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Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Reading assignment: Callister 6.1-6.3, 6.5-6.9, 13.8-13.9
Learning objectives:• Understand the difference between elastic and plastic
deformation• Know how to determine mechanical properties from the results of
a tensile test• Elastic modulus • Yield strength • Tensile strength • Strain to failure
• Understand how the mechanical properties of ceramics differ from those of ductile metals
Lecture 26: Mechanical Properties I: Metals & Ceramics
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Engineering Stress & Strain [Callister 6.2]
from Callister
F
A0
L
L0
tension compression
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Elasticity vs. Plasticity [Callister 6.2]
• Elastic behavior• 0 when 0• Reversible deformation — no permanent shape change after
load is removed
• Plastic behavior• ≠0 when 0 • Some strain remains after load has been removed
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Poisson’s Ratio [Callister 6.5]
• Elastic dimensional change will occur transverse to applied uniaxial load:
v
x
z
y
z
Poisson’s ratio
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
• Stress-strain curve for loading …
• … is retraced on unloading
• Linear elastic behavior: Hooke’s law
Elastic Behavior [Callister 6.3]
Callister Fig. 6.5
E
• Note: not all elastic behavior is linear (see e.g. Callister Figure 6.6) …
• … but all elastic behavior is reversible
modulus of elasticity(a.k.a. Young’s
modulus)
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Modulus of Elasticity and the Interatomic Potential [Callister 6.3]
• Recall that energy between atoms depends on their separation• Recall also that
Minimum in energy zero net force
Callister Fig. 2.8b
tensioncompression
F d(energy)
d(separation)
Applying tension or compression
raises energy of material
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
• F = d(energy)/dr• Modulus of elasticity dF/dr E d2(energy)/dr2
— curvature of interatomic potential near ro
d E d
Callister Fig. 2.8 a
d dF
A
dL dr
dL r
E d
d r
A
dF
dr
Modulus of Elasticity and the Interatomic Potential [Callister 6.3]
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
• Modulus of elasticity dF/dr
Callister Fig. 6.7
Modulus of Elasticity and the Interatomic Potential [Callister 6.3]
high modulus
low modulus
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Mechanical Properties of Metals — Elastic Behavior
• High modulus strong bonding (high curvature of interatomic potential near ro)
(from Callister)
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Elastic Modulus: Temperature Dependence [Callister 6.3]
Callister Fig 6.8
Callister Fig. 2.8
• E gradually as T
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
• Plastic behavior: some strain remains after removal of load
Mechanical Properties of Metals [Callister 6.5]
0.2% yield strength
0.002=0.2%)
• Yield strength: stress that will result in a specified residual strain
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Callister Fig. 6.11
• Plastic behavior in a tensile test• Yielding• Tensile strength (M) (a.k.a. ultimate tensile strength)
• Necking• Fracture (F)
Mechanical Properties of Metals [Callister 6.5]
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Callister Fig. 6.13
• Brittle vs. ductile Two measures of ductility:% elongation
% area reduction
0
0
% 100fl lEL
l
0
0
% 100fA ARA
A
Mechanical Properties of Metals [Callister 6.5]
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Mechanical Properties of Metals — Plastic Behavior
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Callister Fig. 6.14
Plastic Behavior: Effects of Temperature
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Callister Fig. 6.15
Modulus of Resilience [Callister 6.6]
• Measure of a material’s capacity to absorb mechanical energy elastically
• Area under stress-strain curve has units of energy per unit volume
• Approximate this integral with:
0
y
rU d
U
r1
2
y
y
y
2
2E
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Callister Fig. 6.13
• A measure of energy absorbed during fracture
• Area under stress-strain curve has units of energy per unit volume
• Approximate this area as
Modulus of Toughness [Callister 6.6]
UT ut %EL
UT y ut
2%EL
or
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
True Stress and Strain [Callister 6.7]
• Engineering stress and strain: based on initial dimensions
• True stress and strain: based on instantaneous dimensions (i)
F
A0
L
l0
l l
0
l0
T F
Ai
Tln
li
l0
Callister Fig. 6.1
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
• Engineering stress and strain: based on initial dimensions
• True stress and true strain: based on instantaneous dimensions
Callister Fig. 6.16
Start of necking
True Stress and Strain [Callister 6.7]
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Mechanical Properties of Ceramics [Callister 13.8]
• Virtually no plasticity at room T
• Strain to failure typically < 0.2%
• Linear to fracture
Callister Fig. 13.29
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
• Flexural strength: measured in 3-point bending
• a.k.a. modulus of rupture, 3-point bend strength, fracture strength
Callister Fig. 13.28
Compression
Tension
Mechanical Properties of Ceramics [Callister 13.8]
fs 3Ff L
2bd 2
rectangularcross-section
circularcross-section fs
Ff L
R3
Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics
ENGR 145, Chemistry of MaterialsCase Western Reserve University
Mechanical Properties of Ceramics [Callister 13.8]
• Moduli usu. higher than for metals • Wide spread in strengths