MONTHLY MONITORING REPORT AUGUST 2016 Total Integrated Enterprises Page 1 of 10 317 E. Main Street...

Oneida Total Integrated Enterprises Page 1 of 10

317 E. Main Street Ventura, CA 93001

Tel: (805) 585-2110 Fax: (805) 585-2111

MONTHLY MONITORING REPORT AUGUST 2016

DATE: September 29, 2016 (revised Jan 4, 2017 to correct groundwater gradient to southeasterly - see Section 2.0, 3rd line).

PREPARED FOR: Rose Marie Caraway, Remedial Project Manager/Environmental Scientist U.S. Environmental Protection Agency, Region 9 75 Hawthorne Street, SFD 7-2 San Francisco, California 94105

PREPARED BY: Max Ramos, E.I.T., Staff Environmental Engineer, OTIE Lindsey Larsen, Environmental Scientist, OTIE John Wingate, P.E., Project Manager, OTIE

RE: August 2016 Plant Influent and Effluent Sampling Results for the Pemaco Superfund Site Treatment Plant, Maywood, California

1.0 INTRODUCTION The United States Environmental Protection Agency (U.S. EPA) is currently implementing the Long-Term Response Action (LTRA) at the Pemaco Superfund Site in Maywood, California. Oneida Total Integrated Enterprises, LLC (OTIE) performs monthly monitoring work for the U.S. EPA under contract by the United States Army Corps of Engineers (USACE), Los Angeles District Contract Number W912PL 16-C-0016.

OTIE prepared this Report to summarize the results of monthly influent and effluent water and vapor sampling performed on August 12, 2016 at the Pemaco Superfund Site Treatment Plant (Plant).

The influent and effluent water samples (SP-201 and SP-209, respectively), and influent and effluent vapor samples (SP-104 and SP-106, respectively) were analyzed for volatile organic compounds (VOCs) and 1,4-dioxane. Samples were analyzed in accordance with the Final Sampling and Analysis Plan, (Field Sampling Plan and Quality Assurance Project Plan), Long-Term Response Action for the Pemaco Remedial Action (OTIE, 2015).

Monthly water and vapor sampling is performed to demonstrate compliance with Los Angeles County Sanitation District (LACSD) limits and South Coast Air Quality Management District (SCAQMD) guidance; confirm liquid phase granular activated carbon (LGAC) and vapor phase granular activated carbon (VGAC) effectiveness; and summarize data trends necessary for evaluation of remedial progress. The metric for “mass removal” is evaluated in the Quarterly Operations and Maintenance Report.

The groundwater treatment system (GTS) and vapor treatment system (VTS) achieved operational uptimes of approximately 99% and 37%, respectively, during August 2016. The VTS was not operated August 20 through August 31 in accordance with the “pulsed” operational schedule. Additional treatment system shutdowns occurred as follows:

SEMS-RM DOCID # 1163862

Monthly Monitoring Report August 2016 Plant Influent and Effluent Sampling Results

Pemaco Superfund Site, Maywood, California

Page 2 of 10 Oneida Total Integrated Enterprises

• The VTS was not operated from August 1 to August 4 while awaiting the arrival of a replacementcompressor oil pump for RC-201;

• The VTS experienced intermittent shutdowns from August 6 through August 11 due to a fault onthe liquid ring vacuum pump variable frequency drive (VFD);

• The VTS was not operated for a portion of August 19 for blower maintenance on B-101, B-102,and B-301; and

• The GTS was not operated for a portion of August 15 during filter bag change out.

Additional operational details are available in the most recent Operations Summary and the August weekly Quality Control Reports located on the Pemaco SharePoint website. Plant operational details will be summarized in the 2016 Third Quarter Operation and Maintenance Report.

2.0 ‘A’ ZONE GROUNDWATER LEVEL GAUGING Groundwater elevations and analytical data suggest an off-site contaminant source is located northwest of Maywood Riverfront Park, with significant trichloroethene (TCE) concentrations in the Exposition Aquifer ‘A’ Zone (OTIE, 2016a). Groundwater extraction from the ‘A’ Zone may promote a southeasterly migration of contaminants from northwest of the Park toward the former electrical resistive heating (ERH) area. In order to protect the ERH remedy area and discourage potential migration of the off-site source, the ‘A’ Zone wells were shut down on April 28, 2016 following stakeholder discussion and U.S. EPA approval. Groundwater levels in the ‘A’ Zone are gauged monthly to monitor gradient changes while the ‘A’ Zone extraction wells remain inactive.

The August 26, 2016 ‘A’ Zone groundwater gauging event was the fourth groundwater level monitoring task performed since shutdown of ‘A’ Zone extraction wells in April 2016. Groundwater elevation data for the August 2016 gauging event is provided in Attachment 1. August 2016 groundwater elevations are compared to groundwater elevation data from the December 2015 semiannual groundwater monitoring event. ‘A’ Zone groundwater elevation changes at individual well locations include both increases and decreases compared to December 2015 values. The ‘A’ Zone groundwater elevation changes over time are shown in the hydrograph presented in Figure 1 (after text). Groundwater elevations in many ‘A’ Zone wells decreased between the July 2016 gauging event and the August 2016 gauging event; however, evaluation of the long-term ‘A’ Zone groundwater elevation trends requires additional data from future monitoring events. Elevation trends will be included in future monthly monitoring reports following sufficient rounds of monthly gauging.

3.0 PLANT WATER SAMPLING RESULTS Influent and effluent water grab samples were collected on August 12, 2016 and the detected analytical results are summarized in Table 1. The laboratory analysis was performed by Eurofins CalScience, Inc. The laboratory reports containing the full list of analytical results for VOCs and 1,4-dioxane in samples SP-201 and SP-209 are provided in Attachment 2.

The August 2016 influent sample results represent a composite of flow from the following active wells screened in the Perched and Exposition Zones:

• Perched Zone (dual-phase extraction [DPE]): PB-01, PB-02, PB-03, PB-05, PC-06, PD-04, PD-05,PD-06, and PD-07; and

Monthly Monitoring Report August 2016 Plant Influent and Effluent Sampling Results Pemaco Superfund Site, Maywood, California


• Exposition Zones (groundwater only [GW]): DB-01, DB-03, DB-04, DB-05, DB-07, and DB-09.

Table 1 Monthly Summary of Detected VOCs in Influent / Effluent Water Samples

Analyte Method

Sample Locations Sample ID

Sample Date

SP-201 (Influent) SP-201-20160812

8/12/2016 Results

SP-209 (Effluent) SP-209-20160812

8/12/2016 Results SSRL Unit

1,1-Dichloroethane SW8260B 5 μg/L 0.36 J 1.1**

1,1-Dichloroethene SW8260B 6 μg/L 0.81 J <0.43

1,4-Dioxane (P-Dioxane) SW8260SIM 1* μg/L 4.4 J 5.3**

Chloroform SW8260B 80 μg/L <0.46 0.97 J**

cis-1,2-Dichloroethene SW8260B 6 μg/L 13 6.5

trans-1,2-Dichloroethene SW8260B 10 μg/L 0.55 J <0.37

Trichloroethene SW8260B 5 μg/L 180 0.52 J

Vinyl Chloride SW8260B 0.5 μg/L 0.49 J <0.30

Notes: 1. * - Indicates value is a "California Notification Level" which is less than the SSRL of 3.0, listed in the ROD (U.S. EPA, 2005); 2. ** - Indicates effluent sample concentration was higher than influent concentration as a result of preferential desorption; 3. Bold indicates a sample detection; 4. ID = identification; SSRL = site-specific remediation level; μg/L = micrograms per liter; < = indicates compound was not

detected above the method detection limit; and 5. Effluent water quality complied with the LACSD permit limit of 1,000 μg/L for total VOCs.

3.1 PROCESS WATER INFLUENT (SP-201) DISCUSSION The following VOCs are associated with groundwater plumes being monitored as part of the semiannual groundwater monitoring program. Analytical results for samples collected during the August 2016 event for these VOCs are summarized below:

• Cis-1,2-dichloroethene (cis-1,2-DCE) was detected at a concentration of 13 μg/L for the month of August (Figure 2). The cis-1,2-DCE concentration in process water influent shows some variation between monthly samples, although samples from the previous 24 months have not exceeded 17 μg/L. The overall cis-1,2-DCE concentration trend is slightly decreasing for the previous 24 months;

• TCE was detected at a concentration of 180 μg/L, higher than the previous process water influent sample (3 μg/L) and within the typical range for influent TCE concentrations (Figure 3). The TCE concentration in process water influent samples from the previous 24 months shows significant variation between monthly samples, with a slightly decreasing trend over time; and

• 1,4-Dioxane was detected at a concentration of 4.4 J µg/L for the month of August (Figure 4). The 1,4-dioxane concentration in process water influent from the previous 24 months shows some variation between monthly samples, with a slightly decreasing trend.




Figure 2 Historical Concentrations of cis-1,2-Dichloroethene in Influent Water

Figure 3 Historical Concentrations of Trichloroethene in Influent Water

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Figure 4 Historical Concentrations of 1,4-Dioxane in Influent Water

Notes for Figures 2, 3, and 4: 1. Data collected over a 24 month period beginning in September 2014. Concentration values reflected on the figure

represent samples collected during monthly monitoring events; 2. Values that were below the laboratory detection limit are expressed as concentrations of zero; 3. Plant influent water was not analyzed in November 2015; 4. The trend line represents a linear regression of 23 data points from samples collected during monthly monitoring events.

The trend line is a best-fit representation of the data and serves as a forecasting tool; it is not intended to represent the mean value of all samples collected; and

5. GTS = groundwater treatment system; μg/L = microgram per liter.

3.2 PROCESS WATER EFFLUENT (SP-209) DISCUSSION The water effluent quality satisfied the LACSD permit limit for total VOCs of 1,000 μg/L. VOC concentrations in plant effluent were below their respective site-specific remediation levels (SSRLs), with the exception of 1,4-dioxane (5.3 μg/L), which has a low LGAC adsorptive capacity.

The LGAC performance is satisfactory because the LACSD permit limits were satisfied and filter vessels continue to operate with acceptable head loss.

4.0 PLANT VAPOR SAMPLING RESULTS The influent and effluent vapor samples were collected in 1-liter SUMMA® canisters on August 12, 2016. The analytical results for this event are summarized in Table 2. The laboratory analysis was performed by ALS Environmental and the laboratory report is provided as Attachment 3. The August 2016 influent vapor sample represents a composite of concentrations from active DPE wells (PB-01, PB-02, PB-03, PB-05, PC-06, PD-04, PD-05, PD-06, and PD-07), all screened in the Perched Zone.

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Table 2 Summary of Detected VOCs in Influent and Effluent Vapor Samples

Analyte

Sample Location Sample ID

Sample Date

SP-104 (Influent) SP-104-20160812

8/12/2016 Result

SP-106 (Effluent) SP-106-20160812

8/12/2016 Result Method Unit

1,1,1-Trichloroethane TO15 μg/m3 10 <0.60

1,1-Dichloroethane TO15 μg/m3 4.6 J <0.57

1,1-Dichloroethene TO15 μg/m3 12 <0.60

1,2,4-Trimethylbenzene TO15 μg/m3 3.1 J <0.53

2-Butanone TO15 μg/m3 9.3 J 3.7 J

2-Propanol TO15 μg/m3 <7.4 3.9 J*

Acetone TO15 μg/m3 180 31

Benzene TO15 μg/m3 22 <0.57

Carbon disulfide TO15 μg/m3 <2.6 0.68 J*

Chloroform TO15 μg/m3 7.9 J <0.60

Chloromethane TO15 μg/m3 <2.6 0.88 J*

cis-1,2-Dichloroethene TO15 μg/m3 36 <0.57

Cyclohexane TO15 μg/m3 230 <1.0

Dichlorodifluoromethane TO15 μg/m3 <3.0 2.2*

Ethanol TO15 μg/m3 69 J 52

Ethyl Acetate TO15 μg/m3 9.9 J <1.2

Ethylbenzene TO15 μg/m3 3.1 J <0.57

Naphthalene TO15 μg/m3 7.3 J <0.64

N-Heptane TO15 μg/m3 88 <0.60

N-Hexane TO15 μg/m3 290 <0.53

N-Octane TO15 μg/m3 17 <0.64

Tetrachloroethene TO15 μg/m3 84 <0.50

Toluene TO15 μg/m3 <3.0 0.91 J*

Trichloroethene TO15 μg/m3 420 <0.50

Vinyl chloride TO15 μg/m3 <3.0 2.4*

Notes: 1. * - Indicates a compound detected in effluent sample and not in influent sample as a result of higher detection limits for

influent analysis; 2. Bold indicates sample detection; 3. ID = identification; J = estimated value; μg/m3 = micrograms per cubic meter; < = indicates compound was not detected

above the method detection limits; and 4. A complete listing of analytes is found in the laboratory report (Attachment 3).

4.1 PROCESS VAPOR INFLUENT (SP-204) DISCUSSION Influent vapor concentrations over the previous 24 months are presented in Figure 5. The sum of VOCs detected in plant vapor influent shows a decreasing trend. The trend is influenced by the high VOC concentrations detected during the months of January and February 2015. This concentration spike was



associated with prolonged shutdown of the VTS system from December 4, 2014 to January 16, 2015 to facilitate removal of the Flameless Thermal Oxidizer. Influent vapor VOC concentrations since the June 2015 sampling event have been consistent with influent vapor VOC concentrations prior to the VTS shutdown (Figure 5).

The COCs with highest concentrations in the vapor influent were: TCE (420 μg/m3), n-hexane (290 μg/m3), cyclohexane (230 μg/m3), and acetone (180 μg/m3).

Figure 5 Historical Influent VOC Concentrations in Vapor

Notes: 1. Monthly data collected over a 24 month period beginning in September 2014. Concentration values reflected on the figure

represent samples collected during monthly monitoring events; 2. Plant influent vapor was not analyzed in November 2015; 3. The trend line represents a linear regression of 23 data points from samples collected during monthly monitoring events.

The trend line is a best-fit representation of the data and serves as a forecasting tool; it is not intended to represent the mean value of all samples collected; and

4. VTS = vapor treatment system; μg/m3 = microgram per cubic meter.

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4.2 PROCESS VAPOR EFFLUENT (SP-208) DISCUSSION Plant air effluent is not formally permitted but does comply with SCAQMD permit guidance for human health risk assessment. Tier 2 Screening Risk Assessment for the Pemaco Site was conducted using risk assessment methods prescribed in the 2015 SCAQMD Risk Assessment Procedures1 (SCAQMD, 2015). A Tier 2 Screening Risk Assessment Report based on the 2015 SCAQMD procedures for August is included in Attachment 4 and demonstrates plant vapor emission compliance with the 2015 SCAQMD permit guidance. The Tier 2 Screening Risk Assessment Report was generated using the SCAQMD Risk Tool (V1.02) Microsoft excel spreadsheet distributed on the SCAQMD website (SCAQMD, 2016).

A summary of the results from the Tier 2 Air Screening Risk Assessment is presented in Table 3. The maximum incremental cancer risk (MICR) associated with potential exposure to toxic air contaminants (TACs) is roughly two orders of magnitude less than the U.S. EPA acceptable cancer risk of “one in a million” (1 x 10-6) for residential and worker receptors. Calculated non-cancer hazard indices (chronic hazard index [HIc], acute hazard index [HIa], and 8-hour chronic hazard index [HI8]) associated with potential exposure to TACs are less than the established limit of one.

Table 3 Summary of Tier 2 Screening Risk Assessment Health Risk Values

Maximum Individual Cancer Risk (MICR)

Chronic Hazard Index (HIc)

Acute Hazard Index (HIa)

8-Hour Chronic Hazard Index (HI8)

Receptor1 Resident Worker Resident Worker Resident Worker Resident Worker

Maximum Health Risk Value 7.68E-09 3.10E-09 5.31E-08 2.58E-07 2.08E-07 5.99E-07 0.00E-00 0.00E-00

Notes: 1Health risk values are calculated for residential receptors at a distance of 75 meters from the plant vapor effluent stack and for commercial (worker) receptors at a distance of 25 meters from the plant vapor effluent stack; and Health risk values were calculated with the SCAQMD Risk Tool (V1.02) (SCAQMD, 2016) using analytical data from the August 12, 2016 vapor effluent sample. The full Tier 2 Screening Risk Assessment Report is provided in Attachment 4.

Destruction removal efficiency (DRE) is typically calculated to evaluate the performance of the VGAC and the vapor conditioning package. The DRE equals the mass difference between the influent and effluent divided by the total mass in the influent. The sum of VOCs detected in the influent was 1503 μg/m3; the sum of VOCs detected in the effluent was 98 μg/m3. The resulting DRE of 93% for August 2016 is above average and consistent with the previous month (99%), representing a return to typical operational values following the May 10, 2016 VGAC changeout.

1 The Pemaco Final Remedial Design Report (TN&A, 2006) indicated that the VTS will meet the substantive requirements of the SCAQMD Risk Assessment Procedures for Rules 1401 and 212, Version 7.0 (SCAQMD, 2005). Monthly plant vapor effluent monitoring is evaluated according to the June 2015 updated SCAQMD Risk Assessment Procedures for Rules 1401, 1401.1 and 212, Version 8.0 (SCAQMD, 2015) in order to document that continued operation of the VTS is protective of human health.



5.0 CONCLUSIONS • During the month of August, the GTS achieved an uptime of 99% and the VTS achieved an

uptime of 37%. Extended shutdowns of the VFD were required for the repair of the chiller RC-201 and an electrical fault on the liquid ring vacuum pump VFD.

• August ‘A’ Zone groundwater elevation measurements were collected approximately four months following shutdown of the ‘A’ Zone groundwater extraction wells. Elevation trends will be evaluated following additional rounds of monthly gauging.

• Results of the August 2016 plant water and vapor sampling conducted on August 12, 2016 confirmed compliance with LACSD permit limits and 2015 SCAQMD permit guidance.

• The LGAC performance is satisfactory because the LACSD permit limits were achieved and filter vessels continue to operate with acceptable head loss.

• The VGAC performance is satisfactory based on SCAQMD permit guidance and DRE values.

6.0 REFERENCES Oneida Total Integrated Enterprises (OTIE). 2015. Final Sampling and Analysis Plan (Field Sampling Plan

and Quality Assurance Project Plan), Long-Term Response Action for the Pemaco Remedial Action. September.

_____. 2016a. Draft Semiannual Groundwater Monitoring Report, December 2015 Monitoring Event for the Pemaco Superfund Site Treatment Plant, Maywood, California. April.

South Coast Air Quality Management District (SCAQMD). 2005. Risk Assessment Procedures for Rules 1401 and 212 Version 7.0, Permit Application Package “L” Rules 1401 and 212 Version 7.0. July 1.

_____. 2015. Risk Assessment Procedures for Rules 1401, 1401.1 and 212. Version 8.0. June 5.

_____. 2016. Rule 1401 Risk Assessment Program, Risk Tool (V1.02), Version 8.0 & Attachment M, Revision March 2016. Available online at http://www.aqmd.gov/home/permits/risk-assessment. Accessed 4 April 2016.

TN & Associate (TN&A). 2006. Final Remedial Design Report, Pemaco Superfund Site, 5050 E. Slauson Avenue, Maywood, California. August.

United States Environmental Protection Agency (U.S. EPA). 2005. Record of Decision, Pemaco Maywood Superfund Site, Maywood, California. EPA ID: CAD980737092. January 13.

http://www.aqmd.gov/home/permits/risk-assessment




FIGURES (AFTER TEXT) Figure 1 Exposition ‘A’ Zone Hydrograph

ATTACHMENTS Attachment 1 August 2016 ‘A’ Zone Groundwater Gauging Results

Attachment 2 Lab Report from Eurofins CalScience, Inc.

Attachment 3 Lab Report from ALS Environmental

Attachment 4 Tier 2 Screening Risk Assessment Report (Version 8.0 & Attachment M, Revision March 2016) – Risk Tool (V1.02)

FIGURES

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FIGURE 1 Exposition 'A' Zone Hydrograph


DA-01DA-02DA-03DA-04DA-05DA-06DA-07DA-08DA-09DA-10DA-11DA-12MW-01-80MW-03-70MW-04-75MW-07-75MW-08-70MW-09-70MW-10-75MW-12-70MW-14-80MW-19-70MW-20-70MW-21-80MW-22-75MW-26-75MW-27-70MW-36-80MW-37-80MW-38-80RW-01-70Dry

'A' Zone extraction wells shut down (4/28/2016)


ATTACHMENT 1

August 2016 ‘A’ Zone Groundwater Gauging Results

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Attachment 1August 2016 'A' Zone Groundwater Gauging Results


OTIE Page 1 of 1

Depth to Water

(ft btoc)

Groundwater Elevation (ft amsl)

Depth to Water

(ft btoc)

Groundwater Elevation (ft amsl)

1 MW-01-80 Monitoring 59 - 79 75.48 73.08 75.6 72.96 -0.122 MW-03-70 Monitoring 60 - 70 Dry -- Dry -- --3 MW-04-75 Monitoring 65 - 75 70.75 75.32 70.79 75.28 -0.044 MW-07-75 Monitoring 65 - 75 64.11 75.21 63.31 76.01 0.85 MW-08-70 Monitoring 63 - 68 * -- 66.95 72.09 --6 MW-09-70 Monitoring 65 - 70 * -- * -- --7 MW-10-75 Monitoring 68 - 73 67.73 72.89 68.38 72.24 -0.658 MW-12-70 Monitoring 65 - 70 * -- * -- --9 MW-14-80 Monitoring 76 - 81 75.67 73.88 75.65 73.90 0.02

10 MW-19-70 Monitoring 62 - 67 Dry -- Dry -- --11 MW-20-70 Monitoring 63 - 68 Dry -- Dry -- --12 MW-21-80 Monitoring 68 - 78 74.16 74.23 74.07 74.32 0.0913 MW-22-75 Monitoring 69 - 74 Dry -- 75.04 -- --14 MW-26-75 Monitoring 65 - 75 * -- 74.05 72.05 --15 MW-27-70 Monitoring 60 - 70 Dry -- Dry -- --16 RW-01-70 Monitoring 55 - 70 Dry -- Dry -- --17 WW-MW-30A Monitoring 61 - 66 NM -- 65.73 75.11 --18 MW-36-80 Monitoring 67.5 - 77.5 69.15 74.83 69.33 74.65 -0.1819 MW-37-80 Monitoring 68 - 78 69.83 72.61 69.78 72.66 0.0520 MW-38-80 Monitoring 67.5 - 77.5 69.51 73.02 69.54 72.99 -0.0321 DA-01 Extraction 61 - 76 68.11 72.60 70.14 70.57 -2.0322 DA-02 Extraction 72 - 82 67.48 71.22 67.19 71.51 0.2923 DA-03 Extraction 74 - 84 67.85 71.07 67.43 71.49 0.4224 DA-04 Extraction 56 - 66 Dry -- Dry -- --25 DA-05 Extraction 68 - 78 * -- 69.64 71.67 --26 DA-06 Extraction 60 - 70 Dry -- Dry -- --27 DA-07 Extraction 61 - 71 Dry -- Dry -- --28 DA-08 Extraction 65 - 75 * -- 66.42 74.21 --29 DA-09 Extraction 66 - 76 Dry -- Dry -- --20 DA-10 Extraction 66 - 76 Dry -- Dry -- --21 DA-11 Extraction 64 - 74 NM -- Dry -- --32 DA-12 Extraction 66 - 76 65.58 78.04 68.45 75.17 -2.8733 MW-32A Monitoring 57-67 Dry -- 66.38 74.51 --34 MW-33A Monitoring 61-71 NM -- 68.69 72.61 --

Notes:1) Gauging data from the December 2015 semiannual groundwater monitoring event under dynamic (pumping) conditions.

3) "*" indicates the water level could not be determined due to the presence of an in-well pump.Acronyms: amsl = above mean sea level; btoc = below top of casing; ft = feet; NM = not measured; "--" = not available.

Change in GW Elevation

2) Gauging data from August 26, 2016 collected under static (non-pumping) conditions. 'A' Zone groundwater extraction wells were shut down on April 28,2016.

Well ID Well Type

December 4, 20151

Screen Interval (ft btoc)

August 26, 20162


ATTACHMENT 2

Lab Report from Eurofins CalScience, Inc.


WORK ORDER NUMBER: 16-08-0958

Analytical Report ForClient: OTIE

Client Project Name: Pemaco - MonthlyAttention: Orval Osborne

317 East Main StreetVentura, CA 93001-2624

Approved for release on by:Virendra PatelProject Manager

AIR SOIL WATER MARINE CHEMISTRY

Eurofins Calscience, Inc. (Calscience) certifies that the test results provided in this report meet all NELAC requirements for parameters for which accreditation isrequired or available. Any exceptions to NELAC requirements are noted in the case narrative. The original report of subcontracted analyses, if any, is attached tothis report. The results in this report are limited to the sample(s) tested and any reproduction thereof must be made in its entirety. The client or recipient of thisreport is specifically prohibited from making material changes to said report and, to the extent that such changes are made, Calscience is not responsible, legally orotherwise. The client or recipient agrees to indemnify Calscience for any defense to any litigation which may arise.

08/26/2016

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mailto:[email protected]

https://www.calscience.com/clientwebaccess/login.aspx

Contents

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Client Project Name: Pemaco - Monthly

Work Order Number: 16-08-0958

1 Work Order Narrative. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

2 Sample Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

3 Detections Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

4 Client Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64.1 EPA 8260 SIM 1,4-Dioxane (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64.2 EPA 8260B Volatile Organics (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

5 Quality Control Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155.1 MS/MSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155.2 LCS/LCSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

6 Sample Analysis Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

7 Glossary of Terms and Qualifiers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

8 Chain-of-Custody/Sample Receipt Form. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23

Page 2 of 24

Condition Upon Receipt: Samples were received under Chain-of-Custody (COC) on 08/12/16. They were assigned to Work Order 16-08-0958. Unless otherwise noted on the Sample Receiving forms all samples were received in good condition and within the

recommended EPA temperature criteria for the methods noted on the COC. The COC and Sample Receiving Documents are

integral elements of the analytical report and are presented at the back of the report. Holding Times: All samples were analyzed within prescribed holding times (HT) and/or in accordance with the Calscience Sample Acceptance

Policy unless otherwise noted in the analytical report and/or comprehensive case narrative, if required. Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15

minutes (40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being

received outside of the stated holding time unless received at the laboratory within 15 minutes of the collection time. Quality Control: All quality control parameters (QC) were within established control limits except where noted in the QC summary forms or

described further within this report. Subcontractor Information: Unless otherwise noted below (or on the subcontract form), no samples were subcontracted. Additional Comments: Air - Sorbent-extracted air methods (EPA TO-4A, EPA TO-10, EPA TO-13A, EPA TO-17): Analytical results are converted from

mass/sample basis to mass/volume basis using client-supplied air volumes. Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC

results are always reported on a wet weight basis.

Work Order Narrative


Work Order: 16-08-0958 Page 1 of 1

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Sample Identification Lab Number Collection Date and Time Number ofContainers

Matrix

SP-201-20160812 16-08-0958-1 08/12/16 10:30 10 Aqueous

SP-209-20160812 16-08-0958-2 08/12/16 11:30 10 Aqueous

Sample Summary


Client: OTIE

317 East Main Street

Ventura, CA 93001-2624

Work Order: 16-08-0958

Project Name: Pemaco - Monthly

PO Number: 2016160

Date/TimeReceived:

08/12/16 14:20

Number ofContainers:

20

Attn: Orval Osborne

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Subcontracted analyses, if any, are not included in this summary.

SP-201-20160812 (16-08-0958-1)

1,4-Dioxane 4.4 J 1.8* ug/L EPA 8260 SIM EPA 5030C

1,1-Dichloroethane 0.36 J 0.28* ug/L EPA 8260B EPA 5030C

1,1-Dichloroethene 0.81 J 0.43* ug/L EPA 8260B EPA 5030C

c-1,2-Dichloroethene 13 1.0 ug/L EPA 8260B EPA 5030C

t-1,2-Dichloroethene 0.55 J 0.37* ug/L EPA 8260B EPA 5030C

Trichloroethene 180 1.0 ug/L EPA 8260B EPA 5030C

Vinyl Chloride 0.49 J 0.30* ug/L EPA 8260B EPA 5030C

SP-209-20160812 (16-08-0958-2)

1,4-Dioxane 3.6 1.0 ug/L EPA 8260 SIM EPA 5030C

Chloroform 0.97 J 0.46* ug/L EPA 8260B EPA 5030C

1,1-Dichloroethane 1.1 1.0 ug/L EPA 8260B EPA 5030C

c-1,2-Dichloroethene 6.5 1.0 ug/L EPA 8260B EPA 5030C

Trichloroethene 0.52 J 0.37* ug/L EPA 8260B EPA 5030C

Detections Summary


Client: OTIE




Project Name: Pemaco - Monthly

Received: 08/12/16

Attn: Orval Osborne Page 1 of 1

Client SampleID

Analyte Result Qualifiers RL Units Method Extraction

* MDL is shown

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Client Sample Number Lab SampleNumber

Date/TimeCollected

Matrix Instrument DatePrepared

Date/TimeAnalyzed

QC Batch ID

SP-201-20160812 16-08-0958-1-F 08/12/1610:30

Aqueous GC/MS M 08/15/16 08/15/1617:11

160815L017

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

1,4-Dioxane 4.4 5.0 1.8 5.00 J

Surrogate Rec. (%) Control Limits Qualifiers

1,4-Dichlorobutane 88 80-120

SP-209-20160812 16-08-0958-2-F 08/12/1611:30

Aqueous GC/MS M 08/15/16 08/15/1613:45

160815L017



1,4-Dioxane 3.6 1.0 0.35 1.00



Method Blank 099-16-536-103 N/A Aqueous GC/MS M 08/15/16 08/15/1613:15

160815L017



1,4-Dioxane ND 1.0 0.35 1.00



Analytical Report


OTIE



Date Received: 08/12/16


Preparation: EPA 5030C

Method: EPA 8260 SIM

Units: ug/L

Project: Pemaco - Monthly Page 1 of 1

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-201-20160812 16-08-0958-1-A 08/12/1610:30

Aqueous GC/MS XX 08/13/16 08/13/1617:34

160813L002



Acetone ND 20 10 1.00

Benzene ND 0.50 0.14 1.00

Bromobenzene ND 1.0 0.30 1.00

Bromochloromethane ND 1.0 0.48 1.00

Bromodichloromethane ND 1.0 0.21 1.00

Bromoform ND 1.0 0.50 1.00

Bromomethane ND 10 3.9 1.00

2-Butanone ND 10 4.4 1.00

n-Butylbenzene ND 1.0 0.23 1.00

sec-Butylbenzene ND 1.0 0.25 1.00

tert-Butylbenzene ND 1.0 0.28 1.00

Carbon Disulfide ND 10 4.1 1.00

Carbon Tetrachloride ND 0.50 0.23 1.00

Chlorobenzene ND 1.0 0.17 1.00

Chloroethane ND 5.0 2.3 1.00

Chloroform ND 1.0 0.46 1.00

Chloromethane ND 10 3.5 1.00

2-Chlorotoluene ND 1.0 0.24 1.00


Dibromochloromethane ND 1.0 0.25 1.00

1,2-Dibromo-3-Chloropropane ND 5.0 1.2 1.00

1,2-Dibromoethane ND 1.0 0.36 1.00

Dibromomethane ND 1.0 0.46 1.00

1,2-Dichlorobenzene ND 1.0 0.46 1.00



Dichlorodifluoromethane ND 1.0 0.46 1.00

1,1-Dichloroethane 0.36 1.0 0.28 1.00 J

1,2-Dichloroethane ND 0.50 0.24 1.00

1,1-Dichloroethene 0.81 1.0 0.43 1.00 J

c-1,2-Dichloroethene 13 1.0 0.48 1.00

t-1,2-Dichloroethene 0.55 1.0 0.37 1.00 J

1,2-Dichloropropane ND 1.0 0.42 1.00


Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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1,1-Dichloropropene ND 1.0 0.46 1.00

c-1,3-Dichloropropene ND 0.50 0.25 1.00

t-1,3-Dichloropropene ND 0.50 0.25 1.00

Ethylbenzene ND 1.0 0.14 1.00

2-Hexanone ND 10 4.2 1.00

Isopropylbenzene ND 1.0 0.58 1.00

p-Isopropyltoluene ND 1.0 0.16 1.00

Methylene Chloride ND 10 3.8 1.00

4-Methyl-2-Pentanone ND 10 4.4 1.00

Naphthalene ND 10 5.0 1.00

n-Propylbenzene ND 1.0 0.17 1.00

Styrene ND 1.0 0.17 1.00

1,1,1,2-Tetrachloroethane ND 1.0 0.40 1.00


Tetrachloroethene ND 1.0 0.39 1.00

Toluene ND 1.0 0.24 1.00

1,2,3-Trichlorobenzene ND 1.0 0.51 1.00


1,1,1-Trichloroethane ND 1.0 0.30 1.00

1,1,2-Trichloro-1,2,2-Trifluoroethane ND 10 3.9 1.00


Trichloroethene 180 1.0 0.37 1.00

Trichlorofluoromethane ND 10 3.3 1.00

1,2,3-Trichloropropane ND 5.0 0.64 1.00

1,2,4-Trimethylbenzene ND 1.0 0.36 1.00


Vinyl Acetate ND 10 5.6 1.00

Vinyl Chloride 0.49 0.50 0.30 1.00 J

p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00

Methyl-t-Butyl Ether (MTBE) ND 1.0 0.31 1.00


1,4-Bromofluorobenzene 94 80-120

Dibromofluoromethane 108 78-126

1,2-Dichloroethane-d4 121 75-135

Toluene-d8 104 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-209-20160812 16-08-0958-2-C 08/12/1611:30

Aqueous GC/MS CC 08/16/16 08/16/1617:33

160816L017




Benzene ND 0.50 0.14 1.00














Chloroform 0.97 1.0 0.46 1.00 J












1,1-Dichloroethane 1.1 1.0 0.28 1.00


1,1-Dichloroethene ND 1.0 0.43 1.00

c-1,2-Dichloroethene 6.5 1.0 0.48 1.00

t-1,2-Dichloroethene ND 1.0 0.37 1.00



Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Styrene ND 1.0 0.17 1.00




Toluene ND 1.0 0.24 1.00






Trichloroethene 0.52 1.0 0.37 1.00 J






Vinyl Chloride ND 0.50 0.30 1.00

p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00






Toluene-d8 97 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

Method Blank 099-14-001-21081 N/A Aqueous GC/MS XX 08/13/16 08/13/1612:26

160813L002




Benzene ND 0.50 0.14 1.00





























c-1,2-Dichloroethene ND 1.0 0.48 1.00




Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Styrene ND 1.0 0.17 1.00




Toluene ND 1.0 0.24 1.00






Trichloroethene ND 1.0 0.37 1.00







p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00






Toluene-d8 102 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

Method Blank 099-14-001-21093 N/A Aqueous GC/MS CC 08/16/16 08/16/1613:11

160816L017




Benzene ND 0.50 0.14 1.00





























c-1,2-Dichloroethene ND 1.0 0.48 1.00




Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Styrene ND 1.0 0.17 1.00




Toluene ND 1.0 0.24 1.00






Trichloroethene ND 1.0 0.37 1.00







p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00






Toluene-d8 96 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed MS/MSD Batch Number

SP-209-20160812 Sample Aqueous GC/MS M 08/15/16 08/15/16 13:45 160815S006

SP-209-20160812 Matrix Spike Aqueous GC/MS M 08/15/16 08/15/16 15:43 160815S006

SP-209-20160812 Matrix Spike Duplicate Aqueous GC/MS M 08/15/16 08/15/16 16:12 160815S006

Parameter SampleConc.

SpikeAdded

MSConc.

MS%Rec.

MSDConc.

MSD%Rec.

%Rec. CL RPD RPD CL Qualifiers

1,4-Dioxane 3.624 20.00 22.47 94 24.30 103 70-130 8 0-20

Quality Control - Spike/Spike Duplicate


OTIE








RPD: Relative Percent Difference. CL: Control Limits

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16-08-0997-5 Sample Aqueous GC/MS CC 08/16/16 08/16/16 13:44 160816S003

16-08-0997-5 Matrix Spike Aqueous GC/MS CC 08/16/16 08/16/16 14:17 160816S003

16-08-0997-5 Matrix Spike Duplicate Aqueous GC/MS CC 08/16/16 08/16/16 14:49 160816S003


SpikeAdded

MSConc.

MS%Rec.

MSDConc.

MSD%Rec.


Benzene 0.5508 50.00 54.34 108 53.18 105 74-122 2 0-21

Carbon Tetrachloride ND 50.00 48.78 98 48.91 98 60-144 0 0-21

Chlorobenzene ND 50.00 54.10 108 52.97 106 73-120 2 0-22

1,2-Dibromoethane ND 50.00 55.18 110 55.14 110 80-122 0 0-20

1,2-Dichlorobenzene ND 50.00 52.48 105 53.21 106 70-120 1 0-26

1,2-Dichloroethane ND 50.00 43.65 87 42.66 85 64-142 2 0-20

1,1-Dichloroethene ND 50.00 43.42 87 44.22 88 52-136 2 0-21

Ethylbenzene 169.3 50.00 223.3 108 222.8 107 77-125 0 0-24

Toluene ND 50.00 55.49 111 54.42 109 72-126 2 0-23

Trichloroethene 8.621 50.00 62.03 107 60.98 105 74-128 2 0-22

Vinyl Chloride ND 50.00 38.89 78 39.50 79 67-133 2 0-20

p/m-Xylene ND 100.0 118.5 119 116.1 116 63-129 2 0-25

o-Xylene ND 50.00 58.78 118 57.49 115 62-128 2 0-24

Methyl-t-Butyl Ether (MTBE) ND 50.00 53.09 106 54.23 108 68-134 2 0-21



OTIE






Method: EPA 8260B



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16-08-0896-11 Sample Aqueous GC/MS XX 08/13/16 08/13/16 13:22 160813S001

16-08-0896-11 Matrix Spike Aqueous GC/MS XX 08/13/16 08/13/16 13:50 160813S001

16-08-0896-11 Matrix Spike Duplicate Aqueous GC/MS XX 08/13/16 08/13/16 14:18 160813S001


SpikeAdded

MSConc.

MS%Rec.

MSDConc.

MSD%Rec.


Benzene ND 50.00 54.84 110 54.51 109 74-122 1 0-21

Carbon Tetrachloride ND 50.00 60.04 120 59.14 118 60-144 2 0-21

Chlorobenzene ND 50.00 52.58 105 52.07 104 73-120 1 0-22

1,2-Dibromoethane ND 50.00 52.70 105 52.46 105 80-122 0 0-20

1,2-Dichlorobenzene ND 50.00 51.62 103 51.52 103 70-120 0 0-26

1,2-Dichloroethane ND 50.00 52.68 105 50.09 100 64-142 5 0-20

1,1-Dichloroethene ND 50.00 57.03 114 57.18 114 52-136 0 0-21

Ethylbenzene ND 50.00 55.55 111 54.60 109 77-125 2 0-24

Toluene ND 50.00 56.15 112 55.63 111 72-126 1 0-23

Trichloroethene 6.129 50.00 60.98 110 60.53 109 74-128 1 0-22

Vinyl Chloride 2.034 50.00 58.46 113 60.66 117 67-133 4 0-20

p/m-Xylene ND 100.0 115.2 115 113.7 114 63-129 1 0-25

o-Xylene ND 50.00 58.31 117 57.11 114 62-128 2 0-24

Methyl-t-Butyl Ether (MTBE) ND 50.00 53.92 108 52.23 104 68-134 3 0-21



OTIE






Method: EPA 8260B



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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed LCS/LCSD Batch Number

099-16-536-103 LCS Aqueous GC/MS M 08/15/16 08/15/16 11:47 160815L017

099-16-536-103 LCSD Aqueous GC/MS M 08/15/16 08/15/16 12:16 160815L017

Parameter Spike Added LCS Conc. LCS%Rec.

LCSD Conc. LCSD%Rec.


1,4-Dioxane 20.00 18.96 95 19.67 98 80-120 4 0-20

Quality Control - LCS/LCSD


OTIE









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Total number of LCS compounds: 14

Total number of ME compounds: 1

Total number of ME compounds allowed: 1

LCS ME CL validation result: Pass

Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed LCS Batch Number

099-14-001-21093 LCS Aqueous GC/MS CC 08/16/16 08/16/16 11:33 160816L017

Parameter Spike Added Conc. Recovered LCS %Rec. %Rec. CL ME CL Qualifiers

Benzene 50.00 47.56 95 80-120 73-127

Carbon Tetrachloride 50.00 41.97 84 67-139 55-151

Chlorobenzene 50.00 49.01 98 78-120 71-127

1,2-Dibromoethane 50.00 51.65 103 80-120 73-127

1,2-Dichlorobenzene 50.00 50.20 100 63-129 52-140

1,2-Dichloroethane 50.00 39.86 80 70-130 60-140

1,1-Dichloroethene 50.00 38.89 78 66-126 56-136

Ethylbenzene 50.00 50.96 102 80-123 73-130

Toluene 50.00 48.82 98 80-120 73-127

Trichloroethene 50.00 47.71 95 80-122 73-129

Vinyl Chloride 50.00 33.43 67 70-130 60-140 ME

p/m-Xylene 100.0 104.7 105 75-123 67-131

o-Xylene 50.00 52.52 105 74-122 66-130

Methyl-t-Butyl Ether (MTBE) 50.00 52.73 105 69-129 59-139

Quality Control - LCS


OTIE






Method: EPA 8260B



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Total number of LCS compounds: 14

Total number of ME compounds: 0

Total number of ME compounds allowed: 1

LCS ME CL validation result: Pass

Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed LCS Batch Number

099-14-001-21081 LCS Aqueous GC/MS XX 08/13/16 08/13/16 11:02 160813L002

Parameter Spike Added Conc. Recovered LCS %Rec. %Rec. CL ME CL Qualifiers

Benzene 50.00 53.24 106 80-120 73-127

Carbon Tetrachloride 50.00 57.06 114 67-139 55-151

Chlorobenzene 50.00 51.12 102 78-120 71-127

1,2-Dibromoethane 50.00 53.37 107 80-120 73-127

1,2-Dichlorobenzene 50.00 50.68 101 63-129 52-140

1,2-Dichloroethane 50.00 50.22 100 70-130 60-140

1,1-Dichloroethene 50.00 55.68 111 66-126 56-136

Ethylbenzene 50.00 52.98 106 80-123 73-130

Toluene 50.00 54.07 108 80-120 73-127

Trichloroethene 50.00 55.07 110 80-122 73-129

Vinyl Chloride 50.00 53.12 106 70-130 60-140

p/m-Xylene 100.0 110.2 110 75-123 67-131

o-Xylene 50.00 55.57 111 74-122 66-130

Methyl-t-Butyl Ether (MTBE) 50.00 53.94 108 69-129 59-139

Quality Control - LCS


OTIE






Method: EPA 8260B



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Method Extraction Chemist ID Instrument Analytical Location

EPA 8260 SIM EPA 5030C 486 GC/MS M 2

EPA 8260B EPA 5030C 1042 GC/MS CC 2

EPA 8260B EPA 5030C 1042 GC/MS XX 2

Sample Analysis Summary Report



Location 2: 7445 Lampson Avenue, Garden Grove, CA 92841

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Qualifiers Definition

* See applicable analysis comment.

< Less than the indicated value.

> Greater than the indicated value.

1 Surrogate compound recovery was out of control due to a required sample dilution. Therefore, the sample data was reported without furtherclarification.

2 Surrogate compound recovery was out of control due to matrix interference. The associated method blank surrogate spike compound wasin control and, therefore, the sample data was reported without further clarification.

3 Recovery of the Matrix Spike (MS) or Matrix Spike Duplicate (MSD) compound was out of control due to suspected matrix interference. Theassociated LCS recovery was in control.

4 The MS/MSD RPD was out of control due to suspected matrix interference.

5 The PDS/PDSD or PES/PESD associated with this batch of samples was out of control due to suspected matrix interference.

6 Surrogate recovery below the acceptance limit.

7 Surrogate recovery above the acceptance limit.

B Analyte was present in the associated method blank.

BU Sample analyzed after holding time expired.

BV Sample received after holding time expired.

CI See case narrative.

E Concentration exceeds the calibration range.

ET Sample was extracted past end of recommended max. holding time.

HD The chromatographic pattern was inconsistent with the profile of the reference fuel standard.

HDH The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but heavier hydrocarbonswere also present (or detected).

HDL The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but lighter hydrocarbons werealso present (or detected).

J Analyte was detected at a concentration below the reporting limit and above the laboratory method detection limit. Reported value isestimated.

JA Analyte positively identified but quantitation is an estimate.

ME LCS Recovery Percentage is within Marginal Exceedance (ME) Control Limit range (+/- 4 SD from the mean).

ND Parameter not detected at the indicated reporting limit.

Q Spike recovery and RPD control limits do not apply resulting from the parameter concentration in the sample exceeding the spikeconcentration by a factor of four or greater.

SG The sample extract was subjected to Silica Gel treatment prior to analysis.

X % Recovery and/or RPD out-of-range.

Z Analyte presence was not confirmed by second column or GC/MS analysis.

Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC results arereported on a wet weight basis.

Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15 minutes(40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being received outside of thestated holding time unless received at the laboratory within 15 minutes of the collection time.

A calculated total result (Example: Total Pesticides) is the summation of each component concentration and/or, if "J" flags are reported,estimated concentration. Component concentrations showing not detected (ND) are summed into the calculated total result as zeroconcentrations.

Glossary of Terms and Qualifiers



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Return to Contents

Page 23 of 24

Chain of Custody Report To: Bill To: Shaded Areas For Internal Use Only 1_ of 1

Contact: Orval Osborne Contact: -------------- Lab Lot# ~ · OTIE Company: OTIE

· · Address: 317 East Main Street . OrteidaTotallnlegraledEnterpri>;es Ventura, CA 93001

Company: -------------

Address:-------------

4~ Phone: (805) 585-4313 OTIE Fax: (805) 585-2111 Phone:--------------

317 East Main Street E-Mail: [email protected] Fax:--------------

Ventura, CA 93001 ' II Phone: (805) 585-2110 16 08 095· PO#: ______ Quote: -----Fax: (805) 585-2111 J ·. • · .. • · · · ·.. /".· . > ·.·... .·. .··.,···• ... , .. ·· ..... ·. .· .. ·.

Project location: 5973 S. District Date Requested +-=B~lv""'d~M""avw""'""'o""o='-d=CA'-'-"9=10=27,..,'0,.._ ___ 1 Standard TAT

Lab PM: Virendra Patel, Ca1Science 714-895-5494

·. l_abo@e>ry MS

._ .. ··_ID . . · MSD ,'

· ... ·. ··I .. ··-. ._ ... ··· ,;L_

,. .... .., "

'.· ',

.

I

Client Sample 10

SP-201-20160812

SP-209-20160812

'

Sampling Date Time

8/12/16 10:30

8/12/16 11 :30

M G t r g X a ~

b

~

w X X

w X X

X

X

RELINQUISHED Bt'1 U-,.. fA COMPANY DATE R J 2-../ 10 TIME

RELINQUISHED BY

WW E wastewater w =Water S = Soil SL = Sludge MS = Miscellaneous OL = Oil

A =Air

Matrix Key SE = Sediment SO= Solid

COMPANY

DS = Drum Solid DL = Drum Liquid L = Leachate WI =Wipe O= ____ _

DATE TIME

Container Key Preservative Key 1. Plastic 1. HCI, Coolto4° 2 . VOAVial 2. H2S04, Cool to 4° 3. Sterile Plastic 3. HN03, Cool to 4° 4. Amber Glass 4. NaOH, Cool to 4° 5. Widemouth Glass 5. NaOH/Zn Acetate, Cool to 4• 6. Other 6. Cool to4'

7. None

I

RECEIVED BY ('j JrMu k_J; / d'Jh Cc:11:y RECEIVED BY COMPANY

COMMENTS: OTIE-specific EDDs needed 1.4-Dioxane: 1 uQ/L RL

..

Yes No ,' •.· c6c not pr~~e.nt.

. .

Additional Analyses I Remarks

Field grab pH reading at 1130 = 7.31

VTS system is on

( D)\TE

Date Received

Courier:

Bill of Lading:

,/!"IME f y-:z_o TIME

I I

Hand DelivereO

Ret

urn

to C

onte

nts

Page 24 of 24.;:: eurofins WORK ORDER NUMBER: 16-08- 0 ~_g

SAMPLE REdEIPT CHECKLIST COOLER_\_ OF

CLIENT· OTT-6 DATE· 08 / I). / 2016

TEMPERATURE: (Criteria: O.OdP- 6.0°C, not frozen exce~t sediment/tissue)

Thermometer ID: SC2A (CF: o.i°C); Temperature (w/o CF}: -g_.3 °C (w/ CF): '2-3 °C; D Blank /sample

D Sample(s) outside tempertture criteria (PM/APM conitacted by: )

D Sample(s) outside tempe1 ture criteria but received dn ice/chjlled on same day of sampling

D Sample(s) received at ambieQt temperature; placed on ice for transport by courier t . .

Ambient Temperature: D Air g Filter . '. Checked by: l O 11

CUSTODY SEAL: 1 ~

Cooler D Present and Intact

Sample(s) D Present and lntct . ,l

D Present but Not ~ntact .,;:;tl\lot Present

D Present but Not :intact 0"'Not Present

D N/A

D N/A

Checked by: l O f1 Checked by: \ 0 l]

SAMPLE CONDITION: [I -,~ :-; "

Yes ;ii

Chain-of-Custody (COC) docurment(s) received with samples ....... :....... ... ... ... ...... ... ... ......... .... .. zf . ~ :

COC document(s) received co1plete ................ ..... .... ....... ..... , ..... .. ....... ....... ......... . .... ........ D .l ~ .

D Sampling date D Sampl~ng time D Matrix fl Number of containers

D No analysis requested ql Not relinquished D No relinquisHed date D No relinquished time 1

Sampler's name indicated on ere .......... ....... ....... .. ....... ... .... .. .. · .. · · · ·. · · · .. .. · · .. .. · .... · · · · · · · · · .. · · · JA" Sample container label(s) consr~tent with COC ... ... .. . ... .. . .. . ... ... .... ... ... ... ... .. . ... ... ... ... ... ... ... ... ... ~

Sample container(s) intact and ~ good condition .. . ...... ...... ... .... :.. .. . . .. . . . . .. .. . .. . .. . ... . . . .. . . .. . . . . .. . .. 121' Proper containers for analyses i!equested ..... .... ... ......... .... ... ... •.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . c;v

li • Sufficient volume/mass for analr ses requested . .. ... .. . ... .... ... ... ... ... ... ... .. . ... .. . ... .. . ... ... ... .. . ... ... ... ~

Samples received within holding time ..... .. ........ ... ...... .... .. ... .... •.. .......... .. .. .... . ..... ...... ...... ... ... 9"" Aqueous sam~les for ce~aii anal~ses receive~ within .1~-minut~ holding time

D pH D Residual Chlonne;i D Dissolved Sulfide D Dissolved Oxygen . . . .. . .. . . . . .. . . . .. . . . .. . . .. . . D

Proper preservation chemical(si noted on COC and/or sample container ... .. . .... ....... .. ........ .. .... ... j21' Unpreserved aqueous samp~e(s) received for certain analyses

Co~ta~:;(1;; f~r~:=~ a~a::'.f 1::1:; he~d~:::ved ~·t .. .. ·.. ............. .... ........ ... .. . . . . . . . . . . . . z' i:ivolatile Organics D Disi lved Gases (RSK-175) p Dissolved Oxygen (SM 4500)

' . j D Carbon Dioxide (SM 4509) D Ferrous Iron (SM 3500) D Hydrogen Sulfide (Hach)

Tedlar™ bag(s) free of condenf ation .. ... ..... ... ... ......... .i... ..... .. ........... ...... .......... ...... ... . . . . .. ... D

No

D

D

0

D

D

D

D

D

D

D

NIA

D

D

D

0

D

D

D

0

0

0

ll : CONTAINER TYPE: _ (i;i \i • (Trip Blank Lot Number: _ ____ __ )

Aqueous: D VOA l7~h 9lVOAna2 0 100PJ D 10~PJna2 D 125AGB D 125AGBh .0 125AGBp D 125PB

D 125PBznna O 250AGB D t SOCGB D 250CGBs D ~60PB O 250PBn D 500AGB D 500AGJ D 500AGJs

D 500PB O 1AGB D 1AGBn~,2 D 1AGBs O 1 PB D 11fBna D D D D __ _

Solid: D 4ozCGJ D 8ozCGJ r 16ozCGJ D Sleeve~ D ~nCores® L__J D TerraCores® (__J D ---

Air: D Tedlarn.. D Canister O:!Sorbent Tube D PUF D ' .· Other Matrix l ): D D __ _ :, .· ..

Container: A= Amber. B = Bottle, ~ = Clear, E = Envelope, G 7/Gtass, J := Jar, P = Plastic, and Z = Ziploc/Resealable Bag

Preservative: b = buffered, f = filte~ed, h = HCI, n = HNO:,, na = NaOH, na2 = Na2S203, p = H3PQ4, Labeled/Ch~cked by: ~ s = H2S04, u = ultra~f ure, znna = Zn (CH3C02)2 : !NaOH Reviewed by: ~

2015-04-10 Revision

t

ATTACHMENT 3

Lab Report from ALS Environmental


2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com

R I G H T S O L U T I O N S | R I G H T P A R T N E R

LABORATORY REPORT September 1, 2016 Orval Osborne Oneida Total Integrated Enterprises (OTIE) 317 E. Main St. Ventura, CA 93001 RE: Pemaco Plant Vapor Monitoring Dear Orval: Enclosed are the results of the samples submitted to our laboratory on August 12, 2016. For your reference, these analyses have been assigned our service request number P1603977. All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein. If you have any questions, please call me at (805) 526-7161. Respectfully submitted, ALS | Environmental Kelly Horiuchi Laboratory Director

1 of 105

http://www.alsglobal.com/


kelly.horiuchi

Kelly



Client: Oneida Total Integrated Enterprises (OTIE) Service Request No: P1603977 Project: Pemaco Plant Vapor Monitoring _______________________________________________________________________________

CASE NARRATIVE

The samples were received intact under chain of custody on August 12, 2016 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the samples at the time of sample receipt. Volatile Organic Compound Analysis The samples were analyzed for volatile organic compounds in accordance with EPA Method TO-15 from the Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA/625/R-96/010b), January, 1999. This procedure is described in laboratory SOP VOA-TO15. The analytical system was comprised of a gas chromatograph / mass spectrometer (GC/MS) interfaced to a whole-air preconcentrator. This method is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP, LLC accreditation. Any analytes flagged with an X are not included on the NELAP or DoD-ELAP accreditation. The containers were cleaned, prior to sampling, down to the method reporting limit (MRL) reported for this project. Please note, projects which require reporting below the MRL could have results between the MRL and method detection limit (MDL) that are biased high. ______________________________________________________________________________________ The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report. Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory.

2 of 105




ALS Environmental – Simi Valley

CERTIFICATIONS, ACCREDITATIONS, AND REGISTRATIONS

Agency Web Site Number

AIHA-LAP, LLC http://www.aihaaccreditedlabs.org 101661

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0694

PJLA (DoD ELAP)

http://www.pjlabs.com/search-accredited-labs 65818

(Testing) Florida DOH (NELAP)

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E871020

Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

2014025

Minnesota DOH (NELAP)

http://www.health.state.mn.us/accreditation 977273

New Jersey DEP (NELAP)

http://www.nj.gov/dep/oqa/ CA009

New York DOH (NELAP)

http://www.wadsworth.org/labcert/elap/elap.html 11221

Oregon PHD (NELAP)

http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx

4068-003

Pennsylvania DEP http://www.depweb.state.pa.us/labs 68-03307

(Registration) Texas CEQ (NELAP)

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704413-

16-7 Utah DOH (NELAP)

http://www.health.utah.gov/lab/labimp/certification/index.html CA01627201

6-6

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C946

Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website. Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification.

3 of 105


http://www.aihaaccreditedlabs.org/

http://www.azdhs.gov/lab/license/env.htm

http://www.pjlabs.com/search-accredited-labs

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.health.state.mn.us/accreditation

http://www.nj.gov/dep/oqa/

http://www.wadsworth.org/labcert/elap/elap.html



http://www.depweb.state.pa.us/labs

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html

http://www.health.utah.gov/lab/labimp/certification/index.html

http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html


P1603977_Detail Summary_1608261331_RG.xls - DETAIL SUMMARY

Client: Oneida Total Integrated Enterprises (OTIE) Service Request: P1603977Project ID: Pemaco Plant Vapor Monitoring

Date Received: 8/12/2016Time Received: 11:50

Client Sample ID Lab Code MatrixDate

CollectedTime

CollectedContainer

IDPi1

(psig)Pf1

(psig)

SP-106-20160812 P1603977-001 Air 8/12/2016 08:00 1BV06795 -0.07 6.03 XSP-104-20160812 P1603977-002 Air 8/12/2016 09:00 1BV06800 0.07 6.18 X

ALS ENVIRONMENTAL

DETAIL SUMMARY REPORT

TO-1

5 - V

OC

Can

s

4 of 105

5 o

f 10

5

ALS Environmental

286S P•tlt C..nterOrtvo, Sults>A

Simi v,uey, CA 93065

TEL: (SOS) S~·T161 . FAX:(~) $26-7220

CHAIN OF CUSTODY RECORD DATE: 8/12/2016

PAGE:. ____ ..:1'--__ 0F ___ .;.1 __ _

~E ' -~~ 1-,-,000=,~ .. ~------------=-=------------11'p':e::im:i:i:iia;;;c;;;;o:;;·::;P:,,l:.:a:.:.n:.:t..:V:.:a="":.:r..:M=o:.:.n:.:.it:.:o:.:.r:.:.in:,1a._ ____ _,_ __ b==""2"'0"'1""6"'1"'60===d

317 E. Main Street PRO,ECr COlfACT: ' 'o·'""": r··r,1~0V,,::;:;:;D;;:;';!T""'1p' Ventura CA 93001 . Orval Osborne _ _: _ % II_

!-,,~------------------'""'"----------' ~,lMFIL,ER(j:;):(S(:.MJ..1URE) s~.sn Hendton TEl: F"AX: &.r,:.r..il

COELT LOG CODE l;l@~i~~i%!tn' , ... > DD DD •••m~w,., ,,,,,,,,,,,,,,,,,n,:nn:rr~t SOS.585.4313 806.fi8S.2111 i-.cnm

,,..n,,..,. .. OU!IOTME"

OsAME DAY n 2A HR n 4SHR O 12 HR D 5 DAYS (i}:10 DAYS SPFCt.O.l ReQu•REIJcl'tf$ (t.OOlllO!~AL COSTS w.v /\PPl Y}

D 0 D srECl0.l lNSTRV:::TK.m6

Please repor1 EDD$ in both ppmv and mg/m3 SP-108 started at -20.52

SP-104 started at -21.29

SAMPLE 10

: ·,/':·:: SP-106-20160812

~SP-10.t-20160812

• 10.0.0.1 ;'

•..

I

FM!d Point Name

V•por SP-106

V•por SP•Hl4

t

Relinql.l\8hsd tr,: (SigMrutt) ., ,J,.. ::;:-:-__ :- •

RelinquiUled b>j: (Si9Mtute-)

.- 'f!.

~ . rm[vi:

.li' MAlfl:1 .. ~om. 0

SAMPUNG

DATE ll~E X 0 >

08/12/16 8:00 air 1 X

08/12/16 9:00 air 1 X

.,

Recet.1ea cy: cs1gnS11JreJ 11

\ •

/2 YJ ' , .J -: _

Re(;ltt\lea ~; cS1gnAJre)

REQUESTED ANALYSIS

"·

(/) _ ( s

·" ; . ·<

.. CONTAINER TYPE

Bottle 1 BV06796

Botti& 1 BV06800

Time:

Dste:

9/1/16 2:59 PMP1603977_Oneida Total Integrated Enterprises (OTIE)_Pemaco Plant Vapor Monitoring.xls - Page 1 of 1

ALS EnvironmentalSample Acceptance Check Form

Client: Oneida Total Integrated Enterprises (OTIE) Work order: P1603977Project: Pemaco Plant Vapor MonitoringSample(s) received on: 8/12/16 Date opened: 8/12/16 by: KKELPE

Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of

compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP.Yes No N/A

1 Were sample containers properly marked with client sample ID? 2 Did sample containers arrive in good condition? 3 Were chain-of-custody papers used and filled out? 4 Did sample container labels and/or tags agree with custody papers? 5 Was sample volume received adequate for analysis? 6 Are samples within specified holding times? 7 Was proper temperature (thermal preservation) of cooler at receipt adhered to?

8 Were custody seals on outside of cooler/Box/Container? Location of seal(s)? Sealing Lid?

Were signature and date included? Were seals intact?

9 Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?

10 Tubes: Are the tubes capped and intact? 11 Badges: Are the badges properly capped and intact?

Are dual bed badges separated and individually capped and intact?

Lab Sample ID Container Required Received Adjusted VOA HeadspaceDescription pH * pH pH (Presence/Absence) Comments

1.0 L Bottle-Vac™1.0 L Bottle-Vac™

RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4)

Explain any discrepancies: (include lab sample ID numbers):

Do containers have appropriate preservation, according to method/SOP or Client specified information?

Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it?

Receipt / Preservation

P1603977-001.01P1603977-002.01

6 of 105

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603977_TO15_1608231218_SC.xls - Sample

ALS ENVIRONMENTAL

RESULTS OF ANALYSISPage 1 of 3

Client: Oneida Total Integrated Enterprises (OTIE)SP-106-20160812 ALS Project ID: P1603977

ALS Sample ID: P1603977-001

Test Code: EPA TO-15 Date Collected: 8/12/16Instrument ID: Tekmar AUTOCAN/Agilent 5975Cinert/6890N/MS16 Date Received: 8/12/16Analyst: Lusine Hakobyan Date Analyzed: 8/19/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.40 Liter(s)Test Notes: Container ID: 1BV06795

Initial Pressure (psig): -0.07 Final Pressure (psig): 6.03

Canister Dilution Factor: 1.42

CAS # Compound MRL MDL MRL MDL Dataµg/m³ µg/m³ ppbV ppbV Qualifier

115-07-1 Propene ND 1.8 0.50 ND 1.0 0.2975-71-8 Dichlorodifluoromethane (CFC 12) 2.2 1.8 0.60 0.45 0.36 0.1274-87-3 Chloromethane 0.88 1.8 0.53 0.43 0.86 0.26 J

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 1.8 0.67 ND 0.25 0.097

75-01-4 Vinyl Chloride 2.4 1.8 0.60 0.96 0.69 0.24106-99-0 1,3-Butadiene ND 1.8 0.78 ND 0.80 0.3574-83-9 Bromomethane ND 1.8 0.67 ND 0.46 0.1775-00-3 Chloroethane ND 1.8 0.60 ND 0.67 0.2364-17-5 Ethanol 52 18 2.8 27 9.4 1.575-05-8 Acetonitrile ND 1.8 0.64 ND 1.1 0.38107-02-8 Acrolein ND 7.1 0.60 ND 3.1 0.2667-64-1 Acetone 31 18 2.7 13 7.5 1.275-69-4 Trichlorofluoromethane ND 1.8 0.60 ND 0.32 0.1167-63-0 2-Propanol (Isopropyl Alcohol) 3.9 18 1.5 1.6 7.2 0.61 J107-13-1 Acrylonitrile ND 1.8 0.60 ND 0.82 0.2875-35-4 1,1-Dichloroethene ND 1.8 0.60 ND 0.45 0.1575-09-2 Methylene Chloride ND 1.8 0.60 ND 0.51 0.17107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 1.8 0.57 ND 0.57 0.1876-13-1 Trichlorotrifluoroethane ND 1.8 0.60 ND 0.23 0.07975-15-0 Carbon Disulfide 0.68 18 0.53 0.22 5.7 0.17 J156-60-5 trans-1,2-Dichloroethene ND 1.8 0.67 ND 0.45 0.1775-34-3 1,1-Dichloroethane ND 1.8 0.57 ND 0.44 0.141634-04-4 Methyl tert-Butyl Ether ND 1.8 0.60 ND 0.49 0.17108-05-4 Vinyl Acetate ND 18 2.3 ND 5.0 0.6678-93-3 2-Butanone (MEK) 3.7 18 0.75 1.2 6.0 0.25 J

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.J = The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL.

ResultppbV

Resultµg/m³

Client Sample ID:Client Project ID: Pemaco Plant Vapor Monitoring

7 of 105


ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene ND 1.8 0.57 ND 0.45 0.14141-78-6 Ethyl Acetate ND 3.6 1.2 ND 0.99 0.34110-54-3 n-Hexane ND 1.8 0.53 ND 0.50 0.1567-66-3 Chloroform ND 1.8 0.60 ND 0.36 0.12109-99-9 Tetrahydrofuran (THF) ND 1.8 0.71 ND 0.60 0.24107-06-2 1,2-Dichloroethane ND 1.8 0.57 ND 0.44 0.1471-55-6 1,1,1-Trichloroethane ND 1.8 0.60 ND 0.33 0.1171-43-2 Benzene ND 1.8 0.57 ND 0.56 0.1856-23-5 Carbon Tetrachloride ND 1.8 0.53 ND 0.28 0.085110-82-7 Cyclohexane ND 3.6 1.0 ND 1.0 0.3078-87-5 1,2-Dichloropropane ND 1.8 0.57 ND 0.38 0.1275-27-4 Bromodichloromethane ND 1.8 0.53 ND 0.27 0.08079-01-6 Trichloroethene ND 1.8 0.50 ND 0.33 0.093123-91-1 1,4-Dioxane ND 1.8 0.57 ND 0.49 0.1680-62-6 Methyl Methacrylate ND 3.6 1.1 ND 0.87 0.27142-82-5 n-Heptane ND 1.8 0.60 ND 0.43 0.1510061-01-5 cis-1,3-Dichloropropene ND 1.8 0.50 ND 0.39 0.11108-10-1 4-Methyl-2-pentanone ND 1.8 0.57 ND 0.43 0.1410061-02-6 trans-1,3-Dichloropropene ND 1.8 0.57 ND 0.39 0.1379-00-5 1,1,2-Trichloroethane ND 1.8 0.57 ND 0.33 0.10108-88-3 Toluene 0.91 1.8 0.60 0.24 0.47 0.16 J591-78-6 2-Hexanone ND 1.8 0.57 ND 0.43 0.14124-48-1 Dibromochloromethane ND 1.8 0.57 ND 0.21 0.067106-93-4 1,2-Dibromoethane ND 1.8 0.57 ND 0.23 0.074123-86-4 n-Butyl Acetate ND 1.8 0.57 ND 0.37 0.12


ppbV

Pemaco Plant Vapor Monitoring

Resultµg/m³

Result

Client Sample ID:Client Project ID:

8 of 105


ALS ENVIRONMENTAL







MRL MDL MRL MDL Data CAS # Compound µg/m³ µg/m³ ppbV ppbV Qualifier

111-65-9 n-Octane ND 1.8 0.64 ND 0.38 0.14127-18-4 Tetrachloroethene ND 1.8 0.50 ND 0.26 0.073108-90-7 Chlorobenzene ND 1.8 0.57 ND 0.39 0.12100-41-4 Ethylbenzene ND 1.8 0.57 ND 0.41 0.13179601-23-1 m,p-Xylenes ND 3.6 1.1 ND 0.82 0.2575-25-2 Bromoform ND 1.8 0.53 ND 0.17 0.052100-42-5 Styrene ND 1.8 0.53 ND 0.42 0.1395-47-6 o-Xylene ND 1.8 0.53 ND 0.41 0.12111-84-2 n-Nonane ND 1.8 0.53 ND 0.34 0.1079-34-5 1,1,2,2-Tetrachloroethane ND 1.8 0.53 ND 0.26 0.07898-82-8 Cumene ND 1.8 0.53 ND 0.36 0.1180-56-8 alpha-Pinene ND 1.8 0.50 ND 0.32 0.089103-65-1 n-Propylbenzene ND 1.8 0.57 ND 0.36 0.12622-96-8 4-Ethyltoluene ND 1.8 0.57 ND 0.36 0.12108-67-8 1,3,5-Trimethylbenzene ND 1.8 0.57 ND 0.36 0.1295-63-6 1,2,4-Trimethylbenzene ND 1.8 0.53 ND 0.36 0.11100-44-7 Benzyl Chloride ND 1.8 0.39 ND 0.34 0.075541-73-1 1,3-Dichlorobenzene ND 1.8 0.53 ND 0.30 0.089106-46-7 1,4-Dichlorobenzene ND 1.8 0.50 ND 0.30 0.08395-50-1 1,2-Dichlorobenzene ND 1.8 0.53 ND 0.30 0.0895989-27-5 d-Limonene ND 1.8 0.50 ND 0.32 0.08996-12-8 1,2-Dibromo-3-chloropropane ND 1.8 0.35 ND 0.18 0.036120-82-1 1,2,4-Trichlorobenzene ND 1.8 0.57 ND 0.24 0.07791-20-3 Naphthalene ND 1.8 0.64 ND 0.34 0.1287-68-3 Hexachlorobutadiene ND 1.8 0.50 ND 0.17 0.047

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.

µg/m³

Client Project ID:

ppbV

Client Sample ID:

ResultResult


9 of 105

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603977_TO15_1608231218_SC.xls - Sample (2)

ALS ENVIRONMENTAL





Initial Pressure (psig): 0.07 Final Pressure (psig): 6.18



115-07-1 Propene ND 8.8 2.5 ND 5.1 1.475-71-8 Dichlorodifluoromethane (CFC 12) ND 8.8 3.0 ND 1.8 0.6174-87-3 Chloromethane ND 8.8 2.6 ND 4.3 1.3


75-01-4 Vinyl Chloride ND 8.8 3.0 ND 3.4 1.2106-99-0 1,3-Butadiene ND 8.8 3.9 ND 4.0 1.874-83-9 Bromomethane ND 8.8 3.3 ND 2.3 0.8675-00-3 Chloroethane ND 8.8 3.0 ND 3.3 1.164-17-5 Ethanol 69 88 14 37 47 7.5 J75-05-8 Acetonitrile ND 8.8 3.2 ND 5.3 1.9107-02-8 Acrolein ND 35 3.0 ND 15 1.367-64-1 Acetone 180 88 14 75 37 5.775-69-4 Trichlorofluoromethane ND 8.8 3.0 ND 1.6 0.5367-63-0 2-Propanol (Isopropyl Alcohol) ND 88 7.4 ND 36 3.0107-13-1 Acrylonitrile ND 8.8 3.0 ND 4.1 1.475-35-4 1,1-Dichloroethene 12 8.8 3.0 2.9 2.2 0.7675-09-2 Methylene Chloride ND 8.8 3.0 ND 2.5 0.86107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 8.8 2.8 ND 2.8 0.9076-13-1 Trichlorotrifluoroethane ND 8.8 3.0 ND 1.2 0.3975-15-0 Carbon Disulfide ND 88 2.6 ND 28 0.85156-60-5 trans-1,2-Dichloroethene ND 8.8 3.3 ND 2.2 0.8475-34-3 1,1-Dichloroethane 4.6 8.8 2.8 1.1 2.2 0.70 J1634-04-4 Methyl tert-Butyl Ether ND 8.8 3.0 ND 2.4 0.83108-05-4 Vinyl Acetate ND 88 11 ND 25 3.378-93-3 2-Butanone (MEK) 9.3 88 3.7 3.2 30 1.3 J



ResultppbV

Resultµg/m³


10 of 105


ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene 36 8.8 2.8 9.2 2.2 0.71141-78-6 Ethyl Acetate 9.9 18 6.2 2.7 4.9 1.7 J110-54-3 n-Hexane 290 8.8 2.6 83 2.5 0.7567-66-3 Chloroform 7.9 8.8 3.0 1.6 1.8 0.61 J109-99-9 Tetrahydrofuran (THF) ND 8.8 3.5 ND 3.0 1.2107-06-2 1,2-Dichloroethane ND 8.8 2.8 ND 2.2 0.7071-55-6 1,1,1-Trichloroethane 10 8.8 3.0 1.9 1.6 0.5571-43-2 Benzene 22 8.8 2.8 6.8 2.8 0.8856-23-5 Carbon Tetrachloride ND 8.8 2.6 ND 1.4 0.42110-82-7 Cyclohexane 230 18 5.1 66 5.1 1.578-87-5 1,2-Dichloropropane ND 8.8 2.8 ND 1.9 0.6175-27-4 Bromodichloromethane ND 8.8 2.6 ND 1.3 0.3979-01-6 Trichloroethene 420 8.8 2.5 78 1.6 0.46123-91-1 1,4-Dioxane ND 8.8 2.8 ND 2.4 0.7880-62-6 Methyl Methacrylate ND 18 5.5 ND 4.3 1.3142-82-5 n-Heptane 88 8.8 3.0 22 2.2 0.7310061-01-5 cis-1,3-Dichloropropene ND 8.8 2.5 ND 1.9 0.54108-10-1 4-Methyl-2-pentanone ND 8.8 2.8 ND 2.2 0.6910061-02-6 trans-1,3-Dichloropropene ND 8.8 2.8 ND 1.9 0.6279-00-5 1,1,2-Trichloroethane ND 8.8 2.8 ND 1.6 0.52108-88-3 Toluene ND 8.8 3.0 ND 2.3 0.80591-78-6 2-Hexanone ND 8.8 2.8 ND 2.2 0.69124-48-1 Dibromochloromethane ND 8.8 2.8 ND 1.0 0.33106-93-4 1,2-Dibromoethane ND 8.8 2.8 ND 1.1 0.37123-86-4 n-Butyl Acetate ND 8.8 2.8 ND 1.9 0.59



Resultµg/m³

Result


ppbV

11 of 105


ALS ENVIRONMENTAL








111-65-9 n-Octane 17 8.8 3.2 3.7 1.9 0.68127-18-4 Tetrachloroethene 84 8.8 2.5 12 1.3 0.36108-90-7 Chlorobenzene ND 8.8 2.8 ND 1.9 0.61100-41-4 Ethylbenzene 3.1 8.8 2.8 0.71 2.0 0.65 J179601-23-1 m,p-Xylenes ND 18 5.3 ND 4.1 1.275-25-2 Bromoform ND 8.8 2.6 ND 0.85 0.26100-42-5 Styrene ND 8.8 2.6 ND 2.1 0.6295-47-6 o-Xylene ND 8.8 2.6 ND 2.0 0.61111-84-2 n-Nonane ND 8.8 2.6 ND 1.7 0.5079-34-5 1,1,2,2-Tetrachloroethane ND 8.8 2.6 ND 1.3 0.3998-82-8 Cumene ND 8.8 2.6 ND 1.8 0.5480-56-8 alpha-Pinene ND 8.8 2.5 ND 1.6 0.44103-65-1 n-Propylbenzene ND 8.8 2.8 ND 1.8 0.57622-96-8 4-Ethyltoluene ND 8.8 2.8 ND 1.8 0.57108-67-8 1,3,5-Trimethylbenzene ND 8.8 2.8 ND 1.8 0.5795-63-6 1,2,4-Trimethylbenzene 3.1 8.8 2.6 0.63 1.8 0.54 J100-44-7 Benzyl Chloride ND 8.8 1.9 ND 1.7 0.37541-73-1 1,3-Dichlorobenzene ND 8.8 2.6 ND 1.5 0.44106-46-7 1,4-Dichlorobenzene ND 8.8 2.5 ND 1.5 0.4195-50-1 1,2-Dichlorobenzene ND 8.8 2.6 ND 1.5 0.445989-27-5 d-Limonene ND 8.8 2.5 ND 1.6 0.4496-12-8 1,2-Dibromo-3-chloropropane ND 8.8 1.7 ND 0.91 0.18120-82-1 1,2,4-Trichlorobenzene ND 8.8 2.8 ND 1.2 0.3891-20-3 Naphthalene 7.3 8.8 3.2 1.4 1.7 0.61 J87-68-3 Hexachlorobutadiene ND 8.8 2.5 ND 0.83 0.23


ResultResultµg/m³

Client Project ID:

ppbV

Client Sample ID:Pemaco Plant Vapor Monitoring

12 of 105

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603977_TO15_1608231218_SC.xls - MBlank

ALS ENVIRONMENTAL


Client: Oneida Total Integrated Enterprises (OTIE)Method Blank ALS Project ID: P1603977

ALS Sample ID: P160818-MB Test Code: EPA TO-15 Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5975Cinert/6890N/MS16 Date Received: NAAnalyst: Lusine Hakobyan Date Analyzed: 8/18/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



115-07-1 Propene ND 0.50 0.14 ND 0.29 0.08175-71-8 Dichlorodifluoromethane (CFC 12) ND 0.50 0.17 ND 0.10 0.03474-87-3 Chloromethane ND 0.50 0.15 ND 0.24 0.073


75-01-4 Vinyl Chloride ND 0.50 0.17 ND 0.20 0.067106-99-0 1,3-Butadiene ND 0.50 0.22 ND 0.23 0.09974-83-9 Bromomethane ND 0.50 0.19 ND 0.13 0.04975-00-3 Chloroethane ND 0.50 0.17 ND 0.19 0.06464-17-5 Ethanol ND 5.0 0.80 ND 2.7 0.4275-05-8 Acetonitrile ND 0.50 0.18 ND 0.30 0.11107-02-8 Acrolein ND 2.0 0.17 ND 0.87 0.07467-64-1 Acetone ND 5.0 0.77 ND 2.1 0.3275-69-4 Trichlorofluoromethane ND 0.50 0.17 ND 0.089 0.03067-63-0 2-Propanol (Isopropyl Alcohol) ND 5.0 0.42 ND 2.0 0.17107-13-1 Acrylonitrile ND 0.50 0.17 ND 0.23 0.07875-35-4 1,1-Dichloroethene ND 0.50 0.17 ND 0.13 0.04375-09-2 Methylene Chloride ND 0.50 0.17 ND 0.14 0.049107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 0.50 0.16 ND 0.16 0.05176-13-1 Trichlorotrifluoroethane ND 0.50 0.17 ND 0.065 0.02275-15-0 Carbon Disulfide ND 5.0 0.15 ND 1.6 0.048156-60-5 trans-1,2-Dichloroethene ND 0.50 0.19 ND 0.13 0.04875-34-3 1,1-Dichloroethane ND 0.50 0.16 ND 0.12 0.0401634-04-4 Methyl tert-Butyl Ether ND 0.50 0.17 ND 0.14 0.047108-05-4 Vinyl Acetate ND 5.0 0.65 ND 1.4 0.1878-93-3 2-Butanone (MEK) ND 5.0 0.21 ND 1.7 0.071


Client Sample ID:Client Project ID: Pemaco Plant Vapor Monitoring

ResultppbV

Resultµg/m³

13 of 105


ALS ENVIRONMENTAL



ALS Sample ID: P160818-MB

Test Code: EPA TO-15 Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5975Cinert/6890N/MS16 Date Received: NAAnalyst: Lusine Hakobyan Date Analyzed: 8/18/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



156-59-2 cis-1,2-Dichloroethene ND 0.50 0.16 ND 0.13 0.040141-78-6 Ethyl Acetate ND 1.0 0.35 ND 0.28 0.097110-54-3 n-Hexane ND 0.50 0.15 ND 0.14 0.04367-66-3 Chloroform ND 0.50 0.17 ND 0.10 0.035109-99-9 Tetrahydrofuran (THF) ND 0.50 0.20 ND 0.17 0.068107-06-2 1,2-Dichloroethane ND 0.50 0.16 ND 0.12 0.04071-55-6 1,1,1-Trichloroethane ND 0.50 0.17 ND 0.092 0.03171-43-2 Benzene ND 0.50 0.16 ND 0.16 0.05056-23-5 Carbon Tetrachloride ND 0.50 0.15 ND 0.080 0.024110-82-7 Cyclohexane ND 1.0 0.29 ND 0.29 0.08478-87-5 1,2-Dichloropropane ND 0.50 0.16 ND 0.11 0.03575-27-4 Bromodichloromethane ND 0.50 0.15 ND 0.075 0.02279-01-6 Trichloroethene ND 0.50 0.14 ND 0.093 0.026123-91-1 1,4-Dioxane ND 0.50 0.16 ND 0.14 0.04480-62-6 Methyl Methacrylate ND 1.0 0.31 ND 0.24 0.076142-82-5 n-Heptane ND 0.50 0.17 ND 0.12 0.04110061-01-5 cis-1,3-Dichloropropene ND 0.50 0.14 ND 0.11 0.031108-10-1 4-Methyl-2-pentanone ND 0.50 0.16 ND 0.12 0.03910061-02-6 trans-1,3-Dichloropropene ND 0.50 0.16 ND 0.11 0.03579-00-5 1,1,2-Trichloroethane ND 0.50 0.16 ND 0.092 0.029108-88-3 Toluene ND 0.50 0.17 ND 0.13 0.045591-78-6 2-Hexanone ND 0.50 0.16 ND 0.12 0.039124-48-1 Dibromochloromethane ND 0.50 0.16 ND 0.059 0.019106-93-4 1,2-Dibromoethane ND 0.50 0.16 ND 0.065 0.021123-86-4 n-Butyl Acetate ND 0.50 0.16 ND 0.11 0.034


ppbV


Resultµg/m³


Result

14 of 105


ALS ENVIRONMENTAL



ALS Sample ID: P160818-MB




111-65-9 n-Octane ND 0.50 0.18 ND 0.11 0.039127-18-4 Tetrachloroethene ND 0.50 0.14 ND 0.074 0.021108-90-7 Chlorobenzene ND 0.50 0.16 ND 0.11 0.035100-41-4 Ethylbenzene ND 0.50 0.16 ND 0.12 0.037179601-23-1 m,p-Xylenes ND 1.0 0.30 ND 0.23 0.06975-25-2 Bromoform ND 0.50 0.15 ND 0.048 0.015100-42-5 Styrene ND 0.50 0.15 ND 0.12 0.03595-47-6 o-Xylene ND 0.50 0.15 ND 0.12 0.035111-84-2 n-Nonane ND 0.50 0.15 ND 0.095 0.02979-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.15 ND 0.073 0.02298-82-8 Cumene ND 0.50 0.15 ND 0.10 0.03180-56-8 alpha-Pinene ND 0.50 0.14 ND 0.090 0.025103-65-1 n-Propylbenzene ND 0.50 0.16 ND 0.10 0.033622-96-8 4-Ethyltoluene ND 0.50 0.16 ND 0.10 0.033108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.16 ND 0.10 0.03395-63-6 1,2,4-Trimethylbenzene ND 0.50 0.15 ND 0.10 0.031100-44-7 Benzyl Chloride ND 0.50 0.11 ND 0.097 0.021541-73-1 1,3-Dichlorobenzene ND 0.50 0.15 ND 0.083 0.025106-46-7 1,4-Dichlorobenzene ND 0.50 0.14 ND 0.083 0.02395-50-1 1,2-Dichlorobenzene ND 0.50 0.15 ND 0.083 0.0255989-27-5 d-Limonene ND 0.50 0.14 ND 0.090 0.02596-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.099 ND 0.052 0.010120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.16 ND 0.067 0.02291-20-3 Naphthalene ND 0.50 0.18 ND 0.095 0.03487-68-3 Hexachlorobutadiene ND 0.50 0.14 ND 0.047 0.013


ResultppbV


Resultµg/m³


15 of 105

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603977_TO15_1608231218_SC.xls - Surrogates

ALS ENVIRONMENTAL

SURROGATE SPIKE RECOVERY RESULTSPage 1 of 1

Client: Oneida Total Integrated Enterprises (OTIE)ALS Project ID: P1603977

Test Code: EPA TO-15Instrument ID: Tekmar AUTOCAN/Agilent 5975Cinert/6890N/MS16 Date(s) Collected: 8/12/16Analyst: Lusine Hakobyan Date(s) Received: 8/12/16Sample Type: 1.0 L Bottle-Vac™(s) Date(s) Analyzed: 8/18 - 8/19/16Test Notes:

Client Sample ID ALS Sample ID Acceptance DataLimits Qualifier

P160818-MB 70-130 P160818-LCS 70-130 P1603977-001 70-130 P1603977-002 70-130

Surrogate percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly from the on-column percent recovery.

96959796

RecoveredPercent

99

SP-104-20160812

RecoveredRecoveredPercent

Method Blank100

Percent

106

105104

95Lab Control Sample9598

Client Project ID:

SP-106-20160812

1,2-Dichloroethane-d4 BromofluorobenzeneToluene-d8


16 of 105

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603977_TO15_1608231218_SC.xls - LCS

ALS ENVIRONMENTAL

LABORATORY CONTROL SAMPLE SUMMARYPage 1 of 3

Client: Oneida Total Integrated Enterprises (OTIE)Lab Control Sample ALS Project ID: P1603977

ALS Sample ID: P160818-LCS


CAS # Compound Data Qualifier

115-07-1 Propene 95 49-13175-71-8 Dichlorodifluoromethane (CFC 12) 90 65-11774-87-3 Chloromethane 92 48-132

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) 84 65-122

75-01-4 Vinyl Chloride 95 65-128106-99-0 1,3-Butadiene 101 62-14374-83-9 Bromomethane 86 65-13075-00-3 Chloroethane 98 69-12664-17-5 Ethanol 96 57-12675-05-8 Acetonitrile 88 51-134107-02-8 Acrolein 89 55-14667-64-1 Acetone 98 57-12075-69-4 Trichlorofluoromethane 81 59-13967-63-0 2-Propanol (Isopropyl Alcohol) 96 59-129107-13-1 Acrylonitrile 98 64-13675-35-4 1,1-Dichloroethene 96 72-12375-09-2 Methylene Chloride 94 63-117107-05-1 3-Chloro-1-propene (Allyl Chloride) 99 50-14176-13-1 Trichlorotrifluoroethane 89 68-11875-15-0 Carbon Disulfide 82 55-143156-60-5 trans-1,2-Dichloroethene 98 69-12975-34-3 1,1-Dichloroethane 96 66-1221634-04-4 Methyl tert-Butyl Ether 83 55-128108-05-4 Vinyl Acetate 113 66-14078-93-3 2-Butanone (MEK) 97 62-127

Laboratory Control Sample percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly.

212216

203180

11701,040214220

214 1911,080216

1060

172

186

175

µg/m³

190208

403

ALSAcceptance

170

% RecoverySpike AmountLimits

212

173200998

195957

206

187µg/m³

183


200

202

204200

196188


Result

215208

218

210

222

207

196

212216 207

172220

210 206

418

17 of 105


ALS ENVIRONMENTAL





CAS # Compound Data Qualifier

156-59-2 cis-1,2-Dichloroethene 98 65-125141-78-6 Ethyl Acetate 106 64-132110-54-3 n-Hexane 100 58-12667-66-3 Chloroform 92 68-117109-99-9 Tetrahydrofuran (THF) 93 64-123107-06-2 1,2-Dichloroethane 91 63-12471-55-6 1,1,1-Trichloroethane 92 68-12071-43-2 Benzene 92 61-11056-23-5 Carbon Tetrachloride 88 65-137110-82-7 Cyclohexane 97 68-12278-87-5 1,2-Dichloropropane 99 67-12275-27-4 Bromodichloromethane 95 71-12479-01-6 Trichloroethene 88 71-121123-91-1 1,4-Dioxane 103 67-12280-62-6 Methyl Methacrylate 98 76-130142-82-5 n-Heptane 99 67-12510061-01-5 cis-1,3-Dichloropropene 100 73-131108-10-1 4-Methyl-2-pentanone 102 66-13210061-02-6 trans-1,3-Dichloropropene 101 76-13579-00-5 1,1,2-Trichloroethane 95 73-121108-88-3 Toluene 86 67-117591-78-6 2-Hexanone 93 59-128124-48-1 Dibromochloromethane 90 73-132106-93-4 1,2-Dibromoethane 89 73-128123-86-4 n-Butyl Acetate 93 61-136


211

195

211

212

218

216210

190

Client Sample ID:

218

Client Project ID:

µg/m³Spike Amount


428 452

µg/m³213

206

ALS

205205

AcceptanceLimits

% RecoveryResult

225220

210

220197

213

220

226

188205

218

216 214207208

218

230

208

224

213

209

424216

411

210 193

220195214

226

422 415

216217

202

18 of 105


ALS ENVIRONMENTAL





CAS # Compound DataQualifier

111-65-9 n-Octane 93 67-124127-18-4 Tetrachloroethene 86 65-126108-90-7 Chlorobenzene 87 68-120100-41-4 Ethylbenzene 90 69-123179601-23-1 m,p-Xylenes 89 67-12575-25-2 Bromoform 83 68-153100-42-5 Styrene 91 68-13295-47-6 o-Xylene 90 67-124111-84-2 n-Nonane 95 60-13079-34-5 1,1,2,2-Tetrachloroethane 94 72-12898-82-8 Cumene 89 67-12480-56-8 alpha-Pinene 91 67-129103-65-1 n-Propylbenzene 91 67-125622-96-8 4-Ethyltoluene 89 66-128108-67-8 1,3,5-Trimethylbenzene 90 65-12595-63-6 1,2,4-Trimethylbenzene 91 62-134100-44-7 Benzyl Chloride 102 74-145541-73-1 1,3-Dichlorobenzene 90 63-133106-46-7 1,4-Dichlorobenzene 92 62-12995-50-1 1,2-Dichlorobenzene 91 62-1345989-27-5 d-Limonene 96 66-13796-12-8 1,2-Dibromo-3-chloropropane 95 71-147120-82-1 1,2,4-Trichlorobenzene 87 60-14591-20-3 Naphthalene 90 56-15887-68-3 Hexachlorobutadiene 79 56-139


198

190

208


428

193

208

228222

224

201

201

182196

206192

201210218230

230218

210204

228220218

218

210

198185

220

214

197

186

208

202

212 193

210

204

190381

173202220

214

ALSAcceptance

Limits% Recovery

190194

Spike Amount

196

192

Client Project ID:Client Sample ID:

Resultµg/m³µg/m³

19 of 105

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603977_TO15_1608231218_SC.xls - ISS

ALS ENVIRONMENTAL


Client: Oneida Total Integrated Enterprises (OTIE) ALS Project ID: P1603977Pemaco Plant Vapor Monitoring

Internal Standard Area and RT Summary

Test Code: EPA TO-15Instrument ID: Tekmar AUTOCAN/Agilent 5975Cinert/6890N/MS16 Lab File ID: 08181624.DAnalyst: Lusine Hakobyan Date Analyzed: 8/18/16Sample Type: 1.0 L Bottle-Vac™(s) Time Analyzed: 18:18

Test Notes:

IS1 (BCM) IS2 (DFB) IS3 (CBZ)AREA # RT # AREA # RT # AREA # RT #

24 Hour Standard 301827 11.30 1440683 13.42 624172 17.72 Upper Limit 422558 11.63 2016956 13.75 873841 18.05 Lower Limit 181096 10.97 864410 13.09 374503 17.39

Client Sample ID01 Method Blank 261371 11.29 1298046 13.41 546654 17.7202 Lab Control Sample 295388 11.29 1393932 13.42 608165 17.7203 SP-106-20160812 267043 11.28 1299853 13.41 561366 17.7204 SP-104-20160812 282691 11.28 1336270 13.41 576385 17.7205060708091011121314151617181920

IS1 (BCM) = BromochloromethaneIS2 (DFB) = 1,4-DifluorobenzeneIS3 (CBZ) = Chlorobenzene-d5

AREA UPPER LIMIT = 140% of internal standard areaAREA LOWER LIMIT = 60% of internal standard areaRT UPPER LIMIT = 0.33 minutes of internal standard RTRT LOWER LIMIT = 0.33 minutes of internal standard RT

# Column used to flag values outside QC limits with an I.I = Internal standard not within the specified limits.

Client Project ID:

20 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181636.D Acq On : 19 Aug 2016 1:01 Operator: LH Sample : P1603977-001 (400mL) Misc : S29-07291601 ALS Vial : 15 Sample Multiplier: 1 Quant Time: Aug 22 12:54:11 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 267043 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.41 114 1299853 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 561366 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.13 65 415020 13.175 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 105.36% 57) Toluene-d8 (SS2) 15.87 98 1348794 12.074 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.56% 73) Bromofluorobenzene (SS3) 19.11 174 474428 11.897 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.20% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. d 3) Dichlorodifluoromethan... 4.37 85 39376 0.633 ng 98 4) Chloromethane 4.64 50 9987 0.249 ng 93 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 5.07 62 31459 0.688 ng 99 7) 1,3-Butadiene 5.34 54 582 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.41 45 277872 14.527 ng 100 11) Acetonitrile 6.78 41 5909 0.122 ng # 43 12) Acrolein 6.93 56 1583 0.100 ng 100 13) Acetone 7.10 58 166235 8.620 ng 88 14) Trichlorofluoromethane 7.37 101 2425 N.D. 15) 2-Propanol (Isopropanol) 7.59 45 71553 1.088 ng 88 16) Acrylonitrile 8.12 53 701 N.D. 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 0.00 59 0 N.D. d 19) Methylene Chloride 8.55 84 2125 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 0.00 151 0 N.D. 22) Carbon Disulfide 8.84 76 21135 0.191 ng 96 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. 24) 1,1-Dichloroethane 0.00 63 0 N.D. 25) Methyl tert-Butyl Ether 10.21 73 2670 N.D. 26) Vinyl Acetate 10.31 86 1772 0.299 ng # 89 27) 2-Butanone (MEK) 10.59 72 18963 1.030 ng # 89 28) cis-1,2-Dichloroethene 0.00 61 0 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 11.41 61 3130 0.320 ng 94 31) n-Hexane 11.39 57 2770 N.D. 32) Chloroform 11.44 83 2862 N.D. 34) Tetrahydrofuran (THF) 11.88 72 1556 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 13.02 78 16102 0.145 ng 99 42) Carbon Tetrachloride 13.18 117 673 N.D. 43) Cyclohexane 13.31 84 834 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 0.00 63 0 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. 47) Trichloroethene 14.11 130 2509 N.D. 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 14.18 57 3635 N.D.

R16081016.M Mon Aug 22 13:55:22 2016 Page: 1

21 of 105

lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181636.D Acq On : 19 Aug 2016 1:01 Operator: LH Sample : P1603977-001 (400mL) Misc : S29-07291601 ALS Vial : 15 Sample Multiplier: 1 Quant Time: Aug 22 12:54:11 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 14.45 71 990 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 15.97 91 32558 0.257 ng 99 59) 2-Hexanone 16.22 43 4734 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 16.84 43 3156 N.D. 63) n-Octane 16.97 57 900 N.D. 64) Tetrachloroethene 17.11 166 770 N.D. 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 18.12 91 5712 N.D. 67) m- & p-Xylenes 18.27 91 16714 0.150 ng 100 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.60 104 2115 N.D. 70) o-Xylene 18.70 91 6302 N.D. 71) n-Nonane 18.90 43 1769 N.D. 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 19.23 105 7690 N.D. 75) alpha-Pinene 19.58 93 753 N.D. 76) n-Propylbenzene 19.68 91 2705 N.D. 77) 3-Ethyltoluene 19.76 105 5781 N.D. 78) 4-Ethyltoluene 19.80 105 3064 N.D. 79) 1,3,5-Trimethylbenzene 19.87 105 3219 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. d 81) 2-Ethyltoluene 20.04 105 2699 N.D. 82) 1,2,4-Trimethylbenzene 20.23 105 8904 N.D. 83) n-Decane 20.31 57 4187 N.D. 84) Benzyl Chloride 20.23 91 1185 N.D. 85) 1,3-Dichlorobenzene 20.36 146 835 N.D. 86) 1,4-Dichlorobenzene 20.42 146 879 N.D. 87) sec-Butylbenzene 20.47 105 523 N.D. 88) 4-Isopropyltoluene (p-... 20.61 119 1367 N.D. 89) 1,2,3-Trimethylbenzene 20.60 105 2159 N.D. 90) 1,2-Dichlorobenzene 20.72 146 634 N.D. 91) d-Limonene 20.73 68 2569 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 21.41 57 4331 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 22.35 128 6657 N.D. 96) n-Dodecane 0.00 57 0 N.D. d 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 20.23 119 1447 N.D. 100) n-Butylbenzene 20.96 91 2455 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Mon Aug 22 13:55:22 2016 Page: 2

22 of 105

Quantitation Report (QT Reviewed)

Data File: I:\MS16\DATA\2016_08\18\08181636.D Acq On : 19 Aug 2016 1:01 Operator: LH Sample : P1603977-001 (400mL) Misc : S29-07291601 ALS Vial : 15 Sample Multiplier: 1

Quant Time: Aug 22 12:54:11 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

Time-->

Abundance TIC: 08181636.D\data.ms

Brom

oflu

orob

enze

ne (S

S3),S

m- &

p-X

ylen

es,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene,

TTo

luen

e-d8

(SS2

),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IRBe

nzen

e,T1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l Ace

tate

,TBr

omoc

hlor

omet

hane

(IS1

),IR

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Car

bon

Dis

ulfid

e,T

2-Pr

opan

ol (I

sopr

opan

ol),T

Acet

one,

TAc

role

in,T

Acet

onitr

ile,T

Etha

nol,T

Viny

l Chl

orid

e,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R16081016.M Mon Aug 22 13:55:22 2016 Page: 3

23 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181636.D Acq On : 19 Aug 2016 1:01 Operator: LH Sample : P1603977-001 (400mL) Misc : S29-07291601 ALS Vial : 15 Sample Multiplier: 1 Quant Time: Aug 22 12:54:11 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 267043 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.41 114 1299853 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 561366 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.13 65 415020 13.175 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 105.36% 57) Toluene-d8 (SS2) 15.87 98 1348794 12.074 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.56% 73) Bromofluorobenzene (SS3) 19.11 174 474428 11.897 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.20% Target Compounds Qvalue 3) Dichlorodifluoromethan... 4.37 85 39376 0.633 ng 98 4) Chloromethane 4.64 50 9987 0.249 ng 93 6) Vinyl Chloride 5.07 62 31459 0.688 ng 99 10) Ethanol 6.41 45 277872 14.527 ng 100 11) Acetonitrile 6.78 41 5909 0.122 ng # 43 12) Acrolein 6.93 56 1583 0.100 ng 100 13) Acetone 7.10 58 166235 8.620 ng 88 15) 2-Propanol (Isopropanol) 7.59 45 71553 1.088 ng 88 22) Carbon Disulfide 8.84 76 21135 0.191 ng 96 26) Vinyl Acetate 10.31 86 1772 0.299 ng # 89 27) 2-Butanone (MEK) 10.59 72 18963 1.030 ng # 89 30) Ethyl Acetate 11.41 61 3130 0.320 ng 94 41) Benzene 13.02 78 16102 0.145 ng 99 58) Toluene 15.97 91 32558 0.257 ng 99 67) m- & p-Xylenes 18.27 91 16714 0.150 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Mon Aug 22 12:54:27 2016 Page: 1

24 of 105

lusine.hakobyan

Lusine




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

m- &

p-X

ylen

es,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene,

TTo

luen

e-d8

(SS2

),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IRBe

nzen

e,T1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l Ace

tate

,TBr

omoc

hlor

omet

hane

(IS1

),IR

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,T

Car

bon

Dis

ulfid

e,T

2-Pr

opan

ol (I

sopr

opan

ol),T

Acet

one,

TAc

role

in,T

Acet

onitr

ile,T

Etha

nol,T

Viny

l Chl

orid

e,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R16081016.M Mon Aug 22 12:54:28 2016 Page: 2

25 of 105

#3Dichlorodifluoromethane (CFC 12)Concen: 0.63 ng RT: 4.37 min Scan# 142Delta R.T. 0.022 minLab File: 08181636.DAcq: 19 Aug 2016 1:01

Tgt Ion: 85 Resp: 39376Ion Ratio Lower Upper 85 100 87 31.8 12.8 52.8 101 8.6 0.0 29.2 103 5.2 0.0 26.0

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->

Abundance Scan 128 (4.291 min): 06141634.D\data.ms (-117) (-)85

50 10135 66 1207442

30 40 50 60 70 80 90 100 110 1200

50

m/z-->

Abundance Scan 142 (4.368 min): 08181636.D\data.ms85

43

50 1016635

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


43

50 1016635

4.30 4.400

5000

10000

15000

Time-->

Abundance 4.368

#4ChloromethaneConcen: 0.25 ng RT: 4.64 min Scan# 192Delta R.T. -0.033 minLab File: 08181636.DAcq: 19 Aug 2016 1:01

Tgt Ion: 50 Resp: 9987Ion Ratio Lower Upper 50 100 52 28.9 13.0 53.0

Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


473538 43 53

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


6545

41 85

25 30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


65

4585

4.60 4.70 4.800

1000

2000

3000

Time-->

Abundance 4.643

08181636.D R16081016.M Mon Aug 22 12:54:28 2016 Page 3

26 of 105

#6Vinyl ChlorideConcen: 0.69 ng RT: 5.07 min Scan# 269Delta R.T. -0.022 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 700

50

m/z-->


35 47 59 6538 50

25 30 35 40 45 50 55 60 65 700

50

m/z-->


4440 4735 6559

25 30 35 40 45 50 55 60 65 700

50

m/z-->


4440 4735 6559

5.00 5.10 5.200

5000

10000

15000

Time-->

Abundance 5.066

#10EthanolConcen: 14.53 ng RT: 6.41 min Scan# 514Delta R.T. -0.028 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 473633

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 4739

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


43

41 4739

6.20 6.40 6.60 6.80 7.000

20000

40000

60000

80000

Time-->

Abundance 6.413

08181636.D R16081016.M Mon Aug 22 12:54:29 2016 Page 4

27 of 105

#11AcetonitrileConcen: 0.12 ng RT: 6.78 min Scan# 580Delta R.T. -0.011 minLab File: 08181636.DAcq: 19 Aug 2016 1:01

Tgt Ion: 41 Resp: 5909Ion Ratio Lower Upper 41 100 40 94.0 33.5 73.5#

Ref

Raw

Sub

28 30 32 34 36 38 40 42 44 46 48 50 52 540

50

m/z-->


39

37

28 30 32 34 36 38 40 42 44 46 48 50 52 540

50

m/z-->

Abundance Scan 580 (6.776 min): 08181636.D\data.ms41 44

40

28 30 32 34 36 38 40 42 44 46 48 50 52 540

50

m/z-->


4044

6.60 6.80 7.000

1000

2000

3000

4000

5000

Time-->

Abundance

6.776

#12AcroleinConcen: 0.10 ng RT: 6.93 min Scan# 608Delta R.T. -0.000 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


37 5339 42 58

30 35 40 45 50 55 60 650

50

m/z-->


39 41

30 35 40 45 50 55 60 650

50

m/z-->


4139

6.85 6.90 6.95 7.000

100

200

300

400

500

Time-->

Abundance 6.930

08181636.D R16081016.M Mon Aug 22 12:54:29 2016 Page 5

28 of 105

#13AcetoneConcen: 8.62 ng RT: 7.10 min Scan# 639Delta R.T. -0.022 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


58

394137 5645 6052 54

30 35 40 45 50 55 60 650

50

m/z-->


58

3937 41 6045 52 55

30 35 40 45 50 55 60 650

50

m/z-->


58

3937 41 6045 52 55

7.00 7.20 7.40 7.600

50000

100000

150000

Time-->

Abundance

7.101

#152-Propanol (Isopropanol)Concen: 1.09 ng RT: 7.59 min Scan# 728Delta R.T. -0.006 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


41 5938 55 6852

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


41 5938 55 70 81

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


41 5938 55 70 81

7.60 7.800

5000

10000

15000

20000

25000

Time-->

Abundance 7.590

08181636.D R16081016.M Mon Aug 22 12:54:29 2016 Page 6

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#22Carbon DisulfideConcen: 0.19 ng RT: 8.84 min Scan# 956Delta R.T. -0.022 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


4438 6434 7960

25 30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


4438

25 30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


4438

8.70 8.80 8.90 9.00 9.100

1000

2000

3000

4000

5000

Time-->

Abundance 8.844

#26Vinyl AcetateConcen: 0.30 ng RT: 10.31 min Scan# 1222Delta R.T. -0.039 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


8658 6937 53 96

30 40 50 60 70 80 90 1000

50

m/z-->


7586

55

30 40 50 60 70 80 90 1000

50

m/z-->


7586

55

10.25 10.30 10.350

1000

2000

3000

4000

Time-->

Abundance

10.307

08181636.D R16081016.M Mon Aug 22 12:54:30 2016 Page 7

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#272-Butanone (MEK)Concen: 1.03 ng RT: 10.59 min Scan# 1273Delta R.T. -0.011 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725746 53

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725739 7550 53

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

5739 51

10.50 10.60 10.700

10000

20000

Time-->

Abundance

10.587

#30Ethyl AcetateConcen: 0.32 ng RT: 11.41 min Scan# 1423Delta R.T. -0.000 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61 87705135 101

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61 70 1308851

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61 70 1308851

11.35 11.40 11.450

500

1000

1500

Time-->

Abundance11.412

08181636.D R16081016.M Mon Aug 22 12:54:30 2016 Page 8

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#41BenzeneConcen: 0.14 ng RT: 13.02 min Scan# 1715Delta R.T. -0.000 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


517439 6348 5436

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


5641

524438 63 7449 84

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


5641

524538 63 7449 84

13.00 13.100

2000

4000

6000

Time-->

Abundance13.018

#58TolueneConcen: 0.26 ng RT: 15.97 min Scan# 2251Delta R.T. -0.000 minLab File: 08181636.DAcq: 19 Aug 2016 1:01


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


6539 5145 8574

30 40 50 60 70 80 90 1000

50

m/z-->


6539 5145 77 988557

30 40 50 60 70 80 90 1000

50

m/z-->


6539 5145 77 988557

15.90 15.95 16.000

5000

10000

15000

Time-->

Abundance15.965

08181636.D R16081016.M Mon Aug 22 12:54:31 2016 Page 9

32 of 105

#67m- & p-XylenesConcen: 0.15 ng RT: 18.27 min Scan# 2670Delta R.T. -0.017 minLab File: 08181636.DAcq: 19 Aug 2016 1:01

Tgt Ion: 91 Resp: 16714Ion Ratio Lower Upper 91 100106 50.2 30.1 70.1

Ref

Raw

Sub

40 60 80 100 120 140 160 1800

50

m/z-->


106

775139 65 173

40 60 80 100 120 140 160 1800

50

m/z-->


106

51 7739 65 117

40 60 80 100 120 140 160 1800

50

m/z-->


106

51 7739 65

18.20 18.25 18.30 18.350

2000

4000

6000

Time-->

Abundance18.269

08181636.D R16081016.M Mon Aug 22 12:54:31 2016 Page 10

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Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181637.D Acq On : 19 Aug 2016 1:34 Operator: LH Sample : P1603977-002 (80mL) Misc : S29-07291601 ALS Vial : 16 Sample Multiplier: 1 Quant Time: Aug 22 13:50:16 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 282691 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.41 114 1336270 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 576385 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 434451 13.028 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 104.24% 57) Toluene-d8 (SS2) 15.87 98 1378322 12.017 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.16% 73) Bromofluorobenzene (SS3) 19.10 174 491402 12.001 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.00% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. d 3) Dichlorodifluoromethan... 4.35 85 7877 0.120 ng # 96 4) Chloromethane 4.64 50 2244 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 5.05 62 3049 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. d 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.42 45 79211 3.912 ng 98 11) Acetonitrile 0.00 41 0 N.D. 12) Acrolein 0.00 56 0 N.D. d 13) Acetone 7.10 58 204938 10.039 ng 91 14) Trichlorofluoromethane 7.36 101 3440 N.D. 15) 2-Propanol (Isopropanol) 7.61 45 13505 0.194 ng # 59 16) Acrylonitrile 0.00 53 0 N.D. d 17) 1,1-Dichloroethene 8.34 96 18190 0.653 ng 94 18) 2-Methyl-2-Propanol (t... 8.51 59 5344 N.D. 19) Methylene Chloride 8.55 84 1649 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. d 21) Trichlorotrifluoroethane 8.99 151 648 N.D. 22) Carbon Disulfide 8.84 76 3220 N.D. 23) trans-1,2-Dichloroethene 9.84 61 3874 0.096 ng 90 24) 1,1-Dichloroethane 10.08 63 13450m 0.262 ng 25) Methyl tert-Butyl Ether 10.22 73 524 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. d 27) 2-Butanone (MEK) 10.60 72 10319 0.530 ng # 81 28) cis-1,2-Dichloroethene 11.10 61 79560 2.062 ng 94 29) Diisopropyl Ether 0.00 87 0 N.D. d 30) Ethyl Acetate 11.42 61 5799 0.559 ng # 1 31) n-Hexane 11.40 57 767930 16.649 ng 99 32) Chloroform 11.45 83 22931 0.449 ng 98 34) Tetrahydrofuran (THF) 11.88 72 3454 0.178 ng # 76 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 12.28 62 2393 N.D. 38) 1,1,1-Trichloroethane 12.54 97 26585 0.579 ng 99 39) Isopropyl Acetate 13.01 61 772 N.D. 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 13.02 78 140983 1.234 ng 100 42) Carbon Tetrachloride 13.17 117 640 N.D. 43) Cyclohexane 13.31 84 564302 12.938 ng 95 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 13.78 63 662 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. d 47) Trichloroethene 14.12 130 821399 23.754 ng 100 48) 1,4-Dioxane 0.00 88 0 N.D. d 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D. d

R16081016.M Mon Aug 22 13:55:31 2016 Page: 1

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lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181637.D Acq On : 19 Aug 2016 1:34 Operator: LH Sample : P1603977-002 (80mL) Misc : S29-07291601 ALS Vial : 16 Sample Multiplier: 1 Quant Time: Aug 22 13:50:16 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. d 51) n-Heptane 14.45 71 140919 5.010 ng 97 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. d 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. d 58) Toluene 15.97 91 15194 0.117 ng 100 59) 2-Hexanone 0.00 43 0 N.D. d 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 16.86 43 4750 N.D. 63) n-Octane 16.97 57 25567 0.983 ng 94 64) Tetrachloroethene 17.11 166 195445 4.774 ng 99 65) Chlorobenzene 0.00 112 0 N.D. d 66) Ethylbenzene 18.12 91 25314 0.175 ng 97 67) m- & p-Xylenes 18.29 91 13707 0.120 ng 99 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.60 104 1365 N.D. 70) o-Xylene 18.70 91 4290 N.D. 71) n-Nonane 18.90 43 7670m 0.135 ng 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d 74) Cumene 19.23 105 11604 N.D. 75) alpha-Pinene 19.57 93 2848 N.D. 76) n-Propylbenzene 19.68 91 18477 0.101 ng 85 77) 3-Ethyltoluene 19.76 105 2755 N.D. 78) 4-Ethyltoluene 19.80 105 3188 N.D. 79) 1,3,5-Trimethylbenzene 19.87 105 3285 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. d 81) 2-Ethyltoluene 20.03 105 4420 N.D. 82) 1,2,4-Trimethylbenzene 20.23 105 20911 0.177 ng 92 83) n-Decane 0.00 57 0 N.D. d 84) Benzyl Chloride 20.32 91 4445 N.D. 85) 1,3-Dichlorobenzene 20.42 146 676 N.D. 86) 1,4-Dichlorobenzene 20.42 146 676 N.D. 87) sec-Butylbenzene 0.00 105 0 N.D. d 88) 4-Isopropyltoluene (p-... 20.61 119 4017 N.D. 89) 1,2,3-Trimethylbenzene 20.61 105 9420 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. d 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. d 94) 1,2,4-Trichlorobenzene 22.24 180 1699 N.D. 95) Naphthalene 22.34 128 67982 0.412 ng # 29 96) n-Dodecane 0.00 57 0 N.D. d 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 20.23 119 5541 N.D. 100) n-Butylbenzene 0.00 91 0 N.D. d -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Mon Aug 22 13:55:31 2016 Page: 2

35 of 105




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

1.25e+07

1.3e+07

1.35e+07

1.4e+07

1.45e+07

1.5e+07

1.55e+07

Time-->


Nap

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R16081016.M Mon Aug 22 13:55:32 2016 Page: 3

36 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181637.D Acq On : 19 Aug 2016 1:34 Operator: LH Sample : P1603977-002 (80mL) Misc : S29-07291601 ALS Vial : 16 Sample Multiplier: 1 Quant Time: Aug 22 13:50:16 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 282691 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.41 114 1336270 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 576385 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 434451 13.028 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 104.24% 57) Toluene-d8 (SS2) 15.87 98 1378322 12.017 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.16% 73) Bromofluorobenzene (SS3) 19.10 174 491402 12.001 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.00% Target Compounds Qvalue 3) Dichlorodifluoromethan... 4.35 85 7877 0.120 ng # 96 10) Ethanol 6.42 45 79211 3.912 ng 98 13) Acetone 7.10 58 204938 10.039 ng 91 15) 2-Propanol (Isopropanol) 7.61 45 13505 0.194 ng # 59 17) 1,1-Dichloroethene 8.34 96 18190 0.653 ng 94 23) trans-1,2-Dichloroethene 9.84 61 3874 0.096 ng 90 24) 1,1-Dichloroethane 10.08 63 13450m 0.262 ng 27) 2-Butanone (MEK) 10.60 72 10319 0.530 ng # 81 28) cis-1,2-Dichloroethene 11.10 61 79560 2.062 ng 94 30) Ethyl Acetate 11.42 61 5799 0.559 ng # 1 31) n-Hexane 11.40 57 767930 16.649 ng 99 32) Chloroform 11.45 83 22931 0.449 ng 98 34) Tetrahydrofuran (THF) 11.88 72 3454 0.178 ng # 76 38) 1,1,1-Trichloroethane 12.54 97 26585 0.579 ng 99 41) Benzene 13.02 78 140983 1.234 ng 100 43) Cyclohexane 13.31 84 564302 12.938 ng 95 47) Trichloroethene 14.12 130 821399 23.754 ng 100 51) n-Heptane 14.45 71 140919 5.010 ng 97 58) Toluene 15.97 91 15194 0.117 ng 100 63) n-Octane 16.97 57 25567 0.983 ng 94 64) Tetrachloroethene 17.11 166 195445 4.774 ng 99 66) Ethylbenzene 18.12 91 25314 0.175 ng 97 67) m- & p-Xylenes 18.29 91 13707 0.120 ng 99 71) n-Nonane 18.90 43 7670m 0.135 ng 76) n-Propylbenzene 19.68 91 18477 0.101 ng 85 82) 1,2,4-Trimethylbenzene 20.23 105 20911 0.177 ng 92 95) Naphthalene 22.34 128 67982 0.412 ng # 29 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Mon Aug 22 13:50:22 2016 Page: 1

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lusine.hakobyan

Lusine




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

1.25e+07

1.3e+07

1.35e+07

1.4e+07

1.45e+07

1.5e+07

1.55e+07

Time-->


Nap

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R16081016.M Mon Aug 22 13:50:22 2016 Page: 2

38 of 105

#3Dichlorodifluoromethane (CFC 12)Concen: 0.12 ng RT: 4.35 min Scan# 138Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34

Tgt Ion: 85 Resp: 7877Ion Ratio Lower Upper 85 100 87 32.2 12.8 52.8 101 6.9 0.0 29.2 103 0.0 0.0 26.0

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10135 66 1207442

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


85

50 10135 66

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


85

50 10135 66

4.30 4.35 4.400

1000

2000

3000

4000

Time-->

Abundance 4.346

#10EthanolConcen: 3.91 ng RT: 6.42 min Scan# 515Delta R.T. -0.022 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 473633

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


43

4139 47

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


43

41 47

6.20 6.40 6.60 6.800

5000

10000

15000

Time-->

Abundance 6.419

08181637.D R16081016.M Mon Aug 22 13:50:23 2016 Page 3

39 of 105

#13AcetoneConcen: 10.04 ng RT: 7.10 min Scan# 638Delta R.T. -0.028 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


58

394137 5645 6052 54

30 35 40 45 50 55 60 650

50

m/z-->


58

394137 6045 52 55

30 35 40 45 50 55 60 650

50

m/z-->


58

394137 6045 52 55

7.05 7.10 7.150

500000

1000000

1500000

Time-->

Abundance

7.095

#152-Propanol (Isopropanol)Concen: 0.19 ng RT: 7.61 min Scan# 731Delta R.T. 0.011 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 750

50

m/z-->


41 5938 55 6852

30 35 40 45 50 55 60 65 70 750

50

m/z-->


4239 55 59

30 35 40 45 50 55 60 65 70 750

50

m/z-->


41 55 59

7.50 7.60 7.70 7.800

1000

2000

3000

4000

Time-->

Abundance 7.606

08181637.D R16081016.M Mon Aug 22 13:50:23 2016 Page 4

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#171,1-DichloroetheneConcen: 0.65 ng RT: 8.34 min Scan# 864Delta R.T. -0.017 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 827041

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47

8.25 8.30 8.35 8.400

5000

10000

Time-->

Abundance

8.338

#23trans-1,2-DichloroetheneConcen: 0.10 ng RT: 9.84 min Scan# 1137Delta R.T. -0.006 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

4735

30 40 50 60 70 80 90 1000

50

m/z-->


96

44

30 40 50 60 70 80 90 1000

50

m/z-->


96

41

9.75 9.80 9.85 9.90 9.950

500

1000

Time-->

Abundance 9.839

08181637.D R16081016.M Mon Aug 22 13:50:23 2016 Page 5

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#241,1-DichloroethaneConcen: 0.26 ng mRT: 10.08 min Scan# 1181Delta R.T. -0.006 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


839835 47 70 7641

30 40 50 60 70 80 90 1000

50

m/z-->


8342 9835

30 40 50 60 70 80 90 1000

50

m/z-->


834235 100

10.00 10.05 10.10 10.150

1000

2000

3000

4000

5000

Time-->

Abundance10.081

#272-Butanone (MEK)Concen: 0.53 ng RT: 10.60 min Scan# 1275Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725753

-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725739 50

-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->

Abundance Scan 1275 (10.598 min): 08181637.D\data.ms (-1230) (-)

10.50 10.60 10.700

5000

10000

15000

Time-->

Abundance

10.598

08181637.D R16081016.M Mon Aug 22 13:50:24 2016 Page 6

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#28cis-1,2-DichloroetheneConcen: 2.06 ng RT: 11.10 min Scan# 1367Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 48 70 82

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 48 70

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 70

11.00 11.10 11.200

10000

20000

30000

Time-->

Abundance11.104

#30Ethyl AcetateConcen: 0.56 ng RT: 11.42 min Scan# 1424Delta R.T. 0.005 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61 87705135 101

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


43

8671 79 12835

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

8671 128

11.40 11.500

1000

2000

3000

4000

Time-->

Abundance

11.417

08181637.D R16081016.M Mon Aug 22 13:50:24 2016 Page 7

43 of 105

#31n-HexaneConcen: 16.65 ng RT: 11.40 min Scan# 1421Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34

Tgt Ion: 57 Resp: 767930Ion Ratio Lower Upper 57 100 56 51.3 40.9 61.3 86 14.9 13.0 19.6

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


578770 10233

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

8671 79 12849 95

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

8671 79 95 13049

11.30 11.40 11.500

100000

200000

300000

Time-->

Abundance11.401

#32ChloroformConcen: 0.45 ng RT: 11.45 min Scan# 1430Delta R.T. 0.005 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


4735 11872

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


4357

35 70 130118

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


47 57

35 70 130118

11.40 11.500

2000

4000

6000

8000

10000

Time-->

Abundance11.450

08181637.D R16081016.M Mon Aug 22 13:50:24 2016 Page 8

44 of 105

#34Tetrahydrofuran (THF)Concen: 0.18 ng RT: 11.88 min Scan# 1509Delta R.T. 0.011 minLab File: 08181637.DAcq: 19 Aug 2016 1:34

Tgt Ion: 72 Resp: 3454Ion Ratio Lower Upper 72 100 71 93.6 77.1 117.1 42 261.8 188.7 228.7#

Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

39

45 51 54 5735 68

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

39

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

39

11.80 11.85 11.90 11.950

1000

2000

3000

Time-->

Abundance

11.885

#381,1,1-TrichloroethaneConcen: 0.58 ng RT: 12.54 min Scan# 1628Delta R.T. 0.005 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61

11935 47 8270

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61

1174335 82

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61

11735 47 84

12.50 12.600

5000

10000

Time-->

Abundance12.539

08181637.D R16081016.M Mon Aug 22 13:50:25 2016 Page 9

45 of 105

#41BenzeneConcen: 1.23 ng RT: 13.02 min Scan# 1715Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


517439 6348 5436

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


5139 7456 6343 604836

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


5139 7456 6343 604836

12.90 13.00 13.100

20000

40000

60000

Time-->

Abundance13.018

#43CyclohexaneConcen: 12.94 ng RT: 13.31 min Scan# 1769Delta R.T. 0.005 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->

Abundance Scan 1769 (13.315 min): 06141634.D\data.ms (-1757) (-)56 84

41

69

535038 7763 7344 8066

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


41

69

5338 50 77 816344 66 73

30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


41

69

535038 7763 8144 66 73

13.20 13.30 13.400

100000

200000

300000

Time-->

Abundance

13.315

08181637.D R16081016.M Mon Aug 22 13:50:25 2016 Page 10

46 of 105

#47TrichloroetheneConcen: 23.75 ng RT: 14.12 min Scan# 1915Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34

Tgt Ion:130 Resp: 821399Ion Ratio Lower Upper130 100132 96.6 76.2 116.2

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8274

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8270

14.00 14.200

100000

200000

300000

Time-->

Abundance14.117

#51n-HeptaneConcen: 5.01 ng RT: 14.45 min Scan# 1976Delta R.T. 0.005 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


7157

1008550 776337

30 40 50 60 70 80 90 1000

50

m/z-->


7157

1008550 6337 77

30 40 50 60 70 80 90 1000

50

m/z-->


7157

1008551 63 7737

14.40 14.500

20000

40000

60000

Time-->

Abundance14.453

08181637.D R16081016.M Mon Aug 22 13:50:26 2016 Page 11

47 of 105

#58TolueneConcen: 0.12 ng RT: 15.97 min Scan# 2251Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


6539 5145 8574

30 40 50 60 70 80 90 1000

50

m/z-->


7157

85

6551 98

30 40 50 60 70 80 90 1000

50

m/z-->


7157

85

6551 99

15.90 15.95 16.000

2000

4000

6000

Time-->

Abundance15.965

#63n-OctaneConcen: 0.98 ng RT: 16.97 min Scan# 2434Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


855771

11478 99645037

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


855771

11450

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


8557

71

11450

16.90 16.95 17.000

5000

10000

15000

Time-->

Abundance

16.971

08181637.D R16081016.M Mon Aug 22 13:50:26 2016 Page 12

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#64TetrachloroetheneConcen: 4.77 ng RT: 17.11 min Scan# 2459Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


129

9447 5935 82 11770

40 60 80 100 120 140 1600

50

m/z-->


129

9447 59 846935

117

40 60 80 100 120 140 1600

50

m/z-->


129

9447 59 8435 69 117

17.00 17.10 17.200

20000

40000

60000

80000

Time-->

Abundance17.109

#66EthylbenzeneConcen: 0.18 ng RT: 18.12 min Scan# 2643Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


106

51 776539 84 98

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


5570

10641 8477 9863 126117

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


5510670

8441 77 98 12663

18.05 18.10 18.150

5000

10000

Time-->

Abundance18.121

08181637.D R16081016.M Mon Aug 22 13:50:26 2016 Page 13

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#67m- & p-XylenesConcen: 0.12 ng RT: 18.29 min Scan# 2674Delta R.T. 0.005 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

40 60 80 100 120 140 160 1800

50

m/z-->


106

775139 65 173

40 60 80 100 120 140 160 1800

50

m/z-->


10657 71

128

40 60 80 100 120 140 160 1800

50

m/z-->


43106

71

57128

18.20 18.25 18.30 18.350

1000

2000

3000

4000

5000

Time-->

Abundance18.291

#71n-NonaneConcen: 0.13 ng mRT: 18.90 min Scan# 2784Delta R.T. -0.006 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


8571

1289978 11236

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


97

6983

126111

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


8543

128

18.85 18.900

5000

10000

15000

20000

Time-->

Abundance

18.896

08181637.D R16081016.M Mon Aug 22 13:50:27 2016 Page 14

50 of 105

#76n-PropylbenzeneConcen: 0.10 ng RT: 19.68 min Scan# 2926Delta R.T. -0.000 minLab File: 08181637.DAcq: 19 Aug 2016 1:34

Tgt Ion: 91 Resp: 18477Ion Ratio Lower Upper 91 100120 19.5 4.4 44.4 65 20.1 0.0 29.7

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


12065 7839 51 105

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


9141

11183

120 14099

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


69

11141

81 12099 140

19.60 19.700

2000

4000

6000

8000

10000

Time-->

Abundance19.677

#821,2,4-TrimethylbenzeneConcen: 0.18 ng RT: 20.23 min Scan# 3026Delta R.T. -0.006 minLab File: 08181637.DAcq: 19 Aug 2016 1:34


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


91

77 13441 51 65169

40 60 80 100 120 140 1600

50

m/z-->


694183

111 140125

40 60 80 100 120 140 1600

50

m/z-->


41 8314070 120

20.15 20.20 20.25 20.300

5000

10000

Time-->

Abundance20.227

08181637.D R16081016.M Mon Aug 22 13:50:27 2016 Page 15

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#95NaphthaleneConcen: 0.41 ng RT: 22.34 min Scan# 3411Delta R.T. -0.017 minLab File: 08181637.DAcq: 19 Aug 2016 1:34

Tgt Ion:128 Resp: 67982Ion Ratio Lower Upper128 100129 38.1 0.0 31.1#

Ref

Raw

Sub

40 60 80 100 120 140 160 180 2000

50

m/z-->


5743 71 10285 170114 141 207

40 60 80 100 120 140 160 180 2000

50

m/z-->


9741

83131

109146 168

180 196208

40 60 80 100 120 140 160 180 2000

50

m/z-->


55 69 131

81 109 146166

18239 196208

22.30 22.35 22.400

10000

20000

30000

Time-->

Abundance22.344

08181637.D R16081016.M Mon Aug 22 13:50:28 2016 Page 16

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Quantitation Report (Qedit)



9.60 9.65 9.70 9.75 9.80 9.85 9.90 9.95 10.00 10.05 10.10 10.15 10.20 10.25 10.30 10.35 10.40 10.45 10.50 10.55 10.60 10.65 10.70 10.75 10.80

0

500

1000

1500

2000

2500

Time-->

Abundance Ion 63.00 (62.70 to 63.70): 08181637.D\data.ms10.081

|

|

|

|||||| 2d1

Ion 65.00 (64.70 to 65.70): 08181637.D\data.ms

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110

2000

4000

m/z-->


8342 9835 60

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 1100

5000

m/z-->


839835 6047 8766 1025038 70 9541 44 76

TIC: 08181637.D\data.ms

0.00 0.00 0.00

0.00 0.00 0.00

65.00 32.20 30.52

63.00 100 100

Ion Exp% Act%

response 14745

10.081min (-0.006) 0.29ng

(24) 1,1-Dichloroethane (T)

R16081016.M Mon Aug 22 13:34:26 2016 Page: 1

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9.60 9.65 9.70 9.75 9.80 9.85 9.90 9.95 10.00 10.05 10.10 10.15 10.20 10.25 10.30 10.35 10.40 10.45 10.50 10.55 10.60 10.65 10.70 10.75 10.80

0

500

1000

1500

2000

2500

Time-->

Abundance Ion 63.00 (62.70 to 63.70): 08181637.D\data.ms10.081

|

|

|

|||||| 2d1

Ion 65.00 (64.70 to 65.70): 08181637.D\data.ms

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110

2000

4000

m/z-->


8342 9835 60

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 1100

5000

m/z-->


839835 6047 8766 1025038 70 9541 44 76


0.00 0.00 0.00

0.00 0.00 0.00

65.00 32.20 33.46

63.00 100 100

Ion Exp% Act%

response 13450

10.081min (-0.006) 0.26ng m

(24) 1,1-Dichloroethane (T)

R16081016.M Mon Aug 22 13:34:34 2016 Page: 1

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lusine.hakobyan

IPC

lusine.hakobyan

Lusine

simon.cao

Simon




18.60 18.65 18.70 18.75 18.80 18.85 18.90 18.95 19.00 19.05 19.10 19.15 19.20 19.25 19.30 19.35 19.40 19.45

0

2000

4000

6000

8000

10000

12000

Time-->

Abundance Ion 43.10 (42.80 to 43.80): 08181637.D\data.ms

18.896

|

|

|

|

|||

||

|5d

4d3d

2d1

Ion 57.10 (56.80 to 57.80): 08181637.D\data.msIon 85.10 (84.80 to 85.80): 08181637.D\data.ms

30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

2000

4000

m/z-->


97

698339

12658 866551 11179

30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

5000

m/z-->


8571

39 99 12853 6750 7763 82 91 1129636


0.00 0.00 0.00

85.10 39.90 26.18

57.10 98.30 75.40#

43.10 100 100

Ion Exp% Act%

response 9414

18.896min (-0.006) 0.17ng

(71) n-Nonane (T)

R16081016.M Mon Aug 22 13:49:33 2016 Page: 1

55 of 105




18.60 18.65 18.70 18.75 18.80 18.85 18.90 18.95 19.00 19.05 19.10 19.15 19.20 19.25 19.30 19.35 19.40 19.45

0

2000

4000

6000

8000

10000

12000

Time-->


18.896

|

|

|

|

|||

||

|5d

4d3d

2d1


30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

2000

4000

m/z-->


97

698339

12658 866551 11179

30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

5000

m/z-->


8571

39 99 12853 6750 7763 82 91 1129636


0.00 0.00 0.00

85.10 39.90 32.14

57.10 98.30 92.54

43.10 100 100

Ion Exp% Act%

response 7670

18.896min (-0.006) 0.13ng m

(71) n-Nonane (T)

R16081016.M Mon Aug 22 13:49:43 2016 Page: 1

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lusine.hakobyan

IPC

lusine.hakobyan

Lusine

simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181626.D Acq On : 18 Aug 2016 19:25 Operator: LH Sample : MB2 R16081816_1000mL Misc : S29-07291601 AC00442 ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 08:26:33 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 261371 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.41 114 1298046 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 546654 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 407257 13.209 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 105.68% 57) Toluene-d8 (SS2) 15.87 98 1337249 12.293 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.32% 73) Bromofluorobenzene (SS3) 19.10 174 459456 11.832 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 94.64% Target Compounds Qvalue 2) Propene 4.24 42 636 N.D. 3) Dichlorodifluoromethan... 0.00 85 0 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 0.00 62 0 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 6.48 45 2868 0.153 ng 88 11) Acetonitrile 6.80 41 1694 N.D. 12) Acrolein 6.99 56 595 N.D. 13) Acetone 7.17 58 6659 0.353 ng 85 14) Trichlorofluoromethane 0.00 101 0 N.D. 15) 2-Propanol (Isopropanol) 7.66 45 555 N.D. 16) Acrylonitrile 7.95 53 222 N.D. 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 0.00 59 0 N.D. 19) Methylene Chloride 0.00 84 0 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 0.00 151 0 N.D. 22) Carbon Disulfide 8.88 76 1741 N.D. 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. 24) 1,1-Dichloroethane 0.00 63 0 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 10.46 72 950 N.D. 28) cis-1,2-Dichloroethene 0.00 61 0 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 0.00 57 0 N.D. 32) Chloroform 0.00 83 0 N.D. 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 13.03 56 1177 N.D. 41) Benzene 13.02 78 7531 N.D. 42) Carbon Tetrachloride 0.00 117 0 N.D. 43) Cyclohexane 13.41 84 635 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 0.00 63 0 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. 47) Trichloroethene 0.00 130 0 N.D. 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D.

R16081016.M Fri Aug 19 09:37:19 2016 Page: 1

57 of 105

lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181626.D Acq On : 18 Aug 2016 19:25 Operator: LH Sample : MB2 R16081816_1000mL Misc : S29-07291601 AC00442 ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 08:26:33 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 0.00 71 0 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 15.96 91 2832 N.D. 59) 2-Hexanone 0.00 43 0 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 16.87 43 668 N.D. 63) n-Octane 0.00 57 0 N.D. 64) Tetrachloroethene 0.00 166 0 N.D. 65) Chlorobenzene 17.77 112 656 N.D. 66) Ethylbenzene 18.06 91 1821 N.D. 67) m- & p-Xylenes 18.27 91 4174 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 18.60 104 1013 N.D. 70) o-Xylene 18.71 91 1969 N.D. 71) n-Nonane 0.00 43 0 N.D. 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 19.23 105 1048 N.D. 75) alpha-Pinene 0.00 93 0 N.D. 76) n-Propylbenzene 19.87 91 640 N.D. 77) 3-Ethyltoluene 19.76 105 8481 N.D. 78) 4-Ethyltoluene 19.76 105 8481 N.D. 79) 1,3,5-Trimethylbenzene 19.93 105 678 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. 81) 2-Ethyltoluene 20.09 105 862 N.D. 82) 1,2,4-Trimethylbenzene 20.18 105 585 N.D. 83) n-Decane 0.00 57 0 N.D. 84) Benzyl Chloride 20.42 91 903 N.D. 85) 1,3-Dichlorobenzene 20.44 146 575 N.D. 86) 1,4-Dichlorobenzene 20.44 146 575 N.D. 87) sec-Butylbenzene 20.29 105 935 N.D. 88) 4-Isopropyltoluene (p-... 0.00 119 0 N.D. 89) 1,2,3-Trimethylbenzene 20.66 105 586 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. 94) 1,2,4-Trichlorobenzene 22.28 180 1505 N.D. 95) Naphthalene 22.40 128 13063 N.D. 96) n-Dodecane 0.00 57 0 N.D. 97) Hexachlorobutadiene 22.68 225 933 N.D. 98) Cyclohexanone 0.00 55 0 N.D. 99) tert-Butylbenzene 20.09 119 570 N.D. 100) n-Butylbenzene 21.06 91 677 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Fri Aug 19 09:37:19 2016 Page: 2

58 of 105


Data File: I:\MS16\DATA\2016_08\18\08181626.D Acq On : 18 Aug 2016 19:25 Operator: LH Sample : MB2 R16081816_1000mL Misc : S29-07291601 AC00442 ALS Vial : 2 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

1900000

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Brom

ochl

orom

etha

ne (I

S1),I

R

Acet

one,

T

Etha

nol,T

R16081016.M Fri Aug 19 09:37:20 2016 Page: 3

59 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181627.D Acq On : 18 Aug 2016 19:58 Operator: LH Sample : LCS2 R16081816_25ng Misc : S29-07291601/S29-08041602 (9/2) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 09:37:49 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 295388 12.500 ng 0.01 37) 1,4-Difluorobenzene (IS2) 13.42 114 1393932 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 608165 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 431934 12.396 ng 0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.20% 57) Toluene-d8 (SS2) 15.87 98 1444376 11.935 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.52% 73) Bromofluorobenzene (SS3) 19.11 174 537490 12.441 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.52% Target Compounds Qvalue 2) Propene 4.12 42 689598m 23.430 ng 3) Dichlorodifluoromethan... 4.28 85 1462703 21.267 ng 100 4) Chloromethane 4.57 50 1015480 22.897 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.85 135 843338 21.520 ng 100 6) Vinyl Chloride 5.01 62 1198943 23.692 ng 100 7) 1,3-Butadiene 5.27 54 814081 25.947 ng 99 8) Bromomethane 5.73 94 717843 21.674 ng 99 9) Chloroethane 6.06 64 542329 24.357 ng 99 10) Ethanol 6.46 45 2531599 119.648 ng 100 11) Acetonitrile 6.71 41 1240782 23.226 ng 100 12) Acrolein 6.90 56 417067 23.887 ng 99 13) Acetone 7.11 58 2833308 132.827 ng 97 14) Trichlorofluoromethane 7.35 101 1291830 21.858 ng 100 15) 2-Propanol (Isopropanol) 7.61 45 3663244 50.373 ng 99 16) Acrylonitrile 7.88 53 993105 25.907 ng 100 17) 1,1-Dichloroethene 8.33 96 754469 25.930 ng 98 18) 2-Methyl-2-Propanol (t... 8.50 59 3223930 46.552 ng 99 19) Methylene Chloride 8.56 84 773402 26.042 ng 97 20) 3-Chloro-1-propene (Al... 8.72 41 1015125 26.848 ng 98 21) Trichlorotrifluoroethane 8.97 151 646418 24.481 ng 97 22) Carbon Disulfide 8.82 76 2634926 21.546 ng 100 23) trans-1,2-Dichloroethene 9.84 61 1081796 25.777 ng 98 24) 1,1-Dichloroethane 10.09 63 1360283 25.392 ng 100 25) Methyl tert-Butyl Ether 10.18 73 1714437 22.443 ng 99 26) Vinyl Acetate 10.35 86 955342 145.790 ng # 92 27) 2-Butanone (MEK) 10.59 72 543752 26.707 ng 99 28) cis-1,2-Dichloroethene 11.11 61 1074001 26.637 ng 98 29) Diisopropyl Ether 11.41 87 678850 23.525 ng # 63 30) Ethyl Acetate 11.41 61 612071 56.503 ng 99 31) n-Hexane 11.40 57 1271678 26.385 ng 100 32) Chloroform 11.46 83 1363326 25.568 ng 100 34) Tetrahydrofuran (THF) 11.86 72 519906 25.656 ng 99 35) Ethyl tert-Butyl Ether 12.00 87 931565 25.204 ng 96 36) 1,2-Dichloroethane 12.26 62 981582 24.419 ng 100 38) 1,1,1-Trichloroethane 12.54 97 1154831 24.091 ng 100 39) Isopropyl Acetate 12.97 61 1069317 58.669 ng 97 40) 1-Butanol 12.98 56 1558915 55.045 ng 96 41) Benzene 13.02 78 3121036 26.182 ng 100 42) Carbon Tetrachloride 13.18 117 1049690 25.203 ng 100 43) Cyclohexane 13.31 84 2335823 51.339 ng 97 44) tert-Amyl Methyl Ether 13.66 73 2215056 25.791 ng 99 45) 1,2-Dichloropropane 13.88 63 790234 26.641 ng 100 46) Bromodichloromethane 14.06 83 1103048 26.031 ng 100 47) Trichloroethene 14.12 130 855252 23.710 ng 100 48) 1,4-Dioxane 14.08 88 665559 27.100 ng 98 49) 2,2,4-Trimethylpentane... 14.19 57 3196059 26.380 ng 98

R16081016.M Fri Aug 19 09:38:17 2016 Page: 1

60 of 105

lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181627.D Acq On : 18 Aug 2016 19:58 Operator: LH Sample : LCS2 R16081816_25ng Misc : S29-07291601/S29-08041602 (9/2) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 09:37:49 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 690213 51.931 ng 96 51) n-Heptane 14.45 71 783832 26.716 ng 98 52) cis-1,3-Dichloropropene 14.98 75 1250460 25.822 ng 100 53) 4-Methyl-2-pentanone 15.01 58 752140 28.087 ng 99 54) trans-1,3-Dichloropropene 15.50 75 1150830 26.585 ng 100 55) 1,1,2-Trichloroethane 15.67 97 784058 25.806 ng 98 58) Toluene 15.97 91 3222301 23.501 ng 100 59) 2-Hexanone 16.21 43 1705627 25.566 ng 100 60) Dibromochloromethane 16.38 129 962079 24.611 ng 100 61) 1,2-Dibromoethane 16.63 107 927020 24.374 ng 100 62) n-Butyl Acetate 16.84 43 1917658 26.314 ng 100 63) n-Octane 16.97 57 673743 24.548 ng 97 64) Tetrachloroethene 17.11 166 934749 21.637 ng 100 65) Chlorobenzene 17.77 112 2183958 23.950 ng 100 66) Ethylbenzene 18.12 91 3744608 24.574 ng 99 67) m- & p-Xylenes 18.29 91 5753928 47.672 ng 99 68) Bromoform 18.35 173 881117 23.771 ng 100 69) Styrene 18.60 104 2383022 25.286 ng 99 70) o-Xylene 18.71 91 2954052 23.711 ng 99 71) n-Nonane 18.90 43 1461104 24.300 ng 99 72) 1,1,2,2-Tetrachloroethane 18.69 83 1475112 24.742 ng 100 74) Cumene 19.23 105 3691319 23.144 ng 99 75) alpha-Pinene 19.58 93 1922716 24.162 ng 99 76) n-Propylbenzene 19.68 91 4494432 23.232 ng 99 77) 3-Ethyltoluene 19.76 105 3853846 24.490 ng 99 78) 4-Ethyltoluene 19.80 105 3444450 23.787 ng 99 79) 1,3,5-Trimethylbenzene 19.87 105 3085255 24.068 ng 99 80) alpha-Methylstyrene 20.01 118 1688343 24.021 ng 99 81) 2-Ethyltoluene 20.04 105 3583626 23.667 ng 99 82) 1,2,4-Trimethylbenzene 20.23 105 3081603 24.707 ng 99 83) n-Decane 20.32 57 1650995 25.232 ng 98 84) Benzyl Chloride 20.35 91 2771950 28.053 ng 98 85) 1,3-Dichlorobenzene 20.37 146 1952775 25.765 ng 100 86) 1,4-Dichlorobenzene 20.42 146 1907125 24.022 ng 100 87) sec-Butylbenzene 20.47 105 4039556 24.170 ng 99 88) 4-Isopropyltoluene (p-... 20.61 119 3609839 23.177 ng 99 89) 1,2,3-Trimethylbenzene 20.61 105 3127105 24.281 ng 100 90) 1,2-Dichlorobenzene 20.73 146 1839211 25.164 ng 100 91) d-Limonene 20.73 68 1162598 25.132 ng 99 92) 1,2-Dibromo-3-Chloropr... 21.11 157 693228 25.954 ng 97 93) n-Undecane 21.41 57 1727565 26.657 ng 98 94) 1,2,4-Trichlorobenzene 22.23 180 1406848 25.177 ng 100 95) Naphthalene 22.34 128 4267326 24.534 ng 100 96) n-Dodecane 22.33 57 1697679 29.573 ng 98 97) Hexachlorobutadiene 22.66 225 890677 22.693 ng 100 98) Cyclohexanone 18.41 55 1039026 24.014 ng 98 99) tert-Butylbenzene 20.23 119 2925892 23.843 ng 99 100) n-Butylbenzene 20.97 91 3308385 25.484 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Fri Aug 19 09:38:17 2016 Page: 2

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Data File: I:\MS16\DATA\2016_08\18\08181627.D Acq On : 18 Aug 2016 19:58 Operator: LH Sample : LCS2 R16081816_25ng Misc : S29-07291601/S29-08041602 (9/2) ALS Vial : 2 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

1.25e+07

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

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chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

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chlo

roet

hene

,Tn-

Oct

ane,

Tn-

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l Ace

tate

,T1,

2-D

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than

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ne,T

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one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

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than

e,T

trans

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hlor

opro

pene

,T

4-M

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l-2-p

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none

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ne,T

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lpen

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octa

ne),T

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ne,T

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odic

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yl M

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l Eth

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(IS2)

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ne,T

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bon

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ride,

TBe

nzen

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l,TIs

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te,T

1,1,

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(SS1

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HF)

,TC

hlor

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l Ace

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l Eth

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n-H

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e,T

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ochl

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etha

ne (I

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then

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l ter

t-But

yl E

ther

,T1,

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-Dic

hlor

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ene,

T

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hlor

otrif

luor

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e,T

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),TTr

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lein

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e,T

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(CFC

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open

e,T

R16081016.M Fri Aug 19 09:38:17 2016 Page: 3

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3.20 3.30 3.40 3.50 3.60 3.70 3.80 3.90 4.00 4.10 4.20 4.30 4.40 4.50 4.60 4.70 4.80 4.90 5.00 5.10 5.20 5.30

0

500

1000

1500

2000

2500

3000

Time-->


4.280|

|

|

|

|

|| 2d 1


25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130

500000

m/z-->


50 10135 6647 105887042 82 12039 54 74

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130

5000

m/z-->


386044


0.00 0.00 0.00

41.10 151.30 119.89#

39.00 112.00 0.00#

42.10 100 100

Ion Exp% Act%

response 4655

4.280min (+0.082) 0.16ng

(2) Propene (T)

R16081016.M Fri Aug 19 09:37:44 2016 Page: 1

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3.10 3.20 3.30 3.40 3.50 3.60 3.70 3.80 3.90 4.00 4.10 4.20 4.30 4.40 4.50 4.60 4.70 4.80 4.90 5.00 5.10 5.20 5.30

0

200000

400000

600000

800000

Time-->


4.120

|

|

|

|

|

|

|||||

|2d 1


26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69

200000

400000

m/z-->


39 42

403837

4336 44 51 60

26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69

5000

m/z-->


39 42

403837

4336 6044


0.00 0.00 0.00

41.10 151.30 0.81#

39.00 112.00 0.00#

42.10 100 100

Ion Exp% Act%

response 689598

4.120min (-0.077) 23.43ng m

(2) Propene (T)

R16081016.M Tue Aug 23 10:28:03 2016 Page: 1

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lusine.hakobyan

WP

lusine.hakobyan

Lusine

cory.lewis

Cory

Response Factor Report GCMS-16

Method Path : I:\MS16\METHODS\ Method File : R16081016.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Aug 11 09:14:45 2016 Response Via : Initial Calibration

Calibration Files 0.20=08101609.D 0.40=08101617.D 1.0 =08101611.D 5.0 =08101612.D 25 =08101613.D 50 =08101 Compound 0.20 0.40 1.0 5.0 25 50 100 Avg %RSD --------------------------------------------------------------------------------

1) IR Bromochloromethane... ----------------ISTD--------------------- 2) T Propene 1.511 1.268 1.199 1.030 1.141 1.187 1.383 1.245 12.80 3) T Dichlorodifluo... 3.485 3.034 3.105 2.744 2.819 2.705 2.483 2.911 11.26 4) T Chloromethane 2.574 1.791 2.272 1.671 1.813 1.674 1.343 1.877 21.98 5) T 1,2-Dichloro-1... 2.005 1.726 1.772 1.553 1.594 1.517 1.442 1.658 11.53 6) T Vinyl Chloride 2.408 2.121 2.266 2.041 2.150 2.038 1.967 2.142 7.08 7) T 1,3-Butadiene 1.389 1.338 1.365 1.209 1.402 1.349 1.242 1.328 5.56 8) T Bromomethane 1.553 1.369 1.553 1.383 1.269 1.377 1.308 1.402 7.94 9) T Chloroethane 1.019 0.953 0.959 0.859 0.925 0.928 0.952 0.942 5.09 10) T Ethanol 1.043 0.937 0.893 0.785 0.898 0.885 0.826 0.895 9.16 11) T Acetonitrile 2.843 2.532 2.242 1.955 2.111 2.085 2.056 2.261 14.02 12) T Acrolein 0.815 0.749 0.770 0.643 0.733 0.744 0.719 0.739 7.09 13) T Acetone 1.072 0.975 0.901 0.835 0.927 0.875 0.734 0.903 11.81 14) T Trichlorofluor... 2.953 2.585 2.630 2.334 2.442 2.332 2.230 2.501 9.81 15) T 2-Propanol (Is... 4.063 3.134 3.255 2.861 3.120 2.920 2.189 3.077 18.13 16) T Acrylonitrile 1.799 1.643 1.579 1.463 1.668 1.620 1.583 1.622 6.29 17) T 1,1-Dichloroet... 1.302 1.255 1.239 1.129 1.252 1.216 1.225 1.231 4.28 18) T 2-Methyl-2-Pro... 3.544 3.062 3.291 2.782 3.041 2.761 2.033 2.931 16.44 19) T Methylene Chlo... 1.385 1.262 1.277 1.154 1.248 1.248 1.223 1.257 5.52 20) T 3-Chloro-1-pro... 1.769 1.604 1.656 1.420 1.663 1.572 1.516 1.600 7.02 21) T Trichlorotrifl... 1.285 1.131 1.176 1.025 1.114 1.043 1.047 1.117 8.24 22) T Carbon Disulfide 6.211 5.698 5.231 4.548 5.058 4.837 4.642 5.175 11.58 23) T trans-1,2-Dich... 1.983 1.704 1.789 1.644 1.804 1.772 1.735 1.776 5.99 24) T 1,1-Dichloroet... 2.557 2.332 2.357 2.106 2.218 2.182 2.117 2.267 7.08 25) T Methyl tert-Bu... 3.821 3.916 3.444 3.167 2.860 2.188 3.233 20.01 26) T Vinyl Acetate 0.224 0.253 0.241 0.276 0.353 0.323 0.272 0.277 16.49 27) T 2-Butanone (MEK) 0.922 0.852 0.840 0.797 0.910 0.870 0.839 0.862 5.05 28) T cis-1,2-Dichlo... 1.878 1.706 1.758 1.609 1.750 1.653 1.590 1.706 5.86 29) T Diisopropyl Ether 1.414 1.306 1.313 1.204 1.363 1.077 0.871 1.221 15.57 30) T Ethyl Acetate 0.465 0.451 0.473 0.449 0.523 0.473 0.375 0.458 9.66 31) T n-Hexane 2.327 2.120 2.088 1.941 2.184 1.980 1.636 2.040 10.75 32) T Chloroform 2.617 2.304 2.380 2.141 2.266 2.104 1.984 2.256 9.19 33) S 1,2-Dichloroet... 1.529 1.473 1.516 1.493 1.458 1.442 1.412 1.475 2.80 34) T Tetrahydrofura... 1.047 0.845 0.869 0.782 0.844 0.814 0.802 0.858 10.31 35) T Ethyl tert-But... 1.717 1.565 1.589 1.453 1.611 1.534 1.480 1.564 5.63 36) T 1,2-Dichloroet... 1.998 1.761 1.810 1.622 1.687 1.564 1.464 1.701 10.33

37) IR 1,4-Difluorobenzen... ----------------ISTD--------------------- 38) T 1,1,1-Trichlor... 0.496 0.438 0.461 0.408 0.431 0.402 0.373 0.430 9.50 39) T Isopropyl Acetate 0.170 0.159 0.161 0.156 0.182 0.170 0.145 0.163 7.36 40) T 1-Butanol 0.258 0.249 0.247 0.244 0.294 0.269 0.218 0.254 9.23 41) T Benzene 1.427 1.163 1.104 0.963 1.055 0.977 0.793 1.069 18.51 42) T Carbon Tetrach... 0.416 0.372 0.391 0.355 0.381 0.360 0.340 0.373 6.77 43) T Cyclohexane 0.464 0.409 0.425 0.386 0.422 0.408 0.344 0.408 9.04 44) T tert-Amyl Meth... 0.827 0.771 0.781 0.724 0.810 0.764 0.715 0.770 5.34 45) T 1,2-Dichloropr... 0.304 0.264 0.267 0.246 0.270 0.260 0.251 0.266 7.06 46) T Bromodichlorom... 0.415 0.376 0.389 0.362 0.394 0.375 0.348 0.380 5.73 47) T Trichloroethene 0.369 0.338 0.334 0.299 0.324 0.306 0.294 0.323 8.10 48) T 1,4-Dioxane 0.235 0.218 0.223 0.206 0.225 0.223 0.213 0.220 4.24 49) T 2,2,4-Trimethy... 1.210 1.116 1.123 1.036 1.125 1.049 0.946 1.086 7.75 50) T Methyl Methacr... 0.126 0.113 0.118 0.113 0.129 0.124 0.110 0.119 6.28 51) T n-Heptane 0.295 0.267 0.262 0.247 0.274 0.258 0.238 0.263 7.08 52) T cis-1,3-Dichlo... 0.456 0.417 0.425 0.408 0.463 0.446 0.424 0.434 4.88 53) T 4-Methyl-2-pen... 0.248 0.231 0.239 0.229 0.255 0.248 0.232 0.240 4.25 54) T trans-1,3-Dich... 0.385 0.372 0.377 0.367 0.419 0.407 0.390 0.388 4.87 55) T 1,1,2-Trichlor... 0.305 0.274 0.277 0.254 0.276 0.267 0.255 0.272 6.29

65 of 105

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Lusine

56) IR Chlorobenzene-d5 (... ----------------ISTD--------------------- 57) S Toluene-d8 (SS2) 2.525 2.506 2.481 2.499 2.495 2.446 2.460 2.487 1.10 58) T Toluene 3.455 3.051 2.884 2.618 2.823 2.578 2.319 2.818 13.05 59) T 2-Hexanone 1.525 1.420 1.446 1.326 1.432 1.293 1.158 1.371 8.88 60) T Dibromochlorom... 0.872 0.805 0.806 0.756 0.838 0.789 0.759 0.803 5.17 61) T 1,2-Dibromoethane 0.853 0.808 0.782 0.740 0.806 0.759 0.724 0.782 5.68 62) T n-Butyl Acetate 1.585 1.544 1.546 1.452 1.589 1.450 1.319 1.498 6.48 63) T n-Octane 0.632 0.589 0.558 0.524 0.594 0.550 0.501 0.564 7.91 64) T Tetrachloroethene 1.014 0.926 0.906 0.829 0.902 0.842 0.797 0.888 8.17 65) T Chlorobenzene 2.156 1.986 1.914 1.748 1.899 1.776 1.639 1.874 9.11 66) T Ethylbenzene 3.583 3.332 3.255 2.981 3.266 2.964 2.542 3.132 10.71 67) T m- & p-Xylenes 2.858 2.692 2.581 2.407 2.673 2.266 1.890 2.481 13.11 68) T Bromoform 0.775 0.726 0.732 0.742 0.850 0.782 0.727 0.762 5.92 69) T Styrene 2.069 1.941 1.976 1.913 2.116 1.891 1.653 1.937 7.71 70) T o-Xylene 2.910 2.682 2.686 2.539 2.714 2.397 1.997 2.561 11.51 71) T n-Nonane 1.423 1.270 1.317 1.251 1.320 1.143 0.927 1.236 12.95 72) T 1,1,2,2-Tetrac... 1.230 1.214 1.236 1.222 1.380 1.242 1.054 1.225 7.72 73) S Bromofluoroben... 0.866 0.865 0.879 0.903 0.909 0.895 0.899 0.888 2.02 74) T Cumene 3.652 3.432 3.481 3.260 3.502 3.073 2.548 3.278 11.35 75) T alpha-Pinene 1.751 1.680 1.667 1.617 1.780 1.591 1.364 1.636 8.39 76) T n-Propylbenzene 4.378 4.347 4.225 4.001 4.278 3.682 2.922 3.976 13.19 77) T 3-Ethyltoluene 3.699 3.402 3.282 3.163 3.555 2.996 2.544 3.234 11.88 78) T 4-Ethyltoluene 3.109 3.006 3.303 3.194 3.220 2.827 2.174 2.976 13.00 79) T 1,3,5-Trimethy... 2.916 2.740 2.756 2.677 2.855 2.466 2.033 2.635 11.44 80) T alpha-Methylst... 1.407 1.389 1.503 1.503 1.653 1.443 1.214 1.445 9.28 81) T 2-Ethyltoluene 3.555 3.274 3.302 3.175 3.327 2.847 2.305 3.112 13.32 82) T 1,2,4-Trimethy... 2.837 2.733 2.822 2.746 2.848 2.276 1.684 2.564 17.01 83) T n-Decane 1.387 1.320 1.413 1.431 1.544 1.305 1.013 1.345 12.35 84) T Benzyl Chloride 1.642 1.856 2.184 2.532 2.208 1.763 2.031 16.48 85) T 1,3-Dichlorobe... 1.608 1.598 1.633 1.611 1.722 1.492 1.240 1.558 9.99 86) T 1,4-Dichlorobe... 1.705 1.717 1.701 1.650 1.755 1.556 1.338 1.632 8.84 87) T sec-Butylbenzene 3.845 3.614 3.695 3.576 3.712 3.135 2.470 3.435 13.99 88) T 4-Isopropyltol... 3.675 3.397 3.592 3.506 3.534 2.737 1.969 3.201 19.56 89) T 1,2,3-Trimethy... 2.975 2.842 2.913 2.858 2.932 2.314 1.696 2.647 17.97 90) T 1,2-Dichlorobe... 1.609 1.593 1.617 1.589 1.659 1.385 1.064 1.502 14.14 91) T d-Limonene 1.000 0.941 1.027 1.053 1.113 0.884 0.637 0.951 16.55 92) T 1,2-Dibromo-3-... 0.398 0.542 0.507 0.566 0.656 0.609 0.566 0.549 14.88 93) T n-Undecane 1.216 1.166 1.436 1.435 1.602 1.384 1.085 1.332 13.66 94) T 1,2,4-Trichlor... 0.928 1.239 1.147 1.137 1.287 1.202 1.100 1.148 10.14 95) T Naphthalene 2.693 4.892 3.508 3.686 4.135 3.486 2.625 3.575 22.12 96) T n-Dodecane 0.726 1.310 1.358 1.526 1.251 0.909 1.180 25.51 97) T Hexachlorobuta... 0.796 1.045 0.783 0.735 0.818 0.771 0.700 0.807 13.91 98) T Cyclohexanone 0.930 0.899 0.898 0.857 0.966 0.879 0.796 0.889 6.08 99) T tert-Butylbenzene 2.894 2.714 2.783 2.691 2.749 2.185 1.639 2.522 17.85 100) T n-Butylbenzene 2.795 2.766 2.887 2.813 2.938 2.497 1.982 2.668 12.50 ---------------------------------------------------------------------------- (#) = Out of Range

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1ng/L Std. ID:4ng/L Std. ID: S29-08051608

20ng/L Std. ID: S29-08051605200ng/L Std. ID: S29-08051601

Dilution Factors: 5 50 250 1000 0 0 4 4 20 20 200 200 200

Source Std. Injection (L): NA NA 0.050 0.100 0.050 0.25 0.125 0.25 0.50Compounds mg/m3 200ng/L 20ng/L 4ng/L 1ng/L ICAL Points: 0.08ng 0.1ng 0.2ng 0.4ng 1ng 5ng 25ng 50ng 100ngPropene 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 103Dichlorodifluoromethane 1.00 200 20.0 4.00 1.00 NA NA 0.200 0.400 1.00 5.00 25.00 50.0 100Chloromethane 0.98 196 19.6 3.92 0.98 NA NA 0.196 0.392 0.98 4.90 24.50 49.0 98Freon-114 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 103Vinyl Chloride 1.00 200 20.0 4.00 1.00 NA NA 0.200 0.400 1.00 5.00 25.00 50.0 1001,3-Butadiene 1.06 212 21.2 4.24 1.06 NA NA 0.212 0.424 1.06 5.30 26.50 53.0 106Bromomethane 1.00 200 20.0 4.00 1.00 NA NA 0.200 0.400 1.00 5.00 25.00 50.0 100Chloroethane 1.01 202 20.2 4.04 1.01 NA NA 0.202 0.404 1.01 5.05 25.25 50.5 101Ethanol 5.06 1012 101.2 20.24 5.06 NA NA 1.012 2.024 5.06 25.30 126.50 253.0 506Acetonitrile 1.02 204 20.4 4.08 1.02 NA NA 0.204 0.408 1.02 5.10 25.50 51.0 102Acrolein 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107Acetone 5.37 1074 107.4 21.48 5.37 NA NA 1.074 2.148 5.37 26.85 134.25 268.5 537Trichlorofluoromethane 0.99 198 19.8 3.96 0.99 NA NA 0.198 0.396 0.99 4.95 24.75 49.5 99Isopropanol 2.09 418 41.8 8.36 2.09 NA NA 0.418 0.836 2.09 10.45 52.25 104.5 209Acrylonitrile 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 1031,1-Dichloroethene 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107tert-Butanol 2.09 418 41.8 8.36 2.09 NA NA 0.418 0.836 2.09 10.45 52.25 104.5 209Methylene Chloride 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108Allyl Chloride 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108Trichlorotrifluoroethane 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108Carbon Disulfide 0.98 196 19.6 3.92 0.98 NA NA 0.196 0.392 0.98 4.90 24.50 49.0 98trans-1,2-Dichloroethene 1.06 212 21.2 4.24 1.06 NA NA 0.212 0.424 1.06 5.30 26.50 53.0 1061,1-Dichloroethane 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 104Methyl tert-Butyl Ether 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 105Vinyl Acetate 5.07 1014 101.4 20.28 5.07 NA NA 1.014 2.028 5.07 25.35 126.75 253.5 5072-Butanone 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107cis-1,2-Dichloroethene 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107Diisopropyl Ether 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108Ethyl Acetate 2.12 424 42.4 8.48 2.12 NA NA 0.424 0.848 2.12 10.60 53.00 106.0 212n-Hexane 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 104Chloroform 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107Tetrahydrofuran 1.02 204 20.4 4.08 1.02 NA NA 0.204 0.408 1.02 5.10 25.50 51.0 102Ethyl tert-Butyl Ether 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 1051,2-Dichloroethane 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 1051,1,1-Trichloroethane 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 103Isopropyl Acetate 2.21 442 44.2 8.84 2.21 NA NA 0.442 0.884 2.21 11.05 55.25 110.5 2211-Butanol 2.26 452 45.2 9.04 2.26 NA NA 0.452 0.904 2.26 11.30 56.50 113.0 226Benzene 1.11 222 22.2 4.44 1.11 NA NA 0.222 0.444 1.11 5.55 27.75 55.5 111Carbon Tetrachloride 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108Cyclohexane 2.09 418 41.8 8.36 2.09 NA NA 0.418 0.836 2.09 10.45 52.25 104.5 209tert-Amyl Methyl Ether 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dichloropropane 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 105Bromodichloromethane 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107Trichloroethene 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 1031,4-Dioxane 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108Isooctane 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 103Methyl Methacrylate 2.08 416 41.6 8.32 2.08 NA NA 0.416 0.832 2.08 10.40 52.00 104.0 208n-Heptane 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107

Primary Source Standards Concentrations (Working & Initial Calibration)

Working STD Conc.(ng/L):

Primary Working Standards

Q:\TO15 Std. Concentrations\MS16 Std. Conc\2016\R16081016\ICAL Conc. (Primary Source)

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Source Std. Injection (L): NA NA 0.050 0.100 0.050 0.25 0.125 0.25 0.50Compounds mg/m3 200ng/L 20ng/L 4ng/L 1ng/L ICAL Points: 0.08ng 0.1ng 0.2ng 0.4ng 1ng 5ng 25ng 50ng 100ng




cis-1,3-Dichloropropene 1.12 224 22.4 4.48 1.12 NA NA 0.224 0.448 1.12 5.60 28.00 56.0 112



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Source Std. Injection (L): NA NA 0.050 0.100 0.050 0.25 0.125 0.25 0.50Compounds mg/m3 200ng/L 20ng/L 4ng/L 1ng/L ICAL Points: 0.08ng 0.1ng 0.2ng 0.4ng 1ng 5ng 25ng 50ng 100ng




4-Methyl-2-pentanone 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108trans-1,3-Dichloropropene 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 1071,1,2-Trichloroethane 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 105Toluene 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 1052-Hexanone 1.11 222 22.2 4.44 1.11 NA NA 0.222 0.444 1.11 5.55 27.75 55.5 111Dibromochloromethane 1.10 220 22.0 4.40 1.10 NA NA 0.220 0.440 1.10 5.50 27.50 55.0 1101,2-Dibromoethane 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107n-Butyl Acetate 1.11 222 22.2 4.44 1.11 NA NA 0.222 0.444 1.11 5.55 27.75 55.5 111n-Octane 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 103Tetrachloroethene 0.99 198 19.8 3.96 0.99 NA NA 0.198 0.396 0.99 4.95 24.75 49.5 99Chlorobenzene 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107Ethylbenzene 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 105m-&p-Xylene 2.08 416 41.6 8.32 2.08 NA NA 0.416 0.832 2.08 10.40 52.00 104.0 208Bromoform 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107Styrene 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108o-Xylene 1.02 204 20.4 4.08 1.02 NA NA 0.204 0.408 1.02 5.10 25.50 51.0 102n-Nonane 1.01 202 20.2 4.04 1.01 NA NA 0.202 0.404 1.01 5.05 25.25 50.5 1011,1,2,2-Tetrachloroethane 1.00 200 20.0 4.00 1.00 NA NA 0.200 0.400 1.00 5.00 25.00 50.0 100Cumene 1.01 202 20.2 4.04 1.01 NA NA 0.202 0.404 1.01 5.05 25.25 50.5 101alpha-Pinene 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 103n-Propylbenzene 1.00 200 20.0 4.00 1.00 NA NA 0.200 0.400 1.00 5.00 25.00 50.0 1003-Ethyltoluene 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 1044-Ethyltoluene 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 1051,3,5-Trimethylbenzene 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 104alpha-Methylstyrene 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 1032-Ethyltoluene 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 1041,2,4-Trimethylbenzene 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 104n-Decane 1.01 202 20.2 4.04 1.01 NA NA 0.202 0.404 1.01 5.05 25.25 50.5 101Benzyl Chloride 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 1081,3-Dichlorobenzene 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 1081,4-Dichlorobenzene 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 105sec-Butylbenzene 1.06 212 21.2 4.24 1.06 NA NA 0.212 0.424 1.06 5.30 26.50 53.0 106p-Isopropyltoluene 1.00 200 20.0 4.00 1.00 NA NA 0.200 0.400 1.00 5.00 25.00 50.0 1001,2,3-Trimethylbenzene 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dichlorobenzene 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107d-Limonene 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dibromo-3-chloropropane 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 104n-Undecane 1.01 202 20.2 4.04 1.01 NA NA 0.202 0.404 1.01 5.05 25.25 50.5 1011,2,4-Trichlorobenzene 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 104Naphthalene 1.00 200 20.0 4.00 1.00 NA NA 0.200 0.400 1.00 5.00 25.00 50.0 100n-Dodecane 1.04 208 20.8 4.16 1.04 NA NA 0.208 0.416 1.04 5.20 26.00 52.0 104Hexachloro-1,3-butadiene 1.07 214 21.4 4.28 1.07 NA NA 0.214 0.428 1.07 5.35 26.75 53.5 107Methacrylonitrile 1.03 206 20.6 4.12 1.03 NA NA 0.206 0.412 1.03 5.15 25.75 51.5 103Cyclohexanone 1.12 224 22.4 4.48 1.12 NA NA 0.224 0.448 1.12 5.60 28.00 56.0 112tert-Butylbenzene 1.05 210 21.0 4.20 1.05 NA NA 0.210 0.420 1.05 5.25 26.25 52.5 105n-Butylbenzene 1.08 216 21.6 4.32 1.08 NA NA 0.216 0.432 1.08 5.40 27.00 54.0 108



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Calibration Status Report GCMS-16

Method : I:\MS16\METHODS\R16081016.M (RTE Integrator) Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration

# ID Conc ISTD Path\File Conc -- ---- ---- ---- ------------------------------------------------- 3 0.20 0 13 I:\MS16\DATA\2016_08\10\08101609.D 4 0.40 0 13 I:\MS16\DATA\2016_08\10\08101617.D 5 1.0 1 13 I:\MS16\DATA\2016_08\10\08101611.D 6 5.0 5 13 I:\MS16\DATA\2016_08\10\08101612.D 7 25 27 13 I:\MS16\DATA\2016_08\10\08101613.D

# ID Update Time Quant Time Acquisition Time -- -- -------------------- ----------------- --------------------- 3 0.20 Aug 11 07:40 2016 Aug 11 07:35 2016 10 Aug 2016 15:56 4 0.40 Aug 11 08:53 2016 Aug 11 08:52 2016 11 Aug 2016 8:07 5 1.0 Aug 11 07:40 2016 Aug 11 07:35 2016 10 Aug 2016 17:02 6 5.0 Aug 11 07:40 2016 Aug 11 07:35 2016 10 Aug 2016 17:35 7 25 Aug 11 07:40 2016 Aug 11 07:35 2016 10 Aug 2016 18:08

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Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101609.D Acq On : 10 Aug 2016 15:56 Operator: LH Sample : 0.2ng TO-15 ICAL STD Misc : S29-07291601/S29-08051608 (9/3) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Aug 11 07:35:47 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 227678 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 13.41 114 1106452 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 17.72 82 443018 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 348065 12.706 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.68% 57) Toluene-d8 (SS2) 15.87 98 1118539 12.889 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 103.12% 73) Bromofluorobenzene (SS3) 19.10 174 383718 12.323 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.56% Target Compounds Qvalue 2) Propene 4.20 42 5668 0.258 ng 96 3) Dichlorodifluoromethan... 4.35 85 12695 0.240 ng 96 4) Chloromethane 4.68 50 9189 0.259 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.90 135 7522 0.237 ng 100 6) Vinyl Chloride 5.09 62 8771 0.213 ng 96 7) 1,3-Butadiene 5.36 54 5362 0.222 ng # 86 8) Bromomethane 5.80 94 5657 0.217 ng 100 9) Chloroethane 6.12 64 3750 0.216 ng 89 10) Ethanol 6.46 45 19220 1.066 ng 94 11) Acetonitrile 6.80 41 10565 0.261 ng 76 12) Acrolein 6.97 56 3177 0.213 ng 98 13) Acetone 7.13 58 20963 1.179 ng # 67 14) Trichlorofluoromethane 7.38 101 10648 0.221 ng 98 15) 2-Propanol (Isopropanol) 7.60 45 30932 0.522 ng 87 16) Acrylonitrile 7.94 53 6750 0.204 ng 92 17) 1,1-Dichloroethene 8.35 96 5074 0.217 ng 94 18) 2-Methyl-2-Propanol (t... 8.50 59 26984 0.456 ng 93 19) Methylene Chloride 8.56 84 5450 0.220 ng 95 20) 3-Chloro-1-propene (Al... 8.73 41 6959 0.235 ng 88 21) Trichlorotrifluoroethane 8.99 151 5057 0.232 ng 97 22) Carbon Disulfide 8.87 76 22173 0.236 ng 95 23) trans-1,2-Dichloroethene 9.85 61 7657 0.220 ng 97 24) 1,1-Dichloroethane 10.09 63 9686 0.221 ng 98 25) Methyl tert-Butyl Ether 10.20 73 16572 0.243 ng 98 26) Vinyl Acetate 10.35 86 4135 0.851 ng # 28 27) 2-Butanone (MEK) 10.60 72 3595 0.222 ng # 82 28) cis-1,2-Dichloroethene 11.10 61 7321 0.217 ng 99 29) Diisopropyl Ether 11.41 87 5564 0.240 ng # 82 30) Ethyl Acetate 11.42 61 3588 0.415 ng 100 31) n-Hexane 11.40 57 8817 0.223 ng 99 32) Chloroform 11.44 83 10199 0.233 ng 99 34) Tetrahydrofuran (THF) 11.88 72 3889 0.253 ng 93 35) Ethyl tert-Butyl Ether 12.01 87 6568 0.219 ng 95 36) 1,2-Dichloroethane 12.25 62 7644 0.227 ng 97 38) 1,1,1-Trichloroethane 12.53 97 9051 0.223 ng 98 39) Isopropyl Acetate 12.97 61 6668 0.435 ng # 75 40) 1-Butanol 13.00 56 10312 0.434 ng # 75 41) Benzene 13.02 78 28048 0.261 ng 100 42) Carbon Tetrachloride 13.18 117 7952 0.227 ng 99 43) Cyclohexane 13.31 84 17150 0.444 ng 100 44) tert-Amyl Methyl Ether 13.66 73 15217 0.213 ng 94 45) 1,2-Dichloropropane 13.87 63 5647 0.227 ng 92 46) Bromodichloromethane 14.06 83 7854 0.221 ng 100 47) Trichloroethene 14.12 130 6720 0.206 ng 99 48) 1,4-Dioxane 14.10 88 4492 0.217 ng 100 49) 2,2,4-Trimethylpentane... 14.18 57 22057 0.215 ng 93

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lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101609.D Acq On : 10 Aug 2016 15:56 Operator: LH Sample : 0.2ng TO-15 ICAL STD Misc : S29-07291601/S29-08051608 (9/3) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Aug 11 07:35:47 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 4648 0.428 ng 99 51) n-Heptane 14.45 71 5591 0.227 ng 100 52) cis-1,3-Dichloropropene 14.99 75 9051 0.224 ng 99 53) 4-Methyl-2-pentanone 15.02 58 4736 0.210 ng 86 54) trans-1,3-Dichloropropene 15.51 75 7285 0.206 ng 99 55) 1,1,2-Trichloroethane 15.67 97 5661 0.221 ng 100 58) Toluene 15.97 91 25718 0.267 ng 98 59) 2-Hexanone 16.22 43 11997 0.232 ng 87 60) Dibromochloromethane 16.37 129 6798 0.232 ng 95 61) 1,2-Dibromoethane 16.63 107 6467 0.225 ng 96 62) n-Butyl Acetate 16.84 43 12467 0.220 ng 93 63) n-Octane 16.97 57 4617 0.212 ng 98 64) Tetrachloroethene 17.11 166 7113 0.220 ng 98 65) Chlorobenzene 17.77 112 16354 0.234 ng 98 66) Ethylbenzene 18.12 91 26665 0.227 ng 99 67) m- & p-Xylenes 18.29 91 42135 0.464 ng 99 68) Bromoform 18.35 173 5875 0.218 ng 99 69) Styrene 18.60 104 15837 0.225 ng 98 70) o-Xylene 18.71 91 21039 0.221 ng 98 71) n-Nonane 18.90 43 10186 0.218 ng 92 72) 1,1,2,2-Tetrachloroethane 18.69 83 8718 0.215 ng 99 74) Cumene 19.23 105 26148 0.212 ng 97 75) alpha-Pinene 19.58 93 12781 0.218 ng # 50 76) n-Propylbenzene 19.68 91 31032 0.217 ng 97 77) 3-Ethyltoluene 19.76 105 27265 0.226 ng 97 78) 4-Ethyltoluene 19.80 105 23139 0.215 ng 99 79) 1,3,5-Trimethylbenzene 19.87 105 21499 0.213 ng 96 80) alpha-Methylstyrene 20.00 118 10276 0.208 ng 97 81) 2-Ethyltoluene 20.04 105 26210 0.237 ng 95 82) 1,2,4-Trimethylbenzene 20.23 105 20917 0.215 ng 97 83) n-Decane 20.32 57 9931 0.204 ng 96 84) Benzyl Chloride 20.35 91 11520 0.170 ng 90 85) 1,3-Dichlorobenzene 20.36 146 12306 0.232 ng 100 86) 1,4-Dichlorobenzene 20.42 146 12693 0.209 ng 100 87) sec-Butylbenzene 20.47 105 28891 0.233 ng 96 88) 4-Isopropyltoluene (p-... 20.61 119 26049 0.220 ng 96 89) 1,2,3-Trimethylbenzene 20.61 105 21929 0.222 ng 98 90) 1,2-Dichlorobenzene 20.73 146 12202 0.226 ng 97 91) d-Limonene 20.73 68 7372 0.220 ng 99 92) 1,2-Dibromo-3-Chloropr... 21.12 157 2937 0.162 ng # 66 93) n-Undecane 21.43 57 8707 0.188 ng 91 94) 1,2,4-Trichlorobenzene 22.26 180 6839 0.179 ng 98 95) Naphthalene 22.38 128 19091 0.172 ng 94 96) n-Dodecane 22.36 57 4776 0.116 ng 93 97) Hexachlorobutadiene 22.66 225 6038 0.215 ng 100 98) Cyclohexanone 18.42 55 7384 0.223 ng 93 99) tert-Butylbenzene 20.23 119 21540 0.235 ng 96 100) n-Butylbenzene 20.98 91 21393 0.227 ng 92 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Thu Aug 11 07:37:45 2016 Page: 2

72 of 105


Data File: I:\MS16\DATA\2016_08\10\08101609.D Acq On : 10 Aug 2016 15:56 Operator: LH Sample : 0.2ng TO-15 ICAL STD Misc : S29-07291601/S29-08051608 (9/3) ALS Vial : 5 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R16081016.M Thu Aug 11 07:37:45 2016 Page: 3

73 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101617.D Acq On : 11 Aug 2016 8:07 Operator: LH Sample : 0.4ng TO-15 ICAL STD Misc : S29-07291601/S29-08051608 (9/3) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Aug 11 08:52:44 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:41:13 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 242991 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 13.41 114 1166078 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 17.72 82 456100 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 357820 12.339 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.72% 57) Toluene-d8 (SS2) 15.87 98 1143017 12.568 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.56% 73) Bromofluorobenzene (SS3) 19.11 174 394497 12.229 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.84% Target Compounds Qvalue 2) Propene 4.20 42 10154 0.351 ng 95 3) Dichlorodifluoromethan... 4.35 85 23591 0.351 ng 99 4) Chloromethane 4.68 50 13645 0.292 ng 98 5) 1,2-Dichloro-1,1,2,2-t... 4.89 135 13827 0.357 ng 97 6) Vinyl Chloride 5.09 62 16489 0.338 ng 99 7) 1,3-Butadiene 5.35 54 11030 0.381 ng 100 8) Bromomethane 5.79 94 10642 0.343 ng 98 9) Chloroethane 6.12 64 7484 0.367 ng 92 10) Ethanol 6.44 45 36852 1.796 ng 98 11) Acetonitrile 6.79 41 20085 0.367 ng 86 12) Acrolein 6.93 56 6231 0.369 ng 99 13) Acetone 7.12 58 40710 1.921 ng # 83 14) Trichlorofluoromethane 7.38 101 19902 0.344 ng 99 15) 2-Propanol (Isopropanol) 7.60 45 50935 0.663 ng 92 16) Acrylonitrile 7.92 53 13158 0.361 ng 100 17) 1,1-Dichloroethene 8.35 96 10442 0.381 ng 99 18) 2-Methyl-2-Propanol (t... 8.49 59 49763 0.725 ng 97 19) Methylene Chloride 8.56 84 10594 0.369 ng 99 20) 3-Chloro-1-propene (Al... 8.73 41 13469 0.369 ng 93 21) Trichlorotrifluoroethane 8.99 151 9497 0.371 ng 99 22) Carbon Disulfide 8.87 76 43422 0.355 ng 98 23) trans-1,2-Dichloroethene 9.84 61 14043 0.350 ng 98 24) 1,1-Dichloroethane 10.09 63 18857 0.366 ng 98 25) Methyl tert-Butyl Ether 10.20 73 31199 0.386 ng 98 26) Vinyl Acetate 10.35 86 9967 1.791 ng # 67 27) 2-Butanone (MEK) 10.60 72 7092 0.364 ng # 75 28) cis-1,2-Dichloroethene 11.10 61 14196 0.365 ng 100 29) Diisopropyl Ether 11.41 87 10970 0.393 ng # 89 30) Ethyl Acetate 11.41 61 7441 0.738 ng 98 31) n-Hexane 11.40 57 17146 0.368 ng 100 32) Chloroform 11.45 83 19169 0.368 ng 100 34) Tetrahydrofuran (THF) 11.87 72 6699 0.321 ng 96 35) Ethyl tert-Butyl Ether 12.01 87 12777 0.365 ng 97 36) 1,2-Dichloroethane 12.25 62 14380 0.363 ng 99 38) 1,1,1-Trichloroethane 12.53 97 16828 0.353 ng 99 39) Isopropyl Acetate 12.97 61 13150 0.756 ng # 82 40) 1-Butanol 13.00 56 20978 0.770 ng 84 41) Benzene 13.02 78 48190 0.370 ng 99 42) Carbon Tetrachloride 13.18 117 14991 0.367 ng 99 43) Cyclohexane 13.31 84 31860 0.712 ng 99 44) tert-Amyl Methyl Ether 13.66 73 29913 0.361 ng 97 45) 1,2-Dichloropropane 13.87 63 10348 0.358 ng 98 46) Bromodichloromethane 14.06 83 15029 0.362 ng 100 47) Trichloroethene 14.12 130 12986 0.360 ng 100 48) 1,4-Dioxane 14.10 88 8774 0.367 ng 99 49) 2,2,4-Trimethylpentane... 14.18 57 42887 0.362 ng 96

R16081016.M Thu Aug 11 08:53:00 2016 Page: 1

74 of 105

lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101617.D Acq On : 11 Aug 2016 8:07 Operator: LH Sample : 0.4ng TO-15 ICAL STD Misc : S29-07291601/S29-08051608 (9/3) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Aug 11 08:52:44 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:41:13 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 8746 0.686 ng 97 51) n-Heptane 14.45 71 10679 0.376 ng 98 52) cis-1,3-Dichloropropene 14.98 75 17408 0.375 ng 98 53) 4-Methyl-2-pentanone 15.02 58 9302 0.366 ng # 76 54) trans-1,3-Dichloropropene 15.50 75 14846 0.366 ng 99 55) 1,1,2-Trichloroethane 15.68 97 10748 0.365 ng 99 58) Toluene 15.97 91 46759 0.372 ng 99 59) 2-Hexanone 16.22 43 22997 0.390 ng 91 60) Dibromochloromethane 16.38 129 12917 0.383 ng 99 61) 1,2-Dibromoethane 16.63 107 12626 0.379 ng 100 62) n-Butyl Acetate 16.85 43 25007 0.395 ng 95 63) n-Octane 16.97 57 8848 0.372 ng 96 64) Tetrachloroethene 17.11 166 13375 0.351 ng 100 65) Chlorobenzene 17.77 112 31019 0.381 ng 100 66) Ethylbenzene 18.12 91 51066 0.380 ng 99 67) m- & p-Xylenes 18.29 91 81716 0.754 ng 99 68) Bromoform 18.35 173 11334 0.363 ng 99 69) Styrene 18.60 104 30588 0.375 ng 98 70) o-Xylene 18.71 91 39920 0.362 ng 100 71) n-Nonane 18.90 43 18723 0.353 ng 98 72) 1,1,2,2-Tetrachloroethane 18.69 83 17719 0.354 ng 98 74) Cumene 19.23 105 50588 0.361 ng 99 75) alpha-Pinene 19.58 93 25251 0.373 ng 76 76) n-Propylbenzene 19.68 91 63452 0.377 ng 97 77) 3-Ethyltoluene 19.77 105 51637 0.374 ng 98 78) 4-Ethyltoluene 19.80 105 46072 0.360 ng 99 79) 1,3,5-Trimethylbenzene 19.87 105 41594 0.371 ng 98 80) alpha-Methylstyrene 20.01 118 20877 0.356 ng 98 81) 2-Ethyltoluene 20.04 105 49699 0.372 ng 97 82) 1,2,4-Trimethylbenzene 20.23 105 41478 0.374 ng 97 83) n-Decane 20.32 57 19464 0.347 ng 98 84) Benzyl Chloride 20.35 91 25878 0.358 ng 96 85) 1,3-Dichlorobenzene 20.37 146 25191 0.392 ng 100 86) 1,4-Dichlorobenzene 20.42 146 26314 0.383 ng 99 87) sec-Butylbenzene 20.47 105 55908 0.383 ng 97 88) 4-Isopropyltoluene (p-... 20.61 119 49573 0.359 ng 98 89) 1,2,3-Trimethylbenzene 20.61 105 43137 0.380 ng 98 90) 1,2-Dichlorobenzene 20.73 146 24878 0.392 ng 99 91) d-Limonene 20.73 68 14289 0.361 ng 99 92) 1,2-Dibromo-3-Chloropr... 21.11 157 8223 0.407 ng # 79 93) n-Undecane 21.43 57 17185 0.306 ng 93 94) 1,2,4-Trichlorobenzene 22.25 180 18802 0.419 ng 99 95) Naphthalene 22.36 128 71394 0.533 ng 98 96) n-Dodecane 22.35 57 11016 0.253 ng 96 97) Hexachlorobutadiene 22.66 225 16323 0.509 ng 98 98) Cyclohexanone 18.42 55 14696 0.392 ng 97 99) tert-Butylbenzene 20.23 119 41594 0.384 ng 99 100) n-Butylbenzene 20.97 91 43603 0.389 ng 94 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Thu Aug 11 08:53:00 2016 Page: 2

75 of 105




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T1

,2,4

-Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R16081016.M Thu Aug 11 08:53:00 2016 Page: 3

76 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101611.D Acq On : 10 Aug 2016 17:02 Operator: LH Sample : 1.0ng TO-15 ICAL STD Misc : S29-07291601/S29-08051605 (9/3) ALS Vial : 6 Sample Multiplier: 1 Quant Time: Aug 11 07:35:51 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.28 130 228601 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 13.41 114 1091935 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 443816 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 346454 12.597 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.80% 57) Toluene-d8 (SS2) 15.87 98 1101015 12.664 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.28% 73) Bromofluorobenzene (SS3) 19.11 174 389948 12.501 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.00% Target Compounds Qvalue 2) Propene 4.18 42 22576 1.022 ng 94 3) Dichlorodifluoromethan... 4.33 85 56784 1.070 ng 99 4) Chloromethane 4.63 50 40713 1.141 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.87 135 33373 1.048 ng 100 6) Vinyl Chloride 5.05 62 41443 1.001 ng 100 7) 1,3-Butadiene 5.32 54 26462 1.090 ng 98 8) Bromomethane 5.77 94 28402 1.086 ng 100 9) Chloroethane 6.09 64 17711 1.014 ng 97 10) Ethanol 6.42 45 82655 4.566 ng 99 11) Acetonitrile 6.75 41 41826 1.028 ng 91 12) Acrolein 6.92 56 15059 1.008 ng 90 13) Acetone 7.11 58 88517 4.960 ng # 73 14) Trichlorofluoromethane 7.37 101 47625 0.983 ng 99 15) 2-Propanol (Isopropanol) 7.59 45 124401 2.091 ng 91 16) Acrylonitrile 7.89 53 29739 0.897 ng 100 17) 1,1-Dichloroethene 8.34 96 24253 1.034 ng 96 18) 2-Methyl-2-Propanol (t... 8.48 59 125804 2.115 ng 96 19) Methylene Chloride 8.56 84 25232 1.014 ng 99 20) 3-Chloro-1-propene (Al... 8.72 41 32705 1.098 ng 93 21) Trichlorotrifluoroethane 8.98 151 23233 1.062 ng 100 22) Carbon Disulfide 8.85 76 93759 0.992 ng 98 23) trans-1,2-Dichloroethene 9.84 61 34683 0.993 ng 100 24) 1,1-Dichloroethane 10.08 63 44837 1.018 ng 100 25) Methyl tert-Butyl Ether 10.19 73 75196 1.097 ng 98 26) Vinyl Acetate 10.34 86 22362 4.584 ng # 58 27) 2-Butanone (MEK) 10.59 72 16445 1.009 ng # 87 28) cis-1,2-Dichloroethene 11.10 61 34406 1.017 ng 99 29) Diisopropyl Ether 11.41 87 25927 1.113 ng # 86 30) Ethyl Acetate 11.41 61 18354 2.113 ng 99 31) n-Hexane 11.40 57 39722 0.999 ng 99 32) Chloroform 11.44 83 46568 1.058 ng 99 34) Tetrahydrofuran (THF) 11.86 72 16212 1.049 ng 99 35) Ethyl tert-Butyl Ether 12.00 87 30504 1.014 ng 97 36) 1,2-Dichloroethane 12.26 62 34760 1.027 ng 99 38) 1,1,1-Trichloroethane 12.53 97 41520 1.036 ng 100 39) Isopropyl Acetate 12.97 61 31117 2.059 ng # 76 40) 1-Butanol 12.98 56 48794 2.079 ng 80 41) Benzene 13.02 78 107076 1.010 ng 100 42) Carbon Tetrachloride 13.18 117 36848 1.067 ng 100 43) Cyclohexane 13.31 84 77503 2.033 ng 99 44) tert-Amyl Methyl Ether 13.66 73 70963 1.006 ng 97 45) 1,2-Dichloropropane 13.87 63 24485 0.996 ng 99 46) Bromodichloromethane 14.06 83 36365 1.036 ng 99 47) Trichloroethene 14.11 130 30087 0.937 ng 99 48) 1,4-Dioxane 14.09 88 21028 1.031 ng 100 49) 2,2,4-Trimethylpentane... 14.18 57 101059 0.997 ng 94

R16081016.M Thu Aug 11 07:38:31 2016 Page: 1

77 of 105

lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101611.D Acq On : 10 Aug 2016 17:02 Operator: LH Sample : 1.0ng TO-15 ICAL STD Misc : S29-07291601/S29-08051605 (9/3) ALS Vial : 6 Sample Multiplier: 1 Quant Time: Aug 11 07:35:51 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 21457 2.004 ng 97 51) n-Heptane 14.45 71 24481 1.006 ng 98 52) cis-1,3-Dichloropropene 14.98 75 41573 1.040 ng 99 53) 4-Methyl-2-pentanone 15.01 58 22558 1.014 ng 87 54) trans-1,3-Dichloropropene 15.50 75 35266 1.012 ng 100 55) 1,1,2-Trichloroethane 15.67 97 25416 1.008 ng 99 58) Toluene 15.97 91 107501 1.114 ng 99 59) 2-Hexanone 16.21 43 56992 1.100 ng 92 60) Dibromochloromethane 16.37 129 31487 1.071 ng 99 61) 1,2-Dibromoethane 16.63 107 29700 1.030 ng 98 62) n-Butyl Acetate 16.84 43 60939 1.072 ng 96 63) n-Octane 16.97 57 20422 0.937 ng 99 64) Tetrachloroethene 17.11 166 31839 0.981 ng 99 65) Chlorobenzene 17.77 112 72729 1.039 ng 100 66) Ethylbenzene 18.12 91 121366 1.033 ng 99 67) m- & p-Xylenes 18.28 91 190627 2.095 ng 100 68) Bromoform 18.35 173 27796 1.030 ng 100 69) Styrene 18.60 104 75778 1.072 ng 99 70) o-Xylene 18.70 91 97289 1.021 ng 99 71) n-Nonane 18.90 43 47232 1.007 ng 93 72) 1,1,2,2-Tetrachloroethane 18.69 83 43870 1.078 ng 99 74) Cumene 19.23 105 124842 1.010 ng 99 75) alpha-Pinene 19.58 93 60968 1.038 ng 98 76) n-Propylbenzene 19.68 91 150019 1.049 ng 98 77) 3-Ethyltoluene 19.76 105 121197 1.003 ng 98 78) 4-Ethyltoluene 19.80 105 123141 1.145 ng 98 79) 1,3,5-Trimethylbenzene 19.87 105 101759 1.006 ng 98 80) alpha-Methylstyrene 20.00 118 54961 1.112 ng 99 81) 2-Ethyltoluene 20.03 105 121924 1.102 ng 98 82) 1,2,4-Trimethylbenzene 20.23 105 104193 1.070 ng 98 83) n-Decane 20.31 57 50670 1.039 ng 99 84) Benzyl Chloride 20.35 91 71174 1.050 ng 96 85) 1,3-Dichlorobenzene 20.36 146 62634 1.177 ng 99 86) 1,4-Dichlorobenzene 20.42 146 63402 1.044 ng 99 87) sec-Butylbenzene 20.47 105 139063 1.118 ng 98 88) 4-Isopropyltoluene (p-... 20.61 119 127520 1.075 ng 98 89) 1,2,3-Trimethylbenzene 20.60 105 107581 1.087 ng 99 90) 1,2-Dichlorobenzene 20.73 146 61424 1.137 ng 99 91) d-Limonene 20.73 68 37939 1.128 ng 100 92) 1,2-Dibromo-3-Chloropr... 21.11 157 18710 1.032 ng 84 93) n-Undecane 21.41 57 51491 1.113 ng 97 94) 1,2,4-Trichlorobenzene 22.24 180 42355 1.105 ng 100 95) Naphthalene 22.35 128 124542 1.122 ng 98 96) n-Dodecane 22.34 57 48375 1.171 ng 97 97) Hexachlorobutadiene 22.66 225 29729 1.056 ng 99 98) Cyclohexanone 18.42 55 35699 1.074 ng 95 99) tert-Butylbenzene 20.23 119 103739 1.130 ng 97 100) n-Butylbenzene 20.97 91 110696 1.172 ng 96 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Thu Aug 11 07:38:31 2016 Page: 2

78 of 105




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

200000

300000

400000

500000

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800000

900000

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Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

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hlor

oben

zene

,T

n-U

ndec

ane,

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ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

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onen

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oben

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imet

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ne,T

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Buty

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ne,T

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hlor

oben

zene

,TBe

nzyl

Chl

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Buty

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ltolu

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Tal

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Tal

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ofor

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T

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TC

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lene

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12)

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open

e,T

R16081016.M Thu Aug 11 07:38:32 2016 Page: 3

79 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101612.D Acq On : 10 Aug 2016 17:35 Operator: LH Sample : 5.0ng TO-15 ICAL STD Misc : S29-07291601/S29-08051605 (9/3) ALS Vial : 6 Sample Multiplier: 1 Quant Time: Aug 11 07:35:53 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.29 130 226939 12.500 ng -0.01 37) 1,4-Difluorobenzene (IS2) 13.41 114 1084253 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 439892 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.14 65 338849 12.410 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.28% 57) Toluene-d8 (SS2) 15.87 98 1099439 12.759 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.08% 73) Bromofluorobenzene (SS3) 19.11 174 397295 12.850 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.80% Target Compounds Qvalue 2) Propene 4.14 42 96315 4.394 ng 97 3) Dichlorodifluoromethan... 4.30 85 249064 4.726 ng 100 4) Chloromethane 4.60 50 148649 4.198 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.86 135 145219 4.592 ng 100 6) Vinyl Chloride 5.02 62 185302 4.507 ng 100 7) 1,3-Butadiene 5.29 54 116325 4.828 ng 99 8) Bromomethane 5.74 94 125505 4.834 ng 99 9) Chloroethane 6.07 64 78776 4.543 ng 100 10) Ethanol 6.43 45 360779 20.075 ng 99 11) Acetonitrile 6.71 41 181011 4.480 ng 98 12) Acrolein 6.91 56 62480 4.211 ng 98 13) Acetone 7.10 58 407114 22.978 ng # 80 14) Trichlorofluoromethane 7.36 101 209742 4.363 ng 100 15) 2-Propanol (Isopropanol) 7.60 45 542813 9.193 ng 93 16) Acrylonitrile 7.88 53 136816 4.156 ng 99 17) 1,1-Dichloroethene 8.33 96 109704 4.711 ng 98 18) 2-Methyl-2-Propanol (t... 8.49 59 527792 8.939 ng 98 19) Methylene Chloride 8.55 84 113119 4.579 ng 99 20) 3-Chloro-1-propene (Al... 8.72 41 139246 4.710 ng 97 21) Trichlorotrifluoroethane 8.98 151 100510 4.627 ng 99 22) Carbon Disulfide 8.83 76 404566 4.312 ng 99 23) trans-1,2-Dichloroethene 9.83 61 158236 4.563 ng 100 24) 1,1-Dichloroethane 10.09 63 198799 4.548 ng 99 25) Methyl tert-Butyl Ether 10.19 73 328300 4.823 ng 99 26) Vinyl Acetate 10.35 86 126950 26.215 ng # 71 27) 2-Butanone (MEK) 10.59 72 77428 4.787 ng 92 28) cis-1,2-Dichloroethene 11.10 61 156252 4.651 ng 100 29) Diisopropyl Ether 11.41 87 118048 5.106 ng # 86 30) Ethyl Acetate 11.41 61 86343 10.011 ng 99 31) n-Hexane 11.40 57 183209 4.640 ng 99 32) Chloroform 11.46 83 207921 4.760 ng 100 34) Tetrahydrofuran (THF) 11.86 72 72386 4.716 ng 99 35) Ethyl tert-Butyl Ether 12.00 87 138500 4.638 ng 97 36) 1,2-Dichloroethane 12.26 62 154618 4.602 ng 100 38) 1,1,1-Trichloroethane 12.54 97 182171 4.576 ng 99 39) Isopropyl Acetate 12.97 61 149349 9.953 ng # 84 40) 1-Butanol 12.97 56 238704 10.242 ng 87 41) Benzene 13.02 78 463827 4.408 ng 99 42) Carbon Tetrachloride 13.18 117 166066 4.843 ng 100 43) Cyclohexane 13.31 84 349784 9.242 ng 100 44) tert-Amyl Methyl Ether 13.66 73 326412 4.660 ng 98 45) 1,2-Dichloropropane 13.87 63 112003 4.590 ng 100 46) Bromodichloromethane 14.06 83 168052 4.820 ng 100 47) Trichloroethene 14.12 130 133740 4.193 ng 100 48) 1,4-Dioxane 14.08 88 96454 4.762 ng 99 49) 2,2,4-Trimethylpentane... 14.18 57 462622 4.594 ng 96

R16081016.M Thu Aug 11 07:38:48 2016 Page: 1

80 of 105

lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101612.D Acq On : 10 Aug 2016 17:35 Operator: LH Sample : 5.0ng TO-15 ICAL STD Misc : S29-07291601/S29-08051605 (9/3) ALS Vial : 6 Sample Multiplier: 1 Quant Time: Aug 11 07:35:53 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 102231 9.616 ng 99 51) n-Heptane 14.45 71 114742 4.746 ng 100 52) cis-1,3-Dichloropropene 14.98 75 197995 4.990 ng 100 53) 4-Methyl-2-pentanone 15.01 58 107035 4.845 ng 93 54) trans-1,3-Dichloropropene 15.50 75 170535 4.927 ng 99 55) 1,1,2-Trichloroethane 15.67 97 115541 4.613 ng 100 58) Toluene 15.97 91 483656 5.057 ng 99 59) 2-Hexanone 16.21 43 258904 5.042 ng 96 60) Dibromochloromethane 16.38 129 146338 5.021 ng 100 61) 1,2-Dibromoethane 16.63 107 139397 4.878 ng 100 62) n-Butyl Acetate 16.84 43 283656 5.034 ng 97 63) n-Octane 16.97 57 94943 4.395 ng 100 64) Tetrachloroethene 17.11 166 144455 4.489 ng 99 65) Chlorobenzene 17.77 112 329139 4.745 ng 99 66) Ethylbenzene 18.12 91 550824 4.729 ng 99 67) m- & p-Xylenes 18.29 91 880782 9.766 ng 100 68) Bromoform 18.35 173 139693 5.225 ng 100 69) Styrene 18.60 104 363603 5.192 ng 100 70) o-Xylene 18.70 91 455654 4.826 ng 98 71) n-Nonane 18.90 43 222300 4.781 ng 95 72) 1,1,2,2-Tetrachloroethane 18.68 83 215034 5.330 ng 99 74) Cumene 19.23 105 579271 4.730 ng 98 75) alpha-Pinene 19.58 93 292990 5.033 ng 100 76) n-Propylbenzene 19.68 91 704006 4.965 ng 98 77) 3-Ethyltoluene 19.77 105 578858 4.833 ng 97 78) 4-Ethyltoluene 19.80 105 590129 5.534 ng 93 79) 1,3,5-Trimethylbenzene 19.87 105 489818 4.887 ng 99 80) alpha-Methylstyrene 20.00 118 272474 5.564 ng 99 81) 2-Ethyltoluene 20.04 105 581052 5.297 ng 98 82) 1,2,4-Trimethylbenzene 20.23 105 502560 5.207 ng 99 83) n-Decane 20.31 57 254372 5.261 ng 99 84) Benzyl Chloride 20.34 91 415052 6.177 ng 97 85) 1,3-Dichlorobenzene 20.36 146 306126 5.804 ng 100 86) 1,4-Dichlorobenzene 20.42 146 304844 5.065 ng 100 87) sec-Butylbenzene 20.47 105 666982 5.412 ng 99 88) 4-Isopropyltoluene (p-... 20.61 119 616977 5.247 ng 99 89) 1,2,3-Trimethylbenzene 20.61 105 523057 5.330 ng 100 90) 1,2-Dichlorobenzene 20.72 146 299188 5.589 ng 99 91) d-Limonene 20.73 68 192779 5.785 ng 99 92) 1,2-Dibromo-3-Chloropr... 21.11 157 103567 5.766 ng 93 93) n-Undecane 21.41 57 255039 5.560 ng 98 94) 1,2,4-Trichlorobenzene 22.23 180 207989 5.475 ng 100 95) Naphthalene 22.34 128 648544 5.895 ng 99 96) n-Dodecane 22.33 57 248499 6.071 ng 97 97) Hexachlorobutadiene 22.66 225 138413 4.961 ng 99 98) Cyclohexanone 18.41 55 168902 5.128 ng 97 99) tert-Butylbenzene 20.23 119 497186 5.463 ng 98 100) n-Butylbenzene 20.97 91 534619 5.709 ng 98 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Thu Aug 11 07:38:48 2016 Page: 2

81 of 105




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

100000

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900000

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1100000

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1300000

1400000

1500000

1600000

1700000

1800000

1900000

2000000

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Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

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ndec

ane,

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ibro

mo-

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opro

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Buty

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(p-C

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e),T

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Tal

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5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

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ene,

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omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

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chlo

roet

hane

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yren

e,T

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lohe

xano

ne,T

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m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

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hlor

oben

zene

-d5

(IS3)

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Tetra

chlo

roet

hene

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Oct

ane,

Tn-

Buty

l Ace

tate

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2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

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s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

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ethy

lpen

tane

(Iso

octa

ne),T

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hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

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odic

hlor

omet

hane

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2-D

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ropa

ne,T

tert-

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yl M

ethy

l Eth

er,T

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uoro

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ene

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bon

Tetra

chlo

ride,

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ene,

T1-

Buta

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ropy

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1-Tr

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hydr

ofur

an (T

HF)

,TC

hlor

ofor

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l Ace

tate

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opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acr

ylon

itrile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R16081016.M Thu Aug 11 07:38:49 2016 Page: 3

82 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101613.D Acq On : 10 Aug 2016 18:08 Operator: LH Sample : 25ng TO-15 ICAL STD Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 11 07:35:55 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.30 130 253075 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.42 114 1203766 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 490980 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 369016 12.119 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.96% 57) Toluene-d8 (SS2) 15.87 98 1225102 12.738 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.92% 73) Bromofluorobenzene (SS3) 19.11 174 446286 12.932 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 103.44% Target Compounds Qvalue 2) Propene 4.13 42 595073 24.342 ng 100 3) Dichlorodifluoromethan... 4.29 85 1426663 24.276 ng 100 4) Chloromethane 4.58 50 899141 22.770 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.85 135 830803 23.556 ng 100 6) Vinyl Chloride 5.01 62 1088018 23.729 ng 100 7) 1,3-Butadiene 5.29 54 752052 27.989 ng 100 8) Bromomethane 5.74 94 642334 22.183 ng 100 9) Chloroethane 6.07 64 472695 24.446 ng 100 10) Ethanol 6.47 45 2299869 114.758 ng 100 11) Acetonitrile 6.73 41 1089650 24.185 ng 100 12) Acrolein 6.91 56 396752 23.978 ng 100 13) Acetone 7.12 58 2518938 127.488 ng 100 14) Trichlorofluoromethane 7.36 101 1223769 22.825 ng 100 15) 2-Propanol (Isopropanol) 7.63 45 3300530 50.124 ng 100 16) Acrylonitrile 7.89 53 869648 23.687 ng 100 17) 1,1-Dichloroethene 8.33 96 678258 26.120 ng 100 18) 2-Methyl-2-Propanol (t... 8.51 59 3217065 48.862 ng 100 19) Methylene Chloride 8.57 84 682273 24.767 ng 100 20) 3-Chloro-1-propene (Al... 8.72 41 909174 27.579 ng 100 21) Trichlorotrifluoroethane 8.98 151 608790 25.130 ng 100 22) Carbon Disulfide 8.83 76 2508985 23.977 ng 100 23) trans-1,2-Dichloroethene 9.84 61 967992 25.030 ng 100 24) 1,1-Dichloroethane 10.10 63 1167752 23.958 ng 100 25) Methyl tert-Butyl Ether 10.19 73 1682884 22.172 ng 100 26) Vinyl Acetate 10.36 86 905610 167.695 ng 100 27) 2-Butanone (MEK) 10.59 72 493022 27.333 ng 100 28) cis-1,2-Dichloroethene 11.12 61 947564 25.292 ng 100 29) Diisopropyl Ether 11.41 87 745189 28.903 ng 100 30) Ethyl Acetate 11.42 61 561016 58.328 ng 100 31) n-Hexane 11.40 57 1149433 26.107 ng 100 32) Chloroform 11.46 83 1227069 25.188 ng 100 34) Tetrahydrofuran (THF) 11.86 72 435838 25.463 ng 100 35) Ethyl tert-Butyl Ether 12.01 87 856157 25.711 ng 100 36) 1,2-Dichloroethane 12.26 62 896444 23.924 ng 100 38) 1,1,1-Trichloroethane 12.54 97 1068098 24.169 ng 100 39) Isopropyl Acetate 12.97 61 968283 58.122 ng 100 40) 1-Butanol 12.99 56 1598775 61.789 ng 100 41) Benzene 13.02 78 2818865 24.129 ng 100 42) Carbon Tetrachloride 13.18 117 991905 26.055 ng 100 43) Cyclohexane 13.31 84 2122900 50.521 ng 100 44) tert-Amyl Methyl Ether 13.66 73 2028635 26.084 ng 100 45) 1,2-Dichloropropane 13.88 63 683759 25.238 ng 100 46) Bromodichloromethane 14.07 83 1016140 26.251 ng 100 47) Trichloroethene 14.12 130 803901 22.700 ng 100 48) 1,4-Dioxane 14.09 88 585215 26.023 ng 100 49) 2,2,4-Trimethylpentane... 14.19 57 2790743 24.964 ng 100

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Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101613.D Acq On : 10 Aug 2016 18:08 Operator: LH Sample : 25ng TO-15 ICAL STD Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 11 07:35:55 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 647760 54.880 ng 100 51) n-Heptane 14.45 71 705902 26.302 ng 100 52) cis-1,3-Dichloropropene 14.98 75 1249542 28.367 ng 100 53) 4-Methyl-2-pentanone 15.01 58 662172 26.999 ng 100 54) trans-1,3-Dichloropropene 15.50 75 1079014 28.078 ng 100 55) 1,1,2-Trichloroethane 15.67 97 697054 25.066 ng 100 58) Toluene 15.97 91 2910511 27.263 ng 100 59) 2-Hexanone 16.21 43 1560384 27.227 ng 100 60) Dibromochloromethane 16.38 129 905412 27.831 ng 100 61) 1,2-Dibromoethane 16.63 107 846368 26.537 ng 100 62) n-Butyl Acetate 16.84 43 1731895 27.536 ng 100 63) n-Octane 16.97 57 600749 24.915 ng 100 64) Tetrachloroethene 17.11 166 877067 24.422 ng 100 65) Chlorobenzene 17.77 112 1995308 25.775 ng 100 66) Ethylbenzene 18.12 91 3367739 25.904 ng 100 67) m- & p-Xylenes 18.29 91 5459177 54.234 ng 100 68) Bromoform 18.35 173 893178 29.929 ng 100 69) Styrene 18.60 104 2244033 28.708 ng 100 70) o-Xylene 18.71 91 2718785 25.797 ng 100 71) n-Nonane 18.90 43 1308744 25.219 ng 100 72) 1,1,2,2-Tetrachloroethane 18.69 83 1355133 30.092 ng 100 74) Cumene 19.23 105 3473289 25.412 ng 100 75) alpha-Pinene 19.58 93 1800099 27.703 ng 100 76) n-Propylbenzene 19.68 91 4201074 26.546 ng 100 77) 3-Ethyltoluene 19.76 105 3630293 27.158 ng 100 78) 4-Ethyltoluene 19.80 105 3320240 27.898 ng 100 79) 1,3,5-Trimethylbenzene 19.87 105 2915392 26.063 ng 100 80) alpha-Methylstyrene 20.01 118 1671458 30.578 ng 100 81) 2-Ethyltoluene 20.04 105 3397790 27.751 ng 100 82) 1,2,4-Trimethylbenzene 20.23 105 2908416 26.999 ng 100 83) n-Decane 20.32 57 1531159 28.372 ng 100 84) Benzyl Chloride 20.35 91 2685737 35.810 ng 100 85) 1,3-Dichlorobenzene 20.37 146 1826702 31.027 ng 100 86) 1,4-Dichlorobenzene 20.42 146 1809638 26.937 ng 100 87) sec-Butylbenzene 20.47 105 3863412 28.086 ng 100 88) 4-Isopropyltoluene (p-... 20.61 119 3470527 26.442 ng 100 89) 1,2,3-Trimethylbenzene 20.61 105 2993839 27.332 ng 100 90) 1,2-Dichlorobenzene 20.73 146 1743303 29.178 ng 100 91) d-Limonene 20.73 68 1136831 30.564 ng 100 92) 1,2-Dibromo-3-Chloropr... 21.11 157 669580 33.399 ng 100 93) n-Undecane 21.41 57 1588433 31.026 ng 100 94) 1,2,4-Trichlorobenzene 22.23 180 1313924 30.986 ng 100 95) Naphthalene 22.34 128 4060375 33.069 ng 100 96) n-Dodecane 22.33 57 1558275 34.110 ng 100 97) Hexachlorobutadiene 22.66 225 859275 27.596 ng 100 98) Cyclohexanone 18.41 55 1062640 28.907 ng 100 99) tert-Butylbenzene 20.23 119 2834496 27.902 ng 100 100) n-Butylbenzene 20.97 91 3116315 29.814 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Thu Aug 11 07:39:09 2016 Page: 2

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Data File: I:\MS16\DATA\2016_08\10\08101613.D Acq On : 10 Aug 2016 18:08 Operator: LH Sample : 25ng TO-15 ICAL STD Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,Tn-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

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ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TCum

ene,

TBr

omof

luor

oben

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),Sn-

Non

ane,

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ne,T

1,1,

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chlo

roet

hane

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yren

e,T

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lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

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4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

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ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

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odic

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yl M

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pyl A

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an (T

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l Ace

tate

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ane,

TBr

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(IS1

),IR

cis-

1,2-

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hlor

oeth

ene,

T

2-Bu

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ne (M

EK),T

Viny

l Ace

tate

,TM

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l ter

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ther

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1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

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T

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lene

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Met

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-Pro

pano

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rt-Bu

tyl A

lcoh

ol,T

1,1-

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hlor

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anol

(Iso

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anol

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ichl

orof

luor

omet

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lein

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hane

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1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

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hlor

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1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,TD

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ne (C

FC 1

2),T

Prop

ene,

T

R16081016.M Thu Aug 11 07:39:10 2016 Page: 3

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Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101614.D Acq On : 10 Aug 2016 18:41 Operator: LH Sample : 50ng TO-15 ICAL STD Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 11 07:35:58 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.30 130 260869 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 13.42 114 1247176 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 518811 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 376071 11.982 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.84% 57) Toluene-d8 (SS2) 15.87 98 1268877 12.485 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.92% 73) Bromofluorobenzene (SS3) 19.11 174 464458 12.737 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.92% Target Compounds Qvalue 2) Propene 4.13 42 1275998 50.637 ng 98 3) Dichlorodifluoromethan... 4.29 85 2822510 46.593 ng 100 4) Chloromethane 4.59 50 1711921 42.058 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.86 135 1630007 44.836 ng 100 6) Vinyl Chloride 5.02 62 2126514 44.992 ng 100 7) 1,3-Butadiene 5.30 54 1492628 53.892 ng 99 8) Bromomethane 5.74 94 1436627 48.132 ng 100 9) Chloroethane 6.08 64 978358 49.086 ng 100 10) Ethanol 6.51 45 4674568 226.280 ng 100 11) Acetonitrile 6.74 41 2218849 47.776 ng 100 12) Acrolein 6.92 56 830210 48.676 ng 100 13) Acetone 7.13 58 4902550 240.713 ng 89 14) Trichlorofluoromethane 7.36 101 2409316 43.594 ng 100 15) 2-Propanol (Isopropanol) 7.65 45 6368022 93.820 ng 99 16) Acrylonitrile 7.90 53 1740810 46.000 ng 100 17) 1,1-Dichloroethene 8.34 96 1357793 50.726 ng 97 18) 2-Methyl-2-Propanol (t... 8.52 59 6021412 88.722 ng 99 19) Methylene Chloride 8.57 84 1406560 49.534 ng 98 20) 3-Chloro-1-propene (Al... 8.73 41 1771232 52.124 ng 98 21) Trichlorotrifluoroethane 8.98 151 1175378 47.068 ng 99 22) Carbon Disulfide 8.83 76 4946535 45.859 ng 99 23) trans-1,2-Dichloroethene 9.84 61 1959591 49.157 ng 99 24) 1,1-Dichloroethane 10.10 63 2367538 47.122 ng 100 25) Methyl tert-Butyl Ether 10.19 73 3133783 40.053 ng 100 26) Vinyl Acetate 10.37 86 1706504 306.558 ng # 81 27) 2-Butanone (MEK) 10.60 72 971315 52.241 ng 95 28) cis-1,2-Dichloroethene 11.12 61 1845213 47.781 ng 99 29) Diisopropyl Ether 11.41 87 1213289 45.652 ng # 86 30) Ethyl Acetate 11.42 61 1046798 105.582 ng 98 31) n-Hexane 11.40 57 2148764 47.347 ng 99 32) Chloroform 11.47 83 2349592 46.789 ng 100 34) Tetrahydrofuran (THF) 11.86 72 866774 49.126 ng 97 35) Ethyl tert-Butyl Ether 12.01 87 1681192 48.980 ng 98 36) 1,2-Dichloroethane 12.27 62 1714045 44.377 ng 100 38) 1,1,1-Trichloroethane 12.55 97 2066355 45.130 ng 99 39) Isopropyl Acetate 12.97 61 1878896 108.856 ng # 90 40) 1-Butanol 13.00 56 3029564 113.011 ng 96 41) Benzene 13.03 78 5409251 44.691 ng 100 42) Carbon Tetrachloride 13.19 117 1940923 49.209 ng 100 43) Cyclohexane 13.32 84 4253138 97.694 ng 99 44) tert-Amyl Methyl Ether 13.66 73 3962821 49.180 ng 99 45) 1,2-Dichloropropane 13.88 63 1359358 48.429 ng 100 46) Bromodichloromethane 14.07 83 2000852 49.891 ng 100 47) Trichloroethene 14.12 130 1572377 42.853 ng 100 48) 1,4-Dioxane 14.09 88 1199050 51.464 ng 100 49) 2,2,4-Trimethylpentane... 14.19 57 5391129 46.547 ng 98

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,TC

hlor

ofor

m,T

Ethy

l Ace

tate

,TD

iisop

ropy

l Eth

er,T

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T2

-Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

1,1-

Dic

hlor

oeth

ene,

T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEtha

nol,T

Chl

oroe

than

e,T

Brom

omet

hane

,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R16081016.M Thu Aug 11 07:39:30 2016 Page: 3

88 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101615.D Acq On : 10 Aug 2016 19:15 Operator: LH Sample : 100ng TO-15 ICAL STD Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 11 07:36:00 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 07:35:25 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.31 130 268174 12.500 ng 0.01 37) 1,4-Difluorobenzene (IS2) 13.42 114 1285105 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.73 82 527925 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.16 65 378681 11.737 ng 0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 93.92% 57) Toluene-d8 (SS2) 15.87 98 1298555 12.557 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.48% 73) Bromofluorobenzene (SS3) 19.11 174 474467 12.787 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.32% Target Compounds Qvalue 2) Propene 4.13 42 3055119 117.937 ng 96 3) Dichlorodifluoromethan... 4.29 85 5326124 85.526 ng 99 4) Chloromethane 4.58 50 2824474 67.501 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.86 135 3186975 85.275 ng 100 6) Vinyl Chloride 5.02 62 4220718 86.869 ng 100 7) 1,3-Butadiene 5.30 54 2824132 99.189 ng 97 8) Bromomethane 5.75 94 2805407 91.431 ng 100 9) Chloroethane 6.08 64 2063673 100.718 ng 100 10) Ethanol 6.55 45 8970241 422.392 ng 100 11) Acetonitrile 6.77 41 4500017 94.255 ng 99 12) Acrolein 6.92 56 1650649 94.143 ng 99 13) Acetone 7.16 58 8455199 403.838 ng 84 14) Trichlorofluoromethane 7.36 101 4736625 83.370 ng 100 15) 2-Propanol (Isopropanol) 7.67 45 9815856 140.677 ng 98 16) Acrylonitrile 7.92 53 3499022 89.940 ng 99 17) 1,1-Dichloroethene 8.34 96 2811771 102.184 ng 94 18) 2-Methyl-2-Propanol (t... 8.55 59 9114603 130.641 ng 98 19) Methylene Chloride 8.58 84 2833395 97.065 ng 94 20) 3-Chloro-1-propene (Al... 8.73 41 3513171 100.570 ng 96 21) Trichlorotrifluoroethane 8.99 151 2426298 94.515 ng 99 22) Carbon Disulfide 8.84 76 9758963 88.011 ng 99 23) trans-1,2-Dichloroethene 9.85 61 3946198 96.294 ng 98 24) 1,1-Dichloroethane 10.11 63 4723405 91.450 ng 99 25) Methyl tert-Butyl Ether 10.20 73 4928317 61.274 ng 99 26) Vinyl Acetate 10.38 86 2957569 516.828 ng # 61 27) 2-Butanone (MEK) 10.61 72 1924954 100.711 ng # 86 28) cis-1,2-Dichloroethene 11.13 61 3649840 91.936 ng 97 29) Diisopropyl Ether 11.42 87 2017649 73.850 ng 95 30) Ethyl Acetate 11.44 61 1704487 167.235 ng 95 31) n-Hexane 11.40 57 3651337 78.263 ng 99 32) Chloroform 11.48 83 4554549 88.228 ng 100 34) Tetrahydrofuran (THF) 11.87 72 1755067 96.762 ng 95 35) Ethyl tert-Butyl Ether 12.01 87 3332946 94.457 ng 93 36) 1,2-Dichloroethane 12.28 62 3298229 83.066 ng 99 38) 1,1,1-Trichloroethane 12.55 97 3946681 83.652 ng 99 39) Isopropyl Acetate 12.98 61 3290095 184.990 ng # 83 40) 1-Butanol 13.02 56 5065422 183.378 ng 96 41) Benzene 13.03 78 9044476 72.520 ng 99 42) Carbon Tetrachloride 13.19 117 3771758 92.805 ng 100 43) Cyclohexane 13.33 84 7385910 164.646 ng 97 44) tert-Amyl Methyl Ether 13.67 73 7645364 92.082 ng 98 45) 1,2-Dichloropropane 13.89 63 2711686 93.756 ng 100 46) Bromodichloromethane 14.07 83 3832965 92.754 ng 99 47) Trichloroethene 14.13 130 3112490 82.324 ng 99 48) 1,4-Dioxane 14.10 88 2360087 98.306 ng 100 49) 2,2,4-Trimethylpentane... 14.19 57 10019732 83.957 ng 97

R16081016.M Thu Aug 11 07:39:51 2016 Page: 1

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lusine.hakobyan

Lusine


R16081016.M Thu Aug 11 07:39:51 2016 Page: 2

90 of 105




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

2.2e+07

2.3e+07

2.4e+07

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,TC

hlor

ofor

m,T

Ethy

l Ace

tate

,TD

iisop

ropy

l Eth

er,T

n-H

exan

e,T

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,T

Chl

oroe

than

e,T

Brom

omet

hane

,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R16081016.M Thu Aug 11 07:39:52 2016 Page: 3

91 of 105

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101618.D Acq On : 11 Aug 2016 8:40 Operator: LH Sample : 25ng TO-15 ICV STD Misc : S29-07291601/S29-08041602 (9/2) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 11 09:48:52 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.30 130 255763 12.500 ng 0.02 37) 1,4-Difluorobenzene (IS2) 13.42 114 1202631 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 487246 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 364365 12.077 ng 0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.64% 57) Toluene-d8 (SS2) 15.87 98 1217049 12.552 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.40% 73) Bromofluorobenzene (SS3) 19.11 174 437401 12.637 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.12% Target Compounds Qvalue 2) Propene 4.14 42 590125 23.157 ng 99 3) Dichlorodifluoromethan... 4.30 85 1372758 23.051 ng 100 4) Chloromethane 4.59 50 875338 22.795 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.86 135 809414 23.854 ng 100 6) Vinyl Chloride 5.02 62 1073569 24.501 ng 99 7) 1,3-Butadiene 5.29 54 730881 26.904 ng 100 8) Bromomethane 5.74 94 662166 23.091 ng 100 9) Chloroethane 6.08 64 481909 24.997 ng 100 10) Ethanol 6.48 45 2244982 122.540 ng 100 11) Acetonitrile 6.73 41 1085333 23.464 ng 100 12) Acrolein 6.91 56 366242 24.226 ng 99 13) Acetone 7.12 58 2552297 138.190 ng 98 14) Trichlorofluoromethane 7.36 101 1226069 23.960 ng 100 15) 2-Propanol (Isopropanol) 7.63 45 3323744 52.785 ng 100 16) Acrylonitrile 7.89 53 888551 26.771 ng 100 17) 1,1-Dichloroethene 8.33 96 708494 28.122 ng 98 18) 2-Methyl-2-Propanol (t... 8.51 59 3202325 53.404 ng 100 19) Methylene Chloride 8.57 84 706662 27.481 ng 98 20) 3-Chloro-1-propene (Al... 8.73 41 904133 27.617 ng 99 21) Trichlorotrifluoroethane 8.98 151 631002 27.600 ng 99 22) Carbon Disulfide 8.83 76 2435365 23.000 ng 100 23) trans-1,2-Dichloroethene 9.84 61 958574 26.380 ng 99 24) 1,1-Dichloroethane 10.10 63 1223524 26.378 ng 100 25) Methyl tert-Butyl Ether 10.19 73 1614053 24.402 ng 99 26) Vinyl Acetate 10.36 86 945368 166.619 ng 98 27) 2-Butanone (MEK) 10.60 72 505616 28.681 ng 98 28) cis-1,2-Dichloroethene 11.12 61 978119 28.017 ng 98 29) Diisopropyl Ether 11.41 87 650443 26.033 ng # 73 30) Ethyl Acetate 11.42 61 566723 60.422 ng 99 31) n-Hexane 11.40 57 1155818 27.697 ng 100 32) Chloroform 11.47 83 1282598 27.780 ng 100 34) Tetrahydrofuran (THF) 11.86 72 478720 27.284 ng 98 35) Ethyl tert-Butyl Ether 12.01 87 881789 27.553 ng 100 36) 1,2-Dichloroethane 12.26 62 922771 26.512 ng 100 38) 1,1,1-Trichloroethane 12.54 97 1110330 26.847 ng 99 39) Isopropyl Acetate 12.97 61 992221 63.098 ng 96 40) 1-Butanol 12.99 56 1486111 60.821 ng 98 41) Benzene 13.02 78 2931890 28.507 ng 100 42) Carbon Tetrachloride 13.19 117 1014825 28.242 ng 100 43) Cyclohexane 13.32 84 2155952 54.923 ng 99 44) tert-Amyl Methyl Ether 13.66 73 2083636 28.120 ng 99 45) 1,2-Dichloropropane 13.88 63 711186 27.789 ng 100 46) Bromodichloromethane 14.07 83 1046922 28.636 ng 100 47) Trichloroethene 14.12 130 829644 26.658 ng 100 48) 1,4-Dioxane 14.09 88 622741 29.390 ng 99 49) 2,2,4-Trimethylpentane... 14.19 57 2865962 27.418 ng 100

R16081016.M Thu Aug 11 09:48:59 2016 Page: 1

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lusine.hakobyan

Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\10\08101618.D Acq On : 11 Aug 2016 8:40 Operator: LH Sample : 25ng TO-15 ICV STD Misc : S29-07291601/S29-08041602 (9/2) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 11 09:48:52 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.33 100 669384 58.375 ng 99 51) n-Heptane 14.45 71 722589 28.546 ng 100 52) cis-1,3-Dichloropropene 14.99 75 1174621 28.115 ng 100 53) 4-Methyl-2-pentanone 15.01 58 684216 29.615 ng 99 54) trans-1,3-Dichloropropene 15.50 75 1075439 28.796 ng 100 55) 1,1,2-Trichloroethane 15.67 97 737116 28.120 ng 100 58) Toluene 15.97 91 3067556 27.924 ng 100 59) 2-Hexanone 16.21 43 1582898 29.615 ng 100 60) Dibromochloromethane 16.38 129 936679 29.908 ng 100 61) 1,2-Dibromoethane 16.63 107 885966 29.076 ng 100 62) n-Butyl Acetate 16.84 43 1758577 30.120 ng 100 63) n-Octane 16.97 57 608754 27.685 ng 99 64) Tetrachloroethene 17.11 166 924354 26.707 ng 100 65) Chlorobenzene 17.77 112 2103995 28.799 ng 100 66) Ethylbenzene 18.12 91 3550282 29.081 ng 100 67) m- & p-Xylenes 18.29 91 5551225 57.407 ng 98 68) Bromoform 18.35 173 884883 29.797 ng 100 69) Styrene 18.60 104 2330913 30.871 ng 100 70) o-Xylene 18.71 91 2821442 28.267 ng 100 71) n-Nonane 18.90 43 1330802 27.625 ng 100 72) 1,1,2,2-Tetrachloroethane 18.69 83 1402212 29.356 ng 100 74) Cumene 19.23 105 3573282 27.963 ng 100 75) alpha-Pinene 19.58 93 1865606 29.262 ng 98 76) n-Propylbenzene 19.68 91 4318387 27.862 ng 100 77) 3-Ethyltoluene 19.76 105 3696350 29.318 ng 100 78) 4-Ethyltoluene 19.80 105 3418117 29.464 ng 100 79) 1,3,5-Trimethylbenzene 19.87 105 2993219 29.145 ng 100 80) alpha-Methylstyrene 20.01 118 1695191 30.104 ng 100 81) 2-Ethyltoluene 20.04 105 3479309 28.681 ng 100 82) 1,2,4-Trimethylbenzene 20.23 105 3013779 30.159 ng 100 83) n-Decane 20.32 57 1550697 29.580 ng 99 84) Benzyl Chloride 20.35 91 2780514 35.122 ng 100 85) 1,3-Dichlorobenzene 20.37 146 1933743 31.846 ng 100 86) 1,4-Dichlorobenzene 20.42 146 1883871 29.618 ng 100 87) sec-Butylbenzene 20.47 105 3927777 29.334 ng 100 88) 4-Isopropyltoluene (p-... 20.61 119 3575561 28.654 ng 100 89) 1,2,3-Trimethylbenzene 20.61 105 3071177 29.764 ng 100 90) 1,2-Dichlorobenzene 20.73 146 1822653 31.127 ng 100 91) d-Limonene 20.73 68 1138566 30.720 ng 100 92) 1,2-Dibromo-3-Chloropr... 21.11 157 694809 32.469 ng 99 93) n-Undecane 21.41 57 1604779 30.908 ng 100 94) 1,2,4-Trichlorobenzene 22.23 180 1408194 31.456 ng 100 95) Naphthalene 22.34 128 4223143 30.306 ng 100 96) n-Dodecane 22.33 57 1583160 34.422 ng 100 97) Hexachlorobutadiene 22.66 225 889622 28.291 ng 100 98) Cyclohexanone 18.41 55 995122 28.707 ng 99 99) tert-Butylbenzene 20.23 119 2882477 29.319 ng 100 100) n-Butylbenzene 20.97 91 3193459 30.704 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Thu Aug 11 09:48:59 2016 Page: 2

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Data File: I:\MS16\DATA\2016_08\10\08101618.D Acq On : 11 Aug 2016 8:40 Operator: LH Sample : 25ng TO-15 ICV STD Misc : S29-07291601/S29-08041602 (9/2) ALS Vial : 2 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

1.25e+07

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R16081016.M Thu Aug 11 09:48:59 2016 Page: 3

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Page 1 of 2 I:\MS16\0-Instrument Info\0-Security Certificates\ICV_07141501_REV1.CRT 8/11/16 9:50 AM

INITIAL CALIBRATION VERIFICATION CHECK SHEET

Data File Name: 08101618.D Acq. Method File: TO15.MData File Path: I:\MS16\DATA\2016_08\10\ Sample Name: 25ng TO-15 ICV STD

Operator: LH Misc Info: S29-07291601/S29-08041602 (Date Acquired: 8/11/16 8:40 Instrument Name: GCMS-16

Compound Ret. Amt. Spike % Lower Upper * OR# Name Time (ng) Amt.(ng) Rec. Limit Limit Fail2) Propene 4.14 23.2 24.50 95 70 130 *3) Dichlorodifluoromethane (CFC 12 4.30 23.1 23.50 98 70 130 *4) Chloromethane 4.59 22.8 25.00 91 70 130 *5) 1,2-Dichloro-1,1,2,2-tetrafluoroeth 4.86 23.9 25.50 94 70 130 *6) Vinyl Chloride 5.02 24.5 25.00 98 70 130 *7) 1,3-Butadiene 5.29 26.9 25.75 104 70 130 *8) Bromomethane 5.74 23.1 25.25 91 70 130 *9) Chloroethane 6.08 25.0 25.00 100 70 130 *

10) Ethanol 6.48 123 124.75 99 70 130 *11) Acetonitrile 6.73 23.5 26.50 89 70 130 *12) Acrolein 6.91 24.2 26.75 90 70 130 *13) Acetone 7.12 138 134.75 102 70 130 *14) Trichlorofluoromethane 7.36 24.0 27.00 89 70 130 *15) 2-Propanol (Isopropanol) 7.63 52.8 52.25 101 70 130 *16) Acrylonitrile 7.89 26.8 26.50 101 70 130 *17) 1,1-Dichloroethene 8.33 28.1 27.00 104 70 130 *18) 2-Methyl-2-Propanol (tert-Butyl Alco 8.51 53.4 50.00 107 70 130 *19) Methylene Chloride 8.57 27.5 27.75 99 70 130 *20) 3-Chloro-1-propene (Allyl Chlorid 8.73 27.6 27.25 101 70 130 *21) Trichlorotrifluoroethane 8.98 27.6 27.50 100 70 130 *22) Carbon Disulfide 8.83 23.0 26.25 88 70 130 *23) trans-1,2-Dichloroethene 9.84 26.4 26.25 101 70 130 *24) 1,1-Dichloroethane 10.10 26.4 26.50 100 70 130 *25) Methyl tert-Butyl Ether 10.19 24.4 27.00 90 70 130 *26) Vinyl Acetate 10.36 167 129.75 129 70 130 *27) 2-Butanone (MEK) 10.60 28.7 27.50 104 70 130 *28) cis-1,2-Dichloroethene 11.12 28.0 27.25 103 70 130 *29) Diisopropyl Ether 11.41 26.0 27.00 96 70 130 *30) Ethyl Acetate 11.42 60.4 53.50 113 70 130 *31) n-Hexane 11.40 27.7 26.50 105 70 130 *32) Chloroform 11.47 27.8 28.00 99 70 130 *34) Tetrahydrofuran (THF) 11.86 27.3 27.50 99 70 130 *35) Ethyl tert-Butyl Ether 12.01 27.6 26.75 103 70 130 *36) 1,2-Dichloroethane 12.26 26.5 26.75 99 70 130 *38) 1,1,1-Trichloroethane 12.54 26.8 26.25 102 70 130 *39) Isopropyl Acetate 12.97 63.1 57.25 110 70 130 *40) 1-Butanol 12.99 60.8 51.25 119 70 130 *41) Benzene 13.02 28.5 28.25 101 70 130 *42) Carbon Tetrachloride 13.19 28.2 28.75 98 70 130 *43) Cyclohexane 13.32 54.9 53.00 104 70 130 *44) tert-Amyl Methyl Ether 13.66 28.1 26.75 105 70 130 *45) 1,2-Dichloropropane 13.88 27.8 27.00 103 70 130 *46) Bromodichloromethane 14.07 28.6 27.25 105 70 130 *47) Trichloroethene 14.12 26.7 27.00 99 70 130 *48) 1,4-Dioxane 14.09 29.4 26.25 112 70 130 *49) 2,2,4-Trimethylpentane (Isooctane) 14.19 27.4 26.75 102 70 130 *

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Page 2 of 2 I:\MS16\0-Instrument Info\0-Security Certificates\ICV_07141501_REV1.CRT 8/11/16 9:50 AM

INITIAL CALIBRATION VERIFICATION CHECK SHEET

Data File Name: 08101618.D Acq. Method File: TO15.MData File Path: I:\MS16\DATA\2016_08\10\ Sample Name: 25ng TO-15 ICV STD

Operator: LH Misc Info: S29-07291601/S29-08041602 (Date Acquired: 8/11/16 8:40 Instrument Name: GCMS-16

Compound Ret. Amt. Spike % Lower Upper * OR# Name Time (ng) Amt.(ng) Rec. Limit Limit Fail

50) Methyl Methacrylate 14.33 58.4 52.75 111 70 130 *51) n-Heptane 14.45 28.5 27.00 106 70 130 *52) cis-1,3-Dichloropropene 14.99 28.1 26.00 108 70 130 *53) 4-Methyl-2-pentanone 15.01 29.6 27.50 108 70 130 *54) trans-1,3-Dichloropropene 15.50 28.8 26.25 110 70 130 *55) 1,1,2-Trichloroethane 15.67 28.1 27.00 104 70 130 *58) Toluene 15.97 27.9 27.25 102 70 130 *59) 2-Hexanone 16.21 29.6 27.50 108 70 130 *60) Dibromochloromethane 16.38 29.9 27.50 109 70 130 *61) 1,2-Dibromoethane 16.63 29.1 27.25 107 70 130 *62) n-Butyl Acetate 16.84 30.1 28.25 107 70 130 *63) n-Octane 16.97 27.7 26.25 106 70 130 *64) Tetrachloroethene 17.11 26.7 25.25 106 70 130 *65) Chlorobenzene 17.77 28.8 27.50 105 70 130 *66) Ethylbenzene 18.12 29.1 27.25 107 70 130 *67) m- & p-Xylenes 18.29 57.4 53.50 107 70 130 *68) Bromoform 18.35 29.8 28.50 105 70 130 *69) Styrene 18.60 30.9 27.75 111 70 130 *70) o-Xylene 18.71 28.3 26.25 108 70 130 *71) n-Nonane 18.90 27.6 25.50 108 70 130 *72) 1,1,2,2-Tetrachloroethane 18.69 29.4 26.25 112 70 130 *74) Cumene 19.23 28.0 26.00 108 70 130 *75) alpha-Pinene 19.58 29.3 26.50 111 70 130 *76) n-Propylbenzene 19.68 27.9 25.50 109 70 130 *77) 3-Ethyltoluene 19.76 29.3 26.75 110 70 130 *78) 4-Ethyltoluene 19.80 29.5 26.75 110 70 130 *79) 1,3,5-Trimethylbenzene 19.87 29.1 26.75 109 70 130 *80) alpha-Methylstyrene 20.01 30.1 26.25 115 70 130 *81) 2-Ethyltoluene 20.04 28.7 26.75 107 70 130 *82) 1,2,4-Trimethylbenzene 20.23 30.2 27.25 111 70 130 *83) n-Decane 20.32 29.6 26.25 113 70 130 *84) Benzyl Chloride 20.35 35.1 27.50 128 70 130 *85) 1,3-Dichlorobenzene 20.37 31.8 28.50 112 70 130 *86) 1,4-Dichlorobenzene 20.42 29.6 26.00 114 70 130 *87) sec-Butylbenzene 20.47 29.3 27.25 108 70 130 *88) 4-Isopropyltoluene (p-Cymene) 20.61 28.7 26.00 110 70 130 *89) 1,2,3-Trimethylbenzene 20.61 29.8 26.50 112 70 130 *90) 1,2-Dichlorobenzene 20.73 31.1 27.50 113 70 130 *91) d-Limonene 20.73 30.7 26.25 117 70 130 *92) 1,2-Dibromo-3-Chloropropane 21.11 32.5 27.25 119 70 130 *93) n-Undecane 21.41 30.9 25.25 122 70 130 *94) 1,2,4-Trichlorobenzene 22.23 31.5 28.75 110 70 130 *95) Naphthalene 22.34 30.3 27.25 111 70 130 *96) n-Dodecane 22.33 34.4 27.25 126 70 130 *97) Hexachlorobutadiene 22.66 28.3 28.75 98 70 130 *98) Cyclohexanone 18.41 28.7 27.50 104 70 130 *99) tert-Butylbenzene 20.23 29.3 26.75 110 70 130 *

100) n-Butylbenzene 20.97 30.7 28.00 110 70 130 *

Bold = 75 Compound List* = Pass

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Evaluate Continuing Calibration Report Data File: I:\MS16\DATA\2016_08\18\08181624.D Acq On : 18 Aug 2016 18:18 Operator: LH Sample : CCV2 R16081816_25ng Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 08:26:02 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 1 IR Bromochloromethane (IS1) 1.000 1.000 0.0 119 0.02 2 T Propene 1.245 1.135 8.8 119 -0.07 3 T Dichlorodifluoromethane (CF 2.911 2.665 8.5 113 -0.06 4 T Chloromethane 1.877 1.807 3.7 119 -0.09 5 T 1,2-Dichloro-1,1,2,2-tetraf 1.658 1.437 13.3 108 -0.04 6 T Vinyl Chloride 2.142 2.058 3.9 114 -0.08 7 T 1,3-Butadiene 1.328 1.377 -3.7 117 -0.07 8 T Bromomethane 1.402 1.216 13.3 114 -0.06 9 T Chloroethane 0.942 0.931 1.2 120 -0.05 10 T Ethanol 0.895 0.900 -0.6 119 0.03 11 T Acetonitrile 2.261 2.149 5.0 121 -0.07 12 T Acrolein 0.739 0.740 -0.1 121 -0.02 13 T Acetone 0.903 0.914 -1.2 118 0.00 14 T Trichlorofluoromethane 2.501 2.293 8.3 112 -0.03 15 T 2-Propanol (Isopropanol) 3.077 3.096 -0.6 118 0.03 16 T Acrylonitrile 1.622 1.658 -2.2 119 -0.03 17 T 1,1-Dichloroethene 1.231 1.189 3.4 113 -0.02 18 T 2-Methyl-2-Propanol (tert-B 2.931 2.925 0.2 115 0.01 19 T Methylene Chloride 1.257 1.214 3.4 116 0.00 20 T 3-Chloro-1-propene (Allyl C 1.600 1.598 0.1 115 -0.01 21 T Trichlorotrifluoroethane 1.117 1.023 8.4 110 -0.01 22 T Carbon Disulfide 5.175 4.923 4.9 116 -0.04 23 T trans-1,2-Dichloroethene 1.776 1.780 -0.2 118 0.00 24 T 1,1-Dichloroethane 2.267 2.211 2.5 119 0.01 25 T Methyl tert-Butyl Ether 3.233 3.114 3.7 117 -0.01 26 T Vinyl Acetate 0.277 0.316 -14.1 107 0.01 27 T 2-Butanone (MEK) 0.862 0.852 1.2 112 0.00 28 T cis-1,2-Dichloroethene 1.706 1.697 0.5 116 0.01 29 T Diisopropyl Ether 1.221 1.088 10.9 95 0.00 30 T Ethyl Acetate 0.458 0.494 -7.9 113 0.00 31 T n-Hexane 2.040 2.113 -3.6 115 0.00 32 T Chloroform 2.256 2.126 5.8 112 0.02 33 S 1,2-Dichloroethane-d4(SS1) 1.475 1.472 0.2 120 0.01 34 T Tetrahydrofuran (THF) 0.858 0.818 4.7 116 -0.02 35 T Ethyl tert-Butyl Ether 1.564 1.504 3.8 111 0.00 36 T 1,2-Dichloroethane 1.701 1.568 7.8 111 0.01 37 IR 1,4-Difluorobenzene (IS2) 1.000 1.000 0.0 120 0.00 38 T 1,1,1-Trichloroethane 0.430 0.400 7.0 111 0.01 39 T Isopropyl Acetate 0.163 0.174 -6.7 115 0.00 40 T 1-Butanol 0.254 0.276 -8.7 112 0.00 41 T Benzene 1.069 0.990 7.4 112 0.00 42 T Carbon Tetrachloride 0.373 0.350 6.2 110 0.00 43 T Cyclohexane 0.408 0.405 0.7 115 0.00 44 T tert-Amyl Methyl Ether 0.770 0.758 1.6 112 0.00 45 T 1,2-Dichloropropane 0.266 0.263 1.1 116 0.00 46 T Bromodichloromethane 0.380 0.369 2.9 112 0.00 47 T Trichloroethene 0.323 0.296 8.4 109 0.00 48 T 1,4-Dioxane 0.220 0.217 1.4 115 0.00 49 T 2,2,4-Trimethylpentane (Iso 1.086 1.097 -1.0 117 0.00 50 T Methyl Methacrylate 0.119 0.119 0.0 110 0.00 51 T n-Heptane 0.263 0.263 0.0 115 0.00 52 T cis-1,3-Dichloropropene 0.434 0.438 -0.9 113 0.00 53 T 4-Methyl-2-pentanone 0.240 0.254 -5.8 119 0.00 54 T trans-1,3-Dichloropropene 0.388 0.397 -2.3 113 0.00

R16081016.M Fri Aug 19 09:36:57 2016 Page: 1

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lusine.hakobyan

Lusine

Evaluate Continuing Calibration Report Data File: I:\MS16\DATA\2016_08\18\08181624.D Acq On : 18 Aug 2016 18:18 Operator: LH Sample : CCV2 R16081816_25ng Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 08:26:02 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 55 T 1,1,2-Trichloroethane 0.272 0.264 2.9 114 0.00 56 IR Chlorobenzene-d5 (IS3) 1.000 1.000 0.0 127 0.00 57 S Toluene-d8 (SS2) 2.487 2.391 3.9 122 0.00 58 T Toluene 2.818 2.494 11.5 112 0.00 59 T 2-Hexanone 1.371 1.309 4.5 116 -0.01 60 T Dibromochloromethane 0.803 0.732 8.8 111 0.00 61 T 1,2-Dibromoethane 0.782 0.712 9.0 112 0.00 62 T n-Butyl Acetate 1.498 1.467 2.1 117 0.00 63 T n-Octane 0.564 0.540 4.3 116 0.00 64 T Tetrachloroethene 0.888 0.774 12.8 109 0.00 65 T Chlorobenzene 1.874 1.651 11.9 110 0.00 66 T Ethylbenzene 3.132 2.899 7.4 113 0.00 67 T m- & p-Xylenes 2.481 2.252 9.2 107 0.00 68 T Bromoform 0.762 0.706 7.3 106 0.00 69 T Styrene 1.937 1.808 6.7 109 0.00 70 T o-Xylene 2.561 2.361 7.8 111 0.00 71 T n-Nonane 1.236 1.193 3.5 115 0.00 72 T 1,1,2,2-Tetrachloroethane 1.225 1.195 2.4 110 0.00 73 S Bromofluorobenzene (SS3) 0.888 0.868 2.3 121 0.00 74 T Cumene 3.278 3.005 8.3 109 0.00 75 T alpha-Pinene 1.636 1.541 5.8 110 0.00 76 T n-Propylbenzene 3.976 3.690 7.2 110 0.00 77 T 3-Ethyltoluene 3.234 3.037 6.1 109 0.00 78 T 4-Ethyltoluene 2.976 2.693 9.5 106 0.00 79 T 1,3,5-Trimethylbenzene 2.635 2.411 8.5 107 0.00 80 T alpha-Methylstyrene 1.445 1.380 4.5 106 0.00 81 T 2-Ethyltoluene 3.112 2.804 9.9 107 0.00 82 T 1,2,4-Trimethylbenzene 2.564 2.384 7.0 106 0.00 83 T n-Decane 1.345 1.351 -0.4 111 0.00 84 T Benzyl Chloride 2.031 2.102 -3.5 106 0.00 85 T 1,3-Dichlorobenzene 1.558 1.445 7.3 107 0.00 86 T 1,4-Dichlorobenzene 1.632 1.475 9.6 107 0.00 87 T sec-Butylbenzene 3.435 3.141 8.6 108 0.00 88 T 4-Isopropyltoluene (p-Cymen 3.201 2.936 8.3 106 0.00 89 T 1,2,3-Trimethylbenzene 2.647 2.457 7.2 107 0.00 90 T 1,2-Dichlorobenzene 1.502 1.385 7.8 106 0.00 91 T d-Limonene 0.951 0.953 -0.2 109 0.00 92 T 1,2-Dibromo-3-Chloropropane 0.549 0.540 1.6 105 0.00 93 T n-Undecane 1.332 1.425 -7.0 113 -0.01 94 T 1,2,4-Trichlorobenzene 1.148 1.072 6.6 106 -0.02 95 T Naphthalene 3.575 3.462 3.2 106 -0.02 96 T n-Dodecane 1.180 1.362 -15.4 113 -0.02 97 T Hexachlorobutadiene 0.807 0.683 15.4 106 0.00 98 T Cyclohexanone 0.889 0.865 2.7 114 0.00 99 T tert-Butylbenzene 2.522 2.292 9.1 106 0.00 100 T n-Butylbenzene 2.668 2.517 5.7 109 0.00 -------------------------------------------------------------------------- (#) = Out of Range SPCC's out = 0 CCC's out = 0

R16081016.M Fri Aug 19 09:36:57 2016 Page: 2

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Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181624.D Acq On : 18 Aug 2016 18:18 Operator: LH Sample : CCV2 R16081816_25ng Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 08:26:02 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 11.30 130 301827 12.500 ng 0.02 37) 1,4-Difluorobenzene (IS2) 13.42 114 1440683 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 17.72 82 624172 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 12.15 65 444378 12.481 ng 0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.84% 57) Toluene-d8 (SS2) 15.87 98 1492463 12.016 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.16% 73) Bromofluorobenzene (SS3) 19.11 174 541865 12.221 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.76% Target Compounds Qvalue 2) Propene 4.13 42 705791 23.469 ng 99 3) Dichlorodifluoromethan... 4.29 85 1608750 22.891 ng 100 4) Chloromethane 4.58 50 1068835 23.586 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.85 135 893354 22.310 ng 100 6) Vinyl Chloride 5.01 62 1242404 24.027 ng 100 7) 1,3-Butadiene 5.29 54 880958 27.480 ng 100 8) Bromomethane 5.73 94 734253 21.697 ng 100 9) Chloroethane 6.07 64 567507 24.944 ng 100 10) Ethanol 6.47 45 2748034 127.106 ng 100 11) Acetonitrile 6.72 41 1323297 24.242 ng 99 12) Acrolein 6.91 56 478293 26.809 ng 100 13) Acetone 7.12 58 2963774 135.979 ng 97 14) Trichlorofluoromethane 7.35 101 1370091 22.688 ng 100 15) 2-Propanol (Isopropanol) 7.62 45 3906424 52.571 ng 100 16) Acrylonitrile 7.89 53 1030943 26.320 ng 100 17) 1,1-Dichloroethene 8.33 96 767780 25.824 ng 98 18) 2-Methyl-2-Propanol (t... 8.50 59 3689752 52.142 ng 99 19) Methylene Chloride 8.56 84 791607 26.086 ng 98 20) 3-Chloro-1-propene (Al... 8.72 41 1042080 26.973 ng 98 21) Trichlorotrifluoroethane 8.98 151 667132 24.727 ng 97 22) Carbon Disulfide 8.83 76 2912478 23.308 ng 100 23) trans-1,2-Dichloroethene 9.84 61 1138740 26.555 ng 98 24) 1,1-Dichloroethane 10.10 63 1388332 25.363 ng 100 25) Methyl tert-Butyl Ether 10.19 73 1973591 25.284 ng 99 26) Vinyl Acetate 10.36 86 965660 144.220 ng # 91 27) 2-Butanone (MEK) 10.59 72 550541 26.463 ng 97 28) cis-1,2-Dichloroethene 11.12 61 1096136 26.606 ng 97 29) Diisopropyl Ether 11.41 87 709236 24.054 ng # 64 30) Ethyl Acetate 11.42 61 631754 57.076 ng 99 31) n-Hexane 11.40 57 1326275 26.931 ng 99 32) Chloroform 11.46 83 1373326 25.206 ng 100 34) Tetrahydrofuran (THF) 11.86 72 503805 24.331 ng 98 35) Ethyl tert-Butyl Ether 12.01 87 953226 25.240 ng 96 36) 1,2-Dichloroethane 12.26 62 993849 24.197 ng 100 38) 1,1,1-Trichloroethane 12.54 97 1188599 23.991 ng 100 39) Isopropyl Acetate 12.97 61 1109810 58.914 ng 99 40) 1-Butanol 12.99 56 1798224 61.435 ng 100 41) Benzene 13.02 78 3167403 25.709 ng 100 42) Carbon Tetrachloride 13.18 117 1087675 25.267 ng 100 43) Cyclohexane 13.31 84 2437234 51.830 ng 97 44) tert-Amyl Methyl Ether 13.66 73 2271194 25.587 ng 99 45) 1,2-Dichloropropane 13.88 63 795713 25.955 ng 99 46) Bromodichloromethane 14.07 83 1136645 25.953 ng 100 47) Trichloroethene 14.12 130 878228 23.556 ng 100 48) 1,4-Dioxane 14.09 88 674681 26.580 ng 98 49) 2,2,4-Trimethylpentane... 14.19 57 3255464 25.998 ng 99

R16081016.M Fri Aug 19 09:36:44 2016 Page: 1

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Lusine

Quantitation Report (QT Reviewed) Data File: I:\MS16\DATA\2016_08\18\08181624.D Acq On : 18 Aug 2016 18:18 Operator: LH Sample : CCV2 R16081816_25ng Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Aug 19 08:26:02 2016 Quant Method : I:\MS16\METHODS\R16081016.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Aug 11 09:14:45 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 14.32 100 715453 52.083 ng 95 51) n-Heptane 14.45 71 812215 26.785 ng 98 52) cis-1,3-Dichloropropene 14.98 75 1413188 28.236 ng 100 53) 4-Methyl-2-pentanone 15.01 58 789449 28.524 ng 99 54) trans-1,3-Dichloropropene 15.50 75 1224654 27.373 ng 100 55) 1,1,2-Trichloroethane 15.67 97 797216 25.387 ng 98 58) Toluene 15.97 91 3269384 23.233 ng 100 59) 2-Hexanone 16.21 43 1813885 26.492 ng 100 60) Dibromochloromethane 16.38 129 1005161 25.054 ng 100 61) 1,2-Dibromoethane 16.63 107 951296 24.371 ng 100 62) n-Butyl Acetate 16.84 43 2032714 27.178 ng 99 63) n-Octane 16.97 57 694221 24.646 ng 97 64) Tetrachloroethene 17.11 166 956905 21.582 ng 100 65) Chlorobenzene 17.77 112 2204623 23.557 ng 100 66) Ethylbenzene 18.12 91 3799377 24.294 ng 99 67) m- & p-Xylenes 18.29 91 5846530 47.197 ng 99 68) Bromoform 18.35 173 942902 24.786 ng 100 69) Styrene 18.60 104 2437455 25.200 ng 99 70) o-Xylene 18.71 91 3006292 23.512 ng 99 71) n-Nonane 18.90 43 1503715 24.367 ng 99 72) 1,1,2,2-Tetrachloroethane 18.69 83 1492041 24.384 ng 99 74) Cumene 19.23 105 3788308 23.143 ng 99 75) alpha-Pinene 19.58 93 1981153 24.258 ng 100 76) n-Propylbenzene 19.68 91 4606014 23.198 ng 99 77) 3-Ethyltoluene 19.77 105 3942965 24.414 ng 99 78) 4-Ethyltoluene 19.80 105 3529440 23.749 ng 99 79) 1,3,5-Trimethylbenzene 19.87 105 3130346 23.793 ng 99 80) alpha-Methylstyrene 20.01 118 1774170 24.595 ng 99 81) 2-Ethyltoluene 20.04 105 3640678 23.427 ng 99 82) 1,2,4-Trimethylbenzene 20.23 105 3095673 24.183 ng 99 83) n-Decane 20.32 57 1702806 25.356 ng 99 84) Benzyl Chloride 20.35 91 2834313 27.948 ng 98 85) 1,3-Dichlorobenzene 20.37 146 1948662 25.051 ng 100 86) 1,4-Dichlorobenzene 20.42 146 1933981 23.735 ng 100 87) sec-Butylbenzene 20.47 105 4156794 24.234 ng 99 88) 4-Isopropyltoluene (p-... 20.61 119 3665032 22.927 ng 99 89) 1,2,3-Trimethylbenzene 20.61 105 3190309 24.136 ng 99 90) 1,2-Dichlorobenzene 20.73 146 1850570 24.670 ng 100 91) d-Limonene 20.73 68 1237528 26.065 ng 98 92) 1,2-Dibromo-3-Chloropr... 21.11 157 701464 25.589 ng 97 93) n-Undecane 21.41 57 1796665 27.012 ng 98 94) 1,2,4-Trichlorobenzene 22.23 180 1392258 24.277 ng 100 95) Naphthalene 22.34 128 4321532 24.209 ng 100 96) n-Dodecane 22.33 57 1767685 30.003 ng 98 97) Hexachlorobutadiene 22.66 225 912142 22.644 ng 100 98) Cyclohexanone 18.41 55 1208983 27.225 ng 98 99) tert-Butylbenzene 20.23 119 3003769 23.850 ng 100 100) n-Butylbenzene 20.97 91 3393603 25.470 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R16081016.M Fri Aug 19 09:36:44 2016 Page: 2

100 of 105


Data File: I:\MS16\DATA\2016_08\18\08181624.D Acq On : 18 Aug 2016 18:18 Operator: LH Sample : CCV2 R16081816_25ng Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

1.25e+07

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

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chlo

roet

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,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

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moe

than

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Dib

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ochl

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ne,T

2-H

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one,

TTo

luen

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Tolu

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S2),S

1,1,

2-Tr

ichl

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than

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-Dic

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4-M

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l-2-p

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none

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n-H

epta

ne,T

Met

hyl M

etha

cryl

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lpen

tane

(Iso

octa

ne),T

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ioxa

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(SS1

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m,T

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n-H

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,TAc

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T

R16081016.M Fri Aug 19 09:36:45 2016 Page: 3

101 of 105

BFB

Data Path : I:\MS16\DATA\2016_08\10\ Data File : 08101606.D Acq On : 10 Aug 2016 14:16 Operator : LH Sample : 12.5ng TO-15 BFB Misc : S29-07291601 ALS Vial : 2 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS16\METHODS\R16081016.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Aug 11 07:35:25 2016

17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

Time-->


30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

50000

100000

150000

200000

m/z-->

Abundance Average of 19.100 to 19.111 min.: 08101606.D\data.ms (-)95

174

75

5068

876137 8156 14345 117104 130 155148135 161111 124

AutoFind: Scans 2821, 2822, 2823; Background Corrected with Scan 2813

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 16.9 | 35608 | PASS || 75 | 95 | 30 | 66 | 46.0 | 96976 | PASS || 95 | 95 | 100 | 100 | 100.0 | 210880 | PASS || 96 | 95 | 5 | 9 | 6.8 | 14276 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 96.2 | 202837 | PASS || 175 | 174 | 4 | 9 | 7.5 | 15131 | PASS || 176 | 174 | 93 | 101 | 97.2 | 197077 | PASS || 177 | 176 | 5 | 9 | 6.7 | 13155 | PASS |----------------------------------------------------------------------

R16081016.M Thu Aug 11 07:36:12 2016 Page: 1

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Lusine

BFB

Data Path : I:\MS16\DATA\2016_08\18\ Data File : 08181624.D Acq On : 18 Aug 2016 18:18 Operator : LH Sample : CCV2 R16081816_25ng Misc : S29-07291601/S29-08051601 (9/3) ALS Vial : 2 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS16\METHODS\R16081016.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Aug 11 09:14:45 2016

17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.000

2000000

4000000

6000000

8000000

1e+07

Time-->


30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

50000

100000

150000

200000

250000

300000

m/z-->

Abundance Average of 19.100 to 19.111 min.: 08181624.D\data.ms (-)95

174

75

5068

876137 8156 14345 117104 130 155148135 161111 124

AutoFind: Scans 2821, 2822, 2823; Background Corrected with Scan 2813

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 15.6 | 50632 | PASS || 75 | 95 | 30 | 66 | 43.5 | 141133 | PASS || 95 | 95 | 100 | 100 | 100.0 | 324416 | PASS || 96 | 95 | 5 | 9 | 6.6 | 21320 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 92.9 | 301397 | PASS || 175 | 174 | 4 | 9 | 7.4 | 22235 | PASS || 176 | 174 | 93 | 101 | 97.4 | 293483 | PASS || 177 | 176 | 5 | 9 | 6.7 | 19571 | PASS |----------------------------------------------------------------------

R16081016.M Fri Aug 19 09:36:30 2016 Page: 1

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Lusine

Date/Time File Name Sample ID Misc Info Operator Vial Comment1 8/10/16 11:26 08101601.D Blank (100mL) S29-07291601 LH 2

2 8/10/16 11:59 08101602.D LCS R16081016_25ng S29-07291601/S29-08041602 (9/2) LH 2

3 8/10/16 12:32 08101603.D Blank (100mL) S29-07291601 LH 2

4 8/10/16 13:05 08101604.D system blank S29-07291601 LH 2

5 8/10/16 13:43 08101605.D Blank (100mL) S29-07291601 LH 2

6 8/10/16 14:16 08101606.D 12.5ng TO-15 BFB S29-07291601 LH 2 passed

7 8/10/16 14:49 08101607.D 0.08ng TO-15 ICAL STD S29-07291601/S29-08051608 (9/3) LH 5 not used


9 8/10/16 15:56 08101609.D 0.2ng TO-15 ICAL STD S29-07291601/S29-08051608 (9/3) LH 5




13 8/10/16 18:08 08101613.D 25ng TO-15 ICAL STD S29-07291601/S29-08051601 (9/3) LH 2 R16081016.M14 8/10/16 18:41 08101614.D 50ng TO-15 ICAL STD S29-07291601/S29-08051601 (9/3) LH 2

15 8/10/16 19:15 08101615.D 100ng TO-15 ICAL STD S29-07291601/S29-08051601 (9/3) LH 2

16 8/10/16 19:48 08101616.D 25ng TO-15 ICV STD S29-07291601/S29-08041602 (9/2) LH 2 not used


18 8/11/16 8:40 08101618.D 25ng TO-15 ICV STD S29-07291601/S29-08041602 (9/2) LH 2 passed

ICAL R16081016.M passed for all compounds 0.2ng-100ng, except: MTBE, benzyl chloride and Dodecane 0.4ng-100ng.

Levels 0.08ng and 0.1ng were dropped. ICAL will not be used for low level.

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Injection Log

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Page 1 of 1105 of 105

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ATTACHMENT 4

Tier 2 Screening Risk Assessment Report (Version 8.0 & Attachment M, Revision March 2016) – Risk Tool (V1.02)


GLOSSARY – SCAQMD TIER 2 SCREENING RISK ASSESSMENT REPORT

CEF Combined Exposure Factor. The CEF for each exposure type (residential, worker) combines the default exposure parameters for Daily Breathing Rate, Age Sensitivity Factor, Exposure Duration, Fraction of Time Spent at Home, Exposure Frequency, and Averaging Time into a single value.

CP Cancer Potency. The CP factors are developed as estimates of cancer risk from exposure to a lifetime dose (i.e., 70 years) of a carcinogen.

HIA Acute Hazard Index. Total non-cancer health risk due to short term exposures (based upon a maximum one-hour emission level).

HIC Chronic Hazard Index. Total non-cancer health risk due to long term exposures (based upon an annual average emission per year).

HIC 8-hr 8-Hour Chronic Hazard Index. Total non-cancer health risk due to chronic daily 8-hour exposures (e.g., a typical worker or resident exposed to a facility that operates equal to or more than 8 hours per day and 5 days per week); based upon the daily average 8-hour exposure only for those chemicals with 8-hour RELs. There are currently only a limited number of substances with an 8-hour inhalation REL.

MICR Maximum Individual Cancer Risk – estimate of the increased risk of cancer for an individual exposed to the maximum predicted long-term toxic air contaminant concentration.

MP Multi-Pathway Adjustment Factor – used for substances that may contribute to risk from exposure pathways other than inhalation. These substances deposit on the ground in particulate form and contribute to risk through ingestion of soil or backyard garden vegetables or through other routes.

MWAF Molecular Weight Adjustment Factor. The MWAF ensures that the cancer potency factor is applied only to the fraction of the overall weight of the emissions that are associated with health effects of particular metals.

Q(lb/hr) maximum hourly emission rate, used for calculation of acute exposure

Q(ton/yr) maximum yearly emission rate, used for calculation of chronic exposure

R1 uncontrolled emission rate (pounds/hour)

R2 controlled emission rate (pounds/hour) calculated based on the Control Efficiency entered in the Emissions Worksheet

REL Reference Exposure Level – a concentration level (μg/m3) or dose (mg/kg-day) at which no adverse health effects are anticipated.

X/Q Chronic dispersion factor. Dispersion factors are numerical estimates of the amount of dispersion that occurs under specific conditions. The dispersion factor is calculated in the model based on the chosen meteorological station, source characteristics (i.e., stack height) and the receptor distance.

X/Qmax Peak hourly dispersion factor. Dispersion factors are numerical estimates of the amount of dispersion that occurs under specific conditions. The dispersion factor is calculated in the model based on the chosen meteorological station, source characteristics (i.e., stack height) and the receptor distance.

T-BACT Best Available Control Technology for Toxics – is not required if the MICR is less than or equal to one in one million. If cancer risk is greater than one in a million, T-BACT is required and must reduce risk to less than or equal to 10 in a million.

WAF Worker Adjustment Factor – the ratio between residential exposure and facility schedule, used to model a non-continuously emitting source. For screening purposes, the offsite worker schedule is assumed to always overlap with the facility’s operating schedule.

TIER 2 SCREENING RISK ASSESSMENT REPORT(Version 8.0 & Attachment M, Revision Mar 2016 ) - RiskTool (V1.02)

A/N: 123456 Application deemed complete date: 4/1/2016Fac: emaco Superfund Site

2. Tier 2 Data

Equipment Type Other No T-BACTOperation Schedule 24 hours/day; 7 days/week; 52 weeks/yearStack Height 25 ftDistance - Residential 75 mDistance - Commercial 25 mMeteorological Station Pico Rivera

Dispersion Factors tables Point SourceFor Chronic X/Q Table 3For Acute X/Q max Table 6

Dilution Factors

ReceptorΧ/Q

(µg/m³)/(tons/yr)X/Qmax

(µg/m³)/(lbs/hr)Residential 5.234 175.963Commercial - Worker 25.453 507.650

Adjustment and Intake FactorsResidential Worker

Year of Exposure 30

Combined Exposure Factor (CEF) - Table 9.1 & 9.2

676.63 56.26

Worker Adjustment Factor (WAF) - Table 10 1 1.00

Tier 2 Report - SCAQMD 2015 Risk Calculator_Aug16

Page 1 of 11 9/2/2016

A/N: 123456 04/01/16

3. Rule 1401 Compound Data

CompoundR1 -

Uncontrolled (lbs/hr)

R2 - Controlled

(lbs/hr)

CP(mg/kg-day)¯¹

MPMICR

Resident

MP MICR

Worker

MPChronic Resident

MP Chronic Worker

RELChronic(µg/m³)

REL8-hr Chronic

(µg/m³)

RELAcute

(µg/m³)MWAF

1.00 1.00 1.00 1.00 1.00E+03 6.80E+04 15.70E-03 1.00 1.00 1.00 1.00 1

1.00 1.00 1.00 1.00 7.00E+01 17.20E-02 1.00 1.00 1.00 1.00 4.00E+02 14.00E-02 1.00 1.00 1.00 1.00 8.00E+02 12.70E-02 1.00 1.00 1.00 1.00 3.00E+03 3.00E+03 1

2.83E-06 2.83E-06 1.00 1.00 1.00 1.00 1.30E+04 11.00 1.00 1.00 1.00 3.50E-01 7.00E-01 2.50E+00 1

1.00E-01 1.00 1.00 1.00 1.00 3.00E+00 3.00E+00 2.70E+01 15.21E-07 5.21E-07 1.00 1.00 1.00 1.00 8.00E+02 6.20E+03 1

1.50E-01 1.00 1.00 1.00 1.00 4.00E+01 1.90E+03 11.90E-02 1.00 1.00 1.00 1.00 3.00E+02 1.50E+02 18.70E-03 1.00 1.00 1.00 1.00 2.00E+03 13.50E-03 1.00 1.00 1.00 1.00 4.00E+02 1.40E+04 1

1.00 1.00 1.00 1.00 7.00E+03 11.20E-01 1.00 1.00 1.00 1.00 9.00E+00 1

1.00 1.00 1.00 1.00 3.00E+03 11.00 1.00 1.00 1.00 9.00E+02 2.10E+04 1

2.10E-02 1.00 1.00 1.00 1.00 3.50E+01 2.00E+04 16.97E-07 6.97E-07 1.00 1.00 1.00 1.00 3.00E+02 3.70E+04 1

7.00E-03 1.00 1.00 1.00 1.00 6.00E+02 11.00 1.00 1.00 1.00 2.00E+02 1

1.84E-06 1.84E-06 2.70E-01 1.00 1.00 1.00 1.00 1.80E+05 11.00 1.00 1.00 1.00 7.00E+02 2.20E+04 11.00 1.00 1.00 1.00 7.00E+02 2.20E+04 1

2.99E-06 2.99E-06 1.00 1.00 1.00 1.00 7.00E+03 3.20E+03 1

Application deemed complete date:

StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene

ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)

1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)


Page 2 of 11 9/2/2016

A/N: 123456 04/01/164. Emission Calculations

Compound R1 (lbs/hr) R2 (lbs/hr) R2 (lbs/yr) R2 (tons/yr)

2.83E-06 2.83E-06 2.48E-02 1.24E-05

5.21E-07 5.21E-07 4.55E-03 2.28E-06

6.97E-07 6.97E-07 6.09E-03 3.04E-06

1.84E-06 1.84E-06 1.61E-02 8.03E-06

2.99E-06 2.99E-06 2.61E-02 1.30E-05

Total 8.88E-06 8.88E-06 7.76E-02 3.88E-05


Vinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Propylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl Acetate

Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalene

p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon Disulfide

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)


Page 3 of 11 9/2/2016

TIER 2 RESULTS A/N: 123456 Application deemed complete date: 04/01/16

5a. MICRMICR Resident = CP (mg/(kg-day))^-1 * Q (ton/yr) * (X/Q) Resident * CEF Resident * MP Resident * 1e-6 * MWAFMICR Worker = CP (mg/(kg-day))^-1 * Q (ton/yr) * (X/Q) Worker * CEF Worker* MP Worker* WAF Worker* 1e-6 * MWAF

Compound Residential Commercial

NO

7.68E-09 3.10E-09

No Cancer Burden, MICR<1.0E-6

Total 7.68E-09 3.10E-09PASS PASS

X/Q for one-in-a-million (µg/m³)/(tons/yr):New Distance at which MICR is 1 in a million (m):

Cancer Burden:

Vinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

NaphthalenePropylene (Propene)

StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethylene

Carbon Disulfide

5b. Cancer Burden Calculation? NO

Zone Impact Area (km²):Population (7000 person/km²):

Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-Hexane

Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzene

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)


Page 4 of 11 9/2/2016

6. Hazard Index A/N: 123456 04/01/16HIA = [Q(lb/hr) * (X/Q)max * MWAF ]/ Acute RELHIC = [Q(ton/yr) * (X/Q) * MP * MWAF] / Chronic RELHIC 8-hr= [Q(ton/yr) * (X/Q) * WAF * MWAF] / 8-hr Chronic REL

Acute Chronic 8-hr Chronic Acute Pass/Fail

Chronic Pass/Fail

8-hr Chronic Pass/Fail

Alimentary system (liver) - AL Pass Pass PassBones and teeth - BN Pass Pass PassCardiovascular system - CV Pass Pass PassDevelopmental - DEV 5.22E-08 3.78E-07 Pass Pass PassEndocrine system - END Pass Pass PassEye 5.99E-07 Pass Pass PassHematopoietic system - HEM Pass Pass PassImmune system - IMM Pass Pass PassKidney - KID 4.74E-08 Pass Pass PassNervous system - NS 5.74E-08 3.31E-07 Pass Pass PassReproductive system - REP 5.22E-08 3.78E-07 Pass Pass PassRespiratory system - RES 5.99E-07 2.58E-07 Pass Pass PassSkin Pass Pass Pass


Target Organs


Page 5 of 11 9/2/2016

A/N: 123456 04/01/166a. Hazard Index Acute - ResidentHIA = [Q(lb/hr) * (X/Q)max resident * MWAF] / Acute REL

HIA - ResidentialCompound AL CV DEV EYE HEM IMM NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone) 3.84E-08 3.84E-08AcroleinBenzeneCarbon Disulfide 1.48E-08 1.48E-08 1.48E-08Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 3.31E-09 3.31E-09 3.31E-09 3.31E-09 3.31E-09TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene) 1.80E-09 1.80E-09 1.80E-09o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 1.64E-07 1.64E-07

Total 1.81E-08 2.08E-07 1.99E-08 1.81E-08 2.08E-07



Page 6 of 11 9/2/2016

6a. Hazard Index Acute - Worker A/N: 123456 04/01/16HIA = [Q(lb/hr) * (X/Q)max Worker * MWAF] / Acute REL

HIA - CommercialCompound AL CV DEV EYE HEM IMM NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone) 1.11E-07 1.11E-07AcroleinBenzeneCarbon Disulfide 4.26E-08 4.26E-08 4.26E-08Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 9.56E-09 9.56E-09 9.56E-09 9.56E-09 9.56E-09TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene) 5.18E-09 5.18E-09 5.18E-09o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 4.74E-07 4.74E-07

Total 5.22E-08 5.99E-07 5.74E-08 5.22E-08 5.99E-07



Page 7 of 11 9/2/2016

A/N: 123456 04/01/166b. Hazard Index Chronic - ResidentHIC = [Q(ton/yr) * (X/Q) Resident * MP Chronic Resident * MWAF] / Chronic REL

HIC - ResidentialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon Disulfide 1.49E-08 1.49E-08 1.49E-08Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 5.31E-08 5.31E-08 5.31E-08 5.31E-08TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 9.76E-09 9.76E-09 9.76E-09

Total 7.78E-08 9.76E-09 6.80E-08 7.78E-08 5.31E-08



Page 8 of 11 9/2/2016

A/N: 123456 04/01/166b. Hazard Index Chronic - WorkerHIC = [Q(ton/yr) * (X/Q) * MP Chronic Worker * MWAF] / Chronic REL

HIC - CommercialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon Disulfide 7.24E-08 7.24E-08 7.24E-08Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 2.58E-07 2.58E-07 2.58E-07 2.58E-07TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 4.74E-08 4.74E-08 4.74E-08

Total 3.78E-07 4.74E-08 3.31E-07 3.78E-07 2.58E-07



Page 9 of 11 9/2/2016

6c. 8-hour Hazard Index Chronic - Resident A/N: 123456 04/01/16HIC 8-hr = [Q(ton/yr) * (X/Q) Resident * WAF Resident * MWAF] / 8-hr Chronic REL

HIC - ResidentialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Total



Page 10 of 11 9/2/2016

A/N: 123456 04/01/166c. 8-hour Hazard Index Chronic - Worker HIC 8-hr = [Q(ton/yr) * (X/Q) Worker * WAF Worker * MWAF] / 8-hr Chronic REL

HIC - CommercialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Total



Page 11 of 11 9/2/2016


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