LABORATORY RESULTS OF BNA'S IN SOILS MEDIUM LEVEL … · Manual for NERL. Results relate only to...

^ ^ f * | § ™ r ^ j E p l V Office of Environmental Measurement & Evaluation Region lTNe" l iSgi3 1 1 Technology Drive

Page 1 of 30

United States Environmental Protection Agency

North Chelmsford, MA 01863-2431 Superfund Records Cerilev SITE: C . n ^ ^ L < L v̂rfcgjr

Laboratory Report BREAK: 0 .̂02-

September 26,2012 , OTHER: S 5 O Z \ 0 .. ..

Karen Lumino - Mail Code OSRR07-1

Bart Hoskins - ECA / OEME

US EPA New England RI

. • ' • \ Project Number: 12090019 ' Project: Commerce Street Plume - Williston, VT Analysis: BNAs in Soils Medium Level Analyst: BhavitaPatel

Analytical Procedure:

All samples were received and logged in by the laboratory according to the USEPA New England Laboratory SOP for Sample Log-in.

Sample preparation and analysis was done following the EPA Region I SOP, EIASOP-BNAS3.

Samples were prepared using pressurized fluid extraction. The samples were analyzed using high resolution capillary column chromatography and quadrapole mass spectrometry (GC/MS). The SOP for this analysis is based on US EPA SW-846 methods 3545A and 8270C and EIASOP-BNAGCMS7.

Date Samples Received by the Laboratory: 09/14/2012

Data were reviewed in accordance with the internal verification procedures described in the EPA New England Quality Manual for NERL.

Results relate only to the items tested or to the samples as received by the Laboratory. This analytical report shall not be reproduced except in full, without written approval of the laboratory.

If you have any questions please call me at 617-918-8340 .

Sincerely,

Digitally signed by. Dan Boudreau DN: cn=Dan Boudreau, o=EPA, ou=EIA, ff \ email=boudreau,dan^er4ajgov, c=US Date: 2012W& 16:03:05 -04'00*

12090019$BNAMS

SDMS DocID 550230

Page 2 of 30

1

Qualifiers: RL = Reporting limit ND = Not Detected above Reporting limit NA = Not Applicable due to high sample dilutions or sample interferences NC = Not calculated since analyte concentration is ND. J = Estimated value E = Estimated value exceeds the calibration range L = Estimated value is below the calibration range B = Analyte is associated with the lab blank or trip blank contamination. Values are

qualified when the observed concentration of the contamination in the sample extract is less than 5 times the concentration in the blank.

R = No recovery was calculated since the analyte concentration is greater than four times the spike level.

12090019$BNAMS

Page 3 of 30

US ENVIRONMENTAL PROTECTION AGENCY NEW ENGLAND LABORATORY

Commerce Street Plume - Williston, VT

BNAs in Soils Medium Level

Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW17-SED

9/11/2012

9/17/12

9/18/12

Dry Weight Extracted: 9.712 grams

Wet Weight Extracted: 14.032 grams

CAS Number Compound Concentration

»g/Kg

Lab Sample ID: AB32912

. Matrix sediment

Amount Prepared N/A

Percent Solids: 69%

Extract Dilution: 1

pH: N/A

R L

ug/Kg Qualifier 95-94-3 120-82-1 95-50-1 541-73-1

99-65-0 106-46-7 130-15-4 90- 12-0 108-60-1 58- 90-2 95-95-4 88-06-2 120- 83-2 51-28-5 121- 14-2

105- 67-9 87- 65-0 606-20-2 91- 58-7 95-57-8 91-57-6 95-48-7 88- 74-4 88-75-5 108-39-4/106-44-

91-94-1 56-49-5 99- 09-2 534-52-1 101-55-3 59- 50-7 106- 47-8 7005-72-3 100- 01-6 100-02-7 56-57-5 83-32-9 208-96-8 98-86-2 62-53-3

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene 1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- DichIorobenzene 1,4-Naphthoquinone 1 -Methylnaphthalene 2,2'-oxybis(l-chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline

2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine

3- Methylcholanthrene

3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitro'phenol 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone

Aniline

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

260 260 260 260 260 260 260 260 260 260 260 260 260

1000 260 260 260 260 260 260 260 260 260 260 520 260 260 260 260 260 260 260 260 260 520 520 260 260 260 260

12090019$BNAMS




Page 4 of 30

Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW17-SED

9/11/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 69%

Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

120-12-7 140-57-8 103-33-3 92-87-5 56-55-3 50-32-8

205- 99-2 191-24-2 207-08-9

65- 85-0 100-51-6 111-44-4 117-81-7

85- 68-7 86- 74-8 510-15-6 218-01-9 84-74-2 117- 84-0 53-70-3 132-64-9 84-66-2 131-11-3 88-85-7 62-50-0 206- 44-0 86- 73-7 118- 74-1 87- 68-3 77- 47-4 67-72-1 1888-71-7 193-39-5 465-73-6

78- 59-1 120-58-1 143-50-0 66- 27-3 86-30-6 621-64-7

Anthracene Aramite Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzoic acid Benzyl alcohol Bis(2-Chloroethyl)ether Bis(2-ethylhexyl)phthalate Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene

Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate

Dinoseb Ethyl methanesulfonate Fluoranthene

Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(l,2,3-cd)pyrene

Isodrin Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine

ND ND ND ND ND ND ND

ND ND

ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND. ND ND

ND ND ND ND ND ND

ND ND ND ND ND

260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260

12090019$BNAMS

Page 5 of 30




Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW17-SED

9/11/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 69%

Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

62-75-9 91-20-3

98-95-3 608-93-5 82-68-8 87-86-5 62-44-2 85-01-8 108-95-2 129-00-0 110- 86-1 94-59-7

111- 91-1

N-nitrosodimethylamine Naphthalene

Nitrobenzene Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin

Phenanthrene Phenol Pyrene Pyridine

Safrole bis(-2-Chloroethoxy)methane

ND ND ND ND ND ND ND ND ND ND ND ND ND

260 260 260 260 260

1000 260 260 260 260 260 260 260

Surrogate Compounds

2-Fluorophenol (SSI) Phenol-d6 (SS2) Nitrobenzene-d5 (SS3) 2-Fluorobiphenyl (SS4) 2,4,6-Tribromophenol (SS5) p-Terphenyl-d!4(SS6)

Recoveries (%) 65 65 60 65 75 75

QC Ranges 22- 97 23- 99 20-98 23 - 104 12- 127 23 - 120

Comments: The reporting level for 4-nitrophenol, 4-nitroquinoline-l-oxide, 2,4-dinitrophenol, and pentachlorophenol have been raised to reflect the calibration range.

12090019$BNAMS




Page 6 of 30

Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

Reference-SED

9/13/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 61%

Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

95-94-3 120-82-1

95-50-1 541-73-1

99-65-0 106-46-7

130-15-4

90- 12-0 108-60-1

58- 90-2 95-95-4 88-06-2 120- 83-2 51-28-5 121- 14-2 105- 67-9 87- 65-0 606-20-2 91- 58-7 95-57-8 91-57-6 95-48-7 88- 74-4 88-75-5 108-39-4/106-44-91-94-1 56-49-5 99- 09-2 534-52-1 101-55-3 59- 50-7 106- 47-8 7005-72-3 100- 01-6 100-02-7 56-57-5 83-32-9 208-96-8 98-86-2 62-53-3

1.2.4.5- Tetrachlorobenzene

1.2.4- Trichlorobenzene

1.2- Dichlorobenzene

1.3- Dichlorobenzene

1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone

1- Methylnaphthalene 2,2'-oxybis(l-chloropropane)

2.3.4.6- Tetrachlorophenol

2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2- Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine 3- Methylcholanthrene

3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone

Aniline


260 260 260 260 260 260 260 260 260 260 260 260 260

1100 260 260 260 260 260 260 260 260 260 260 530 260 260 260 260 260 260 260 260 260 530 530 260 260 260 260

12090019$BNAMS

Page 7 of 30




Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

Reference-SED

9/13/2012

9/17/12

9/18/12




us/Ks


Matrix sediment

Amount Prepared N/A

Percent Solids: 61%

Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

120-12-7 140-57-8

103-33-3 92-87-5 56-55-3 50-32-8 205- 99-2 191-24-2 207-08-9 65- 85-0 100-51-6 111-44-4 117-81-7 85- 68-7 86- 74-8 510-15-6 218-01-9 84-74-2 117- 84-0 53-70-3 132-64-9 84-66-2 131-11-3 88-85-7 62-50-0

206- 44-0 86- 73-7 118- 74-1 87- 68-3

77- 47-4 67-72-1 1888-71-7 193-39-5 465-73-6

78- 59-1 120-58-1 143-50-0 66- 27-3 86-30-6 621-64-7

Anthracene Aramite

Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzoic acid Benzyl alcohol Bis(2-Chloroethyl)ether Bis(2-ethylhexyl)phthalate Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate

Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate

Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene

Hexachlorocyclopentadiene

Hexachloroethane

Hexachloropropene Indeno(l ,2,3-cd)pyrene Isodrin

Isophorone

Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine

ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ' ND ND ND ND ND ND ND ND ND M X


260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260

12090019$BNAMS

Page 8 of 30




Client Sample ID: Date of Collection: Date of Extraction: Date of Analysis:

Reference-SED

9/13/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 61%

Extract Dilution: 1

pH: N/A

RL ug/Kg Qualifier

62-75-9 91-20-3 98-95-3 608-93-5 82-68-8 87-86-5 62-44-2 85-01-8 108-95-2 129-00-0 110- 86-1 94-59-7 111- 91-1

N-nitrosodimethylamine Naphthalene Nitrobenzene Pentachlorobenzene Pentachloron itrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol Pyrene Pyridine Safrole bis(-2-Chloroethoxy)methane

ND ND ND ND ND ND ND ND ND 380 ND ND ND

260 260 260 260 260 1100 260 260 260 260 260 260 260

Surrogate Compounds 2-Fluorophenol (SSI) Phenol-d6 (SS2) Nitrobenzene-d5 (SS3) 2-Fluorobiphenyl (SS4) 2,4,6-Tribromophenol (SS5) p-Terphenyl-d!4(SS6)

Recoveries (%) 55 55 41 55 65 65

QC Ranges 22- 97 23- 99 20-98 23 - 104 12-127 23 - 120

Comments: The reporting level for 4-nitrophenol, 4-nitroquinoline-l -oxide, 2,4-dinitrophenol, and pentachlorophenol have been raised to reflect the calibration range.

12090019SBNAMS




Page 9 of 30

Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW20-SED

9/11/2012

9/17/12

9/18/12





Matrix sediment

Amount Prepared N/A

Percent Solids: 78%

Extract Dilution: 1

pH: N/A

R L

ug/Kg Qualifier 95-94-3 120-82-1

95-50-1 541-73-1 99-65-0 106-46-7 130-15-4

90- 12-0 108-60-1 58- 90-2 95-95-4 88-06-2 120- 83-2 51-28-5 121- 14-2 105- 67-9 87- 65-0 606-20-2 91- 58-7 95-57-8 91-57-6 95-48-7 88- 74-4 88-75-5 108-39-4/106-44-91-94-1

56-49-5 99- 09-2 534-52-1 101-55-3

59- 50-7

106- 47-8 7005-72-3 100- 01-6 100-02-7 56-57-5 83-32-9 208-96-8 98-86-2 62-53-3

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene

1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methy lnaphthalene 2,2'-oxybis(l-chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methy lnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine

3- Methylcholanthrene

3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-l-oxide Acenaphthene Acenaphthylene Acetophenone

Aniline

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 460 ND ND ND ND ND

200 200 200 200 200 200 200 200 200 200 200 200 200 820 200 200 200 200 200 200 200 200 200 200 410 200 200 200 200 200 200 200 200 200 410 410 200 200 200 200

12090019$BNAMS

Page 10 of 30




Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW20-SED

9/11/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 78%

Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

120-12-7 140-57-8

103-33-3

92-87-5

56-55-3 50-32-8

205- 99-2 191-24-2 207-08-9

65- 85-0 100-51-6 111-44-4 117-81-7 85- 68-7 86- 74-8 510-15-6 218-01-9 84-74-2 117- 84-0 53-70-3 132-64-9 84-66-2 131-11-3 88-85-7 62-50-0 206- 44-0 86- 73-7 118- 74-1 87- 68-3 77- 47-4 67-72-1 1888-71-7 193-39-5 465-73-6 78- 59-1 120-58-1 143-50-0 66- 27-3 86-30-6 621-64-7

Anthracene Aramite Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene

Benzo(g,h,i)perylene

Benzo(k)fluoranthene

Benzoic acid Benzyl alcohol Bis(2-Chloroethyl)ether Bis(2-ethylhexyl)phthalate Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(l,2,3-cd)pyrene

Isodrin Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine

y

1>

ND 210 ND ND 270 240 570 v/ 610 540 V ND ND ND 250 V 300 V ND

240 Y 680 ND 260 510 ND ND ND ND ND ND ND ND ND ND ND ND 500 ND ND ND ND ND ND ND

200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200

12090019$BNAMS

Page 11 of 30




Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW20-SED

9/11/2012

9/17/12

9/18/12 Dry Weight Extracted: 12.202 grams



US/Ji£


Matrix sediment

Amount Prepared N/A

Percent Solids: 78%

Extract Dilution: 1

pH: N/A

RL ug/Kg Qualifier

62-75-9 91-20-3 98-95-3 608-93-5 82-68-8 87-86-5 62-44-2 85-01-8 108-95-2 129-00-0 110- 86-1 94-59-7 111- 91-1

N-nitrosodimethylamine Naphthalene Nitrobenzene Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol Pyrene Pyridine Safrole bis(-2-Chloroethoxy)methane

ND ND ND ND ND 860 x / f 320 / ND ND ND ND ND ND

200 200 200 200 200 820 200 200 200 200 200 200 200

Surrogate Compounds

2-Fluorophenol (SSI) Phenol-d6 (SS2) Nitrobenzene-d5 (SS3) 2-Fluorobiphenyl (SS4) 2,4,6-Tribromophenol (SS5) p-Terphenyl-d!4 (SS6)

Recoveries (%) 73 73 65 70 85 80

QC Ranges 22-97 23 - 99 20-98 23 - 104 12- 127 23 - 120


Pentachlorophenol out of spec in the CCV.

12090019$BNAMS




Page 12 of 30

Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW2-SED

9/12/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 75%

Extract Dilution: 1

pH: N/A

RL ug/Kg Qualifier

95-94-3 120-82-1 95-50-1 541-73-1 99-65-0 106-46-7 130-15-4 90- 12-0 108-60-1 58- 90-2 95-95-4 88-06-2 120- 83-2 51-28-5 121- 14-2 105- 67-9 87- 65-0 606-20-2 91- 58-7 95-57-8 91-57-6 95-48-7 88- 74-4 88-75-5 108-39-4/106-44-91-94-1 56-49-5 99- 09-2 534-52-1 101-55-3 59- 50-7 106- 47-8 7005-72-3 100- 01-6 100-02-7 56-57-5 83-32-9 208-96-8 98-86-2 62-53-3

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene 1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methy lnaphthalene 2,2'-oxybis(l -chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine 3- Methylcholanthrene 3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone Aniline


220 220 220 220 220 220 220 220 220 220 220 220 220 900 220 220 220 220 220 220 220 220 220 220 450 220 220 220 220 220 220 220 220 220 450 450 220 220 220 220

12090019$BNAMS

Page 13 of 30




Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW2-SED

9/12/2012

9/17/12

9/18/12




"g/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 75%

Extract Dilution: 1

pH: N/A

R L

ug/Kg Qualifier

120-12-7 140-57-8 103-33-3 92-87-5 56-55-3 50-32-8 205- 99-2 191-24-2 207-08-9 65- 85-0 100-51-6 111-44-4 117-81-7 85- 68-7 86- 74-8 510-15-6 218-01-9 84-74-2 117- 84-0 53-70-3 132-64-9 84-66-2 131-11-3 88-85-7 62-50-0 206- 44-0 86- 73-7

118- 74-1

87- 68-3 77- 47-4 67-72-1 1888-71-7 193-39-5 465-73-6

78- 59-1 120-58-1 143-50-0 66- 27-3 86-30-6 621-64-7

Anthracene Aramite Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzoic acid Benzyl alcohol B is(2-Chloroethy l)ether B is(2-ethy lhexyl)phthalate Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene

Hexachlorobutadiene Hexachlorocyclopentadiene

Hexachloroethane Hexachloropropene

Indeno(l ,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine


220 220 220 220 220 220 220 220. 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220 220

12090019$BNAMS

Page 14 of 30





PW2-SED

9/12/2012

9/17/12

9/18/12





Matrix sediment

Amount Prepared N/A

Percent Solids:

Extract Dilution:

pH:

RL ug/Kg

75%

1 N/A

i

Qualifier

62-75-9 91-20-3 98-95-3 608-93-5 82-68-8 87-86-5 62-44-2 85-01-8 108-95-2 129-00-0 110- 86-1 94-59-7 111- 91-1



220 220 220 220 220 900 220 220 220 220 220 220 220

Surrogate Compounds


Recoveries (%) 55 55 55 60 70 70

QC Ranges 22-97 23 - 99 20-98 23 - 104 12- 127 23 - 120


12090019$BNAMS



Laboratory Blank

Page 15 of 30

Client Sample ID: N/A

Date of Collection: N/A

Date of Extraction: 9/17/12

Date of Analysis: 9/18/12


. Wet Weight Extracted: 10.177 grams


ug/Kg

Lab Sample ID: N/A

Matrix sediment

Amount Prepared N/A

Percent Solids: 100%

Extract Dilution: 1

pH: N/A

RL ug/Kg Qualifier

95-94-3 120-82-1 95-50-1 541-73-1 99-65-0 106-46-7 130-15-4 90- 12-0 108-60-1 58- 90-2 95-95-4 88-06-2 . 120- 83-2 51-28-5 121- 14-2 105- 67-9 87- 65-0 606-20-2 91- 58-7 95-57-8 91-57-6 95-48-7 88- 74-4 88-75-5 108-39-4/106-44-91-94-1 56-49-5 99- 09-2 534-52-1 101-55-3 59- 50-7 106- 47-8 7005-72-3 100- 01-6 100-02-7 56-57-5 83-32-9 208-96-8 98-86-2 62-53-3

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene 1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methy lnaphthalene 2,2'-oxybis(l-chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine 3 -Methy lcholanthrene 3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol . 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone Aniline


250 250 250 250 250 250 250 250 250 250 250 250 250 980 250 250 250 250 250 250 250 250 250 250 490 250 250 250 250 250 250 250 250 250 490 490 250 250 250 250

12090019$BNAMS



Laboratory Blank

Page 16 of 30








ug/Kg

Lab Sample ID: N/A

Matrix sediment

Amount Prepared N/A


Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

120-12-7 140-57-8 103-33-3 92-87-5

56-55-3 50-32-8

205- 99-2 191-24-2 207-08-9

65- 85-0 100-51-6 111-44-4 117-81-7 85- 68-7

86- 74-8 510-15-6 218-01-9 84-74-2 117- 84-0 53-70-3 132-64-9 84-66-2 131-11-3 88-85-7 62-50-0 206- 44-0 86- 73-7 118- 74-1 87- 68-3 77- 47-4 67-72-1 1888-71-7 193-39-5 465-73-6

78- 59-1 120-58-1 143-50-0 66- 27-3 86-30-6 621-64-7

Anthracene Aramite Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene

Benzo(g,h,i)perylene Benzo(k)fluoranthene

Benzoic acid Benzyl alcohol B is(2-Chloroethy l)ether Bis(2-ethylhexyl)phthalate Butylbenzylphthalate

Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene

Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(l ,2,3-cd)pyrene Isodrin

Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine


250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250 250

12090019$BNAMS



Laboratory Blank

Page 17 of 30








ug/K£

Lab Sample ID: N/A

Matrix sediment

Amount Prepared N/A


Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

62-75-9 91-20-3 98-95-3 608-93-5 82-68-8 87-86-5 62-44-2 85-01-8 108-95-2 129-00-0 110- 86-1 94-59-7 111- 91-1

N-nitrosodimethylamine Naphthalene Nitrobenzene Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin

Phenanthrene Phenol

Pyrene Pyridine

Safrole bis(-2-Chloroethoxy)methane


250 250 250 250 250 980 250

250' 250

250 250

250 250

Surrogate Compounds

2-Fluorophenol(SSl) Phenol-d6 (SS2) Nitrobenzene-d5 (SS3) 2-Fluorobiphenyl (SS4) 2,4,6-Tribromophenol (SS5) p-Terphenyl-d!4(SS6)

Recoveries (%) 56 58 58 93 47 74

QC Ranges 22 - 97 23 - 99 20 - .98 23 - 104 12- 127 23 - 120


12090019$BNAMS




Page 18 of 30

Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW11-SED

9/12/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 80%

Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

95-94-3 120-82-1 95-50-1 541-73-1 99-65-0 106-46-7 130-15-4

90- 12-0 108-60-1

58- 90-2 95-95-4 88-06-2 120- 83-2 51-28-5

121- 14-2 105- 67-9 87- 65-0 606-20-2 91- 58-7 95-57-8 91-57-6 95-48-7 88- 74-4 88-75-5 108-39-4/106-44-91-94-1 56-49-5 99- 09-2 534-52-1 101-55-3 59- 50-7 106- 47-8 7005-72-3 100- 01-6 100-02-7 56-57-5 83-32-9 208-96-8 98-86-2 62-53-3

1.2.4.5- Tetrachlorobenzene

1.2.4- Trichlorobenzene

1.2- Dichlorobenzene 1.3- Dichlorobenzene

1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methylnaphthalene 2,2'-oxybis(l-chloropropane)

2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol

2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine 3- Methylcholanthrene 3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone

Aniline


210 210 210 210 210 210 210 210 210 210 210 210 210 830 210 210 210 210 210 210 210 210 210 210 420 210 210 210 210 210 210 210 210 210 420 420 210 210 210 210

12090019$BNAMS

Page 19 of 30




Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW11-SED

9/12/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 80%

Extract Dilution: 1

pH: N/A

RL Mg/Kg Qualifier

120-12-7 140-57-8 103-33-3 92-87-5 56-55-3 50-32-8 205- 99-2 191-24-2 207-08-9 65- 85-0 100-51-6 111-44-4 117-81-7 85- 68-7 86- 74-8 510-15-6 218-01-9 84-74-2 117- 84-0 53-70-3 132-64-9 84-66-2 131-11-3 88-85-7 62-50-0 206- 44-0 86- 73-7 118- 74-1 87- 68-3 77- 47-4 67-72-1 1888-71-7 193-39-5 465-73-6 78- 59-1 120-58-1 143-50-0 66- 27-3 86-30-6 621-64-7

Anthracene Aramite Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzoic acid Benzyl alcohol B is(2-Chloroethy l)ether Bis(2-ethylhexyl)phthalate Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene Fluorene , Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(l ,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine


210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210 210

12090019$BNAMS




Page 20 of 30

Client Sample ID: PW 11 -SED

Date of Collection: 9/12/2012







Matrix sediment

Amount Prepared N/A

Percent Solids: 80%

Extract Dilution: 1

pH: N/A

R L ug/Kg Qualifier

62-75-9 91-20-3 98-95-3 608-93-5

82-68-8 87-86-5 62-44-2 85-01-8 108-95-2

129-00-0 110- 86-1 94-59-7 111- 91-1

N-nitrosodimethylamine Naphthalene Nitrobenzene Pentachlorobenzene Pentachloronitrobenzene

Pentachlorophenol

Phenacetin Phenanthrene

Phenol

Pyrene Pyridine Safrole bis(-2-Chloroethoxy)methane

ND .ND ND ND ND ND ND ND ND ND ND ND ND

210 210 210 210 210 830 210 210 210 210 210 210 210

Surrogate Compounds

2-Fluorophenol (SSI) Phenol-d6 (SS2) Nitrobenzene-d5 (SS3) 2-Fluorobiphenyl (SS4) 2,4,6-Tribromophenol (SS5) p-Terphenyl-d!4 (SS6)

Recoveries (%) 55 55 55 60 68 70

QC Ranges 22- 97 23- 99 20-98 23 - 104 12-127 23 - 120


12090019$BNAMS

Page 21 of 30





PW11-DUP-SED

9/12/2012

9/17/12

9/18/12 Dry Weight Extracted: 12.324 grams



»g/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 77%

Extract Dilution: 1

pH: N/A

RL ug/Kg Qualifier

95-94-3 120-82-1 95-50-1 541-73-1 99-65-0 106-46-7 130-15-4 90- 12-0 108-60-1 58- 90-2 95-95-4 88-06-2 120- 83-2 51-28-5 121- 14-2 105- 67-9 87- 65-0 606-20-2 91- 58-7 95-57-8 91-57-6 95-48-7 88- 74-4 88-75-5 108-39-4/106-44-91-94-1 56-49-5 99- 09-2 534-52-1 101-55-3 59- 50-7 106- 47-8 7005-72-3 100- 01-6 100-02-7 56-57-5 83-32-9 208-96-8 98-86-2 62-53-3

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene 1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methylnaphthalene 2,2'-oxybis(l-chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichloropheriol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methy lnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3 &4-Methy lphenol 3,3'-Dichlorobenzidine 3- Methylcholanthrene 3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone Aniline


200 200 200 200 200 200 200 200 200 200 200 200 200 810 200 200 200 200 200 200 200 200 200 200 410 200 200 200 200 200 200 200 200 200 410 410 200 200 200 200

12090019$BNAMS

Page 22 of 30




Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW11-DUP-SED

9/12/2012

9/17/12

9/18/12




Matrix sediment

Amount Prepared N/A

Percent Solids: 77%

Extract Dilution: 1

pH: N/A


ug/Kg R L

ug/Kg Qualifier

120-12-7 140-57-8 103-33-3 92-87-5

56-55-3 50-32-8 205- 99-2 191-24-2 207-08-9

65- 85-0 100-51-6 111-44-4 117-81-7 85- 68-7

86- 74-8 510-15-6 218-01-9 84-74-2 117- 84-0 53-70-3 132-64-9 84-66-2 131-11-3 88-85-7 62-50-0 206- 44-0 86- 73-7 118- 74-1 87- 68-3 77- 47-4 67-72-1 1888-71-7 193-39-5 465-73-6 78- 59-1 120-58-1 143-50-0 66- 27-3 86-30-6 621-64-7

Anthracene Aramite Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene

Benzoic acid Benzyl alcohol Bis(2-Chloroethyl)ether Bis(2-ethylhexyl)phthalate Butylbenzylphthalate

Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(l,2,3-cd)pyrene Isodrin Isophorone

Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND. ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200

12090019$BNAMS




Page 23 of 30

Client Sample ID:

Date of Collection:

Date of Extraction:

Date of Analysis:

PW11-DUP-SED

9/12/2012

9/17/12

9/18/12




ug/Kg


Matrix sediment

Amount Prepared N/A

Percent Solids: 77%

Extract Dilution: 1

pH: N/A

RL ug/Kg Qualifier

62-75-9 91-20-3 98-95-3 608-93-5 82-68-8 87-86-5 62-44-2 85-01-8 108-95-2 129-00-0 110- 86-1 94-59-7 111- 91-1



200 200 200 200 200 810 200 200 200 200 200 200 200-

Surrogate Compounds


Recoveries (%) 65 63

(60 65 80 80

QC Ranges 22 - 97 23-99 20-98 23 - 104 12-127 23 - 120


12090019$BNAMS


Page 24 of 30

MATRIX SPIKE (MS)


Sample ID: AB32916

PARAMETER

SPIKE SAMPLE ADDED CONCENTRATION

ug/Kg ug/Kg

MS MS QC CONCENTRATION % LIMITS

ug/Kg REC (% REC)

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene 1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methy lnaphthalene 2,2'-oxybis( 1 -chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline

2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine 3- Methylcholanthrene 3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-l-oxide Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Aramite Azobenzene Benzidine B enzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene

3,342 3,342 3,342 3,342 3,342 •3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 6,684 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

2100 2000 1900 1800 2300 1800 1500 2100 1900 2900 2700 2300 2200 1800 2400 2300 2200 2300 2100 2100 2100 2200 2300 2000 4400 1900 2300 2000 2200 2300 2300 1600 2300 2200 2500 1300 2200 2200 2100 1300 2300 2400 2200 ND 2300 2400 2400 2300

63 60 57 54 69 54 45 63 57 87 81 69 66 54 72 69 66 69 63 63 63 66 69 60 66 57 69 60 66 69 69 48 69 66 75 39 66 66 63 39 69 72 66 ND 69 72 72 69

1209001

47- 97 46-95 42-90 41 - 86 36-117 41 - 86 10- 123 49- 99 35-117 7.7-168 54-103 33- 119 42- 107 10- 114 29- 129 35 - 105 28-114 57- 105 45 - 108 41 - 102 43- 101 45- 102

- 40-142 48- 99 10- 154 10-137 25- 123 30- 114 10-115 48 - 116 43-112 17-94

52- 103 17-117 17-141 4.4- 101 53 - 101 56-99

46- 101 10-90

58- 108 39-118 53- 117 10-41

50- 112 34- 122 42- 120 50-108

9$BNAMS


Benzo(k)fluoranthene Benzoic acid Benzyl alcohol Bis(2-Chloroethyl)ether Bis(2-ethylhexyl)phthalate . Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(l,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine N-nitrosodimethylamine Naphthalene Nitrobenzene Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol Pyrene Pyridine Safrole

bis(-2-Chloroethoxy)methane

Comments:

3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3|342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342 3,342

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

2400 1400 2500 2000 2400 2400 2400 2600 2300 2400 2500 2400 2200 2300 2300 2400 2000 2300 2300 2300 2000 360 1700 1400 2400 1300 2100 2100 ND 1900 2200 2000 1900 2100 2000 2300 2300 4800 2400 2300 2100 2500 1400 2100 2100

72 42 75 60 72 72 72 78 69 72 75 72 66 69 69 72 60 69 69 69 60 11 51 42 72 39 63 63 ND 57 66 60 57 63 60 69 69 144 72 69 63 75 42 63 63

Page 25 of 30

33-116 10-168 18- 131 45- 98 22- 151 56- 120 52- 114 50- 129 43 - 111 57- 125 39- 128 31 - 129 53- 100 54- 106 54 - 104 6.4- 114 46- 100 43 - 126 57- 103 46-113 44-93 10-115 36-88 10-112 29-131 6.7-141 52- 108 49- 97 10-126 15 - 112 50- 107 45 - 108 34-90 43 - 100 46- 103 50- 101 51- 119 6.2-128 54-124 47- 119 48- 97 49- 117 14-67 49- 103 47- 102

12090019$BNAMS

Page 26 of 30


Laboratory Duplicate Results


Sample ID: AB32916

PARAMETER

SAMPLE SAMPLE DUPLICATE RESULT RESULT

ug/Kg "g/K-g

PRECISION RPD

% QC

LIMITS

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene 1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methylnaphthalene 2,2'-oxybis( 1 -chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine 3- Methylcholanthrene 3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Aramite Azobenzene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND



50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50

12090019$BNAMS


Benzoic acid Benzyl alcohol Bis(2-Chloroethyl)ether Bis(2-ethylhexyl)phthalate Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene Fluorene Hexach lorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexach loroethane Hexachloropropene Indeno(l,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine N-nitrosodimethylamine Naphthalene Nitrobenzene Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol Pyrene Pyridine Safrole bis(-2-Chloroethoxy)methane

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND



Page 27 of 30

50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 52 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50

12090019SBNAMS


Laboratory Fortified Blank (LFB) Results


Page 28 of 30

PARAMETER

LFB AMOUNT SPIKED

ug/L

LFB RESULT

ug/L

LFB RECOVERY

%

QC LIMITS

%

1.2.4.5- Tetrachlorobenzene 1.2.4- Trichlorobenzene 1.2- Dichlorobenzene 1.3- Dichlorobenzene 1.3- Dinitrobenzene 1.4- Dichlorobenzene 1,4-Naphthoquinone 1 -Methy lnaphthalene 2,2'-oxybis( 1 -chloropropane) 2.3.4.6- Tetrachlorophenol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenol 2,4-Dichlorophenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,4-dimethylphenol 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline 2- Nitrophenol 3&4-Methylphenol 3,3'-Dichlorobenzidine 3- Methylcholanthrene 3- Nitroaniline 4,6-Dinitro-2-methylphenol 4- Bromophenyl-phenylether 4-Chloro-3-methylphenol 4-Chloroaniline 4-Chlorophenyl-phenylether 4-Nitroaniline 4-Nitrophenol 4-nitroquinoline-1 -oxide Acenaphthene Acenaphthylene Acetophenone Aniline Anthracene Aramite Azobenzene Benzidine B enzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Benzoic acid Benzyl alcohol Bis(2-Chloroethyl)ether

3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 7878 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939

2550 2460 2290 2200 2860 2250 2720 2640 2390 3390 3180 2750 2690 1650 3020 2390 2650 2830 2590 2540 2600 2640 2890 2420 5630 2680 2820 2620 2520 2860 2950 2200 2840 2810 2950 2210 2710 2720 2610 1730 2920 2930 2720

355 2990 2990 3100 2920 3040 373 3130 2480

65 63 58 56 73 57 69 67 61 86 81 70 68 42 77 61 67 72 66 65 66 67 73 61 72 68 72 67 64 73 75 56 72 71 75 56 69 69 66 44 74 74 69 9

76 76 79-74 77 9 80 63

41 - 113 39- 111 36- 106 35 - 103 26-138 35 - 103 37- 134 41 - 117 30-134 16-153 38- 122 39 - 121 40- 118 10-71 47- 127 30-120 40- 116 46 - 128 42- 125 41 - 115 35 - 120 40-119 29- 163 35 - 115 3.5 - 149 29-114 40 - 126 44- 120 10-97 40 - 133 36- 133 28-99 45- 119 37- 131 15 - 141 19- 118 44-119 44 - 121 41 - 115 20- 99 40- 137 37- 118 41 - 141 2-76

46- 128 49 - 124 41 - 135 47 - 123 50- 114 10 - 122 28 - 129 40-112

12090019$BNAMS


Bis(2-ethylhexyl)phthalate Butylbenzylphthalate Carbazole Chlorobenzilate Chrysene Di-n-butylphthalate Di-n-octyl phthalate Dibenz(a,h)anthracene Dibenzofuran Diethylphthalate Dimethyl phthalate Dinoseb Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(l,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methyl methanesulfonate N-Nitrosodiphenylamine N-nitroso-di-n-propylamine N-nitrosodimethylamine Naphthalene Nitrobenzene Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol Pyrene Pyridine Safrole bis(-2-Chloroethoxy)methane

3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939 3939

2920 2920 3080 3160 2990 3040 3000 2940 2740 2840 2840 2920 2570 3060 2820 2900 2390 2090 2160 2270 3030 2900 2580 2590 2170 2470 2760 2540 2270 2550 2420 2800 2940 5440 3030 2950 2630 3160 1580 2590 2580

74 74 78 80 76 77 76 75 70 72 72 74 65 78 72 74 61 53 55 58 77 74 66 66 55 63 70 65 58 65 61 71 75

138 77 75 67 80 40 66 66

Page 29 of 30

38 - 143 40 - 143 42-133 45 - 139 47- 118 33 - 183 44-125 47-128 44-118 44 - 132 46- 121 10-118 41 - 117 42- 135 47- 122 38- 133 40-108 18 - 130 34- 106 31 - 115 46 - 127 43 - 137 45 - 125 41 - 115 12-101 6.3- 136 30- 148 41 - 122 28-107 38 - 118 40-119 44-116 39 - 139 10- 117 39- 146 39- 134 39 - 121 45 - 130 22-77 45 - 119 40- 119

Comments:

12090019$BNAMS

CHAIN OF CUSTODY RECORD

Distribution: Original Accompinin Shipment; Cof>y to Coordinitoi^itld Filei q a^-.

1- 1 Qn7n

Date post:	30-Apr-2020
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LABORATORY RESULTS OF BNA'S IN SOILS MEDIUM LEVEL … · Manual for NERL. Results relate only to...

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