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Lecture 8.4b- Polar Molecules

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Section 8.4 lecture (part B) for Honors & Prep Chemistry
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BELLWORK- Determine Shape Draw the Lewis Dot Structure and the 3D structure for ethane (C 2 H 6 ) and ethene (C 2 H 4 ). Do these molecules have any polar bonds?
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Page 1: Lecture 8.4b- Polar Molecules

BELLWORK- Determine ShapeDraw the Lewis Dot Structure and the 3D structure for ethane (C2H6) and ethene (C2H4). Do these molecules have any polar bonds?

Page 2: Lecture 8.4b- Polar Molecules

In reviewEqual sharing of electrons = covalent

LOW electronegativity difference

Unequal sharing of electrons = polar

MEDIUM electronegativity difference

Transfer of electrons = ionic

HIGH electronegativity difference

Page 3: Lecture 8.4b- Polar Molecules

2 bonding domains

Three bonding domains

Four bonding domains

Three bonding and one lone pair

Two bonding and two lone

pairs

Page 4: Lecture 8.4b- Polar Molecules

Bond polarity and molecule shape determine if a molecule is polar

Bond polarity --- When a bond has a partial negative charge on one atom and a partial positive charge on the other atom.

Molecule shape--- the arrangement of atoms in three dimensions (3-D)

Page 5: Lecture 8.4b- Polar Molecules

A polar molecule has polar bonds and asymmetry

Page 6: Lecture 8.4b- Polar Molecules

A polar molecule has polar bonds and asymmetry

Polar bonds Non-polar molecule

Symmetry- all sides are the same

δ-

δ-

δ-

δ-δ+

Page 7: Lecture 8.4b- Polar Molecules

A polar molecule has polar bonds and asymmetry

Polar bonds Non-polar molecule

Symmetry- all sides are the same

Polar bonds Polar molecule

Asymmetry- has different sides

δ-

δ-

δ-

δ-

δ-

δ+δ+

negative side

Positive side

Page 8: Lecture 8.4b- Polar Molecules

If the electrons are not distributed equally, the

molecule is polar.

The molecule has a negative

end and a positive end.

Page 9: Lecture 8.4b- Polar Molecules

A polar molecule has a partially positive side and a partially negative side.

The arrow labels the molecular polarity.

It shows that electrons are mostly by the oxygen atom

OH H

Page 10: Lecture 8.4b- Polar Molecules

Polar molecules are affected by electric fields

Page 11: Lecture 8.4b- Polar Molecules

Polar molecules have two poles; one is partially positive and one is

slightly negative.

Positive end

Negative end

N

HHH

Page 12: Lecture 8.4b- Polar Molecules

The positive pole (+) is attracted to

negative ions

and

the negative poles(-) in other polar molecules.

POLAR MOLECULES INTERACT!!

Page 13: Lecture 8.4b- Polar Molecules

+

POLAR MOLECULES INTERACT!!

The negative pole (-) is attracted to

positive ions

and

the positive poles(+) in other polar molecules.

Page 14: Lecture 8.4b- Polar Molecules

Water is a molecule that has two polar O-H bonds.

Page 15: Lecture 8.4b- Polar Molecules

The electrons are not distributed evenly, so the water molecule is polar.

The negative pole is at the oxygen.

O is more electronegative than H, so electrons are

pulled toward O.

Also, there are two lone pairs around oxygen.

negative end

positive end

Page 16: Lecture 8.4b- Polar Molecules

Na+(aq)

A dissolved sodium ion

Page 17: Lecture 8.4b- Polar Molecules

Water is very good at dissolving salts because it can surround anions & cations.

Page 18: Lecture 8.4b- Polar Molecules

Practice- Using last night’s homework assignment, label the molecular polarity

on the four pictures

H F

Page 19: Lecture 8.4b- Polar Molecules

For the rest of the period work on your molecular modeling lab•Find a molecule that contains polar bonds•Build the molecule using a molecular modeling kit•Draw a sketch of the molecule

•Label the bond polarity using δ+ and δ- •Label the molecular polarity using

HW- complete bonding practice problems #1-#17

Tuesday = cover network solids and intermolecular forces. HW- Section 8.4

Block Day = Complete modeling lab, plus finish

bonding practice problems. Friday = Chapter Eight QUIZ!!

Page 20: Lecture 8.4b- Polar Molecules

Practice- Draw the 3D structures for these molecules and label the bond polarity and the molecule polarity.

1. H2O

2. CH4

3. CH3F

4. CH3CH3

5. CH3CH2OH

6. NH3

7. CO2

8. CH2CH2

9. HCN

10.

11.


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