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Lecture 14.1 & 14.2- Gas Laws & KMT

Date post: 15-Nov-2014
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Section 14.1 & 14.2 lecture for Honors & Prep Chemistry
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Properties of Gases In organized soccer, a ball that is properly inflated will rebound faster and travel farther than a ball that is under- inflated. If the pressure is too high, the ball may burst when it is kicked. You will study variables that affect the pressure of a gas. What factors affect the pressure of the air inside the ball? What causes the pressure in the ball?
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  • 1. Properties of Gases
    • In organized soccer, a ball that is properly inflated will rebound faster and travel farther than a ball that is under-inflated. If the pressure is too high, the ball may burst when it is kicked. You will study variables that affect the pressure of a gas.

What factors affect the pressure of the air inside the ball? What causes the pressure in the ball? 2.

      • Compressibilityis a measure of how much the volume of matter decreases under pressure.
      • When a person collides with an inflated airbag, the compression of the gas absorbs the energy of the impact.

3.

      • Gases are easily compressed because there is a lot of space between the particles in a gas.
          • The distance between particles in a gas is much greater than the distance between particles in a liquid or solid.
          • Under pressure, the particles in a gas are forced closer together.

4.

      • At room temperature, the distance between particles in an enclosed gas is about 10 times the diameter of a particle.

5.

    • The amount of gas, volume, and temperature are factors that affect gas pressure.
    • The relationships between these factors are described by GAS LAWS.

6.

      • The four variables used to describe a gas and their common units are
        • pressure ( P ) in kilopascals or atm
        • volume ( V ) in liters
        • temperature ( T ) in kelvins
        • the number of moles ( n ).

7.

    • Avogadros Law- n P
      • You can use kinetic theory to predict and explain how gases will respond to a change of conditions.
      • If you inflate an air raft,
      • for example, the pressure
      • inside the raft will increase.

8.

      • Collisions of particles create pressure.
      • Increasing the number of gas particles increases the number of collisions, which is why the gas pressure increases.
      • Avogadros Law- n P
      • directly proportional

9.

      • If the gas pressure increases until it exceeds the strength of an enclosed, rigid container, the container will burst.

10. Not for the faint at heart 11.

  • Aerosol Spray Paint
  • Gas flows from a region of higher pressure to a region of lower pressure

12.

    • Boyles law - V P orV P
      • You can raise the pressure exerted by a contained gas by reducing its volume.
      • The more a gas is compressed, the greater the pressure of the gas.

13.

    • When volume decreases, particles do not have to travel as far before they hit the side of the container.

14.

    • This causes more collisions and therefore more pressure.

15.

    • Boyles Law- V P
    • Indirect relationship

16.

      • When the volume of the container is halved, the pressure the gas exerts is doubled.

17.

    • Gay-Lussacs Law- T P
      • An increase in the temperature of an enclosed gas causes an increase in its pressure.
      • As a gas is heated, the average kinetic energy of the particles in the gas increases.

18.

    • Gay-Lussacs Law- T P
      • An increase in the temperature of an enclosed gas causes an increase in its pressure.
      • Faster-moving particles strike the walls of their container more often and with more energy.

19.

    • Gay-Lussacs Law - T P
      • An increase in the temperature of an enclosed gas causes an increase in its pressure.
      • Pressure = force/area
      • So more force (harder & more frequent collisions) makes more pressure.

20.

      • When the Kelvin temperature of the enclosed gas doubles, the pressure of the enclosed gas doubles.

21.

      • Gay-Lussacs Law - T P
      • Directly proportional

22.

  • Gay-Lussacs Law: T P
        • As the temperature of an enclosed gas increases, the pressure increases, if the volume is constant.

23.

  • A pressure cooker demonstrates Gay-Lussacs Law.

24.

  • Charles Law- T V
  • When a gas is heatedat constant pressure , the volume increases.

25.

  • Charles Law- T V
        • As the temperature of an enclosed gas increases, the volume increases, if the pressure is constant.
        • T ,V

26.

  • As the temperature of the water increases, the volume of the balloon increases.

27.

  • The KMT explains Gay-Lussacs Law-
  • as temperature increases particles movefaster, so they will collide more often andharder, increasing the pressure.
  • In orderto maintain constant pressure,the volume will need to increase!
  • Charles Law- T V
  • if pressure is constant

28.

  • Thecombined gas lawdescribes the relationship among the pressure, temperature, and volume of an enclosed gas.

29.

    • The combined gas law allows you to do calculations for situations in which only the amount of gas is constant.

30.

    • 1.Compared to liquids and solids, gases are easily compressed because the particles in a gas
      • attract each other.
      • are spaced relatively far apart.
      • are very small.
      • repel each other.

14.1 Section Quiz. 31.

    • 2.Gas pressure is affected by
      • temperature, volume, and the amount of the gas.
      • temperature, volume, and the molar mass of the gas.
      • phase diagram, volume, and the size of the container.
      • temperature, phase diagram, and the mass of the gas container.

14.1 Section Quiz. 32.

    • 3. For gases, the SI units for volume ( V ), pressure ( P ), and temperature ( T ) are, respectively,
      • liters, kilopascals, and C.
      • liters, kilopascals, and kelvins.
      • cm 3 , kilopascals, and kelvins.
      • liters, atmospheres, and C.

14.1 Section Quiz.


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