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Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from...

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Lake Pleasant Limnology and Down-Canal Water Quality Implications
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Page 1: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Lake Pleasant Limnology and Down-Canal Water Quality

Implications

Page 2: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Spatial Variation in Reservoirs

Thermal stratification (latitudinal variation)Longitudinal variation from incoming river to the dam

Page 3: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 4: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 5: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 6: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

A priori Information

Taste and odor complaints decreased dramatically when the CAP canal contained water directly from the Colorado River as opposed to water that had been stored in Lake Pleasant.Taste and odor complaints increased among utilities in the Phoenix Valley that were the farthest from Lake Pleasant.

Page 7: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 8: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Thermal Stratification

Page 9: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 10: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Nutrient Loading

Allochthonous (from canal into reservoir) during periods of annual refilling of reservoir.Autochthonous (from reservoir into canal) during periods of release into the canal.

Page 11: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

0

10000

20000

30000

40000

50000

60000

Tota

l Alg

ae (c

ells

or c

olon

ies/

mL)

-34.5 -32.2 -30.8 -22 -16 -15.8 -15.6 -10.2 -0.1Depth (meters)

Lake Pleasant Total Algae Count 12/04/96

A

B

C

D

Page 12: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Algal Divisions with Depth

0

5000

10000

15000

20000

25000

Cel

ls o

r col

onie

s/m

L

-22 A

-10.

2

-0.1

-34.

5B

-15.

8

-0.1

-30.

8C

-15.

6

-0.1

-32.

2D -1

6

-0.1

A lg a l D iv is io n s with D e p th 1 2 /0 4 /9 6S um of Chlorophy taS um of Cy anophy taS um of Chry s ophy ta

Page 13: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Algal Speciation During Filling With Water From CAP Canal

Between dams at depthmostly periphytic species that are usually found growing along the side of the CAP canal

Sites to the north of the old dammore planktonic (true lacustrine) species

Page 14: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Preliminary data from 1996 suggested an increase in dissolved and/or reduced forms of algal nutrients within the hypolimnion

Hypolimnion

Metalimnion

Epilimnion

.0 .1 .2mg/L

Y

Mean(Total P)

Mean(Nitrate/nitrite-N)

Mean(Ortho P)

Mean(Ammonia-N)

y

Page 15: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 16: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 17: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

0

2

4

6

8

10

12

Sediment Mesocosm Results for Sites B and D Non-Aerated

Mean Ferrous Iron (mg/L) 10.03 0.6

Mean Ortho P (mg/L) 5.45 0.65

Mean Ammonia-Nitrogen (mg/L) 5.56 0.63

B D

Page 18: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Recommendation

Prior to 1996, water was released from the top gate (epilimnion) into the canal.This left the hypolimnion intact to become anoxic and accumulate nutrients.These nutrients were slowly released into the canal when stratified and in a large pulse during turn over.

Page 19: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Hypolimnetic Withdrawal

Recommended for the Spring/Summer of 1997 to try and siphon off the hyplominion as early in the year as possible. Done to increase dissolved oxygen over the sediments especially in the area between the old and new Waddell dams.

Page 20: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

-35

-30

-25

-20

-15

-10

-5

0

Dep

th (m

)

0 1 2 3 4 5 6 7 8D.O. (mg/l)

1996

-35

-30

-25

-20

-15

-10

-5

0

Dep

th (m

)

0 1 2 3 4 5 6 7 8D.O. (mg/l)

1997

Page 21: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Mean Hypolimnetic Nutrient Levels in Lake Pleasant by Year

0.06 mg/L0.14 mg/L0.01 mg/L1997

0.18 mg/L0.21 mg/L0.06 mg/L1996

Ortho PTotal PAmmoniaYear

Page 22: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Numbers of Periphytic Algae by Distance from Lake Pleasant During 1996

Cyanophyta

Chrysophyta

Chlorophyta

Pyrrophyta

Cyanophyta

Chrysophyta

Chlorophyta

Pyrrophyta

6 - 4

570

- 78

Div

isio

n by

Dis

tanc

e fro

m L

ake

Ple

asan

t (km

)

0 5000 10000 15000 20000 25000 30000Mean(Units/cm2)

Page 23: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Numbers of Periphytic Algae in the CAP Canal by Year.

Cyanophyta

Chrysophyta

Chlorophyta

Pyrrophyta

Cyanophyta

Chrysophyta

Chlorophyta

Pyrrophyta

1996

1997

0 10000 20000Mean(Units/cm2)

Page 24: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Mean Levels of MIB by Distance from Lake Pleasant by Year

0 - 45

70 - 78

0 - 45

70 - 78

1996

1997

0 1 2 3 4 5 6 7 8 9 10 11Mean MIB (ng/l)

Page 25: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Mean Levels of Geosmin by Distance from Lake Pleasant and Year

0 - 45

70 - 78

0 - 45

70 - 78

1996

1997

.0 .5 1.0 1.5 2.0 2.5 Mean Geosmin (ng/l)

Page 26: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Generalized Model of MIB and GeosminProduction in the CAP Canal1) Increased sedimentation of material between the old and new Waddell dams during re-filling of Lake Pleasant with CAP water. 2) This sedimentation may lead to increased oxygen demand and anoxia within the hypolimnion during thermal stratification.

Page 27: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

3) Under anoxic (and reducing) conditions, this sediment may release nutrients at a faster rate than other areas of the reservoir. 4) These nutrients accumulate within the hypolimnion. If water is released from the top gate, the hypolimnion remains undisturbed for long periods and this may lead to further nutrient accumulation.5) Geosmin or MIB may be quickly degraded in the turbulent release water

Page 28: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

6) Release of nutrient-rich water from the hypolimnion into the CAP canal may lead to the proliferation of taste and odor causing organisms in the canal, especially in areas 70 km or more away from Lake Pleasant.

Page 29: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Current Problems

Increased biomass of periphyton growing alongside the CAP canal (not this summer).Hydrogen sulfide emissions upon release during mid-late summer.Iron and manganese in canal water from Lake Pleasant. Spikes in tastes and odors during late summer/early fall 2004.

Page 30: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Hypolimnetic DO Levels by Year

DO

_mg_

per_

L

0

1

2

3

4

5

6

Summer 02 Summer 03 Summer 04

Sampling_Period

Sampling_PeriodErrorC. Total

Source 2 57 59

DF 99.05619 63.94067 162.99686

Sum of Squares 49.5281 1.1218

Mean Square 44.1519

F Ratio <.0001Prob > F

Analysis of Variance

Summer 02Summer 03Summer 04

Level 15 26 19

Number 3.64400 0.45577 1.19526

Mean0.273470.207710.24298

Std Error 3.0964 0.0398 0.7087

Lower 95% 4.1916 0.8717 1.6818

Upper 95%

Std Error uses a pooled estimate of error variance

Means for Oneway Anova

Oneway Anova

Oneway Analysis of DO_mg_per_L By Sampling_Period

Page 31: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Taste and Odor Increases During Late October of 2004.

Probably attributable to earlier-than-normal de-stratification.Huge pulses of mib and/or geosmin have occurred in the past when water was switched from the lower to the upper gate and occurred even when there was little or no mib/geosmin production within the lake itself.

Page 32: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

The majority of the mib spike downstream of Pleasant is probably due to lysing of periphyton growing alongside the canal.Lysing of periphytic cells occurs when there are large, sudden changes in temperature, or other parameters, in the canal. Tastes and odors greatly diminished when release was once again switched back to the lower gates.

Page 33: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Numbers of periphytic species capable of miband geosmin production growing periphytically alongside the CAP are less than what we find growing in the Salt and Verde Rivers below the reservoirs.However, if large amounts are suddenly lysed, it will result in large mib or geosminhits.

Page 34: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Why Earlier-Than-Normal De-stratification?

Profile data on 9/24/04 indicated strong stratification (>24o C at the surface to <14o C at the bottom of the hypolimnion). Samples taken by Steve Rottas and Al Grochowski of CAP on 10/19, showed that almost the entire reservoir was de-stratified. They also noticed a strong smell of hydrogen sulfide in the open water, an indication of recent turnover.

Page 35: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

USGS data from the Agua Fria River near Rock Springs, showed a significant flooding event on 9/19 and 9/20/04. The Agua Fria approached 2000 cfs and this pulse of water could have aided in an earlier-than-normal de-stratification.We have no data on other drainages into Pleasant such as Humbug Creek, Castle Creek, or Cole’s Wash.

Page 36: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

However, it appears that the lake level actually rose slightly while water was being released from Waddell Dam.

Page 37: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 38: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)
Page 39: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Summary

Most of the water quality problems down-canal of Lake Pleasant are dependant upon dissolved oxygen and ORP levels within the hypolimnion which are, in turn, dependent upon other limnological processes.

Page 40: Lake Pleasant Limnology and Down-Canal Water Quality ...Pyrrophyta 6 - 45 Division by Distance from Lake Pleasant (km) 70 - 78 0 5000 10000 15000 20000 25000 30000 Mean(Units/cm2)

Operational changes in the release of water from Lake Pleasant will address several of

these water quality issues.


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