7/23/2019 Levulinic Acid Reactor and Process Development

1/24

ZW 2

Mavmlbia NohdmrrBhlvi~rohl

@ivy`olob Mboa w~haybqohl f~hd `ojlhbi``y`hrinohdmrr5 bhdwm~orhl hf qci AONMLIQ

w~hwhria airojl zoqc qci Nohfoli w~hbirr fh~qci mboa ca~h`ror ~hyqi qh @ivy`olob MboaAhllbcm Cmvi~q, Km~`m Ayrrml, A~ Mllm V Woqi~olm, A~ Nymlm Jo~oryqm,

A~ A Cmir, A~ E @imc, W~hf D Cmir

7/23/2019 Levulinic Acid Reactor and Process Development

2/24

Hvi~voiz

Bmwmno`oqoir aivi`hwia mq Bm~nh`im ay~olj AONMLIQ

Bhlqisq @odoqolj fmbqh~r ol @M w~haybqohl

Isorqolj bcidobm` w~hbirrir fh~ `ivy`olob mboa w~haybqohl

AONMLIQ w~iq~imqdilq mr qci nmror hf ml odw~hvia mboaca~h`ror w~hbirr

Qci airojl

Bhdwm~orhl zoqc Nohfoli

7/23/2019 Levulinic Acid Reactor and Process Development

3/24

W~hbirrolj bmwmboq

@mn rbm`i 7= @q 3@q

Mqdhrwci~i 97 Nm~

Ol `oli rmdw`olj

Wo`hq rbm`i =77 R} d

Bhlqolyhyr rrqid

Yw qh =@q(dolqc~hyjcwyq

7/23/2019 Levulinic Acid Reactor and Process Development

4/24

7/23/2019 Levulinic Acid Reactor and Process Development

5/24

7/23/2019 Levulinic Acid Reactor and Process Development

6/24

Airo~mn`i ri~oir hf ~imbqohlr

@ojlol olqi~fi~ilbi

^ibm`boq~mlbi

Wcrobm` rqmqi #Dmrr q~mlrfi~/

^imbqovi olqi~diaomqir

Hwqodyd koliqobr(oi`ar(w~hbirriljolii~olj

Ri`ibqovoq cojc` Q aiwilailq

W~mbqobm`oqoir5 Q, W [MboaT

/=,>32#,>:39,7,77??,7

dms6

dms+4

4

MBZi_

_R

Q

CY

@M

7/23/2019 Levulinic Acid Reactor and Process Development

7/24

H~ojolm`` AONMLIQ nmria hl

Nohfoli

7/23/2019 Levulinic Acid Reactor and Process Development

8/24

M~imr fh~ odw~hvidilq

Ca~h`ror hf Bi``y`hri `odoqolj #cojc ili~j olwyq/

Dy`qow`i bhdwhlilqr Mboa iffibq hl w~hbirr i}yowdilq

Airo~mn`i w~haybqr lhq rqmn`i ylai~ w~hbirr bhlaoqohlr

@hz qc~hyjc wyq #?9) zmqi~/

Ili~j olqilrovi

Whrq w~hbirrolj bhdw`obmqia n qci ry`wcy~ob mboa

Rbm`mno`oq #cojc w~irry~i BRQ^/

7/23/2019 Levulinic Acid Reactor and Process Development

9/24

Qci Bhlqisq

Or qci~i m w~hbirr qh 5

^iaybi Dibcmlobm` ili~j olwyqr #J~olaolj, Bchwwolj/

^iaybi Ili~j olwyqr #cimq/ Olb~imri @M _oi`ar

Ilvo~hldilqm`` ryrqmolmn`i

Bhrq iffibqovi

Bmwoqm`, ili~j, ~ilai~olj hf hyqwyq rq~imdr

Ilbhdwmrrir qci nirq mqq~onyqir hf aoffi~ilq mww~hmbcir5f~mbqohlmqohl, ~iaybia ~ibm`boq~mlbi iqb

7/23/2019 Levulinic Acid Reactor and Process Development

10/24

W~iq~imqdilq

Fimron`i dimlr hf f~mbqohlmqolj qci nohdmrr

^ilai~r qci bi``y`hri qh m cojc ry~fmbi m~im fh~d F~hd 9 qh :9) wi~hsoai mla cojc dmrr `hmaoljr

< ?7) `ojlol ~idhvm` ol 9 dol

< 39 ) Cidobi``y`hri bhlvi~qia qh dhlhdi~ob ryjm~r ol qci

`o}yh~ ol 9 dol < Chdhjilihyr bi``y`hrob fiiarqhbk fh~ ca~h`ror

Qci rrqid or myqh$qci~dm`5 qidwi~mqy~ir hf ==7hBzoqchyq isqi~lm` cimq

^iry`qmlq bi``y`hri or =7$=> qodir dh~i aojirqon`i

7/23/2019 Levulinic Acid Reactor and Process Development

11/24

9) Mboa=97 BW~i$q~imqia

=) Mboa=:9 B^mz dmqi~om`

=) Mboa=97 BW~i$q~imqia

=) Mboa=97 B^mz dmqi~om`

9) Mboa=97 BW~i$q~imqia

=) Mboa=:9 B^mz dmqi~om`

=) Mboa=97 BW~i$q~imqia

=) Mboa=97 B^mz dmqi~om`

7/23/2019 Levulinic Acid Reactor and Process Development

12/24

Mvobi`

^mz #lhl$q~imqia/

nohdmrr/

7

7=

7>

72

71

79

76

7:

73

7?

=

==

=>

=2

7 719 =9 : >1 13 :>

Jy

bhri~iimri

#ALR

mrrm/,917ld

Ay~mqohl hf qci iludmqob ca~h`ror #c~r/

Rynrq~mqi qwi

W~i$q~imqia nohdmrr

FM(C>H> $#9)/

W~i$q~imqia nohdmrr

FM(C>H> $#:,9)/

W~hfo`i hf j`ybhri ~i`imri ay~olj iludmqob aojirqohl hf Mvobi` #dob~hb~rqm``oli bi``y`hri/, ~mz mla

w~iq~imqia Dorbmlqcyr #97) mla :9) C>H>/ mq 19 hB zoqc m bhddi~bom` bi``y`mri iludi dos

Iludmqob Aojirqohl

hf W~iq~imqia Dorbmlqcyr

7/23/2019 Levulinic Acid Reactor and Process Development

13/24

Airojl W~hwhrm` Nmror

W~i$q~imqdilq qh oi`a qzh rq~imdr

$ < Bi``y`hri ~obc r`yaji

$ < FM `o}yh~ zoqc aorrh`via B9 ryjm~r mla @ojlol @o}yh~ or fia qh BRQ^ fh~ bhlvi~rohl hf B9 qh fy~fy~m`

$ < [FMT mffibqr bhlvi~rohl

Qci dosqy~i or b`imlia hf cydolr mla ro`obmqir Vm~ohyr ivmwh~mqohl mla zmqi~ maaoqohl rqiwr m~i yria qhw~ibowoqmqi qci `ojlol

M `o}yoa rq~imd bhlqmololj FM, Fy~fy~m` mla Zmqi~ or rilqfh~ w~haybq ~ibhvi~ mla ~ibb`olj #`m~ji` aiqi~dolir qcifimrono`oq/

Bi``y`hri rilq fh~ bhlvilqohlm` ca~h`ror mq =97 B ol mri~oir hf BRQ^r

7/23/2019 Levulinic Acid Reactor and Process Development

14/24

W~i$q~imqdilq mla fy~fy~m`

w~haybqohl

7/23/2019 Levulinic Acid Reactor and Process Development

15/24

@ivy`olob Mboa W~haybqohl

7/23/2019 Levulinic Acid Reactor and Process Development

16/24

Fy~fy~m` ~ibhvi~ mla FM ~ibb`i

7/23/2019 Levulinic Acid Reactor and Process Development

17/24

@M W~haybqohl5 NOHFOLI

7/23/2019 Levulinic Acid Reactor and Process Development

18/24

Bhdwm~orhl hf AONMLIQ mla

NOHFOLI _oi`arAONMLIQ NOHFOLI

Ol Kj(c~ _oi`a Ol Kj(c~ _oi`a Odw~hvidilqNohdmrr =77,77 =77,77

C>H> 99,77 7,77

C>RH1 7,67 =,29

DQCF 7,>7 7,17BmH 7,97 =,77

Hyq Hyq

@M =?,19 :7,77 =6,19 9:,77 >>)

FY^FY^M =9,=7 6?,>7 3,?9 1=,7> 6?)

FM #37)/ 6,19 19,77 :,1> 9>,>7 $=6)

@ojlol >>,97 :9,77 7,77 7,77 $

MC^ >2,1= 9:,2?

7/23/2019 Levulinic Acid Reactor and Process Development

19/24

Bhdwm~orhl hf AONMLIQ mla

NOHFOLI5 Ili~j

Aonmliq Nohfoli

@M w~haybqohl + ibhvi~ =:=,= 912,6

Fy~fy~m` +FM ibhvi~ >31,9 >93,6

Qhqm` 196 37>

Rqmji Ayq #kZ/

7/23/2019 Levulinic Acid Reactor and Process Development

20/24

Bhdwm~orhl hf AONMLIQ mla

NOHFOLI5 W~haybq vm`yiAonmliq Nohfoli

Ol Ol

Kj(c~ h~ KZc~ Yloq bhrq(kj Ryn bhrq(c~ Kj(c~ h~ KZc~ bhrq(kj Ryn bhrq*(c~

Nohdmrr =77,77 7,=7 =7,77 =77,77 7,=7 =7,77

C>H> 99,77 7,27 =6,97 7,77 7,27 7,77

C>RH1 7,67 7,27 7,=3 =,29 7,27 7,1=

DQCF 7,>7 =,77 7,>7 7,17 =,77 7,17

BmH 7,97 7,27 7,=9 =,77 7,27 7,27

Ili~j 66>,77 7,7= 6,6> 379,77 7,7= 3,79

Ryn Qhqm` Bhrq(c~ 22,69 =?,=6

Hyq Hyq

@M =?,19 >,77 23,?7 =6,19 >,77 2>,?7

FY^FY^M@ =9,=7 >,77 27,>7 3,?9 >,77 =:,?7

FM #37)/ 6,19 7,27 =,?1 :,1> 7,27 >,>2

@ojlol >>,97 7,97 ==,>9 7,77 7,97 7,77

Rynqhqm` W~haybq wi~ c~ 3>,>? 92,72

J~hrr Dm~jol(c~ 13,61 22,3:

7/23/2019 Levulinic Acid Reactor and Process Development

21/24

Dhvolj Nohdmrr olqh qci

w~i$q~imqdilq ~imbqh~ mq rbm`i Rh`oa ahrolj wydwr

Rivi~m` Dmlyfmbqy~i~r Wy`qudiorqi~

Zio~

Cojc rh`oar `hmaolj 69) r`yaji

@m~ji wm~qob`ir #lh ~i}yo~idilq fh~ do``olj/

Isoq qh AL>77

F`hz ~mqir qh 67 D 2(c~

W~irry~ir qh

7/23/2019 Levulinic Acid Reactor and Process Development

22/24

W~i$q~imqdilq ~imbqh~

7/23/2019 Levulinic Acid Reactor and Process Development

23/24

Qcmlk _hy

Mbklhz`iajidilqr

K Ayrrml

A~ N Jo~orqyqm

A~ A Cmir

A~ M Woqi~olm

W~hf D Cmir A~ E E @imc

]yirqohlr8

No fo ` a

7/23/2019 Levulinic Acid Reactor and Process Development

24/24

Nohfoli wmwi~ r`yaji

#bi``y`hri hl`/