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7/31/2019 Lesson Min 5 Carbonates
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ACO3 ACO3
A =
A =A =
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CaCO 3 MgCO 3 FeCO 3 MnCO 3 ZnCO 3
CaCO3 MgCO3 FeCO3 MnCO3 ZnCO3
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CaCO 3 PbCO 3
BaCO
3 SrCO 3
CaCO3 PbCO3
BaCO3
SrCO3
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CaMg(CO 3 ) 2 CaFe(CO 3 ) 2 CaMg(CO3 )2 CaFe(CO3 )2
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() () Cu 2 CO 3 (OH) 2
CuCO3 .Cu(OH)2
Cu
3 (CO
3 )
2 (OH)
2 2CuCO3 .Cu(OH)2
Cu2 CO3 (OH)2CuCO3
.Cu(OH)2
Cu3
(CO3
)2
(OH)2
2CuCO3 .Cu(OH)2
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(CO3 ) 2+ (CO3 ) 2+
-
2/
3
+11/3
.. = 3.. = 3
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(10-11) (10-11)10-11
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2H+ + CO3 => H2 O + CO2 2H+ + CO3 => H2 O + CO2
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CaCO3
CaCO3
, , .
10-11 21-31 0001
10-10
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CaCO3
CaCO3
.
.
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CaCO3
CaCO3
, , , , ,
, , ..
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,
, . , ,, , ,, , .
.
3. 2,7
(10-11)
HCl
CaCO3
CaCO3
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CaCO3
CaCO3
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CaCO3
CaCO3
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CaCO3
CaCO3
A () A ()
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.
, , ...
CaCO3
CaCO3
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CaCO3
CaCO3
...
.
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CaCO3
+ H2 O + CO2 Ca(HCO3)2CaCO3 + H2 O + CO2 Ca(HCO3)2
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, .
.Calcite
(GB),
Calcite (F),
Calcit, Kalkspat (D)
CaCO3
CaCO3
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MgCO3
MgCO3
.
().
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,
. ,
, .
.
3 - 5. 2,9 - 3,1
HCl
MgCO3
MgCO3
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.
MgCO3
MgCO3
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(MgO), .
: .
: .Magnesite (GB), Magnsite (F), Magnesit (D)
MgCO3
MgCO3
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FeCO3
FeCO3
. ,, , .
.
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,
. ,.
. , .
3 - 4. 4,0
HCl
FeCO3
FeCO3
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, Fe. .
Siderite
(GB),
Sidrite (F),
Siderit, Eisenspat (D)
FeCO3
FeCO3
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.
, ,, .
MnCO3
MnCO3
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,
.
.
3 - 4
.
3,5 - 3,7
HCl
MnCO3
MnCO3
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, ,, . ,
.
MnCO3
MnCO3
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. , .
Rhodochrosite (GB), Rhodochrosite (F), Rhodochrosit, Manganspat (D)
MnCO3
MnCO3
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, .
, ,. .
ZnCO3
ZnCO3
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,
, ,, ,
, ,
, , .
.
4 -
4
. 4,3 - 4,5
HCl
ZnCO3
ZnCO3
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Zn , , , , ..
ZnCO3
ZnCO3
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Zn. .
: James L. M. Smithson (1765-1829).
: Zn, cadmia .Smithsonite
(GB),
Smithsonite (F),
Smithsonit,
Zinkspat (D)
ZnCO3 ZnCO3
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, .
, .
.
.
Cu2
(OH)2
CO3
Cu2 (OH)2 CO3
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, ,
, .
.
. 3
-
4
. 3,7 - 3,8
HCl
Cu2
(OH)2
CO3
Cu2 (OH)2 CO3
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, , , , ..
Cu2
(OH)2
CO3
Cu2 (OH)2 CO3
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Cu. .
, ,
.Malachite (GB), Malachite (F), Malachit (D)
Cu2
(OH)2
CO3
Cu2 (OH)2 CO3
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Cu3
(OH)2
(CO3
)2
Cu3 (OH)2 (CO3 )2
,
. ,
.
.
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, .
, .
. 3 - 4. 3,7 - 3,8
HCl
Cu3
(OH)2
(CO3
)2
Cu3 (OH)2 (CO3 )2
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( ). ,, , , ,
..
Cu3
(OH)2
(CO3
)2
Cu3
(OH)2
(CO3
)2
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Cu. .
lazhward = Azurite (GB), Azurite (F), Azurit, Kupferlasur (D)
Cu3
(OH)2
(CO3
)2
Cu3
(OH)2
(CO3
)2
