MANOIR PETROCHEM ® Heat-resistant alloys for hydrocarbon processing

MANOIR INDUSTRIES

www.manoir-industries.com MANOIR PETROCHEM®

Heat-resistant alloys for hydrocarbon processing

MA

NO

IR PETROC

HEM

®

Manoir Petrochem12, rue des Ardennes - BP 8401 – PITRES

27108 VAL DE REUIL CEDEXTel.+33 2 32487200 – Fax +33 2 32495726

Hi-Tech Fabrication LtdBretby Business Park - Ashby Road

Burton on Trent – Staffordshire DE15 0YZTel. +44 (0) 1283 817902 – Fax +44 (0) 1283 817909

Manoir Petro India LimitedHead office address : Universal Business Park

602, B – Wing – Chandivali Farm Road – Andheri (E)Mumbai – 400 072, India

Tel : +91 9920167 307 - Fax: +91 22 22082113Manoir Petro India Limited

造⼚Casting Plant: 造⼚地址：烟台市芝罘区只楚南路Casting Factory address: Zhichu South Road, Zhifu district, Yantai

: 6851895, 6851881 真: 6851895 Tel: 6851895, 6851881 Fax: 6851895

MMG 4 - MARS 09........................... 1

Owned by Sun Capital, an American

investment fund, the Manoir Industries

Group, a specialist in steel transfor-

mation through casting and forging, has

been structured into Business Units.

While the Aerospace & Specialties

Business Units consist of 4 forges and 3

foundries, the petrochemical BU, known

as Manoir Petrochem has grown in

strength through significant internal and

external development:

• The plant of Pitres, France, well known

historically for having given its name to

the Group, is still positioned as the

leading plant in the Group and focuses

on the production of sophisticated

alloys. The current boom observed in

the nuclear market has also reinforced

the position of this plant for being one

of the most knowledgeable companies

in respect of QA systems for the casting

industry. This facility is dedicated to the

manufacture of high integrity products

and recently developed alloys (as

detailed in this document) which have

gained market acceptance since their

introduction in 2005.

• Manoir Yantai, in China, is now a well

established manufacturer for the

petrochemical industry and has

supplied reformer tubes and ethylene

coils direct to engineering companies

and end users. The production has

been transferred as planned to a brand

new facility and operates with

production tools similar to the ones

established in France.

• The most recent acquisition of Manoir

Industries and addition to Manoir

Petrochem is Hi-tech Fabrication, a

fabrication shop located near to

Birmingham, UK. HTF is a small but

extremely capable shop when it comes

to complex welding in various alloys

and processes. This unit significantly

enhances our product portfolio

through the production of cold inlet &

outlet systems, transfer lines, and other

fabricated components, including

convection banks. This addition to the

Group reinforces our objective to

become a major supplier of a wide

package of spares for furnaces in the

petrochemical industry.

• The latest development of our Group is

the creation of a JV on the outskirts of

Mumbai, India which will lead to the

building of another fabrication shop. A

sales office is currently in place and the

aim of this unit is to service the Indian

and Middle East markets, with tubes

being cast in France and China and

assembled in India.

This brochure will provide you with

an update on the mechanical properties

of our current alloy portfolio, as well as

the latest alloy releases available.

Visit us on www.manoir-industries.com

for the latest updated news.

Thank you.

HEAT-RESISTANT ALLOYS FOR HYDROCARBON PROCESSING

2 .................. MMG 4 - MARS 09

MMG 4 - MARS 09........................... 3


4 .................. MMG 4 - MARS 09

MMG 4 - MARS 09........................... 5


6 .................. MMG 4 - MARS 09

MA

NA

UR

ITE

50/5

0Nb

XTM

XTM

low

C40

XO

XM

XO

R40

XX

O36

X90

0B90

020

Tem

per

atu

re L

imit

°F16

52**

2192

1976

2192

2015

*20

15*

2102

2102

1922

1976

1835

1850

2102

°C90

0**

1200

1080

1200

1100

*11

00*

1150

1150

1050

1080

1000

1010

1150

Tub

es

Rad

ian

tEl

bo

ws

sect

ion

Rad

ian

t co

ilh

ang

ers

Co

nve

ctio

nTu

bes

sh

eets

sect

ion

& b

rack

ets

Tran

sfer

lin

elin

e

Rad

ian

tTu

bes

sect

ion

Co

nve

ctio

nTu

bes

sh

eets

sect

ion

& b

rack

ets

Tran

sfer

Man

ifo

lds

line

Rad

ian

tTu

bes

Sect

ion

Stat

icca

stin

gs

Co

nve

ctio

nTu

bes

sh

eets

sect

ion

& b

rack

ets

Tran

sfer

lin

elin

e

STEA

MC

RA

CK

ING

REF

OR

MIN

GH

ydro

gen

,am

mo

nia

,m

eth

ano

l)

DR

I

Main

hig

h t

em

pera

ture

ap

pli

cati

on

s

* fo

r sp

ecif

ic a

pp

licat

ion

s, a

lim

it o

f 11

35°C

(20

80°F

) ca

n b

e g

uar

ante

d**

in s

ever

e fu

el a

sh e

nvi

ron

men

ts

MMG 4 - MARS 09........................... 7

Man

oir

Ind

ust

ries

Addi

tions

Ap

plic

atio

ns

Mai

n F

eatu

res

des

ign

atio

nEN

102

95C

Mn

SiN

iC

rC

o

Au

sten

itic

All

oys

18 -

91.

4825

HF0.

25/0

.40

0.70

/1.2

51.

00/1

.75

9.5/

11.5

18/2

1Ti

, Nb

Man

aurit

e 20

1.48

48HK

0.30

/0.5

51.

00/2

.00

1.00

/2.5

018

/24

23/2

8

Man

aurit

e 24

/24

Nb

1.48

550.

25/0

.50

0.50

/1.5

00.

50/2

.00

23/2

523

/25

Nb

Man

aurit

e 36

X1.

4852

HP0.

35/0

.60

1.00

/1.5

01.

00/2

.00

33/3

823

/28

Nb

Man

aurit

e 35

-25W

0.35

/0.6

00.

70/1

.25

1.00

/2.0

033

/28

21/2

8W

Man

aurit

e XM

1.48

520.

35/0

.60

0.50

/1.5

01.

00/2

.00

33/3

823

/28

Man

aurit

e XO

R0.

35/0

.50

0.50

/1.5

01.

00/2

.00

33/2

823

/28

Man

aurit

e 40

X0.

35/0

.60

0.50

/1.5

01.

00/2

.00

38/4

228

/32

Man

aurit

e XT

M1.

4889

0.40

/0.6

00.

50/2

.00

1.00

/2.0

043

/48

34/3

7

Au

sten

itic

All

oys

wit

h a

lum

iniu

m

Man

aurit

e XO

0.35

/0.6

00.

50/1

.50

1.00

/2.0

033

/28

23/2

8

Man

aurit

e 40

XO0.

35/0

.60

0.50

/1.5

01.

00/2

.00

38/4

228

/32

Nb, T

i,an

dot

hers

Ta, T

i,an

dot

hers

Al, T

a, T

i,an

dot

hers

Al, T

a, T

i,an

dot

hers

Nb, T

i,an

dot

hers

Nb, T

i,an

dot

hers

Tube

shee

ts fo

rpe

troc

hem

ical f

urna

ces

Refo

rmin

g an

d et

hyle

ne c

rack

ing

tube

sCa

st fi

ttin

gs a

nd tu

be sh

eets

Refo

rmer

tube

san

d fu

rnac

e pa

rts

Amm

onia

& m

etha

nol f

urna

ces

Refo

rmin

g an

d cr

acki

ng c

oils

Amm

onia

& m

etha

nol f

urna

ces

Refo

rmin

g an

d cr

acki

ng c

oils

Amm

onia

& m

etha

nol f

urna

ces

Refo

rmin

g an

d cr

acki

ng c

oils

Amm

onia

& m

etha

nol f

urna

ces

Refo

rmin

g co

ils

DRI r

adia

tion.

Cra

ckin

g co

ilsHi

gh c

arbu

rizin

g an

d m

etal

dus

ting

atm

osph

eres

DRI r

adia

tion.

Cra

ckin

g co

ilsHi

gh c

arbu

rizin

g an

d m

etal

dus

ting

atm

osph

eres

DRI r

adia

tion.

Cra

ckin

g co

ilsHi

gh c

arbu

rizin

g an

d m

etal

dus

ting

atm

osph

eres

DRI r

adia

tion.

Ref

orm

ing

& Cr

acki

ngco

ils H

igh

carb

urizi

ng a

nd m

etal

du

sting

atm

osph

eres

Oxy

datio

n re

sista

nce

up to

800

°C (1

472°

F)

Resis

tanc

e to

cre

epup

to 9

80°C

(180

0°F)

Impr

oved

stre

ss ru

ptur

e, o

ver H

K 40

. Bet

ter d

uctil

ityat

ope

ratin

g te

mpe

ratu

re w

ithou

t im

paire

d w

elda

bilit

y re

sista

nce

to o

xyda

tion,

car

buris

atio

n an

d th

erm

al fa

tigue

High

cre

ep re

sista

nce

and

cree

p du

ctili

tyGo

od c

arbu

rizat

ion

and

oxid

atio

n re

sista

nce

Good

wel

dabi

lity

afte

r age

ing

High

car

buriz

atio

n an

d ox

idat

ion

resis

tanc

eup

to 1

080°

C (1

976°

F). G

ood

cree

pst

reng

ht a

nd g

oodc

reep

stra

in ra

te

Supe

rior c

reep

resis

tanc

e an

d cr

eep

duct

ility

Impr

oved

car

buriz

atio

n an

d ox

idat

ion

resis

tanc

e up

to 1

100°

C (2

012°

F)

Supe

rior c

reep

resis

tanc

e to

XM

with

sam

e pr

oper

ties f

or c

reep

duc

tility

, car

buriz

atio

n an

d ox

idat

ion

resis

tanc

e.

Supe

rior c

arbu

rizat

ion

and

oxid

atio

nre

sista

nce

to X

M w

ith sa

me

cree

pre

sista

nce

and

cree

p du

ctili

ty

Supe

rior c

arbu

rizat

ion

and

oxid

atio

nre

sista

nce

to 4

0X w

ith sa

me

cree

pre

sista

nce

and

cree

p du

ctili

ty

Supe

rior c

arbu

rizat

ion

and

oxid

atio

n re

sista

nce

with

very

hig

h cr

eep

stre

ngh

and

cree

p du

ctili

ty. O

pera

ting

t°up

to 1

150°

C fo

r car

buriz

atio

n re

sista

nce.

Supe

rior c

arbu

rizat

ion

and

oxid

atio

n re

sista

nce.

High

cree

pstr

engh

and

cree

p du

ctilit

y. Op

erat

ing

t°up

to 1

160°

C(2

120°

F) fo

r cra

ckin

g fu

rnac

es. A

lso re

form

ing

appl

iance

re

sista

nce

to co

ntam

inat

ion

by h

eavy

gas

oil (

S, Na

, V)

No

min

al C

om

po

siti

on

%A

STM

A29

7/A

351

Sim

ilar

grad

e


8 .................. MMG 4 - MARS 09

Man

oir

Ind

ust

ries

Addi

tions

Ap

plic

atio

ns

Mai

n F

eatu

res

des

ign

atio

nEN

102

95C

Mn

SiN

iC

rC

o

Au

sten

itic

All

oys

Man

aurit

e 50

W2.

4879

0.35

/0.5

51.

00/1

.50

1.00

/2.0

045

/52

25/3

2W

Man

aurit

e 50

/50N

b2.

4680

0.05

/0.1

00.

30/0

.50

0.70

/1.0

048

/52

48/5

2Nb

Man

aurit

e 75

2.48

15HX

0.15

/0.3

00.

70/1

.25

1.00

/2.0

065

/76

14/1

9

Man

aurit

e 90

01.

4859

0.06

/0.1

51.

00/1

.50

0.75

/1.5

029

/37

16/2

2Nb

Man

aurit

e 90

0 B

0.10

/0.1

81.

00/1

.50

1.00

/1.5

033

/37

24/2

7Nb

Au

sten

itic

all

oys

wit

h c

ob

alt

Man

aurit

e 35

K1.

4869

0.40

/0.6

00.

50/1

.25

1.20

/2.0

033

/37

24/2

8W

Man

aurit

e 50

WK

0.40

/0.5

50.

50/1

.50

1.00

/1.7

547

/49

27/2

9W

Au

sten

itic

all

oys

wit

h t

un

gst

en

Man

aure

20.

15/0

.40

0.50

/1.5

0<

1.50

48/5

232

/54

W: 1

2/14

%

Elbo

ws i

n pe

troc

hem

ical f

urna

ces.

Tube

shee

ts a

nd su

ppor

ts.

Chris

tmas

tree

supp

orts

.

Tube

shee

ts a

nd tu

be su

ppor

ts.

Spec

ial p

etro

chem

ical c

ompo

nent

s

For p

arts

loca

ted

outsi

de fu

rnac

es e

.g.

refo

rmer

furm

ace

man

ifold

s, tra

nsfe

rline

s, py

rolys

is fu

rnac

e cro

ssove

rs

Used

at h

ighe

r tem

pera

ture

s e.g

. fo

r par

ts in

side

furn

aces

Refo

rmer

tube

s for

pet

roch

emica

lap

plia

nces

at h

igh

tem

pera

ture

Amm

onia

furn

aces

Tub

e sh

eets

.

Sim

ilar t

o M

anau

rite

50 W

but

use

dat

hig

her t

empe

ratu

res.

Radi

ant

tube

s. Tu

be su

ppor

ts

Tube

shee

ts a

ns su

ppor

ts -

furn

ace

part

s The

rmow

ells.

Ope

ratin

g at

ele

vate

d te

mpe

ratu

res i

n cr

acki

ng

proc

ess.

Very

goo

d re

sista

nce

to o

xida

tion

up to

1200

°C (2

192°

F). E

xcel

lent

cre

ep re

sista

nce.

Resis

tanc

e to

oxi

datio

n an

d fu

el a

sh c

orro

sion.

Good

age

d du

ctili

ty

Good

cre

ep st

reng

th. H

igh

ther

mal

shoc

k re

sista

nce.

Good

duc

tility

aft

er a

gein

g. O

pera

ting

tem

pera

ture

up to

100

0°C

(183

2°F)

Sim

ilar p

rope

rtie

s to

MAN

. 900

with

hig

her

oxid

atio

n an

d ca

rbur

izat

ion

resis

tanc

e : o

pera

ting

tem

pera

ture

exc

eedi

ng 1

000°

C (1

832°

F°

With

stan

ds h

igh

tem

pera

ture

s up

to 1

245°

C (2

300°

F). G

ood

resis

tanc

e to

hot

cor

rosio

n.

Impr

oved

cre

ep re

sista

nce

with

resp

ect t

o M

anau

rite

50 W

. Ope

ratin

g te

mpe

ratu

re u

p to

1200

°C (2

192°

F). G

ood

resis

tanc

e to

car

buriz

atio

n.

Cree

p an

d ox

idat

ion

resis

tanc

e up

to 1

300°

C (2

372°

F)

No

min

al C

om

po

siti

on

%

AST

M

Sim

ilar

grad

e

MMG 4 - MARS 09........................... 9

18-9 10

MANAURITE 20 12

MANAURITE 900 14

MANAURITE 900 B 22

MANAURITE 36 X 24

MANAURITE XM 26

MANAURITE 35-25 W 36

MANAURITE XTM 38

MANAURITE 50 W 44

MANAURITE 50/50 Nb 45

MANAURITE 75 46

MANAURE 2 48

MANAURITE 35 K 49

MANAURITE 50 WK 50

MANAURITE 24/24 Nb 51

Latest release MANAURITE 40X 54

MANAURITE XO 62

MANAURITE 40XO 68

MANAURITE XOR 78

Comparative COMPARATIVE INFORMATION 85

data

PhysicalandMechanicalproperties

10 ................ MMG 4 - MARS 09

18-9

MMG 4 - MARS 09...........................11

18-9SHORT TIME TENSILE PROPERTIES

18-9SHORT TIME TENSILE PROPERTIES

18-9

12 ................ MMG 4 - MARS 09

MANAURITE 20

MMG 4 - MARS 09...........................13

MANAURITE 20CREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

14 ................ MMG 4 - MARS 09

MANAURITE 900

MMG 4 - MARS 09...........................15

MANAURITE 900

16 ................ MMG 4 - MARS 09

MANAURITE 900

MMG 4 - MARS 09...........................17

MANAURITE 900

18 ................ MMG 4 - MARS 09

MANAURITE 900

MMG 4 - MARS 09...........................19

MANAURITE 900CREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

20 ................ MMG 4 - MARS 09

MANAURITE 900

MMG 4 - MARS 09...........................21

MANAURITE 900

22 ................ MMG 4 - MARS 09

MANAURITE 900 B

MMG 4 - MARS 09...........................23

MANAURITE 900 BCREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

24 ................ MMG 4 - MARS 09

MANAURITE 36X

MMG 4 - MARS 09...........................25

MANAURITE 36XCREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

26 ................ MMG 4 - MARS 09

MANAURITE XM

MMG 4 - MARS 09...........................27

MANAURITE XM

28 ................ MMG 4 - MARS 09

MANAURITE XM

MMG 4 - MARS 09...........................29

MANAURITE XMCREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

30 ................ MMG 4 - MARS 09

MANAURITE XM

MMG 4 - MARS 09...........................31

100

Mp

a 10 1 10-6

10-5

10-3

10-2

10-1

Cre

ep r

ate

(%h

r-1 )

10-4

Ksi

1000

°C -

183

2°F

1050

°C -

192

2°F

1100

°C -

201

2°F

1150

°C -

210

2°F

950°

C -

174

2°F

Stress Mpa

MANAURITE XMCREEP RATES

32 ................ MMG 4 - MARS 09

MANAURITE XM

MMG 4 - MARS 09...........................33

MANAURITE XMPACK CEMENT CARBURIZATION TEST

(850°C - 1150°C)

34 ................ MMG 4 - MARS 09

MANAURITE 36 XS

MMG 4 - MARS 09...........................35

MANAURITE 36XSCREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

36 ................ MMG 4 - MARS 09

MANAURITE 35-25 W

MMG 4 - MARS 09...........................37

MANAURITE 35-25 WCREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

38 ................ MMG 4 - MARS 09

MANAURITE XTM

MMG 4 - MARS 09...........................39

MANAURITE XTM

40 ................ MMG 4 - MARS 09

MANAURITE XTM

MMG 4 - MARS 09...........................41

MANAURITE XTMCREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

42 ................ MMG 4 - MARS 09

MANAURITE XTM

MMG 4 - MARS 09...........................43

MANAURITE XTMCARBURIZATION RESISTANCE DATA

44 ................ MMG 4 - MARS 09

MANAURITE 50 W

MMG 4 - MARS 09...........................45

MANAURITE 50/50 Nb

46 ................ MMG 4 - MARS 09

MANAURITE 75

MMG 4 - MARS 09...........................47

MANAURITE 75

48 ................ MMG 4 - MARS 09

MANAURE 2

MMG 4 - MARS 09...........................49

MANAURITE 35 K

50 ................ MMG 4 - MARS 09

MANAURITE 50 W K

MMG 4 - MARS 09...........................51

MANAURITE 24/24 Nb

MMG 4 - MARS 09...........................53

LATESTRELEASE

54 ................ MMG 4 - MARS 09

MANAURITE 40X

MMG 4 - MARS 09...........................55

MANAURITE 40X

56 ................ MMG 4 - MARS 09

MANAURITE 40X

MMG 4 - MARS 09...........................57

MANAURITE 40XCREEP RUPTURE DATA (95% CONFIDENCE LEVEL)

58 ................ MMG 4 - MARS 09

MANAURITE 40X

MMG 4 - MARS 09...........................59

MANAURITE 40XCREEP RATES

60 ................ MMG 4 - MARS 09

MANAURITE 40X

MMG 4 - MARS 09...........................61

MANAURITE 40XSIMULATED CARBURIZATION TEST IN SOLID CEMENT

(850°C - 1150°C)

62 ................ MMG 4 - MARS 09

MANAURITE XO

PHYSICAL PROPERTIES

Specific gravity: 0.29 lb/inch3 (8.02 kg/dm3) Coefficient of expansion

Melting point: 1350°C (2460°F) in/in °F (10-6) mm/mm/°C (10-6)

From 70° F to 1560°F: 10,21 20°C to 850°C: 18.5

From 70° F to 1740°F: 10,4 20°C to 950°C: 18.9

Thermal conductivity From 70° F to 1920°F: 10,6 20°C to 1050°C: 19.3

At 1050°C (1922°F): 30 W/m.°C From 70° F to 2100°F: 10,9 20°C to 1150°C: 19.7

(17 Btu/h.ft.°F)

At 20°C (68°F): 10.5 W/m.°C

(6 Btu/h.ft.°F)

Specific heat Young modulus

Temperature Cal/g. °C or J/kg. °C

°C °F BTU/lb. °F

20 68 0,112 469

100 212 0,117 489,9

200 392 0,124 519,3

300 572 0,130 544,4

400 752 0,137 573,7

500 932 0,143 598,8

600 1112 0,150 628,2

700 1292 0,157 657,5

800 1472 0,163 682,6

900 1652 0,170 711,9

1000 1832 0,177 741,2

1100 2012 0,183 766,4

1200 2192 0,190 795,7

Temperature

°C °F MPa ksi

20 68 161,900 23,470

100 212 155,000 22,475

200 392 147,150 21,337

300 572 138,000 20,010

400 752 133,400 19,343

500 932 126,000 18,270

600 1112 117,700 17,066

700 1292 111,000 16,095

800 1472 106,000 15,360

900 1652 101,000 14,650

1000 1832 97,100 14,080

1100 2012 93,200 13,510

MMG 4 - MARS 09...........................63

MANAURITE XO

MECHANICAL PROPERTIES

1 • At room temperature(minimum values)

Ultimate tensile strength: 450 MPa 65 000 psi

Yield strength: 250 MPa 35 500 psi

Elongation (on 4d): 8% for centrifugally pipes

2 • Short time tensile test at various temperatures on as cast material

Temperature U.T.S. Y.S. E

°C °F MPa ksi MPa ksi %

750 1382 333 48,4 157 22,8 16

800 1472 265 38,2 147 21,3 20

850 1562 196 28,4 137 19,9 22

900 1652 147 21,3 118 17,1 30

950 1742 118 17,1 88 12,8 32

1000 1832 93 13,5 78 11,4 40

1050 1922 72 10,7 67 10,0 40

1100 2012 57 8,8 52 8,0 40

CREEP PROPERTIES

Long time creep rupture data

64 ................ MMG 4 - MARS 09

MANAURITE XO

Manaurite XO 100 000 hrs creep rupture strength

Temperature Average Minimum values ° C values (MPa) (MPa)

850 44.5 38.2

875 36.6 31.8

900 30.3 26.6

925 24.8 21.7

950 20.1 17.6

975 16.3 14.2

1000 13.2 11.7

1025 10.4 9.1

1050 8.2 7.1

1075 6.4 5.4

1100 4.8 4.1

MMG 4 - MARS 09...........................65

3031

3233

3435

3637

3839

40

100 10 1

Var

iab

les

Mp

a

100

000

hr

900

1000

1100

°C °F20

0018

00

LMP

= T

/100

0(22

.96

+ lo

g(t

)) T

: °K

t: h

r

1600

Ave

rag

e St

ress

Min

imu

m S

tres

s

MANAURITE XOCREEP RUPTURE STRENGTH (95% CONFIDENCE LEVEL)

66 ................ MMG 4 - MARS 09

2.0

1.8

1.6

1.4

1.2

1.0

0.8

0.6

0.4

0.0

00.

51

1.5

22.

53

3.5

4

Dep

th f

rom

ID (

mm

)

Δ Carbon (%)

MANAURITE XOCARBURIZATION TEST 850 - 1150° C

MMG 4 - MARS 09...........................67

MANAURITE XO

0.00

5

0.00

4

0.00

3

0.00

2

0.00

1

01

Nu

mb

er o

f cy

cles

Cyc

le :

hea

t u

p =

300

° C

per

hr

/ so

akin

g t

ime

= 1

0 h

r / c

oo

ling

do

wn

= 3

00°

C p

er h

r

23

47

67

89

10

Δm per surface unit (g/cm2)

Tem

per

atu

res

1000

° C

1100

° C

CYCLING OXIDATION IN AIR:TOTAL WEIGHT INCREASE PER SURFACE UNIT

OXYDATION RESISTANCE

1 • Oxydation processAfter ethanol cleaning, samples are weighed (3 times)

Cycle: Heat up : 300° C.h-1

Soaking time : 10 hours

Cooling : 300° C.h-1

After cycle, sample (with scale eventually) is weighed.

See curves obtained for weight increase hereafter.

68 ................ MMG 4 - MARS 09

MANAURITE 40XO

PHYSICAL PROPERTIES

Specific gravity:

at 20°C (68°F) : 0.292 Ib/inch3 (8.05 kg/dm3) Coefficient of expansion

Melting point: 1340°C (2440° F) 106.(°K)-1

68°F to 1112°F - 20°C to 600°C: 16.1

68°F to 1292°F - 20°C to 700°C: 16.6

Thermal conductivity 68°F to 1472°F - 20°C to 800°C : 16.9

At 23°C (73°F) : 9.95 W/m.°C 68°F to 1652°F - 20°C to 900°C : 17.2

(5.8 Btu/h.ft.°F) 68°F to 1832°F - 20°Cto 1000°C : 17.6

At 100°C (212°F) : 11.2 W/m.°C 68°F to 2012°F - 20°Cto 1100°C : 17.9

(6.5 Btu/h.ft.°F) 68°F to 2192°F - 20°Cto 1200°C : 18.4

At 750°C (1382°F) : 20.3 W/m.°C

(11.7 Btu/h.ft.°F)

At 1050°C (1922°F) : 30 W/m.°C

(17 Btu/h.ft.°F)



°C °F BTU/lb. °F

20 68 0.112 469

100 212 0.117 490

750 1382 0.145 606

Temperature

°C °F MPa ksi

20 68 166,200 24.087

100 212 159,000 23.040

200 392 150,500 21.800

300 572 141,000 20.430

400 752 136,000 19.710

500 932 128,000 18.550

600 1112 119,800 17.360

700 1292 113,000 16.380

800 1472 107,000 15.510

900 1652 101,500 14.710

1000 1832 97,500 14.130

1100 2012 93,500 13.550

MMG 4 - MARS 09...........................69

MANAURITE 40XO



700 1292 380 55 176 26 15

800 1472 275 40 155 22 25

900 1652 160 23 127 18 35

1000 1832 100 14 82 12 40

1100 2012 57 8.5 52 7.6 40


1 • At room temperature(Minimum values) (Typical values)

Ultimate tensile strength : 450 MPa 65 000 psi 540 MPa

Yield strength 250 MPa 35 500 psi 280 MPa

Elongation (on 4d) 8% for centrifugally cast pipes 12%

5% for static castings

2 • Short time tensile tests at various temperatures on as cast material

CREEP PROPERTIESLong time test creep dataManaurite 40XO 100,000 hrs creep rupture strength


800 47.5 40.7

825 41.3 35.8

850 35.5 30.9

875 30.6 26.6

900 25.8 22.3

925 321.4 18.5

950 17.6 15.3

975 14.3 12.6

1000 11.5 10.1

1025 9.2 8

1050 7.3 6.3

1075 5.8 4.9

1100 4.4 3.8

70 ................ MMG 4 - MARS 09

100

Mp

a 10

2627

2829

3031

3233

3435

36

1

AV

G s

tres

s 40

XO

MIN

str

ess

40X

O

1400

1600

1800

2000

°F°C11

0010

0090

080

010

0 00

0 h

r

LMP

= T

/100

0(20

.3 +

log

(t)

) T

: °K

t

: hr

MANAURITE 40X0CREEP RUPTURE STRENGTH (95% CONFIDENCE LEVEL)

MMG 4 - MARS 09...........................71

100

820

870

920

970

Tem

per

atu

re (

°C)

Co

mp

arai

son

in 1

00 0

00 h

r ru

ptu

re t

ime:

40X

O v

s X

M a

nd

XTM 10

2010

7011

20

1

MPa

XM

min

40X

O m

in

XTM

min

MANAURITE 40XOCOMPARATIVE CREEP DATA

72 ................ MMG 4 - MARS 09

MANAURITE 40XO2.

0

1.8

1.6

1.4

1.2

1.0

0.8

0.6

0.4

0.0

00.

51

1.5

22.

53

3.5

4

Dep

th f

rom

ID (

mm

)

Δ Carbon (%)CARBURIZATION TEST 850-1150°C

MMG 4 - MARS 09...........................73

MANAURITE 40XO


1 • Oxydation processAfter ethanol cleaning, samples are weighed (3 times)

Cycle: Heat up : 300° C.h-1

Soaking time : 10 hours

Cooling : 300° C.h-1

After cycle, sample (with scale eventually) is weighed.

See curves obtained for weight increase hereafter.

2 • These curves show a tendancy to have a constant rate of weight gain after acertain number of cycles ; this rate can be calculated and the results are obtained in 10-6g.cm-2.h-1.

These results can be converted in corrosion depth in mm/year

Corrosion depth in cycling oxidation in air

1000 °C 1050 °C 1100 °CXM 1.05

XTM 0.42 0.52 0.83

40XO 0.22 0.45 0.75

74 ................ MMG 4 - MARS 0974 ................ MMG 4 - MARS 09

MANAURITE 40XO

0.00

20

0.00

15

0.00

10

0.00

05

0.00

25

XTM

40X

O


01

23

45

6

Nu

mb

er o

f cy

cles

78

910

CYCLING OXIDATION IN AIR AT 1000°CTOTAL WEIGHT INCREASE PER SURFACE UNIT

Cyc

ling

oxi

dat

ion

in a

ir a

t 11

00°

C, s

ee c

om

par

tive

cyc

ling

oxi

dat

ion

in a

ir c

urv

es p

89

MMG 4 - MARS 09...........................75

MANAURITE 40XO

0.00

35

0.00

30

0.00

25

0.00

15

0.00

10

0.00

05

0.00

20

0.00

40

XTM

40X

O


01

23

45

6

Nu

mb

er o

f cy

cles

78

910

Cyc

ling

oxi

dat

ion

in a

ir a

t 11

00°

C, s

ee c

om

par

ativ

e cy

clin

g o

xid

atio

n in

air

cu

rves

p 8

9


MMG 4 - MARS 09...........................75

76 ................ MMG 4 - MARS 0976 ................ MMG 4 - MARS 0976 ................ MMG 4 - MARS 09

MANAURITE 40XO

Weldability of as cast 40XO material is comparable to 40X material and same WPS can be used for both

materials. Aged tubes can also be welded as shown hereunder.

78 ................ MMG 4 - MARS 09

MANAURITE XO


MANAURITE XOR

PHYSICAL PROPERTIES

Specific gravity: 0,295 lb/inch3 (8,15 kg/dm3) Coefficient of expansion

Melting point : 1350°C (2460°F) in/in °F (10-6) mm/mm/°C (10-6)

From 70° F to 1560°F : 10,21 20°C to 850°C : 18,5

From 70° F to 1740°F : 10,4 20°C to 950°C : 18,9

Thermal conductivity From 70° F to 1920°F : 10,6 20°C to 1050°C : 19,3

At 1050°C (1922°F) : 30 W/m.°C From 70° F to 2100°F : 10,9 20°C to 1150°C : 19,7

(17 Btu/h.ft.°F)

At 20°C (68°F) : 10,5 W/m.°C

(6 Btu/h.ft.°F)



°C °F BTU/lb. °F

20 68 0,112 469

100 212 0,117 489,9

200 392 0,124 519,3

300 572 0,130 544,4

400 752 0,137 573,7

500 932 0,143 598,8

600 1112 0,150 628,2

700 1292 0,157 657,5

800 1472 0,163 682,6

900 1652 0,170 711,9

1000 1832 0,177 741,2

1100 2012 0,183 766,4

1200 2192 0,190 795,7

Temperature

°C °F MPa ksi

20 68 161,900 23,470

100 212 155,000 22,475

200 392 147,150 21,337

300 572 138,000 20,010

400 752 133,400 19,343

500 932 126,000 18,270

600 1112 117,700 17,066

700 1292 111,000 16,095

800 1472 106,000 15,360

900 1652 101,000 14,650

1000 1832 97,100 14,080

1100 2012 93,200 13,510

MMG 4 - MARS 09...........................79

Temperature U.T.S. Y.S E


750 1350 333 48.4 157 22.8 16

800 1470 265 38.2 147 21.3 20

850 1560 196 28.4 137 19.9 22

900 1650 147 21.3 118 17.1 30

950 1740 118 17.1 88 12.8 32

1000 1830 93 13.5 78 11.4 38

1050 1920 74 10.7 69 10.0 47

1100 2010 61 8.8 55 8.0 39

MMG 4 - MARS 09...........................79

Temperature U.T.S. Y.S E


750 1350 333 48.4 157 22.8 16

800 1470 265 38.2 147 21.3 20

850 1560 196 28.4 137 19.9 22

900 1650 147 21.3 118 17.1 30

950 1740 118 17.1 88 12.8 32

1000 1830 93 13.5 78 11.4 38

1050 1920 74 10.7 69 10.0 47

1100 2010 61 8.8 55 8.0 39

MMG 4 - MARS 09...........................79MMG 4 - MARS 09...........................79

MANAURITE XOR


1 • At room temperature(minimum values)

Ultimate tensile strength : 450 MPa 65 000 psi

Yield strength 250 MPa 35 500 psi

Elongation (on 4d) 8% for centrifugally cast pipes

6% for static castings

2 • Short time tensile test at various temperatures on as cast material

(typical values)



750 1382 333 48,4 157 22,8 16

800 1472 265 38,2 147 21,3 20

850 1562 196 28,4 137 19,9 22

900 1652 147 21,3 118 17,1 30

950 1742 118 17,1 88 12,8 32

1000 1832 93 13,5 78 11,4 38

1050 1922 74 10,7 69 10,0 47

1100 2012 61 8,8 55 8,0 39

80 ................ MMG 4 - MARS 09

MANAURITE XO


MANAURITE XOR

3• Creep propertiesLong time test creep dataManaurite XOR 100000 hrs creep rupture strength


825 52 47.2

850 45.1 41.4

875 39 35.7

900 33.3 30.3

925 27.7 25.2

950 22.8 20.5

975 18.5 16.6

1000 14.6 12.9

1025 11.4 10.1

1050 8.7 7.7

1075 6.6 5.8

1100 4.9 4.2

MMG 4 - MARS 09...........................81MMG 4 - MARS 09...........................81MMG 4 - MARS 09...........................81

MANAURITE XORCREEP RUPTURE STRENGTH(95% CONFIDENCE LEVEL)

MMG 4 - MARS 09...........................81

Mp

a

100 10 1

3031

3233

3435

3637

3839

40

Ave

rage

Str

ess

Min

imum

Str

ess

100

000

hr

900

1600

1000

1100

°C

1800

2000

°F

LMP

= T

/100

0(22

.96

+ lo

g (

t))

T: °

K

t: h

r

82 ................ MMG 4 - MARS 09

MANAURITE XO


MANAURITE XOR


Oxydation processAfter ethanol cleaning, samples are weighed (3 times)

Cycle: Heat up: 300° C.h-1

Soaking time: 10 hours

Cooling: 300° C.h-1

After cycle, sample (with scale eventually) is weighed

See curves obtained for weight incresae hereafter.


MANAURITE XORCYCLING OXIDATION IN AIR AT 1000°C

TOTAL WEIGHT INCREASE PER SURFACE UNIT

0.00

20

0.00

15

0.00

10

0.00

05

0.00

25

XM

cra

ckin

g


01

23

45

6

Nu

mb

er o

f cy

cles

78

910

XO

R


MANAURITE XOR

84 ................ MMG 4 - MARS 09

0.00

6

0.00

4

0.00

5

0.00

3

0.00

1

0.00

2

0.00

7

XM

cra

ckin

g


01

23

45

6

Nu

mb

er o

f cy

cles

78

910

XO

R


MMG 4 - MARS 09...........................85MMG 4 - MARS 09...........................85MMG 4 - MARS 09...........................85MMG 4 - MARS 09...........................85MMG 4 - MARS 09...........................85

COMPARATIVEDATA




90 ................ MMG 4 - MARS 0990 ................ MMG 4 - MARS 0990 ................ MMG 4 - MARS 0990 ................ MMG 4 - MARS 09

MMG 4 - MARS 09...........................91MMG 4 - MARS 09...........................91

0.00

7

0.00

6

0.00

5

0.00

4

0.00

3

0.00

2

0.00

1

0.00

0

pg

01

2N

um

ber

of

cycl

es3

45

67

89

10

XTM

40X

O

XO

XM

cra

ckin

g

Co

mp

arat

ive

cycl

ing

oxy

dat

ion

in a

ir a

t 1

100°

C

Manoir Petrochem12, rue des Ardennes - BP 8401 – PITRES

27108 VAL DE REUIL CEDEXTel.+33 2 32487200 – Fax +33 2 32495726

Hi-Tech Fabrication LtdBretby Business Park - Ashby Road

Burton on Trent – Staffordshire DE15 0YZTel. +44 (0) 1283 817902 – Fax +44 (0) 1283 817909

Manoir Petro India LimitedHead office address : Universal Business Park

602, B – Wing – Chandivali Farm Road – Andheri (E)Mumbai – 400 072, India

Tel : +91 9920167 307 - Fax: +91 22 22082113Manoir Petro India Limited

造⼚Casting Plant: 造⼚地址：烟台市芝罘区只楚南路Casting Factory address: Zhichu South Road, Zhifu district, Yantai

: 6851895, 6851881 真: 6851895 Tel: 6851895, 6851881 Fax: 6851895

MANOIR INDUSTRIES

www.manoir-industries.com MANOIR PETROCHEM®

Heat-resistant alloys for hydrocarbon processing

MA

NO

IR PETROC

HEM

®

Date post:	11-Mar-2016
Category:	Documents
Upload:	luis-vargas
View:	272 times
Download:	15 times

MANOIR PETROCHEM ® Heat-resistant alloys for hydrocarbon processing

Documents