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LightPeriodic Trends
Quantum Numbers
Electron Configurati
onMixed Bag
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Mixed Bag
Which element has the electron
configuration 1s22s22p63s23p3?
If you add up the exponents,
there are 15 electrons which corresponds to phosphorous.
What is the difference
between the ground state
and the excited state for an electron?
The ground state is the lowest energy level for an electron; the excited
state is when an electron is at an energy level above its normal
state (the excited state is temporary).
How many valence electrons does
carbon have in it’s outer shell?
(Hint: first write out the e-
configuration)
C = 1s22s22p2
The second energy level is the outside shell in this case.
There are 4 electrons in the
second energy level (valence shell) for
carbon.
How many unpaired
electrons does germanium have
in it’s valence shell?
(Hint: draw the orbital diagram
first!)
After drawing the orbital diagram,
there are 2 unpaired electrons
in the germanium atom.
How many unpaired electrons
are in there in a bromine atom? How does this relate to the charge on a
bromide ion?
Bromine has 1 unpaired electron in it’s orbital diagram which makes sense since bromide
ions have a charge of -1 (they have gained 1 e-
to complete their valence shell).
Periodic Trends
Which atom would have the
largest ionization energy –Mg or Cl?
Chlorine would have the largest I.E. because it is
farther right on the periodic table
(e- are held closer so it will be harder
to rip the e- off)
Define the term “electron
affinity”
The energy involved when an
atom gains an electron.
(The opposite of ionization energy)
Rank the following
elements in order of
increasing atomic radius:
In, Al, B, Ga
B < Al < Ga < In
Rank the elements in
order of increasing metallic
character:N, Zr, Cs, Co
N < Co < Zr < Cs
Describe the comparative
size of a cation compared to the atom from which
it forms.
Cations are smaller than the atoms from which they form due
to the increasing proton/electron
attraction due to the loss of electrons.
Electron Configurati
on
What is the electron
configuration for cobalt?
Co = 1s22s22p63s23p64s2
3d7
What is the noble gas
configuration for zirconium?
Zr =[Kr]5s24d2
What is the orbital
configuration for sulfur?
1s 2s 2p
3s 3p
What do the coefficient, letter,
and exponent signify when
writing electron configurations?
Coefficient = principal energy
level
Letter = sublevel
Exponent = # of electrons in sublevel
What is the electron
configuration for iridium?
Ir = 1s22s22p63s23p64s23
d10
4p65s24d105p66s24f14
5d7
Quantum #’s
What is the maximum number of
electrons that can be contained in an:
s sublevel?p sublevel?d sublevel?f sublevel?
s sublevel – 2 e-
p sublevel – 6 e-
d sublevel – 10 e-
f sublevel – 14 e-
Which sublevels (s, p, d, or f) are
located in the fourth principal energy level?
The third energy level has s, p, d, and f sublevels
present.
How many total electrons can fit into
the third principal energy level? (Take
into account all sublevels present in the 3rd energy level)
The third energy level contains s,
p, and d sublevels so 2 +
6 + 10 = 18 total
electrons!
How do you draw arrows in an
orbital diagram and why are they drawn that way?
Arrows are drawn with the first pointing
up and the second pointing down due to the Pauli Exclusion Principal (electrons must have opposite spins in the same
orbital).
Define the Aufbau Principle and how it
relates to the electrons in an
atom.
The Aufbau Principle says that electrons completely fill from the lowest energy
level to the highest energy level.
Light
Describe the dual nature of
light
Light behaves as both a particle
and a wave.
What is the wavelength of a portion of light
having a frequency of
4.73 x 1012 Hz?
Use c = λν…
λ = 6.34 x 10-5 m
Calculate the energy of a
photon of light having a
frequency of 3.11 x 1013 kHz.
Use E = hv…
E = 2.06 x 10-17
J
What is the wavelength of a portion of light
having an energy of 1.44 x 10-12
J?
Use both light equations!
First calculate the frequency…
v = 2.17 x 1021 Hz
Then use v to find λ…
λ = 1.38 x 10-13 m
Describe why you saw colors in the flame during the
flame test lab (think about what is going
on with the electrons)
As the element samples are placed in the flame, the
electrons are given energy so they jump from the
ground state to the excited state. When the electrons
go back down to the ground state, they emit this extra
energy which we see as light (the color depends on the λ
and v.
Final JeopardyFinal Jeopardy
What are the general shapes of the four orbitals
(s, p, d, and f)?
Final JeopardyFinal Jeopardy
s = spherical
p = peanut
d = dumbell (clover)
f = flower