Literature Review
Introduction
Graph 1: In this graph, the x-axis represents time and the y-axis represents average global temperature changes
Graph 2: In this graph, the x-axis represents time and the y-axis represents the million metric tons of carbon produced a year from fossil fuels.Due to the increase in carbon dioxide concentration in
the earth’s atmosphere, global temperatures have risen steadily and could rise as much as 4ºC in the next
decade. (Cox, 2000) Lipids in the form of triglycerides can react with methanol to form methyl esters (biodiesel) and glycerol (Hossain, 2008).
Picture 1 – Transesterfication Reaction
Chart 1 – Comparison of Sources of Triglycerides for Biodiesel
Algae yields the largest amount of oil for the smallest percentage of cropping area (Christi, 2007).
PurposeThe purpose of this experiment was to determine the effects of an acid, base, or enzyme catalyst on the fuel produced by a transesterification reaction between methanol and algal oilHypotheses1(a) – The acid catalyst will make significantly more biodiesel that is significantly more pure than that of the other catalysts2(a) – The enzyme catalyst will make significantly more biodiesel that is significantly more pure than that of the other catalysts3(a) – The base enzyme catalyst will make significantly more biodiesel that is significantly more pure than that of the other catalysts
Pictures 2&3: Sterile cultures of Nannochloropsis sp. were maintained in 1L Erlenmeyer Flasks and 40mL test tubes
Picture 5: Algae being farmed on a large scale. Algae can be grown in otherwise unarable land as shown
Graph 3: Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification. The x-axis represents time and the y-axis represents the percent of esters converted to biodiesel
Graph 4: Enzymatic production of biodiesel from cotton seed oil using t-butanol as a solvent. The x-axis represents time and the y-axis represents triglyceride conversion to biodiesel
Kulkarni (2006) and Royon (2007) found that a solid acid or an enzyme could be used to catalyze the transesterification reaction
Picture 4: The saponification reaction occurs when FFA’s in the triglyceride source react with a base catalyst, this reaction reduces the quality of biodiesel synthesized by transesterification
Chart 2 – Comparison of Algae Sources