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Front Matter Source: Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, Vol. 308, No. 1501, Metal Clusters in Chemistry (Dec. 20, 1982), pp. 1-2 Published by: The Royal Society Stable URL: http://www.jstor.org/stable/37213 . Accessed: 02/05/2014 00:57 Your use of the JSTOR archive indicates your acceptance of the Terms & Conditions of Use, available at . http://www.jstor.org/page/info/about/policies/terms.jsp . JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range of content in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new forms of scholarship. For more information about JSTOR, please contact [email protected]. . The Royal Society is collaborating with JSTOR to digitize, preserve and extend access to Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences. http://www.jstor.org This content downloaded from 130.132.123.28 on Fri, 2 May 2014 00:57:41 AM All use subject to JSTOR Terms and Conditions
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Front MatterSource: Philosophical Transactions of the Royal Society of London. Series A, Mathematical andPhysical Sciences, Vol. 308, No. 1501, Metal Clusters in Chemistry (Dec. 20, 1982), pp. 1-2Published by: The Royal SocietyStable URL: http://www.jstor.org/stable/37213 .

Accessed: 02/05/2014 00:57

Your use of the JSTOR archive indicates your acceptance of the Terms & Conditions of Use, available at .http://www.jstor.org/page/info/about/policies/terms.jsp

.JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range ofcontent in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new formsof scholarship. For more information about JSTOR, please contact [email protected].

.

The Royal Society is collaborating with JSTOR to digitize, preserve and extend access to PhilosophicalTransactions of the Royal Society of London. Series A, Mathematical and Physical Sciences.

http://www.jstor.org

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P H L O O H IC A L T R N A T I O N

THE ROYAL SOCIETY

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A.- MATHEMATICAL AND PHYSICAL SCIENCES

ISSN 0080-4614 :

VOLUME: 308 PAGES 1-166 NUMBER1501,

20 December 1982

Metal clusters in chemistry

A DISCUSSION ORGANIZED AND EDITED BY

SIR JATc KLEWIs, NF.R.S., AND M. L. H. GREEN

:: :

PUBLISHED BY THE ROYAL SOCIETY

HOUSE TERRACE LONDO Y 5AG

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PROCEEDINGS AND PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY

Notice to contributors The Royal Society welcomes suitable communications for publication in its scientific journals: papers estimated to occupy up to 24 printed pages are con- sidered for the Proceedings and longer papers and those with numerous or large illustrations for the Philosophical Transactions.

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The Editors particularly welcome short communications to Proceedings; as far as possible they will be given expeditious treatment both in consideration and in printing, and this will be facilitated if a paper is submitted with a firm recommendation by a Fellow.

Associate Editors: series A, Mathematical and Physical Sciences

(For Standing Orders see current Year Book.)

Professor E. A. Ash Professor D. S. Jones Professor J. M. Thomas Professor F. F. Bonsall Professor T. W. B. Kibble Dr D. W. Turner Professor G. Gee Professor M. S. Longuet-Higgins Professor R. Week Professor A. Hewish Professor G. W. Series Professor A. J. C. Wilson

Copyright ? 1982 The Royal Society and the authors of individual papers.

It is the policy of the Royal Society not to charge any royalty for the production of a single copy of any one article made for private study or research. Requests for the copying or reprinting of any article for any other purpose should be sent to the Royal Society.

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Phil. Trans. R. Soc. Lond. A 308, 1-166 (1982) [ 1 ] Printed in Great Britain

METAL CLUSTERS IN CHEMISTRY

A DISCUSSION ORGANIZED AND EDITED BY

SIR JACK LEWIS, F.R.S., AND M. L. H. GREEN

(Discussion held 20 and 21 May 1982 - Typescripts received 8 July 1982)

CONTENTS PAGE

SIR JACK LEWIS, F.R.S.

Introductory remarks 3

B. F. G. JOHNSON AND SIR JACK LEWIS, F.R.S.

Aspects of ruthenium and osmium cluster chemistry 5

Discussion: D. M. P. MINGOS 14

H. VAHRENKAMP

Heteronuclear cluster compounds 17

J. A. IGGO, M.J. MAYS AND P. L. TAYLOR

The chemistry of stabilized clusters 27

J. G. NOLTES

Chemistry of organocopper clusters 35

G. LONGONI, A. CERIOTTI, R. DELLA PERGOLA, M. MANASSERO, M. PEREGO, G. PIRO AND M. SANSONI

Iron, cobalt and nickel carbide-carbonyl clusters by CO scission 47

A.J. DEEMING AND P.J. MANNING

Nucleophilic addition at g1-alkyne clusters leading to carbon-carbon bond formation 59

R. E. COLBORN, A. F. DYKE, S. A. R. KNOX, KIRSTY A. MACPHERSON, K. A. MEAD, A. G. ORPEN, J. Rout AND P. WOODWARD

Carbon-carbon bond formation at dinuclear metal centres 67

D. . M.P. MINGOS

Some theoretical and structural aspects of gold cluster chemistry 75

General discussion

M. B. HALL, J. C. GREEN 85

[Published 20 December 1982 Vol. 208. A 150 I .

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CONTENTS

PAGE F. G. A. STONE, F.R.S.

Novel routes to heteronuclear metal clusters containing rhodium 87

B. T. HEATON

Nuclear magnetic resonance studies in cluster chemistry 95

Discussion: JOAN MASON, E. W. RANDALL 101

J. S. BRADLEY

Carbidocarbonyl clusters of iron 103

Discussion: E. W. RANDALL 113

J. M. BASSET, B. BESSON, A. CHOPLIN AND A. THEOLIER

Catalysis by supported clusters: two examples of catalytic reactions that involve a molecular cluster frame 115

Discussion: R. WHYMAN 124

A. FusI, R. UGO, R. PSARO, P. BRAUNSTEIN AND J. DEHAND

The homogeneous hydrogenation of carbon-carbon multiple bonds with hetero- nuclear platinum clusters 125

R. WHYMAN

Industrial aspects of cluster chemistry 131

R. E. MCCARLEY

Halide and chalcogenide clusters of the early transition metals 141

C. D. GARNER, S. R. ACOTT, G. CHRISTOU, D. COLLISON, F. E. MABBS AND

V. PETROULEAS

Iron-molybdenum-sulphur clusters 159

2

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