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Today Kirchoff’s Laws Emission and Absorption Stellar Spectra & Composition 1
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Page 1: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

Today

Kirchoff’s Laws

Emission and Absorption

Stellar Spectra & Composition

1

Page 2: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Three basic types of spectra

Continuous Spectrum

Emission Line SpectrumAbsorption Line Spectrum

Spectra of astrophysical objects are usually combinations of these three basic types.

Wavelength

Intensity

2

Page 3: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Kirchoff’s Laws• Hot, dense objects emit a

– continuous spectrum• light of all colors & wavelengths• follows thermal distribution• obeys Wien’s & Stefan-Boltzmann Laws.

• Hot, diffuse gas emits light only at specific wavelengths.– emission line spectrum

• A cool gas obscuring a continuum source will absorb specific wavelengths – absorption line spectrum

e.g., a light bulb

e.g., a neon light

e.g., a star 3

Page 4: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Continuous Spectrum

• The spectrum of a common (incandescent) light bulb spans all visible wavelengths, without interruption.

4

Page 5: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Kirchoff’s Laws• Hot, dense objects emit a

– continuous spectrum• light of all colors & wavelengths• follows thermal distribution• obeys Wien’s & Stefan-Boltzmann Laws.

• Hot, diffuse gas emits light only at specific wavelengths.– emission line spectrum

• A cool gas obscuring a continuum source will absorb specific wavelengths – absorption line spectrum

e.g., a light bulb

e.g., a neon light

e.g., a star 5

Page 6: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Emission Line Spectrum

• A thin or low-density cloud of gas emits light only at specific wavelengths that depend on its composition and temperature, producing a spectrum with bright emission lines.

6

Page 7: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Kirchoff’s Laws• Hot, dense objects emit a

– continuous spectrum• light of all colors & wavelengths• follows thermal distribution• obeys Wien’s & Stefan-Boltzmann Laws.

• Hot, diffuse gas emits light only at specific wavelengths.– emission line spectrum

• A cool gas obscuring a continuum source will absorb specific wavelengths – absorption line spectrum

e.g., a light bulb

e.g., a neon light

e.g., a star 7

Page 8: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Absorption Line Spectrum

• A cloud of gas between us and a light bulb can absorb light of specific wavelengths, leaving dark absorption lines in the spectrum.

8N2-32

Page 9: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

How does light tell us what makes up things?

Spectrum of the Sun9

Page 10: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Atomic Terminology

• Atomic Number = # of protons in nucleus • Atomic Mass Number = # of protons + neutrons

10

Page 11: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Atomic Terminology • Isotope: same # of protons but different # of

neutrons (4He, 3He)

• Molecules: consist of two or more atoms (H2O, CO2)11

Page 12: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

• Each type of atom has a unique set of energy levels.

• Each transition corresponds to a unique photon energy, frequency, and wavelength.

Energy levels of hydrogen

Chemical Fingerprints

12

Page 13: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Energy levels of hydrogen

Possible Electron orbits

13

Page 14: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Energy levels of hydrogen

Transitions between orbitsrelease energy (photons)

14EmissionLine

Page 15: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

• Downward transitions produce a unique pattern of emission lines.

Chemical Fingerprints

15

Page 16: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

• Atoms can absorb photons with those same energies, so upward transitions produce absorption lines.

Chemical Fingerprints

16ProductionOfAbsorpLines

Page 17: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

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Page 18: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Chemical Fingerprints

• Each type of atom has a unique spectral fingerprint.

18

Page 19: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Chemical Fingerprints

• Observing the fingerprints in a spectrum tells us which kinds of atoms are present.

19

N2-02/IntroToSpectroscopy

Page 20: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Example: Solar Spectrum

All the dark regions are absorption lines due to all the elementsin the sun’s atmosphere. The strengths of the lines tell us about the sun’s composition and other physical properties.

20

Page 21: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

Composition of the Sun

A. The Sun is mainly made of heavy stuff

B. Most of the lines are actually from Earth’s atmosphere

C. Light stuff (H, He) has its electrons stripped off, so no lines

D. Just the outer layers of the Sun are made of heavy stuff

E. I don’t know21

Most of the lines in the solar spectrum arefrom heavy elements such as oxygen and carbon.

This means:

Page 22: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

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Page 23: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

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Of all objects, the planets are those which appear to us under the least varied aspect. We see how we may determine their forms, their distances, their bulk, and their motions, but we can never known anything of their chemical or mineralogical structure Auguste Comte, 1842

Page 24: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Solar composition

• 73% Hydrogen• 25% Helium• 2% everything else

– “metals”

• Other stars similar– H & He most common stuff in the universe– Helium was discovered in the spectrum of the sun

24

Page 25: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Interpreting an Actual Spectrum

• By carefully studying the features in a spectrum, we can learn a great deal about the object that created it.

25MysteryGasComposition

Page 26: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

What is this object?

Reflected Sunlight: Continuous spectrum of visible light is like the Sun’s except that some of the blue light has been absorbed—object must look red

26

Page 27: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

What is this object?

Thermal Radiation: Infrared spectrum peaks at a wavelength corresponding to a temperature of 225 K

27

Page 28: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

What is this object?

Carbon Dioxide: Absorption lines are the fingerprint of CO2

28

Page 29: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

What is this object?

Ultraviolet Emission Lines: Indicate a hot emitting gas

29

Page 30: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

What is this object? Mars!

Hot upper atmosphere Carbon Dioxide in atmosphere

Reflected Sunlight: Mars is red

Infrared peak wavelength tells us T = 225 K

We can learn an enormous amount from spectra!30

Page 31: Kirchoff's Laws Emission and Absorption Stellar Spectra ...

© 2007 Pearson Education Inc., publishing as Pearson Addison-Wesley

Molecules in space!

31

Molecules have sigsas well, typically atlonger wavelengths.

More than 160(!!) different molecules havebeen found in space.

Notables: water, alcohol,glycine (simplest amino acid)


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