Cape Fear River Estuary; The

Role of Particle-Water Interactions,” 7th UNCW Symposium on Chemistry and Biochemistry, Wilmington NC, poster presentation. 2004.

Loucaides, S., Cahoon, L.B., Henry, E.J., Leonard, L.A. and Willey, J.D. “Human Impact On The Silica Cycle: Reduction Of Dissolved Silica Inputs Into The Ocean As A Result Of Increasing Impervious Cover,” Water Resources Research Institute, NC, poster presentation, 2004.

Willey, J.D. “The changing chemistry of rainwater in the continental USA,” 18th Annual Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC. 2004.

Willey, J.D. “The changing chemical composition of rainwater in the continental USA: Part 2,” 19th Annual

Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC. 2005. Avery G.B., Jr., Kieber, R.J., Willey, J.D., Shank, G.C. and Whitehead, R.F. “The Impact of Hurricanes on the Flux of Rainwater and Cape Fear River Water Dissolved Organic Carbon to Long Bay, Southeastern United States” Biennial Conference of the Estuarine Research Federation, Norfolk, VA October 2005. Kieber, R.J., Skrabal, S.A., Willey, J.D. and Bradshaw, L. “Nitrogen Inputs into the Cape Fear River Estuary: A System-Wide Approach” 18th Biennial Conference of the Estuarine Research Federation, Norfolk, VA. October 2005. Willey, J.D. “The Changing Chemical Composition of Rainwater in the Continental USA: Implications for Earth and Ocean Sciences,” Invited seminar, University of North Carolina Chapel Hill, March 1, 2006. Willey, J.D. “The Changing Chemical Composition of Rainwater in the Continental USA: Implications for Earth and Ocean Sciences,” UNCW College Day, November 11, 2006. Miller, C., Kieber, R.J., Willey, J.D. and Gordon, K. “Composition of Chromophoric Dissolved Organic Matter in Rainwater” SOLAS, Corsica, France, 2007. Willey, J.D. “Rainwater: Where has all the Fe(II) gone?,” 22th Annual Duke-UNC Oceanographic Consortium

Meeting, Beaufort, NC. 2008. Willey, J.D. “Rainwater: A Dynamic Episodic Source of Dissolved Fe(II) to Surface Seawater,” Invited seminar, University of Utrecht, the Netherlands, March 16, 2009. Willey, J.D. “Manganese in Coastal Seawater: Speciation, Photochemistry and Deposition to Seawater,” 23th

Annual Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC. 2009. Willey, J. D. “Decadal Variations of Rainwater Formic and Acetic Acid Concentrations in Wilmingtom, NC,

USA: Bioavailable Carbon to Seawater” 24th Annual Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC. 2010.

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Willey, J. D. “Controls on the Redox Chemistry in Rainwater” 25th Annual Duke-UNC Oceanographic

Consortium Meeting, Beaufort, NC. 2011. Willey, J. D., Tatum, S. K., Avery, G. B., Kieber, R. J., Mead, R. N., Campos, L., Giubbina, F. F. “Rainwater

Ethanol in Wilmington, North Carolina and Ribeirão Preto, São Paulo, Brazil” 26th Annual Duke-UNC Oceanographic Consortium Meeting, Beaufort, NC. 2012.

Cala, J. M., Willey, J. D., Felix, J. D., Avery, G. B., Kieber, R. J., Mead, R. N., “Tracking Ethanol”, Southeastern

Estuarine Research Society Annual Meeting 2014, Carolina Beach, NC. Wilenta, K. L., Skrabal, S. A., Willey, J. D., Felix, J. D. and Hopwood, M. J. “Temporal Changes in Total Iron

in Rainwater,” Southeastern Estuarine Research Society Annual Meeting 2014, Carolina Beach, NC. Best poster at meeting award.

Doctoral Thesis Directed Suzanne Zvalaren Schneider, Mercury Sources and Cycling Processes in the Cape Fear River Estuary, North Carolina, 2009 (UNCCH). Master's Theses Directed Raymond P. Brandi, The Use of Natural Fluorescence to Describe Water Type Mixing in the Cape Fear Estuary,

1986. John R. Kucklick, Undescribed Sources of Nutrients to Lake Waccamaw, North Carolina, 1988. G. Brooks Avery, Jr., Formic and Acetic Acids in Coastal North Carolina Rainwater, 1989. Richard D. Lancaster, Variations of Hydrogen Peroxide Concentrations in Coastal North Carolina Rainwater,

1995. Cindy L. D. Heffern, Gas Phase Hydrogen Peroxide in Coastal North Carolina, 1996. Kris A. Rudolph, Effect of Acid Rain on Alkalinity and Calcium Carbonate Saturation in the Albemarle Sound of

North Carolina, 1996. Mary W. Eyman, “Dissolved Organic Carbon in Coastal North Carolina Rainwater,” 1998. Kelly Hostetler Williams, “Iron Concentration and Speciation in Rain,” 1998. Yan Tang, “Organic Acids in Coastal North Carolina Rainwater,” 1998. Bethany Jacobs, “Factors Affecting Iron Speciation in Remote Marine Rain,” 2000. Suzanne Zvalaren, Chromium Speciation and Cycling in Coastal Rainwater, 2002.

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Donnie Ransom Hardison, "Photochemistry and Kinetics of Iron Reactions in Rain," 2002.

Cliff Reid Smith, "Copper Speciation in Coastal Rain and Estuarine Water,” 2003.

Bernard Jason Smith, "Iron Speciation in Coastal Rainwater: Oxidation Kinetics and Organic Complexation," 2003.

Seth Neil Reid, "Rainwater Chromophoric Dissolved Organic Material (CDOM): Characteristics and Photoreactivity," 2003. Michael S. Long, "Atmospheric Deposition in Southeastern North Carolina and its Impact on the Cape Fear River Estuary," 2004. Nichole E. Parler, “Speciation of Mercury in Coastal Rain,” 2005. Lorri Resetar, “Chromophoric Dissolved Organic Matter in Coastal Rain,” 2005. Michael Inscore, “Manganese Concentration and Speciation in Coastal Rainwater,” 2006. Kelly Gordon, “Characterization of Chromophoric Dissolved Organic Matter in Coastal Rainwater,” 2006. Sarah D. Manley, “Mercury Concentration, Variability, and Speciation in Wilmington, NC Rainwater,” 2008. Josephine Yavari, “Temporal Variability of Iron Speciation in Rainwater and its Impact on the Biogeochemical Cycling of Iron in Seawater,” 2009. M. Beth Adams, Photochemically Induced Changes in the Optical Properties of Chromophoric Dissolved Organic Matter (CDOM) in Rainwater, 2010. J. Nikki Byrd, Carbohydrates in Coastal North Carolina Rainwater, 2011. Joshua J. Humphreys, Effect of Fossil Fuel Derived Ligands on the Stability of Fe (II) in Rainwater and Seawater. 2013. Brianna C. Rice, Temporal Variability Of Iron(II) Concentration And Stability In Wilmington, NC, Rainwater: Anthropogenic Impacts. 2013. Current MS students: John Cala, Matthew Casas, Erin Dingess, Shannon Hammacher, Jacqueline Powell, Rachel Thomas

Honors Theses Directed Carol A. Wilson, Formic and Acetic Acids in Atmospheric Condensate in Wilmington, North Carolina, 1991. David B. Wagoner, A Trophic State Evaluation of Trask's Pond and Bluethenthal Wildflower Preserve Pond,

Wilmington, North Carolina, co-direct with Dr. Lawrence Cahoon, 1994. David Wagoner won a first place award for his presentation at the Annual Meeting of the Collegiate Academy of the North Carolina

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Academy of Science held at Davidson College, North Carolina, March 25, 1994. Shelia Greene, Mixing Patterns and Biological Impacts of Rainwater Hydrogen Peroxide on Surface Seawater,

1994. Matthew Rhines, “Analysis for Nitrite and Formaldehyde in Rain,” 1998, Jamie Crozier, “Iron Speciation in La Nina Rain,” 1999. J. Will Thompson, “Organic Complexation of Iron in Rain,” 2001. Will Thompson received a first place award

for best undergraduate talk in his session of the Collegiate Academy of the NC Academy of Science Annual Meeting at the University of NC at Greensboro in March, 2001.

Tomi Hill,”Measurement of Dissolved Organic Matter in the Cape Fear River Estuary by 3D Fluorescence

Spectroscopy,” 2002. Tomi Hill presented her work at the Collegiate Academy of the NC Academy of Science Annual Meeting at the University of NC at Greensboro in March, 2001.

Josephine Yavari, “Determination of Labile Mercury in Rainwater, Cape Fear River Estuarine Water and

Seawater,” 2007. Andrew McGinnis, “Iron Concentrations in Chromophoric Dissolved Organic Material in Rain,” 2008. Donna Glinski, “Formic, Acetic and Oxalic Acids in Rainwater.” 2009. Kelsey Wilenta, “Temporal Changes in Total Iron in Rainwater,” expected 2015. Community Service Challenge judge, high school Ocean Science Bowl, 2003, 2004, 2010 Environmental science advisor to local radio, television and newspaper reporters. Rainwater chemistry advisor to local industries. Science project advisor to middle and high school students. UNCW College Day presentation, 2006 Mentor, high school senior, spring 2007, fall 2010, fall 2013. Department of Chemistry and Biochemistry Seminar, February, 2014 Developed campus land use proposal (with Drs. Hackney, Padgett and Posey in the Department of Biological Sciences) to preserve unique natural areas on campus for teaching and research. This proposal has been approved by the Board of Trustees and is incorporated into the twenty year plan for the UNCW campus. In collaboration with Drs. Noland (English) and Posey (Biological Sciences), This plan is continuously being revised and expanded as needed. This project benefits both UNCW and the local community. Collaborators (within the last 48 months): At UNCW: G. B. Avery, R.J. Kieber, R. N. Mead, S.A. Skrabal, P. J. Seaton, R.F. Whitehead; At the University São Paulo, Brazil, L. Campos, Giubbina, F. F., At Southampton University, UK, P. J. Statham, M. J. Hopwood. Postdoctoral Scholars Supervised: G. Brooks Avery, Jr., Melanie Witt, Carrie Miller, Melissa Southwell, B. Karabi Farhana, Kate Mullaugh, J. David Felix

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Ph.D. Advisor: Peter J. Wangersky, Dalhousie University, Nova Scotia Postdoctoral Advisor: Roger Slatt, Memorial University of Newfoundland