3M MATERIAL SAFETY DATA SHEET 3M(TM) OTC 3ft. End Cap Kit PN 38014 01/16/2007
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Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.
PRODUCT NAME: 3M(TM) OTC 3ft. End Cap Kit PN 38014 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 01/16/2007 Supercedes Date: Initial Issue
Document Group: 22-0770-2
ID Number(s):
60-4550-3076-1
This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS foreach of these components is included. Please do not separate the component MSDSs from this cover page. The documentnumbers of the MSDSs for components of this product are:
07-7563-5, 16-6445-7, 06-5214-9, 18-5336-5, 08-3027-3, 19-7425-2, 21-8630-2, 19-8268-5, 20-2814-0, 21-8199-8, 19-7494-8, 19-7411-2, 19-7521-8, 16-0778-7
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method ofuse or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
3M MATERIAL SAFETY DATA SHEET 3M(TM) OTC 3ft. End Cap Kit PN 38014 01/16/2007
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In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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Material Safety Data Sheet
Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M (TM) High Power Brake Cleaner, P.N. 08880 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/05/09Supercedes Date: 10/24/08
Document Group: 06-5214-9
Product Use:Intended Use: AutomotiveSpecific Use: Solvent Blend Cleaner for Automobile Brake Systems
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtHydrotreated Light Naptha (Petroleum) 64742-49-0 30 - 60Propane 74-98-6 10 - 30Xylene 1330-20-7 10 - 30Methyl Alcohol 67-56-1 7 - 13Ethylbenzene 100-41-4 3 - 7Toluene 108-88-3 < 0.1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: AerosolOdor, Color, Grade: clear, colorless, solvent odorGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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flash back. Aerosol container contains flammable material under pressure. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficultybreathing, bluish colored skin (cyanosis), and may be fatal.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
May cause blindness.
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description RegulationEthylbenzene 100-41-4 Group 2B International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention.
4.2 NOTE TO PHYSICIANSExposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point -50.00 ºFFlammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data Available
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in an approved metal container. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents. Avoid skin contact.
7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Do not store containers on their sides. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Use with
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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functioning spray booth or local exhaust. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton), Polyethylene/Ethylene Vinyl Alcohol.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface supplied-air respirator. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationEthylbenzene ACGIH TWA 100 ppm Table A3Ethylbenzene ACGIH STEL 125 ppm Table A3Ethylbenzene CMRG TWA 25 ppm Ethylbenzene CMRG STEL 75 ppm Ethylbenzene OSHA TWA 100 ppm Table Z-1AEthylbenzene OSHA STEL 125 ppm Table Z-1AHydrotreated Light Naptha (Petroleum) CMRG TWA 50 ppm Methyl Alcohol ACGIH TWA 200 ppm Skin Notation*Methyl Alcohol ACGIH STEL 250 ppm Skin Notation*Methyl Alcohol OSHA TWA 200 ppm Skin Notation*; Table Z-1AMethyl Alcohol OSHA STEL 250 ppm Skin Notation*; Table Z-1APropane ACGIH TWA 1000 ppm Propane OSHA TWA 1000 ppm Table Z-1Toluene ACGIH TWA 20 ppm Table A4Toluene CMRG STEL 75 ppm Skin Notation*Toluene OSHA TWA, Vacated 100 ppm Toluene OSHA STEL, Vacated 150 ppm Toluene OSHA TWA 200 ppm Table Z-2Toluene OSHA CEIL 300 ppm Table Z-2Xylene ACGIH TWA 100 ppm Table A4Xylene ACGIH STEL 150 ppm Table A4Xylene CMRG TWA 50 ppm Xylene CMRG STEL 75 ppm Xylene OSHA TWA 100 ppm Table Z-1AXylene OSHA STEL 150 ppm Table Z-1A
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: AerosolOdor, Color, Grade: clear, colorless, solvent odorGeneral Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point -50.00 ºFFlammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point No Data Available
Vapor Density >=1.0 [Ref Std: AIR=1]
Vapor Pressure 40 psi [Details: Conditions: @ 70 F]
Specific Gravity 0.699 [Ref Std: WATER=1]pH Not ApplicableMelting point No Data Available
Solubility in Water NilEvaporation rate No Data AvailableVolatile Organic Compounds 699 g/l [Test Method: calculated SCAQMD rule 443.1]Percent volatile 100 %VOC Less H2O & Exempt Solvents 699 g/l [Test Method: calculated SCAQMD rule 443.1]Viscosity No Data Available
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionCarbon monoxide During CombustionCarbon dioxide During CombustionToxic Vapor, Gas, Particulate During Combustion
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.The facility should be equipped to handle gaseous waste.Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0311-1, 60-4550-3010-0, 60-4550-4502-5, 60-9800-2110-3, 60-9800-3309-0
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by WtMethyl Alcohol 67-56-1 7 - 13Ethylbenzene 100-41-4 3 - 7Xylene 1330-20-7 10 - 30
STATE REGULATIONSContact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. ClassificationEthylbenzene 100-41-4 **CarcinogenToluene 108-88-3 *Developmental Toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 1 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
MATERIAL SAFETY DATA SHEET 3M (TM) High Power Brake Cleaner, P.N. 08880 05/05/09
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presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Revision Changes:Section 1: Product name was modified.Section 16: NFPA hazard classification for health was modified.Copyright was modified.Section 3: Potential effects from eye contact was modified.Section 3: Potential effects from skin contact information was modified.Section 3: Potential effects from inhalation information was modified.Section 3: Potential effects from ingestion information was modified.Section 3: Immediate other hazard(s) was modified.Section 3: Other health effects information was modified.Page Heading: Product name was modified.Section 2: Ingredient table was modified.Section 8: Exposure guidelines ingredient information was modified.Section 3: Carcinogenicity table was modified.Section 15: California proposition 65 ingredient information was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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Material Safety Data Sheet
Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 11/06/2006Supercedes Date: 07/07/2005
Document Group: 07-7563-5
Product Use:Intended Use: AutomotiveSpecific Use: Automotive Fuel Tank Additive
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt HYDROTREATED LIGHT NAPHTHENIC PETROLEUM DISTILLATES 64742-53-6 60 - 100 HEAVY AROMATIC SOLVENT NAPHTHA (PETROLEUM) 64742-94-5 1 - 5 2-ETHYLHEXANOL 104-76-7 0.5 - 1.5 NAPHTHALENE 91-20-3 < 0.1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Amber Liquid, Solvent OdorGeneral Physical Form: LiquidImmediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat fromfire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.Contains a chemical or chemicals which can cause cancer. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose andthroat pain.
Intentional concentration and inhalation may be harmful or fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficultybreathing, bluish colored skin (cyanosis), and may be fatal.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,slowed reaction time, slurred speech, giddiness, and unconsciousness.
Carcinogenicity: Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description Regulation NAPHTHALENE 91-20-3 Group 2B International Agency for Research on Cancer NAPHTHALENE 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices arefollowed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medicalattention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconsciousperson. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available Flash Point 143 ºF [Test Method: Tagliabue Closed Cup] [Details:
CONDITIONS: ASTM D56] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available OSHA Flammability Classification: Class IIIA Combustible Liquid
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposedcontainers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-containedbreathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may buildpressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decompositioninformation.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for moreinformation on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should becleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanicalventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignitionsource and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drainsand build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover withbentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Place in aclosed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according tolocal, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid breathing of vapors,mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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agents.
7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse in a well-ventilated area.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult withyour glove and/or protective clothing manufacturer for selection of appropriate compatible materials.Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton).
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance withOSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3MRespiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information HEAVY AROMATIC SOLVENT NAPHTHA(PETROLEUM)
CMRG TWA 17 ppm
HYDROTREATED LIGHT NAPHTHENICPETROLEUM DISTILLATES
CMRG TWA 5 mg/m3
NAPHTHALENE ACGIH TWA 10 ppm Skin Notation*; Table A4 NAPHTHALENE ACGIH STEL 15 ppm Skin Notation*; Table A4 NAPHTHALENE OSHA TWA 10 ppm Table Z-1A NAPHTHALENE OSHA STEL 15 ppm Table Z-1A
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: Amber Liquid, Solvent Odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 143 ºF [Test Method: Tagliabue Closed Cup] [Details:
CONDITIONS: ASTM D56] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point >=95 ºF
Vapor Density >=5 [Ref Std: AIR=1]
Vapor Pressure 0.04 mmHg [Details: CONDITIONS: @ 20 C]
Specific Gravity 0.88 [Ref Std: WATER=1] pH Not Applicable Melting point Not Applicable
Solubility in Water Negligible Volatile Organic Compounds No Data Available Percent volatile 100 % weight VOC Less H2O & Exempt Solvents No Data Available Viscosity 38.4 Saybolt Universal Second [Details: CONDITIONS: @ 100 F]
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or itscomponents.
SECTION 12: ECOLOGICAL INFORMATION
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in afacility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):60-4550-2998-7, 60-9800-3032-8, 60-9800-3468-4
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for thismaterial.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS Contact 3M for more information.
311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status 2-ETHYLHEXANOL 104-76-7 Toxic Substances Control Act (TSCA) 4 Test
Rule Chemicals Applicable
NAPHTHALENE 91-20-3 Toxic Substances Control Act (TSCA) 4 TestRule Chemicals
Applicable
STATE REGULATIONS Contact 3M for more information.
CALIFORNIA PROPOSITION 65
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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Ingredient C.A.S. No. Classification NAPHTHALENE 91-20-3 **Carcinogen
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification Health: 2 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that arepresented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on theinherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known tobe generated in significant quantities.
Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazardsof the product have not changed. We encourage you to reread the MSDS and review the information.
Revision Changes:Section 1: Product use information was modified.Copyright was modified.Section 3: Potential effects from ingestion information was modified.Section 14: ID Number(s) was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
3M MATERIAL SAFETY DATA SHEET 3M(TM) Fuel Injection Cleaner Tank Additive, P.N. 08812, 08814 11/06/2006
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use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
3M MATERIAL SAFETY DATA SHEET 3M Glass Cleaner, P.N. 08888, 39888 12/29/2006
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Material Safety Data Sheet
Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M Glass Cleaner, P.N. 08888, 39888MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 12/29/2006Supercedes Date: 11/06/2006
Document Group: 08-3027-3
Product Use:Intended Use: AutomotiveSpecific Use: Automotive Glass Cleaner
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt WATER 7732-18-5 80 - 90 ISOBUTANE 75-28-5 1 - 10 2-BUTOXYETHANOL 111-76-2 1 - 10
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: AerosolOdor, Color, Grade: foamy white, slight ammonia-like odor.General Physical Form: LiquidImmediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure andexplode. Aerosol container contains gas under pressure. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
3M MATERIAL SAFETY DATA SHEET 3M Glass Cleaner, P.N. 08888, 39888 12/29/2006
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Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
May be absorbed through skin and cause target organ effects.
Inhalation:Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose andthroat pain.
Single exposure, above recommended guidelines, may cause:Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,slowed reaction time, slurred speech, giddiness, and unconsciousness.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices arefollowed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medicalattention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Nevergive anything by mouth to an unconscious person. Get medical attention.
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4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable
5.2 EXTINGUISHING MEDIANon-combustible. Choose material suitable for surrounding fire.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus(SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Aerosolcontainer contains gas under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decompositioninformation.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for moreinformation on handling and managing the spill. Ventilate the area with fresh air. For large spill, or spills in confined spaces, providemechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could bean ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. If possible, sealleaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors onan impermeable surface until appropriate packaging for the leaking container or its contents is available. Working from around theedges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficientabsorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Placein a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according tolocal, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors,mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children.
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7.2 STORAGEStore away from heat. Do not store containers on their sides.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSDo not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced.Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limitsand/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult withyour glove and/or protective clothing manufacturer for selection of appropriate compatible materials.Gloves made from the following material(s) are recommended: Neoprene.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information 2-BUTOXYETHANOL ACGIH TWA 20 ppm Table A3 2-BUTOXYETHANOL OSHA TWA, Vacated 25 ppm Skin Notation* 2-BUTOXYETHANOL OSHA TWA 50 ppm Skin Notation*; Table Z-1 ISOBUTANE ACGIH TWA 1000 ppm
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your localregulatory agency.
SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
3M MATERIAL SAFETY DATA SHEET 3M Glass Cleaner, P.N. 08888, 39888 12/29/2006
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Specific Physical Form: Aerosol Odor, Color, Grade: foamy white, slight ammonia-like odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable
Vapor Density 4.07 [Ref Std: AIR=1]
Specific Gravity 0.96 [Ref Std: WATER=1] [Details: CONDITIONS: @ 70F] pH 10.90 - 11.30 [Details: CONDITIONS: @ 70F] Melting point No Data Available
Solubility in Water Complete Evaporation rate Approximately 45 Units not avail. or not appl. [Ref Std: ETHER=1] Volatile Organic Compounds 9.9 % weight Percent volatile 99.00 % weight VOC Less H2O & Exempt Solvents 947 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity Not Applicable
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or itscomponents.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
3M MATERIAL SAFETY DATA SHEET 3M Glass Cleaner, P.N. 08888, 39888 12/29/2006
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Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of waste product in a facility permitted to accept chemical waste. As a disposal alternative,incinerate in an industrial or commercial facility in the presence of a combustible material. Facility must be capable of handlingaerosol cans. Dispose of empty product containers in a sanitary landfill.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0305-4, 60-4550-3014-2, 60-9800-2541-9, 60-9800-3075-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for thismaterial.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS Contact 3M for more information.
311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt 2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 1 - 10
STATE REGULATIONS Contact 3M for more information.
3M MATERIAL SAFETY DATA SHEET 3M Glass Cleaner, P.N. 08888, 39888 12/29/2006
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CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None Aerosol Storage Code: 1
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that arepresented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on theinherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known tobe generated in significant quantities.
Revision Changes:Section 14: ID Number(s) was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method ofuse or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
3M MATERIAL SAFETY DATA SHEET 3M Glass Cleaner, P.N. 08888, 39888 12/29/2006
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Complete Fuel System Cleaner PN 08813 05/23/2007
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Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Complete Fuel System Cleaner PN 08813 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/23/2007Supercedes Date: 11/06/2006
Document Group: 16-0778-7
Product Use:Intended Use: AutomotiveSpecific Use: Clean Automotive Fuel System Components
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtHYDROTREATED LIGHT NAPHTHENIC PETROLEUM DISTILLATES 64742-53-6 60 - 90MEDIUM ALIPHATIC SOLVENT NAPHTHA 64742-88-7 5 - 10POLYOLEFIN AMINE Trade Secret 1 - 5TRIMETHYLBENZENE 25551-13-7 0.5 - 1.5ETHYLBENZENE 100-41-4 <= 0.025
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Pale straw to amber liquid. Petroleum and/or Aromatic hydrocarbon ordor.General Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Contains a chemical or chemicals which can cause cancer. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
3M MATERIAL SAFETY DATA SHEET 3M(TM) Complete Fuel System Cleaner PN 08813 05/23/2007
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Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Carcinogenicity:Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description RegulationETHYLBENZENE 100-41-4 Group 2B International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
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If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point 188 ºF [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableOSHA Flammability Classification: Class II Combustible Liquid
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing
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agents.
7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationETHYLBENZENE ACGIH TWA 100 ppm Table A3ETHYLBENZENE ACGIH STEL 125 ppm Table A3ETHYLBENZENE OSHA TWA 100 ppm Table Z-1AETHYLBENZENE OSHA STEL 125 ppm Table Z-1AHYDROTREATED LIGHT NAPHTHENIC
PETROLEUM DISTILLATESCMRG TWA 5 mg/m3
MEDIUM ALIPHATIC SOLVENT NAPHTHA
CMRG TWA 100 ppm
TRIMETHYLBENZENE ACGIH TWA 25 ppm TRIMETHYLBENZENE OSHA TWA 25 ppm Table Z-1A
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: Pale straw to amber liquid. Petroleum and/or Aromatic hydrocarbon ordor.
General Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point 188 ºF [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point >=300 ºFDensity 7.1 - 7.6 lb/galVapor Density No Data Available
Vapor Pressure <=1 mmHg [@ 20 ºC]
Specific Gravity 0.88 [Ref Std: WATER=1]pH Not ApplicableMelting point Not Applicable
Solubility in Water NegligibleEvaporation rate No Data AvailableVolatile Organic Compounds No Data AvailablePercent volatile No Data AvailableVOC Less H2O & Exempt Solvents No Data AvailableViscosity <=15 centistoke
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong acids; Strong oxidizing agents; Reducing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionAldehydes Not SpecifiedCarbon monoxide Not SpecifiedCarbon dioxide Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
3M MATERIAL SAFETY DATA SHEET 3M(TM) Complete Fuel System Cleaner PN 08813 05/23/2007
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ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):60-4550-3008-4, 60-9800-3811-5
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
STATE REGULATIONSContact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. ClassificationETHYLBENZENE 100-41-4 **Carcinogen
** WARNING: contains a chemical which can cause cancer.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Complete Fuel System Cleaner PN 08813 05/23/2007
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CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 2 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information.
Revision Changes:Copyright was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Complete Fuel System Cleaner PN 08813 05/23/2007
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3M MSDSs are available at www.3M.com
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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Material Safety Data Sheet
Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) General Trim Adhesive P.N. 08088 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 02/09/10Supercedes Date: 11/05/08
Document Group: 16-6445-7
Product Use:Intended Use: AutomotiveLimitations on Use: Not recommended for bonding polystyrene foam.Specific Use: Automotive trim adhesive.General Use: High strength adhesive for bonding automotive materials (carpeting, fabrics, plastics) to
metal and other surfaces.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtDIMETHYL ETHER 115-10-6 30 - 60METHYL ACETATE 79-20-9 15 - 40CYCLOHEXANE 110-82-7 7 - 13BICYCLO[3.1.1]HEPT-2-ENE,2,6,6-TRIMETHYL-,POLYMER WITH 6,6-
DIMETHYL-2-METHYLENEBICYCLO[3.1.1]HEPTANE31393-98-3 5 - 10
BENZENE, 1-ETHENYL-4-METHYL-, POLYMER WITH (1-METHYLETHENYL)BENZENE
100199-62-0 1 - 5
PETROLEUM DISTILLATE 64742-48-9 1 - 5HYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 1 - 5NONVOLATILE COMPONENTS - TRADESECRET Trade Secret 1 - 51,1-DIFLUOROETHANE 75-37-6 1 - 5METHYL ALCOHOL 67-56-1 < 0.5
SECTION 3: HAZARDS IDENTIFICATION
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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3.1 EMERGENCY OVERVIEW
Specific Physical Form: AerosolOdor, Color, Grade: Liquid in aerosol, clear, sweet fruity odorGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause frostbite. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Frostbite: Signs/symptoms may include intense pain, clouding of the cornea, redness, swelling, and blindness.
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:Frostbite: Signs/symptoms may include intense pain, discoloration of skin, and tissue destruction.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
May be absorbed through skin and cause target organ effects.
Inhalation:Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.
4.2 NOTE TO PHYSICIANSExposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point -40 ºF [Test Method: Tagliabue Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableOSHA Flammability Classification: Class IA Flammable Liquid
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available.
Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. For industrial or professional use only. Do not breathe vapors.
7.2 STORAGEStore away from heat. Store out of direct sunlight. Store away from areas where product may come into contact with food or pharmaceuticals.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Use in a well-ventilated area. If exhaust ventilation is not available, use appropriate respiratory protection.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene, Nitrile Rubber.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray. Do not breathe vapors.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information1,1-DIFLUOROETHANE AIHA TWA 2700 mg/m3 1,1-DIFLUOROETHANE CMRG TWA 1000 ppm CYCLOHEXANE ACGIH TWA 100 ppm CYCLOHEXANE OSHA TWA 1050 mg/m3 DIMETHYL ETHER AIHA TWA 1880 mg/m3 DIMETHYL ETHER CMRG TWA 1000 ppm PETROLEUM DISTILLATE 3M TWA 100 ppm PETROLEUM DISTILLATE CMRG TWA 300 ppm HYDROTREATED LIGHT PETROLEUM DISTILLATES
CMRG TWA 300 ppm
METHYL ACETATE ACGIH TWA 200 ppm METHYL ACETATE ACGIH STEL 250 ppm METHYL ACETATE OSHA TWA 610 mg/m3 METHYL ALCOHOL ACGIH TWA 200 ppm Skin Notation*METHYL ALCOHOL ACGIH STEL 250 ppm Skin Notation*METHYL ALCOHOL OSHA TWA 260 mg/m3 PETROLEUM DISTILLATES OSHA TWA 2000 mg/m3
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: AerosolOdor, Color, Grade: Liquid in aerosol, clear, sweet fruity odorGeneral Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point -40 ºF [Test Method: Tagliabue Closed Cup]
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point No Data AvailableDensity 0.781 g/ml [Details: Refers to density of the liquid]Vapor Density 2.97 [Ref Std: AIR=1]
Vapor Pressure No Data Available
Specific Gravity 0.781 [Ref Std: WATER=1]pH Not ApplicableMelting point No Data Available
Solubility in Water NilEvaporation rate 1.90 [Ref Std: ETHER=1]Hazardous Air Pollutants <=0.4 % weightVolatile Organic Compounds 53.62 % [Test Method: calculated SCAQMD rule 443.1]Kow - Oct/Water partition coef No Data AvailablePercent volatile 53.62 % weightVOC Less H2O & Exempt Solvents 553.61 g/l [Test Method: calculated SCAQMD rule 443.1]Viscosity No Data AvailableConditions to avoid HeatMaterials to avoid Strong oxidizing agentsMaterials to avoid Alkali and alkaline earth metalsMaterials to avoid
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: 10.1 Conditions to avoidHeat, Sparks and/or flames 10.2 Materials to avoidStrong oxidizing agents, Alkali and alkaline earth metals
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionCarbon monoxide Not SpecifiedCarbon dioxide Not SpecifiedToxic Vapor, Gas, Particulate Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans. Combustion products will include HF. Facility must be capable of handling halogenated materials.Dispose of empty product containers in a sanitary landfill.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):60-4550-3005-0, 60-4550-4615-5, 60-4550-4629-6, 60-4550-4837-5, 60-9800-4516-9, 60-9801-0537-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by WtCYCLOHEXANE 110-82-7 7 - 13
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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METHYL ACETATE 79-20-9 Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals
Applicable
STATE REGULATIONSContact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 2 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 2
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Revision Changes:Copyright was modified.Section 8: Skin protection phrase was modified.Section 9: Property description for optional properties was modified.Section 14: ID Number(s) Template 1 was modified.Section 2: Ingredient table was modified.
MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 02/09/10
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Section 8: Exposure guidelines ingredient information was modified.Section 15: TSCA section 12[b] information was modified.Section 9: Property description for required properties was added.Section 10.1 Conditions to avoid was added.Section 10.2 Materials to avoid was added.Section 6: Release measures information was added.Section 6: Release measures information was added.Section 6: Release measures information was added.Section 10: Materials to avoid physical property was added.Section 10: Conditions to avoid physical property was added.Section 6: Release measures information was deleted.Section 10: Materials and conditions to avoid physical property was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
MATERIAL SAFETY DATA SHEET 3M(TM) PERFORMANCE FINISH PN 38112, 39030, 06072 & Performance Finish Synthetic Wax Protectant PN 39037 07/29/10
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Material Safety Data Sheet
Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) PERFORMANCE FINISH PN 38112, 39030, 06072 & Performance Finish Synthetic Wax Protectant PN 39037
MANUFACTURER: 3MDIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 07/29/10Supercedes Date: 07/27/10
Document Group: 18-5336-5
Product Use:Intended Use: AutomotiveSpecific Use: Enhances and protects automotive painted surface.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtWATER 7732-18-5 40 - 70DECAMETHYLCYCLOPENTASILOXANE 541-02-6 < 30DODECAMETHYLCYCLOHEXASILOXANE 540-97-6 < 20CERAMIC MATERIALS AND WARES, CHEMICALS 66402-68-4 5 - 10HYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 3 - 7SILOXANES AND SILICONES, DI-ME, [[[3-[(2-
AMINOETHYL)AMINO]PROPYL]DIMETHOXYSILYL]OXY]-TERMINATED71750-80-6 1 - 5
NAPHTHA (PETROLEUM), HYDRODESULFURIZED HEAVY 64742-82-1 < 3STODDARD SOLVENT 8052-41-3 < 3SILOXANES AND SILICONES, DI-ME, HYDROXY-TERMINATED,
REACTION PRODUCTS WITH TRIMETHOXYMETHYLSILANE AND N-[3-(TRIMETHOXYSILYL)PROPYL]-1,2-ETHANEDIAMINE
69430-37-1 0.1 - 1.0
METHYL ALCOHOL 67-56-1 <= 0.2
SECTION 3: HAZARDS IDENTIFICATION
MATERIAL SAFETY DATA SHEET 3M(TM) PERFORMANCE FINISH PN 38112, 39030, 06072 & Performance Finish Synthetic Wax Protectant PN 39037 07/29/10
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3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Opaque, colored, viscous liquid; Slightly fragrantGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause: Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
SECTION 4: FIRST AID MEASURES
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4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point 110 ºF [Test Method: Closed Cup]
OSHA Flammability Classification: Class II Combustible Liquid
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal precautionsEvacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.
Environmental procedures
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For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
Clean-up methodsRefer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Seal the container.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Avoid breathing of vapors, mists or spray. Keep out of the reach of children. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Avoid skin contact. Avoid eye contact with vapors, mists, or spray.
7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse in an enclosed process area is recommended. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Safety Glasses with side shieldsIndirect Vented Goggles.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: NeopreneNitrile Rubber
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.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationDECAMETHYLCYCLOPENTASILOXANE CMRG TWA 10 ppm HYDROTREATED LIGHT PETROLEUM DISTILLATES
CMRG TWA 300 ppm
METHYL ALCOHOL ACGIH TWA 200 ppm Skin Notation*METHYL ALCOHOL ACGIH STEL 250 ppm Skin Notation*METHYL ALCOHOL OSHA TWA 260 mg/m3 STODDARD SOLVENT ACGIH TWA 100 ppm STODDARD SOLVENT OSHA TWA 2900 mg/m3
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: Opaque, colored, viscous liquid; Slightly fragrantGeneral Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point 110 ºF [Test Method: Closed Cup]
Boiling point 212 ºFDensity 8.3 lb/gal
Vapor Pressure No Data Available
Specific Gravity 1.024 [Ref Std: WATER=1]pH 7.5 - 8.5
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Solubility in Water NegligibleEvaporation rate No Data AvailableVolatile Organic Compounds 111.26 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
excluding exempt compounds]Kow - Oct/Water partition coef No Data AvailablePercent volatile 12.01 % weight [Details: excluding exempt compounds]VOC Less H2O & Exempt Solvents 275.77 g/l [Test Method: calculated SCAQMD rule 443.1]Viscosity 7000 - 13000 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: 10.1 Conditions to avoidNone known
10.2 Materials to avoidNone known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionFormaldehyde During CombustionCarbon monoxide During CombustionCarbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
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SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0318-6, LB-K100-0763-2, 60-4300-5031-4, 60-4300-5042-1, 60-4400-9659-6, 60-4400-9660-4, 60-4401-0048-9, 60-4401-0063-8, 60-4550-2922-7, 60-4550-2923-5, 60-4550-2924-3, 60-4550-2935-9, 60-4550-2999-5, 60-4550-3097-7, 60-4550-3306-2, 60-4550-3473-0, 60-4550-3475-5, 60-4550-5288-0, 60-4550-5289-8
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
STATE REGULATIONSContact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
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INTERNATIONAL REGULATIONSContact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 1 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard ClassificationHealth: 1 Flammability: 2 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA).
Revision Changes:Section 2: Ingredient table was modified.Section 8: Exposure guidelines ingredient information was modified.Section 3: Carcinogenicity table was deleted.Section 15: California proposition 65 ingredient information was deleted.Section 15: California proposition 65 heading was deleted.Section 15: California proposition 65 cancer warning was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
MATERIAL SAFETY DATA SHEET 3M(TM) PERFORMANCE FINISH PN 38112, 39030, 06072 & Performance Finish Synthetic Wax Protectant PN 39037 07/29/10
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3M MSDSs are available at www.3M.com
MATERIAL SAFETY DATA SHEET 3M(TM) LEATHER AND VINYL RESTORER PN 39040 09/05/2008
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Material Safety Data Sheet
Copyright, 2008, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) LEATHER AND VINYL RESTORER PN 39040 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 09/05/2008Supercedes Date: 12/29/2006
Document Group: 19-7411-2
Product Use:Intended Use: AutomotiveSpecific Use: AUTOMOTIVE INTERIOR DETAILING
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtWATER 7732-18-5 70 - 90POLY(DIMETHYLSILOXANE) 63148-62-9 15 - 40POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER 60828-78-6 1 - 5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: WHITE LIQUID, light fruit scentGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards:
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
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Skin Contact:Contact with the skin during product use is not expected to result in significant irritation.
Inhalation:No health effects are expected.
Ingestion:No health effects are expected.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: No need for first aid is anticipated.
If Swallowed: No need for first aid is anticipated.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data Available
5.2 EXTINGUISHING MEDIAMaterial will not burn.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
MATERIAL SAFETY DATA SHEET 3M(TM) LEATHER AND VINYL RESTORER PN 39040 09/05/2008
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Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGKeep out of the reach of children. Avoid contact with oxidizing agents.
7.2 STORAGEStore away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSNot applicable. Do not use in a confined area or areas with little or no air movement.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin ProtectionNot applicable. Gloves are not required.
8.2.3 Respiratory ProtectionUnder normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half mask or full facepiece air-purifying respirator with N100 particulate filters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating.
8.3 EXPOSURE GUIDELINES
None Established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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Odor, Color, Grade: WHITE LIQUID, light fruit scentGeneral Physical Form: Liquid Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point 212 ºFDensity 8.3 lb/galVapor Density No Data Available
Vapor Pressure No Data Available
Specific Gravity 1 [Ref Std: WATER=1]pH 7 - 8 Melting point Not Applicable
Solubility in Water NegligibleViscosity <= 20 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionCarbon monoxide During CombustionCarbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
MATERIAL SAFETY DATA SHEET 3M(TM) LEATHER AND VINYL RESTORER PN 39040 09/05/2008
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Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0306-1, 60-4400-9524-2, 60-4550-3001-9
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - Yes
STATE REGULATIONSContact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
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This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 1 Flammability: 0 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard ClassificationHealth: 1 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA).
Revision Changes:Copyright was modified.Section 14: ID Number Heading Template 1 was added.Section 14: ID Number(s) Template 1 was added.Section 2: Ingredient table was added.Section 8: Exposure guidelines information - none - was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
3M MATERIAL SAFETY DATA SHEET 3M(TM) Foaming Engine Degreaser, PN 08899 12/29/2006
_________________________________________________________________________________________________ Page 1 of 8
Material Safety Data Sheet
Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Foaming Engine Degreaser, PN 08899MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 12/29/2006Supercedes Date: 11/06/2006
Document Group: 19-7425-2
Product Use:Intended Use: AutomotiveSpecific Use: Engine Cleaner
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt WATER 7732-18-5 40 - 70 2-BUTOXYETHANOL 111-76-2 7 - 13 HEAVY AROMATIC NAPHTHA 64742-94-5 5 - 10 ETHOXYLATED NONYLPHENOL 127087-87-0 3 - 7 MESITYLENE 108-67-8 1 - 5 BUTANE 106-97-8 1 - 5 PROPANE 74-98-6 1 - 5 LIGHT AROMATIC NAPHTHA 64742-95-6 1 - 5 1,2,4-TRIMETHYLBENZENE 95-63-6 1 - 5 TRIPROPYLENE GLYCOL METHYL ETHER 25498-49-1 0.5 - 1.5 ETHYLBENZENE 100-41-4 < 0.15
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: AerosolOdor, Color, Grade: White foam spray; slight solvent odor
3M MATERIAL SAFETY DATA SHEET 3M(TM) Foaming Engine Degreaser, PN 08899 12/29/2006
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General Physical Form: LiquidImmediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure andexplode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source andflash back. Aerosol container contains flammable material under pressure. May cause target organ effects. Contains achemical or chemicals which can cause cancer.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose andthroat pain.
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,slowed reaction time, slurred speech, giddiness, and unconsciousness.
Carcinogenicity: Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description Regulation ETHYLBENZENE 100-41-4 Group 2B International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices arefollowed.
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Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medicalattention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Nevergive anything by mouth to an unconscious person. Get medical attention.
4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available Flash Point -50 ºF [Details: (Propellant)] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposedcontainers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-containedbreathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremelyflammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosolcontainer contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decompositioninformation.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more informationon handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned upby qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation todisperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source andcould cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and builddikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam designed for use onsolvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around
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the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix insufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean upresidue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and followsafety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in an approved metalcontainer. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according tolocal, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking whilehandling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol containercontains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reachof children. Avoid contact with oxidizing agents. Avoid skin contact.
7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not store containers ontheir sides. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSDo not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilationto control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is notadequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin ProtectionNot applicable. Avoid skin contact. Gloves are not required.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult withyour glove and/or protective clothing manufacturer for selection of appropriate compatible materials.Gloves made from the following material(s) are recommended: Butyl Rubber, Nitrile Rubber, Polyethylene/Ethylene VinylAlcohol.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance withOSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and N95 particulate prefilters.Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Foaming Engine Degreaser, PN 08899 12/29/2006
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8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information 2-BUTOXYETHANOL ACGIH TWA 20 ppm Table A3 2-BUTOXYETHANOL OSHA TWA, Vacated 25 ppm Skin Notation* 2-BUTOXYETHANOL OSHA TWA 50 ppm Skin Notation*; Table Z-1 BUTANE ACGIH TWA 1000 ppm BUTANE OSHA TWA 800 ppm Table Z-1A ETHYLBENZENE ACGIH TWA 100 ppm Table A3 ETHYLBENZENE ACGIH STEL 125 ppm Table A3 ETHYLBENZENE OSHA TWA 100 ppm Table Z-1A ETHYLBENZENE OSHA STEL 125 ppm Table Z-1A HEAVY AROMATIC NAPHTHA CMRG TWA 17 ppm LIGHT AROMATIC NAPHTHA CMRG TWA 50 ppm MESITYLENE ACGIH TWA 25 ppm MESITYLENE OSHA TWA 25 ppm Table Z-1A PROPANE ACGIH TWA 1000 ppm PROPANE OSHA TWA 1000 ppm Table Z-1
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your localregulatory agency.
SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: Aerosol Odor, Color, Grade: White foam spray; slight solvent odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point -50 ºF [Details: (Propellant)] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point <=0 ºF [Details: CONDITIONS: Compressed Gas]
Vapor Density >=1 [Ref Std: AIR=1]
Specific Gravity Approximately 0.872 Units not avail. or not appl. [Ref Std:WATER=1]
pH No Data Available Melting point Not Applicable Solubility In Water Not Applicable Solubility in Water Appreciable Evaporation rate >=1 [Ref Std: ETHER=1] Volatile Organic Compounds 35 [Test Method: calculated per CARB title 2] Percent volatile 85 - 90 %
3M MATERIAL SAFETY DATA SHEET 3M(TM) Foaming Engine Degreaser, PN 08899 12/29/2006
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Viscosity No Data Available
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or itscomponents.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste productin a permitted hazardous waste facility.Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. Absorbed waste may also be incinerated in a permitted hazardous waste incinerator in the presence of a combustible material.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
3M MATERIAL SAFETY DATA SHEET 3M(TM) Foaming Engine Degreaser, PN 08899 12/29/2006
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LB-K100-0305-5, 60-4100-0945-4, 60-4550-3012-6
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for thismaterial.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS Contact 3M for more information.
311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt 1,2,4-TRIMETHYLBENZENE 95-63-6 1 - 5 2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 7 - 13 ETHYLBENZENE 100-41-4 < 0.15
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status MESITYLENE 108-67-8 Toxic Substances Control Act (TSCA) 4 Test
Rule Chemicals Applicable
STATE REGULATIONS Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification ETHYLBENZENE 100-41-4 **Carcinogen
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Foaming Engine Degreaser, PN 08899 12/29/2006
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INTERNATIONAL REGULATIONSContact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None Aerosol Storage Code: 1
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that arepresented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on theinherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known tobe generated in significant quantities.
Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazardsof the product have not changed. We encourage you to reread the MSDS and review the information.
Revision Changes:Section 14: ID Number(s) was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method ofuse or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
3M MATERIAL SAFETY DATA SHEET 3M(TM) Tire Restorer PN 39042 10/23/2007
_________________________________________________________________________________________________ Page 1 of 7
Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Tire Restorer PN 39042 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 10/23/2007Supercedes Date: 12/29/2006
Document Group: 19-7494-8
Product Use:Intended Use: AutomotiveSpecific Use: APPREARANCE ENHANCEMENT
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtWATER 7732-18-5 60 - 90POLY(DIMETHYLSILOXANE) 63148-62-9 10 - 20GLYCERIN 56-81-5 3 - 7
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: White Emulsion,General Physical Form: Liquid Immediate health, physical, and environmental hazards:
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Tire Restorer PN 39042 10/23/2007
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Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL Not ApplicableFlammable Limits - UEL Not Applicable
5.2 EXTINGUISHING MEDIAOrdinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Tire Restorer PN 39042 10/23/2007
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Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors, mists or spray. Avoid prolonged or repeated skin contact. Keep out of the reach of children. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGEKeep from freezing.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSDo not use in a confined area or areas with little or no air movement.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact.
8.2.2 Skin ProtectionGloves not normally required. Avoid prolonged or repeated skin contact.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece air-purifying respirator with P95 particulate filters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
3M MATERIAL SAFETY DATA SHEET 3M(TM) Tire Restorer PN 39042 10/23/2007
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Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationGLYCERIN ACGIH TWA, as mist 10 mg/m3 GLYCERIN OSHA TWA, as mist,
respirable5 mg/m3 Table Z-1
GLYCERIN OSHA TWA, Vacated, as mist, total dust
10 mg/m3
GLYCERIN OSHA TWA, as mist, total dust
15 mg/m3 Table Z-1
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: White Emulsion,General Physical Form: Liquid Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL Not ApplicableFlammable Limits - UEL Not ApplicableBoiling point 212 ºF
Vapor Density Not Applicable
Vapor Pressure No Data AvailableSpecific Gravity 1 [Ref Std: WATER=1]
Melting point Not Applicable
Solubility in Water CompleteEvaporation rate Not ApplicableVolatile Organic Compounds < 1 % [Test Method: calculated per EPA method 24]Percent volatile 60 - 90 %VOC Less H2O & Exempt Solvents Not ApplicableViscosity 1 - 50 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
3M MATERIAL SAFETY DATA SHEET 3M(TM) Tire Restorer PN 39042 10/23/2007
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Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionFormaldehyde During CombustionCarbon monoxide During CombustionCarbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0306-0, 60-4400-9525-9, 60-4550-3002-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
3M MATERIAL SAFETY DATA SHEET 3M(TM) Tire Restorer PN 39042 10/23/2007
_________________________________________________________________________________________________ Page 6 of 7
Contact 3M for more information.
311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
STATE REGULATIONSContact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 1 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Revision Changes:Copyright was modified.Section 3: Potential effects from eye contact was modified.Section 14: ID Number Heading Template 1 was added.Section 14: ID Number(s) Template 1 was added.Section 2: Ingredient table was added.Section 8: Exposure guidelines ingredient information was added.Section 8: Exposure guidelines legend was added.Section 8: Exposure guidelines data source legend was added.
3M MATERIAL SAFETY DATA SHEET 3M(TM) Tire Restorer PN 39042 10/23/2007
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DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
MATERIAL SAFETY DATA SHEET 3M(TM) TIRE AND WHEEL CLEANER PN 39036 04/22/10
_________________________________________________________________________________________________Page 1 of 7
Material Safety Data Sheet
Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) TIRE AND WHEEL CLEANER PN 39036 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 04/22/10Supercedes Date: 07/17/07
Document Group: 19-7521-8
Product Use:Intended Use: AutomotiveSpecific Use: Automotive Tire and Wheel Cleaner
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtWATER 7732-18-5 60 - 100POLY(OXY-1,2-ETHANEDIYL),.ALPHA.-UNDECYL-.OMEGA.-HYDROXY- 34398-01-1 0.1 - 1ETHOXYLATED TETRAMETHYLDECYNEDIOL 9014-85-1 0.1 - 1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Slight YellowGeneral Physical Form: Liquid Immediate health, physical, and environmental hazards:
3.2 POTENTIAL HEALTH EFFECTS
MATERIAL SAFETY DATA SHEET 3M(TM) TIRE AND WHEEL CLEANER PN 39036 04/22/10
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Eye Contact:Sprayed material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:Contact with the skin during product use is not expected to result in significant irritation.
Inhalation:No health effects are expected.
Ingestion:No health effects are expected.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: No need for first aid is anticipated.
If Swallowed: No need for first aid is anticipated.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point Not Applicable
5.2 EXTINGUISHING MEDIANon-combustible. Choose material suitable for surrounding fire.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated.
MATERIAL SAFETY DATA SHEET 3M(TM) TIRE AND WHEEL CLEANER PN 39036 04/22/10
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Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Ventilate the area with fresh air.For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGAvoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. For industrial or professional use only.
7.2 STORAGEKeep container tightly closed.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse in a well-ventilated area. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin ProtectionAvoid prolonged or repeated skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
8.2.3 Respiratory Protection
MATERIAL SAFETY DATA SHEET 3M(TM) TIRE AND WHEEL CLEANER PN 39036 04/22/10
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Avoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece air-purifying respirator with P95 particulate filters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationPETROLEUM DISTILLATES OSHA TWA 2000 mg/m3
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: Slight YellowGeneral Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point Not Applicable
Boiling point 212 ºFDensity 1 [Ref Std: WATER=1]Vapor Density No Data Available
Vapor Pressure No Data Available
Specific Gravity 1 [Ref Std: WATER=1]pH 10 Melting point Not Applicable
Solubility in Water CompleteEvaporation rate No Data AvailableVolatile Organic Compounds 0.12 % [Test Method: calculated SCAQMD rule 443.1]Kow - Oct/Water partition coef No Data AvailableVOC Less H2O & Exempt Solvents 51.26 g/l [Test Method: calculated SCAQMD rule 443.1]Viscosity No Data Available
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: 10.1 Conditions to avoidNone known
10.2 Materials to avoidNone known
MATERIAL SAFETY DATA SHEET 3M(TM) TIRE AND WHEEL CLEANER PN 39036 04/22/10
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Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionNone known. Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatment system. Reduce discharge rate if foaming occurs. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0306-2, 60-4400-9523-4, 60-4550-3004-3, 60-4550-3472-2, 60-4550-3480-5
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
MATERIAL SAFETY DATA SHEET 3M(TM) TIRE AND WHEEL CLEANER PN 39036 04/22/10
_________________________________________________________________________________________________Page 6 of 7
Contact 3M for more information.
311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No
STATE REGULATIONSContact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
Revision Changes:Section 1: Product use information was modified.Copyright was modified.Section 3: Potential effects from eye contact was modified.Section 5: Unusual fire and explosion hazard information was modified.Section 8: Skin protection phrase was modified.Section 8: Prevention of swallowing information was modified.Section 13: Waste disposal method information was modified.Section 8: Eye/face protection information was modified.Section 8: Respiratory protection - recommended respirators information was modified.Section 15: Inventories information was modified.Sections 3 and 9: Odor, color, grade information was modified.Section 9: Property description for optional properties was modified.
MATERIAL SAFETY DATA SHEET 3M(TM) TIRE AND WHEEL CLEANER PN 39036 04/22/10
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Section 14: ID Number Heading Template 1 was added.Section 14: ID Number(s) Template 1 was added.Section 2: Ingredient table was added.Section 8: Exposure guidelines ingredient information was added.Section 10.1 Conditions to avoid heading was added.Section 10.2 Materials to avoid heading was added.Section 6: Personal precautions information was added.Section 6: Environmental procedures information was added.Section 6: Methods for cleaning up information was added.Section 10: Materials to avoid physical property was added.Section 10: Conditions to avoid physical property was added.Section 8: Hand protection information was added.Section 6: Release measures information was deleted.Section 10: Materials and conditions to avoid physical property was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806
MANUFACTURER: 3MDIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 09/14/2007Supercedes Date: 12/29/2006
Document Group: 19-8268-5
Product Use:Intended Use: AutomotiveSpecific Use: REMOVES LIGHT OXIDATION AND OTHER IMPERFECTIONS FROM
AUTOMOTIVE PAINTED SURFACE
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtWATER 7732-18-5 40 - 70ALUMINUM OXIDE 1344-28-1 5 - 15DISTILLATES (PETROLEUM), ACID TREATED, LIGHT 64742-14-9 5 - 15GLYCERIN 56-81-5 1 - 5POLYURETHANE DISPERSION 71394-31-5 1 - 5CARNAUBA WAX 8015-86-9 1 - 5WHITE MINERAL OIL (PETROLEUM) 8042-47-5 1 - 5OXIDIZED POLYETHYLENE 68441-17-8 0.5 - 1.5NONYLPHENOXYPOLY(OXYETHYLENE)ETHANOL 9016-45-9 0.1 - 1.0
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Slight solvent odor, Tan
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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General Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point 170 ºF [Test Method: Pensky-Martens Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableOSHA Flammability Classification: Class II Combustible Liquid
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid breathing of vapors, mists or spray. Keep out of the reach of children. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGE
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber.
8.2.3 Respiratory ProtectionUnder normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationALUMINUM OXIDE ACGIH TWA, particulate
matter, < 1% crystalline silica
10 mg/m3 Table A4
ALUMINUM OXIDE CMRG TWA 1 fiber/cc ALUMINUM OXIDE OSHA TWA, respirable 5 mg/m3 Table Z-1ALUMINUM OXIDE OSHA TWA, Vacated, as
dust10 mg/m3
ALUMINUM OXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1GLYCERIN ACGIH TWA, as mist 10 mg/m3 GLYCERIN OSHA TWA, as mist,
respirable5 mg/m3 Table Z-1
GLYCERIN OSHA TWA, Vacated, as mist, total dust
10 mg/m3
GLYCERIN OSHA TWA, as mist, total dust
15 mg/m3 Table Z-1
OIL MIST, MINERAL ACGIH TWA, as mist 5 mg/m3 OIL MIST, MINERAL ACGIH STEL, as mist 10 mg/m3 OIL MIST, MINERAL OSHA TWA, as mist 5 mg/m3 Table Z-1VEGETABLE OIL MISTS OSHA TWA, as mist 10 mg/m3 Table Z-1AVEGETABLE OIL MISTS (EXCEPT
CASTOR, CASHEW, OR SIMILAR IRRITANT OILS)
ACGIH TWA, as mist 10 mg/m3
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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WHITE MINERAL OIL (PETROLEUM) CMRG TWA 5 mg/m3 WHITE MINERAL OIL (PETROLEUM) CMRG STEL 10 mg/m3 VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: Slight solvent odor, TanGeneral Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point 170 ºF [Test Method: Pensky-Martens Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point 212 ºFDensity 8.4 lb/galVapor Density No Data Available
Vapor Pressure No Data Available
Specific Gravity 1 [Ref Std: WATER=1]pH 7.5 - 8.5 Melting point No Data Available
Solubility in Water AppreciableEvaporation rate No Data AvailableVolatile Organic Compounds 14 % weightVOC Less H2O & Exempt Solvents 1.17 lb/gal [Test Method: calculated per EPA method 24]Viscosity 7,000 - 20,000 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionCarbon monoxide During CombustionCarbon dioxide During Combustion
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0305-7, 60-4300-5033-0, 60-4400-9502-8, 60-4400-9519-2, 60-4550-2982-1, 60-4550-3098-5, 60-4550-3308-8
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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Contact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 1 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Revision Changes:Copyright was modified.Section 2: Ingredient table was modified.Section 14: ID Number(s) was modified.Section 15: WHMIS regulations heading was added.Section 15: WHMIS regulations information was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
3M MATERIAL SAFETY DATA SHEET 3M(TM) ONE STEP CLEANER WAX, LIGHT OXIDATION REMOVER - PN 39006 39806 09/14/2007
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particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
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Material Safety Data Sheet
Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 04/14/10Supercedes Date: 03/10/10
Document Group: 20-2814-0
Product Use:Intended Use: AutomotiveSpecific Use: Removes defects from painted surface
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtWATER 7732-18-5 30 - 60SILICA 7631-86-9 15 - 40HYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 10 - 30KAOLINITE 1318-74-7 3 - 7OLEIC ACID 112-80-1 1 - 5ASSOCIATED MINERALS Mixture 1 - 5SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES 64741-88-4 1 - 5QUARTZ SILICA 14808-60-7 < 3GLYCERIN 56-81-5 0.5 - 1.5MINERAL OIL 64741-89-5 0.5 - 1.5POLY(OXYETHYLENE)SORBITAN MONOSTEARATE 9005-67-8 0.1 - 1.0
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
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Odor, Color, Grade: Light brown. Slight solvent odor.General Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.
Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Carcinogenicity:Contains a chemical or chemicals which can cause cancer.
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
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Ingredient C.A.S. No. Class Description RegulationQUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to
humansInternational Agency for Research on Cancer
QUARTZ SILICA 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point >= 150 ºF [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableOSHA Flammability Classification: Class IIIA Combustible Liquid
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures:
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
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Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Do not breathe vapors. Do not breathe dust. Avoid contact with oxidizing agents. Avoid eye contact. Avoid breathing of dust created by sanding, grinding or machining.
7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Safety Glasses with side shieldsIndirect Vented Goggles.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: NeopreneNitrile Rubber
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
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.
8.2.3 Respiratory ProtectionDo not breathe vapors. Do not breathe dust. Avoid breathing of dust created by sanding, grinding or machining.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefiltersHalf facepiece or fullface air-purifying respirator with P95 particulate filters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationGLYCERIN ACGIH TWA, as mist 10 mg/m3 GLYCERIN OSHA TWA, respirable
fraction5 mg/m3
GLYCERIN OSHA TWA, as total dust 15 mg/m3 HYDROTREATED LIGHT PETROLEUM DISTILLATES
CMRG TWA 300 ppm
QUARTZ SILICA ACGIH TWA, respirable fraction
0.025 mg/m3
QUARTZ SILICA OSHA TWA concentration, respirable
0.1 mg/m3
QUARTZ SILICA OSHA TWA concentration, as total dust
0.3 mg/m3
SILICA CMRG TWA, as respirable dust
3 mg/m3
SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES
CMRG TWA 5 mg/m3
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: Light brown. Slight solvent odor.General Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point >= 150 ºF [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point > 150 ºF [Test Method: ASTM METHOD]Density 1.2 g/mlVapor Density No Data Available
Vapor Pressure 14.7 mmHg [@ 20 ºC] [Test Method: ASTM METHOD]
Specific Gravity 1.2 [Ref Std: WATER=1]pH >=7.5
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Melting point Not Applicable
Solubility in Water NegligibleEvaporation rate No Data AvailableVolatile Organic Compounds 15.47 % [Test Method: calculated SCAQMD rule 443.1] [Details:
Excluding Exempt Compounds]Kow - Oct/Water partition coef No Data AvailablePercent volatile 55.97 %VOC Less H2O & Exempt Solvents 390.7 g/l [Test Method: calculated SCAQMD rule 443.1]Viscosity 14000 - 25000 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: 10.1 Conditions to avoidHeatSparks and/or flames
10.2 Materials to avoidNone known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionFormaldehyde During CombustionCarbon monoxide During CombustionCarbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
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Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D018 (Benzene)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0305-8, LB-K100-0393-4, 60-4300-5037-1, 60-4300-5038-9, 60-4300-5039-7, 60-4300-5040-5, 60-4550-3020-9, 60-4550-3281-7, 60-4550-3477-1
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
311/312 Hazard Categories:Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
STATE REGULATIONSContact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. ClassificationSILICA, CRYSTALLINE (AIRBORNE
PARTICLES OF RESPIRABLE SIZE)SEQ677 **Carcinogen
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
_________________________________________________________________________________________________ Page 8 of 9
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 1 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Revision Changes:Section 8: Eye/face protection information was modified.Section 8: Skin protection - recommended gloves information was modified.Section 8: Respiratory protection - recommended respirators information was modified.Section 2: Ingredient table was modified.Section 10: Materials to avoid physical property was modified.Section 10: Conditions to avoid physical property was modified.Section 5: OSHA flammability heading was added.Section 5: OSHA flammability data was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
MATERIAL SAFETY DATA SHEET 3M™ Perfect-It II Rubbing Compound PN05973 PN05974 PN05968 PN039002 04/14/10
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3M MATERIAL SAFETY DATA SHEET 3M(TM) QUICK WAX PN 39034 12/29/2006
_________________________________________________________________________________________________ Page 1 of 7
Material Safety Data Sheet
Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) QUICK WAX PN 39034MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 12/29/2006Supercedes Date: 11/06/2006
Document Group: 21-8199-8
Product Use:Intended Use: AutomotiveSpecific Use: ENHANCE APPEARANCE OF AUTOMOTIVE SURFACE
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt WATER 7732-18-5 60 - 100 CARNAUBA WAX 8015-86-9 0.5 - 1.5 2-BUTOXYETHANOL 111-76-2 0.1 - 1.0
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: clear, little odorGeneral Physical Form: LiquidImmediate health, physical, and environmental hazards:
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
3M MATERIAL SAFETY DATA SHEET 3M(TM) QUICK WAX PN 39034 12/29/2006
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Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:This product may have a characteristic odor; however, no adverse health effects are anticipated.
Ingestion:No health effects are expected.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices arefollowed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: No need for first aid is anticipated.
If Swallowed: No need for first aid is anticipated.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available Flash Point Not Applicable Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available
5.2 EXTINGUISHING MEDIANon-combustible. Choose material suitable for surrounding fire. Material will not burn.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus(SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decompositioninformation.
3M MATERIAL SAFETY DATA SHEET 3M(TM) QUICK WAX PN 39034 12/29/2006
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SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for moreinformation on handling and managing the spill. Ventilate the area with fresh air. Contain spill. Working from around the edges ofthe spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficientabsorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closedcontainer approved for transportation by appropriate authorities. Discharge the resulting residue containing solution to a municipal orindustrial wastewater treatment facility.
In the event of a release of this material, the user should determine if the release qualifies as reportable according tolocal, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGKeep out of the reach of children. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures tobelow Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGEKeep container tightly closed.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSNot applicable.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin ProtectionAvoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposureassessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
8.2.3 Respiratory ProtectionUnder normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information 2-BUTOXYETHANOL ACGIH TWA 20 ppm Table A3 2-BUTOXYETHANOL OSHA TWA, Vacated 25 ppm Skin Notation*
3M MATERIAL SAFETY DATA SHEET 3M(TM) QUICK WAX PN 39034 12/29/2006
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2-BUTOXYETHANOL OSHA TWA 50 ppm Skin Notation*; Table Z-1
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your localregulatory agency.
SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: clear, little odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point Not Applicable Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point 200 ºF Density 1 [Ref Std: WATER=1] Vapor Density No Data Available
Vapor Pressure <=1 mmHg [Details: CONDITIONS: @ 68 F.]
Specific Gravity 1.0 - 1.1 [Ref Std: WATER=1] pH 8.8 Melting point Not Applicable
Solubility in Water Complete Evaporation rate No Data Available Volatile Organic Compounds 1.6 % weight Percent volatile 90 - 100 % Viscosity 1 - 50 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition Carbon monoxide During Combustion
3M MATERIAL SAFETY DATA SHEET 3M(TM) QUICK WAX PN 39034 12/29/2006
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Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or itscomponents.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Slowly discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatmentsystem. Reduce discharge rate if foaming occurs. Large quantities may adversely affect biological wastewater treatment systems.For larger quantities:Dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):LB-K100-0305-9, 60-4550-3000-1
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for thismaterial.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS Contact 3M for more information.
311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
3M MATERIAL SAFETY DATA SHEET 3M(TM) QUICK WAX PN 39034 12/29/2006
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STATE REGULATIONS Contact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification Health: 1 Flammability: 0 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that arepresented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on theinherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known tobe generated in significant quantities.
Revision Changes:Section 14: ID Number(s) was modified.Section 1: Initial issue message was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method ofuse or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MATERIAL SAFETY DATA SHEET 3M(TM) QUICK WAX PN 39034 12/29/2006
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3M MSDSs are available at www.3M.com
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
_________________________________________________________________________________________________Page 1 of 8
Material Safety Data Sheet
Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Multi Purpose Spray Lubricant PN 08898 MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M CenterSt. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 01/07/2009Supercedes Date: 05/29/2007
Document Group: 21-8630-2
Product Use:Intended Use: AutomotiveSpecific Use: Lubricant
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by WtHYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 40.0 - 70BUTANE 106-97-8 10.0 - 20.0PROPANE 74-98-6 10.0 - 20.0HYDROTREATED HEAVY NAPHTHENIC PETROLEUM DISTILLATES 64742-52-5 3.0 - 7.0HYDROTREATED HEAVY PARAFFINIC DISTILLATE (PETROLEUM) 64742-54-7 1.0 - 5.0PETROLATUM 8009-03-8 1.0 - 5.0
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Clear liquid sprayed as an aerosol. Solvent odor.General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
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Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Single exposure, above recommended guidelines, may cause: Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
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4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data AvailableFlash Point <=00 ºFFlammable Limits - LEL 0.6 [Details: Propellant]Flammable Limits - UEL 9.5 [Details: Propellant]
5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Flammable liquefied gas. Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Place in an approved metal container. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
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SECTION 7: HANDLING AND STORAGE
7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing agents.
7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Use with functioning spray booth or local exhaust. Use in a well-ventilated area. If exhaust ventilation is not available, use appropriate respiratory protection. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin ProtectionAvoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber.
8.2.3 Respiratory ProtectionAvoid breathing of vapors, mists or spray.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half mask R95 particulate respirator. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional InformationBUTANE ACGIH TWA 1000 ppm BUTANE OSHA TWA 800 ppm Table Z-1AHYDROTREATED HEAVY NAPHTHENIC PETROLEUM DISTILLATES
CMRG TWA 5 mg/m3
HYDROTREATED HEAVY NAPHTHENIC CMRG STEL 10 mg/m3
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
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PETROLEUM DISTILLATESHYDROTREATED LIGHT PETROLEUM DISTILLATES
CMRG TWA 300 ppm
PROPANE ACGIH TWA 1000 ppm PROPANE OSHA TWA 1000 ppm Table Z-1
SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Odor, Color, Grade: Clear liquid sprayed as an aerosol. Solvent odor.General Physical Form: Liquid Autoignition temperature No Data AvailableFlash Point <=00 ºFFlammable Limits - LEL 0.6 [Details: Propellant]Flammable Limits - UEL 9.5 [Details: Propellant]Boiling point No Data AvailableDensity 5.95 lb/galVapor Density No Data Available
Vapor Pressure 760 mm [Details: Propellants]
Specific Gravity 0.72 pH Not ApplicableMelting point Not Applicable
Solubility in Water NegligibleVolatile Organic Compounds 89.17 % [Test Method: calculated SCAQMD rule 443.1] [Details:
excluding exempt compounds]Volatile Organic Compounds 612.00 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
excluding exempt compounds]VOC Less H2O & Exempt Solvents 612.00 g/l [Test Method: calculated SCAQMD rule 443.1]
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance ConditionCarbon monoxide Oxidation, heat or reactionCarbon dioxide Oxidation, heat or reaction
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
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SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.Dispose of empty product containers in a sanitary landfill.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONSContact 3M for more information.
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
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STATE REGULATIONSContact 3M for more information.
CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONSContact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard ClassificationHealth: 2 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Revision Changes:Copyright was modified.Section 9: Property description for optional properties was modified.Section 2: Ingredient table was added.Section 8: Exposure guidelines ingredient information was added.Section 8: Exposure guidelines data source legend was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
MATERIAL SAFETY DATA SHEET 3M(TM) Multi Purpose Spray Lubricant PN 08898 01/07/2009
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OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com