KELLY, MclAuoHLiN & FOSTEH · kelly, mclauohlin & fosteh a paofbssionajl ... causeohemicae...

KELLY, MclAuoHLiN & FOSTEHA PaOFBSSIONAJL

ATTOHNBYS AT17OO ATLANTICaeo SOUTH B«OAD STKHT

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(ais) TOO- roooFAX: (us) »ea-o«78

RoBnrG. Ksu«J&** R. TIOMA* KcLuNMUn S0ITX 1OSWILUAU C. FO*T**> TBOMAI B. S«o» ,,__ IT .._—_,. », _„ _C>A>u»I.MeCbim*TT Jsmnmanu - 9OO HACBOW Av*xu«JXMM J. B««»** TBOWA* P. B«ACAOtt4." V.OLUHOWTOOO. Mrw Jams KT oaioaJomx M. CoKoa*** T»«A»C» R Kamm* TBUSPHOMS: (OOO) s»«-33OOJO««F» A. DAIT Basim*M.riacsCI«AJU> F. Linmi* Gunon R VoesJO«IF« R TkAaocco JAJTB A. EmnsJo*cv> P. CBAM* Ktnrr Y. IUunKsvm G. Cotnuo* MAJTT Etixuun VMS*SOIAJT M. Surrm* Sozunu I. Eusnu* DlVSCT DlAU (318) T9O--?nn tD*»r0F.w«rt.« Ho.,«J.McD ,. OumF«t«.

•ZZZiSZZi.ZZZ—————. November 21, 1990» AoMima in Niw YonAU ADMITTU n PHOTTlTAjret ,

REs Blosenakl Landfill,, a/fc/a Route 340 Site.West Cain Township. Cheater County. PA

Clay Monroe, Esquire (3RC22)Assistant Regional CounselEPA Region III841 Chestnut StreetPhiladelphia, PA-. 19106

Dear Mr. Monroe:

Pursuant to our recent conversation and .correspondence datedNovember 7, 1990, I enclose Material Safety Data Sheets recentlyreceived from Ashland Chemical Corporation for various Tectyl productswhich may have been used at The Budd Company's Trailer Division plant.We believe that any possible volatiles in these Tectyl products would,in all likelihood, have vaporized while stored at the plant prior topick-up by the hauler.

If you have any questions, please call.

Very truly yours,

KELLY, McLAUGHLIN & FOSTER

BY: willard R. Burns

WRB/mrcc: Richard O. Lemke

flR(JI]0123

MATERIAL SAFETYDATA SHEET

• : ' • -• <**siMBIASHLAND CrffifcAL, INO 24-HOU!tsubiniir, oi iu.ii.* oiu.T

P.O. BOX 2219COLUMBUS, OHIO 43216 1(800) 274-5263 01

(614) 889-3333 ________ 1(800) ASHLAND

ENVIRONMENTAL, HEALTH andSAFETY DEPARTMENTPRODUCT INFORMATION SERVICES GROUP

THE 9UOO COMPANYATTN: CHARLES PAVNB

Dear Customer:

Enclosed is the Material Safety Data Sheet(s) that you recently requested. If you have any questionsplease contact the department listed above.

A Material Safety Data Sheet is enclosed for the following product(s):

TECTYL 151 A

TECTYL 127 CG

TECTYL 165 G (DORD) ..•

TFCTYL 506 G

TECTYL 127 CGH

TECTYL 121 B

TECTY& 175-GW-BASE (DORD)

Enclosure(s);

NOV 21 890AROOOI2t*

*s

DATA SHEET ^ BBBBR»P ________(614) 889-3333_______1 (800) ASHLAND

ooooio TECTYL 151 A PagotTHIS USDS COMPLIES WITH 29 Cm 1910.1200. (THE HAZARD COWUNIUTION STANDARD)--•-•-—~r- r- -*••• • •.. - i«.--jfc-1 •~-'-»i(.. -pV :«iliii«:«»i««i"««-•.«*•.•**««.r;a»% jTirV

«••••••••••••*•••••••*••••••«•**••••••••••••••*••••••**•••*••••*«••••••*•***•••*••••••••••*•••*••••••***••«*«•••Product NaiMt TECTVL 151 A

OS 90 110 8091603-59*THE BUOO COMPANYATTN: CHARLES PAYNE3155 W. BIG BEAVER ROAD PRODUCT:TROY. MI 48084 INVOICE: REQST

INVOICE DATE: 11/08/90TO:

Data ShMt Not 0008427-004Pr«per*d» 10/11/90Sup*r*«JM: 08/24/88

ON i nRomjrrGcnaral or G*n«r1c ID: MIXTURE - POLYMERIC RESIN WITH SOLVENTSDOT Hazard Claaalf 1cat1ont COMBUSTIBLE (173.115)

1 . 1 - C Q M P O N E N r S

THE COMPOSITION OF THIS PRODUCT IS BEING WITHHELD AS A TRAM SECRET.1 IP PRESENT.IARC. NTP AND OSHA CARCINOGENS ANO CHEMICALS SUBJECT TO THE REPORT-

ING REQUIREMENTS OP SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION.SEE DEFINITION PAGE FOR CLARIFICATION ;

INGREDIENT "~-—- ^ % (by WT) PEL TLV- Not*-AflOMATIC PETgOtBUM OISTTLUT 55-«0 100 PP» ( 1)

Ukii ft 64/42-99*0———~~~~ • •

Not***( 1) TLV NOT ESTABLISHED FOR THIS MATERIAL. ^

THIS ITEM CONTAINS APPROXIMATELY 7% XVLENC (CAS » 1MO-M-7) WHICH HAS A PEL AND TLV Of 100 PPM ANO « STB.OF ISO PPM« APPROXIMATELY 3% CUMENE (CAS * 98-82-S). MH1CH HAS A PEL ANO TLV O/ SO PPM-SKINs APPROXIMATT3.Y

TRIMETHYLBENZe* (CAS * 25551-'3-7). WHICH HAi A PEt AND A TLV Of 28 PPM. TTRIMETHYLSENZ&e MAY CONTAINHYLBENZENt CAS * 95-WHI AMD 22.5% MESITYLENtTHE PEL LISTED FOR THIS ITOI IS FOR COAL TAR NAPHTHA. BASED ON 1C(SINCE DELETED). XYLEM> CUMENC ANO 1.2.4-TRIMETHYLBENZENE AA«

OF SECTION 313 » SARA TITte III.OH I I I,- P H Y S I C A L D A T A

801 Una, Point for PRODUCT 315.00- 345.00 0*9 F. . ( 157.22- iZ3.8IOa9.Cl780.00 ••

Vapor Praaaur* for COMPONENT( 55-60%) . 3.00 «•88iOO 0*920.00 0 C)

.Spael*le vapor Oanalty ___________.___________________._._________: HEAVIER THAM AIRSpaclflc Gravity . 77-00°Oa« f

•_______________________________________________, ( 25!00 0*9 C)Pareant VolatUaa 55-70%Evaporation Rata SLOWER THAN rXRAppaaranc* ' "" WATER wxtfStataFont ~ HCMOG SOUI

I U F I R E . A M J

FLASH POINT(TCC ) 113.0- 120.0 O** C -».0 - 49.9 0(Mj C)EXPLOSIVE LIMIT (PRODUCT) LOWER - 1 .Oft UPPCff - 9.0*EXTINGUISHING NED!At REQUUM FQM OR CARBON OlOXIOt OR ORV CHHCM.HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS*. CAMON DIOXIDE AMD CARBON MONOXIDE. VARIOUS

HYDROCARBONS. ETC. — 'FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED SREATMNB A**AR*TU$ «1TH A FULL FACWIECB OPERATED IN THE POSIHvV

» CR NEAR CRU, (EV» E*TY, BECAUST ~

VAPORS ARE HEAVIER THAN AIR ANO MAY TRAVEL ALONG "O9 QROUMB OR Bf MDVEDBV VENJIUnONANO IGNITO) IVPILOT LIGHTS. OTHER FLAMES ANO IGNITION SOURCES AT LOCAfTONS OISTANT FROM MATERIAL HANDLING POINT.ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS ANO TANK TRUCKS SHOULD Bt

COPYRIGHT 1990 CONTINUED OH PAGI: 2) . AROOOI25

MATERIAL SAFETYDATASHffiT

___ f - A$HLAN1> CUEMICALv NC 24-HOU!f-~i . ^ M SrtK««y» *I*IM« ai». IM:' Ea*rf«ney~ ' ",\Snl3nO p'°' BOX 2219 T«l«phon«

COLUMBUS, OHIO 43216 1(800* 274-5263 or_______(614) 889-3333 1(800> ASHLAND

000010 TECTYL 151 A Pag«:IV F I H t AND t X P L a S I O N I N F Q H M A r i O N ( C u n I i 1 n c

AND/OR BONDED WHEN MATERIAL IS TRANSFERRED.NFPA CODES: HEALTH- 1 FUMWABILITY- 2 REACTIVITY- 0

H t A L l H H A / A R U OAIA

PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II.EFFECTS OF ACUTE OVEREXPOSURE:EVES - CAN CAUSE SEVERE IRRITATION. REDNESS. TEARING. BLURRED VISION.SKIN - PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION. OEFATTTNG. DERMATITIS.BREATHING - EXCESSIVE INHALATION OF VAPORSCAN CAUSE NASAL AND RESPIRATORY [R*ITATI ON.CENTRAL NERVOUS SYSTEMEFFECTS INCLUOING DIZZINESS. WEAKNESS. FATIGUE. NAUSEA. HEADACHE AND POSSIBLE UNCONSCIOUSNESS. AND EVENSWALLOWING'- CAN CAUSE GASTROINTESTINAL IRRITATION. NAUSEA. VOMITING. AND DIARRHEA. ASPIRATION OF MATERML INTOTHE LUNGSCAN CAUSEOHEMICAL PNEUMONITIS WHICH CAN BE FATAL.FIRST AID:

i SOAR AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER,REMOVE CONTAMINATED SHOES PROMPTLY. DISCARD SHOES SATURATED WITH THIS PRODUCT.

IF IN EYES: FLUSH WITH LARGE AMOUNTS OF WATER. LIFTINO UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.IF SWALLOWED: 00 NOT INDUCE VOMITING, KEEP PERSON WARM. QUIET. AND GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL

INTO THE LUNGS OUIiTT) VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.IF BREATHED: IF AFFECTED. REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN. IF

BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON MAM. QUIET AND GET MEDICAL ATTENTION. .

PRIMARY ROUTE(S) OP ENTRY:INHALATION. SKIN CONTACT

O H V I R t A C M V I f Y D A T A

HAZAROOUS POLYMBWZATIONi CANNOT OCCURSTABILlTVt STASLiINCOMPATIBILITY: AVOID CONTACT WITHr. STRONft OXIDIZING AGENTS.

; t C ? I O N V I I S P I L L O * i f A H

STEPS TO 81 TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEOtSMALL SPILL: ABSORB LIQUID ON PAPER. VERWCULITE. FLOOR ABSORBENT. OR OTHER ABSORBENT MATERIAL AND TRANSFER TO

LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FUMES. FLAMES INCLUDING PILOT LIGHTS. ELECTRICAL SPARKS) .PERSONS— WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.P SPILL AT SOURCE. OlS AREA OF SPILL TO PREVENT SPREADING. PUMP LIQUID-JO SALVAGE TANK. REMAININGUIO MAY BE TAKEN UP ON SAND. CLAY. EARTH. FLOOR ABSORBENTTOR OTHER ABSORBENT MATERIAL AND SHOVELED INTOTAINERS.

PREVENT RUN-OFF TO SEWERS. STREAMS ORAS REQUIRED/THAT A SPILL HAS OCCUREO.

OTHER BODIES OF WATER. IF RUN-OFF OCCURS. NOTIFY PROPER AUTHORITIES

WASTE DISPOSAL METHODSSMALL SPILL: ALLOW VOLATILEPORTTOM TO EVAPORATE IN HOOD. ALLOM SUFFICIENT TIN1 FOR VAPORS TO COMPLETELY CLEAR

HOOD DUCT WORK. DISPOSE OF REMAININft MATERIAL IN ACCOROAtCE WITH APPLICABLE REGULATIONS.DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.

LARGE SPILL: DESTROY BY LIQUID INCINERATION.DISPOSE OF IN ACCORDANCE WITH ALL LOCAL. STATt AND FEDERAL RBOULAnOMS.

C T I O N V I I I P H O I t C r i V t t (1. J l •• M» •• I IO HE UStO

VENTILATION! PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOOM. 1M4AUST) VENTILATION TO MAINTAIN EXPOSURE BELOW

PROTECTIVE GLOVES. NEAR RESISTANT GLOVES SUCH ASt. NEOPRENf. NITOU

OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SUN CONTACT. VEAR IMPERVIOUS CUOTHtNt AND BOOTS.ON IX S P t C I A L P H f C A i i r i r j t S •)-! O r - t t H COMMfc N F

CONTAINERS OF THIS MATERIAL MkV BE HAZAROOUS WHEN EMPTIED, SINCt EVHEO CONTAINERS RETAIN PRODUCT RESIDUES(VAPOR. LIQUID. AND/OR SOLID). ALLHAZARO PRECAUTIONi OIvS IN >aS OATA4HHT MUST Bt OBSERVED.

THE SPECIFIC CHEMICAL IDENTITY HAS BEEN M1HCLO AS * TRAOt SECRBT.

; AROOOI26COPYRIGHT 1990 CONTINUIO ON PAGI: 3 ~ ~

ASHLANI* CHBp QS iNCl 24-HOl__„ jvavHCHfu P.O. BOX 2219 Telephone

MATERIAL SAFETY ™J™*"* COLUMBUS, OHIO 43216 1 (800) 274-5263 otDATASHEET ^ " ^ _______(614) 889-3333______1(800) ASHLAND

000018 fECTYL 151 A PagSrX S P E C I A L P R t C A U r i O N S OH Q f r t t H COVMt NTS I

ATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATING-RNOT^RECIPIENTS ARE ADVISED TOCONPIRM IN ADVANCE OP NEED THAT THE INFORMATION ISCURRENT; APPUCABLE. O SUITABLE TO THEIR CIRCUMSTANCES.

X- LAB EL I HF OR MAT I ON

CAUTION!COMUSTIBLE LIQUID AND VAPORWAV CAUSE EVE AM) SKIN IRRITATION. • .INFLATION OF VAPOR ««V CAUSE IRRITATION OP NASAU ANO RBSPIRATORV PASSAGES. '- ,SWAU.OWIH6 *«AV CAUSE IRRITATION OP HBUTH, ESOPHAGUS. ANO GASTROINTESTIKAI. SVSTBI AND HAVB6 FATAL.

*'** -,«-*———• - -:- -•' • .—— - -*f-'

ONLY WITH ADEQUATE VENTI

NUMER

FIRST AID:EYES: FLUSH THOROUGH.* WTH *»TER. GET ««)ICAL ATTENTIOM IWCJIATELY.SKIN: WASH THOROUGHLY WITH SOAP AND WATER.INHALATIONt IP APPECTED, REMOVE TO FRESH AW. IP WEATWINa IS OIPPICW.T. GET MEDICAL ATTENTION.. .INUSTIONt 00 NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ASPIRATION' HAZARD^SWALLoSmT^ B^ l3tNGSAWO CAUSE DAMAGE. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

CHBONIC INMRMWrtONi l " ""CONTAINS! PETBOLEUN DISTILLATES. CONTAINS MATERIALS) WHICH MAY CAUSE CENTRAL NERVOUS SYSTEN OEPRESSICN.

1 •'. '• ••• COMPONENTS APPCA* IN SECTION II •••

COPYRIGHT 1990 LAST PAGI--SK XTTACHMirr ^ ^ 8 7 PAG1

ASHLAND CHEMICA NC ————— 24-HOUR ———— ~ " lirf Ad*M« Oil. lie. Emergency

MATERIAL SAFETY AlSJI/«?/l47 P.O. BOX 2219 TelephoneDATA SHEET ~ ———r. ___JOLOS,8 0«03 «21S J (|OOX J7J-S2J, „

___ DEFINITIONSTnfs (JellMtlWfllJi* is?1r*li«dedv73Puser wfth Mste*ef- SafetyRecipients of these datasheets should consult the OSHA Safety and Health Standards (29 CfR 1910). particularlysubpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment 'orgeneral guidance on control of potential Occupational Health and Safety Hazards.

SECTION I SECTION IV feontJIDENT.F.CATKW

..GENERAL OB GENERIC 10: Chemical family or product Protection Association criteria,description. FIREFIGHTINO PROCEDURE* Minimum equipment to

ffis fX?*™* Product m"tt OOT ss 'rs ss for (wards listed. flighting haiards may also be indicated/SPECIAL FIRS AND EXPLOSION) HAZARD* Stateshazards not covered by other section*.

Components arc listed in this section if they present a NFPA COOES: Hazard ratings assigned by the Nationalphysical or health hazard . and are present at or above Fire Protection Association.1% m the mixture. If a component is identified as aCARCINOGEN by NTP. IARC. or OSHA as of the date SECTION Von the MSOS. it will be listed and footnoted in this HEALTH HAZARD DATAsection when present ac or above 0.1% m the product PERMISSIBLE EXPOSURE LIMIT For productNegative conclusions concerning carcinogenicity are not —,.-..-..- , ,.„- „....- - *• *««.•.reported. Additional health information may be found m THRESHOLD LIMIT VALUE: For product • .Section V. Components subject to the reporting EFFECTS Of ACUTB OVERIXPOSURft Potential localrequirements of Section 313 of SARA Title III arc and systemic effects due to single or short termidentified in the footnotes in this section, along with overexposure to the eyes ana sk.n :- through inhalationtypical percentages. Other components may be listed if or mgestion,deemed appropriate.

, . „„_ EFFECTS Of CHRONIC OVEREXPOSURt Potential localExposure recommendations are for components, OSHA ^ lystwn<c .ff t, <&• to repeated or long termPermissible Exposure limits (PELS) and American overe*oosure to the eyes and skin or through .nnataiionConference of Governmental industrial Hygienists & aestian.(ACGIH) Threshold Limit Values (TLVs) appear on theline with, the component identification. Other FIRST AlOt Procedures to be followed when dealingrecommendations appear as footnotes. w.tn accidental overexposure.

SECTION III' ' PRIMARY ROUTE OP ENTRY: Based on properties andPHYSICAL DATA expected use. --—„.. ...

BOILING POINT: Of product if known. The lowest SE nqn yivalue of the components is listed for mixtures. REACnVlTUBAIA, ~«» „„,...._ n* -rw HAZARDOUS POLYMERIZATION! Conditions to avoid :oVAPOR PRESSURE Of product if knowa The h.ghest *<+,«« N«zardous polymerization resulting in a >argevalue of the components is. listed for mixtures. release of energy.SPECIFIC VAPOH DENSITY: Compared to AIR » t. If STAMJTYr Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known, »>oier* decomposition.the value is expressed as lighter or greater than atr. ,» ..*-.«.— .— . ..<>»**,*»* ,-..,„»«. ^ ^ ,»,.«« , ,. INCOMTATWUTY: Materials and conditions to avoid toSPECIFIC GRAVITY: Compared to WATER • 1. If or even* naaardous reactions.Specific Gravity of product is not known, the value) isexpressed as less than or greater than water. SECTION VIIpht If applicable. SPttL OB LEAK PROCEDURESPERCENT VOLATILESt Percentage of materiel with _ „ __initial boiling pomt below 42S degrees Fahrenheit and »«asonaWe precautions to be taken and methods 9fvapor pressure above O.tmm Hg at 33 F. conunmew. ciean-uQ and disposal Consult federal»j*Bs»»<r»<u« •.*& •„«_-» . *•*• «"* loc>l regulations for accepted procedures and^ SSl SU*1* lndle«t** » fatMr » »lowtr ar» reoortmg or noufieation requrements.than ETHYL ETHER, unless otherwise stated.

SECTION VIIIPROTICmi EQU.PM1NT TO 81 USEDF,R« A N O x o N DATA

RASH POINT: Method identified,EXPLOSION LIMITS: For product if known. The lowsetvalue of the components is listed for mixtures. SECTION IXHAZARDOUS DECOMPOSITION PRODUCTS: Known or SPtCtAI. PR1CAUT10N8 OH OTHCT COMMENT!expected hazardous products resulting from heating, Ca , m ^ ^ oomts „<„ 0,,0, tKined.burning or other reactions,

ADDITIONAL COMMENTSContainers should be either reconditioned by CERTIFIED firms or oroeeriv disposed of by APPROVED firms. Disposal :•containers should be m accordance with applicable laws and 'egwauons.. 'EMPTY* drums should not be given •?individuals. Serious accidents nave resulted from the misuse ol EMpTiiQr containers <drums.Baas.eyX Beferryort**' <x~»'V and IX

ASHLAMT> CBEJ eAL, INOof »««* Fi«r

DATA SHEET "•• 5 ________ (614) 889-3333 _______ 1(800) ASHLAND

ooQOii TBCTYL. 127 CG2? SU«&18U2££gRS«! ^ _ ._«••••••••••••••••*••••••••*••••••••••*•••••••••••••*••*•••••*•••••••••*•••••••••••••••••••••••••*•••••••••••••••

Product N*«». TECJYL 127 CO

THE 9UOO COMPANY OS 90 110 3091603-591ATTN: CHARLES PAVNC3155 W. BIG BEAVER ROAO PRODUCT:TROY. MI 48Q84 INVOICE: REQST

INVOICE QATEi 11/08/90

stcrioN i - p H o o u c r i o t M r i F i c A T i o nCentral or G*n«Mc IDt PETROLEUM BASED RUST PREVENTATIVHDOT Hun* ClM«if Icatloos COMBUSTiatt (173.113)

Data ShMt Mot 0020192-009Pr«pir«ds 10/11/9001/24/90

OH I I - C O M P O N E N T S

n« COMPOSITION or THIS PRODUCT is BEING WIIHAJJ AS * TRAOC scowr.IF PRESENT. I ARC. NIP AND OSH» CARCINOGENS i&Q OBWCALS SU8JECT TO THE REPORT-m REQUIREMENTS « SAW S E C n O t IN THIS SECTION.

INGREDIENT % (by WT) PEU TUV Not*TALC I-'O 20 PPM 2 MG/M3 ( 1)

CAS *t 14«07-9«-« .

ALUMINUM ' ' 1-3 10 MOAO 10 MB/MS (2)CAS It 7429-90-9

TITANIUM OtOXIOe . 1-10 10 MS/MI 10 Mi/M ( 3)CAS *: 134«3-«7-7

MAGNESIUM ALUMINOSILICATE t-10 1J MO/M3 10 MVM9 ' (4)CAS *J 1327-43-1

ALIPHATIC HVOROCAABON9 (STODOARO TVPC) 23-40 100 PPV 100 PPM (5)CAS »« 8092-41-3 . • •

NotMt

( i ) AS IOUSTPEL/TLV NOT ESTAHISHEO FOR THIS DMTERIM. . :THIS INGREDIENT IS NOT EXPeCTHJ TO BECOME AIRBOHM AM PRESENT A HAZARD UNOEM NORMAL CONDITIONS OP U SI Obi

( 2) PEL AND TLV ARt FOR TOTAL NUISANCE PARTICULATES.THIS CHEMICAL IS SUBJECT TO TV* REPORTING, REOUIR8MHTS OP SECTION 313 OP SARA TITLC III.

( 3) PEL AND TLV ARC FOR TOTAL NUISANCt PARTICULATES.

( 4) PEL AND TLV ARf FOR TOTAL NUISANCE PARTICULATES.THIS INGREDIENT IS NOT ITO THE mVSICAL FORM OPNIOSHIMINUTE

THIS. INGREDIENT ISJOt EXPECTBTO,BECOME AIRBORNE AM PRESENT A HAZARD UNDER NORMAL CONDITIONS V USB OUt

( S> .NJP "fCOMBlNOS A LIMIT OP 380 MB/CUB - 9 HOUR) TTM9 WOMTEO AVERMi. IBM MO/CUM AS OETERMINBJ ft A '9

ON 111 , •• •« » S I C AL D A I A

Boiling Point for COMPOHEKT( 29-40%) U7"?? oS Cl"________________________________•____________t 790-00 «• "•

V«oor PrcMur* for COMPONENT( 29-40%)

HEAVIER THA« »•

. •( *lTa?.P«re*nt ____________________________Evipormtion Rat* ___ _________________________________ SLO>W

3Com. ALUMINUM CO.JB

COPYRIGHT 1990 COHTIM0BD OM PAGIt 2 A.ROOOI29

MATERIAL SAFETYDATASHEET

24-HOUlor **•« one i«^P.O. BOX 2219

COLUMBUS, OHIO 43216 1(800> 274-5263 or(614) 889-333?_______1(800) ASHLAMP

000011 TKCTYL 127 CG Pag«:I I P H Y S I C A L D A T A t C u n l i n u c d i

Stat* _____________________________________________________LIQU10form • HETER SOU*

O N I V F I H t A N D t X F L O S I O N I N F O H M A r i Q M

PUSH PO!NT(PMCC ) > 100.0 0«g F ( 37.• 0«fl C)EXPLOSIVE LIMIT (LOWEST VALUE OP COMPONENT) LOWER - 1.0% UPPER - 8.0%EXTINGUISHING MEOIAt REGULAR FOAM OR CARBON DIOXIDE OR DRV CHEMICAL

"w%® 1l %Sffi r*»S£ M£5TEft?"<**** OIOXIDe *"° C*R80H "0"oxloe- VAWOU,»FIREFIGHTING PROCEDURESi HEAR SELF-CONTAINED BREATHIN8 APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVfPRESSURE DEMAND MODE WHEN FIGHTING FIRES.SPECIAL FIRE t EXPLOSION HAZARDSI NEVER USE MELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN BffTV) BECAUSfPRODUCT "EVEN JUSTRESIDUE) CAN IGNITE EXPLOSIVELY.

ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDEDAND/OR BONDED WHEN MATERIAL IS TRANSFERRED.NFPA CODES t HEALTH- 1 FLAMMABILITY- 2 REACTIVITY- 0

ON V M L A L T H HA/AHO DATA

PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II.EFFECTS OP ACUTE OVWEXPOSURE:EVES - CAN CAUSE SEVER* IRRITATION. REDNESS. TEARING, BLURRED VISION.SKIN - PROLONG!! OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION. OEFATTTNO. DERMATITIS.BREATHING - EXCESSIVE INHALATION OF VAPORSCAN CAUSE NASAL AMD RESPIRATORY IRRITATION .CENTRAL NERVOUS SYSTEMEFFECTS INCLUDING DIZZINESS. WEAKNESS. FATIGUE. NAUSEA. HEAOACHI AND POSSIBLE UNCONSCIOUSNESS. AND EVENSWALLOWING'- CAN CAUSE GASTROINTESTINAL IRRITATION. NAUSEA. VOBTINB.. AM DIARRHEA. ASPIRATION OP MATERIAL INTOTHE LUNGS CAN CAUSE CWMJCAL PNEUMONITIS WHICH CAN M FATAL.FIRST AIDtIF ON SKINt THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHIN9. LAUNDER

IF IN evES. FLUSH WITH LARGE AMOUNTS OP WATER. LIFTING UPPER AMO LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.

IF SREATHEDt IF AFFECTED. REMOVE INDIVIDUAL TO FRESH AIR. IF 9REATWNO IS DIFFICULT. ADMINISTER OXYGEN. IfBREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM. QUIET AND GET MEDICAL ATTENTION.

PRIMARY ROUTE(S) OP ENTRY tINHALATION. SKIN CONTACT

EFFECTS OP CHRONIC OVEREXPOSUREiOVEREXPOSURE TO THIS MATERIAL (C« ITS CTgOMBffS) HAS BCBI 9UOOUTB AS A CAUS1 OP THf FOLLOW NO EFFECTS IN

s f c r i ON vi H t A(. t i -j i r y ,) A r AHAZARDOUS POLYMERIZATIONS CANNOT OCCUR,STABILITY t STABLEIHCCMPATIBILITYt AVOID CONTACT WITHt. STROMB OXIDIZING AGBNTS.

»' •< oc f :)LIH t sSTEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEOsSMALL SPILLi ABSORB LIQUID ON PAPER. VERMCULIT1. FLOOR ABSORB*)*. OB QTHfJI ABSORBENT MATCRIAL AMD TRANSPOI T«

LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDIM* PILOT LIGHTS. ELECTRICAL SPARKS). PERSONS"~ WEARING PROTECTIVE EOUIPMENT»DULD BE EXCLUDED FROBA«C 0? SPILL UNTILCLEAN-U* HAS BEEN (XMPLgTBDV

' SPILL AT SOURCE. DIKE AREA OP SPILL TO PREVENT SPREAQIME, PUMP C7qUIQ,TO SALVAGE TAMt. REMAIN I NO_[ID MAY BE TAKEN UP ON SANff. CLAY. EARTH. FLOOR aiOMMBMTTCR QTHEftiBSORBBfT MATtRIAL AND SHOVELfB IN IAXNcKS*

PREVENT RUN-OFF TO SEWERS. STREAMS OR OTHER BODIES OP WATWM. IP MUH-OPP OCCURS. NOTIFY PROPER AUTHORITIESAS REQUIRED. THAT A SPILL HAS OCCURED.

WASTE DISPOSAL METHOD!SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW ***!CIEWr HMi FOR VAPORS TO COMPLETELY OJU*

HOOD DUCT WORK. DISPOSE OP REMAINING MATERIAL IN ACCORDANCE WfM APPLICABLE REGULATIONS.DISPOSE OP IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL

COPYRIGHT 1990 CONTINUED OH FAGIt 3 flRQQQ I 30

MATERIAL SAFETY «J"OJW COLOOTUSÔHIO^ZW USUU) Z7*-5Z« otDATA SHEET_____ ^BBMMMMWT_____ (614) 889-3333 1(800) ASHLAND

oooon_____________________TECTYL 127 CG________________ Pag«:

LARGE SPILL: DISPOSE OP IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL REGULATIONS.O N V I I I P R O T E C T I V E E Q U I P M E N T T O H E LJSEO

RESPIRATORY PROTECTION: IP WORKPLACE EXPOSURE LINIT(S) OP PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION II)A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OP PROPER ENVIRONMENTAL CONTROL. OSH»REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS(SEE VOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TOREDUCE EXPOSURE.

VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOWTLV(S).

PROTECTIVE GLOVESt NEAR RESISTANT GLOVES SUCH AS>. NITRILE RUBBER. NEOPRENE

.-.OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. WEAR IMPERVIOUS CLOTHING AND BOOTS.

ONS OH O T H E R COMMENTS

CONTAINERS OP-THIS MATERIAL MOV 16-HAZARDOUS WHEN aCTIED. SINCE EMPTIED CONTAINBB.JKTAIN* PRODUCT «*S10U«c*(VAPOR. LIQUID.-AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. *""*

THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO 3E ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATINGWITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM! IN ADVANCE OP NEED THAT THE INFORMATION ISCURRENT. APPLICABLE. AND SUITABLE TO THEIR CIRCUMSTANCES.

O N X L A 6 E L I N F O R M A T I O N

CAUTION!COMBUSTIBLE LIQUID AND VAPORMAY CAUSE EYE AND SKIN IRRITATION.INHALATION OP VAPOR MAY CAUSE IRRITATION OP NASAL AND RESPIRATORY PASSAGES.SWALLOWING MAV CAUSE IRRITATION OP MOUTH. ESOPHAGUS. AND GASTROINTESTINAL SYSTEM) AND MAY BE FATAL.

HANDLING fc STORAGE* '«

uun i «t* i wi in 3111 n« PHJM% jwrc i T 'TI JTT J w*« T_ TT.•: TI cj* ji«*»* ukwvc^t ww V»MBI* p» FT*vm**« i c prnw c\. i i »eEQUIPMENT ESSENTIAL FOR VOUR OPERATION: MINIMIZE EXPOSURE THROUGH GOOD HYGIENIC PRACTICES. 00 NOTTRANSFER TO UNLABELEO CONTAINER. 00 NOT USE CUTTING OR WELDING TORCH ON THIS CONTAINER (EVEN EMPTY). FORINDUSTRIAL USE ONLY-. 24-HOUR EMERGENCY NUMBER 1-900-ASHLANO.

FIRST AIDt ' 'EYESt FLUSH THOROUGHLY WITH WATER. GET MEDICAL ATTENTION IMMEDIATELY.SKIN: WASH THOROUGHLY WITH SOAP AND WATER. ;INHALATIONt IP AFFECTED. RCMDVC TO FMSH AIR. IP BREATHING IS DIFFICULT. GET MEDICAL ATTENTION.INGESTION: 00 NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER* IMMEDIATELY. ASPIRATION HA£AJM)

IF SWALLOWED/CANTlNTER LUNGS AND CAUSE OAMMt. NEVER GIVE ANYTHING 8V MOUTH TO AN UNCONSCIOUS PERSON.CHRONIC INFORMATIONS ' "CONTAINS: PETROLEUM DISTILLATES. CONTAINS MATERIAL(S) WHICH MAV CAUSE CENTRAL NERVOUS SYSTEM OEPRESSIQM.

••• COMPONENTS APPEAR IN SECTION II ••• ''

COPYRIGHT 1990 LAST PAGE—SIS ATTACHMENT PAGE KlI€l£9Ea-rIA6T PAGEA R O O Q i S f


ASHLAND CHEMICAl INC 24-HOURgt Auiii* oif. ne. Emergency

P.O. BOX 2219 TelephoneCOLUMBUS, OHIO 43216 1(800) 274-5263 or

(614) 889-3333 1(800) ASHLAND

DEFINITIONSThis definition P«g.* '* intended for us* with Material Safety, Data Sheets supplied, by the AiNjnd. Qiermcji Company ...Recipients of these data sheets should consult the OSHA' Safety and' Heafth Standards" (2§: CW"t9TO)f paHIcuTaiiy ~"""subpart G - Occupational Health and Environmentai Control, and subpart I - Personal Protective Equipment forgeneral guidance on control of potential Occupational Health and Safety Hazards.

SECTION I SECTION IV leant.)PRODUCT IDENTIFICATION ev»,iu«,,,eu, « .»«.. e „ », . ,-— «—— * —————— = —— *— EXTINGUISHING MEDIA: Following National Pire

GENERAL OB GENERIC 10: Chemical family or product Protection Association criteria.description. FIREFIGHTING PROCEDURES: Minimum equipment to

Product mMtt DOTcntena for hazards . firefighting hazards may also be indicated.SECTION II SPECIAL F1R1 AND EXPLOSION HAZARDS: States

COMPONENTS hazards not covered by other sections.• ' •

Components are listed in this section if they present a NFPA COOES: Hazard ratings assigned by the Nationalphysical or health hazard and are present at or above Fire Protection Association.1% in the mixture. If a component is identified as aCARCINOGEN by NTP. IARC. or OSHA as of the date SECTION Von the MSDS. it will be listed and footnoted m this HEALTH HAZARO DATAsection when present at or above 0.1% in the product PERMISSIBLE EXPOSUM LIMIT For productNegative conclusions concerning carcinogentcity are not —.-»...-.- ......... ....... - _._reported. Additional health information may be found in THRESHOLD LIMIT VALUE: For productSection V. Components subject to the reporting EFFECTS Of ACUTt OVEREXPOSURE: Potential localrequirements of Section 313 of SARA Title III are and systemic effects due to single or short termidentified m the footnotes m this section, along with overexposure to the eyes and skin or through inhalationtypical percentages. Other components may be listed if or mgestion,deemed appropriatex EFFECTS Of CHHONtC OVEREXPOSURE: Potential localExposure recommendations are foY- components. OSHA ^ systemic effects due) to repeated or long termPermissible Exposure Limits (PELS) and American overexposure to the eyes and skin or through inhalationConference of Governmental Industrial Hygtemsts & maestion.(ACGIH) Threshold Limit Values (TLVs) appear on the)line with the component- identification. Other FIRST AKk Procedures to b« followed when dealingrecommendations appear as footnotes. with accidental overexposure.

SECTION III ' ' PRIMARY ROUTE Of ENTRY: Based on properties andPHYSICAL PATA •xptc"d "" SECT1ON „

BOILING POINT: Of product if known. The lowestvalue of the components is listed for mixtures.

'— . ...... .. «. . . . «..._ HAZARDOUS POLYMERIZATION! Conditions to avoid 10VAPOR PRESSURE: Of product it known. The) highest present hazardous polymerization resulting in a urgevalue of the components is listed for mixtures. , release) of energy.SPECIFIC VAPOR DENSITY: Compared to AIR » 1. If STA1NJTV; Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known. violent decomposition.the value is expressed as lighter or greater than air. ,»».«..-..« ._*. .. . ..__ _„. „_ _ „ . .„„ . .„ INCOMPATItlUTY; Materials and conditions to avoid toSPECIFIC GRAVITY: Compared to WATER * t. If prevent hazardous reactions.Specific Gravity of product is not known, the) value) isexpressed as less than or greater than water. SECTION VIIprt If applicable. SPILL OR LEAK PROCEDURESPERCENT VOLATILE* Percentage) of material with _ . _ . . .. , .initial boiling point below 42S degree* Fahrenheit and «eaeona»« precautions to be taken and methods ofvapor pressure above) a 1mm Ha a«88 P conta«wnent clean-up and disposal. Consult federal.

«. ™ . -L itaw and locsi regulations for accepted procedures «*EVAPORATION RATE; Indicated as faster or slower w rtportmfl or notification requirements.than ETHYL ETHER, unless otherwise) stated

SECTION IV SlffPON. Y!»PROTECTS EOU.PMENT TO 8E USED

F.R8 A N D p o N DATA

**** "* ""PO.NT: MethodEXPLOSION LIMITS: For product if known. The lowsetvalue of the components is listed for mixtures. SECTION IXHAZARDOUS DECOMPOSITION PRODUCTS: Known or SPf OAt PRECAUTIONS OR OTHEPI COMMENTSexpected hazardous products resulting from heating. Cov-r, relevant points not previously mentioned,burning or other reactions.

ADDITIONAL COMMENTSContainers should be either reconditioned by CERTIFIED firms or property disposed of by APPROVED firms. Disposal a*containers should be in accordance with applicable laws jnd '•guabone. 'EMPTY* drum* Bfft'fi) Pfti b* <«ven '3md/vidua/s. Serious accidents have) resulted from the) misuse of 'EMPTfQ* contaners (drumsjswietejj M f «r ArStctiIV and IX

P<n BOX TiTia £»?r$ency f_:MATERIAL SAFETY ™»""™- COLUMNS* OHIO 43216 1 (800>'552-5261 a,DATA SHEET " •.M. r_______(614) 889-3333_______1 (800) SJLJSS* *

TECTYL 165 6 (DORD) Pag«s000012———

*•••••••••••••••••••••*••*•••**•••*••••••••••••*•*••**••••••••••*••••*••••••*•*•••••••••*•••••*••••••••Product N*MI TECTVL IBS G (OORO) '.

09 90 MO 8091603-59*THE 9UOO COMPANY:ATTN; CHARLES PAYNE3155 W. BIG 8EAVER ROAO . ..__..TROY, MI 48084 INVOICE: REOST----- -Yrgi r

Data ShMt No: OQ20t9t-003Prepsredt i2/22/8fSuper**dees 08/26/Si

INVOICE OATS: 11/08/90TO:

ON l - P R O Q U C r I OE HT I F I CAT I ON

General or Generic ID: PETROLEUM BASS) RUST PREVENTATIVEDOT Huard CJaealf 1cat1ont COMBUSTIBLE (173.119)

ON I I - C O M P O N E N T S

THE COMPOSITION OF THIS PRODUCT IS KING WXTHCLD AS A TRAOf SECRET.• IP PRESENT. IARC. MTP AND OSHA CARCINOGENS ANB CHEMICALS SUBJECT-TO-TV* REPOM**"—j — -

ING REOURfrEKTl OF SARA S o , , . IN THIS SECTION.

INGREDIENT « (by WT) PEL TLV Not*

1302-78-9

ALIPHATIC HYDROCARBONS (STODOARO TYW 40-fS 100 PPM 100 PP» (2)CAS •*$ 805 2-41 *3

HYOROTREATB) NAPHTHWIC BASC OIL _, t-1Q 9 NQ/tti 9 MGAO ( 3)CAS *: 64742-92-9 '• -v,.,

ceoETMVUENE avCOL WNOBUTYL ETHH t-9 29 PPM • SKIN 29 PPM - SKIN (4)

CAS *» 111-78-2

Notes: _ .. . . ., --. : -_,--_( 1) PBL/TLV NOT ESTABLISrtD FOR THJS MATWIAt

PEL AND TLV ARE FOR TOTAL NUISANCE PARTICULATE4.BECOME AinaORHI AND PRESOfT A HAZARD UNOBI NORMAL CONDITIONS OP uSt OH

( 2) NIOSH RECOMMENDS A LIMIT Of 390 MO/CUM - 8 HOW TTHf WIGHTBD AVERAGC. 1800 MS/CUM AS OETERMINCO t» • 5MINUTc

( 3) PEUTLV NOT ESTA8USHED FOR THIS MATBIIALPCL/TLV IS FOR OIL MIST. AOSIH SHORT TBW EXPOSUal LIMIT (STEL) FOR OIL MIST IS 10 MO/CUM.

( 4) SKIN ABSORPTION MAV POTBmALLV CONTRIBUTl TO THI OVERALL 6XPOSURE TO THIS MATERIAL. APPROPRIATE MCASHOULD BG TAKEN TO PREVWT A0SORFTICN SO THAT THt TLVtrNOT INVALIDATED.THIS CHBOCAL IS SUBJECT TO THE REPORTINa REOUIRaMNTS OP SECTION 313 Of SAM* TITLE III.

, I C A L D A T A

Boiling Point for PRODUCT uS'9 °** '

vapor ProsauTM for COMPONENT!40-991)

Specific vapor Density _________________________________________ KAY18R •>•* AI»Specific Gravity ,

_... ...i.î*..,Percent Volatile* ^____________ ______________________- "Evaporation Rats ______________________________________ SLOMRRAppearance _______________________________________-___State ________________________________________F_____u:ou:aFone , ~~~~" """"""""""™" '. NTtH SOL*

COPYRIGHT 1388 CONTIMUBO OH PACK 2 AROOOI33


ASHLAND (JHEMlt'AV-NC; 24-HOUIt——~"s«b»i««rv at AI*IM« an. IK' Em«r»tncv '• •P.O. BOX 2219 "tSphSSJi

COLUMBUS, OHIO 43216 1(800) 274-5263 or(614) 889-3333_______1(800) ASHLAND

000012 T1CT7L 165 G (DORD) Pag«:Q M I « - F I H E -AND E X P L O S I Q M I N F O H M A r i Q M

PUSH POINT(COC ) 100.0 Otfl f ( 37.8 0«fl C)EXPLOSIVE LIMIT (LOWEST VALUE OP COMPONENT) LOWER - 1 . 0 %EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRV CHEMICALHAZARDOUS DECOMPOSITION PRODUCTSs MAY FORM TOXIC MATERIALS:. CARBON DIOXIDE AMD CARBON MONOXIDE. VARIOUS

HYDROCARBONS. SULFUR COMPOUNDS. ETC.FIREP1GHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE

WATER OR FOAM MAV CAUSE FROTHING WHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF TOE FIREFIGHTER.CSPECIALtV IF SPRAYED INTO CONTAINERS OF HOT. BURNING LIQUID.

SPECIAL FIRE fc EXPLOSION HAZARDS. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) KCAUS&PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY HEAT.PILOT LIGHTS. OTHER FLAMES AND IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING POINT.ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDEDANO/OR BONDED WHEN MATERIALlTTRANSFERRED.

NFPA COOES: HEALTH- * FLAMMABILITV- 2 REACTIVITY- 0S b C I I O N U H E A L T H HAZARD OAIA

PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II.EFFECTS OF ACUTE OVEREXPOSUREiEVES - CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING. BLURRED VISION. __ ___BREATHING • EXCESSIVE INHALATION OF VAPORJCAN CAUSE NASAL AND RESPIRATORY IRRITATION. CENTRAL NERVOUS SYSTEM

EFFECTS INCLUDING DIZZINESS. WEAKNESS. FATIGUE, NAUSEA. HEAOACHi AND POSSIBLE UNCONSCIOUSNESS. AND EVENSWALLOWING*- CAN CAUSE GASTROINTESTINAL IRRITATION. NAUSEA. VOMITING. AND DIARRHEA. ASPIRATION OF MATERIAL INTO

THE LUNGS CANCAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.SKIN - PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION. OEFATTTNG, DERMATITIS. COMPONENT IS READILY

A8SOPB60THROUCH THE SKIN AND MAY PRODUCE TOXIC EFFECTS.FIRST AID:IF ON SKIN i THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVf CONTAMINATED CLOTHING. LAUNDER

CONTAMINATEDCLOTHING BEFORE RE-USE.REMOVE CONTAMINATED SHOES PROMPTLY. DISCARD SHOES SATURATES WITH THIS PRODUCT.

IF IN EYES: FLUSH WITH LARGE AMOUNTS OF WATER. LIFTING UPPER AMB LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.IF SWALLOWEOi 00 NOT INDUCE VOMITING. KEEP PERSON WARM, QUIET. AND GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL

INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNCUHDNtTli WHICH CAN M FATAL.IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TQ,FRESH AIR. IF 8REAT>«IN9_IS OJFPJCULT..AOW1I1ST8I OXYGEN. IF

REATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON •***. QUIET AND GET MEDICAL ATTENTION.

PRIMARY ROUTB(S) Of ENTRVt .INHALATION. SKIN CONTACT. SKIN ABSORPTION

EFFECTS OP CHRONIC OVEREXPOSUM*ETHVLENE GLYCOL MONOBUTYL ETHER (GLYCOLETHIR EB) CAUSES HARB) TOTMI PfTVS IN LABORATORY ANIMALSTUOIff. HAW

TO THE FETUSOCQJRS ONLY AT EXPOSURt LEVELS THAT HAW THB MMOMMT AMIMAL. THE RELEVANCE OP THESt FINDINGSTO HUMANS IS UNCERTAIN.

, t C I I Q N U I H t

HAZARDOUS POLYMERIZATIONt CANNOT OCCURSTABILITY: STABLEINCOMPATIBILITY! AVOID CONTACT WITHt. STRONG OXIDIZING AGRWTI.

ION M I I SH I L U )•«

STEPS TO BB TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ISMALL SPILL. ABSORB LIQUID ON PAPER. VERMKULITE. FLOOR ABSORBBMr. 01 0*MB1 'HOBBBIT MATERIAL AND TRANSFER TO

LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES. FLAMKSIMCLueiMB. PILOT LIGHTS. __••" WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUOEO FlOB A«EA OP SPILL UNTIL CLEAN-*

P SPILL AT SOURCE. Olffi AREA OF SPILL TO PREVENT SPtCAOtMft. •«•> LlQUIOJOmwuui° *i »C TAKEN UP ON SAND. CLAY. EARTH. FLOOR IBSORBBMT. OR 0THBR uTORJEUT MACONTAINERS M ON SAND. OAV. EARTH. FLOOR ABSORBBMTTOR OTH|R~ABSOPJBNT MAttRXAL AND SHOVELED INTO

PREVENT RUN-OFF TO SEWERS. STREAMS OR OTHER BODIES OP WftTV. IP «*-OPP OCCURS. NOTIFY PROPER AUTHORITIES

COPYRIGHT 1988 COMTINUIO OH PAGlt 3 ARQOO I 8(4

ASHLAiNTJ CttJsr CAU Kit. 24-HOuTT-~-

MATERIAL SAFETY ——————"* COLuTBUsfoHIO Zl* l(8<3o} 1 263 ofDATA SHEET '••W _______(614) 889-3333_______1J800)ASHLAND

000012 TECT7L 165 6 (OORO) Pag«:OH L E A K P H O C E U U H t S

AS REQUIRHJ. THAT A SPILL HAS OCCUR60.

WASTE DISPOSAL METHODS•SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW SUFFICIENT TIME FOR VAPORS TO COMPLETELY CLEAR

HOOD OUCT WORK. DISPOSE OP REIMINING MATERIAL IN ACCORDANCE WITH APPLICABLE REGULATIONS.DISPOSE OF IN ACCORDANCE WITH ALL LOCAL. STATE ANO FEDERAL REGULATIONS.

LARGE SPILL: DESTROY 8V LIQUID INCINERATION. .DISPOSE OP IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL REGULATIONS.

ro BF ustnRESPIRATORY PROTECTION* IP WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION II),

A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTWX. OSHAREGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS(SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLSCNTED TO

VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOWTLV(S).

PROTECTIVE GLOVES. WEAK RESISTANT GLOVES SUCH AS>. NITRILE RUBBER, NEOPRENS

OTHER PROTECTIVE EQUIPMENT; TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. WEAR IMPERVIOUS CLOTHING ANO BOOTS.AL P R E C A U T I O N S OR O T H E R COMMENTS

CONTAINERS OP THIS MATERIAL MAY M HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES(VAPOR. LIQUID. AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST EC OBSERVED.

THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE »«THER ORIGINATINGWITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OP NEED THAT THE INFORMATION ISCURRENT, APPLICABLE..AND SUITABLE TO THEIR CIRCUMSTANCES.

S E C f l O N X - t A H E L ) I N F Oft MA'^»I»Q H

WARNING!COMBUSTIBLE LIQUID ANO VAPO»MAY CAUSE EVE AND SKIN; IRRITATION.INHALATION OP VAPOR MAY CAUSE IRRITATION OP NASAL AND RESPIRATORY PASSAGES..SWALLOWING MAY CAUSE IRRITATION OP MOUTH. ESOPHAGUS. ANO GASTROINTESTINAL SYSTEM ANO MAY BE FATAL.COMPONENT(S) MAY BE IBSORBED THROUGH SKIN IN TOXIC AMOUNTS.

HANDLING tr STORAGEi ' ' :MAINTAIN AMBIENT AIR. CONCENTRATTON(S) OP VOLATILE COMPONENT(S) BELOW PERMISSIBLE EXPOSURE LIMITS. M!A*

OR GOmES7.ReSXSTANT GLQVEfTANO OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR.

SAFETY GLASSES OR GOmES7.ReSXSTANT GLQVEfTANO OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR «*fOPERATION. 00 NOT TRANSFEfl TO. UNLABELEO CONTAINe*. USE OR STORE ONLY WITH AOEQUATE VENTILAnON. 00 NOTUSE CUTTING OK WELDING TOUCH ON THIS CONTAINEIMEVEN EMFTYt. KEEP AWAY FROM HEAT. SPARKS. ANO OPEN FLAM*.AVOID CONTACT WITH EYES ANO SKIN. MINIMIZE EXPOSUM THWUOH GOOD HYGIENIC PRACTICES. 24-HOUR EMERGENCYNUMBER 1-800-ASHLANO.

FIRST AIOs 'EYESs FLUSH THOROUGHLY WITH WATER. GET MEDICAL ATTENTION IMMEDIATELY.'SKINs WASH THOROUGHLY WITH SOA» ANO WATER.INHALATIOMt IP AFFECTED. REMMI TO FRESH AIR. IP BREATHIN* IS DIFFICULT. GET MEDICAL ATTENTION.INGESnONt 00 NOT INDUCC VOMITING.GIve TWO GLASSES OP WATER AND GET MEDICAL ATTENTION IMMEDIATELY. NEVERGIVE ANYTHfNa BY MOUTH TO AN UNCONSCIOUS PERSON. ASPIRATION HAZARD IP SWALLOWED. CAN ENTER LUNGi ANO CAbStOAMAGf. . • ; ^

CHRONIC INFORMATIONtCONTAINS! PETROLEUM1 DISTILLATES ANO ETHVLENC GLVCOL HCMBUTVL ETHER. CONTAINS MATERIAL(S) WHICH MAY CAUBLOOD ABNwWjlTIES. CeHT«£ NERVOUS SYSTEM OePRJ&ICft.»fS»IRATC«Y SYSTEM. EYt. KIDNEY AND/OR LIVER

••• COMPONENTS AMCA* IN SECTION II •••

COPYRIGHT 1988 LAST PAGE--SI* ATTACBMBMT PACK KMCLOSKO—LAST PAGE


ASHLAND CHEMICAMNO 24-HOTOOH. I**««•«* OH. I* Emergency

P.O. BOX 2217 TelephoneCOLUMBUS, OHIO 43216 1(800) 274-5263 or

(614) 889-3333 1(800) ASHLAND

DEFINITIONSThis definition page if intended for use with Material Safety Data Sheets supplied by the Ashland piemical Company.

suboart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment forgeneral guidance on control of potential Occupational Health and Safety Hazards.

SECTION I SECTION IV (eontl-- - -- PRODUCT IQENTIPtCATION- — • ~ -•••**• - ~— <*.,-;.,>..„-.,...;* ""»«i».-i- -:. -rr *.- -*•=*.-, ;••.- •*-«.-—,-.— 'YT'T —————— * —— *•* EXTINGUISHING MEDIA: Following National Pfre

GENERAL OR GENERIC ID: Chermcat family or product Protection Association criteria,description. FIREFIGHT1NG PROCEDURES: Minimum equipment to

srs fSSF"** Productfor hazards listed. firefighting hazards may also be indicated,SPECIAL FIRt AND EXPLOSION HAZARDS: States

COMPONENTS hazards not covered by other sections.Components are listed in this section if they present a NFFA COOES: Hazard ratings assigned by the Nation*physical or health hazard and are present at or above Fire Protection Association.1% in the mixture. If a component is identified as aCARCINOGEN by NTP. IARC. or OSHA as of the date SECTION Von the MSDS. it will be listed and footnoted in this HgALTH HAZARD DATAForreported. Additional health information may be found in THRESHOLD LIMIT VALUfc For productSection V. Components subject to the reporting EFFECTS OP ACUTI OVERSXPOSURf: Potential localrequirement* of Section 313 of SAflA Title ill are and systemic effects due) to single or short termidentified in the footnotes in this section, along with overexposure to the eyes and skin -,- -"rough 'creationtypical percentages. Other components may be listed if or ingestion.deemed appropriate. _____ m ^ ^ Q ^ ^ Potent,* localExposure recommendations are for components. OSHA ^ ,¥sten»e .ffw:ts ag. to f«,,K* or long termPermissible Exposure Limits (P1LS) and American overexposure to the eyes and sktn or through inhalationConference of Governmental Industrial Hygtemsts «, ,rv3*.t,an.(ACGIH) Threshold Lirmt Values <TLVs) appear on the ^line with the component identification. Other FIRST AlOt Procedures to be followed wntn dealingrecommendations appear as footnotes. with accidental overexposure.

SECTION IM . PRIMARY ROUT! OP ENTRY; Based on properties andPHYSICAL DAfA expected use.

BOILING POINT: Of product if known. The> lowest $f ff"0. *f Vtvalue of the components is listed for mixtures. RiACTIVlTY DATA„.„„. «„,...»,. «. ^ « . «. u-^ HAZAROOOS POLYMERIZATIONt Conditions to avo.d toVAPOR PRiSSURt Of product if known, The highest prevent hazardous polymerization resulting in a Urgevalue of the components is listed, for mixtures. release) of energy,SPECIFIC VAPOR DENSITY: Compered to AIR • 1. If STAWUT* Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known. violent decomposition.the value is expressed as lighter or greater then sir. ,««-«...».....,-».. .. ^ _ . ^ .<...<..«« >...T««w /. .. ....-PH. . .. INCOMPATIBILITY: Materials and conditions to avoid toSPECIFIC GRAVITY: Compared to WATifl « 1. If prtvent hazardous reactions.Specific Gravity of product is not known, the value isexpressed as less than or greater then water. . SECTION VIIpht If applicable. ' 8P11L OH

*

PERCENT VOLATNJSt Percentage, of material with „ . _ . . , _ .initial boiling point below 425 degree* Fahrenheit and "eeiowwe precautions to be taken ind methods ofvapor pressure abov« a 1mm Hg et8t P. COM*!'T> JlM"7° " *«0«sei Consult federal«T* .«..««« .AM. , :, • , »<*• «"* l«el* r««ul«t"ens for accepted procedures andEVAPORATION RATfc Intfcsted as faster or slower **, .. orting or notification requirements.than ETHYL ETHER unless otherwise stated

SECTION .V PROTECTM EQU NT TO «. US«O

" "*'* "" "*

F.RI A N x N DATA

FLASH POINT: Method ,dent,fied.EXPLOSION LIMITS: For product if known. The lowset ««-.,*,.,value of the components is listed for mixtures. SECTION IXHAZARDOUS OfCOMPOSITtON PRODUCTS: Known or SPECIAL PRiCAUTIONS OR OTHiR COMMENTSexpected hazardous products resulting from heating, Co¥-rf f»t«ant points not previously mentioned,burning or other reactions.

ADDITIONAL- COMMENTSContainers should be either reconditioned by CERTIFIED firms or 0roeer«v disposed of by APPROVED firms. Disposal a*containers should be in accordance with applicable laws an4 ••queno"*. 'EMPTY* drums should not be $"•*•• »individuals. Serious accidents have resulted from the misuse of 6V»T'fO* comakers (drums.peMs.etci Refer to S*ct><X"»IV4ndlx AR000136

ASHLAND CHEf*jJAi INCsunnily of »3i3Ljr tr'v~

SE ff" "mm" COL&fifi»!°S.SlS,2W UaJo)'!! orDATA SHEET •••••»' ________(614) 889-3333 1(800) ASHLAND

000013 TICTYL 506 G Pag«:COMPLIES —•-" -•»—•-• •

Product N«wt TECTVL 506 G

THE BtJOO COMPANYOS 90 110 8091803-591

ATTN; CHARLES PAYNE315S W. BIG BEAVER ROM) PRODUCT:TROV, MI 48084. INVOICE: REQST

INVOICE OATEt 11/08/90TO:

Sheet NOJ 0020239-007Prepered: 10/11/90- -*~---- 05/31/89

ON I • P H OOU C f

General! or Generic IDt PETROLEUM BASED RUST PREVENTATIVEDOT Hu«rcl Cl»Mlf1cmt1on« COMBUSTIBLE (173.119)

OH I I - C O M P O N E . N T S

THE COMPOSITION OP THIS PRODUCT IS BEING WITHHELD AS A TRAOC SECRET.If PRESENT. IARC. NTP ANO QSHA CARCINOGENS AND CHEMICALS SUBJECT TQ THE REPORT- "

i ING REQUIREMENTS OP SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION.SEE DEFINITION PAG* mi CLARIFICATION

INCXEOIBfT * (by WT) PEL TLV Not*

1302-7M '-10 1

ALIPHATIC HYDROCARBONS (STODOARO TYPE) 40-99 '00 PPM 100 PPM { 2)CAS *i 80S2-41-3

NottMt '; '( 1) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL

PEL ANO TLV ARE FOR TOTAL NUISANCE PARTICULATES.THIS INGREDIENT ISNOT EWECTEDTQBECOME AIRBORM AM PMCSENT A HAZARD UNDER NORMAL CONDITIONS OF USE OUC

( 2) N!OSH_RECO*E»S A' LIMIT OP 350 MO/CUM - 8 HOUR HMf tCIGHTED AVERAGI. IBM MO/CUM AS DETERMINED 8V A 19MINUTE

O N I I I , P H Y S I C A L O A I A

Soiling Point for COMPONENT 40-59%) 334.00 0*f F____________ ._. _____ 4 T&igsrH?Vapor Pr«M«jr« f or COMPONENT( 40-55%) -• 2. CO <m HB________ ; ___________ !( 8:8ialiSpecific v sor 0«ra1ty ________________ _________ _________________ HEAVIER THAN AIRSc«c1f 1C Gr-vlty .B7J - ff

______________ _ ( ja.la-iSS oP«rc«nt volatllt* ___________________ __________ ______________ 40-55%6v )or«t1on R«t« SLOWER THAN

For. HBTW SXIIs t c r i on i v f- i H t A<« » • «• . >•• i OM i tt OH MA r i

FLASH POINT 100.0 Oeoj P ( 37.8 Oet C)EXPLOSIVE LIMIT (LOWEST VALUE OP COMPONENT) LOWER • i.0» UPPER)- «.0>EXTINGUISHING MEDIA t REGULAR POM OR CARBON DIOXIDE 01 OR* OEM CM.

PRODUCTS. MAY POM TOXIC NATBJU-UU. CARBON OIOMOE ANO CARBON MOMKIOR. VARIOUS

NAtER OR FOAM MAY CAUSE FROTHING WIQ4 CAN M VTOUNT AMR •OSSIBLV ENOANGER THf LIFE OP THEESPECIALLX IF SPRAVED INTO CONTAINERS OF HOT. BURMIMi UQUIOTIAL FIRE & EXPLOSION HAZARDS: NEVER USE WELDINPRODUCT (EVEN JUST RESIDUE) CAN IGNITE GXPLOS

SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE WELDING OR CUmM» tMM ON OR NEAR ORURI (EVEN EMPTV) BECAUSESIVELV.

COPYRIGHT 1990 CONTINUIO OM PACK 2ftROOOI37


AshlandASHLAMT CHEMICAI-JCNC!: "

SrtMitf? Of AtftH* OW liiT *P.O. BOX 2219 —

COLUMBUS, OHIO 43216(614) 889-333*

24-HOUIfE»«rj«ncy '- .T*L*phon«

1(800) 274-5263 or1(800) ASHLAND

~2

OOOQ13 TECT71, SOS G Pag«N F O R M A T I O N

VAPORS AM HEAVIER THAN AIR AND MAY TRAVEL ALONG TVS GROUND OK M MOVED 8V VENTILATION AND IPILOT \I3JTSTOTHSI FLAMES AND IGHinON SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING

BY HEAT.

AND PI'loSic »I T At*?: nAKJEB y*IN<a$ IMaiJOING TW4K CMS *** TAWt TPUCKS SHOULDNFPA COOESt HEALTH- I FUNMABILITY- 2 R6ACTIVITV- 0

ON V H E A L T H HAZARD DATA

PERMISSIBU EXPOSUP* LEVELS NOT ESTABLISHED FOR PRODUCT. SEE SECTION II.EFFECTS OF ACUTE OVEREXPOSUREj

SKIN - PROLONGED OR REPEATED_CONTACT CAN £AUSE MODERATE IRRITATION. OEFATTING. DERMATITIS. ''BREATHING - EXCESSIVE INHALATION OP VAPORSCAN CAUSE NASAL AND RESPIRATORY IRRITATION.CENTRAL NERVOUS SYSTEM

EFFECTS INCLUDING DIZZINESS. WEAKNESS. FATIGUE. NAUSEA. HEADACHE AND POSSIBLE UNCONSCIOUSNESS. AND EVEN'"NG"- CAN CAUSE GASTROINTESTINAL IRRITATION. NAUSEA. VOMITING. AND DIARRHEA. ASPIRATION OP MATERIAL INTO! LUNGSCAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.

FIRST AID:IF ON SKIN: THOROUGHLY WAJHEXPOSEO AREA WITH SOAP AND WATER. RSOVE CONTAMINATED CLOTHING. LAUNDER

IF IN EYES: FLUSH WITH LARGE AMOUNTS OP WATER. LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.IF SWALLOWED: 00 NOT INDUCE VOMITING. KEEP PERSON WARM. QUIET. AM) GET MEDICAL ATTENTION. ASPIRATION OP MATERIAL

INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.IF BREATHED: IF AFFECTED. REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN. IP ' '

BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON MUM. QUIET AND GET MEDICAL ATTENTION.

PRIMARY BOUTKS) OP ENTRY tINHALATION. SKIN CONTACT

EFFECTS OP.CHRONIC OVEREXPOSUREiOVEREXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A CAUSE OP THE POLLOMNB EFFECTS IN

HUMANS:. CENTRAL NERVOUS SYSTEM EFFECTSI I ON VI H t AC f I « I ( Y U A I A

HAZARDOUS POLVMBHZATIONr CANNOT OCCUR)STABILITY: STABLE,INCOMPATIBILITYt AVOID CONTACT WITH:. STRONG OXIDIZING AGENTS.

S E C T I O N V I I S P I L L O R L f A K P R O C E D U R E S

STEPS TO M TAKEN IN CASE MATERIAL IS RELEASED OR SPILLS iSMALL SPILLs ASSOM LIQUID .ON PAPER. VERKCUUTC. FLOOR IB50RBUIT. OR OTHER ABSORBENT MATERIAL AND TRANSFER TO

LARGE SPILLi ELIMINATE ALL IGNITION SOURCES (FLARES. FLAMESINCUJOIM PILOT LIGHTS. ELECTRICAL SPARKS). PERSONSNOT WEARING PROTECTIVE EQUIPMeNTSffitB BfwttUOeoPlai I«SS OP SPILL UNTIL CLEAN-UP HA| BEEN COMPLETEOVSTOP SPILL AT SOURCE. DIKE AREA Of SPILL TO PREVENT SP*tA01M». PUMP LIOUIO*TQ SALVAGS TANK. REMAININdLIWIO MAY BC TAKEN UP ON SAND. CLAY, EARTH. FLOOR IISORBENT. OR OTHER ABSORBENT MATERIAL AND SHOVELED INTOCuNTA INCUS*

M°ltS * ™' l" « OCCURS. NOTirY PROP* AUTHORITIES

WASTE DISPOSAL METHOBtSMALL SPILLi ALLO» VOLATH4_PORTION TO EVAPORATE IN HOOO.ALLOM SUFFICIENT HMf FOR VAPORS TO COMPLETELY CLEARHOW oua iaRK.oiSpBi OP ROIAINING MATERIAL IN ACCOROAMCI WITH AMUCABU REGULATIONS.

OlSPOSt OP IN ACCOROANO WITH ALL LOCAL. STATE AND FEOBJNM. MOULAnON*.LARGE SPILLi DESTROY BY LIQUID INCINERATION.

DISPOSE OP IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDOUM, •COULAnONS.I TO Hfc U StO

RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMJT(S) OP PRODUCT ON AMYOIpSHyMS .APJR AnrSjpPL TypB

'SHOULD if It"C WCi* B t OSUN >•

VENTILATION* PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOOM, t*«UST) veNTILATION TO MAINTAIN EXPOSURE BELOW)

PROTfCnvt GLOVESt WEAN RESISTANT GLOVES SUCH AS:. NEOPRENE. N11ILE RUBMI

' •ZSBSMXM-COPYRIGHT 1990 CONTINU10 OH PAGll 3 AROODI38

MATERIAL SAFETY «f»«WM» COLHMBOS" OHI043216 1(800)DATA SHEET ^ •• ' _______(614) 889-3331 1(800) ASHLAND

000013 ________________ TBCTYt 506 G_____ ____ Pag«;

OTHBI PROTECTIVE EQUIPMENT, TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. WEAR IMPERVIOUS CLOTWN8 ANO BOOTS.P R E C A U T I O N S OH O T H E R COMMtNTS

RESIDUESCONTAINERS OP THIS MATERIAL IMV BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT Rl(VAPOR. LIQUID. AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST M OBSERVED.

THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATINGWITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TQ CONFIRM IN ADVANCE OP NEED THAT THE INFORMATION ISCURRENT. APPLICABLE. AMD SUITABLE TO THEIR CIRCUMSTANCES.

CAUTION!S E C T I O N X L A B E L I N F O H M A M O N

*WV CAUSE EYE AND SKIN IRRITATION.INHALATION OP VAPOR IMV CAUSE IRRITATION OP NASAL ANO RESPIRATORY PASSAGES.SWALLOWING MAV- CAUSE I«MKATJON-0*-MOUTH. ESOPHAGUS, *» GASTOIKTETOM SXSCT*W>*> «tt* ifc,MTA»»

HANOLINQ I STORAGE*KEEP AWAY FROM HEAT ANO OPEN FLAIC. USE OR STORE ONLY WITH ADEQUATE VENTILATION. WINTAIN AMBIENT AIR

CONTACT.

AVOID CONTACT WITH EYES ANO PROLONGED OR. RESISTANT GLOVES.ANO OTHER APPROPRIATE

. IMIZE EXPOSURE THROUGH GOOD HYGIENIC PRACTICES.TRANSFER TO UNLASELEO CONTAINER. DO NOT USE CUTTING OR WELOINGTORCH ON THIS CONTAINER XEVEN EMPTY). FOBINDUSTRIAL USE ONLY 24-HOUR EMERGENCY NUMBER 1-800- ASHLAND.

FIRST AID. .-' - -EYESt FLUSH THOROUGHLY WITH WATER. GET MEDICAL ATTENTION IMMEDIATELY.SKIN: WASH THOROUGHLY WITH SOAP ANO WATER. -INHALATIONS IP AFFECTED,, REMOVE TO FRESH AIR. IP BREATHING IS DIFFICULT, GET »ICAL ATTENTION.INGESTIONi 00 NOT INDUCE'1 VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IM0IATELY. ASPIRATION HAZARDSWALLOWED. CAN QJTER LUNGS AND CAUSE DAMAGE. NEVER 01 Vf ANYTHING BY MOUTH TQ AM UNCONSCIOUS PERSON.

CHRONIC iNFORMATIONtCONTAINSs PCTROLEtM DISTILLATES. CONTAINS IHTERIAL(S) WHICH MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.

. . ••• COMPONENTS APPCAN IN SECTION II •••

COPYRIGHT 1990 LAST PAGI—Sit ATTACHMUTT PACK KNCLOSID--LAST PAG 1BflfflTfS?

1MATERIAL SAFETY

DATASHEET

ASHLAND CHKM1CAL-4NC;—————24-HOUr———~sntiMiacy it *a«M on if EnerzencyP.O. BOX 2219?-' Telephore

COLUMBUS, OHIO 43216 1(800) 274-5263 or(614) 889-3333 1(800) ASHLAND

DEFINITIONSThis definition page i* intended for use with Material Safety Data Sheets supplied by the Ashland Chemical Company.Recipients-- of the** data> sheeW-she*** consult -CSrUresfety m*H****9ix**4*W9i9tm+91*rf****m+n "•subpart G - Occupational -Health and Environmental Control, and subpart I - Personal Protective Equipment forgeneral guidance on control of potential Occupational Health and Safety Hazards.

SECTION \ SECTION IV (eont)PROogcr IDENTIFICATION EXTINGUISHING MEDIA: Fallowing Nat.on* P.,.

GENERAL OB GENERIC 10: Chem.cal family or product Protection Association enter*description. F1REF1GHT1NG PROCEDURES: Minimum- aquipmtm to

,ACAT10'* *•** mMt* OOThazards firefightmg hazards may also be indicated. MlISTJSfiLU ,-, ... ;,- , SPECIAl F1R» ANE*> fXPtOStON* HAZARDS - StatesCOMPONENTS hazards not covered by other sections.

Components are listed in this section if they present a NFPA COOES: Hazard ratings assigned by thephysical or health hazard and are present at or above Fire Protection Association.1% in the mixture. If a component is identified as aCARCINOGEN by NTP. I ARC, or OSHA as of the date SECTION Von the MSDS, it will be listed and footnoted in this HEALTH HAZARD DATA

ffiX ai ^ «*£ ISST1 «£>« «•*• "» *•*"•sported. Additional health information may be found in THRESHOLD UIMIT VALlfe For productSection V. Components subject to the reporting EFFECTS Of ACUTE OVEREXPOSURE: Potential 'ocalrequirements of Section 313 of SARA Title ill are and systemic effects :-» :2 single or short termidentified m the footnotes in this section, along with overexposure to the eyes **a s*-n or through >nnaU»ontypical percentages. Other components may be listed if or mgestion.deemed appropriate.

__ -«_ EFFECTS OP CHRONIC OVER1XPOSURI: Potential localExposure recommendations are far component*. OSHA ^ mttm,e ,ffteu &„ <a repeated or long termPermissible) Exposure Limits (PfLS) and American Overe*posure to the eyes and skm or throughConference of Governmental Industrial Hvgienists -. ,na««tion.(ACGIH) Threshold Limit Values (TLVs) appear on the- yline with the component identification Other FIRST AlOt Procedures to be followed whenrtcommendstions appear as footnote*. with accidental overexposure.

SECTION III • PRIMANV ROUTE Of ENTRY: Based on oropert as «viPHYSICAL DATA expected usa

BOILING POINT: Of product if known. The lowest . F " -vaiue of the components is listed for mixtures. nirtCTlVITT PATA.«. ......... ^ , «. _ HAZARDOUS POUYMERIZATlONb Conditions to *vo-<l toVAPOR PRESSURE Of product if known. The highest prevent hazardous polymerization resulting ,n a «rge

value of the components is listed for mixtures. -<nase of energy.SPECIFIC VAPOR DENSITY: Compared to AIR * 1. If STASNJT* Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known. violent decomposition.the value is expressed as lighter or greater than air. . « ..«—— - _~. . .. ^ ^,.„.„...— -,.\.., /. ^ ,»,.«. , ,. INCOM ATJSIUTYi Materials and conditions to **«•« toSPECIFIC GRAVITY: Compared to WATER * 1. If prevent hazardous reactions.Specific Gravity of product is not known, the value isexpressed as less than or greater than water. SECTION VIIpKfc If applicable , SPILL OR LEAK PROCEDURESPERCENT VOLATlUESe Percentage) of material with „ __ ^.mtiai boiling point below 428 degrees Fahrenheit and "•****• o *""** » "• ^ «« m€tt V.°vapor pressure above a 1mm Kg * 63 R cont wem clean-up and disposal Consult 'ederiiEIT.» .,.«MU .... , :. . **** ** loe** regulauons for accepted proceduree jneEVAPORATION RATt Indicated as faster or slower w rsoonmg or notification requirements.than ETHYL ETHER, unless otherwise stated

SECTION IV SECTION VIIIF.R« J EXPLOSION DATA PROTECTS EQUIPMENT TO » USEO

PO.NT: Method id t,fi«tEXPtOSION LIMITS: For product if known. The lowsetvalue of the components is listed for mixtures. SECTION IX,HAZARDOUS DECOMPOSITION PRODUCTS: Known or SPf OAC PRECAUTIONS OR OTHER COMMCHTSexpected hazardous products resulting from heating, Co,wf r ant point* not previously memiore*burning or other reactions.

ADDITIONAL COMMOfTSContainers should be either reconditioned by CERTIFIED firms or arooenv atoosed of by APPflOVEO firms. 0<soo«ji a»containers should be >n accordance with applicable laws an« •• uiaaone. •EMPTY* drums should not be 9w«n 'aindividuals. Serious accidents have resulted from the misuse ot '€MPTl€O* eontawiers (drums.pails.etcJ. Refer to

AROOOIUO

COLUMBUs!°OHl5l?321d 1 (800)'$1-5263 «DATA SHEET * B _______(614) 889-3333______ 1(800) ASHLAND "

000014 . TECTYL 127 CGW Pag«:TWS MSOS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD)

Product Nonot TECTVL 127 COM

.8WJO. COMPANYOS 90 HO 3091603-591

Tr B t L. — ». — . — --ATTN: CHARLES PAVNE3159 W. 8IQ BEAVER ROAD PRODUCT:— , MI 48084 INVOICE: REQST

INVOICE

Data Shoot Not 0027599-004Pr«por*ds 10/11/90Suporsodoat 09/31/89

DATE: 11/08/90TOj

ON i - P R O D U C T l o t ^ ^ r l F l C A r l o ^ 4Gonoral or Gonorte- 10* PETROLEUM- SAMD. RUST PREVEHTATIVEDOT Hazard C10*a1Hcat1oni COMBUSTIBLE (173.119)

S E C T I O N

THE COMPOSITTOM OP THIS PRODUCT IS BEING WITHCU) AS A TRADE SECRET.

If PRESENT, ZAAC. NTP ANO OSHA CARCINOGENS AMD CHEMICALS SUBJECT TO TI N G REQUIRE « * T f l , I JJIffl I M THXS

tNGRCDIEKT % (by *T)' PIEL TLV N«tcALUMIMJB , 10-19 10 «yiO 10 MB/MS ( D

CAS *» 7429-90-5

COMPLEX ALUMINUM SILICATESCAS *: 1327-43-1

1-10 <9 MG/M3 10 MS/M3 ( 2)

ORGANIC SALT . •', 1-1Q ( 3). CAS »: 68909-29-4

ALIPHATIC HVOROCARBOHS (STOODARO TYPE) 40-99 100 PPM 100 PPM ( 4)CAS ft 8092-41-3

( 1) THIS CHEMICAL IS SUBJECT TO THE REPORTING REOUIREMBtTS OF SECTION 313 OP SARA TITLE III.( 2) PEUTLV NOT ESTABLISHED FOR THIS MATERIAL

PEL ANO TLV ARE FOR TOTAL NUISANCE PARTICULATES.THIS INGREDIENT IS NOT EXPECTED TQ BECOME AIRBORM AMD PRESENT A HAZARD UNDER NORM**. CONDITIONS OP USE OU9

( 3) PEL/TLV NOT ESTABLISHED FOR THIS MATERIALPEUTLV IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT (STEL) FOR OIL MIST IS 10 MS/CUM).

( 4) MIOSH RECOMMENDS A LIMIT OP 390 MB/CUM - 8 HOUR TIME •HOffW AVERAGE. 1800 MO/CUM AS OETBWNeD 8V A '9MINUTE SAMPLE.

I I I r - ' i r S I C A L UA[A

Boiling Point for COMPONENT! 40-95%) 334.00 OM P(

vapor ProMur* for COMPONEMTf 40-95%)___ ^ ___________________________________________________._______ OB.UU umm

vapor oanaity ____________________________________ HEAVIER THMI AIRGravity !« WKoTo*. *

Porcant Volatlloa _________________________________________ *0-991Evaporation Rata SLOMHI THAM"Appoaranca ______________^____ --_____-^—-•stato ______________ u;x;aFof»

S E C T I O N IV F I H t A««;> (^''.OSIIJS I •! )• U H M A T I U *4

FLASHPOINT > 100.0 0*fl P ( 37.9 Oof C)EXPLOSIVE LIMIT (LOWEST VALUE OP COMPONENT) LOW* - 1.«

COPYRIGHT 1990 CONTINUED ON PAGI: 2 AROOO'i'lfl

MATB3IAL SAFETYDATASHKT

ASHLAND CHEMICAI/"\O——————24-HOTO———*~"Sntiiiiwy of *ui«M oir. IK -..- EmartanevP.O. BOX 2219 T.l.phSS.

COLUMBUS, OHIO 43216 1(800) 274-5263 or(614) 889-3333 1(800) ASHLAND

000014 _ TECTYL 127 CGW Pag«:U N I V F I H E A N D E X P L O S I O N I N F O H M A T I O N { C o n t i n u e d )

EXTINGUISHING MEDIAt REGULAR FOAM OK CARBON 010X106 OR DRY CHEMICALTOXIC MATERIALS.. CARBON 010X106 AND CARBON MONOXIDE. VARIOUS

*PP*«*TUS WITH A FULL FACEPIECE OPERATED IN THI POSITIVE

ENT AND POSSIESPECIALLY IF SPRAYED INTO CONTAINERS V HOT. BURNING UQUIO.WATER OR FOAM MAY CAUSE FROTHING WHICH CAN M VIOLENT AND POSSI8UY ENDANGER THE LIFE Of THE FIREFIOHTER.. BURNING <"*"*** "• "™s " ** rin.riwi.af.

"*"""* ™ < ™ TRUCKS SKULO BE «**»NFPA COOES t HEALTH- 1 FLAMHMILITY- 2 REACTIVITY- 0

ON tf H t A L T H HA/ARO D A T A

PERMISSIBLE EXPOSURE LEVELi NOT ESTABLISHED FOR PROOUCT. SEE SECTION II.EFFECTS OP ACUTE OVEREXPOSURE:EYES - CAN CAUSE SEVERE IRRITATION.REDNESS. TEARING. BLURRED VISION.SKIN - PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION. OEFATTING. DERMATITIS.BREATHING - EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION. CENTRAL NERVOUS SYSTEM

EFFECTS INCLUDING DIZZINESS. WEAKNESS. FATIGUE. NAUSEA. HEADACHE AND POSSIBLE UNCONSCIOUSNESS. AND EVEN

feii* ^ •FA ™- "• OIMW' ASPIWT:ONFIRST AIOi

CONTAMtNATEO CLOTHINa. LAU««

IF IN EYESt FLUSH WITH LARGE AMOUNTS OP WATER. LIFTING UPPER AMD LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.IF SWALLOWED: 00 NOT INDUCE VOMITING KEEP PERSON WARM. QUIET. AND GET MEDICAL ATTENTION. ASPIRATION OP MATERIAL

INTOTHE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.IF BREATHEDt IF AFFECTED. REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN. IP

BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM. QUIET AND GET MEDICAL ATTENTION.

PRIMARY ROUTE(S) OP ENTRYtINHALATION. SKIN CONTACT

EFFECTS OP CHRONIC OVEREXPOSUREiHAS BEEN SUGGESTED AS A CAUSt -OP THI FOLLOW NO EFFECTS IN

HUMANSI.V I R f c A C r i V I f Y :)ATA

HAZARDOUS POLYMERIZATIONt CANNOT OCCURSTABILITY: STABLtINCOMPATIIXUTVi AVOID CONTACT WITHt. STRONB OXIDIZING AOWTS.

S t C M U N Ull f, P I L UH I ' A H

STEPS TO BE TAKEN IN CASt MATERIAL IS RELEASED OR SPILLEOiSMALL SPIU: ABSORB UQUIO ON PAPER, VEMOCUUTI. FLOOR HSORBMjrT. OR OTHER HSOnECIT MATERIAL AND TRANSFER TO

HOOD.PILOT L, .|LECrRICAL g

SPMEAOII4. PUM» LIQUID TQ SALVAGE TANK. REMAINING————— . OR OTHER H50RBBIT MATERIAL. AND SHOVELCO INTO

WATER. IP RUN-OPP OCCURS. NOTIFY PROPER AUTHORITIES

WASTE DISPOSAL METHODiSMALL fflUi ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW SUFFICIENT TTMJ FOR VAPORS TO COMPLETELY CLEAR

HOOD DUCT WORK. DISPOSE OP REMAINING MATERIAL IN ACCORDANCE WITH AmtCABUl REGULATIONS.DISPOSE OP IN ACCORDANCE WITH AU. LOCAL. STATE AND FEDERAL RCOUUTtOM.

LARGE SPILLs DESTROY BY LIQUID INCINERATION.DISPOSE OP IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAt. •taULATTONS.

AROOOU2COPYRIGHT 1990 COMTIMU1D OH PAGE: 3

ASHLANI*Srtf.4i»rP.O.

DATA SHEET \ «MMMMMMT » (614)

000014 TICTYL 127 CGW Pag«: 3ro at usto

RESPIRATORY PRQTBCnONt IP WORKPLACE EXPOSURE LIMXT(S) OP PRODUCT OR ANY COMPONENT IS EXCEEDED (SEi SECTION II).A NWSH/M9* APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAC CONTROL. OSHAREGULATIONS ALSO PERMIT OTHER NIOSWMSHA RESPIRATORS (NEGATIVE PRESSURE TVPE) UNDER SPECIFIED CONDITIONS(SEi VOURSMETV EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD 86 IMPLEMENTED TOREDUCE EXPOSURE.

VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL ANO/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE KLOMTLVtS).

PPOTECTTVE GLOVES: WEAR RESISTANT GLOVES SUCH ASi. NEOPRENB. NITRILE mj8BWEVE PROTECTION: CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS ARE AOVISEO: HOMEVSI. OSHA

REGULATIONS ALSO PERMIT OTHEl TYPi SAFETY GLASSES. (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER)OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. WEAR IMPERVIOUS CLOTHING AMD BOOTS.

ON I X i S P t C I A L PHE C AU F I O N S OH O T H E R CO MIME M F S

CONTAINERS OF THIS MATERIAL MAV M HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES(VAPOR. LIQUID. ANO/OR SOLID}. "" '—— —— ——- —— — ~~- ——-—— --— — —ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST K OBSERVED.THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO 86 ACCURATE BUT IS NOT WARRANTED TO SE WHETHER ORIGINATING,

WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TQ CONFIPJI IN ADVANCE OP NEED THAT THE INFORMATION ISCURRENT. APPLICABLE. AND SUITABLE TO THEIR CIRCUMSTANCES.

S E C T I O N X L A B E L I N F O H M A U O N

CAUTIONfCOMBUSTIBLE LIQUID AND VAPOftMAY CAUSE EYE AND SKIN IRRITATION.INHALATION OP VAPOR MAV CAUSE IRRITATION OP NASAL ANQ RESPIRATORY PASSAGES. !SWALLOWING MAV CAUSE IRRITATION Of MOUTH. ESOPHAGUS. AND GASTROINTESTINAL SYSTEM AND MAV K FATAL.

HANDLING & STORAGEt 'KEEP AWAY FROM HEAT AND OPEN FLAME. USE OR STORE ONLY WI1M ADEQUATE VENTILATION. MAINTAIN AMBIENT A|»CONCENTRATION'S} BELOW-PERMISSIBLE EXPOSURE LIMITS. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATflBCONTACT WITH SKIN. WEAR SAFETY GLASSES OR GOGGLEj. RESISTANT GLOVES. AND OTHER APPROPRIATE PROTECTIVEEQUIPMENT ESSENTIAL FOR YOUR OPERATpT MINIMIZE EXPOSURE THROUO4G&XI HYGIENIC PRACTICES. 00 NOTTRANSFER TO UNLABELED CONTAINER. 00 NOT USE CUTTTNQ OR WELDING/TORCH ON THIS CONTAINER (EVEN £MPtV). FORINDUSTRIAL USE ONLY 24-HOUR EMERGENCY NUMBER 1-900-Al

FIRST AIDtEYESt FLUSH THOROUGHLY WITH MATER. GET MEDICAL ATTENTION IMMEDIATELY.SKINt WASH THOROUGHLY WITH SOAR AND MATER.INHALATION. IF AFFECTED, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION.INGESTIONt 00 NOT INDUCT VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ASPIRATION *UAAS>IP SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. NEVER GIVE ANVTHIM BY MOUTH TO AN UNCONSCIOUS PCRSOM.

CHRONIC INFORMATION!CONTAINS» PETROLEUM DISTILLATES. CONTAINS MATERIAL(S) WHICH MAV CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.

••• COMPONENTI APPEAR IH SECTION II •••

COPYRIGHT 1990 LAST PAGE—SKI ATTACHXWT PACK ENCLOSED—LAST PAGE; RROOOU3

ASHLANT> CHEMICAf^NC.—————24-HOUR———~s«»ii«ncy * »«*«•* om i«te— Emergency

MATERIAL SAFETY /iSII/s?l?lF P.O. BOX 2219 Telephon*DATA SHEET E i E* COLUMBUS, OHIO 43216 1(800) 274-5263 orDATAbr«ei r E» E»VT (6U) 339.3333 t (800)

DEFINITIONSThis definition page is intended for us* with Material Safety Data Sheets supplied by the Ashland Chemical Company.Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularlysubpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, forgeneral guidance on control of potential Occupational Health and Safety Hazards;

SECTION I SECTION IV (cent)PRODUCT IDENTIFICATION ewiuMn«u»u» »*««•* = ,, ., .. .,— y T|T —————— s ——— * EXTINGUISHING MEDIA: Following National Fire

GENERAL OB GENERIC 10: Chemical family or product Protection Association criteria,description. F1REFIGHTING PROCEDURES: Minimum- equipment to

ssxisfXF™0" Product m"" OOTfor hazaras listed. firefighting hazards may also be indicated. ,/SECTION II SPECIAL FIR! AND EXPLOSION HAZARDS: StatesCOMPONENTS hazards not covered by other sections.

Components are listed in this section if they present a NFPA COOES: Hazard ratings assigned by the Nationalphysical or health hazard and are present at or above Fire Protection Association.1% in the mixture. If a component is identified as aCARCINOGEN by NTP, lAflC. or OSHA as of the date SECTION Von the MSOS. it will be listed and footnoted in this HEALTH HAZARD DATAsection when present at or above 0.1% in the product PERMISSIBLE EXPOSUHt LIMIT: For productNegative conclusions concerning carcmogenicity are not ruae.n . « ...*.* ,/*..«. r .reported. Additional health information may be found in THRESHOLD LIMIT VALUE: For productSection V. Components subject to the reporting EFFECTS OP ACUTE OVEREXPOSURC: Potential localrequirements of Section 313 of SARA Title III are and svstermc effects due to single or short termidentified m the footnotes in this section, along with overexposure to the eyes and skin or through inhalationtypical percentages. Other components may be listed if or mgesuon.deemed approbate. EFFECTS OP CHRONIC OVEHlXPOSURt Potential localExposure recommendations are for components, OSHA ^ mttnwe ., f-ea *„ tO repeated or long termPerm.ss.bl* Exposure Limits (PELS and American overexpose* to th* eves and skin or through .mutationConference of Governmental Industrial Hygiemsts -, tfiaamt.an,(ACGIH) Threshold Limit Values (TLVs) appear on th* •*•»«-line with the component identification. Other FIRST AlOs Procedures to be followed when da«mgrecommendations appear as footnotes. with accidental overexposure.

SECTION lit. • PRIMARY ROUT! OP ENTRY: iased on properties andPHYSICAL DATA expected us*

BOILING POINT: Of product if known. Th* lowest M T V*,value of the components is listed for mixtures. REACTIVITY QATA

««. ..«.,»». *. -n. u--^ HAZARDOUS POLYMERIZATIONS Conditions to avoid toVAPOR PRESSURE: Of product if known. Th* highest prevent hazardous polymerization resulting in a >vgevalue of the components is listed for mixtures. t re<eas* of energy.SPECIFIC VAPOR DENSITY: Compared to AIR - 1. If STAMJTVi Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known. violent decomposition.the value is expressed as lighter or greater than air. ,.-..«.— ._._ .......«...« ~.,..,«~. ,. - ,.,A«i. , . iNCOMfUTItlUTV! Materials and conditions to avoid toSPECIFIC GRAVITY: Compared to WATER » 1. if prevent naivdous reactions,Specific Gravity of product is not known th* valu* isexpressed as less dun or greater than water. SECTION Vliprt If applicable. SPttL OH LEAK PROCEDURESPERCENT VOLATILE* Percentage of material with . _ înitial boiling point betow 428 degrees Fahrenheit and a«"***r precautions to be taken and '"•'hods ofvapor pressure above 0.1mm Hg at 63 P. cowawment den-up md disposal. Consult federalTT. »«...««« ..*. . -u L. , «•*• •"* loe** regulations for accepted procedures «*»EVAPORATIOM RATt- Indicated M feitir or slower „ raoowg or notificaaon requirements.than ETHYL ETHER, unless otherwise stated.

SECTION VIII

F.R. A N O p N DATA PROTECT". ™»«« T° "n . ».. ... .. . .. .. .. *»o«eetiv* equipment which may be neededFLASH POINT: Method identified. -j-a_ni m* productEXPLOSION LIMITS: For product if known. Th* lowset Sfl ,nvalue of the components is listed for mixtures. • SECTION IXHAZARDOUS DECOMPOSITION PRODUCTS: Known or SPECIAL PMCAUTtONS OH OTHEH COMMENTSexpected hazardous products resulting from heating. £<*** •* relevant points not previously mentioned.burning or other reactions.

ADDITIONAL COMMENTSContainers should be either reconditioned by CERTIFIED firms or oroeeriv disposed of by APPROVED firms. Disposal o'containers should be in accordance with applicable laws an*) 'eejuuMne, "EMPTY* drums should not be given -3individuals. Serious accidents have resulted from th* misus* of 'EVpT.fflr contaners (drums.pails.etcl Refer to SectionsIV and IX

ASHLAND '"T«M*-i~ • - "^ -- — —- "" *".

MATERIAL SAFETY •——•—»»- COlS»Ol!°«IM 43216DATA SHEET "^M^^%_______ (614) 889-3331______1(800) ASHLANP

000019 TECTYL 121 B Page:THIS MSOS COMPLIES WITH 29 Oft 1910.1200 (THI HAZARD COMMUNICATION STANDARD*

Product N«MS TECTYL 121 B

09 90 110 8091603-59>ATTN: CHARLES PA WE3155 W. BIG BEAVER ROADTROY, MI 48084 ,...„„. .__.

INVOICE DATE: 11/09/90TO:

SuprswttSt 07/29/8

General or Q«n«r1e IDi PETROLEUM BASS) RUST PReVENTATiveDOT Huwtt ClaMlf 1C»t10lt» COMBUSTIBLE (173.115)

U N I I COMf'ONt>*[!v

THE COMPOSITION Of THIS PRODUCT IS WING WITHHELD AS A TRADE SECRET.if Pflesarr. lAftc. NTP AMD OSHA CARCINOGENS ANO OBHCALS SUBJECT TOING REQUIRE. C* SAW

INGREDIBfT % (by NT) PEL TVf Not*ASPHM.T 10-29 S MB/IO (I)

CAS *t 64742-93-4

POTASSIUM IRON MAGNESIUM ALUMINOSIUCATE 10-29 '5 M5/M9 10 MB/M9 ( 2)CAS »t 1318-94-1

' (3,

ALIPHATTC HVDROCARBONSCAS *i «092-41-3

(STOOOARO TVP«) 2S-40 1QO PMT 100 PP» (9)'

NOtMt( t) AS FUMES

PEL NOT ESTABLISHED FOR THIS MATERIAL.( 2) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL

PEL AND TLV ARK FOR TOTAL NUISANCE PARTICULATES.THIS INGREDIENT IS NOT EXPECTED TOMCOMI AIRMAN! AM PRESENT A HAZARD UNDER NORMAL CONDITIONS OP USI OUCTO THE PHYSICAL FORM OP THE PRODUCT.

( 3) PEUTLV NOT ESTABLISHED FOR THIS MATERIALPEL AND TLV ARC FOR TOTAL NUISAMCt PARTICULATES.THIS INgJ£DXgfl' I£JjPT EffigCTiBOTIBaiflOMl AIREORNt AND PHSSCNT A HAZARD UNDER NORMAL CONDITIONS OF USE OU9

( 4) PEL/TLV NOT ESTABUSHEO FOR THIS MATERIALPEL7TLV IS FOR OIL MIST. ACBXH SHORT TERM EXPOSURt UIM1T (JTEL) FOR OIL MIST IS 10 MO/CUM.

( 9) NIOSH RECpjiEgBS * LIMIT OP 390 MB/CUM) - 9 HOUR TIM MIOMTEO AVCRAGf. 1100 MO/CUM AS DETERMINED BV A '»

•< r •; i c A L D A T ABo1Hn« Point for COMPONtMrC 29-4Qft) 334.0 OM

; 9 7«o.'oo •• >far COMPONCNT( 29-40»> , .

0«r«1ty•y

HEAVIER

*< *

5 oJJoTHM *!•

55 0«« Ci

Volat11««Rat* SLQiRgi

' ' ^

COPYRIGHT 1990 COMTIWUIO ON PAGIt 2flRQQQ j g


ASHLAND CHEMICAL-INC24-HOOTT————s"*»*;r afa%i"tW<FT EmergencyP.O. BOX 2219 -- Telephone

COLUMBUS, OHIO 43216 1(800) 274-5263 or(614) 889-3333 __1(800) ASHLAND

000019 TECTYL 121 B P«g,:DA r A I Cu n I

State _________________________________________________________LIQUIDFom HETER SOLN

O N I V f l H E A N D E X P L O S I O N I N F O H M A T I O N

FLASH POINT(PMCC ) > '00.0 Oeo P ( 37.8 CWg C)EXPLOSIVt LIMIT— (LOWEST VALUE OP COMPONENT) LONM — -* 1.01V CPPtH - B.0»EXTINGUISHING MEDIA: REGULAR FOAM OM CARBON DIOXIDE OR DRY CHEMICALHAZARDOUS OECOMPOSITigN PRODUCTS « MAY FORM TOXIC MATERIALS:. CARBON OIOXIOE AND CARBON MONOXIDE. VARIOUS

FIREPIGHTING PRQCEDURE^WEARSELP-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE

SPECIAL FIRE I EXPLOSION HAZARDS: NEVER USE WELDING OR .CUTTINO TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSEPRODUCT (E

.(EVEN JUST RESIDUE) CAW IGNITE EXPLOSIVELY.

•TA.R CARS AND TAN« TRUCKS «ULD BE GROUNDED

NFPA COOES: HEALTH- I FLA»*»8ILITY- 2 REACTIVITY- 0ON V H E A L T H HAZARD DATA

PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II.EFFECTS OP ACUTE OVEREXPOSURE:

38 : pMf§ ^ ^ ^ pos CS rT ^ MrT; oER nns.^ - îl.0.!^^ rsEAo A Posto"c g tS S Wl'ZSk S -FATS™- *"Oltm**- AS*IIwnc" * ""«*•INTO

FIRST AIDt

IF IN EYESs FLUSH WITH LARGE AMOUNTS* OP WATER. LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.IF SWALLOWED: 00 NOT INDUCE VOMITING. KEEP PERSON WARM. QUIET. AMD GET MEDICAL ATTENTION. ASPIRATION OP MATERIAL

INTO THE LUNGS DUE TOVOMITING CAN CAUSE CHEMICAL PNEUMONtTIS WHICH CAN BE FATAL.IF BREATHED: IP AFFECTED. REMOVE INDIVIDUAL TOFRESH AIR. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN. IP

BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM. QUIET- AND GET MEDICAL ATTENTfON.


EFFECTS OP CHRONIC OVEREXPOSURIf

i t C M U N V I H t A C r i U I I Y .JATA

HAZARDOUS POLVMSIIZATXONr CANNOT OCCU*STABILITY: STABUINCOMPATISlLITYj AVOID CONTACT «THt, STRONft OXIOIZINft AGJKTJ.

, ( C I I O N

STEPS TO Bt TAKW IN CASi MATCRIAX IS RBJUSB 01 9ILUDtSMMXVOLt ABSORB) LIQUID ON PAPER, VERMXCUUT8. FLOOR ABSORBBBT. 01 QTHtl HiORBBrT MATBWA4. AND TMNSKM TO

LARGE SPILL: ELIMINATE ALL IGNITION SOURCES {FLARES, FLAMES INCLUOIM PILOT LIQHTS. ELECTRICAL SPARKS). PERSON*-^ RING PHOTKTIve E(XIPMBfrS<5ULD SEEXttUOEO FROB MCA 7 SPILL UNTIL CLCAM-Uf S3 BEoTcOIIPlETeDr

ILL AT SOURCE. DIKE AREA OP SPILL TO PREVENT SP«€AOI»*. <XJ» LIQUID TQ SALVAGB TANK. REMAININQJAV Bt TAKEN UP ON SAND. CLAY. EARTH. FLOOR ABSQRMMT. 01 OTHBI HiORBUIT MATERIAL AND SHOVfUS INTO

COPYRIGHT 1990 CONTINUIO ON PACK 3

MATERIAL SAFETYDATA SHEET _______(614) 889-333* (865)

ocooif TECTYL 121 B Pag«s, F, c r i a N vit

VMSTfi DISPOSAL MTHOOrSMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW SUFFICIENT TIM1 KM VAPORS TO COMPLETELY

HOOD DUCT WORK. DISPOSE OF REMAINING MATERIAL IN ACCORDANCE WITH APPLICABLE REGULATIONS. """"•* "•DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.— * • ~.z:?f —•» ."*-4>i . 2 _;

LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL REGULATIONS.VE E Q U I P M E N T TO BE USED

RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION II).A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. 0SNAREGULATIONS ALSO ?ERMIT_OTJHER..NIOSWI«SHA RESPIRATORS T TIJS.PRESSUReTVPE) UNDER SPECIF I ED CONDITIONS..lSEEJrtXR._SAfETY EQUIPMENT SUPPLIER). ENGINEERING OR AOMINI STRATI VECOMTHOLS SHOULD BE IMPWMENTEO TORcREDUCE EXPOSURE.

VENTILATIONi PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE SELOWTLV(S). :

PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NEOPRENE. NITRILE RUBflER

*• WLTT s bSr ff r i i* ErTGiA ?IIc Nl2T( c 2F ~«OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. «EAR IMPERVIOUS CLOTHING AND BOOTS.

S E C T I ON I X - S P E C I A L P H f c C A U M Q H S OH O T H E R COMMENTS

CONTAINERS OF THIS MATERIAL MAV BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES(VAPOR. LIQUID. AND/ON SOLID). ALL HAZARD PRECAUTION* GIVEN IN THIS DATASHEET MUST M OBSERVED. •

THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO M ACCURATE BUT IS NOT WARRANTED TQ BE WCTHER ORIGINAHNQi

-tt-a-fflHPl*"""" * "" ™*T ™ INf0l TIflM I$L A H k L I IF O H M A T I ON

CAUTION! .'.-COMBUSTIBLE LIQUID AMD VAPOR . -MAV CAUSE EVE AND SKIN IRRITATION.INHALATION OF VAPOR MAV CAUSE IRRITATION OF NASAL AMD RESPIRATORY PASSAGES.SWALLOWING MAV CAUSE IRRITATION OF MOUTH. ESOPHAGUS. AND GASTROINTESTINAL. SYSTEM AND WtV M. FATAL.

HANDLING ft STORAGE* :'• ; ' .KEEP AWAY FROM HEAT AND OPEN FLAME. USE OR STORE ONLY WITH ADEQUATE VENTILATION. MAINTAIN AMIENT AIRCONCENTRATION(S) BELOW PERMISSIBLE EXKSURE LIMITS. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATEDCONTACT WITH SKIN. WEAR SAFETY GLA!5ES OR GOGGLES. RESISTANT <*Q*3i*"O OTHER APPROPRIATE PROTECTIVEEQUIPMENT ESSENTIAL FOR YOUR OPERATION^ MINIMia E POSM l lSSK OO HYGIENIC PRACTICES. 00 NOT.._„..._.. __....._._. ....._-_-.._ ON. MINIMIZJ_ EXPOSURE THWUGM GOOD HYGIENIC PRACTICES, oo NOTTRANSFER TO UNLABELED CONTAINER. 00 NOT l^d^NOORWEUIMaTORCH ON THIS CONTAINER (EVEN EMPTY).INDUSTRIAL USEONLY 24-HOUR EMERGENCY NUMBER 1-400-ASttUMO.

FIRST AID:EYESt FLUSH THOROUGHLY WITH WATER. GET MEDICAL ATTENTION INNBSATELV.SKIN: WASH THOROUGHLY WITH SOAP AMD WATER.INHALATIONt IF AFFECTED. REMOVE. TO FRESH AIR. IF BREATMIMt IS DIFFICULT. GET tCOICAL ATTENTION.INGESTION: 00 NOT INDUCt VOCTINa. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMBDIATELY. ASPIRATION HAZARD

IF SWALLOWED. CAN ENTER LUNGS AMD CAUSE DAMAGi. NEVER GiVE ANYTHIN» BY MOUTH TO AN UNCONSCIOUS PERSON.CHRONIC INFORMATIONrCONTAINS* PETROLEUM DISTILLATES. CONTAINS MATERIAL,! S> *HCH MAV CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.

*•• COMPONENTS APPEAR IM SECTION IS •••

COPYRIGHT 1990 LAST PAGE—SIS ATTACaCSMT PAGS INCLOSED--LAST PAGE


ASHLAND CHEMICAL. INC 24-HOUlf•* AIMM oir. i«e. Emergency

P.O. BOX 2219" TelephoneCOLUMBUS, OHIO 43216 1(800) 274-5263 or

(614) 889-3333 1(800) ASHLAND

DEFINITIONSThis definition pig* i* intended for use with Material Safety Data Sheets supplied by the Ashland Chemical Company.Recipients of these data-sheets should consult the OSHA Safety and Health Standards (29 CFR 1910). particularlysubpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment forgeneral guidance on control of potential Occupational Health and Safety Hazards.

SECTION I SECTION IV (eontjPRODUCT IDENTIFICATION ev-rnu/M H«UIM« U«M. e „— VTyj! ———— • —— s — — =~* EXTINGUISHING MIOIAt Following National Fire

GENERAL OB GENERIC IDc Chemical family or product Protection Association criteriadescription. FIREFIGHTINO PROCEDURES: Minimum equipment to

ffiZSfSff™" Product m"u DOTfor hazards listed. firtf.ght.ng hazards may also be .ndicated.SECTIC-N U SPECIAL FIR* AND EXPLOSION HAZARDS: States

COMPONENTS hazards not covered by other sections.Components are listed in this section if they present a NFPA COOES: Hazard ratings assigned by the Nationalphysical or health hazard and are present at or above Fire Protection Association.1% in the mixture. If a' component is identified as aCARCINOGEN by NTP. (ARC or OSHA as of the date SICTIQfl, Yon the MSOS. it will be listed and footnoted in this HEALTH HA2ARO OATAsection when present at or above 0.1% in the product PCMMISSItU EXPOSUR* LIMIT: For productNegative conclusion* concerning carcinogeroaty are not _,-..„-... , ,...-, .,...-. - ^reported. Additional health information may be found in THRESHOLD LIMIT VALUft For productSection V. Components subject to the reporting EFFECTS Of ACUTI OVEREXPOSURE: Potential localrequirements of Section 313 of SARA Title ill are and systemic effects due) to single or short termidentified m the footnotes m this section, along with overexposure to the eyes and skin or through inhalationtypical percentages. Other components may be listed if or mgestion.deem appropriate. EFFECTS OF CHRONIC OVEREXPOSURf: Potential localExposure recommendations are far components. OSHA ^ system* effects du« to repeated or long termPermissible Exposure Limits (PELS) and American overexposure to the eyes and skin or through mr.aiat.onConference of Governmental industrial Hygienists g, .ngestion.(ACGIH) Threshold Limit Values (TLVs) appear on theline with the component identification, Other FIRST AID: Procedures to be followed when daaungrecommendations appear as footnotes. with accidental overexposure.

SECTION III' ' PRIMARY ROUT! OP ENTRY: Based on properties andPHYSICAL DATA expected use.

SOILING POINT: Of product if known. Th« lowest . SS T?..value of the components is listed for mixtures. REAgnViT3LBAI4,.„„. „»«..««. «. ^ •• ,. -n. — HAZAROOtW POtYMWMZATIOI* Conditions to avoid toVAPO* PRESSUM: Of product .f knowa The highest p, ^ haijrdeus polyrrferization resulting .n a >argevalue of the components is listed for mixtures). raieasa) of energy.SPECIFIC VAPOR DENSITY: Compared to AIR » 1. If STAWUT* Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known. violent decompositionthe value is expressed as lighter or greater than a*. . _. ._ .-._.. _ „„-,....- --J „_„ - _ ,.,.,« . ,« iNCOMTATItlUTY! Materials and conditions to avoid toSPECIFIC GRAVITY: Compared to WATER * 1. If prevent nasardou* reactions.Specific Gravity of product is not known. th« value) isexpressed as less than or greater than water. SECTION VIIpH: If applicable; SPILL Oft L.E/JJ PROCEDURESPERCENT VOLATILE* Percentage) or materiel with _ _initial boiling point below 425 degree* Fahrenheit and «eaeonae«e) precautions to »• taken ana memoes o»

above) a Irnm Hflat68 P eonuwwnem. dean-uo and disposal Consult »»<Jera».st*« «* '««* 'ifluKiont for accepted procedures md

F.R. A N DATA PROTECTS EOU.PMENT TO n USEDa .«u BAIUVL .< i. -i «•„. P»o«ectivei equipment which may be neededFLASH POINT: Method identified. far***)*; me) productEXPLOSION LIMITS: For product if known. The> lowset -«,*««•.value of ttie components is listed for mixtures. SECTION IXHAZARDOUS DECOMPOSITION PRODUCT* K —— , or SPECIAL PRICAUTIONS OH OTHCT COMMENTSexpected hazardous products resulting from heating. <.„,„, ,„„,„, powtt „«,, previously mentionedburning or other reactions*

ADDITIONAL COMMOCTSContainers should be either reconditioned by CERTIFIED firms or orooeny disposed of by APPROVED firms. Disposal a*containers should oe m accordance with applicable laws ana • equations.. 'EMPTY* drums should not oe givan -9individuals. Senous accidents have resulted from the msuse of 'EMPTieor contawers (drums.paMs.eteX Refer to Sect'ori1Vjndlx • . AROOOI-rB

ASHLANU CHEf1* tAU. INCl 24-* U^'


4 s.»,Mi«y wi.*i.w_\shlantt P.O. BOX 2219COLUMBUS, OHIO 43216 1 (800> 274-5263 or

(614) 889-3333 _______ 1 (800) ASHLAND

000010 TECTYL 175-GW-BASB (OORO) Pag«:THIS MSOS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD*

Product N«MI TECTYL 17S-GW-BASE (OORO)

•me BUOO COMPANY OS 90 110 8091603-591ATTN; CHARLES PAYNE3155 W. BIG BEAVER ROAD PRODUCT*TROY, MI 44084 INVOICH: REQST

" iTH: 1

Data Sheet Not 0232518-001Pr«par«dt 07/20/89Superaedeax ( N/A )

INVOICH DATE: 11/08/90T0«

G«c«ni1 or G«n«Hc IDs PETROLEUM BASS) RUST PREVCNTATIveDOT Huard ClMSlflcatlont COMBUSriBLB (173.115)

I - P R O D U C T I D E N T I F I C A T I O N

ON I I - C O M P O N E N T S

THE COMPOSITION OP THIS PRODUCT IS BEING WITHHELD AS A TRADE SECRET.IF PRESENT. IARC, NTP AND OSHA CARCINOGENS AMD CHING REQUIRBWrrs C* SARA TITLE III SECTION 313 ARL ._.... .

SEE DEFINITION PAGE FOR CLARIFICATIONINGREDIENT % (by WT) PEL TLV Not,

*: 1302-78-9

ALIPHATIC HVDROCAPflONS (STQOOAPO TVP8) 40-5S 100 PPM 100 PP» ( 3)CAS *: 3092-41-3 '- '

NotMl( 1) PEUTLV NOT ESTABLISHED FOR THIS MATERIAL

PEL AND TLV ARE FOR. TOTAL NUISANCE PARTICULATES.THIS NGR60IiNT I E E E O i B e C O M i AIRBORNE AND PRESEHT A HAZARD UNDER NORNM. CONDITIONS 0* USE Ob*

( 2) PEL/TLV NOT ESTABLISHED FOR THIS MATERIALPEL/TLV IS FOR OIL MIST. ACGXH SHORT TERN EXPOSUM LIMIT (STEL) FOR OIL MIST IS 10 MO/OJI.

( 3) NIOSH RECCMMBOS A LIMIT OP 350 MB/CUM - • HOU* TIHf LIGHTED AVERAGE. 1800 Mfi/CUM AS DETERMINED ft A 19MINUTE SAMPLE* „ *

5. t C F I O M III > * > « Y S I C A L D A T A

Sol Hnfl Point for CCMPONENT( 40-551) 300.00 CX* F____ ______________ • laiiarvapor Pr«t«ur« for CCMPONCNT( 40-55%) : "" 2.00 •• »•

____ _________ . _________ fc 8:8 a1»Specific vapor Density ____________________________________________ HEAVIERSpecific Gravity " """"" ~""TvPercent Volatile* ________________^_________ 4Q-aa%Evaporation Rat* ___________________________________________SLOWER______Appearance NOT SPtCIFIBiState ___'__________ '__________ L:OL:OFone••FLASH POINT(PMCC ) > 100.0 Dog F ( 37.8 0*« C)EXPLOSIVE LIMIT (LOWEST VALUE V COMPONENT) LOME* • ».«EXTINGUISHING MEOIAt REGULAR FOAM OR CARBON DIOXIDE OB OBV CHBWCAt,HAZARDOUS OCCCMPOSITIQN PRODUCTS« M»V FORM TOXIC MkTERIAUi. CAJMBM DIOXIDE AND CARBON MONOXIDE. VARIOUS

HYDROCARBONS. ETC.FIREFIOHTING PROCEDURES I WEAR SelF-COKTAINED aREATHXMB A***MTXS «TH A FULL F.ACEPICCI OPERATED tN THX

COPYRIGHT 1989 CONTINUtO ON PAGIt 2AROOOU9


___ ASHLAND CHEMICAI*-4£!C——————24-HOUFf——i , _ ~~• y s«s?i<i«»y o* AIM*** on, iict Eo^rE^ncy\Snlantf p'°- BOX 2219- - Telephon*

** COLUMBUS, OHIO 43216 1(800) 274-5263(614) 889-3333________1(800) ASHLAND

a

000018 TECTYL 175-GW-BASK (DORD) Pag«:Si CM ON IV F I H f c AND E X P L O S I O N I N F O R M A T I O N I Con I i nuc d I

PRESSURE DEMAND MQOt WrtEN FIGHTING FIRES.WATER OR FOAM MAY CAUSE FROTHING MUCH CAN 9E VIOLENT AND POSSIBLY ENDANGER TV* LIPS OF THE FIREPIGHTE*.ESPECIALLY IF SPRAYED INTO CONTAINERS OP HOT, BURNING LIQUID.

SPECIAL FIRE I EXPLOSION HAZARDS: NEVER USE WELDING OR CUTTING TORCH ON OR NEAR ORUtt (EVEN EMPTY) BECAUSEPRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED 8Y HEAT.PILOT LIGHTS. OTHER FLAMES AND IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING POINT.ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDEDANO/OR BONDED WHEN MATERIAL IS TRANSFERRED.

NFPA CODESi HEALTH- 1 FLAMMAMLITY- 2 REACTIVITY- 0 ,.,I Of* V H t A L I H HAZARD D A T A

PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II.EFFECTS OP ACUTE OVEREXPOSURBiEYES - CAN CAUSE SEVERE IRRITATION, REDNESS. TEARING. BLURRED VISION.SKIN - PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, OEPATTTNG, DERMATITIS.BREATHING - EXCESSIVE INHALAT" " —— ' " " '" "- —— ——' —— " '

~ tr VJwUnuCU UK ncrejv < cu \#un i PW»I w*n unv c t jw** ' c *nn* ' *» i k\/nt wem » i ir**>. ucj UIE* i * i u.HING - EXCESSIVE INHALATION OP VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION.CENTRAL NERVOUS SYSTEMEFFECTS INCLUDING DIZZINESS. WEAKNESS. FATIGUE. NAUSEA. HEAOACHi AND POSSIBLE UNCONSCIOUSNESS. AND EVEN

SWALLOWING*- CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA. VOMITING. AND DIARRHEA. ASPIRATION OP MATERIAL INTOTHE UINGSCAN CAUSE CHEMICAL PNEUMOMTIS WHICH CAN BE FATAL.

FIRST AIOiIF ON SKINj THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER

CONTAMINATED CLOTHING BEFORE RE-USE.IF IN EYESi FLUSH WITH LARGE AMOUNTS OP WATER. LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.IF SWALLOWED: 00 NOT INDUCE VOMITING. KEEP PERSON WARM. QUIET, AMO GET WDICAL ATTENTION. ASPIRATION OP MATERIAL

INTO THE LUNGS DUE TOVOMITING CAN CAUSE CHEMICAL PNEUMQMITIS WHICH CAN Bt FATAL.IF BREATHED: IP AFFECTED. REMOVE INDIVIDUAL TO FRESH AIR. IF BREATH!NO IS DIFFICULT. ADMINISTER OXYGBt, IP

BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM. QUIET AND GET MEDICAL ATTENTION.


EFFECTS OP CHRONIC OVEMXPOSURitEXPOSURE TO THIS MATERIALHUMANSt. CENTRAL NERVOUS

OVEREXPOSURE TOJTHIS. MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A CAUSE OP THE FOLLOWING EFFECTS IN

I ON VI HI AC I I V I I Y

HAZARDOUS POLYMERIZATION! CANNOT OCCURSTABILITY: STAMLftINCOMPATIBILITY: AVOID CONTACT WITHt. STRONG OXIDIZING AGENTS.

S t C I I O N V I I S P I L L O H I I A « . > > M O C t O J H t S

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEOtSMALL SPILL: ABSORB LIQUID ON PAPER. VERMCUUTE. FLOOR IBMIMMHT. OH OTHER ABSORBENT MATERIAL AND TRANSFER TO

HOOD.URGE SPILL: ELIMINATE, ALL IGNITION SOURCES (FLARES. FLAMES INCLUOINt PILOT LIGHTS. ELECTRICAL SPARKS). PERSONS

COMPLETED.LL: ELIMINATE, ALL IGNITION SOURCES (FLARES. FLAMES INCLUOINt PILOT LIGHTS. ELECTRICAL SPARKS). PWEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM *S5 OP SPILL UNTIL CLEAN-UP HAS BEEN COMPLSPILL AT SOURCE. OIKI AREA OP SPILL TO PREVENT SPRCAOINO. 1MB* LIQUID TO SALVAGE TANK. REMAININ

.. . UID TO SALVAGE TANK. REMAINING

UID MAY BE TAKEN UP ON SAND, CLAY. EARTH. FLOOR iBTnMBMT. ON QTHBt ABSORBENT MATERIAL AND SHOVELED INTOTAINERS.

PREVENT RUN-OFF1 TO SEMENS. STREAMS OR OTHBt BODIES OP *AAS REQUIRED. THAT A SPILL HAS OCCURS.

TW. IP ftUN-OFP OCCURS. NOTIFY PROPER AUTHORITIES

WASTE DISPOSAL IBTTHCO,SMALL SPILL: ALLOW. VOLATILE PORTION TO EVAPORATE IN HOOD, ALLOW SWPPICIEttT HMi FOR VAPORS TO COMPLETELY CLEAN

HOOD DUCTWORK. DISPOSE OF REMAINING MATERIAL IN ACCOROAK* Mm AMtlCAAU REGULATIONS.OlSPOSi OP IN ACCORDANCE WITH ALL LOCAL. STATE AMD KDEMfL BMULAnOMS.

LARGE SPILL: DISPOSE OP IN ACCORDANCE WITH ALL LOCAL. STATE AND 'COMMA. REGULATIONS.ON V I I I P R O f f c C r i V t t ' l ) t - W » > « f I U HE USED

RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMITCS) OP PRODUCT OB AMV COMPONENT IS EXCEEDED (SU.SKTION II).A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS AOVtsIoiS UBCMCf OPMOPat ENWR<Me"tALttNTROL. OSHA

ATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NCGArt^MElSUNI TYPE) UNOCR SPECIFIED CONDITIONSVQUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING QM ACM • I JnUn VtOTrnWLS SHOULD M IMPLEMENTED TOCE EXPOSURE.

VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL ANO/OR UXM. IftWWST) VENTILATION TO MAINTAIN EXPOSURE BELOWTLV(S).

COPYRIGHT 1989 CONTINUED OH PAGE: 3 AROOOI50

-,_ --sm , f-

SAFETYDATASHEET

ASHLANff CHfi.

COLUMBUS, OHIO 43215 1(800) 274-526(614) 889-33331(800) ASHLAND

: nCTlL 175-GWrH«.lQQil« ,. *„* -. . Pag«:O N v i i i P H o r t c r i v E E Q U I P M E N T r o H E U S E D i

PROTECTIVE GLOVUt WEAR RESISTANT GLOVES SUCH AS<. NEOPRENE. NITRILE RUBBER

"RfflBHSliWF ^ ' -OTHER PROTECTIVE EQUIPMENTt TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. WEAR IMPERVIOUS CLOTHING ANO BOOTS.

At P R E C A U T I O N S OH O f H t R C QMME NTS

CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES(VAPOR; LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS OATASWET MUST BE OBSERVED.

THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATINGWITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION ISCURRENT. APPLICABLE. ANO SUITABLE TO THEIR CIRCUMSTANCES.

ON X L A B E L I N F O H MA I I O N

CAUTION!COMBUSTIBLE LIQUID AND VAPORMAY CAUSE EVE AND SKIN IRRITATION.INHALATION Of VAPOR MAV CAUSE IRRITATION OP NASAL AM} RESPIRATORY PASSAGES.SWALLOWING MAV CAUSE IRRITATION Of MOUTH, ESOPHAGUS. AND GASTROINTESTINAL SYSTEM AND MAY' BE FATAL.

HANDLING ft STORAGESKEEP AWAY PROM HEAT AND OPEN FLAME. USE OR STORE ONLY WITH ADEQUATE VENTILATION. MAINTAIN AMBIENT AIMCONCEHTlttTION(S) BELOW PERMISSIBLE EXPOSURE LIMITS. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATEDCONTACT WITH SKiNTv«AR SAFETY GLASSES OR GOGGLES. RESISTANT GLOVES .ANO OTHER APPROPRIATE PROTECTIVEEQUIPMENT ESSENTIAL FOR YOUR OPERATION. MINIMIZE EXPOSURE THROUGHGOOO HYGIENIC PRACTICES. 00 NOTTRANSFER TO UNLAECLEO CONTAINER. 00 NOT USE CUTTING OR «CLOINO TORCH ON THIS CONTAINER (EVEN EMPTY). FORINDUSTRIAL USE ONLY 24-HOUR EMBWENCY NUMBER 1-900-ASMJWO.

«RSt AlOt' •.-'; "EYESt PLUSH THOROUGHLY WITH WATER. GET MEDICAL ATTENTION IMMEDIATELY.SKINt WASH THOROUGHLY WITH SOAP ANO WATER.INHALATION« IP AFFECTED, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION.INGESTTONt 00 NOT INOUej? VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ASPIRATION HA&MOItF SW LLoilEO. CAN Jn&LUNGS kND CAUSE DAMAGE. NEVER GIVE ANYTHING BY NOUTHTd AN UNCONSCIOUS PERSON.

CHMNIC INFORMATIONS 'CONTAINS. PETROLEUM DISTILLATES. CONTAINS MATERIAL(S) WHICH MAV CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.

*•• COMPONENTS APPEAR IN SECTION II *••

COPYRIGHT 1989 LAST PAGE— SH ATTACHMENT PAGE IMCtrx-XACT "PAGt• -- ' / * : (


~" ASHLAND CHEMICAJ NCL 24-HOUR» • 'â_^^^î srtiuiwy •• »«»«*•«». n ' Emergency

\Snlana P.O. BOX" 2219~ TelephoneCOLUMBUS, OHIff 43216 1(800) 274-5263 or

(614) 889-3333 1(800) ASHLAND

DEFINITIONSThis definition page is intended for use with Material Safety Data Sheets supplied by the Ashland Chemical Company.Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910). particularlysubpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment forgeneral guidance on control of potential Occupational Health and Safety Hazards.

SECTION I SECTION IV (eont>PRODUCT IDENTIFICATION _„_,».— ,,.ui*isa uem* = „ .. ^—T TT ——•—•———=-* EXTINGUISHING MEDIA: Following National Fire

GENERAL OR GENERIC ID: Chemical family or product Protection Association criteria,description. FIREFIGHTING PROCEDURES: Minimum equipment toDOT HAZARD CLASSIFICATION: Product meets DOT protect firefighters from toxic products of vaporization.rnt«ria for hj»«-d« listed. combustion or decomposition m fire situations. Other

™ '* ' *•* ' '•••" "Hp it»*eji*> f ifiînhtWlfl KAVswHel nt w eiA K U BB J S A S\

c ECTI 4 jtt ti-r.1':"! " SPECIAL FIR! AND EXPLOSION HAZARDS: StatesCOMPONENTS hazards not covered by other sections.

Components are listad> « -this- MetiojV if <"ev present a . NFPA COOES: Hazard, cattogev assigned. b^ thephysical or health hazard and are present at or above Fir* Protection Association1% in the mixture. If a component is identified as aCARCINOGEN by NTP. IARC. or OSHA as of the date SECTION Von the MSOS. it will be listed and footnoted in this HEALTH HAZARD DATA

tSS ZSZ? ££ £Z£Sl *£?% SSSVIX, T' L'M1T Fof praduetreported. Additional health information may be found in THRESHOLD LIMIT VALUE: For productSection V. Components subject to the reporting EFFECTS OP ACUTE OVEREXPOSURE: Potential localrequirements of Section 313 of SARA Title III are and systemic effects due to single or short termidentified m the footnotes in this section; along with overexposur* to the eyes and skm or through inhalationtypical percentages. Other components may be listed if or mgestion,deemed appropriate.

_._ EFFECTS Of CHRONIC OVEREXPOSURf: Potential localExposure recommendations are for components. OSHA ^ sv$twwc 9,t9Ct* due to repeated or long termPermissible Exposure Limits (PS.S) and American overexposure to the eyes and skin or through .nhaiationConference of Governmental industrial Hygienists -. .noestion,(ACGIH) Threshold Limit Values (TLVs) appear on theline with the component identification. Other FIRST Alft Procedures to be followed when dealingrecommendations appear as footnotes. with accidental overexposure.

SECTION' lit': PRIMARY ROUTE Of ENTRY: Based on properties andPHYSICAL DATA expected use.

SOILING POINT: Of product if known. The lowestvalue of the components is listed for mixtures. REACTIVITY DATA.,.„„-, ......... «„ ., , ,. «. __.. HAZARDOUS POLYMERIZATION: Conditions to avoid toVAPOR .PRESSURE: Of product if known. The highest prevent Hazardous polymer.zation resulting in a largevalue of the components is listed for mixtures. release of energy.SPECIFIC VAPOR DENSITY: Compared to AIR » 1. If STAM.ITY: Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known. violent decomposition.the value is expressed as lighter or greater than a*. ..„-.„„._«.. _ ..*»<..«*. /••*».«» /- ^ . >./»«•• , ,. INCOMPATHIUTY! Materials and conditions to avoid toSPECIFIC GRAVITY: Compared to WATifl « 1. If prevent hazardous reactions.Specific Gravity of product is not known, the value isexpressed as less than or greater than water. SECTION VIIpH: If applicable. SPILL OR LEAK PROCEDURESPERCENT VOLATILE* Percentage) of material with „ _ înitial boiling point below 425 degrees Fahrenheit and "easonaWe precautions to be taken and methods o»vapor pressure above 0.1mm Ho at 68 P. coma-wenc clean-up and disposal Consult federal«... B.*i«u a.«K , -u \ * iut* «* loc** regulations for accepted procedures ana6VAFOJ,A7I?I1~AT* Indicated as faster or slower ^ ftcortinfl ,,, notification reqwrements.than ETHYL ETHER, unless otherwise stated.

SECT10M VlltF,Ri J EROSION DATA PROTECTS EQUIPMENT TO 11 USED

FLASH POINT: Method identified. "*EXPLOSION LIMITS: For product if known. The lowset «.-•«. ,-value of the components is listed for mixtures. SECTION IX.HAZARDOUS DECOMPOSITION PRODUCTS: K —— , or SPtCtAt PRECAUTIONS OH OTHEH COMMENTSexpected hazardous products resulting from heating. Covtr> relevant points not previously mentioned.Burning or other reactions.

ADDITIONAL COMMENTSContainers should be either reconditioned by CERTIFIED firms or property duoosed of by APPROVED firms. Disposal a*containers should be m accordance with applicable laws and regulations. 'EMPTY" drums should not be given -aindividuals. Serious accidents have resulted from the misuse of 'EMPT'W comaker* (drums.pails.etc). Refer to

«BnnniS2

rDATA SHEET ________(614) 889-3333________1(800) ASHLAND

ENVIRONMENTAL, HEALTH andSAFETY DEPARTMENTPRODUCT INFORMATION SERVICES GROUP

THE BUCO COMPANYATTN: CHARLES PAYN63155 W. BIG 3CAVBI ROAOTTOV. MI 480M

Dear Customer:

Enclosed is the Material Safety Data Sheet(s) that you recently requested. If you have any questionsplease contact the department listed above.

A Material Safety Data Sheet is enclosed for the following product(s):

TECTYL 127 B

Enclosurds):

ftROOOISS

MATEftfAL SAFETY -«WJF"«* COUMBOrfSfif 432!5DATA SHEET " R R T_______(614) 889-333?______ 1(800) ASHLAND

000017 TKCT7L 127 B pag«$

Product Na»0* TECTVt 127 8 : : ._.„__=

... OS 90 110

3 i 55'W. "BliTBEAVER ROAO PROOUCTsTROV. MI 48094 INVOICE: REQST

INVOICE OATEt 11/OR/9O< . TQj

9189-009V'JfcJ

S E C T I O N l

Gm«r»l or G«wr1c lOt PCTROLEUM BASED RUST PRgvEHTATivlDOT Huard Classification* COMBUSTIBLE (173.119)

O N I I C O M H O M S » j r

me COMPOSITION or THIS PRODUCT is BEING WITHHELD AS A TRAOC SECRET.if PRESENT. lAflC. NTP AND osm CAACINOGBIS AND OCMXCALS SUBJBCT TO Tm RCPORT-KHON.

% (by wo PCL TT.V.AUJM1MW f M. 10-15 10 MI/MB to IB/10 ( O

CAS »t 7429-90 '9 • •

ALIPHATIC HVOROCAMMNS (STOOOAAO TVPC) 40-99 100 PM 100 PPM ( 2)T ; _ ^

ALIPHATIC PeTPOLfiJI OISTILLATK 1-9 S MO/MI 9 MB/M (3)

NotMt ! :( 1) PR. AND TLV AM KR TOTAL NUlSANCt PAimCUUTiS.

THIS CWnCAI. IS SU8JKT TO TH1 RtPORHNO RtOUKWIWTJ « SCCTIOH 313 OP SAM TITLI HI.( 2) NIOSH RECOMBIOS A LIfHT OP 390 MB/CUM - 9 HOUR TIW «IOMT» AVBMQI. 1900 MO/CUI AS OeTBWHH) 8V A 15

MI NU re

{ 3) PEL/TLV IS FOR OIL MIST. AOSIH SHORT TERM EXPOSUM LIMIT (STEL) FOR OIL MIST IS 10 «/OJ».

883.1.ON III >' M y S I C A I [J A r A

Soiling Point for PRODUCT • , > J: . '" • 7

v«por PTMMIT* f«r COMPOMBffl 40-99%)

Specific vaear Ovwlty • _____ HEAVIHI TMMI AIRSp 1f1c(Sr««y' . 77lq*o**

______.__________|____ , ( ?9!oa 55 c>Pcrewt Vo1«1t«» j '4Q-H*

'_'-• ; . _________________________ ______________________• SILVER COLORst«t« ""*"•".• • j. .;. t:ou«8For«r " - • . . - • ; . KTBI SOL*

S F C f I () N . I V f I H t AH) • « >• {) ', I k) S

PUSH POINT(OOe ) 100.0 0* f ( 3T.i CM* CIexnosxvi LIMIT (Lowsr VMM <* coMNorn "*•» - *•<»

MOUA* MQULAR POAJI OR CARMH oioxioi OR OR» O«*CM. .. ' . "SmOH PROOyCTSi M»V KM TOXIC MATCRIAUt. QiRMI OIOXXOI AM CARMM MONOXIQI. VARIOUS^ SULFUR COMPOUMOS. KTC.

» IM THI Wl

<i ^... _ •. ' J4 -i,.K;

COPYRIGHT 1990 CONTINUIO ON PAGlt 2 * ^ „. .AROOOI51*


ASHLAND &IEM1CAK-1.NC——————24-HOUR- ——Ts«k>i«i«rv of »«•!••* on, IM Eta«rg«ncvP.O. BOX 2219 - T*l«phoS«

COLUMBUS, OHIO 43216 1(800) 274-5263 or(614) 889-3333 1(800) ASHLANP

TECTYL 127 B Pagt:000017

INau°INO ™ c*« ™ ™«s SHOULD BE GROW**,NFPA COOES: HEALTH- 1 FLAHMA8ILITY- 2 REACTIVITY- 0

E X P L O S I O N I N F O R M A f l O N I C a n l i n a c d )

PERMISSIBLE EXPOSURE LEVEL: SEE SECTION IIEFFECTS Of ACUTE OVEREXPOSUREj

H t A L T H HAZARD DATA

EYCS — CAN CA4JS& SEVERS Irw«* i« i &v**t r*6i r»i» Jt i **»**m»« Bbvrmsv T*^4VT*« __SKIN - PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION. OEFATTING, DERMATITIS.BREATHING - EXCESSIVE INHALATION Of VAPORSCAN CAUSE NASAL AND RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM

EFFECTS INCLUDING DIZZINESS. WEAKNESS. FATIGUE. NAUSEA. HEADACHE ANO POSSIBLE UNCONSCIOUSNESS. ANO EVENDEATH.

FIRST AID:IF ON SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP ANO'tMTEft. REMOVt COKTAMIKATEO CLOTHIHa. LAUNDER

CONTAMINATED CLOTHING BEFORE RE-USE.IF IN EVES: FLUSH WITH LARGE AMOUNTS OF WATER. LIFTING UPPER AND LOVER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.IF SWALLOWED! 00 NOT INDUCE VOMITING. KEEP PERSON WARM. QUIET. ANO GET MEDICAL ATTENTION. ASPIRATION Of MATERIAL

INTO THE LUNGS OUETO VOMITING CAN CAUSE CHEMICAL PNEUMQNITIS MHICH CAN SE FATAL.IF BREATHED* IF AFFECTED. REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IP

BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM). QUIET AND GET MEDICAL ATTENTION.

PRIMARY ROUTE(S) Of ENTRY:INHALATION. SKIN CONTACT

EFFECTS OF CHRONIC OVEREXPOSURE*

&ffJBBff™ ™ ** ****** *« * CAU* » «*«•» »«crs »U N V I H L A C I I V l I f UAIA

HAZARDOUS POLVMERIZATIONt CANNOT OCCURSTABILITY: STABLEINCOMPATIBILITYi AVOID CONTACT WITH.. STRONG OXIDIZING AGENTS.

U l l S P I L L O H L t A * P H O C t L J U H E S

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDiSMALL SPILL: ABSOM LIQUID ON PAPER. VERKCUUTB. FLOOR IBMRMMT. OR OTHER ABSORBENT MATERIAL AMD TRANSFER TO

HOOD. • '

LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES. FUMESINCLUOINa PILOT LIGHTS. ELECTRICAL SPARKS) .PERNOT WEARING PROTECTIVE EO II=MENT SHOULD BEEXaJJOEOFffOM AREA OF SPILL UNTIL aEANHj* HAS BEEN CCNKET1STOP SPILL AT SOURCE. DIKE AREA Of SPILL TO PREVSTT SPWAOINa. PUMP LIQUID TO SALVAfii TANK. RSMININi

——— ' ~P SPILL AT SOURCE. DIKE AREA Of SPILL TO PREVENT SPRCAOINa. PUMP LIQUID TO SALVAGE TANK. REMAINING

LIQUID MAY BE TAKEN UP ON SAND. CLAY. EARTH. FLOOR ABSORBENT. OR OTHER ABSORBENT MATERIAL ANO SHJVELEO INTOTAlNCflS*

800IiS * "**• lf "" ^ OCOJW-WASTE DISPOSAL METHODSSMALL SPILL: DISPOSE OP IN ACCORDANCE WITH ALL LOCAL. STATE ANO FEDERAL REGULATIONS.LARGE SPILL: DISPOSE Of IN ACCORDANCE WITH ALL LOCAL. STATE AMD FCDERAL WOULATIONS.

S t c f i o « 4 VIM f ^ o r t c r i v t t a ,j i - • •»* •« r r o u t u r, t oRESPIRATORY PROTECTTON,. IF WORKPLACE EXPOSURB LIMT(S) OP PRODUCT 0» AMV COMPONENT IS EXCEEDED (Sjj gCTIOM II).

A NIOSH/MSHA APPTOVEO AIR SUPPLIES RE9IRATOR IS AOVISHJ IN ACSEWQ1 OP PROPER CNVIf*OM*!NTAL"CONTBOL. OSHA(SEE YOUR SAFETY EQUIPMENT SUPPLIERKENGINEERINa OR AO«*IST«ATIV«Cc5TROLS SHOULD Bt IMPLEMENTED TO

VENTILATTgNt PROVIDE SUFFICIENT MMMNICAL (GENERAL AND/OR LOCAL OMUST1 VENTILATION TO MAINTAIN EXPOSURB BELOW

PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS*. NEOPRENR. NfWILB HUBBR*

OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SUM CONTACT. MUM IMPERVIOUS OOTH1N8, AND BOOTS.

COPYRIGHT 1990 COMTIMU10 Oil PAGIt 3 AROOOI55

ASHLANTJ<

MATERIAL SAFETY t-««"-" C Q l S X O l*> iDATA SHgT {'••••M* ______ (614) 889-3333 1 (800) ASHLAND

000017. ____ - " " " _ _ = _ ' ' " - ; ^

TICTYL 127 B Pag«uX S P E C I A L H H t C A U r i Q H r . OH 0 r H t R C 0 VMt N r S

i, AMD SUITABLE TO THEIR CIRCUMSTANCES.

<KR mamm asfe«1 wa

CURRBfT,I NF OR MA r I ON

CAUTION!COMBUSTIBLE LIQUID AND VAPOR 'IMV CAUSE EVE AND SKIN IRRITATION.INFLATION <* VAPO" IMV CMISa IMITATION OP NASAL AND RESPIRATORY PASSAGES. "StMLLOKINS IMV CAUSE IRRITATION OP MOUTH. ESOPHAGUS. AND GASTROINTESTINAL SVSTBI AND MAY BE FATAL.

HANOLINO ft STORAGe* 'AWftV FROM HEAT AND OPEN PUIK. USE OR STORE ONLY WITH ADEQUATE VENTILATION. MAINTAIN AMISTORE ONLY WITH ADEQUATE VENTILATION. MAINTAIN A

LIMITS. AVOID CONTACT WITH EVES AND PROLONGED OROGGLES: RESISTANT GLOVES.ANO OTHW APPROPRIATE PK?,

UIPMBIT'ESsiNflAL FSTvoiS OPWATIoSr INl&lH'EXPOsWTVl.OuESB ^ 0. ..,.iSAZ ^ "*

FIRST AIDSEYESt PLUSH THOROUGHLY WITH WATER. GET MEDICAL ATTENTION IMMBIATELY.SKIN* WASH THOROUGHLY WITH SOAP AND WATER. - ' '. •INHALATIONS IP APPECTED. REM3VC TO FRESH AIR. IP 8REATHINO IS OIPPICULT. GET MBOICAU ATTENTION.INGESTIOKt 00 NOT INDUCE VOnTtNO. CALL A PHYSICIAN OR POISON CONTROL CENTER IMM9IATELY. ASPIRATION HAZARDipafiLLo8B)7cANeffi*IJJMGSTND CAUSE OANAGI. NEVE* GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.OMNIC INFORMATION* .CONTAINSt PETROLEUM blSTILLATM. CONTAINS MATERIAL(S) WHICH »»V CAUSE CENTRAt NERVOUS SYSTEM DEPRESSION.

*•• COMPONENTS APPEAR IN SECTION IX •••

COPTRIGHT 19SJO LAST PAGE--SIK ATTACHMENT PAOE.l LftS IJ-eLAST PACE. \ .- ' " ' n :-. -

ASHLAND CHEMICAL INC—————24-HOUK———'sn»ii4i«y >t AIM** an. i. Emergency

MATERIAL SAFETY ASManO P.O. BOX 2219' Telephone-DATASHEET e e e COLUMBUS, OHIO 43216 1(800) 274-5263UAiAaneet_____| ^ e »7________(614) 889-3333 1(800) ASHLAND

DEFINITIONSThis definition page-isJnteode4.for use wtttx Material. Safety. Oau Sheets, supplied b»> theuAshiand (,Recipients of these daU sheets should consult the OSHA Safety and Health Standards (29 CFff 1910). particularlysubpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment forgeneral guidance on control of potential Occupational Health and Safety Hazards. •- • •

SECTION I SECTION IV (eontJPRODUCT IDENTIFICATION evi-i.i/Wiiaui«i« ueniA B . -i cT T T———————• EXTINGUISHING MEDIA: Following National Fire

GENERAL OR GENERIC ID: Chemical family or product Protection Association criteria.description. FIREFIGHTING PROCEDURES: Minimum equipment to

or azar s ist firefighting hazards may also be indicated./,SPECIAL FIR! AND EXPLOSION HAZARDS: States

COMPONENTS hazards not covered by other sections.Components are listed in this section if they present a NFPA COOES: Hazard ratings assigned by the Nation**physical or health hazard, and are present at or above> Fire Protection Association.1% m the mixture. If a component is identified as aCARCINOGEN by NTP. I ARC. or OSHA as of the date SECTION Von the MSOS. it will be listed and footnoted in this HEALTH HAZARD DATA

^ Sc ^ X ? SSEF, LXPT0TVT Fof •*oductreported. Additional health information may be found in THRESHOLD LIMIT VALUt: For productSection V. Components subject to the reporting EFFECTS OP ACUTf OVERfXPOSURfe Potential localrequirements of Section 313 of SARA Title HI are and systemic effects due to single or short termidentified in the footnotes in this section, along with overexoosure to the eyes and skin or through inhalationtypical percentages. Other components may be listed if or mgesuon.deemed appropriate-

_ . . _eu. EFFECTS OP CHRONIC OVERIXPOSURt Potential localExposure recommendations are for components. OSHA ^ $¥iwnie t»fects due to repeated or long termPermissible Exposure Limits (PELS and American overexoosure to the eves and skin or through inhalationConference of Governmental Industrial Hygienists & mcastion.(ACGIH) Threshold Limit Values (TLVs) appear on thehne with the component identification. Other FIRST AID: Procedures to be followed whenrecommendations appear as footnotes. with accidental overexposure.

SECTION III • PRIMARY ROUTI OP ENTRY: Based on properties andPHYSICAL QAT'A expected use.

SOILING POINT: Of product if known. The lowest Sf 5" ** V* -value of the components is listed for mixtures. REACTIVITY DATA.«- ...... .-«. «. «. ^ HAZARDOUS POLYMERIZATION: Conditions to avo.d :o

VAPOR PRESSUHfe Of product if known. The highest prevent n«erdous polymerization resulting ,n a >argevalue of the components is listed for mixtures. <-vieaee of energy.SPECIFIC VAPOR DENSITY: Compared to AIR » 1. If STAtHJTY; Conditions to avoid to prevent hazardous orthe Specific Vapor Density of a product is not known. violent decomposition,the value is expressed as lighter or greater than aw. ,.«.*,•«•.-,•., ~. .. ^ ^ ^~~~~.~,~ -...»«» ^ -. ,.,»T™ , .. iNCOMPATIiltlTY: Materials and conditions to avoid toSPECIFIC GRAVITY: Compared to WATER » 1. If prevent hazardous reactions.Specific Gravity of product is not known, the) value isexpressed as less than or greater than water. SECTION VIIprt If applicable. SPILL OR LEAK PROCEDURESPERCENT VOLATILISt Percentage) of material with _ w ^,n,t.al boiling point below 42S degrees Fahrenheit and »««onawe precautions to be taken and methods o»vapor pressure above O.tmm Hg at 83 * eonta-went clean-up and disposal Consult f.derat«,../>«>•»«» **•**. , \ . , *'*• ** loc** regulations for accepted procedures andEVA'SSAT19!L«5AT* lndte»t** •• '«•«» <* »low«r «m, reeortmg or notification requirements.than ETHYL ETHER, unless otherwise stated.

SECTIQNJV 9KFW Y'HFIR! ANf! EXP?5s.L DATA PROTECTIVE EQUIPMENT TO Bi USED

FLASH POINT: Method MfM. "*'* "" "* ""**EXPLOSION LIMITS: For product if known. The lowsetvalue of the components is listed for mixtures. SECTION IXHAZARDOUS DiCOMPOSITtON PRODUCTS: Known or SPtCtAl PRECAUTIONS OH QTHC* COMMENTSexpected hazardous products result.ng from heating. c r.ievant points not prev,ousiy mentioned,burning or other reactions.

ADDITIONAL COMMENTSContainers should be either reconditioned by CERTIFIED firms or orooem disposed of by APPROVED firms. Disposal 3*containers should be in accordance with applicable laws ana 'egwanons. "EMPTY" drums should not be given 3individuals. Serious accidents have resulted from the misuse of EMPTIED" containers (drums.pails.etcJ. Refer to Sect o tlv-1dlx AROOOI57

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