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Loss Optimisation in Boilers

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    The Heat Balance and

    Efficienc of Steam Boilers

    1

     

    By : Debanjan Basak

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    The efficient utilization of fuel in steam boilersis primarily determined by the following three

    factors :

    Complete combustion of the fuel in thefurnace

     

    2

    Deep cooling of the combustion productsduring their passage through heatingsurfaces.

    Minimization of heat losses to theenvironment.

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    Heat absorbed by workingfluid in boiler :

    Heat content of superheated steamfrom boiler

    Heat content of reheated steam from

    3

     boiler

    Heat content of boiler blow- downwater

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    Heat in Fuel

    Heat in atomi sing steam

    Sensible he at in fuel

    INPUT Pulver iser or crusher power Boiler Circulating pump power 

    Primary air fan power 

    Recirculating gas fan power 

    Heat supplied by moisture in entering air 

    Heat in Final superheater steamHeat in desuperheater water 

    Heat in feedwater 

    Boundary envelope Heat in blowdown water  OUTPUT

     

    HEAT BALANCE IN STEAM GENERATOR

    4

    Heat in reheat s team outHeat in desuperheater water 

    Heat in reheat steam i n

    Unburnt carbon in a sh

    Heat in dry gas

    Moisture in fuel

    Moisture from burni ng hydrogen

    Moisture in ai r 

    LOSSES Heat in atomising steam

    Unburnt gases

    Radiation and convection

    Sensible he at in slag

    Heat in mill rejects Reference : PTC ; 4.1

    Sootblowing

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    Efficiency

    Input = Heat input

    Output = Input – losses

    5

    Efficiency = Input

    Output

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    The Heat balance Equation

    The distribution of the heat supplied tothe boiler as useful heat and lost heat is

    the basis for compiling the heat

    6

    balance of a steam boiler

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    The Heat Balance Equation

    Q = Q1 + (Q2 +Q3 + Q4 +Q5 + Q6) where :

    Q= available heat of burnt fuel

    7

    Q1= heat absorbed by working fluid 

    Q2 to Q6 = heat losses

    Dividing both sides by Q and expressing as a %age we get :100 = q1 +(q2 +q3+q4+q5+q6)

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    Methods of determining BoilerGross efficiency

    Direct method

    Inverse balance method

    8

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    The direct method

    Uses the heat balance equation

    Measures Q and Q1

    Method is insufficientl inaccurate

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      Accurate measurements of certainparameters like mass flow rate of steamand fuel,heating value of fuel etc is not

    possibleNot a preferred method

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    The inverse balance method

    Uses the equation

    Efficiency = 100 –(q2 +q3+q4+q5+q6)

    Determines the sum of heat losses

     

    10

    s more accurate met o s nce t e sum othe heat losses roughly constitutes 10% ofQ1.

     All the items can be reliably measured

    Is the SOLE method used for determiningefficiency

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    Heat Losses in Steam Boilers

    Item Symbol % as relative loss of Q

    Waste Gases q1 4 - 7

    Incomplete q2 0 – 0.5

    11

    Unburnt Carbon q3 0.5 - 5

    Cooling throughlining

    q4 0.2 - 1

    Pysical heat of

    removed slag

    q5 0 - 3

    Sum of heat losses 6 - 12

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    Chart depicting heat losses

    Waste gases

    Incomplete combstion

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    Unburnt carbon

    Cooling through lining

    Physical heat of 

    removed slag

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    13

    na ys s o eat osses nSteam Boilers

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    Dry Flue gas loss

    Is the largest component of heat loss

    It depends on the absolute difference

    between the enthal of waste ases

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     and the enthalpy of cold air supplied.

    The enthalpy of waste gases dependson the exit temperature of waste gases

    and its volume.

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    Dry Flue gas loss

    It is the heat lost to the atmosphere bydry component of flue gas

     Also referred as stack loss

    15

     Carbon and sulphur in coal burn to formthe dry component of flue gas

    Carbon can burn to form either CO or

    CO2

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    Components of Dry Flue gas

    Carbon- Dioxide

    Carbon Monoxide

     

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     Nitrogen

    Sulphur Dioxide – can be neglected forIndian coals

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    Seigert Formula for estimation of Dry Fluegas loss

    % loss = K ( T – t )

    % CO2

    17

    K is a constant whose value are taken as :

    For anthracite : 0.68

    For Bituminous coal : 0.63

    For coke : 0.70

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    Wet flue gas loss

    Wet products of combustion are obtainedfrom the following components in fuel :

    Moisture

     

    18

     –1 Kg of hydrogen burn to form 9 Kg of

    moisture

    The heat lost with the mass of the water

    vapour along with flue gas to the atmosphereis known as wet flue gas loss

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    Sensible Heat of water vapour

    This is the amount of sensible heatabsorbed by moisture in coal

    Is calculated b :

    19

     ( Wet FG loss – (GCV – NCV)) KJ/Kg fuel

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    Moisture in combustion air

    This is the amount of heat absorbed bythe moisture present in cold air

    However this loss is ver small and is

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     normally not calculated

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    Heat loss with waste gases

    By reducing the temperature of waste gases by 22degree cent it is possible to increase boiler efficiencyby 1%.

    he exit tem erature of waste ases de ends on

    21

     feed water temperature at economizer inlet and andcold air temperature at air heater inlet.

    The exit temperature depends on the moisturecontent of fuel used.A higher moisture content

    results in increase of heat loss for the same heatingsurface due to higher volume of combustion.

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    Heat loss with waste gases

     A cost economic approach is taken fordetermining the design optimal flue gas exittemperature.

     

    22

    ne o t e ma n cons erat ons n m t ng t eFGET is the low temperature acid corrosion inair preheaters.The waste gas temperature isgenerally kept within 140- 160 deg cent to

    prevent acid condensation.

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    Reasons for high FGET

    Improper soot blowing

    Deposition on furnace wall tubes

     

    23

     Low temperature at air heater inlet

    High moisture content of fuel

    High excess air ratioHigh air infiltration

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    Clean

    Tube

    1200ºC

     

    Scale

    Both side

    depositsSoot

    300ºC

    m t ng etaTemp of 450ºC

    200M

    Kcal/hr/m2150M

    Kcal/hr/m2

    155M

    Kcal/hr/m2

    120MKcal/hr/m2

    Typical Heat transfer and temperature drop across furnace tube

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    Heat loss with unburnt carbon

    In the combustion of solid fuels, unburnt cokeparticles are carried off from the combustionchamber by flue gases.

    Durin the short time the are resent in the hi h

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     temperature zone of the flame, these particles evolvevolatile mater but remain partially unburnt.

    Under normal operating conditions, these unburntcarbon loss may range from 0.5% to 5%

    More the VM of fuel less is the heat loss.

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    Heat loss with unburnt carbon

    This loss can be divided into :

    Carry over loss

    Loss with slag or bottom ash

     

    26

    e carry over oss s muc pre om nant overthe loss with slag.

    The carry over loss is determined by thecarbon content in Fly ash samples collected

    from ESP hoppers.The slag loss is determined by the carboncontent in bottom ash samples.

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    Heat loss with unburnt carbon

    The carry over loss depends on :

    Excess air ratio

     

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    The slag loss depends on :

    Improper fineness of pulverized fuelfrom mills

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    Heat loss by Incompletecombustion

    The products of combustion containgaseous combustible substances suchas CO,H2 or CH4.

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    Their afterburning beyond the boilerfurnace is practically impossible sincethe temperature of gases and

    concentrations of combustiblecomponents and oxygen are too low.

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    Heat loss by Incompletecombustion

    The heat that may be produced by afterburningthese components constitutes the heat loss dueto incomplete combustion.

     

    29

     the concentration of CO and to a lesser extentH2 in flue gas.

    However analysis for incomplete combustionshould always be done for all components of

    flue gas since even a slight quantity of CH4 mayhave a noticeable effect .

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    Heat loss by Incompletecombustion

    Heat loss due to incomplete combustionsubstantially depends on excess air ratio andboiler load conditions.

     

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    eoret ca y, t oroug nterm x ng o ueand oxygen ensures that this heat loss maytake place only for K

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    Heat loss by Incompletecombustion

    With reduced load conditions, the exitrate of fuel and air through the burnersdecreases causing improper mixing

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    which results in increase in heat loss.

     Also the temperature of the combustionzone decreases with reduced load

    causing an increase in incompletecombustion

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    Unaccounted losses

    Radiation loss

    Loss due to unburnt volatilehydrocarbons

     

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    Loss due to combination of carbon andwater-vapour

    Mill rejection

    Physical heat carried by bottom and fly-ash

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    Heat Loss by Radiation

    Since the temperature of the boiler liningsand casings are higher than the surroundings,they give up heat to the environment.

     

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    g er s t e temperature o t e n ngs ancasings higher is this heat loss.

    In general the boiler casings should beinsulated in such a way that the average

    temperature of the casings is not more than55 degree cent.

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    Typical summary of Radiation and

    Unaccounted losses

    BoilerRating

     Approximate Range in %

    020 0.6 – 1.7

    34

    050 0.38 – 1.2

    060 0.35 – 1.15

    100 0.3 – 1.0

    200 0.25 – 0.93

    500 0.2 – 0.88

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    Heat Loss by Cooling

    In rough calculations, the heat flux from theboiler surfaces to the surroundings is taken atan average level of 200 – 300 W/m2

     

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    t ncreas ng o er power, t e a so uteand relative heat loss q5% becomes lower asthe total heat release and the volume ofcombustion products increase more quickly

    than the area of exposed boiler surfaces.

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    Heat loss with physical heat ofslag

    The slag removed from the bottom of a boilerfurnace has rather high temperature andpossesses a significant amount of heat.

     

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     the slag bath and is lost irreversibly

    In dry bottom furnaces the temperature ofslag is 600- 700 deg cent.

    In slagging bottom furnaces the temperatureof flowing slag is 1400 – 1600 degree cent.

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    Heat loss with physical heat ofslag depends on

    Total ash content of fuel

     

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     furnace

    Enthalpy of slag

    Method of removal of slag fromfurnace.

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    Theoretical Air

    It is the quantity of air required by afuel which will provide just sufficientoxygen for complete oxidation of the

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     fuel

    It is also known as the stoichometric air

    requirement

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    Quantity of theoretical air

    The theoretical air is calculated from the

    Ultimate analysis of fuel by the formula :

    39

    4.31 x 83

    C 8 ( H -O

    8) S Kg/Kg of fuel

    •The value within the bracket denotes the quantity of

    oxygen reqd.

    •The factor 4.31 gives the amount of air required to supply

    this oxygen

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    Excess Air

    The actual amount of air required for completeburning of a fuel is always more than the theoreticalair.

     

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    his additional quantity of air required over thetheoretical air is known as excess air

    Present designs allow for 20% excess air for coalfired boilers

    THE SUM OF THEORETICAL AIR AND EXCESS AIR ISTHE TOTAL AIR REQUIOREMENT FOR A BOILER 

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    Reasons for excess air

    To overcome the uncertainties in thefuel-air mixing process

    o ensure intimate mixin of fuel and

    41

     oxygen at point of injection

    To account for errors in ultimateanalysis of fuel

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    Quantity of excess air

    Excess air =

    (O2 % X100)/ (21 – O2%)

    42

    OR 

    (CO2 %(max) x 100)/CO2% - 100

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    Conclusion

    The quantity of excess air adverselyaffects boiler efficiency

    he uantit of excess air needs to be

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     optimized for achieving maximumefficiency of boiler

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    Monitoring of excess air

    By residual carbon dioxide in flue gas

    By residual oxygen in flue gas

    44

    By residual carbon- monoxide influe gas

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    12

    11

    Total Loss

    10

    9 Optimum Total air 

    8 Dry Gas loss

    7

       o  s  s   %

    Optimisation of To tal Air supply

    45

    6

    5

    4

    3  Aux . Pow er 

    Unburnt Gas

    2

    1 Comb. In ash

    14 15 16 17

    Carbon- Dioxi de %

       B  o   i   l  e  r

     

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    Optimisation of Total Air

    • Unburnt gas (primarily CO) is formed just a littlehigher than the optimum CO2

    • Measurement of CO is a better method of

    46

     • Oxygen measurement in flue gas can be misleading

    due to air ingress

    • Modern combustion control utilizes CO measurement

    in addition to Oxygen measurement

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    Saturation

    700

    600

     Air Defici ent Air Rich

    500

    400

    Graph Depicting variation of Oxygen with Carbon Monoxide in Flue gas

     

       f  a  n   d   i  s  c   h  a  r  g  e

    47

    Ideal Operating Point

    300

    200

    100

    5 6 7 8 At ID Discharge

    1 2 3 4 5 At AH Inlet

      p  p  m   v

      o   l   C   O

      a   t   I   D

     

    % Oxygen In Flue gas

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    6 Mill s equally loaded

    6 Mills unequally loaded

    500

    5 Mills equally loaded

    400

     

       i  s  c   h  a  r  g  e

    Effect of mill operation on CO breakpoint for a 500 MW PF boiler 

    48

    300

    200

    100

    2 3 4 5

      p  p  m   v

      o   l   C   O

      a   t   I   D   f  a  n

       d

     

    % Oxygen In Flue gas at Air Heater Inlet

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    CO2 %

    CO2 %

       I  n  c  r  e  a  s   i  n  g

    Trend o f Boiler Gases with variations in excess air 

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    O2 %

    SO2 ppm

    -20 -10 0 10 20Excess Air %age

       D  e  c  r  e  a  s   i  n  g

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