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Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section...

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PAPER-I impression at the corresponding place on the Candidate’s sheet. 7) The ORS will be collected by the invigilator at the end of the examination. 8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work. 9) Write your name, roll number and code of the examination center, and sign with pen in the space provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS. Darken the appropriate bubble under each digit of your roll number. DARKENING THE BUBBLES ON THE ORS 10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS. 11) Darken the bubble COMPLETELY. 12) The correct way of darkening a bubble is as : 13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way. 14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or “un-darken” a darkened bubble. Master JEE CLASSES Kukatpally, Hyderabad. Max. Marks: 210 IMPORTANT INSTRUCTIONS: 1) This booklet is your Question Paper. 2) Use the Optical Response Sheet (ORS) provided separately for answering the questions 3) Blank spaces are provided within this booklet for rough work. 4) Write your name, roll number and sign in the space provided on the back cover of this booklet. 5) You are allowed to take away the Question Paper at the end of the examination. OPTICAL RESPONSE SHEET: 6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an IIT-JEE-2012-P1-Model
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Page 1: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

PAPER-I

impression at the corresponding place on the Candidate’s sheet. 7) The ORS will be collected by the invigilator at the end of the examination. 8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work. 9) Write your name, roll number and code of the examination center, and sign with pen in the space

provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS. Darken the appropriate bubble under each digit of your roll number.

DARKENING THE BUBBLES ON THE ORS 10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS. 11) Darken the bubble COMPLETELY. 12) The correct way of darkening a bubble is as : 13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way. 14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or

“un-darken” a darkened bubble.

Master JEE CLASSES Kukatpally, Hyderabad.

Max. Marks: 210

IMPORTANT INSTRUCTIONS: 1) This booklet is your Question Paper. 2) Use the Optical Response Sheet (ORS) provided separately for answering the questions 3) Blank spaces are provided within this booklet for rough work. 4) Write your name, roll number and sign in the space provided on the back cover of this booklet. 5) You are allowed to take away the Question Paper at the end of the examination. OPTICAL RESPONSE SHEET: 6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an

IIT-JEE-2012-P1-Model

Page 2: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

Section Question Type +Ve Marks

- Ve Marks

No.of Qs

Total marks

Sec – I(Q.N : 1 – 10) Questions with Single Correct Choice 3 -1 10 30

Sec – II(Q.N : 11 – 15) Questions with Multiple Correct Choice 4 0 5 20

Sec – III(Q.N : 16 – 20) Questions with Integer Answer Type 4 0 5 20

Total 20 70

CHEMISTRY:

Section Question Type +Ve Marks

- Ve Marks

No.of Qs

Total marks

Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 3 -1 10 30

Sec – II(Q.N : 31 – 35) Questions with Multiple Correct Choice 4 0 5 20

Sec – III(Q.N : 36 – 40) Questions with Integer Answer Type 4 0 5 20

Total 20 70

MATHEMATICS: Section Question Type +Ve

Marks - Ve

Marks No.of

Qs Total marks

Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 3 -1 10 30

Sec – II(Q.N : 51 – 55) Questions with Multiple Correct Choice 4 0 5 20

Sec – III(Q.N : 56 – 60) Questions with Integer Answer Type 4 0 5 20

Total 20 70

IIT-JEE-2012-P1-Model IMPORTANT INSTRUCTIONS Max Marks: 210 PHYSICS:

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Page 3: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

PHYSICS: Max.Marks : 70 SECTION I

Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. A machine delivers power to a body which is proportional to the instantaneous

velocity ‘v’ of the body. If the body starts with a velocity which is almost negligible,

then the distance covered by the body is proportional to:

A) v B) 32v C) 3

5

v D) 2v

2. A particle of mass m slides on a frictionless surface ABCD, starting from rest as

shown in the figure. The part BCD is a circular arc. If it loses contact at point P, find

the maximum height attained by the particle from point C.

BR

R

C

D

P

Am

450

h

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Page 4: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

A) 1222 2hR

B) 1222 2hR

C) 32hR D) none of these

3. A collar B of mass 2 kg is constrained to move along a horizontal smooth and fixed

circular track of radius 5m. The spring lying in the plane of the circular track and

having spring constant 200 N/m, is undeformed when the collar is at A. If the collar

starts from rest at B, the normal reaction exerted by the track on the collar when it

passes through A is:

.

7m

5mC

B

A

D

. .

A) 360 N B) 720 N C) 1440 N D) 2880 N

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Page 5: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

A) 0 B) 90º C) 1cos 1 3 D) 1sin 1 3

5. A simple pendulum consisting of a mass M attached to a string of length L is released

from rest at an angle . A pin is located at a distance l below the pivot point. When the

pendulum swings down, the string hits the pin as shown in figure. The maximum

angle which the string makes with the vertical after hitting the pin is:

Ll

4. A simple pendulum is vibrating with an angular amplitude of 900 as shown in fig. For

what value of (angle between string and vertical) during its motion, the total

acceleration is directed horizontally?

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Page 6: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

A)

lLlL coscos 1 B)

lLlL coscos 1

C)

lLlL coscos 1 D)

lLlL coscos 1

6. A particle suspended from a fixed point, by a light inextensible thread of length L is

projected horizontally from its lowest position with a velocity 2

7gL . The string will

slack after swinging through an angle , the value of is:

A) 300 B) 1350 C) 1200 D) 1500

7. The force acting on a body moving along x-axis varies with the position of the particle

as shown in figure. The body is in stable equilibrium at:

F

Xx2x1

A) x = x1 B) x = x2

C) both x1 and x2 D) neither x1 nor x2

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Page 7: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

k = 40N/m. The speed of 5kg block when 2kg block leaves contact with the ground is:

5kg

2kg

A) sm /2 B) sm /22 C) 2 m/s D) None of these

9. Consider the situation show in figure. Initially the spring is unstretched when the

system is released from rest. Assuming no friction in the pulley, find the maximum

elongation of the spring?

8. The system shown in figure is released from rest with spring in natural length and

string just taut. The pulley and the springs are massless and friction is absent

everywhere. The value of spring constant is

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Page 8: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

M

A) mgk

B) 2mgk

C) 2mg

k D) 2

3mgk

relaxed state. Find the minimum value of ‘H’ so that the m2 has a tendency to rebound

after hitting the ground during the subsequent motion. Assume that the lower

block stops after hitting the ground. (Initial height of m2 above the ground is H.

Neglect the size of m2)

10. A spring mass system is held at rest at height H from the ground with the spring in

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Page 9: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

m2

m1

K

H

A) 2 1 2

1

22

m g m mK m

B) 2 1 2

1

22 2m g m m

K m

C) 2m gK

D) 1 22

1

22

m m gm k

SECTION II Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct. 11. Two blocks of masses M and 2M are connected to a light spring of spring constant k

that has one end fixed as shown in figure. The horizontal surface and pulley are

frictionless. The blocks are released from rest when the spring is in its relaxed state.

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Page 10: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

k

M

2 M

A) Maximum extension in the string is kMg4

B) Maximum kinetic energy of the system is k

gM 222

C) Maximum energy stored in the spring is four times that of maximum kinetic energy

of the system

D) When kinetic energy of the system is maximum, energy stored in the spring is

kgM 224

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Page 11: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

12. In the system shown in figure the mass ‘m’ moves in a circular arc of angular

amplitude 600. Mass 4m is stationary, then:

4M

mx

B

m

A

600

A) the minimum value of coefficient of friction between the mass 4m and the surface

of the table is 0.5.

B) the work done by the gravitational force on the block m is positive when it moves

from A to B.

C) the power delivered by tension when m moves from A to B is zero

D) the kinetic energy of m in position B equals the work done by gravitational force

on the block when it moves position A to B.

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Page 12: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

13. A small block of mass m is released from rest from position A inside a smooth

hemispherical bowl of radius R as shown in figure. Choose the wrong option. A

B

R

A) Acceleration of block is constant throughout

B) Acceleration of block is g at A

C) Acceleration of block is 3g at B

D) Acceleration of block is 2g at B.

14. The potential energy of the moving particle along x-axis is given by 20 5sin(4 )U x ,

Where U is in joule and ‘x’ is in meter under the action of conservative force.

A) If mechanical energy is 20J, then at x=7/8m; particle is at equilibrium.

B) If mechanical energy is 20J, then at x=7/8m; particle is not at equilibrium.

C) If mechanical energy is 20J, then at x=3/8m; particle is at equilibrium.

D) If mechanical energy is 20J, then at x=3/8m; particle is not at equilibrium. space for rough work Page Page 12

Page 13: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

A) The total acceleration of the sphere as a function of

C) The thread tension at the moment when the vertical component of the sphere’s

velocity is maximum will be 3mg

D) The thread tension at the moment when the vertical component of the sphere’s

velocity is maximum will be ‘mg’.

SECTION- III Integer Answer Type

This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both inclusive). 16. The blocks of masses m1 = 1kg and m2 = 2kg are connected by a spring and rest on a

horizontal surface. The spring is unstretched initially. The spring constant of the

spring is k = 8 N/m. The coefficient of friction between blocks and horizontal surface

is = 21 . Now the left block is imparted a velocity u towards right as shown in figure.

Then what is the largest value of u such that the block mass m2 never moves.

15. A small sphere of mass ‘m’ suspended by a thread is taken a side, so that thread forms

the right angle with the vertical and then released, then which options are correct

(Here ' ' is the angle of with vertical).

' ' is "g 13cos2 "

B) The total tension in the thread as a function of ' ' is '3mg cos '

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Page 14: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

u

m2

'k'

m1

molecule is approximately given by 12 6a bU(x)= -

x x, where a and b are constants

and x is the distance between the atoms. If the dissociation energy of the molecule

is at infinity at equilibriumD U U , then D is2b

na. Find n=?

18. Figure shows a smooth track, a part of which is a circle of radius 10cm. A block of

mass 3kg is pushed against a spring of spring constant 100 N/m fixed at the left end

and is then released. If the initial compression of the spring is 10x cm, find the value

of x so that the block pushes the track with a force of 30 N when it reaches point P,

where the radius of the track is horizontal.

17. The potential energy function for the force between two atoms in a diatomic

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Page 15: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

.Pk

m

is held at rest by a force P in equilibrium as shown (at equilibrium compression in

spring is l1). Suddenly the force P changes its direction opposite to the previous one. If

the maximum extension of the spring during the subsequent motion is l2 then find

l2/l1=?

19. A block of mass m placed on a smooth horizontal surface is attached to a spring and

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Page 16: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

20. One end of a light spring of natural length d and spring constant k=64N/m is fixed on

a rigid wall and the other is attached to a smooth ring of mass m=1 kg which can slide

without fraction on a vertical rod fixed at a distance d=3m from the wall. Initially the

spring makes an angle 370 with the horizontal as shown in fig. When the system is

released from rest find the speed of the ring when the spring becomes horizontal (in

m/s) 0[sin 37 3 / 5]

dv

h

Ringv=0A

I370

B

Road

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Page 17: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

CHEMISTRY: Max.Marks : 70 SECTION I

Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

4 4SrCrO BaCrO B) 2 4 2 4BaC O SrC O C) 3 3KHCO NaHCO D)

A) electrovalent and covalent

B) electrovalent and co-ordinate covalent

C) electrovalent, covalent and co-ordinate covalent

D)covalent and co- ordinate covalent

23. Carbon suboxide (C3O2) has recently been shown as a component of the atmosphere of

Venus. Which of the following formulation represents the correct ground state Lewis

structure for carbon suboxide?

A) : O : C: :C:C: O : B) : O::C::C:C::O:

C) : O:: C :: C :: C :: O : D) : O : C : C : C : O :

21. Which of the following solubility order is not correct?

A) BaS2O3 SrS2O3

22. The types of bonds present in CuSO4.5H2O are only

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Page 18: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

A) 3MgCO B) 3SrCO C) 3BaCO D) 3BeCO

A) 3 2 [cov ]AlCl MgCl NaCl alent character

B) 3 2 [ int]AlF MgF NaF melting po

C) 3 2 [ int]AlCl MgCl NaCl melting po

D) 3 3 3[ int]AlCl AlI AlBr melting po

1S - size of cation increases due to polarization

2S - 3Al has more polarizing power than 3Ga

3S - 2S has more polarisability than Cl

Which of the following given statements are correct:

A) 1 2 3S ,S ,S B) only 3S C) 1 3S ,S D) 2 3S ,S

24. Thermodynamic decomposition temperature is maximum for

25. Which of the following order is not correct?

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Page 19: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

A) KF B) NaF C) CsF D) RbF.

A) 2 3 4LiCl BeCl BCl CCl B) 2 3 4LiCl BeCl BCl CCl

C) 2 3 4LiCl BeCl BCl CCl D) 2 3 4LiCl BeCl BCl CCl

ionic character respectively are:

A) LiCl and RbCl B) RbCl and BeCl2

C) RbCl and MgCl2 D) MgCl2 and BeCl2

Choose the correct order of lattice energy:-

A) 2CsF CaF B) 3 2 3AlF Al O C) 2MgI KI D) 2 2MnBr MnF

27. Among the following, which compound will have the highest lattice energy?

28. Among LiCl, BeCl2, BCl3 and CCl4, the covalent character follows the order?

29. Amongst LiCl, RbCl, BeCl2 and MgCl2, the compounds with the greatest and the least

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Page 20: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

SECTION II Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct.

A) 2 2Cd Hg (polarizing power)

B) 3 3S P (ionic radius)

C) F Ne (covalent radius)

D) 4 4SnF SnCl (melting point)

2BaCl in

water?

A) Hydration energy of 2Ba B) lattice energy of

33. The correct order of decreasing electron affinity of B, C, N and O is:

A) O C N B B) B N C O

C) O C B N

31. Which of the following order is incorrect ?

32. Which of the following energy terms are associated with dissolution of

BaCl2

C) Sublimation energy of Ba D) Electron Affinity of Cl

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D) O B C N

Page 21: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

A) AgF > AgCl > AgBr > AgI [solubility in water]

B) 2 2 2ZnCl ZnBr ZnI [covalent character]

C) 4 4LiClO NaClO [thermal stability]

D) 2BeO BeF [melting Point]

35. Which of the following statements is/are true?

A) low solubility of LiF in water is due to high lattice energy

B) 3KNO is water soluble due to high entropy change

C)CsI is less soluble in water due to smaller hydration energy

D) KI is more soluble in acetone than KCl

34. Which of the following orders is/are true?

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Page 22: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

SECTION III Integer Answer Type

This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both inclusive).

4 2 3 2 2Tl , Pb ,Hg , Bi ,Pb , Ag ,Cs , Be

x = lowest Possible formal charge on ‘N’ atom in Lewis structure(s) of azide ion( 13N )

13N )

dot structures?

36. How many of the followings cations have non-inert gas configuration

37. What is the value of |x| + |y| where

38. How many of the following molecule does not follow octet rule?

BeCl2 , BF3 , SF6 , SF2 , NO ,ClO2, PF5

39. How many of the following molecules contain lone pair(s) on central atom in Lewis

y= highest possible formal charge on ‘N’ atom in Lewis structure(s) of azide ion(

NO2 , SF4 ,O3,CO2 ,PCl3

40. The number of total electrons shared between nitrogen atoms in N2 is_____

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Page 23: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

MATHEMATICS: Max.Marks : 70 SECTION I

Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 41. Let :[ 1,3] [ 8,72]f be defined as 3( ) 4 12f x x x , then f is

A) Injective but not surjective

B) Injective as well as surjective

C) Neither injective nor surjective

D) surjective but not injective

42. The function : { : 1 1}f R x R x defined by ( )1

xf xx

is

A) one-one and into B) one-one and onto

C) many-one and into D) many-one and onto

43. For the real number x, let[x] denote the greatest integer less than or equal to x.

let :f R R be defined as ( ) 2 [ ] sin .cosf x x x x x then f is

A) one-one but not onto B) onto but not one-one

C) both one-one and onto D) neither one-one nor onto

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Page 24: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

44. If the following functions are defined from R to R then identify the function which is

bijective?

A) ( )2

x xe ef x

B) 4 3( ) 3 1f x x x

C) 3 2( ) 18 21 8 1f x x x x D)

that x+3, x rational4x, x irrational( ) andf x

x+ 5 , x irrational-x, x rationalg(x)= then(f-g)(x) is

A) one-one and onto B) neither one-one nor onto

C) one-one but not onto D) onto but not one-one

46. If ( ( )) ( ( ))f g x g f x x for all real number x, and f (2) = 5 and f (5) =3,then the value

of (3) ( (2))g g f is

A) 7 B) 5 C) 3 D) 2

47. Let f(x) = ax+b, Where a and b are integers. If ( (0)) 0 ( ( (4))) 9,f f and f f f then the

f (x) x3 4x2 16x 17

45. If the function f(x)and g(x) are defined on R R such

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value of f ( f ( f ( f (10)))) is equal to

A) 0 B) 4 C) 9 D)10

Page 25: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

174 71( ) 4cos ( ) 2cos(2 ) cos(4 ) ,

2g x x x x x

then the value of ( (100))g g is equal to

A)-1 B)0 C)1 D)100 3 2

( ) .3 2x xf x ax b the latest value of ‘a’ for which ( )f x is

14

B) 18

C) 12

D)1

50. Let 2( ) ( ) sinf x x and g x x for all x R .then the set of all x satisfying (fogogof) (x) =

(gogof) (x), where (fog) (x) = f(g(x)),is

A) , {0,1, 2,........}n n B) , {1, 2,........}n n

C) 2 , {... 2, 1,0,1,2,....}2

n n D) 2 , {...., 2, 1,0,1, 2,....}n n

SECTION - II Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct.

2

[ ]0

[ ] 12x x

isx x

A)1 B) 3 C) 5 D) 6

49. Let f : R R be defined as

injective function is.

A)

51. The maximum value of the function defined by f (x) min (ex , 2 ex ,7) is then integral

value of x satisfying the in equality

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Page 26: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

,1x x Then which of the following hold(s) good?

A) Rang of f is ( ,1] B) f is even function C) f Is function odd D) f is neither injective nor surjective. 53. Let: :f A B and g B C be two functions and :gof A C is defined. Then which of the

following statement(s) is (are) incorrect? A) If gof is onto then f must be onto

B) If f is into and g is onto then gof must be onto function.

C) If gof is one-one then g is necessarily one-one.

D) If f is injective and g is surjective then gof must be bijective mapping.

54. Let f , g & h be three function defined as follows:

2 22 4

32( ) , ( ) 9 ( ) 34

f x g x x and h x x x kx x

Identify which of the following

statement(s) is (are) correct?

A) Number of integers in the range of ( )f x is 8.

B) Number of integral value of k for which ( ( )) 0 ( ( )) 0 20h f x and h g x x R is

C) Number on integral value of k for which ( ( )) 0 ( ( )) 0 19.h f x and h g x x R is

D) Maximum value of ( ( )) 73.g f x is

52. Let f : R R defined by f(x)=min

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Page 27: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

x ;x rational1-x ;x rationalf(x)= ir

If fof(x)=p+qx, x [0,1]Where p,q I , then the value

of 2( 2 )p q is greater than

A) 0 B) 1 C) 2 D) 3

SECTION III Integer Answer Type

This section contains 5 questions. The answer to each question is single digit integer, ranging from 0 to 9 (both inclusive).

56. Let 1( )cos{ }

f xx

where [y] and {y} denote greatest integer and fractional part

function respectively and g(x) = 22 3 ( 1) (3 1). ( ( )) 0x x k k k if g f x x R then find

the number of integral value of k.

57. If 5 1( ) sin ln 71

xh x Ax B x Cx

, Where A, B, C are non-zero real constants and

1 6,2

h

then find the value of sgn( ) .2

xeh

55. Let f(x) be a function defined on [0, 1] such that

space for rough work Page Page 27

Page 28: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

2( ) log ( 9 12 1)ef x x x be an onto function where

is a real parameter belong to (0, 10) Find the greatest possible value of .

2x+p , for x 22px+5, for x>2R R as f(x)=

If the function is

surjective, then the sum of all possible integral value of p in [-100,100] is

100

1

rr k then (k-2) =

2( 1) (2 3)a x x b be satisfied by three distinct value of x, where

3 2a,b R.if f(x)=(a-1)x +(2b+3)x +2x+1,and f(g(x))=6x-7 where g(x) is a linear function

then find the value of g(2) is equal to

58. Let f : R [0,) be defined as

59. Let a function f defined from

60. Let the equation

space for rough work Page Page 28

Page 29: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

KEY SHEET

PHYSICS

1 D 2 A 3 C 4 C 5 C

6 C 7 B 8 B 9 B 10 A

11 ABC 12 ABCD 13 AC 14 AC 15 ABC

16 5 17 4 18 3 19 3 20 9

CHEMISTRY

21 D 22 C 23 C 24 C 25 C

26 A 27 B 28 C 29 B 30 C

31 ABD 32 AB 33 C 34 ABD 35 ABCD

36 3 37 3 38 6 39 3 40 6

MATHS

41 D 42 B 43 A 44 D 45 B

46 A 47 D 48 D 49 A 50 A

51 ACD 52 BD 53 ABCD 54 ACD 55 AB

56 1 57 8 58 4 59 8 60 2

Master JEE CLASSES Kukatpally, Hyderabad.

IIT-JEE-2012-P1-Model Max.Marks:210

Page 1

Page 30: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

SOLUTIONS CHEMISTRY 22. The bond between Cu2+ and 2

4SO ion is ionic ; between S and O in 2-4SO ions and

between H and O atoms in H2O are covalent ; those between Cu2+ and H2O molecules

are coordinate.

H-O | H

H |H-O

Cu

H-O | H

H |H-O O

H

H

O

O O

O

S

2-

2+

23. In (c), each C and O atom has octet of electrons.

24. A -bond is stronger than a -bond hence option (a) is not correct.

.

.

27. For compounds containing ions of same charge, lattice energy increases as the size the

ions decrease. Thus, NaF has highest lattice energy.

28. As we move from LiBe BC, the electonegativity (EN) increases and hence the

EN difference between the element and Cl decreases and accordingly the covalent

character increases.

Thus option (c) i.e. 2 3 4LiCl BeCl BCl CCl is correct.

29. Electronegativity difference (EN) is highest in RbCl (3 – 0.8 = 2.2) and least in BeCl2

(3-1.5 =1.5) and hence option (b) is correct.

30. In H C=C O-H

O

the asterisked carbon has a valency of 5 and hence this formula is

not correct.

31. Because of the triple bond, the carbon –carbon bond distance in ethyne is shortest.

.

33. Conceptual.

Page 2

Page 31: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

36.

C=CH

H

H

H

=5/1

38. 2 3 2 5 6; ; ; ; ;BeCl BF NO ClO PF SF

39. Conceptual.

40. Each N atom in N2 molecule shares three electrons, i.e., :N::N:

MATHS

41. 3

' 2

( ) 4 12( ) 12( 1) 12( 1)( 1)

f x x xf x x x x

x=3

y

x

(3,72)

(0,0) x=1

(1,-8)

x=-1

(-1,8)

42. , 0

1

, 01

( ) 0, 0

x xx

x xx

f x x

(0) 0. , , 0

1

0 ( 1,0)1

xf Now y xx

yx yy

Also, , 0 0 (0,1)1 1

x yy x x yx y

So, range of function=(-1,1)

Page 3

Page 32: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

y

x

y=-1

0

y=1

43. If x=a, where ‘a’ is an integer then 1( ) 2 sin 22

f a a a a

But 0

1lim ( ) 2 ( 1) sin 22h

f a h a a a

Value between 0

lim ( )h

f a h

and f(a) are never achieved.

Also, '

( ) 2 cos 2 0, . ., ( )f x x i e f x is strictly increasing.

44. ( ) ( )2

x xe eA f x

is even function.

4 3( ) ( ) 3 1B f x x x is an even degree polynomial function.

3 2( ) ( ) 18 21 8 1C f X x x x

F(X) is an odd degree polynomial function hence its range is R. ' 2( ) 3 8 16f X x x 0D , hence f(x) is one-one as well as onto.

45. We have (f-x) (x) = (f(x)-g(X))= 2 3,4 ,( ( ) ( ( ) ( )) x x rational

x x irrationalf g x f x g x

As, 3 502 3

f f

and so on.

( )f x is many one function.

Also, 5 does not belong to the range, because if3 5 5x

0x Q

( )f x Is into function

46. Since g and f are inverses, g(3)=5 and so g(3)+g(f(2))=5+2=7.

47. ( )f x ax b

Page 4

Page 33: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

2

(0)( (0)) . 0 ( 1) 0 1 0( ( (4))) 9( (4 ) ) 9

( (4 ) ) 9(4 ) 9

f bf f a b b a b a or bf f fff f a b b

f a a b bf d ab b

2

3 2

3 3

(4 ) 94 9

90, 4 9 int4

a a ab b ba a b ab b

when b a a a is not an eger

When a=-1,-4+b-b+b=9=>b=13

( ) 13

( ( )) ( 13) 13( ( ( (10)))) ( (10)) 10

f x xf f x x x

f f f f f f

48. We have

4 7

4 2 2 7

177

11777 7

14cos 2cos 2 cos 42

14cos 2(2cos 1) (2cos 2 1)2

3( )2

3 3 3( ( )) ( ( ))2 2 2

x x x x

x x x x

We get g x x

g g x g x x x

49. If f(x) is one-one then f(x) must be monotonic.

Now, ' 2( ) 0f x x x a x R

min

10 . .,1 4 04

1,4

D i e a a

So a

50.

Page 5

Page 34: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

2 2 2

2

2

2

2

2

( ( ( ( )))) ( ( ( )) sin (sin ) sin(sin )sin(sin ) 0,1)

sin , (4 1) , , .2

1 sin 1sin 0

, 0,1,2,.....

, {0,1,2,....

f g g f x g g f x x xx

x m k where m k I

But xx

x n n

x n n

51. 2( ) min( , 2 ,8)xf x e e From the graph it is clear that maximum value of 2( ) ,f x is e

2[ ] [ ] 7e

2

( 7) ( 7)0 07 12 ( 3)( 4)

x x x xx x x x

0 3 4 7

52. ( ) . ,1f x Min x x

fD R

( ) ( )f x f x

f is even function.

Put

112

x x

x

(-1/2,0) (1/2,0) x

y=1- x

y= x(1/

2,1/2)

y

(0,1)

(-1/2,1/2)

Page 6

Page 35: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

53. (A) We have :f A B

: :g B C and gof A C

.

.

..

.

.

.

.

.

. .

Af

B

g

C

(A)

..

.

.

.

Af

B

g

C

(B)

. .

..

.

Af

B

g

C

(C)

.

..

Af

B

g

C

.

..

.

.

(D)

54. 2 22 4

32( ) ; ( ) 9 ; ( ) 34

f x g x x h x x x kx x

(A) Range of f is [0,8]

(B) ( ( )) 0 ( ( )) 0h f x and h g x

(0) 0 0h k

Page 7

Page 36: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

& (8) 0 64 24 0 88h k k

, (9) 0 81 27 0 108Also h k k

Number of integral value of k is 19.

(D) Maximum value of g(f(x))is g(8)=64+9=73.

x-axis

y-axis

0 8

55. Given, ;1 ;( ) x x Q

x x Qf x

;1 ;

;1 ;

2

( )

, ( )

( ( ) ) , [ 0 ,1]0 1

, ( 2 ) 2

x x Qx x Q

x x Qx x Q

fo f x

S o fo f x

f f x x xp a n d q

h e n c e p q

56. ( ) 1f x x R

2

2

(1) 02 3( 1) 3 03 2 1 0(3 1)( 1) 0

1,13

g xk k k

k kk k

k

57. Given 1 62

h

5

5

1( ) sin ln 71

1( ) sin ln 71

xh x Ax B x cx

xh x Ax B x Cx

Page 8

Page 37: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

( ) ( ) 141 1 142 2

1 6 1421 82

h x h x

h h

h

h

58. Given 29 ) log( 9 12 1)r x x x

& [0, ]f fD R R So, it is possible when 29 12 0x x hence equal roots

. 0, 144 36

4

DiscSo

59. For f to be surjective range =Co-domain2 , 2

2 5, 2( ) x p for xpx forxf x

For 2,x range of f is 2( , 2 0p and

For x>2, range of f is (4p+5, ). [Note that p>0]

For range of f to be R, 24 5 2p p

2 4 3 0 ( 3)( 1) 0 ( , 1) [3, ] 0.p p p p p but p

Hence, [3, )p

3 4 ........ 100 5050 3 5047s

60. 2( 1) (2 3)a x x b

The above equation is satisfied by three distinct values of x therefore it is an identity.

32 2 0 1 2 3 02

a a and b b

Now, ( ) 2 1f x x

'

'

( ) ( )( ( )) 6 7 2( ) 1 6 72 2 1 6 72 6 3 4(2012) 3

Let g x px q g x pf g x x px q x

px q xp p and q

g

Page 9

Page 38: Master JEE CLASSES...PHYSICS: Max.Marks : 70 SECTION I Single Correct Answer Type This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

Page 10


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