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Mario Carere, Bernd Gawlik, Madalina David
Bratislava 25 November 2010First meeting of CMEP group
Task 3.1 C: QA/QC case studies
Task 3.1 D: Field Trials
Task 3.1 E: Reference Materials
Task 3.1 F: Standardization (analytical methods-evaluation of LOD/LOQ
Task 3.2 C: effect based tools (e.g pharmaceuticals, dioxins, ed chemicals)
Passive Sampling, Biotic Ligand Model (zinc?)
New Priority SubstancesSubstance BCF Log Kow Matrix Uses
Methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate (Bifenox)
1500 3.64 W, B
It is used as a control of weeds in post-emergence applications in winter cereals
Terbutryn 181 3,48-3.77 W Selective herbicide, triazine compound
Cybutryne (Irgarol®) 160-30000 2,8-3,95 W, B
Effective herbicidal biocide mainly used as an antifouling agent in paints for boats and vessels. It is applied at marine as well as at inland freshwater sites
Cypermethrin 1204 6.6 S B Insecticide
Dichlorvos 1,2 1.9 W
organophosphorous insecticide
New Priority SubstancesSubstance BCF Log Kow Matrix Uses
Heptachlor/Heptachlor epoxide
56000 5.40-6.10 B-S Organochlorinated
insecticide-banned
Polychlorinated biphenyls (PCBs)
30000-50000
6-8 B-SUse in components of early fluorescent light fittings, electrical transformers, plasticizers in paints and cements, stabilizing additives in flexible PVC, paints, eccet..
“Dioxins” PCDD+PCDF+PCB DL 30000-
500006.1 - 8.20 B-S
PCDDs and PCDFs are unintentionally formed and released from thermal processes as a result of incomplete combustion or chemical reactions.
Perfluorooctane sulfonic acid and its salts (PFOS)
2796 5.16
(KOC)B-S
Providing grease, oil and water resistance to materials such as textiles, carpets, paper and in general coatings
New Priority Substances
Substance BCF Log Kow Matrix Major Uses
Hexabromo-cyclododecane (HBCDD)
18100 5.07-5.62 S B
Used as a flame retardant,
Quinoxyfen 5040 4.66 W B Fungicide
Dicofol 8050-13500 6
W B
Organochlorinated acaricide
Cyanides (free cyanides)
Cyanides mainly occur in waters as free cyanides, mostly hydrogen cyanide (HCN) which represents the main toxic form with cyanide ion CN- 0,5
0,44-0,66 W
Basic inorganic chemicals, incineration, paper production, eccet
New Priority Substances
Substance BCF Log Kow Matrix Major Uses
Aclonifen 2896 4.37 B
herbicidal active substance belonging to the chemical class of diphenylether
Diclofenac
69-2732 3,28-4.02
W B
pharmaceutical ingredient used by patients for the treatment of inflammation and pain
17alpha-ethinylestradiol
610 3.67-4.2 W B synthetic
steroid
CMEP Mandate FeedbackTASKS MS/stakeholders Task Coordinator
3.1 B-Statistical Methods
U.K., Germany, Medpol
3.1 C- QA/QC implementation
Finland, France, Italy, Medpol,
3.1 D-CM- ON-SITE
Netherland, France, Italy, Medpol
3.1 E-Reference Materials
Finland, France, Sweden
3.1 FStandardisation (analyt.
methods)
Finland, Netherland, France, Sweden
3.2 AEmerging Pollutants-research
Czeck Republik
3.2 BEmerging Pollutants-EU-wide
UK, Finland, Czeck Republik, Italy, Medpol
3.2 CEffect Based Tools
Finland, Sweden, Italy, Medpol, Swizerland