Mark Mathieson Turnbull Curriculum Vitae

Professor of Chemistry

Clark University, 950 Main St.

Worcester, Mass. 01610 (508)-793-7167

Professional Experience

Professor, Carlson School of Chemistry and Biochemistry, Clark University, 2000-present

John Angus Erskine Visiting Fellow, University of Canterbury, Christchurch, NZ 2017.

Carl J. and Anna (Kranz) Carlson Endowed Chair in Chemistry, 2013-2015.

Profesor Visitante, Departamento de Química Física, Facultad de Química, Universitat de

Barcelona, 2001-2002

Iberdrola Fellow, Universitat de Barcelona, 2001-2002.

Chairman, Carlson School of Chemistry and Biochemistry, 1999-2001, 2003-8.

Associate Professor of Chemistry, Clark University, 1992-1999.

Visiting Lecturer in Chemistry, University of Canterbury, Christchurch, New Zealand, 1995.

Assistant Professor of Chemistry, Clark University; Sept. 1986 - 1992.

Chemistry and Physics Teacher, Londonderry High School, Londonderry, N.H., 1978-1982.

Education

Ph.D. in Organic Chemistry, Brandeis University, February 1987.

Research Director: Prof. Myron Rosenblum

Dissertation: "Synthesis and Reactions of (C5H5)(CO)2Fe Complexes Of Vinyl

Diethers: Asymmetric Synthesis Through Organoiron Reagents"

M.S. in Inorganic Chemistry, University of New Hampshire, Sept. 1984.

Research director: Prof. Edward H. Wong

Thesis: “Reactions of Alkoxy and Amino Substituted Phosphine Oxides and

Diphosphine Monoxides With Hexacarbonylmolybdenum(0)"

B.S. in Chemistry, University of New Hampshire, May 1978.

Honors and Awards

Outstanding Undergraduate Teacher of the Year, Clark University (2017).

John A. Timm Award for the Furtherance of the Study of Chemistry (presented by the New

England Association of Chemistry Teachers) (2016)

Student-Athlete Advisory Council Appreciation Award, Clark University (2015)

Carl J. and Anna (Kranz) Carlson Endowed Chair in Chemistry (2013-2015)

Clark University Senior Faculty Fellow – 2005-6

Siemens Outstanding Mentor – 2004-5

Pratt-Diniak Award For Excellence In Teaching, University of New Hampshire, 1983 and 1984.

Teacher of the Year - Londonderry High School 1980-81.

Professional Service

Co-Editor – Journal of Coordination Chemistry, 2017-present

Editorial Board – Journal of Coordination Chemistry – 2003-14

European Chemical Bulletin – 2012-present

Treasurer, Central Massachusetts Section, ACS – 2012-present

Secretary/Treasurer, Central Massachusetts Section, ACS – 2011

Member-at-Large, Executive Board, Central Massachusetts Section, ACS – 2008-2010

Current Research Interests: Current research activities involve two areas of study:

1) Molecular Magnetic Materials. This area of research is conducted as a joint project with

Prof. Christopher Landee (Dept. of Physics, Clark University). Three classes of magnetic

material are under investigation. a) Synthetic Ferrimagnets: This project focuses on the

design and preparation of materials that exhibit bulk ferrimagnetism at room temperature.

The substances under investigation are bimetallic coordination polymers that are expected to

be transparent in a range of wavelengths in the visible and/or infrared. Their transparency

will allow these materials to be used as optical switching devices and for magneto-optical

data storage. b) Frustrated magnets: Frustrated magnets occur when competing interactions

lead to a degenerate ground state. Unlike other complex magnets with similar properties

(such as spin glasses), randomness is not a necessary condition for frustration. Since there

are few known examples of frustrated magnetic lattices, a clear need exists for new materials

and we have begun investigations directed toward the design and synthesis of a new series

of frustrated magnets. c) Low-Dimensional Heisenberg Antiferromagnets: The motivation

for this project was the discovery of high temperature superconductors (HTSC), all of which

contain copper oxide layers. A prominent theory for the origin of their superconductivity is

based upon the magnetic properties of these layers. However, it is difficult to study HTSC

directly since the magnetic interaction strengths are large and the samples are very sensitive

to impurities, oxygen levels, etc... Conversely, insulating analogues such as the coordination

polymer [Cu(pyrazine)2]n2+ have moderate interaction strengths and order magnetically at

convenient temperatures. We are systematically preparing model systems with varying

interaction strengths and interplanar exchange so that the properties of this important model

system can be studies in detail. Similarly, we have recently begun studies targeted toward

the preparation of novel quantum Spin-Ladder systems. Spin-ladders are unique systems

where theory predicts the existence of superconductivity in doped materials. Few spin

ladders exist with ordering temperatures in the appropriate range for many experiments

which prevents the testing of existing theories. We have prepared several new materials and

are continuing our work in this area.

2) The preparation and reactivity of transition metal-phosphine complexes with novel

structures. Amino-substituted phosphine oxides undergo an unusual thermal condensation

reaction with transition metal carbonyls. The products are cage-like molecules with

adamantane (or larger) skeletons made up of phosphorus, oxygen and metal atoms. In

addition, the bimetallic cage products undergo redox and substitution reactions which we

intend to exploit for metal-directed organic synthesis. The oxidized metal-containing

compounds involved here have two distinct properties: 1) there are up to three sites available

for coordination of organic ligands to be activated 2) The compounds are bimetallics with

the two metals available in either the (0) or (+2) state, hence they may show very unique

reactivity with a potential for application as stoichiometric or catalytic templates for organic

synthesis. This project is not currently active.

Publications

Research Papers

1) Comins,D.L.;Jacobine,A.F.;Marshall,J.L.;Turnbull,M.M. Synthesis 1978, 309. "Phosphonate

Ester Preparation From Active Methylene Compounds And Phosphorochlorodate Esters"

2) Wong,E.H.;Turnbull,M.M.;Gabe,E.J.;Lee,F.L.;LePage,Y. J. Chem. Soc., Chem. Commun.

1983, 14, 776. "2,4,6,8-Tetrakis(N,N-di-isopropylamino)cyclotetraphosphoxane (iPr2NPO)4, a

Tetradentate Ligand That Chelates Two Metals: Assemblage Of A P4O4Mo2 Cage Structure"

3) Turnbull,M.M.;Wong,E.H.;Gabe,E.J.;Lee,F.L. Inorg. Chem. 1986, 25, 3189-94.

"(Diethoxyphosphoryl)phosphines as Ligands toward Molybdenum Hexacarbonyl"

4) Rosenblum,M.;Turnbull,M.M.;Foxman,B.F. Organometallics 1986, 5, 1062. "Asymmetric

Carbon-Carbon Bond Formation Using Optically Active (h-C5H5)Fe(CO)2-Vinyl Ether

Complexes. Asymmetric Control at Two Adjacent Carbon Centers"

5) Rosenblum,M.;Foxman,B.F.;Turnbull,M.M. Heterocycles 1987,25,419-431. "Stereoselective

Synthesis Of 1,2-Diethoxy- and 1,4-Dioxino[2,3b]furans Using Organoiron Reagents"

6) †Rosenblum,M.;Turnbull,M.M.;Begum,M.K. J. Organomet. Chem. 1987,431,67-77.

"2-Acrylonitrile-Cyclopentadienyldicarbonyliron(II) Tetrafluoroborate: An Unusual

High-Valent Transition Metal Complex"

7) Turnbull,M.M.;Foxman,B.M.;Rosenblum,M. Organometallics 1988, 7,200-210. "Optically

Active Organoiron Complexes. Preparation and Chemistry"

8) Wong,E.H.;Turnbull,M.M.;Hutchinson,K.D.;Valdez,C.;Gabe,E.J.;Lee,F.L.; LePage,Y.

J.Am.Chem.Soc. 1988, 110, 8422-28. "Two Approaches to the Synthesis of Bimetallic Cage

Complexes of the Tetraoxatetraphosphorinane [RPO]4 Ring"

9) †Erlacher,H.E.*;Turnbull,M.M.;Chu,H.-S.;Rosenblum,M. J. Org. Chem. 1989, 54, 3012-15.

"Stereoelectronic Constraints in Metal-assisted ß-eliminations"

10) †Banse,C.M.*;Pray,M.L.*;Turnbull,M.M. Polyhedron 1989, 8, 2719. "Synthesis of a Bimetal-

lic Chromium Complex Containing the Novel Pentaoxapentaphosphorinane [RPO]5 Ring"

11) †Bader,D.S.*; Turnbull, M.M. Polyhedron 1990, 9, 2619. "Rotational Barriers in Dialkyl-

aminophenylchlorophosphines: Steric Effects in the Preparation of Cage Complexes"

12) †Turnbull,M.M.; Nelson,D.J.; Lekouses,W.*; Sarnov,M.L.*; Tartarini,K.A.*; Huang, T.-K.#

Tetrahedron 1990, 46, 6613. "Rotational Barriers in N,N-Diethylbenzamides: Substituent and

Solvent Effects

13) †Turnbull,M.M.;Pon,G.;Willett,R.D. Polyhedron 1991, 10, 1835. "Autoreduction of Cu(II) By

a Non-Chelating Ligand: Synthesis and X-Ray Structure of Tris(2,3-dimethylpyrazine)-

dicopper(I) Perchlorate"

14) †Li,H.J.#; Turnbull, M.M. J. Organomet. Chem. 1991, 419, 245. "Synthesis of Alkyl-Fp

Complexes via Organometallic Reagents"

15) †Jones,E.J.*;Nelson,D.J.;Turnbull,M.M. J. Inorg. Biochem. 1992, 45, 85. "Enhancement and

Quenching of Fluorescence of Quin-2 by Metal Ions"

16) †Turnbull,M.M.;Valdez,C.;Wong,E.H.;Gabe,E.J.;Lee,F.L. Inorg. Chem. 1992, 31, 208.

"Halogenated Derivatives of the Dimolybdenum Tetraphosphoxane Cage Complex

(CO)4Mo[iPr2NPO]4Mo(CO)4"

17) †Marathias,V.*;Turnbull,M.M.;Abdon,R.L.;Coppola,B.P. Polyhedron 1992, 11,2759.

"Substituent Effects on 13C-NMR Chemical Shifts in Dialkylaminophenylchloro-

phosphines"

18) †Li,H.J.#;Turnbull,M.M. Syn. and React. in Inorg. and Metal-Org. Chem. 1993, 23, 797.

"Na[Fe(CO)2(C5H5)] Mediated Coupling Reactions of Benzyl and Allyl Halides"

19) †Navas,C.*;Turnbull,M.M.;Giogas,C.*;Landee,C.P.;Zhang,W.#;Pon,G.;Willett,R.D.

Polyhedron 1993, 12, 1019-26. "Synthesis, Structure and Magnetic Studies of Cu(II) and

Cu(I) Complexes of Methylpyrazines"

20) †Zhang,W.#; Landee,C.P.; Turnbull,M.M.; Willett, R.D. J. Appl. Phys. 1993, 73, 5379-81.

"Magnetic Interactions in Homometallic Chains M(4-cyanopyridine)2Cl2, M = Cu, Ni, Co"

21) Willett,R.D.; Wang,Z.; Molner,S.; Brewer,K.; Landee,C.P.; Turnbull,M.M.; Zhang,W.# Mol.

Cryst. Liq. Cryst. 1993, 233, 277-82. "Synthetic Design of Ferrimagnetic Materials: One

Dimensional Bimetallic Coordination Polymers"

22) †Turnbull,M.M.; Landee,C.P.; Soesbe,T.C.*; Willett,R.D. Mol. Cryst. Liq. Cryst. 1993, 233,

269-86. "Synthetic Design of Ferrimagnetic Materials: Two and Three Dimensional

Bimetallic Coordination Polymers"

23) Liu,Y.#;Turnbull,M.M.;Jones,A.A.;Inglefield,P.T.;Kambour,R.P. Solid State NMR 1993, 2,

289. "Concentration and Temperature Dependence of Diluent Dynamics through One- and

Two-Dimensional Line Shape Experiments on a Phosphate Ester in Polycarbonate"

24) Sun,X.;Wong,E.H.;Turnbull,M.M.;Waltermire,B.E.;Ostrander,R.L.; Rheingold,A.L. J. Chem.

Soc., Chem. Commun. 1994, 237-8. "Dichromium Cage Complexes of Cyclotetra-,

Cyclopenta-, and Cyclohexaphosphoxane"

25) †Landee,C.P.; Wynn,C.M#.; Albrecht,A.S.#; Zhang,W.#; Vunni,G.B.*; Parent,J.L.#; Navas,C.*;

Turnbull,M.M. J. Appl. Phys. 1994, 75, 5535-7. "Magnetic Properties of a New

Amorphous Magnet"

26) †Turnbull, M.M.; Wei, M.Y.; Willett, R.D. J. Coord. Chem. 1995, 35, 11-17. "Copper

Catalyzed Hydrolysis of Triazine: Synthesis and Structure of

Cu(HN=CHNHCH=NH)2(ClO4)2"

27) Sun,X.;Wong,E.H.;Turnbull,M.M.;Rheingold,A.L.;Waltermire,B.E.; Ostrander,R.L.

Organometallics 1995, 14, 83-97. "Metal-Assisted Formation of Phosphorus-Oxygen

Heterocyclic Complexes"

28) †Turnbull,M.M.;Albrecht,A.S.#;Landee,C.P.;Maurer,J.A.*;Wynn,C.M.#, Mol. Crys. Liq.

Crys. 1995, 273, 203-210. "Oxamide Derived Bimetallic Ferrimagnets"

29) †Wynn,C.M.#;Landee,C.P.;Albrecht,A.S.#;Navas,C.*;Turnbull,M.M. Mol. Crys. Liq. Crys.

1995, 274, 1-10. "Properties of Molecular-Based Frustrated Magnets"

30) Fujiwara,N.; Jeitler,J.R.#; Navas,C.*; Turnbull,M.M.; Goto,T.; Hosoito,N. J. Mag. Mag.

Mat. 1995, 140-4, 1663-4. "Doping Effect of Non-magnetic Impurities in Haldane

Systems"

32) †Coffey,T.#; Robinson,W.T.; Turnbull,M.M. Acta Cryst. C, Crys. Struct. Commun., 1996,

C52, 248-50. "2-Amino-3-methylpyridinium Bromide"

33) †Prince,B.J.; Turnbull,M.M. Acta Cryst. C, Crys. Struct. Commun., 1996, C52, 1843-4.

"2-Amino-5-bromopyrimidinium Chloride"

34) †Kaplan,R.W.*; Turnbull,M.M. Acta Cryst. C, Crys. Struct. Commun., 1996, C52, 2049-51.

"2,2,6,6-Tetramethylpiperidinium chloride"

35) †Williams,J.M.#; Landee,C.P; Turnbull, M.M. Malaysian J. Sci., 1996, 17, 33-6. "Magnetic

Susceptibility Measurements of a One Dimensional Heisenberg Antiferromagnet"

36) Curnow,O.J.; Huttner,G.; Smail,S.J.; Turnbull,M.M. J. Organomet. Chem. 1996, 524, 267-75.

“Synthesis and Coordination Chemistry of the Tethered Bis(cyclopentadienyl)phosphine ligand

precursor PPh(CH2CH2C5H5)2: X-ray structure of transPdCl2[PPh(CH2CH2C5H4)2Fe]2”

38) House, D.A.; Turnbull, M.M. Inorg. Chim. Acta 1997, 254, 401-5. "The synthesis, structure

and acid hydrolysis kinetics of exo-cis--[CrCl2(1,4,7,11-tetraazaundecane]ClO4.

39) Pon,G.; Willett,R.D.; Prince,B.J.; Robinson,W.T.; Turnbull,M.M. Inorg. Chim. Acta 1997,

255, 325-34. "Crystal Chemistry of the Copper Bromide/2-aminopyrimidine System"

40) †Zhang,W.#; Jeitler,J.R.#; Turnbull,M.M.; Landee,C.P.; Wei,M.; Willett,R.D. Inorg. Chim.

Acta. 1997, 256, 183-98. "Synthesis, X-ray structures and Magnetic Properties of Linear Chain

4-Cyanopyridine Compounds: [Cu(4-CNpy)4(H2O)](ClO4)2 and M(4-CNpy)2Cl2, M = Mn, Fe,

Co, Ni, and Cu"

41) Hindemarsh, K.; House, D.A.; Turnbull, M.M. Inorg. Chim. Acta 1997, 257, 11-18. "The

Hydrolysis Products of cis-Diamminedichloroplatinum(II) 9. Chloride and Bromide Anation

Kinetics for Some [PtII(N)2(OH2)2]2+ complexes and the Structures of [PtIVBr4(N)2] ((N)2 = en,

tn)"

42) Gladkikh, O.P.; Curtis, N.F.; Turnbull, Mark M. Acta Cryst.C, Crys. Struct. Commun. 1997,

C53, 586-7. “A 13-Membered Cyclic Tetraamine Salt: 12,12-Dimethyl-4,7,10-triaza-1-

azoniacyclotridecane Perchlorate Hydrate”

43) Derwahl,A.; Dickie,A.; House,D.A.; Jackson,W.G.; Schaffner,S.; Svensson,J.; Turnbull,M.M.;

Zhender, M. Inorg. Chim. Acta 1997, 257, 179-87. “Anionopentaaminecobalt(III) complexes

with polyamine ligands. 28. The crystal structures of [Co(tacn)(en)]ZnCl4,

[Co(tacn)(ampy)]ZnCl4(H2O), unsym-[CoCl(N-Metacn)(en)]ZnCl4(H2O), trans-(R,S)-

[CoCl(2,2,3-tet)(NH3)]ZnCl4, and unsym-fac-[CoCl(bn)(dien)]ZnCl4”

44) Srivivas, V.; Rodley,G.A.; Ravikumar,K.; Robinson,W.T.; Turnbull,M.M.;

Balasubramanian,D. Langmuir 1997, 13, 3235-39. "Crystal Packing of Sodium Benzosulfonates

Provides Evidence on Solubilising Properties of Hydrotropes"

45) †Turnbull,M.M. Acta Cryst. C, Cryst. Struc. Commun 1997, C53, 818-20.

"N-Methylmorpholine salts: N-Methylmorpholinium chloride and bromide”

46) †Albrecht,A.S.#; Landee,C.P.; Slanic, Z.*; Turnbull,M.M. Mol. Cryst. Liq. Cryst.. 1997, 305,

333-40. "New Square S=1/2 Heisenberg Antiferromagnetic Lattices: Pyridinium

Tetrahalocuprates and Bispyrazinecopper(II) Tetrafluoroborate"

47) †Prince,B.J.;Turnbull,M.M J. Coord. Chem. 1997,41, 339-45. “Synthesis and Structure of (2-

Amino-5-bromopyrimidine)bromocopper(I)”

48) †Anagnostis,J.#; Turnbull,M.M. Acta Cryst. C, Cryst. Struc. Commun. 1998, C54, 681-3.

“2-Amino-3,5-dichloropyridinium chloride”

49) Francisco, M.E.Y.#; Turnbull, M.M.; Erickson, K.L. Tetrahedron Lett. 1998, 5298-92.

“Cartilagineol, The Fourth Lineage of Laurencia-Derived Polyhalogenated Chamigrene”

50) Ng, S.W.; Turnbull, M.M. Acta Cryst. C, Cryst. Struc. Commun. 1998, C54, 1025-1027.

“Methylphenylammonium Hydrogen 2,6-Pyridinedicarboxylate at 158 K”

51) †Prince,B.J.;Turnbull,M.M Acta Cryst. C, Cryst. Struc. Commun. 1998, C54, 1178-80.

“8-Aminoquinolinium Chloride Dihydrate”

52) Edwards, R.A.; Easteal, A.J.; Gladkikh, O.P.; Robinson,W.T.; Turnbull, M.M.; Wilkins,

C.J. Acta Cryst.B, 1998, B54, 663 - 670. “A Reversible Non-disruptive Phase Transition

Shown by the Zinc Iodide Dimethylformamide Complex ZnI2(dmf)2”

53) Curtis, N.F.; Gladkikh, O.P.; Turnbull, M.M. Aust. J. Chem 1998, 51, 631-6. “Copper(II)

Compounds with Amine Imine Ligands; Structures of (2,4,6,9,11-Pentamethyl-5,8-

diazadodeca-4,8-diene-2,11-diamine)copper(II) Perchlorate and (2,4-Dimethyl-5,8,11-

triazatridec-4-ene-2,13-diamine)copper(II) Perchlorate”

54) Hammar, P.R.; Stone, M.B.; Reich, D.H.; Broholm, C.; Gibson, P.J.*; Turnbull, M.M.;

Landee, C.P.; Oshikawa, M. Phys. Rev. B 1999, 59, 1008-15. “Characterization of a quasi-

one-dimensional spin-1/2 magnet which is gapless and paramagnetic for gBH=J and kBT«J”

55) Adams, J.A.; Curnow, O.J.; Huttner, G.; Smail, S.J.; Turnbull, M.M. J. Organomet. Chem.

1999, 577, 44-57. “Synthesis and Electrochemistry of Complexes Containing the

Ferrocenyl-phosphine Ligand PPh(CH2CH2--5-C5H5)2Fe.”

56) †Turnbull, M.M.; Albrecht, A.S.#; Jameson, G.B.; Landee, C.P. Mol. Cryst. Liq. Cryst., 1999,

335, 245-52. “High-Field Magnetization Studies of Two-Dimensional Copper

Antiferromagnets”

57) Landee, C.P.; Turnbull, M.M. Mol. Cryst. Liq. Cryst., 1999, 335, 193-200. “Pyrazine-bridged

Copper Linear Chains: Molecule-Based 1D-Quantum Antiferromagnets”

58) †Maxcy,K.R.*; Turnbull,M.M. Acta Cryst. C, Cryst. Struc. Commun. 1999, C55, 1986-8.

“Redetermination of Bis(ethylenediamine)copper(II) perchlorate”

59) †Maxcy,K.R.*; Turnbull,M.M. Acta Cryst. C, Cryst. Struc. Commun. 1999, C55, 1984-6.

“Bis(ethylenediamine)dinitrocobalt(III) perchlorate”

60) †Coffey, T.J.#; Landee,C.P., Robinson, W.T., Turnbull,M.M., Winn,M.* and Woodward,

F.M.# Inorg. Chim. Acta 2000, 303, 54-60. “Transition Metal Halide Salts of 2-Amino-3-

methylpyridine: Synthesis, Crystal Structures and Magnetic Properties of (3-MAP)2CuX4 [3-

MAP = 2-amino-3-methylpyridinium; X = Cl, Br]

61) †Giantsidis,J.*; Turnbull, M.M. Acta Cryst. C, Cryst. Struc. Commun. 2000, C56, 334-5.

“6-Aminonicotinic acid”

62) Matsumoto, T.; Miyazaki, Y.; Albrecht, A.S.#; Landee, C.P.; Turnbull, M.M.; Sorai, M. J.

Phys. Chem. B., 2000, 104, 9993-10000. "Heat Capacities of the S=1/2 Two Dimensional

Heisenberg Antiferromagnet, (5CAP)2CuBr4, and Its Diamagnetic Analog, (5CAP)2ZnBr4”

63) Turnbull,M.M.; Wikaira,J.L.; Wilkins,C.J. Z. Kristallogr. 2000, 215, 702-6. “A Comparison

of the Molecular and Crystal structures of the Dimethylacetamide Complexes from Zinc

Chloride, Bromide and Iodide”

64) †Landee, C.P.; Turnbull, M.M.; Galeriu, C.#; Giantsidis, J.*; Woodward, F.M.# Phys. Rev. B,

Rapid Commun. 2001, 63, 100402R. “Magnetic properties of a new molecular-based spin-

ladder system: (5-IAP)2CuBr4· 2H2O”

65) †Amaral, S.*; Jensen, W.E.*; Landee, C.P.; Turnbull, M.M.; Woodward, F.M.# Polyhedron

2001, 20, 1317-22. “Quantum Linear Magnetic Chains: Structure and Magnetic Behavior of

(2-methylpyrazine)copper(II) nitrate”

66) Jones, B.R.; Varughese, P.A.; Olwjniczak, I.; Pigos, J.M.; Musfeldt, J.L.; Landee, C.P.;

Turnbull, M.M.; Carr, G.L. Chem. Mater. 2001, 13, 2127. “Lattice Dynamics of the One-

dimensional S=1/2 Heisenberg Antiferromagnet Copper Pyrazine Nitrate”

67) †Giantsidis, J.*; Turnbull, M.M.; Galeriu, C.#; Landee, C.P.; Woodward, F.M.# Syn. Metals

2001, 122, 517-22. “S=1/2 Quantum Heisenberg Antiferromagnet Ladders”

68) †Wynn, C.M#.; Albrecht, A.S.#; Landee, C.P.; Turnbull, M.M.; Dodrill, B. J. Sol. St. Chem.

2001, 159, 379-84. “Resonance in the nonlinear susceptibilities of Co3BTCA2(H2O)4, a

molecular-based magnet.”

69) †Li, H.-J.#; Castro, A.*; Turnbull, M. M. J. Organomet. Chem. 2001, 630, 33-43. “Chemical

Shift Effects in the 13C-NMR Spectra of [(C5H5)(CO)2Fe(II)]-substituted Cyclohexanes,

Dioxanes and Tetrahydropyrans”

70) †Woodward, F.M.#; Landee, C.P.; Giantsidis, J.*; Turnbull, M.M; Richardson, C. Inorg.

Chim. Acta 2001, 324, 324-330. “Structure and magnetic Properties of (5BAP)2CuBr4:

Magneto-structural Correlations of Layered S = ½ Heisenberg Antiferromagnets”

71) †Masaki, M.E.; Turnbull, M.M. Heterocycles 2002, 57, 47-54. “Lewis Acid Catalyzed

Dimerization of 2-Aminopyrimidine: Synthesis and X-ray structure”

72) †Glynn, C.W.#; Turnbull, M.M. Inorg. Chim. Acta. 2002, 332, 92-100. “Synthesis and metal

complexes of 2,6-bis(1-triazolo)pyridine: X-ray structure of 2,6-bis(1-triazolo)pyridine

dihydrochloride”

73) †Woodward, F.M.#; Albrecht, A.S.#; Wynn, C.M.#; Landee, C.P.; Turnbull, M.M. Phys. Rev.

B. 2002, 65, 144412 . “Two dimensional S = ½ Heisenberg antiferromagnets: synthesis,

structure and magnetic properties”

74) †Giantsidis, J.*; Turnbull, M.M.; Landee, C.P.; Woodward, F.M.# J. Coord. Chem. 2002, 55,

393-402. “Synthesis and Structure of Bis(2-amino-5-cyanopyridinium)

Diaquadichlorocopper(II) Dichloride”

75) †Turnbull, M.M.; Galeriu, C.#; Giantsidis, J.*; Landee, C.P. Mol. Cryst. Liq. Cryst. 2002, 376,

469-76. “Synthesis, Structure and Magnetic Susceptibility of Two 5-Nitro-2-aminopyridinium

Cuprates: (5-NAP)2CuCl4 and the Quantum Magnetic Ladder (5-NAP)2CuBr4·H2O”

76) †Amaral, S.* and Turnbull, M.M. J. Chem. Cryst. 2002, 32, 11. “Synthesis and structure of

bis(2,6-dimethylpyrazine)(THF)copper(II) nitrate”

77) †Giantsidis, J.;* Galeriu, C.#; Landee, C.P.; Turnbull, M.M. J. Coord. Chem. 2002, 55, 795.

“Transition Metal Halide Salts of 2-Amino-5-substituted-pyridines: Synthesis, Crystal

Structure and Magnetic Properties of Two Polymorphs of (5-IAP)2CuCl4 [5-IAP = 2-

amino-5-iodopyridinium]”

78) †Masaki, M.E.; Prince, B.J.; Turnbull, M.M., J. Coord. Chem. 2002, 55, 1337-51.

“Transition Metal Halide Salts and Complexes of 2-Aminopyrimidine: Cobalt(II) and

Nickel(II) compounds. Crystal Structures of bis(2-aminopyrimidinium)MX4 [M = Co, Ni;

X = Cl, Br] and 2-aminopyrimidinium(+2) [NiBr2(H2O)4]Br2”

79) †Turnbull, M.M.; Landee, C.P. Science 2002, 298, 1723-4. (Perspective) “Porous Materials

with a difference”

80) Broholm, C.; Aeppli, G.; Chen, Y.; Dender, D.C.; Enderle, M.; Gibson, P.J.*; Hammar, P.R.;

Honda, Z.; Katsumata, K.; Landee, C.P.; Oshikawa, M.; Reich, D.H.; Regnault, L.P.;

Shapiro, S.M.; Sieling, M.; Stone, M.B.; Turnbull, M.M.; Zaliznyak, I.; Zheludev, A. in

High Magnetic Fields – applications in condensed matter physics and spectroscopy C.

Berthier, L. P. Lévy, and G. Martinez, Eds. Springer Verlag (2002), p 211-234. “Magnetized

States of Quantum Spin Chains”

81) †Glynn, C.W.#; Turnbull, M.M. Trans. Met. Chem.2002, 27, 822-31. “Transition metal

complexes of 2,6-diacetylpyridine dioxime (dapdoH2): Crystal structures of

[M(dapdoH2)2](ClO4)2 [M = Cu, Mn]”

82) †Zhang, W.#; Bruda, S.#; Landee, C.P.; Parent, J.L.#; Turnbull, M.M. Inorg. Chim. Acta.

2003, 342, 193-201. “Structures and Magnetic Properties of Transition Metal Complexes

of 1,3,5-Benzenetricarboxylic Acid”

83) †Prince, B.J.; Turnbull, M.M.; Willett, R.D., J. Coord. Chem. 2003, 56, 441. “Copper(II)

Halide Complexes of 2-Aminopyrimidines: Crystal Structures of [(2-

aminopyrimidine)nCuCl2] (n = 1,2) and (2-amino-5-bromopyrimidine)2CuBr2”

84) †Albrecht, A.S.#; Landee, C.P.; Turnbull, M.M. J. Chem. Cryst. 2003, 33, 269-76.

“Structure of bis(2-amino-5-methylpyridinium) tetrachlorozincate at 298 K and 150 K.”

85) †Landee, C.P.; Delcheva, A.*; Galeriu, C.#; Peña, G.*; Turnbull, M.M.; Willett, R.D.

Polyhedron 2003, 22, 2325-9. “Molecular-Based Quantum Magnets: The Isotropic Spin

Ladder Cu(Quinoxaline)Br2”

86) †Deumal, M.; Landee, C.P.; Novoa, J.J.; Robb, M.A.; Turnbull, M.M. Polyhedron 2003, 22,

2235-9. “Through Space Magnetic Exchange In Tetrabromocuprates: Theoretical

Considerations”

87) †Jeitler, J.R.#; Turnbull, M.M.; Wikaira, J. Inorg. Chim. Acta. 2003, 351, 331-44.

“Synthesis, Characterization And Structure Of Transition Metal Complexes Of 4’-

Methylthio-2,2’:6’,2”-Terpyridyl”

88) Choi,J.; Woodward, J.D.; Musfeldt, J.L.; Landee, C.P.; Turnbull, M.M. Chem. Mater. 2003,

15, 2797-2802. “Vibrational Properties of Cu(pz)2(ClO4)2: Evidence for Enhanced Low-

Temperature Hydrogen Bonding in Square S= ½ Molecular Antiferromagnets”

89) †Zhang, W.#; Landee, C.P.; Willett, R.D.; Turnbull, M.M. Tetrahedron 2003, 59, 6027-34.

“Structure and isomerization in 4,4’-biimidazoles: A comparison of crystal structures and

theoretical calculations of 2,2’-dimethyl-4,4’-biimidazole and 2,2’-dimethyl-4,4’-

biimidazolium bis-trifluoroacetate”

90) Stone, M.B.; Reich, D.H.; Broholm, C.; Lefmann, K.; Rischel, C.; Landee, C.P.; Turnbull,

M.M., Phys. Rev. Lett. 2003. 91, 037205. “Extended quantum critical phase in a magnetized

spin-1/2 antiferromagnetic chain”

91) †Lee, J-H. P.*; Lewis, B.D.*; Mendes, J.M.*; Turnbull, M.M.; Awwadi, F.F. J. Coord.

Chem. 2003, 56, 1425-42. (cover article) “Transition Metal Halide Salts and Complexes of

2-Aminopyrimidine: Manganese(II) compounds. Crystal Structures of (2-

aminopyrimidinium)4 [MnCl4(H2O)]2, [(2-aminopyrimidine)2MnBr2(H2O)2 · 2H2O and (2-

aminopyrimidinium)2+[MnBr2(H2O)4]Br2”

92) †Anagnostis, J.#; Turnbull, M.M. Polyhedron 2004, 25, 125-133. “Rotational Barriers in

Dialkylaminochlorophosphines: Methyl substituted piperidinochlorophenyl-phosphines”

93) Long, V.C.; Schundler, E.C.; Makumbe, P.O.; Wei, X.; Landee, C.P.; Turnbull, M.M. J.

Mag. Mag. Mat. 2004, 272-6, 968-9. “Magnetic field-induced changes in the electronic

absorption intensities of NENB”

94) Willett, R.D.; Galeriu, C.#; Landee, C.P.; Turnbull, M.M.; Twamley, B. Inorg. Chem. 2004,

43, 3804-11. (cover article) “Structure and Magnetism of a Spin Ladder System:

(C5H9NH3)2CuBr4”

95) †Wells, B.M.*; Landee, C.P.; Turnbull, M.M., Awwadi, F.F.; Twamley, B. J. Mol. Cat. A.

2005, 228, 117-123. “Design and Synthesis of Magnetic Ladders: Structure and Magnetic

Properties of Cu(2,3-dimethylpyrazine)Br2”

96) Woodward, J.D.; Choi, J.; Musfeldt, J.L.; Haraldsen, J.T.; Wei, X.; Koo, H.-J.; Dai, D.;

Whangbo, M.-H.; Galeriu, C.#; Landee, C.P.; Turnbull, M.M. Physics Review B 2005, 71,

174416/1-8. “Understanding the color properties of (C5H9NH3)2CuBr4 in high magnetic

fields”

97) López, C.; Costa, R.; Illas, F.; de Graaf, C.; Turnbull, M.M.; Landee, C.P.; Espinosa, E.;

Molins. E. Dalton Trans. 2005, 2322-30. “Magnetostructural correlations in binuclear

copper(II) compounds bridged by a ferrocenecarboxylato(-1) and an hydroxo- or methoxo-

ligands: tuning the sign of superexchange in heterobridged complexes.”

98) †Jeitler, J.R.#; Turnbull, M.M. Acta Cryst. E 2005, 61, m1846-m1848. “Aqua(4’-hydroxy-

2,2’;6’,2”-terpyridyl)copper(II) perchlorate”

99) †Awwadi, F.F.; Landee, C.P.; Turnbull, M.M.; Twamley, B.; Wells, B.M.* Polyhedron 2005,

24, 2152-59. “Low-dimensional Quantum Magnetic Systems: Synthesis, Structure and

Magnetic Behavior of (2,5-dimethylpyrazine)copper(II) chloride and Synthesis and

Magnetic Behavior of Bis(2,6-dimethylpyrazine)copper (II) chloride.”

100) †Turnbull, M.M.; Landee, C.P.; Wells, B.M.* Coord. Chem. Rev. 2005, 249, 2567-2576.

“Magnetic Exchange Interactions in Tetrabromocuprate Compounds”

102) †Deumal, M.; Giorgi, G.; Robb, M.A.; Turnbull, M.M.; Landee, C.P.; Novoa, J.J. Euro. J.

Inorg. Chem. 2005, 4697-4706 (cover article). “The mechanism of magnetic interaction in

spin-ladder molecular magnets: A first principles bottom-up theoretical study of the

magnetism in the two-leg spin-ladder bis(2-amino-5-nitropyridinium) tetrabromocuprate

monohydrate”

103) †Bruda, S.#; Turnbull, M.M.; Landee, C.P.; Xu, Q.# Inorg. Chim. Acta, 2006, 359, 298-

308. “Synthesis, Structures and Magnetic Properties of 2-Aminomethylpyridine-Ni(II)

Complexes”

104) †Markowitz, B.E.M..*; Turnbull, M.M., Awwadi, F.F. Acta Cryst. E 2006, E62, m1278-80.

“Bis(quinoxaline)dichlorozinc(II)”

105) Brown, M.J.; Henderson, D.E.; Hunt, C.; Turnbull, M.M. E. J. Envi. Ag. Food Chem.

2006, 5, 1265-77. “Comparison of Antioxidant Properties of Supercritical Fluid Extracts of

Herbs and the Confirmation of Pinocembrin as a Principle Antioxidant in Mexican Oregano

(Lippa gravolens).”

106) †Li, L.#, Turnbull, M.M.; Landee, C.P.; Twamley, B. J. Coord. Chem. 2006, 59,1311-20.

(cover article) “ Synthesis, crystal structure and properties of bis(hexafluoroacetylacetonato)

tetrazinecopper(II)”

107) †Andrews,S.*; Corwin,J.*; Landry, B.*; Martin, M.*; Parnass, K.*; Suen, A.#; Turnbull,

M.M.; Schneider, R.T.*; Landee, C.P.; Awwadi, F.F. J. Coord. Chem. 2006, 59, 1451-65.

“Bis(2-Amino-5-bromopyrimidinium) Tetrahalometallates: Crystal Structures of (2-

amino-5-bromopyrimidinium)2 MCl4 (M = Co, Zn).”

108) Hong, T.; Kenzelmann, M.; Turnbull, M.M.; Landee, C.P.; Lewis, B.D.*; Schmidt, K.P.;

Uhrig, G.S.; Qiu, Y.; Broholm, C.; Reich, D.H. Phys. Rev. B. 2006, 74, 094434:1-9.

“Neutron scattering from a coordination polymer quantum paramagnet”

109) †Landry, B.R.*; Turnbull, M.M.; Twamley, B. J. Chem. Cryst. 2007, 37, 81-86. “Synthesis

and Structure of a Novel Copper (II) Nitrate Complex of 2,4-dioxo-4-phenylbutanoic acid”

110) †Shapiro, A.*; Landee, C.P.; Turnbull, M.M.; Jornet, J.; Deumal, M.; Novoa, J.J.; Robb,

M.; Lewis, W. J. Am. Chem. Soc. 2007, 129, 952-9. “Synthesis, Structure and Magnetic

Properties of an Antiferromagnetic Ladder Complex: bis(2,3-dimethylpyridinium)

tetrabromocuprate”

111) Sologubenko, A.V.; Berggold, K.; Lorenz, T.; Rosch, A.; Shimshoni, E.; Phillips, M.D.*;

Turnbull, M.M. Phys. Rev. Lett. 2007, 98, 107201. “Magnetothermal transport in the spin

½ chains of copper pyrazine dinitrate”

112) †Parent, A.R.*; Landee, C.P.; Turnbull, M.M. Inorg. Chim. Acta. 2007, 360, 1943-1953.

‘Transition metal halide salts of N-methylmorpholine: synthesis, crystal structures and

magnetic properties of N-methylmorpholinium salts of copper(II), cobalt(II) and

manganese(II)”

113) †Schneider, R.T.*; Landee, C.P.; Turnbull, M.M.; Awwadi, F.F.; Twamley, B. Polyhedron,

2007, 26, 1849-58. “Copper Azine Compounds: Synthesis, Structure and Magnetic

Properties of Cu(phenazine)Cl2, (Phenazinium)2CuCl4 and [Cu(phenazine)Cl2·H2O]2”

114) †Woodward, F.M.#; Gibson, P.J.*; Jameson, G.; Landee, C.P.; Turnbull, M.M; Willett,

R.D., Inorg. Chem. 2007, 46, 4256-66. “Syntheses, X-ray structures and Magnetic

Behavior of [Cu(pz)2](ClO4)2, [Cu(pz)2](BF4)2 and [Cu(pz)2(NO3)](PF6).”

115) †Markowitz, B.E.M..*; Turnbull, M.M., Awwadi, F.F. Acta Cryst. E 2007, E63, m2043.

“Bis(quinoxaline)dibromozinc(II)”

116) Long, V.C.; Chou, Y.-H.; Cross, I.A.; Schundler, E.C.; Wei, X.; McGill, S.A.; Landry,

B.R.*; Maxcy-Pearson, K.R.*; Turnbull, M.M.; Landee, C.P. Phys. Rev. B 2007, 76,

024439(1-14). “Magnetic field-induced electronic structure modifications in NENB: a

signature of the Haldane gap in the electronic excitation intensities” [and in Virtual Journal

of Nanoscale Science and Technology 2007, 16(7)].

117) †Turnbull, M.M. Acta Cryst. E 2007,E63, m2148. “N-Methylmorpholinium

trichloronickelate”

118) Brown, S.; Cao, J.; Musfeldt, J.L.; Conner, M.M.; McConnell, A.C.; Southerland, H.I.;

Manson, J.L.; Schlueter, J.A.; Phillips, M.D.*, Turnbull, M.M.; Landee, C.P. Inorg. Chem.

2007, 46, 8577-83. “Hydrogen bonding and multiphonon structure in copperpyrazine

coordination polymers”

119) †Li, L.#; Turnbull, M.M.; Landee, C.P.; Jornet, J.; Deumal, M.; Novoa, J.J.; Wikaira, J.L.

Inorg. Chem. 2007,46, 11254-65. “Synthesis, structure and magnetic behavior of bis(2-

amino-5-fluoropyridinium) tetrachlorocuprate(II)”

120) †Parent, A.R.*; Vedachalam, S.&; Landee, C.P.; Turnbull, M.M. J. Coord. Chem. 2008, 61,

93-108. (cover article) “Syntheses, Crystal Structures and Magnetic Properties of

Heteronuclear Bimetallic Compounds of [Cu(pdc)2][M(H2O)5]·2H2O [M = Ni(II), Co(II),

Mn(II); pdc = 2,6-pyridinedicarboxylato]”

121) Sologubenko, A.V.; Berggold, K.; Lorenz, T.; Rosch, A.; Shimshoni, E.; Phillips, M.D.*;

Turnbull, M.M. Physica B 2008, 403, 1445-6. “Magnetic field-dependent thermal transport

in a spin-1/2 chain compound”

122) Sologubenko, A.V.; Lorenz, T.; Mydosh, J.A.; Rosch, A.; Shortsleeves, K.C.*; Turnbull,

M.M.; Phys. Rev. Lett. 2008, 100, 137202. “Field-dependent thermal transport in the

Haldane chain compound NENP”

123) Čižmár, E.; Ozerov, M. Ignatchik, O.; Papageorgiou, T.P.; Wosnitza, J.; Zvyagin, S.A.;

Krzystek, J.; Zhou, Z.; Landee, C.P.; Landry, B.R.*; Turnbull, M.M.; Wikaira, J.L. New J.

Phys. 2008, 10, 033008. “Magnetic Properties of the Haldane-gap material NENB”

124) †Butcher, R.T.#; Landee, C.P.; Turnbull, M.M.; Xiao, F.# Inorg. Chim. Acta. 2008, 361,

3654-58. “Rectangular Two-Dimensional Antiferromagnetic Systems: Analysis of

Copper(II) pyrazine dichloride and dibromide”

125) †Herringer, S.N.*; Turnbull, M.M.; Landee, C.P.; Wikaira, J.L. J. Coord. Chem. 2009, 62,

863-75. (cover article) “Synthesis, Structure, and Magnetic Properties of Bis(3-amino-2-

chloropyridinium) tetrahalocuprate (II) [halide= Cl or Br]”

126) †Butcher, R.T.#; Turnbull, M.M.; Landee, C.P.; Wells, B.M.*; Novoa, J.J.; Ribas-Ariño, J.;

Sandvik, A.W.; Awwadi, F.F. ChemComm. 2009, 1359-61. “Through-space Two-halide

Magnetic Exchange of 2J = -234(1) K in (2,5-Dimethylpyrazine)copper(II) Bromide”

127) Matos, J.; Dudo, T.*; Landee, C.P.; Silva, P.; Turnbull, M.M. The Open Materials Science

Journal 2009, 3, 28-32. “Magnetic behavior at low temperature of carbon foams prepared

by the controlled pyrolysis of saccharose”

128) †Li, L.#; Landee, C.P.; Turnbull, M.M.; Foxman, B.M. J. Coord. Chem. 2009, 62, 1207-17.

“Synthesis and structure determination of bis(hexafluoroacetylacetonato)-

triazinecopper(II)”

129) †Xiao, F.#; Woodward, F.M.#; Landee, C.P.; Turnbull, M.M.; Mielke, C.; Harrison, N.;

Lancaster, T.; Blundell, S.J.; Baker, P.J.; Babkevich, P.; Pratt, F.L. Phys. Rev. B 2009, 79,

134412. “Observation of 2D XY Behavior in quasi-2D Quantum Heisenberg

Antiferromagnets”

130) †Shortsleeves, K.C.*; Dawe, L.N.; Landee, C.P.; Turnbull, M.M. Inorg. Chim. Acta. 2009,

362, 1859-66. “Transition metal complexes of 2-amino-3,5-dihalopyridines: Synthesis,

structures and magnetic properties of Cu(3,5-diCAP)2X2 and Cu(3,5-diBAP)2X2”

131) Čižmár,E.; Ozerov, M.; Wosnitza, J.; Zvyagin, S.A.; Krzystek, J.; Landee,C.P.; Landry,

B.R.*; Turnbull, M.M.; Wikaira, J.L. J. Physics: Confer. Series 2009, 150, 042017.

“Magnetic properties of the Zn-doped Haldane-gap material NENB”

132) Ozerov, M.; Čižmár,E.; Wosnitza, J.; Zvyagin, S.A.; Xiao, F.#; Landee, C.P.; Turnbull,

M.M., J. Physics: Confer. Series 2009, 150, 042159. “Magnetic properties of the S = 1/2

Heisenberg spin-chain material (6MAP)CuCl3”

133) Tsyrulin, N.; Pardini,T.; Singh, R.R.P.; Xiao, F.#; Link, P.; Schneidewind, A.; Hiess, A.;

Landee, C.P.; Turnbull, M.M.; Kenzelmann, M. Phys. Rev. Lett. 2009, 102, 197201.

“Quantum effects in a weakly-frustrated S=1/2 two-dimensional Heisenberg

antiferromagnet in an applied magnetic field” (selected for inclusion in the 2009 ILL

annual report)

134) †Butcher, R.T.#; Dawe, L.N.; Landee, C.P.; Turnbull, M.M. Polyhedron 2009, 28, 1710-3.

“Copper Diazine Ladders: Synthesis, Structure and Magnetic Analyses of Cu(2-

methylthiopyrazine)Br2”

135) Jornet-Somoza, J.; Deumal, M.; Turnbull, M.M.; Novoa, J.J. Polyhedron 2009, 28, 1965-

71. “On the existence of temperature induced changes in the magnetic topology of crystals

that show no first-order crystallographic phase transitions”

136) †Li, L.#; Turnbull, M.M.; Ackers, J.; Chen, J.; Lin, H.; Pan, B.; Wang, H.; Foxman, B.M.

Inorg. Chim. Acta 2009, 362, 3845-52. “Copper(II) complexes of 3-amino-1,2,4-triazine

and 2-aminopyrazine: Strategies for designing crystalline materials using coordination

polymers”

137) Kühne, H.; Klauss, H.-H.; Grossjohann, S.; Brenig, W.; Litterst, F.J.; Reyes, A.P.;

Kuhns, P.L.; Turnbull, M.M.; Landee, C.P. Phys. Rev. B 2009, 80, 045110. “Quantum

critical dynamics of a S = 1/2 antiferromagnetic Heisenberg chain studied by 13C-NMR

spectroscopy” (selected as a “Highlight” by the National High Magnetic Field Laboratory,

Tallahassee, FL).

138) †Tremelling, G.W.*; Foxman, B.M.; Landee, C.P.; Turnbull, M.M.; Willett, R.D. Dalton

Trans. 2009, 10518-26. “Transition metal complexes of 2-amino-3,5-dihalopyridines:

Syntheses, structures and magnetic properties of (3,5-diCAPH)2CuX4 and (3,5-

diBAPH)2CuX4.”

139) †Butcher, R.T.#; Turnbull, M.M.; Shapiro, A.*; Xiao, F.#; Landee, C.P.; Garrett, D.J.;

Robinson, W.T.; Twamley, B. Inorg. Chem. 2010, 49, 427-34. “Crystal structure and

magnetism of a well isolated 2D-Quantum Heisenberg Antiferromagnet,

(Quinolinium)2CuBr4·2H2O and its anhydrous form”

140) Jornet-Somoza, J.; Deumal, M.; Robb, M.A.; Landee, C.P.; Turnbull, M.M.; Feyerherm,

R.; Novoa, J.J. Inorg. Chem. 2010, 49, 1750-60. “The 1D to 3D magnetic transformation

in the copper pyrazine dinitrate S=1/2 antiferromagnetic crystal. A first-principles bottom-

up study”

141) Kühne,H.; Günther, M.; Grossjohann, S.; Brenig, W.; Litterst, F.J.; Reyes, A.P.; Kuhns,

P.L.; Turnbull, M.M.; Landee, C.P.; Klauss, H.-H. Phys. Status Solidi B 2010, 247, 671-5.

(cover article) “Low frequency spin dynamics in the quantum magnet copper pyrazine

dinitrate”

142) White, J.L.; Lee, C.; Günaydin-Şen, Ö.; Tung, L.C.; Christen, H.M.; Wang, Y.J.; Turnbull,

M.M.; Landee, C.P.; McDonald, R.D.; Crooker, S.A.; Singleton, J.; Whangbo, M.-H.;

Musfeldt, J.L. Phys. Rev. B 2010, 81, 052407.1-4. “Magneto-optical properties of charge-

spin coupling in the molecular (2,3-dmpyH) 2CuBr 4 spin-ladder material”

143) †Herringer, S.N.*; Longendyke, A.J.*; Turnbull, M.M.; Landee, C.P.; Wikaira, J.L.;

Jameson, G.B.; Telfer, S.G. Dalton Trans. 2010, 39, 2785-97. “Synthesis, Structure, and

Magnetic Properties of bis(monosubstituted-pyrazine)dihalocopper (II) [where substituent

= Cl, CN, OCH3, OCH2CH3 and halogen = Cl or Br].”

144) Validov, A.A.; Lavrentyeva, E.M.; Ozerov, M.; Zvyagin, S.A.; Turnbull, M.M.; Landee,

C.P.; Teitel’baum, G.B. J. Physics, Conf. Ser. 2010, 200, 022070. “Quantum Critical

Dynamics of S = 1/2 Antiferromagnetic Heisenberg Chains Studied in CuPzN by ESR”

145) Rohrkamp, J.; Phillips, M.D.*; Turnbull, M.M.; Lorenz, T. J. Physics, Conf. Ser. 2010, 200,

012169. “Thermal expansion of the spin-1/2 Heisenberg-chain compound

Cu(C4H4N2)(NO3)2”

146) Günaydin-Şen, Ö.; Lee, C.; Tung, L.C.; Chen, P.; Turnbull, M.M.; Landee, C.P.; Wang,

Y.J.; Whangbo, M.-H.; Musfeldt, J.L. Phys. Rev. B 2010, 81, 104307.1-5. “Spin-lattice

interactions through the quantum critical transition in Cu(pyz)(NO3)2”

147) Tsyrulin, N.; Xiao, F.#; Schneidewind, A.; Link, P.; Rǿnnow, H.M.; Gavilano, J.; Landee,

C.P.; Turnbull, M.M.; Kenzelmann, M. Phys. Rev. B 2010, 81, 134409/1-9. “The two-

dimensional square-lattice S=1/2 antiferromagnet Cu(pz)2(ClO4)2”

148) †Carnevale, D.J.*; Landee, C.P.; Turnbull, M.M.; Winn, M.*; Xiao, F.# J. Coord. Chem.

2010, 63, 2223-38. “Co(II) halide complexes with 2-amino-3-methylpyridinium and 2-

amino-5-methylpyridinium: Synthesis, Crystal Structures and Magnetic Properties”

149) †Wikaira, J.L.; Li, L.#; Butcher, R.; Fitchett, C.M.; Jameson, G.B.; Landee, C.P.; Telfer,

S.G.; Turnbull, M.M. J. Coord. Chem. 2010, 63, 2949-64. “Transition metal complexes of

2-amino-3-chloro-5-trifluoromethylpyridine: Syntheses, structures and magnetic properties

of [(TMCAPH)2CuBr4] and [(TMCAPH)2CuCl4]” (cover article)

150) Jornet-Somoza, J.; Deumal, M.; Landee, C.P.; Turnbull, M.M.; Novoa, J.J Inorg. Chem.

2010, 49, 8017-24. “A Reexamination of the Magnetic Properties of (5MAP)2CuBr4

[5MAP = 5-methyl-2-aminopyridinium].”

151) Hong, T.; Kim, Y.H.; Hotta, C.; Takano, Y.; Tremelling, G.*; Turnbull, M.M.; Landee,

C.P.; Kang, H.-J.; Christensen, N.B.; Lefmann, K.; Schmidt, K.P.; Uhrig, G.S.; Broholm,

C. Phys. Rev. Lett. 2010, 105, 137207(1-4). “Field induced Luttinger-liquid phase in a two-

leg spin-1/2 ladder with strong rail interactions”

152) †Selmani,V.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L.; Xiao, F. Inorg. Chem.

Commun. 2010, 13, 1399-1401. “An Extremely Well Isolated 2D-Antiferromagnetic

Layer”

153) †Ludy, S.J.#; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L. J. Coord. Chem. 2011, 64, 134-

44. “Synthesis, Structure and Magnetic Behavior of a Pyrazine-bridged Cu(II)/Au(CN)2

Complex”

154) Walha, S.; Naïli, H.; Yahyaoui, S.; Ali, B.F.; Turnbull, M.M.; Mhiri, T.; Bataille, T. Sol.

St. Sci., 2011, 13, 204-8. “Crystal structure, thermal analysis and magnetic properties of the

bis(2-amino-5-ammoniopyrinium) hexachloridomanganate(II)”

155) Hong, T.; Gvasalia, S.N.; Herringer, S.#; Turnbull, M.M.; Landee, C.P.; Regnault, L.-P.;

Boehm, M.; Zheludev, A. Phys. Rev. B. 2011, 83, 052401(1-4). “Dynamics of the two-

dimensional S=(1/2) dimer system (C5H6N2F)2CuCl4”

156) †Edwards, K.*; Herringer, S.N.*; Parent, A.R.*; Provost, M.*; Shortsleeves, K.C.*; Turnbull,

M.M.; Dawe, L.N. Inorg. Chim. Acta 2011, 368, 141-51. “Transition Metal Halide Salts of 8-

Methylquinolinium: Crystal Structures of (8-methylquinolinium)2 MX4 · nH2O (M = Cu, Co,

Zn; X = Cl, Br; n = 0,1)”

157) Kühne, H.; Zvyagin, A.A.; Günther, M.; Reyes, A.P.; Kuhns, P.L., Turnbull, M.M.;

Landee, C.P.; Klauss, H.-H. Phys. Rev. Rapid Comm. 2011, 83, 100407(R). “Dynamics of a

Heisenberg spin chain in the quantum critical regime: NMR experiment versus effective

field theory.”

158) †Herringer, S.N.*; Turnbull, M.M.; Landee, C.P.; Wikaira, J.L. Dalton Trans. 2011, 40,

4242-52. “Copper (II) Complexes of 2-halo-3-methylpyridine: Syntheses, Structures, and

Magnetic Behavior of Cu(2-X-3-CH3py)2X’2 [X, X’ = chlorine or bromine; py = pyridine]”

159) Leach, M.T.; Henderson, W.; Wilkins, A.L.; Lane, J.R.; Fortney-Zirker, R.G.; Turnbull,

M.M.; Nicholson, B.K. Inorg. Chim. Acta 2011, 375, 228-35. “Platinum(II) phosphonate

complexes derived from endo-8-campanylphosphonic acid”

160) †Keith, B.C.#; Landee, C.P.; Valleau, T.*; Turnbull, M.M.; Harrison, N. Phys. Rev. B. 2011,

84, 104442 “Rectangular two-dimensional S=1/2 rectangular Heisenberg antiferromagnets;

simulation and experiment”

161) †Keith, B.#; Xiao, F.#; Landee, C.P.; Turnbull, M.M.; Zheludev, A. Polyhedron, 2011, 30,

3006-9. “Random Rung Exchange in the Spin Ladder Cu(quinoxaline)X2 (X = Cl, Br)”

162) Hajlaoui, F.; Naïli, H.; Yahyaoui, S; Turnbull, M.M.; Mhiri, T.; Bataille, T. Dalton Trans.

2011, 40, 11613-20. “Synthesis, Characterization and Magnetic Properties of Four New

Organically Templated Metal Sulfates: [C5H14N2][MII(H2O)6](SO4)2 (M

II = Mn, Fe, Co,

Ni)”

163) Ninios, K.; Hong, T.; Manabe, T.; Hotta, C.; Herringer, S.N.#; Turnbull, M.M.; Landee,

C.P.; Takano, Y.; Chan, H.B. Phys. Rev. Lett., 2012, 108, 097201.1-5. “Wilson ratio of a

Tomonaga-Luttinger liquid in a spin-1/2 Heisenberg Ladder”

164) Schlueter, J.A.; Park, H.; Halder, G.J.; Armand, W.R.; Dunmars, C.; Chapman, K.W.;

Manson, J.L.; Singleton, J.; McDonald, R.; Plonczak, A.; Kang, J.; Lee, C.; Whangbo, M.-

H.; Lancaster, T.; Steele, A.J.; Franke, I.; Wright, J.M.; Blundell, S.J.; Pratt, F.L.;

DeGeorge, J.*; Turnbull, M.M.; Landee, C.P. Inorg. Chem.2012, 51, 2121-29. “Importance

of Halogen···Halogen Contacts for the Structural and Magnetic Properties of Cu(pyrazine-

N,N′-dioxide)(H2O)2X2 (X = Cl, Br)”

165) †Abdalrahman, M.*; Landee, C.P.; Telfer, S.; Turnbull, M.M.; Wikaira, J.L. Inorg. Chim.

Acta, 2012, 389, 66-76. “Copper(II) halide coordination complexes and salts of 3-halo-2-

methylpyridines: Synthesis, structure and magnetism”

166) Rademeyer, M.; Turnbull, M.M.; Landee, C.P.; Kunene, M.; Liles, D.C. Sol. St. Sci. 2012,

14, 1106-10. “Crystal structure and magnetic properties of catena-poly[[bromido[trans

(1S,2S)/(1R,2R)-cyclohexane-1,2-diamine copper(II)]-3-bromido]”

167) Husain, A.; Turnbull, M.M.; Nami, S.A.A.; Moheman, A.; Siddiqi, K.S. J.Coord. Chem.

2012, 65, 2593-611. “Synthesis, Crystal structure and magnetic properties of single end-to-

end azido bridged 1D chain coordination polymers of copper(II)”

168) †Jornet-Somoza, J.; Codina-Castillo, N.; Deumal, M.; Mota, F.; Novoa, J.J.; Butcher, R.T.#;

Turnbull, M.M.; Keith, B.#; Landee, C.P.; Wikaira, J.L. Inorg. Chem. 2012, 51, 6315-25.

“Synthesis, structure, magnetic behavior and theoretical analysis of diazine-bridged

magnetic ladders: Cu(quinoxoline)X2 and Cu(2,3-dimethylpyrazine)X2 (X = Cl, Br)”

169) †Awwadi, F.F.; Dawe, L.N.; Landee, C.P.; Turnbull, M.M. J. Coord. Chem. 2012, 65, 3064-

74. “Catena-Bis(aqua(3-oxy-2-pyridono)copper(II))µ-pyrazine diperchlorate: a perchlorate

bridged magnetic ladder”

170) Kuppuswamy, S.; Bezpalko, M.W.; Powers, T.M.; Turnbull, M.M.; Foxman,B.M.;

Thomas, C.M. Inorg. Chem. 2012, 51, 8225-40. “Utilization of Phosphinoamide Ligands in

Homobimetallic Fe and Mn Complexes: The Effect of Vastly Different Coordination

Environments on Metal-Metal Interactions and Magnetic and Redox Properties”

171) Datta, A.; Liu, P.-H.; Huang, J.-H.; Garribba, E.; Turnbull, M. ; Machura, B.; Hsu, C.-L.;

Chang, W.-T.; Pevec, A. Polyhedron 2012, 44, 77-87. “End-to-end Thiocyanato-Bridged

Zig-zag Polymers of CuII, CoII and NiII with a Hydrazone Ligand : EPR, Magnetic

Susceptibility and Biological Study”

172) Henderson, W.; Oliver, A.G.; Turnbull, M.M., Inorg. Chem. Comm. 2013, 27, 142-5.

“Iron(III) complexes of the metalloligand [Pt2(µ-S)2(PPh3)4]”

173) Walha, S.; Naïli, H.; Yahyaoui, S.; Ali, B.F.; Turnbull, M.M.; Mhiri, T; Ng, S.W. J.

Supercon. Nov. Mag. 2013, 26, 437-42. “Three dimensional network polymeric structure

of (2-amino-5 ammoniopyridinium)[CuCl4]: Crystal supramolecularity and magnetic

properties”

174) Vela, S.; Deumal, M.; Turnbull, M.M.; Novoa, J.J. Theoretical Chemistry Accounts, 2013,

132, 1-12. “A rigorous theoretical analysis on the magnetics properties of the low

dimensional copper(II)-2-X-3-methylpyridine (X = Cl and Br) complexes.”

175) †deGeorge, J.*; Landee, C.P.; Turnbull, M.M. Acta Cryst. E. 2013, E69, o471.

“Phenazinium bisulfate monohydrate” http://dx.doi.org/10.1107/S160053681300562X

176) † Wikaira, J.L.; Landee, C.P.; Turnbull, M.M. Acta Cryst E. 2013, E69, m229-30.

“Hexaaquacopper(II) tetrafluoroborate tris-1,4-pyrazinedioxide”

177) †Gale, A.*; Landee; C.P.; Turnbull, M.M.; Wikaira, J.L. Polyhedron 2013, 62, 986-91.

“Synthesis, Structure, and Magnetism of two tetrahalocuprate salts: (5-TFAPH)2CuX4 (5-

TFAP = 2-amino-5-trifluoromethylpyridine, X = Cl, Br)”

178) Vela, S.; Deumal, M.; Turnbull, M.M.; Novoa, J.J. Polyhedron 2013, 62, 699-705.

“Assigning the dimensionality in low-dimensional materials: a rigorous study of the

dimensionality of (2,5-dimethylpyrazine)CuCl2”

179) †Wikaira, J.L.; Landee, C.P.; Ludy, S.J.#; Turnbull, M.M. Polyhedron 2013, 62, 770-80.

“Tetrahalocuprate salts of substituted 4-aminopyridines: Synthesis, Structure and Magnetic

Properties”

180) †Wikaira, J.L.; Landee, C.P.; Turnbull, M.M. Acta Cryst. E 2013, E69, m229-30.

“Hexaaquacopper(II) bis(tetrafluoridoborate)–pyrazine-1,4-dioxide (1/3)”

http://dx.doi.org/10.1107/S1600536813007629

181) Awwadi,F.F.; Haddad, S.F.; Turnbull, M.M.; Landee, C.P.; Willett, R.D. CrystEngComm

2013, 15, 3111-8. “Copper-halide Bonds as Magnetic Tunnels; Structural, Magnetic and

Theoretical Studies of trans-Bis(2,5-dibromopyridine)dihalocopper(II) and trans-Bis(2-

bromopyridine)dibromocopper(II)”

182) †Landee, C.P.; Turnbull, M.M. Eur. J. Inorg. Chem. 2013, 2266-85. “Recent

Developments in Low-Dimensional Cu(II) Molecular Magnets” (cover article and research

profile, pg. 2250)

183) †Abdalrahman, M.A.*; Awwadi, F.F.; Jameson, G.B.; Landee, C.P.; Saunders, C.G.;

Turnbull, M.M.; Wikaira, J.L., CrystEngComm 2013, 15, 4309-20. “Effects of Halogen and

Hydrogen Bonding on Defect Disorder: The Ladder That Wasn’t There”

184) †Solomon, B.L.*; Landee, C.P.; Jasinski, J.P.;Turnbull, M.M. Eur. Chem. Bull. 2013, 2,

845-9. “Synthesis, Structure, and Magnetic Behavior of [Cu2(pyrazine)3(CH3O)2] (ClO4)2”

185) †Turnbull, M.M.; Bruda, S.#; Wikaira, J.L. Eur. Chem. Bull. 2013, 2, 2038-40. “[(N-(2-

pyridylcarboyl)pyridine-2-carbamido)(pyridine-2-carbamide)-copper(II)] nitrate dihydrate”

186) Vela, S.; Deumal, M.; Turnbull, M.M.; Novoa, J.J. Polyhedron 2013, 64, 163-71. “A

theoretical analysis of the magnetic properties of the low dimensional copper(II)-dichloro-

(2-Cl-pyrazine)2 molecule-based magnet”

187) †Shortsleeves, K.C.*; Turnbull, M.M.; Seith, C.B.*; Tripodakis, E.N.*; Xiao, F.#; Landee,

C.P.; Dawe, L.N.; Garrett, D.; Diaz de Delgado, G.; Foxman, B.M. Polyhedron 2013, 64,

110-21. “Crystallographic and Magnetic Studies of the 2-Pyridone/Copper Halide System”

188) †Polson, M.; Turnbull, M.M.; Wikaira, J.L. Acta Cryst. C. 2013, C69, 1152-6. “2-Amino-5-

iodopyridinium chloride sesquihydrate and 2-amino-5-iodopyridinium

bromide hemihydrate”

189) †Bruda, S.#; Turnbull, M.M.; Wikaira, J.L. Acta Cryst E 2013, E69, m598-9. “[(N-(2-

pyridylcarboyl)pyridine2-carboxamido)(azido)(aqua)copper(II)]”

190) †Nye, L.N.*; Turnbull, M.M.; Wikaira, J.L. Acta Cryst C. 2013, C69, 1317-21. “3,4-

Dihydroxy-1,6-di(4-methoxyphenyl)-2,4-hexadiene-1,6-dione and catena-(μ-(4-

methoxyphenyl-2-hydroxy-4-oxo-2-butenoato)-μ (4-methoxyphenyl- 2-hydroxy-4-oxo-2-

butenoic acid) potassium”

191) Vela, S.; Jornet-Somoza, J.; Turnbull, M.M.; Feyerherm, R.; Novoa, J.J.; Deumal, M.

Inorg. Chem. 2013, 52, 12923-32. “The role of pyrazine ligands and perchlorate

counterions in the magnetic properties of [Cu(pz)2](ClO4)2”

192) Validov, A.A.; Ozerov, M.; Wosnitza, J.; Zvyagin, S.A.; Turnbull, M.M.; Landee, C.P.

Teitel’baum, G.B. J.Phys.-Cond. Matt. 2014, 26, 026003:1-5. “ESR of coupled spin-1/2

chains: unveiling zig-zag-type interchain correlations”

193) †Forman, R.L.*; Landee, C.P.; Wikaira, J.L.; Turnbull, M.M. Eur. Chem. Bull. 2014, 3, 190-

4. “Synthesis, structure, and magnetic behavior of [Cu2(2-amino-5-

(trifluoromethyl)pyridine)4(OH)2](ClO4)2•(2-amino-5-(trifluoromethyl)pyridine)2”

194) Awwadi, F.F.; Taher, D.; Haddad, S.F.; Turnbull, M.M. Cryst.Grw.Des. 2014, 14, 1961-71.

“The Competition Between Hydrogen and Halogen Bonding Interactions: Theoretical and

Crystallographic Studies”

195) †Landee, C.P.; Turnbull, M.M. J. Coord. Chem., 2014, 67, 375-439. “A gentle introduction

to magnetism: units, fields, theory, and experiment”

196) Hong,T.; Schmidt, K.P.; Coester, K.; Awwadi, F.F.; Turnbull, M.M.; Qiu, Y.; Rodriguez,

J.A.; Zhu, M.; Ke, X.; Aoyama, C.P.; Takano, Y.; Cao, H.; Tian, W.; Ma, J.; Custelcean, R.;

Zhou, H.D.; Matsuda, M. Phys. Rev. B 2104, 89, 174432. “Magnetic ordering induced by

interladder coupling in the spin-1/2 Heisenberg two-leg ladder antiferromagnet

C9H18N2CuBr4”

197) Kono,Y.; Sakakibara, T.; Aoyama, C.P.; Turnbull, M.M.; Landee, C.P.; Takano, Y. J.

Phys. Soc. Jpn. Conference Proceedings 2014, 3, 012015 (1-5). “Magnetization Study of

the Quantum Critical Behavior of the One Dimensional Spin-1/2 Heisenberg

Antiferromagnet CuPzN” Proceedings of the International Conference on Strongly

Correlated Electron Systems 2013.

198) Ben Salah, A.M.; Walha,S.; Yahyaoui, S.; Abdalrahman, M.*; Turnbull, M.M.; Mhiri, T.;

Bataille; Naïli, H. Monat. fur Chem. 2014, 145, 1575-81. “Crystal growth, thermal and

magnetic properties of a ferromagnetic Ni(II) dimer single crystal”

199) †Herringer,S.N.#; Deumal, M.; Ribas-Ariño, J.; Novoa, J.J.; Landee, C.P.; Wikaira, J.L.;

Turnbull, M.M. Chem.-Eur. J. 2014, 20, 8355-62. “A S=1/2 1-Dimensional Random-

Exchange Ferromagnetic Zigzag-Ladder Which Exhibits Competing Interactions in a

Critical Regime”

200) †Solomon, B.L.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L. J. Coord. Chem. 2014, 67,

3953-71. “Transition metal complexes of 2-amino-5-chloro-3-fluoropyridine: Syntheses

and magnetic properties of (3,5-FCAP)2CuX2 and (3,5-FCAPH)2CuX4”

201) Fortune, N.A.; Hannahs, S.T.; Landee, C.P.; Turnbull, M.M.; Xiao, F.# J. Phys.: Conf. Ser.

2014, 568, 042004. “Magnetic-field-induced Heisenberg to XY crossover in a quasi-2D

quantum antiferromagnets”

202) Kono, Y.; Sakakibara, T.; Aoyama, C.P.; Hotta, C.; Turnbull, M.M.; Landee, C.P. Takano,

Y. Phys. Rev. Lett., 2015, 114, 037202/1-5. “Field-Induced Quantum Criticality and

Universal Temperature Dependence of the Magnetization of a Spin-1/2 Heisenberg Chain”

203) †Forman, R.L.*; Gale, A.J.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L. Polyhedron 2015,

89, 76-84. “Synthesis, structure and magnetic properties of copper(II) complexes of 2-

amino-5-trifluoromethyl pyridine (5-TFMAP): (5-TFMAP)2CuX2,( X = Cl or Br), (5-

TFMAP)3CuBr2 and [(5-TFMAP)2CuBr2](5-TFMAPH)Br”

204) †Bellesis, A.G.*; Landee, C.P.; Polson, M.; Turnbull, M.M.; Wikaira, J.L. Eur. Chem. Bull.

2015, 4, 110-16. “Serendipitous Synthesis of a Cu(OAc)2 complex VIA CuCl2 Catalyzed

Oxidation of 2-butanone: Synthesis, Crystal Structure, and Magnetic Behavior of (5-

NAP)2(CH3COO)4Cu2∙nH2O (n = 0 and 2) (5-NAP=2-amino-5-nitropyridine)”

205) Awwadi, F.F.; Willett, R.D.; Twamley, B.; Turnbull, M.M.; Landee, C.P. Cryst. Growth

Des. 2015, 15, 3746-54. “The Dual Behavior of Bromine Atoms in Supramolecular

Chemistry; The Crystal Structure and Magnetic Properties of Two Copper(II) Coordination

Polymers.”

206) †Hobson, A.D.; Konopacki, D.; Shortsleeves, K.C.#; Turnbull, M.M.; Wikaira, J.L. Eur. J.

Org. Chem. 2015, 5453-63. "Lewis Acid Catalyzed Cyclizations of Epoxidized Baylis–

Hillman Products: A Straightforward Synthesis of Octahydro­ benzo[e]azulenes"

207) Ozerov, M.; Maksymenko, M.; Wosnitza, J.; Honecker, A.; Landee, C.P.; Turnbull, M.M.;

Furuya, S.C.; Giamarchi, T.; Zvyagin, S.A. Phys. Rev. B-Rapid Commun. 2015, 92,

241113(R) (1-5). “ESR modes in a Strong-Leg Ladder in the Tomonaga-Luttinger Liquid

Phase”

208) †Wikaira, J.L.; Butcher, R.J.; Kersen, U.; Turnbull, M.M., J. Coord. Chem. 2016, 69, 57-

71. “Magnetic properties of 4,4’-bipiperidinediium tetrahalocuprates: Crystal structures of

4,4’-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4’-bipiperidinediium)

hexabromodicuprate(I)”

209) O’Neal, K.R.; Zhou, J.; Cherian, J.G.; Turnbull, M.M.; Landee, C.P. Jena, P.; Liu, Z.;

Musfeldt, J. L. Phys. Rev. B. 2016, 93, 104409(1-5). “High pressure properties of the S=1/2

quasi-one-dimensional Heisenberg antiferromagnet copper pyrazine dinitrate”

210) †Monk, M.C.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L. Eur. Chem. Bull. 2016, 5, 54-

59. “Synthesis, Structure and magnetic properties of a copper (II) complex of 5-nitro-2-

hydroxypyridine and pyrazine: [Cu(5-NO2 -2-HOPY)(pz)2(H2O)] (ClO4)2∙H2O”

211) Lada, Z.G.; Beobide, A.S.; Savvidou, A.; Raptopoulou, C.P.; Psycharis, V.; Voyiatzis,

G.A.; Turnbull, M.M.; Perlepes, S.P. Dalton Trans. 2017, 46, 260-74. "A unique

copper(II)-assisted transformation of acetylacetone dioxime in acetone that leads to one-

dimensional, quinoxaline-bridged coordination polymers"

212) Möller, J.S.; Lancaster, T.; Blundell, S.J.; Pratt, F.L.; Baker, P.J.; Xiao, F.; Williams, R.C;

Hayes, W.; Turnbull, M.M.; Landee, C.P. Phys. Rev. B – Rapid Comm. 2017, 95,

020402(R) (1-5). “Universal scaling of local spin correlations in a Tomonaga-Luttinger

liquid probed with μ+SR”

213) †Krasinski, C.A.*; Solomon, B.L.*; Awwadi, F.F.; Landee, C.P.; Turnbull, M.M.; Wikaira,

J.L. J. Coord. Chem. 2017, 70, 914-35. "Copper(II) halide salts and complexes of 4-

amino-2-fluoropyridine: Synthesis, structure and magnetic properties"

214) Vela, S.; Reardon, M.B.#; Jakobsche, C.E.; Turnbull, M.M.; Ribas-Arino, J.; Novoa, J.J.

Chem. Eur. J. 2017, 23, 3479-89. “Bistability in organic magnetic materials. A comparative

study of the key differences between hysteretic and non-hysteretic spin transitions in

dithiazolyl radicals“

215) Dgachi, S.; Saïd, S.; Naïli, H.; Monroe, J.C.#; Turnbull, M.M. J. Alloys and Comp. 2017,

709. 356-61. “Magneto-structural correlations in a Bromo-Bridged Dimer: Structural and

Magnetic Characterizations of novel Copper(II) cluster constructed from an unusual planar

seesaw geometry.”

216) Hong, T.; Qiu, T.; Matsumoto, M.; Tennant, D.A.; Coester, K.; Schmidt, K.P; Awwadi,

F.F.; Turnbull, M.M.; Agarwal, H.; Chernyshev, A.L. Nature Comm. 2017, 8, 15148(1-8).

“Field-induced spontaneous quasiparticle decay and renormalization of quasiparticle

dispersion in a quantum antiferromagnet”

217) †Herringer, S.N.#; Landee, C.P.; Turnbull, M.M.; Ribas-Ariño, J.; Novoa, J.J.; Polson, P.;

Wikaira, J.L Inorg. Chem. 2017, 56, 5441-54. "Ferromagnetic Exchange in Bichloride

Bridged Cu(II) Chains: Magnetostructural correlations between ordered and disordered

systems"

218) Hong, T.; Matsumoto, M.; Qiu, Y.; Chen, W.; Gentile, T.; Watson, S.; Awwadi, F.F.;

Turnbull, M.M.; Dissanayake, S.E.; Agrawal, H.; Toft-Petersen, R.; Klemke, B.; Coester,

K.; Schmidt, K.P.; Tennant, D.A. Nature Physics 2017, 13, 638-42. “Higgs amplitude

mode in a two-dimensional quantum antiferromagnet near the quantum critical point.”

Accepted/In Press

219) Dgachi, S.; Ben Salaha, A.M.; Turnbull, M.M.; Naïli, H. submitted for publication in J.

Alloys Cmpds. “Investigations on (C6H9N2)2[MIIBr4] halogenometallate complexes with

MII = Co, Cu and Zn: Crystal structure, thermal behavior and magnetic properties.”

Encyclopedia Entries 31) †Turnbull, M.M., Encyclopedia of Reagents for Organic Synthesis, ed. Leo Paquette, 1996,

John Wiley and Sons. "Dicarbonyl(cyclopentadienyl)-(isobutylene)iron Tetrafluoroborate".

101) †Landee, C.P.; Turnbull, M.M., Encyclopedia of Inorganic Chemistry, 2nd ed., Ed. R.B. King,

2005, John Wiley and Sons. “Magnetism in Extended Arrays of Inorganic Solids”

DOI: 10.1002/0470862106.ia124

Edited Volumes 37) †Molecule-Based Magnetic Materials: Theory, Techniques, and Applications, Turnbull, M.M.

Sugimoto, T.; Thompson, L.K., Eds.; ACS Symposium Series 644; American Chemical

Society: Washington, D.C., Dec. 1996.

Book Reviews

Magnetism: Molecules to Materials V. Ed. J.S. Miller and M. Drillon. Wiley-VCH Verlag

GmbH & Co. KGaA: Weinheim. 2005. xiv + 381 pp. ISBN: 3-527-30665. Review published in

J. Am. Chem. Soc. 2005, 127(39), 13739.

Reports N. Tsyrulin, T. Pardini, R. R. P. Singh, F. Xiao, P. Link, A. Schneidewind, A. Hiess, C. P.

Landee, M. M. Turnbull, M. Kenzelmann 2009 Annual Report of the Institut Laue-Langevin,

(ILL) “Quantum Effects in a Weakly-Frustrated S=1/2 Two-Dimensional Square-Lattice

Antiferromagnet in Zero and Applied Magnetic Field”

* Clark Undergraduate Student Co-author

# Clark Graduate Student Co-author

& High School Student conducting research at Clark

† Principle Author and/or Work Done at Clark

Papers Presented at Meetings (Last five years)

Xiao, F.; Landee, C.P.; Turnbull, M.; Fortune, N.; Hannahs, S. March Meeting of the American

Physical Society, Feb. 27-Mar. 2, 2012, Boston MA. ABS: T13.0000001.

“Magnetic phase diagram of quasi-2D quantum Heisenberg antiferromagnets with XY

anisotropy” (presented by C. Landee).

Ozerov, M.; Woxnitza, J.; Xiao, F.; Turnbull, M.M.; Landee, C.P.; Zvyagin, S.A. International

Workshop on Strongly Correlated Electron Systems in High Magnetic Fields, Grenoble, France,

May 20-25, 2012. “High-field electron spin resonance ina a spin-1/2 ladder with strong leg

interactions” (presented by M. Ozerov)

Herringer, S.N.; Turnbull, M.M.; Landee, C.P.; Ribas-Ariño, J.; Novoa, J.J. American

Crystallographic Association Annual Meeting, July 28-August 1, 2012, Boston MA. Abs.

13.02.05 “Effects of Random Exchange in Ferromagnetic Copper Chloride Chains” (presented

by S.N. Herringer)

Turnbull, M.M.; Abdalrahman,M.; Gale, A.J.; Herringer, S.N.; Xiao, F.; Landee, C.P.; Deumal,

M.; Ribas-Ariño, J.; Vela, S.; Novoa, J.J.; Dawe, L.N.; Wikaira, J.L. INDABA-7 Conference

‘Insights from Structure’, Skukuza, South Africa, Sept. 2-7, 2012. (Abstracts book pg. 145)

“Magneto-structural correlations in low-dimensional copper(II) complexes”

Rademeyer, M.; van der Westhuizen, B.; Kunene, M.; Overbeek, G.; Liles, D.C.; Turnbull,

M.M.; Landee, C.P. INDABA-7 Conference ‘Insights from Structure’, Skukuza, South Africa,

Sept. 2-7, 2012.(Abstracts Book pg. 141) “Structures and Magnetic Properties of Hybrid

Materials” (presented by Prof. Melanie Rademeyer)

Landee, C.P.; Awwadi, F.F.; Dawe, L.N.; Turnbull, M.M. XIII International Conference on

Molecule-based Magnets, Orlando, FL, Oct. 7-11, 2012. Abs: MC-05. “An AFM/FM spin

ladder” (presented by C.P. Landee)

Wikaira, J.L.; Landee, C.P.; Ludy, S.J.; Turnbull, M.M. AsCA-12, Adelaide, Australia, Dec. 2-

5, 2012. “Synthesis, Structure and Magnetic Properties of 4-Aminopyridinium

Tetrahalocuprates” (presented by Dr. Jan Wikaira).

Hong, T.; Ninios, K.; Kim, Y.H.; Manabe, T.; Hotta, C.; Tremelling, G.; Herringer, S.N.;

Turnbull, M.M.; Landee, C.; Kang, H.-J. Schmidt, K.P., Uhrig, G.S.; Chan, H.B.; Broholm, C.;

Takano, Y. March Meeting of the American Physical Society, Mar. 18-22, 2013, Baltimore, MD.

Abstract: G16.00005 : “Wilson ratio of a Tomonaga-Luttinger liquid in a spin-1/2 Heisenberg

ladder” (Presented by Tao Hong)

Kuehne, H.; Reyes, A.P.; Kuhns, P.L.; Zvyagin, A.A.; Grossjohann, S.; Brenig, W.; Guenther,

M.; Klauss, H.-H.; Landee, C.P.; Turnbull, M.M. March Meeting of the American Physical

Society, Mar. 18-22, 2013, Baltimore, MD. Abstract: G16.00013 : “Quantum critical dynamics

in the one-dimensional spin chain compound copper pyrazine dinitrate probed by NMR

spectroscopy” (Presented by Hannes Kuehne)

Marino, K.E.; Aoyama, C.P.; Turnbull, M.M.; Landee, C.P.; Takano, Y. March Meeting of the

American Physical Society, Mar. 18-22, 2013, Baltimore, MD. Abstract: A46.00010 :

“Magnetic-Field Dependence of the Spinon Velocity in the S=1/2 Linear-Chain Heisenberg

Antiferromagnet Copper Pyrazine Dinitrate” (presented by K.E. Marino)

Landee, C.; Xiao, F.; Turnbull, M.; Bartolomé, J. March Meeting of the American Physical

Society, Mar. 18-22, 2013, Baltimore, MD. Abstract: G16.00008 : “Low-temperature studies of a

2D Quantum Heisenberg Antiferromagnet” (presented by C.P. Landee)

Kono, Y.; Sakakibara, T.; Aoyama,C.; Turnbull, M.M.; Landee, C.P.; Takano, Y., Fall Meeting

of the Physical Society of Japan, September 25-28, 2013, Tokushima, Japan "Quantum criticality

in the quasi-one-dimensional S=1/2 Heiseneberg antiferromagnet CuPzN" (presented by Y.

Kano)

Hong, T.; Schmidt, K.P.; Coester, K.; Awwadi, F.F.; Turnbull, M.M.; Qiu, Y.; Rodriguez, J.A.;

Ke, X.; Aoyama, C.; Takano, Y.; Cao, H.; Tian, W.; Ma, J.; Custelcean, R.; Zhou, H.D.;

Matsuda, M.; March Meeting of the American Physical Society, Mar. 3-7, 2014, Denver, CO.

Abstract: A54.00003. “Impact of inter-ladder coupling in a coupled spin-1/2 two-leg ladder”

(presented by T. Hong)

Landee, C.P.; Herringer, S.N.; Turnbull, M.M.; Ribas, J.; Novoa, J.J.; March Meeting of the

American Physical Society, Mar. 3-7, 2014, Denver, CO. Abstract: Y4.00002. “A new S = 1/2

frustrated ferromagnetic chain with random exchange” (presented by C.P. Landee)

Herringer, S.N.; Deumal, M.; Ribas-Arino, J.; Novoa, J.J.; Landee, C.P.; Wikaira, J.L.; Turnbull,

M.M. XIV International Conference on Molecule-based Magnets, , July 5-9, 2014, St.

Petersburg, Russia. Abs: O-36. “A S=1/2 1-dimensional random-exchange ferromagnetic zigzag-

ladder with exhibits competing interactions in a critical regime”

Rademeyer, M.; Bothma, S.; Coetzee, S.; Liles, D.C; Turnbull, M.M.; Landee, C.P. 23rd

Congress and General Assembly of the International Union of Crystallography, August 5-12,

2014, Montreal, Quebec, Canada. “Magneto-structural relationships in Cu(II)-containing hybrid

materials” (presented by M. Rademeyer)

Landee, C.P.; Naitlho, N.; Turnbull, M.M.; March Meeting of the American Physical Society,

Mar. 2-6, 2015, San Antonio, Texas. Abstract: M31.00005 : “An extremely well-isolated 2D

antiferromagnets” (presented by C.P. Landee)

O’Neal, K.; Cherian, J.; Landee, C.P.; Turnbull, M.M.; Liu, Z.; Musfeldt, J.; March Meeting of

the American Physical Society, Mar. 2-6, 2015, San Antonio, Texas. Abstract: Y31.00005 :

“Pressure-induced structural distortions in copper pyrazine dinitrate” (presented by J. Musfeldt)

Aoyama, C.; Kono, Y.; Marino, K.; Zhou, H.; Hotta, C.; Turnbull, M.M.; Landee, C.P.;

Sakakibara, T.; Takano, Y.; March Meeting of the American Physical Society, Mar. 2-6, 2015,

San Antonio, Texas. Abstract: Y31.00006 : “Wilson ratio of a Tomonaga-Luttinger liquid in the

one-dimensional spin-1/2 Heisenberg antiferromagnet CuPzN” (presented by C. Aoyama)

Monroe, J.C.#; Turnbull, M.M.; Landee, C.P. 40th Northeast Regional Meeting of the American

Chemical Society, June 10-13, 2015, Ithaca, NY. ABS-48 “Investigations of a well isolated 2-

dimensional quantum Heisenberg antiferromagnets: EPR and SQUID studies of

(quinolinium)2Cu1-xZnxBr4·2H2O ” (presented by Jeff Monroe)

Monk, M.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L. 40th Northeast Regional Meeting of the

American Chemical Society, June 10-13, 2015, Ithaca, NY. ABS-132 “The effect of 2-pyridone

substitutions on the magnetic exchange of pyrazine in 2-pyridone/pyrazine linear-chain

complexes of copper (II) perchlorate” (presented by Meghan Monk)

Farris, P.C.*; Chellali, J.E.*; Landee, C.P.; Turnbull, M.M. 40th Northeast Regional Meeting of

the American Chemical Society, June 10-13, 2015, Ithaca, NY. ABS-133 “The

mechanochemical synthesis of 2-amino-5-substitutedpyridine copper(II) halide complexes and

their magnetic properties” (presented by Penelope Farris and Jonathan Chellali)

Richardson, A.D.*; Zirkman, T.J.*; Landee, C.P.; Turnbull, M.M.; Rademeyer, M. 40th Northeast

Regional Meeting of the American Chemical Society, June 10-13, 2015, Ithaca, NY. ABS-134

“Synthesis, structure and magnetic behavior of a family of Copper(II) halide/isoquinoline salts

and complexes” (presented by Alistair Richardson and TJ Zirkman)

Krasinski, C.A.*; Solomon, B.L.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L. 40th Northeast

Regional Meeting of the American Chemical Society, June 10-13, 2015, Ithaca, NY. ABS-183

“Copper(II) halide salts and complexes of 4-amino-2-fluoropyridine: Syntheses, structures and

magnetic properties”

Bellesis, A.G.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L.; Polson, M. 40th Northeast Regional

Meeting of the American Chemical Society, June 10-13, 2015, Ithaca, NY. ABS-261 “Unusual

redox reactions in the synthesis of copper coordination compounds: The synthesis of bis(5-

NAP)CuCl2 and multiple polymorphs of bis(5NAPH)CuCl4” (presented by Andrew Bellesis)

Hong, T.; Qiu, Y.; Coester, K.; Schmidt, K.P.; Awwadi, F.F.; Turnbull, M.M.; Tennant, D.A.

Physical Phenomena at High Magnetic Fields, Tallahassee, FL, Jan. 6-9, 2016. “Magnetic Field-

Induced Spontaneous Magnon Decay in a Spin-1/2 Coupled Two-Leg Ladder Antiferromagnet

C9H18N2CuBr4”

Hong, T.; Qiu, Y.; Tennant, D.A.; Coester, K.; Schmidt, K.P.; Awwadi, F.F.; Turnbull, M.M.

March Meeting of the American Physical Society, Mar. 14-18, 2016, Baltimore, MD. Abstract:

H21.00008. “Field-induced spontaneous magnon decay in a spin-1/2 coupled two-leg ladder

antiferromagnet C9H18N2CuBr4 with small Ising anisotropy”

Zvyagin, S.; Ozerov, M.; Maksymenko, M.; Wosnitza, J.; Honecker, A.; Landee, C.P.; Turnbull,

M.M.; Furuya, S.C.; Giamarchi, T. March Meeting of the American Physical Society, Mar. 14-

18, 2016, Baltimore, MD. Abstract: H21.00007: “ESR modes in a Strong-Leg Ladder in the

Tomonaga-Luttinger Liquid Phase”

Saïd, S.; Naïle, H.; Monroe, J.C.#; Landee, C.P.; Turnbull, M.M. XV International Conference on

Molecule-based Magnets, Sept. 4-8, 2016, Sendai, Japan. Abs: 5P-025. “Preparation, structure

and magnetic properties of an antiferromagnetic strong-rail/ferromagnetic rung spin ladder:

(PhCH2NEt3)2Cu2Br6”

Chellali, J.E.*; Farris, P.C.*; Landee, C.P.; Turnbull, M.M. 41st Northeast Regional Meeting of

the American Chemical Society, Oct. 5-8, 2016, Binghamton, NY. ABS-026 “Mechanochemical

synthesis of [LnCuX2] (L = 3-cyanopyridine, 2-amino-3-cyanopyridine, 2-amino-5-

cyanopyridine; n = 1, 2; X = Cl, Br] via drop-solvent grinding” (presented by J.E. Chellali)

Monroe, J.C.#; Landee, C.P.; Rademeyer, M.; Greenaway, F.T.; Turnbull, M.M. 41st Northeast

Regional Meeting of the American Chemical Society, Oct. 5-8, 2016, Binghamton, NY. ABS-

029 “Structural, magnetic and EPR results for a family of weakly interaction copper(II) halide

compound with 1,4’-bipyridinium” (presented by J.C. Monroe)

Farris, P.C.*; Landee, C.P.; Turnbull, M.M.; Wall, A.D.*; Wikaira, J.L. 41st Northeast Regional

Meeting of the American Chemical Society, Oct. 5-8, 2016, Binghamton, NY. ABS-030

“Mechanochemical synthesis of copper(II) halide complexes: Synthesis, structure and magnetic

properties of 2-amino-5-bromo- and 2-amino-5-chloropyridine complexes”

Cipi, J.*; Landee, C.P.; Turnbull, M.M.; Wikaira, J.L. 41st Northeast Regional Meeting of the

American Chemical Society, Oct. 5-8, 2016, Binghamton, NY. ABS-454. “Transition metal

complexes of 2-amino-3,5-dihalopyridines: Synthesis, structures and magnetic properties of (3,5-

diCAP)2Cu2X6 and (3,5-diBAP)2Cu2X6” (presented by J. Cipi)

Kebede, M.T.*; Landee, C.P.; Rademeyer, M.; Turnbull, M.M. 41st Northeast Regional Meeting

of the American Chemical Society, Oct. 5-8, 2016, Binghamton, NY. ABS-468. “Synthesis,

structure and magnetic behavior of nickel (II) and cobalt (II) halide complexes of isoquinoline.”

(presented by M.T. Kebede)

Perlepes, S.P.; Lada. Z.G.; Katasoulakou, E.; Kitos, A.; Polyzou, C.D.; Danelli, P.; Raptopoulou,

C.; Psycharis, V.; Turnbull, M.M. 6th Workshop on Current trends in Molecular and Nanoscale

Magnetism, October 9-13, 2016, Pylos, Greece. “Metal Ion-Assisted Transformations of

Carbonyl- and Oxime-Containing Ligands as a Means of preparing Magnetically Interesting

Complexes” (presented by S.P. Perlepes)

Xiao, F.; Williams, R.; Lancaster, T.; Landee, C.; Turnbull, M. March Meeting of the American

Physical Society, Mar. 11-15, 2017, New Orleans, LA. Abs. A50.00006 “Magnetic phase

diagram of the randomized two dimensional Heisenberg antiferromagnet

(QuinH)2CuCl4xBr4(1−x)⋅2H2O” (presented by F. Xiao)

Hong, T.; Matsumoto, M.; Qiu, Y.; Chen, W.C.; Gentile, T.R.; Watson, S.; Awwadi, F.F.;

Turnbull, M.M.; Dissanayake, S.E.; Agrawal, H.; Toft-Petersen, R.; Klemke, B.; Coester, K.;

Schmidt, K.P. Tennant, D.S. March Meeting of the American Physical Society, Mar. 11-15,

2017, New Orleans, LA. Abs. P50.00012 “Direct observation of the Higgs amplitude mode in a

two-dimensional quantum antiferromagnet near the quantum critical point” (presented by T.

Hong)

Landee, C.; Turnbull, M.; Goddard, P.; Blackmore, W. March Meeting of the American Physical

Society, Mar. 11-15, 2017, New Orleans, LA. Abs. A50.00005 “Specific Heat Studies of a New

2D S = 1/2 Heisenberg Antiferromagnet, [Cu(pz)2(2-OHpy)2](PF6)2” (presented by C. Landee)

Invited Presentations At Meetings (Last five years)

Herringer, S.N.*; Turnbull, M.M.; Landee, C.P.; Ribas-Ariño, J.; Deumal, M.; Novoa, J.J.

Canadian Society for Chemistry 2011 National Meeting, June 5-9, 2011, Montreal, Quebec,

Canada. ABS: 1249 “Ferromagnetic Copper Chloride Chains: Effects of Randomness”

Turnbull, M.M. 525th NEACT Central Division Meeting (New England Association of

Chemistry Teachers), May 12th, 2012, Clark University, Worcester MA 01610 “Demonstrating

equilibrium with Co(II) salts”

Turnbull, M.M.; Herringer, S.N.#; Landee,C.P.; Ribas-Ariño, J.; J.J. Novoa J.J. Fourth Workshop

on Current Trends in Nanoscale and Molecular Magnetism, Chalkidiki, Greece, June 10-14,

2012. “Ferromagnetic exchange in chloride bridged Cu(II)-chain: Ordered and random systems.”

Turnbull, M.M. 32nd Boston Regional Inorganic Colloquium, Boston College, Oct. 19th, 2013.

“Low-Dimension Magnetic Lattices: Ferromagnetic Chains and Antiferromagnetic Ladders”

Krasinski, C.A.*; Solomon, B.L.*; Landee, C.L.; Turnbull, M.M.; Awwadi, F.F. and Wikaira,

J.L. 5th Canadian Molecular Magnetism Meeting, Halifax, NS, Canada, June 4th, 2016. “Further

investigations of halide mediated magnetic exchange”

Farris, P.C.;* Chellali, J.E.;* Landee, C.P.; Turnbull, M.M.; Wall, A.D.;* Wikaira, J.L. 6th

Workshop on Current trends in Molecular and Nanoscale Magnetism, October 9-13, 2016, Pylos,

Greece. “Mechanochemical synthesis of Cu(II)-based magnetic materials”

Turnbull, M.M. 78th Annual Summer Conference, New England Association of Chemistry

Teachers, July 14th, 2017, Fitchburg State University, Fitchburg, MA. “Materials Properties

Demonstrations for All Ages”

* Clark Undergraduate Student Co-author

# Clark Graduate Student Co-author

& High School Student conducting research at Clark