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Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials...

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Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment: Callister 6.1-6.3, 6.5-6.9, 13.8-13.9 Learning objectives: • Understand the difference between elastic and plastic deformation • Know how to determine mechanical properties from the results of a tensile test Elastic modulus Yield strength Tensile strength Strain to failure • Understand how the mechanical properties of ceramics differ from those of ductile metals Lecture 26: Mechanical Properties I: Metals & Ceramics
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Page 1: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Reading assignment: Callister 6.1-6.3, 6.5-6.9, 13.8-13.9

Learning objectives:• Understand the difference between elastic and plastic

deformation• Know how to determine mechanical properties from the results of

a tensile test• Elastic modulus • Yield strength • Tensile strength • Strain to failure

• Understand how the mechanical properties of ceramics differ from those of ductile metals

Lecture 26: Mechanical Properties I: Metals & Ceramics

Page 2: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Engineering Stress & Strain [Callister 6.2]

from Callister

F

A0

L

L0

tension compression

Page 3: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Elasticity vs. Plasticity [Callister 6.2]

• Elastic behavior• 0 when 0• Reversible deformation — no permanent shape change after

load is removed

• Plastic behavior• ≠0 when 0 • Some strain remains after load has been removed

Page 4: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Poisson’s Ratio [Callister 6.5]

• Elastic dimensional change will occur transverse to applied uniaxial load:

v

x

z

y

z

Poisson’s ratio

Page 5: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

• Stress-strain curve for loading …

• … is retraced on unloading

• Linear elastic behavior: Hooke’s law

Elastic Behavior [Callister 6.3]

Callister Fig. 6.5

E

• Note: not all elastic behavior is linear (see e.g. Callister Figure 6.6) …

• … but all elastic behavior is reversible

modulus of elasticity(a.k.a. Young’s

modulus)

Page 6: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Modulus of Elasticity and the Interatomic Potential [Callister 6.3]

• Recall that energy between atoms depends on their separation• Recall also that

Minimum in energy zero net force

Callister Fig. 2.8b

tensioncompression

F d(energy)

d(separation)

Applying tension or compression

raises energy of material

Page 7: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

• F = d(energy)/dr• Modulus of elasticity dF/dr E d2(energy)/dr2

— curvature of interatomic potential near ro

d E d

Callister Fig. 2.8 a

d dF

A

dL dr

dL r

E d

d r

A

dF

dr

Modulus of Elasticity and the Interatomic Potential [Callister 6.3]

Page 8: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

• Modulus of elasticity dF/dr

Callister Fig. 6.7

Modulus of Elasticity and the Interatomic Potential [Callister 6.3]

high modulus

low modulus

Page 9: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Mechanical Properties of Metals — Elastic Behavior

• High modulus strong bonding (high curvature of interatomic potential near ro)

(from Callister)

Page 10: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Elastic Modulus: Temperature Dependence [Callister 6.3]

Callister Fig 6.8

Callister Fig. 2.8

• E gradually as T

Page 11: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

• Plastic behavior: some strain remains after removal of load

Mechanical Properties of Metals [Callister 6.5]

0.2% yield strength

0.002=0.2%)

• Yield strength: stress that will result in a specified residual strain

Page 12: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Callister Fig. 6.11

• Plastic behavior in a tensile test• Yielding• Tensile strength (M) (a.k.a. ultimate tensile strength)

• Necking• Fracture (F)

Mechanical Properties of Metals [Callister 6.5]

Page 13: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Callister Fig. 6.13

• Brittle vs. ductile Two measures of ductility:% elongation

% area reduction

0

0

% 100fl lEL

l

0

0

% 100fA ARA

A

Mechanical Properties of Metals [Callister 6.5]

Page 14: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Mechanical Properties of Metals — Plastic Behavior

Page 15: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Callister Fig. 6.14

Plastic Behavior: Effects of Temperature

Page 16: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Callister Fig. 6.15

Modulus of Resilience [Callister 6.6]

• Measure of a material’s capacity to absorb mechanical energy elastically

• Area under stress-strain curve has units of energy per unit volume

• Approximate this integral with:

0

y

rU d

U

r1

2

y

y

y

2

2E

Page 17: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Callister Fig. 6.13

• A measure of energy absorbed during fracture

• Area under stress-strain curve has units of energy per unit volume

• Approximate this area as

Modulus of Toughness [Callister 6.6]

UT ut %EL

UT y ut

2%EL

or

Page 18: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

True Stress and Strain [Callister 6.7]

• Engineering stress and strain: based on initial dimensions

• True stress and strain: based on instantaneous dimensions (i)

F

A0

L

l0

l l

0

l0

T F

Ai

Tln

li

l0

Callister Fig. 6.1

Page 19: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

• Engineering stress and strain: based on initial dimensions

• True stress and true strain: based on instantaneous dimensions

Callister Fig. 6.16

Start of necking

True Stress and Strain [Callister 6.7]

Page 20: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Mechanical Properties of Ceramics [Callister 13.8]

• Virtually no plasticity at room T

• Strain to failure typically < 0.2%

• Linear to fracture

Callister Fig. 13.29

Page 21: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

• Flexural strength: measured in 3-point bending

• a.k.a. modulus of rupture, 3-point bend strength, fracture strength

Callister Fig. 13.28

Compression

Tension

Mechanical Properties of Ceramics [Callister 13.8]

fs 3Ff L

2bd 2

rectangularcross-section

circularcross-section fs

Ff L

R3

Page 22: Lecture 26, summer 2007 Mechanical Properties I: Metals & Ceramics ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment:

Lecture 26, summer 2007Mechanical Properties I: Metals & Ceramics

ENGR 145, Chemistry of MaterialsCase Western Reserve University

Mechanical Properties of Ceramics [Callister 13.8]

• Moduli usu. higher than for metals • Wide spread in strengths


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