MATERIAL SAFETY DATA SHEET PAGE 1 OF 33 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Calcigel - Calcium Hydroixde Paste with Barium Sulphate INTENDED USE: Pulp Capping on vital pulp. Company Name: Prevest Denpro Limited Address: 38, Industrial Estate, Digiana, Jammu-180010 (India) Tel: + 91-191-2430442 Fax No. +91-191-2430442 Email: [email protected]Web: www.prevestdenpro.com Emergency Contact No:- +91-191-2432548 SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS EINECS Classification Content Calcium Hydroxide 001305-62-0 215-137-3 C; R36/38 35 Barium Sulfate 007727-43-7 231-784-4 C; R36/38 2 SECTION 3: HAZARDS IDENTIFICATION HAZARD DESIGNATION “C” – Corrosive R36/38: Irritating to eyes and skin. EMERGENCY OVERVIEW PHYSICAL APPEARANCE: White Paste IMMEDIATE CONCERNS: R36/38:Irritating to eyes and skin. POTENTIAL HEALTH EFFECTS EYES: Causes eye burns SKIN: Causes skin burns INGESTION: Harmfull if swallowed INHALATION: Irritating to the nose, throat and respiratory tract. SECTION 4: FIRST AID MEASURES Eyes : Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and tested by medical personnel. Skin : Immediately flush skin with plenty of water. Remove clothing. Get medical
Transcript
MATERIAL SAFETY DATA SHEET
PAGE 1 OF 33
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: Calcigel - Calcium Hydroixde Paste with Barium Sulphate
IMMEDIATE CONCERNS: R36/38:Irritating to eyes and skin.
POTENTIAL HEALTH EFFECTS
EYES: Causes eye burns
SKIN: Causes skin burns
INGESTION: Harmfull if swallowed
INHALATION: Irritating to the nose, throat and respiratory tract.
SECTION 4: FIRST AID MEASURES
Eyes : Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and
tested by medical personnel.
Skin : Immediately flush skin with plenty of water. Remove clothing. Get medical
attention immediately. Wash clothing separately before reuse.
Ingestion : if swallowed, do not induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to
an unconscious person.
Inhalation : Remove to fresh air, if not breathing , give artificial respiration or give oxygen by
trained personnel. Seek immediate medical attention.
SECTION 5: FIRE-FIGHTING MEASURES
Fire Fighting Procedures : General: Evacuate all personnel; use protective equipment for fire-fighting . use self –contained breathing apparatus when the
product is involved in fire.
Fire-Fighting Equipment : Non combustible
SECTION 6: ACCIDENTAL RELEASE MEASURES
Small Spill : Clean up spills immediately, observing precautions in Protective
Equipment section. Large Spill : Collect in tightly closed containers
Environmental Precautions
Water Spill : Do not allow to enter sewers or drains that many lead to waterways.
SECTION 7: HANDLING AND STORAGE
Handling : Use suitable protective equipment
Storage : Room Temperature
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal Protective Equipment
Eyes And Face : Wear safety glasses with side shields(or goggles) and a face shield.
Skin: S36/37 : Wear suitable protective clothing and gloves
Respiratory : S51 : Use only in well-ventilated areas.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State : Paste
Odor : Odorless or no characteristic odor Colour : White
SECTION 10: STABILITY AND REACTIVITY
Stability : Stable when stored and handled under recommended conditions.
Conditions To Avoid : Acidic conditions
Incompatible Meterials : Strong acids, metals
MATERIAL SAFETY DATA SHEET
PAGE 3 OF 33
SECTION 11: TOXICOLOGICAL INFORMATION
N/A
SECTION 12: ECOLOGICAL INFORMATION
Environmental Data : Biodegradability-Non established
Ecotoxicological Information : Not yet determined
SECTION 13: DISPOSAL CONSIDERATIONS
Disposal Method : Dispose of in compliance with governmental requlation (EC-1975l0442-20/11
FOR DENTAL USE ONLY: Use as directed. The information and recommended are taken from sources(
raw material MSDS(s) and manufacture’ s knowledge) believed to be accurate; however, Oratech
Products, LLC , makes no warrenty with respect to the accuracy of the information or the suitability of
the recommendation and assumes no liability to any use thereof. Each user should review these recommendation in the specific context of the intended use and determine whether they are
appropriate.
MATERIAL SAFETY DATA SHEET
PAGE 4 OF 33
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: Calplus - Calcium Hydroxide Paste with Iodoform
INTENDED USE: Direct & indirect pulp capping, apexification, temporary & permanent filling of infected root canal
Provide eye washes in workshops where the product is constantly handled
Skin protection:
For further information, see § 11 of S.D.S. - Toxicological information.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
General information:
Physical state: paste
Important health, safety and environmental information:
pH of the substance or preparation: not relevant.
The pH is impossible to measure or its value is not relevant. Boiling point/boiling range: not specified.
Flash point interval: not relevant.
Vapour pressure: not relevant.
Density: not stated.
Water solubility: Dilutable.
Other information: melting point/melting range: not specified.
Self-ignition temperature: not specified.
Decomposition point/decomposition range : not specified.
SECTION 10: STABILITY AND REACTIVITY
The preparation is stable at the handling and storage conditions recommended per § 7 of the safety
data sheet,
SECTION 11: TOXICOLOGICAL INFORMATION
No data is available regarding the preparation itself.
It is generally agreed that substances contained are likely to cause, when applied to the eye of an
animal, serious eye damage which persists
for at least twenty-four hours.
SECTION 12: ECOLOGICAL INFORMATION
No ecological data on the product itself is available.
The product must not be allowed to run into drains or waterways.
SECTION 13: DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
Waste : Recycle or dispose of waste in compliance with current legislation,
preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging : Empty container completely. Keep label(s) on container.
MATERIAL SAFETY DATA SHEET
PAGE 7 OF 33
Give to a certified disposal contractor.
SECTION 14: TRANSPORT INFORMATION
Exempt from transport classification and labelling. Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and
ICAO/IATA for air transport (ADR 2009 - IMDG 2008 - ICAO/IATA 2009).
SECTION 15 : REGULATORY INFORMATION
This preparation was classified in compliance with the directive known as <All preparations>
1999/45/EC and its adaptations. In addition directive 2008/58/EC with the 30° adaptation of
directive 67/548/EEC (Hazardous substances) have been taken into account.
In addition directive 2009/2/EC with the 31° adaptation of directive 67/548/EEC (Hazardous
substances) have been taken into account. In addition Regulation (EC) No 1272/2008 have been taken into account.
This product is not classed as flammable.
Packaging < 125 ml.
Preparation classification:
Contains:
215-137-3 CALCIUM HYDROXIDE
Particular hazards associated with the preparation and safety recommendations:
R 41 Risk of serious damage to eyes. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/39 Wear suitable protective clothing and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
S 60 This material and its container must be disposed of as hazardous waste.
SECTION 16: OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data
sheet is based on our current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without
first obtaining written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal
requirements and local regulations.
The information given on this safety data sheet must be regarded as a description of the safety
requirements relating to our product and not a guarantee of its properties
Full text of risk phrases appearing in section 3: R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
MATERIAL SAFETY DATA SHEET
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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: Dolo EDTA Gel - EDTA Gel Carbamode Peroxide in water soluble base INTENDED USE: EDTA Lubricant
Measures for environmental protection : Do not allow product to reach sewage system or
any water course.
Measures for cleaning/collecting : Pick up mechanically. Additional information : No dangerous substances are released.
SECTION 7: HANDLING AND STORAGE
HandlingProduct is intended for dental use only.
Information for safe handling : No special measures required. Observe normal care for
working with chemicals.
Information about fire - and explosion protection: No special measures required.
Storage Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
Information about storage in one common storage facility : Not required.
Further information about storage conditions : Protect from heat and direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
· Additional information about design of technical facilities: No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:
57-55-6 propane-1,2-diol
OES
Long-term value: 474* 10** mg/m³, 150* ppm
total (vapour and particulates) **particulates
Additional information: The lists valid during the making were used as basis.
Personal protective equipment
General protective and hygienic measures The usual precautionary measures are to be adhered to when handling chemicals. Keep away from
foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands
before breaks and at the end of work.
Respiratory protection: Not required.
MATERIAL SAFETY DATA SHEET
PAGE 10 OF 33
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the
product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of
the penetration times, rates of diffusion and thedegradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
Eye protection : Safety glasses
Body protection : Protective work clothing.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
General Information
Form: paste
Colour: Whitish
Odour: Weak, characteristic
Change in condition
Melting point/Melting range: undetermined
Boiling point/Boiling range: undetermined
Ignition temperature: 400°C
Flash point: Not applicable
Self-igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Density: Not determined
Solubility in / Miscibility with Water: Soluble
SECTION 10: STABILITY AND REACTIVITY
Thermal decomposition / conditions to be avoided : No decomposition if used according
to specifications. Dangerous reactions No : Dangerous reactions known
Dangerous decomposition products : No dangerous decomposition
products known
SECTION 11: TOXICOLOGICAL INFORMATION
Acute toxicity : Nil
Primary irritant effect : Nil
on the skin : May cause skin irritation
MATERIAL SAFETY DATA SHEET
PAGE 11 OF 33
on the eye : Irritating effect.
Sensitization : No sensitizing effects known. Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to
our experience and the information provided to us.
SECTION 12: ECOLOGICAL INFORMATION
General notes : Water hazard class 1 (German Regulation) (Self-assessment):
slightly
hazardous for water.
SECTION 13: DISPOSAL CONSIDERATIONS
Product
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach
sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
SECTION 14: TRANSPORT INFORMATION
Land transport ADR/RID (cross-border)
ADR/RID class: - Not Known
Maritime transport IMDG:
IMDG Class: -
Marine pollutant: No
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class:- Non Dangerous
SECTION 15: REGULATORY CONSIDERATIONS
Labelling according to EU guidelines : Observe the general safety regulations when handling chemicals. The product is not subject to
identification regulations under EU Directives and
the Ordinance on Hazardous Materials (German
GefStoffV).
National regulations Technical instructions (air):
MATERIAL SAFETY DATA SHEET
PAGE 12 OF 33
Class
Share in %
III 9.0
SECTION 16: OTHER INFORMATION
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
Relevant R-phrases
34 Causes burns.
8 Contact with combustible material may cause fire.
S 60 This material and its container must be disposed of as hazardous waste.
SECTION 4: FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Australia: 13 1126, New Zealand: 0800 764 766) or
a doctor (at once). If swallowed, do NOT induce vomiting. Avoid giving milk or oils. Urgent hospital treatment is likely to
be needed at once.
As a general rule, in case of doubt or if symptoms persist, always call a doctor. NEVER induce
swallowing in an unconscious person.
In the event of exposure by inhalation:
In the event of inhalation, move the patient into the fresh air and keep him/her warm and still. If breathing is irregular or has stopped, effect mouth-to-mouth resuscitation and call a doctor. Do not
give the patient anything orally. If the person is unconscious, place in the recovery position and call an
ambulance.
In the event of splashes or contact with eyes:
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
In the event of skin or hair contact:
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running
water.
SECTION 5: FIRE-FIGHTING MEASURES
Not relevant.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal precautions : Avoid any contact with the skin and eyes. Avoid
inhaling dust. Consult the safety measures listed under headings 7 and 8. If a large quantity has been spilt,
evacuate all personnel and only allow intervention by trained
operators equipped with safety apparatus.
Environmental precautions : Prevent any material from entering drains or
waterways. Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13). If the
product contaminates waterways, rivers or drains, alert the
relevant authorities in accordance with statutory procedures
Methods for cleaning up : Clean preferably with a detergent, do not use
solvents
SECTION 7: HANDLING AND STORAGE
The regulations relating to storage premises apply to workshops where the product is handled. Anyone with a history of skin sensitisation must on no account handle such products
Handling : Handle in well-ventilated areas.
MATERIAL SAFETY DATA SHEET
PAGE 15 OF 33
Fire prevention : Prevent access by unauthorised personnel.
Recommended equipment and
procedures : For personal safety, see §8. Observe precautions stated on
label and also industrial safety regulations Avoid inhaling vapors. Carry
out any industrial operation which may give rise to this in a sealed
apparatus. In all cases, recover emissions at source Provide vapor extraction at the emission
source and also general ventilation of the
premises Also provide breathing apparatus for certain
short tasks of an exceptional nature and for emergency
interventions Avoid contact of product with the skin and eyes.
Prohibited equipment and procedures : Smoking, eating and drinking are prohibited in premises
where the preparation is used Never open the packages
under pressure
Storage : Keep the container tightly closed in a dry place. Keep away
from food and drink, including those for animals.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Use personal protection equipment. Anyone with a history of skin sensitisation must on no account
handle such products.
Technical measures : Ensure adequate ventilation, if possible with
extractor fans at work posts and appropriate
general extraction. Check the atmosphere periodically. If this
ventilation is insufficient to maintain the concentration of vapors below the exposure limits, wear breathing apparatus
Respiratory protection : With this preparation, avoid in particular any
inhalation of vapors.
Hand protection : Protective creams may be used for exposed skin,
but they should not be applied after contact with
the product. In the event of prolonged or repeated contact with the hands, use appropriate gloves.
Eye and face protection : Avoid contact with eyes. Wear safety goggles.
Provide eye washes in workshops where the product is constantly
handled.
Skin protection : For further information, see § 11 of S.D.S. – Toxicological information.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
General information : Physical state: paste
Important health, safety
and environmental information : pH of the substance or preparation: not
relevant.
The pH is impossible to measure or its value is not relevant.
Boiling point/boiling range : not specified.
MATERIAL SAFETY DATA SHEET
PAGE 16 OF 33
Flash point interval : not relevant.
Vapour pressure : not relevant. Density : not stated.
Water solubility : Insoluble.
Other information : Melting point/melting range: not specified.
Self-ignition temperature: not specified.
Decomposition point/ decomposition range : not specified.
SECTION 10: STABILITY AND REACTIVITY
The preparation is stable at the handling and storage conditions recommended per § 7 of the safety
data sheet.
SECTION 11: TOXICOLOGICAL INFORMATION
No data is available regarding the preparation itself.
It is generally agreed that substances contained are likely to cause tissue damage in less than four
hours after application to the healthy, unbroken skin of an animal.
It is generally agreed that substances contained are likely to cause serious irritation of the respiratory
system It is generally agreed that substances contained are likely to cause, among certain predisposed subjects, a sensitisation reaction by cutaneous route. It is generally agreed that substances contained are
likely to cause category 3 mutagenic effects
SECTION 12: ECOLOGICAL INFORMATION
No ecological data on the product itself is available. The product must not be allowed to run into
drains or waterways.
Ecotoxicity : Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
SECTION 13: DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
Waste : Recycle or dispose of waste in compliance with current
legislation, preferably via a certified collector or company. Do not
contaminate the ground or water with waste, do not dispose of waste into
the environment. Soiled packaging : Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.
SECTION 14: TRANSPORT INFORMATION
Exempt from transport classification and labelling. Transport product in compliance with provisions of
the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR 2007 - IMDG 2006
- ICAO/IATA 2007).
SECTION 15: REGULATORY INFORMATION
MATERIAL SAFETY DATA SHEET
PAGE 17 OF 33
Hazard classification according to Approved Criteria for Classifying Hazardous Substances [NOHSC:1008(2004)] 3rd Edition and the Australian Code for the Transport of Dangerous Goods by
Road and Rail (6th Edition) M.S.D.S prepared in accordance with the National Code of Practice for the
Preparation of Material Safety Data Sheets, 2nd Edition [NOHSC:2011(2003)]
SECTION 16: OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The
product must not be used for any purposes other than those specified under heading 1 without first
obtaining written handling instructions. It is at all times the responsibility of the user to take all
necessary measures to comply with legal requirements and local regulations. The information given on
this safety data sheet must be regarded as a description of the safety requirements relating to our product and not a guarantee of its properties
Full text of risk phrases appearing in section 3:
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 20/22 Harmful by inhalation and if swallowed.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin. R 43 May cause sensitisation by skin contact.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment
MATERIAL SAFETY DATA SHEET
PAGE 18 OF 33
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: Orafil LC - Light Cured Temporary Filling Material
INTENDED USE: - Temporary fillings, temporary protection in inlay and onlay technique
Health effects are based on the unmixed/uncured material.
Under FDA regulations this product is classified as a medical device. Medical devices are exempt from the labelling provisions of GHS according to the Hazard
Communication Standard (HCS).
Classification of the substance or mixture
Skin Sens. 1H317May cause an allergic skin reaction.
Label elements
Hazard pictograms GHS07 Signal word Warning
Hazard statements
May cause an allergic skin reaction.
Precautionary statements
Wear protective gloves / protective clothing. If skin irritation or rash occurs: Get medical advice/attention.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards Use only for intended scope of application
After inhalation : Seek medical treatment in case of complaints.
After skin contact : Immediately wash with water and soap and rinse thoroughly.
After eye contact : Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing : If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed : No further relevant information
available.
Indication of any immediate medical attention and special treatment needed : No further
relevant information available.
SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
Special hazards arising from the substance or mixture :No further relevant information available.
Advice for firefighters Protective equipment : No special measures required.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures : Not required.
Environmental precautions : No special measures required.
Methods and material for containment and cleaning up : Pick up mechanically.
SECTION 7: HANDLING AND STORAGE
Handling:
Precautions for safe handling : For dental use only.
Information about protection against explosions and fires : No special measures required.
Conditions for safe storage, including any incompatibilities Storage:
Requirements to be met by storerooms and receptacles : See storage instructions on
package Information about storage in one common storage facility : Not required.
Further information about storage conditions : None.
MATERIAL SAFETY DATA SHEET
PAGE 20 OF 33
Specific end use(s) No further relevant information available.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems : No further data; see item 7. Control parameters
Components with limit values that require monitoring at the workplace :
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information : The lists that were valid during the creation were used as basis. Exposure controls
Personal protective equipment:
General protective and hygienic measures : The usual precautionary measures for
handling chemicals should be followed. ·
Breathing equipment : Not required.
Protection of hands: Protective gloves
Material of gloves The selection of the suitable gloves does not only depend on the material, but also
on further marks of quality and varies from manufacturer to manufacturer. As the product is a
preparation of several substances, the resistance of the glove material can not be calculated in
advance and has therefore to be checked prior to the application. Eye protection : Not required
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form : Pasty
Color : Whitish Odor : Characteristic
pH-value : Not determined.
Change in condition
Melting point/Melting range : Undetermined
Boiling point/Boiling range : Undetermined
Flash point : Not applicable. Auto igniting : Product is not selfigniting.
Danger of explosion : Product does not present an explosion hazard.
Density : Not determined.
Solubility in / Miscibility with Water : Not miscible or difficult to mix.
Viscosity: Dynamic : Not determined
Kinematic : Not determined.
Other information : No further relevant information available.
SECTION 10: STABILITY AND REACTIVITY
Reactivity : No further relevant information available.
Chemical stability
MATERIAL SAFETY DATA SHEET
PAGE 21 OF 33
Thermal decomposition / conditions
to be avoided : No decomposition if used according to specifications. Possibility of hazardous reactions : No dangerous reactions known.
Conditions to avoid : No further relevant information available.
Incompatible materials : No further relevant information available.
Hazardous decomposition products : No dangerous decomposition products known.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin : No irritant effect on the eye : No irritating effect
Sensitization : Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations
SECTION 12: ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity : No further relevant information available.
Persistence and degradability : No further relevant information available.
Behavior in environmental systems
Bioaccumulative potential : No further relevant information available.
Mobility in soil : No further relevant information available. Additional ecological information:
General notes : Water hazard class 1 (Self-assessment): slightly hazardous for
water
Results of PBT and vPvB assessment
PBT : Not applicable. vPvB : Not applicable.
Other adverse effects : No further relevant information available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation : Smaller quantities can be disposed of with household waste. Uncleaned packagings
Recommendation : Disposal must be made according to official regulations
SECTION 14: TRANSPORT INFORMATION
UN-Number
DOT, ADR, ADN, IMDG, IATA : Void
MATERIAL SAFETY DATA SHEET
PAGE 22 OF 33
UN proper shipping name DOT, ADR, ADN, IMDG, IATA : Void
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA Class : Void
Packing group
DOT, ADR, IMDG, IATA : Void
Environmental hazards:
Marine pollutant : No Special precautions for user : Not applicable.
Transport in bulk according to
Annex II of MARPOL73/78 and
the IBC Code : Not applicable
UN "Model Regulation" : Void
SECTION 15: REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances) : None of the ingredients are listed. Section 313 (Specific toxic chemical listings) : None of the ingredients are listed.
TSCA (Toxic Substances Control Act):
One or more substances contained in this material are not listed on the TSCA Inventory. Contact
VOCO for more information.
Proposition 65 Chemicals known to cause cancer:
None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed Chemicals known to cause developmental toxicity:
None of the ingredients are listed
Cancerogenity categories
EPA (Environmental Protection Agency)
None of the ingredients are listed TLV (Threshold Limit Value established by ACGIH)
Contact VOCO for more information.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients are listed
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS07
Signal word Warning
MATERIAL SAFETY DATA SHEET
PAGE 23 OF 33
Hazard statements
May cause an allergic skin reaction. Precautionary statements
Wear protective gloves / protective clothing.
If skin irritation or rash occurs : Get medical advice/attention.
Dispose of contents/container in accordance with local/regional/national/international regulations.
SECTION 16: OTHER INFORMATION
The information contained herein is based on our present knowledge and is believed to be correct at
the date issued. The information is subject to change without notice. However, all information, statements, recommendations or suggestions shall not constitute any guarantee, representation or
warranty, expressed or implied. Final determination whether the product is fit and suitable for a
particular purpose and the user's method of use or application is the sole responsibility of the user.
MATERIAL SAFETY DATA SHEET
PAGE 24 OF 33
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: Chlor X - Chlorhexidine Gluconate Solution
INTENDED USE: Dental Company Name: Prevest Denpro Limited
to EU Regulation 1272/2008: The composition is not classified as hazardous.
Label information: The product does not need to be labelled in accordance with
EU directives.
SECTION 4: FIRST AID MEASURES
Inhalation: Fresh air Skin contact: Rinse immediately with plenty of water. If the symptoms remain, seek medical
advice.
Eye contact: Keep the eyelids open and rinse immediately with plenty of water. Call hospital
and continue with the treatment to the ophthalmologist is reached.
Ingestion: Rinse with water. Drink water in small sips.
Further information: Never give any food and/or drink to an unconscious person. Please show this safety data sheet to the doctor on duty. Get medical attention
· Vapour pressure: -- · Density, kg/m³: 1060 – 1070 · Solubility in water: Mixable. · Solubility in organic
solvents: and ethanol acetone
· Vapour density: -- · Evaporation rate: --
· Partition coefficient:
noctanol/water: -- · Viscosity: --
SECTION 10: STABILITY AND REACTIVITY
Conditions to avoid: Stable under normal conditions.
When heated to decomposition produces toxic fumes of chlorine and nitrogen oxides.
SECTION 11: TOXICOLOGICAL INFORMATION
Human health effects and symptoms: · inhalation: Under normal use, no danger
· ingestion: May be irritating to the lining of the esophagus and the
stomach. For concentrated chlorhexidinedigluconat :LD50oral
rat, 2000 mg/kg.
· Skin contact: Under normal use, no danger. May cause skin irritation in
sensitive individuals after repeated and/or prolonged contact · eye contact: Eye contact may cause transient mild stinging
· Further information: Carcinogenicity and teratogenicity: No indications.
SECTION 12: ECOLOGICAL INFORMATION
Toxicity: No data available.
Biodegradation: Biodegradable
Bioaccumulation: No bioaccumulation potential
SECTION 13: DISPOSAL CONSIDERATIONS
Product: Disposed of in compliance with local and national regulations. Contaminated packaging: Should be dispose of as normal waste, incineration.
SECTION 14: TRANSPORT INFORMATION
The product is not dangerous goods. No special transport conditions are required.
ADR/RID Not dangerous goods
ICAO/IATA
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PAGE 27 OF 33
Not dangerous goods
IMO/IMDG Not dangerous goods
SECTION 15: REGULATORY INFORMATION
Health, safety and environmental information shown on the label: The product is not labelled. It must be used according to manufacturer’s recommendations and
managed by medically qualified person.
Precautions:
P102; Keep out of reach of children + P405; Store locked up.
P305; IF IN EYES + P351; Rinse cautiously with water for several minutes + P314; Get medical Advice /attention if you feel unwell.
Further information:
Safety Data Sheet according to REACH 1907/2006/EC. Classification
and Labelling (CLP) EU Regulation 1272/2008. This product meets the demands of MDD
93/42/EEC. The product is CE marked.
SECTION 16: OTHER INFORMATION
References: Not Available
Other Special Considerations: Not Available
Created: 27.04.2013
The information contained herein is based on data considered accurate. However , No warranty is
expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. In no event will the manufacture of the distributor be responsible for damages of any nature
whatsoever resulting from the use of or reliance upon this information. General properties
are to be regarded as guidelines and are not guaranteed for all samples
Full text of risk phrases appearing in section 3: see section 16. Hazardous substances present on their own: (present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a 100% pure state)
INDEX CAS EC Name Symb R: %
10808019 1314-13-2 ZINC OXIDE N 50/53 50 <= x % < 100
10808048 552-22-7 IODOFORM C 34 25 <= x % < 50
Other substances representing a hazard:
No known substance in this category present.
Substances present at a concentration below the minimum danger threshold:
No known substance in this category present.
Other substances with occupational exposure limits: No known substance in this category present.
SECTION 3: HAZARDS IDENTIFICATION
This product is not classed as flammable. Refer to the recommendations regarding the other products
present on the site Possibility of corrosive effects. Very toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.
Other data : Packaging < 125 ml.
SECTION 4: FIRST AID MEASURES
As a general rule, in case of doubt or if symptoms persist, always call a doctor. NEVER induce swallowing in an unconscious person.
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open. If there is any redness, pain or visual impairment, consult an ophthalmologist.
In the event of splashes or contact with skin:
Remove all contaminated or stained clothing immediately. Do not use them again until they have been
decontamined.
Wash the skin thoroughly with soap and water or a recognised cleaner. DO NOT use solvents or thinners.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted
or the patient transferred to hospital
In the event of swallowing:
If swallowed accidentally, do not allow to drink, do not induce vomiting and transfer to hospital
immediately by ambulance. Show the label to the doctor.
SECTION 5: FIRE-FIGHTING MEASURES
Not relevant.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal precautions : Avoid any contact with the skin and eyes.
Consult the safety measures listed under headings 7 and 8.
Environmental precautions: Prevent any material from entering drains or waterways.
Use drums to dispose of waste recovered in accordance with
applicable regulations (see heading 13). If the product contaminates waterways, rivers or drains, alert the relevant
authorities in accordance with statutory procedures
Methods for cleaning up : Clean preferably with a detergent, do not use solvents.
SECTION 7: HANDLING AND STORAGE
The regulations relating to storage premises apply to workshops where the product is handled.
Fire prevention : Prevent access by unauthorised personnel.
Recommended equipment and procedures : For personal safety, see §8. Observe precautions stated on label and also industrial safety regulations
Product must not come into contact with the skin and eyes
Provide safety showers and eye washes in workshops where the product is handled constantly
Prohibited equipment and procedures:
Smoking, eating and drinking are prohibited in premises where the preparation is used. Never open the packages under pressure
Storage : Keep the container tightly closed in a dry place.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Use personal protection equipment as per Directive 89/686/EEC.
Exposure limit values per INRS ED 984:
France VME-ppm: VME-mg/m3: VLE-ppm: VLE-mg/m3: Notes: TMP N°:
ADR/RID Class Code Pack gr. Label Ident. LQ Provis.
8 C10 III 8 80 LQ24 274
IMDG Class 2°Label Pack gr. LQ EMS Provis.
8 - III 5kg F-A, S-B 223 274 944
IATA Class 2°Label Pack gr. Passager Passager Cargo Cargo note
8 - III 822 25Kg 823 100KG -
8 - III 822 5Kg - - -
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SECTION 15 : REGULATORY INFORMATION
This preparation was classified in compliance with the directive known as <All preparations>
1999/45/EC and its adaptations. In addition directive 2004/73/EC with the 29° adaptation of
directive 67/548/EEC (Hazardous substances) have been taken into account. This product is not
classed as flammable.
Packaging < 125 ml.
Preparation classification:
Corrosive Dangerous for the environment
Contains: IODOFORM
Particular hazards associated with the preparation and safety recommendations: R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 34 Causes burns.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
S 60 This material and its container must be disposed of as hazardous waste.
S 57 Use appropriate container to avoid environmental contamination.
SECTION 16: OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data
sheet is based on our current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without
first obtaining written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal
requirements and local regulations.
The information given on this safety data sheet must be regarded as a description of the safety
requirements relating to our product and not a guarantee of its properties
Full text of risk phrases appearing in section 3:
R 34 Causes burns.
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R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
