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page 1 LightCheck® light monitoring dosimeters From the laboratory to the museum A.-L. Dupont Centre de Recherche sur la Conservation des Collections, National Natural History Museum, Paris P. Menino Homem Faculdade de Letras da Universidade do Porto SUPP-CZ COST D42 – Workshop SHOWCASES INSIDE OUT May 24 th -26 th 2009
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Page 1: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

page 1

LightCheck® light monitoring dosimeters From the laboratory to the museum

A.-L. Dupont Centre de Recherche sur la Conservation des Collections, National Natural History Museum, ParisP. Menino HomemFaculdade de Letras da Universidade do Porto

SUPP-CZ

COST D42 – Workshop SHOWCASES INSIDE OUTMay 24th-26th 2009

Page 2: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LiDo “A Light Dosimeter for Monitoring Cultural Heritage:Development, Testing and Transfer to Market

(FP 5 2001 – 2004)

Tapestry of the Apocalypse, Angers (photo LRMH)Front Back

LightCheck® Sensitive

LightCheck® Ultra

Effect of light exposure on artefacts…

Page 3: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LCS and LCU

LightCheck® Sensitive LCSblue dye - Ormocer® / glassProgressive bleaching blue / white

Fraunhofer (ISC)

LightCheck® Ultra LCU(blue + red) dyes + additives - PVAc / paperProgressive change blue / purple / pink / white

CNRS (CRCC)

LD

LD

Page 4: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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Dose-Response FunctionLightCheck®U & LightCheck®S vs. BWS no.1

L um inous exposure [kluxh]0 100 200 300 400 500 600

Col

our c

hang

e∆ E

0

10

20

30

40

50LC U LC SBW S 1

To obtain a total colour variation

∆E ≅ 10-12the exposure needed is

12 klx.h for LCU

60 klx.h for LCS

250 klx.h for BWS1Ex. 50 lx: LCU 30 days, LCS 150 days, BSW1 625 days

LCU

BWS 1LCS

Curves obtained with controlled light-ageing (500 lx QTH, T=23°C, 50% rH)

Page 5: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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light-sensitivity

BWS BWS -- LCS LCS -- LCU LCU Low exposure levels, not detectable with BWS are detectable with LightCheck®

LightCheck®U and LightCheck®S have different and complementary operational ranges

Very-light sensitive, fugitive objects

Short exposure periods

More durable objects

Longer exposure periods

LCU 0 to 100 klxh

LCS 60 to 400 klxh

Page 6: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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Influence of light source / illuminance

LightCheck®U

Similar behaviour with- QTH (40 – 500 lx)- Natural (no direct sunlight)- Simultaneous multiple sources

Different behaviour with- 100% fluorescent light- metal halide

Some characteristics of LC

0

10

20

30

40

50

60

0 20 000 40 000 60 000 80 000 100 000 120 000LD (lx h)

DE

500 lux halogen5000 lux fluonatural light (avg 100 lx)mixed natural+halogen+fluo (avg 300 lux)in-field halo exp (avg 40 lux)Servathin 193 klx

∆E*

LCU

Page 7: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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Influence of other environmental parameters:temperature / rH

05

101520253035404550

0 20 000 40 000 60 000 80 000 100 000LD (lx h)

Del

ta E

DE* 40 C-50% rHDE* 30 C-50% rHDE* 25 C-50% rHDE* 20 C-50% rH

05

101520253035404550

0 20 000 40 000 60 000 80 000 100 000LD (lx h)

Del

ta E

DE* 20 C-70% rH

DE* 20 C-50% rH

DE* 20 C-30% rH

∆E

∆E

rH variation: no influence on fading T raise: increase in fading rate and saturation threshold

LightCheck®U

LightCheck®SrH raise: increase in fading rate and

saturation thresholdT raise: increase in fading rate and

saturation threshold

Page 8: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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From laboratory tests to calibration

LightCheck® integrates the light effects with a cooperative action of other environmental parameters

choice for calibration: Reference Colour Scale with few colour steps to take into account the variability due to the environment but also to account for the subjectivity involved in the colour evaluation (observer dependent)

Page 9: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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Reference Calibration Scales (RCS)

0S

1S

2S

3S

4S

4U

3U

2U

1U

0U

LCU Equivalent luminousexposure (lux hours)

0U 0 - 5 000

1U 5 000 - 30 000

2U 30 000 - 45 000

3U 45 000 - 75 000

4U 75 000 - 100 000

LCS Equivalent luminousexposure (lux hours)

0S Below 60 000

1S 60 000 - 100 000

2S 80 000 - 240 000

3S 200 000 - 340 000

4S Above 340 000

LightCheck®S

LightCheck®U

Page 10: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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In-situ exposures

Page 11: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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In-situ exposures

Investigation of different aspects:

• Simultaneous exposure of LightCheck® prototypes and Blue Wool Standards with monitoring of illuminance, T and rH (ELSEC IrLog data-loggers)

• Corroborate laboratory experiments

• Suitability / limitations due to the respective operational ranges

• Use of the Reference Colour Scales for quantitative assessment of Light Dose

• Influence of seasonal / environmental variations

Page 12: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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Selected results – Uffizi Gallery, summer 2003

data-logger ELSEC

VIS light, UV, T, rH

LCUBWS1

LCS

“Maestà”, Giotto (c.1310)

Site 1. Giotto roomNo windows, 100% artificial lightStable lighting conditionsHighly frequented by public

Site 2. Geographic maps roomLarge windows with curtains, almost 100% natural lightwide illuminance fluctuationMost often closed to public

Page 13: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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Uffizi gallery - "Geographic maps" room

measurement time30 days 45 days 90 days

∆0

5

10

15

20

25

30

35

40

45

50

Geographic maps: Imean 100 lx - Imax 830 lxUVmean 6.4 mW/Lm (UVmax 42 mW/Lm) T 30°C (Tmin 27°C – Tmax 32°C)rH 60% (rHmin 42% - rHmax 90%)

LCU: saturation within 1st monthLCS: visible fading after 1st month(not reached saturation at 3rd month)BWS 1: visible fading after 3rd month

LCU

LCS

BWS1

Uffizi gallery - "Giotto" room

measurement time30 days 45 days 90 days

∆E

0

5

10

15

20

25

30

35

40

45

50LightCheck U LigthCheck SBWS 1

Giotto room: Imean 11 lx - Imax 50 lxUV 0 mW/LmT 28°C (Tmin 26°C – Tmax 29°C)rH 53% (rHmin 35% - rHmax 67%)

Selected results – Uffizi Gallery

LCU: visible variation 1st month(not reached saturation at 3rd month)LCS: visible fading at 3rd monthBWS 1: under threshold

LCU

LCS

BWS1

Page 14: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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In-situ exposures - LCU

LightCheckU

Luminous exposure [klux*h]

0 20 40 60 80 100 120 140

∆E

0

10

20

30

40

50

Prague (June 03) London (June 03) Florence (June 03)Calibration Artif light Ageing 500lux Halogen

Calibration curveQTH lamp, 500 lx23°C, 50% rH

LCUs exposed for one month (June 2003)

LD of in-situ samples monitored with IrLog data-logger

All data points obtained in-situfall on the standard colour variation path of LCU as calibrated in the laboratory

Page 15: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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In-situ exposures - LCS

Calibration curve QTH lamp, 500 lx; T=23°C, 50% rH

LD of in-situ samples monitored with IrLog data-logger

∆E obtained is equal or higher to that obtained in laboratory⇒ More severe damage occursthan expected on the basis of calibration under stable conditions

Integrating effect of the overall environment impact on the evolution of the indicator’s colour

0 100 200 300 400 500 600 7000

5

10

15

20

25

30

35

40

Calibration curve 500lux in labFlorence (3th Camp.). Paris (3th Camp.) Prague (3th Camp.). Florence (4th Camp.) Prague (4th Camp.) London (4th Camp.) Berlin (5th Camp.)

Luminous exposure [klx*h]

∆E

/ 13090

Page 16: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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End user’s experience

Page 17: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LCU

Caim’s head. António Teixeira Lopes, 1866-1942

Sanguine. Facing artificial and natural light

The drawing has been chosen because:

a) It is signed by the artist and it has a great value;

b) It is considered as a very fragile and sensitive object;

c) The museum is planning a permanent exhibition and wants to assess the risk of damage if the drawing is placed near the north window.

Page 18: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LCUStart date / end date: 11.02.2005 / 04.03.2005 (22 days)

Light exposure: Artificial and natural light. North window and skylight.

Climatic conditions: 13 - 18ºC / 36 - 66% rH

Mitigation measures: double window, with curtains. Artificial light is always off except during visits

Hours of light exposure: 8 h/day of natural light + avg 1 h/day of artificial light (visits and maintenance routine)

Luxmeter reading : average on one day (11.02.05) 173 lux

Page 19: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LCU

hours of exposure: 8h/day; 56h/week

evaluation from colour chart: closest reading 2U = avg 35 000 lx.h [30 000 to 45 000] lx.h

= calculation dose / annual exposure in hours

173 lx × 56h/week = 9 688 lx.h/week

- 9 688 lx.h/week × 52 weeks = 503 776 lx.h/year (estimated from one punctual reading)

- 35 000 lx.h × 365 days / 22 days = 580 682 lx.h/year (estimated with LightCheck RCS) [497 727 – 746 591] lx.h/year

LCU Equivalent luminousexposure (lux hours)

0U 0 - 5 000

1U 5 000 - 30 000

2U 30 000 - 45 000

3U 45 000 - 75 000

4U 75 000 - 100 000

Page 20: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LCS

Flowering apple trees. Silva Porto, 1850-1893

Oil painting. Facing artificial and natural light

This painting has been chosen because:

a) It was painted by Silva Porto, very important Portuguese artist who played a prominent role in the introduction of the Naturalism in Portugal. He was a personal friend of António TeixeiraLopes. The Collection has only three Silva Porto paintings, all very valuable. This is the most valuable one.

b) a CCTV security system was installed which lead to the decision of leaving the artificial light on during the night to enable the guard to see.

Page 21: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LCS

Start date / end date: 30.11.2004 / 24.01.2004 (56 days)

Light exposure: Artificial and natural light. Facing south windows.

Climatic conditions: 12.5 – 18.9ºC / 36.5 – 69.5% rH

Mitigation measures : Double window, with curtains. Artificial light always off, except during visits… and night surveillance (!)

Hours of light exposure: 8 h/day of natural light + 11 h/day of artificial light (night period) + avg 1 h/day of artificial light (visits and maintenance routine)

Luxmeter reading: with natural light, the differences within one

day are very high

Difficult to choose a number(176 lux was chosen)

30.11.04Natural and artificial light

Page 22: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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LCS

hours of exposure: 20h/day; 140h/week

evaluation of the reading from colour chart: Between 3S and 4S, 340 000 lx.h

= calculation dose / annual exposure in hours

- 24 640 lx.h/week × 52 weeks = 1 281 280 lx.h/year (estimated from one punctual reading)

- 340 000 lx.h × 365 days / 56 days = 2 216 071 lx.h/year (estimated with LightCheck RCS)

LCS Equivalent luminousexposure (lux hours)

0S Below 60 000

1S 60 000 - 100 000

2S 80 000 - 240 000

3S 200 000 - 340 000

4S Above 340 000

Page 23: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

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Comments made by the end-users

For LCS

Fading occurred faster than expected from the punctual luxmeter reading.

The hues of colours of the RCS do not really match the actual coloursdisplayed by the LCS, especially for stages 3S and 4S, which makes the reading and the assessment of the luminous exposure difficult.

For both LC

It was a very useful exercise, it equipped the team with friendly and innovative tools to assess and to “prove” damage

Helped in taking decisions about lighting conditions, think about strategies to mitigate light damage, ensuring a better preventive conservation policy.

Page 24: LightCheck® light monitoring dosimeters - web.letras.up.ptweb.letras.up.pt/showcases.costD42/online_pubs_docs/Session VI/AnneLD... · in-field halo exp (avg 40 lux) ... LCS Equivalent

page 24

Thank you!


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