MONTHLY MONITORING REPORT JUNE 2016Monthly Monitoring Report June 2016 Plant Influent and Effluent...

Oneida Total Integrated Enterprises Page 1 of 11

317 E. Main Street Ventura, CA 93001

Tel: (805) 585-2110 Fax: (805) 585-2111

MONTHLY MONITORING REPORT JUNE 2016

DATE: August 5, 2016 (revised Jan 4, 2017 to correct groundwater gradient to southeasterly - see Section 2.0, 3rd line)

PREPARED FOR: Rose Marie Caraway, Remedial Project Manager/Environmental Scientist U.S. Environmental Protection Agency, Region 9 75 Hawthorne Street, SFD 7-2 San Francisco, California 94105

PREPARED BY: Max Ramos, E.I.T., Staff Environmental Engineer, OTIE John Wingate, P.E., Project Manager, OTIE Lindsey Larsen, Environmental Scientist, OTIE

RE: June 2016 Plant Influent and Effluent Sampling Results for the Pemaco Superfund Site Treatment Plant, Maywood, California

1.0 INTRODUCTION The United States Environmental Protection Agency (U.S. EPA) is currently implementing the Long-Term Response Action (LTRA) at the Pemaco Superfund Site in Maywood, California. Oneida Total Integrated Enterprises, LLC. (OTIE) performs monthly monitoring work for the U.S. EPA under contract by the United States Army Corps of Engineers (USACE), Los Angeles District Contract Number W912PL 13-D-0017, Task Order 0002.

OTIE prepared this Report to summarize the results of monthly influent and effluent water and vapor sampling performed on June 14, 2016 at the Pemaco Superfund Site Treatment Plant (Plant).

The influent and effluent water samples (SP-201 and SP-209, respectively), and influent and effluent vapor samples (SP-104 and SP-106, respectively) were analyzed for volatile organic compounds (VOCs) and 1,4-dioxane. Samples were analyzed in accordance with the Final Sampling and Analysis Plan, (Field Sampling Plan and Quality Assurance Project Plan), Long-Term Response Action for the Pemaco Remedial Action (OTIE, 2015).

Monthly water and vapor sampling is performed to demonstrate compliance with Los Angeles County Sanitation District (LACSD) limits and South Coast Air Quality Management District (SCAQMD) guidance; confirm liquid phase granular activated carbon (LGAC) and vapor phase granular activated carbon (VGAC) effectiveness; and summarize data trends necessary for evaluation of remedial progress. The metric for “mass removal” is evaluated in the Quarterly Operations and Maintenance Report.

The groundwater treatment system (GTS) and vapor treatment system (VTS) achieved operational uptimes of approximately 86% and 55%, respectively, during June 2016. The VTS was not operated June

SEMS-RM DOCID # 1163859

Monthly Monitoring Report June 2016 Plant Influent and Effluent Sampling Results Pemaco Superfund Site, Maywood, California


1 in accordance with the “pulsed” operational schedule. Additional treatment system shutdowns occurred as follows:

The VTS was not operated on June 7 due to a mounting plate failure for the fan shroud onblower B-102;

The VTS was not operated from June 10 to June 12 due to a high motor temperature fault onblower B-101;

The VTS was not operated from June 20 to June 21 due to high ambient air temperature;

The VTS was not operated from June 26 to June 27 due to an air heater failure on the vaporconditioning control panel;

GTS and VTS operation was shut down on June 28 and June 30, respectively, for the remainderof the month of June to achieve “static” conditions for the July semiannual groundwatermonitoring event.

Additional operational details are available in the most recent Operations Summary and the June weekly Quality Control Reports located on the Pemaco SharePoint website. Plant operational details will be summarized in the 2016 Second Quarter Operation and Maintenance Report.

2.0 ‘A’ ZONE GROUNDWATER LEVEL GAUGING Groundwater elevations and analytical data suggest an off-site contaminant source is located northwest of Maywood Riverfront Park, with significant trichloroethene (TCE) concentrations in the Exposition Aquifer ‘A’ Zone (OTIE, 2016a). Groundwater extraction from the ‘A’ Zone may promote a southeasterly migration of contaminants from northwest of the Park toward the former electrical resistive heating (ERH) area. In order to protect the ERH remedy area and discourage potential migration of the off-site source, the ‘A’ Zone wells were shut down on April 28, 2016 following stakeholder discussion and U.S. EPA approval. Groundwater levels in the ‘A’ Zone will be gauged monthly to monitor gradient changes while the ‘A’ Zone extraction wells remain inactive.

The June 21, 2016 ‘A’ Zone groundwater gauging event was the second groundwater level monitoring task performed since shutdown of ‘A’ Zone extraction wells in April 2016. Groundwater elevation data for the June 2016 gauging event is provided in Attachment 1. June 2016 groundwater elevations are compared to the most recent groundwater elevation data from the December 2015 semiannual groundwater monitoring event. ‘A’ Zone groundwater elevation changes at individual well locations include both increases and decreases compared to December 2015 values. The ‘A’ Zone groundwater elevation changes over time are shown in the hydrograph presented in Figure 1 (after text). The wells with the greatest change in groundwater elevation were DA-12 (3.8-foot decrease) and DA-01 (2.74-foot decrease). Evaluation of the overall ‘A’ Zone groundwater elevation trends will be included in future monthly monitoring reports following sufficient rounds of monthly gauging.

3.0 PLANT WATER SAMPLING RESULTS Influent and effluent water grab samples were collected on June 14, 2016 and the detected analytical results are summarized in Table 1. The laboratory analysis was performed by Eurofins CalScience, Inc. The laboratory reports containing the full list of analytes are provided in Attachments 2 and 3. Attachment 2 shows the analytical results for VOCs and 1,4-dioxane in sample SP-201 and for 1,4-



dioxane in SP-209. Attachment 3 shows analytical results for VOCs in sample SP-209, as well as additional data used for the 2nd Quarter 2016 Industrial Wastewater Self-Monitoring Report for the Pemaco Superfund Site Treatment Plant, Maywood, California prepared for the LACSD (OTIE, 2016b).

The influent sample results represent a composite of flow from the following active wells screened in the Perched and Exposition Zones:

Perched Zone (dual-phase extraction [DPE]): PB-01, PB-02, PB-03, PB-05, PC-06, PD-04, PD-05, PD-06, and PD-07; and

Exposition Zones (groundwater only [GW]): DB-01, DB-03, DB-04, DB-05, DB-07, and DB-09.

Table 1 Monthly Summary of Detected VOCs in Influent / Effluent Water Samples

Analyte Method

Sample Locations Sample ID

Sample Date

SP-201 (Influent) SP-201-20160614

6/14/2016 Results

SP-201 (Effluent) SP-201-20160614

6/14/2016 Results SSRL Unit

1,1-Dichloroethane SW8260B 5 μg/L <0.28 1.5**

1,4-Dioxane (P-Dioxane) SW8260SIM 1* μg/L 8.2 5.2

Chloroform SW8260B 80 μg/L <0.46 1.1**

cis-1,2-Dichloroethene SW8260B 6 μg/L 6.6 6.3

Trichloroethene SW8260B 5 μg/L 80 0.42 J

Vinyl Chloride SW8260B 0.5 μg/L <0.30 0.45 J**

Notes:

1. * - Indicates value is a "California Notification Level" which is less than the SSRL of 3.0, listed in the ROD (U.S. EPA, 2005).

2. ** - Indicates effluent sample concentration was higher than influent concentration as a result of preferential desorption.

3. Bold indicates a sample detection.

4. ID = identification; SSRL = site-specific remediation level; μg/L = micrograms per liter; < = indicates compound was not detected above the method detection limit.

5. Effluent water quality complied with the LACSD permit limit of 1,000 μg/L for total VOCs.

3.1 PROCESS WATER INFLUENT (SP-201) DISCUSSION

The following VOCs are associated with groundwater plumes being monitored as part of the semiannual groundwater monitoring program. Analytical results for samples collected during the June 2016 event for these VOCs are summarized below:

Cis-1,2-dichloroethene (cis-1,2-DCE) was detected at a concentration of 6.6 μg/L for the month of June (Figure 2). The cis-1,2-DCE concentration in process water influent shows some variation between monthly samples, although samples from the previous 24 months have not exceeded 17 μg/L. The overall cis-1,2-DCE concentration trend is relatively stable for the previous 24 months.

TCE was detected at a concentration of 80 μg/L, lower than the previous process water influent sample (84 μg/L) and within the typical range for influent TCE concentrations (Figure 3). The TCE concentration in process water influent samples from the previous 24 months shows significant variation between monthly samples, but the concentration trend over time is relatively stable.



1,4-Dioxane was detected at a concentration of 8.2 µg/L, slightly higher than the previous process water influent sample (7.9 μg/L) (Figure 4). The 1,4-dioxane concentration in process water influent from the previous 24 months shows some variation between monthly samples, with a relatively stable trend over this period of time.



Figure 2 Historical Concentrations of cis-1,2-Dichloroethene in Influent Water

Figure 3 Historical Concentrations of Trichloroethene in Influent Water

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GTS

In

flu

en

t C

on

cen

trat

ion

(µ

g/L)

Sample Date (Plant Water)

Historical Concentrations of cis-1,2-DCE

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en

t C

on

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(µ

g/L)


Historical Concentrations of TCE



Figure 4 Historical Concentrations of 1,4-Dioxane in Influent Water

Notes for Figures 2, 3, and 4:

1. Data collected over a 24 month period beginning in July 2014. Concentration values reflected on the figure represent samples collected during monthly monitoring events.

2. Values that were below the laboratory detection limit are expressed as concentrations of zero.

3. Plant influent water was not analyzed in July 2014 and November 2015.

4. The trend line represents a linear regression of 22 data points from samples collected during monthly monitoring events. The trend line is a best-fit representation of the data and serves as a forecasting tool; it is not intended to represent the mean value of all samples collected.

3.2 PROCESS WATER EFFLUENT (SP-209) DISCUSSION

The water effluent quality satisfied the LACSD permit limit for total VOCs of 1,000 μg/L. VOC concentrations in plant effluent were below their respective SSRLs, with the exception of 1,4-dioxane (5.2 μg/L), and cis-1,2-Dichloroethene (6.3 μg/L), which have low LGAC adsorptive capacities.

The LGAC performance is satisfactory because the LACSD permit limits were satisfied and filter vessels continue to operate with acceptable head loss.

4.0 PLANT VAPOR SAMPLING RESULTS The influent and effluent vapor samples were collected in 1-liter SUMMA® canisters on June 14, 2016. The analytical results for this event are summarized in Table 2. The laboratory analysis was performed by ALS Environmental and the laboratory report is provided as Attachment 4. The June 2016 influent vapor sample represents a composite of concentrations from active DPE wells (PB-01, PB-02, PB-03, PB-05, PC-06, PD-04, PD-05, PD-06, and PD-07), all screened in the Perched Zone.

8/6/14

9/3/14

10/1/14 11/3/14

12/2/14

1/19/15 2/12/15

3/5/15

4/14/15

5/15/15

6/1/15

7/23/15

8/11/15

9/3/15

10/23/15

12/2/15

1/5/16

2/12/16

3/8/16 4/6/16

5/12/16 6/14/16

0

2

4

6

8

10

12

14

16

18

20

Jul-14 Oct-14 Feb-15 May-15 Aug-15 Nov-15 Mar-16 Jun-16

Infl

ue

nt

Co

nce

ntr

atio

n (

µg/

L)


Historical Concentrations of 1,4-Dioxane



Table 2 Summary of Detected VOCs in Influent and Effluent Vapor Samples

Analyte

Sample Location Sample ID

Sample Date

SP-104 (Influent) SP-104-20160614

6/14/2016 Result

SP-106 (Effluent) SP-106-20160614

6/14/2016 Result Method Unit

1,1,1-Trichloroethane TO15 μg/m3 12 <0.63

1,1-Dichloroethane TO15 μg/m3 8.8 <0.60

1,1-Dichloroethene TO15 μg/m3 44 <0.63

1,2,4-Trimethylbenzene TO15 μg/m3 4.5 <0.56

2-Butanone TO15 μg/m3 3.8 J 0.95 J

Acetone TO15 μg/m3 35 J 4.8 J

alpha-Pinene TO15 μg/m3 <1.0 0.82 J*

Benzene TO15 μg/m3 17 <0.60

Chloroform TO15 μg/m3 15 <0.63

cis-1,2-Dichloroethene TO15 μg/m3 65 <0.60

Cumene TO15 μg/m3 1.3 J 1.5 J**

Cyclohexane TO15 μg/m3 130 <1.1

Dichlorodifluoromethane TO15 μg/m3 2.0 J 1.8 J

Ethanol TO15 μg/m3 16 J 18 J**

Ethylbenzene TO15 μg/m3 2.1 J 0.85 J

Isopropylbenzene TO15 μg/m3 1.3 J 1.5 J**

Limonene TO15 μg/m3 <1.0 1.3 J**

Naphthalene TO15 μg/m3 21 0.80 J

N-Heptane TO15 μg/m3 42 <0.63

N-Hexane TO15 μg/m3 150 <0.56

N-Octane TO15 μg/m3 6.8 <0.67

N-Propylbenzene TO15 μg/m3 3.9 <0.60

o-Xylene TO15 μg/m3 <1.1 0.64 J*

Tetrachloroethene TO15 μg/m3 240 <0.52

Tetrahydrofuran TO15 μg/m3 2.7 J <0.75

Toluene TO15 μg/m3 <1.2 1.1 J*

trans-1,2-Dichloroethene TO15 μg/m3 3.5 J <0.71

Trichloroethene TO15 μg/m3 1200 <0.52

Vinyl chloride TO15 μg/m3 3.0 J 1.7 J

Xylenes, m & p TO15 μg/m3 <2.2 1.2 J*

Notes:

1. * - Indicates a compound detected in effluent sample and not in influent sample as a result of higher detection limits for influent analysis.

2. ** - Indicates effluent sample concentration was higher than influent sample concentration as a result of preferential desorption.

3. Bold indicates sample detection.

4. ID = identification; J = estimated value; μg/m3 = micrograms per cubic meter; < = indicates compound was not detected

above the method detection limits.

5. A complete listing of analytes is found in the laboratory report (Attachment 4).



4.1 PROCESS VAPOR INFLUENT (SP-204) DISCUSSION

Influent vapor concentrations over the previous 24 months are presented in Figure 5. The sum of VOCs detected in plant vapor influent shows a decreasing trend. The trend is influenced by the high VOC concentrations detected during the months of January and February 2015. This concentration spike was associated with prolonged shutdown of the VTS system from December 4, 2014 to January 16, 2015 to facilitate removal of the Flameless Thermal Oxidizer. Influent vapor VOC concentrations since the June 2015 sampling event have been consistent with influent vapor VOC concentrations prior to the VTS shutdown.

The COCs with highest concentrations in the vapor influent were: TCE (1200 μg/m3), tetrachloroethene (PCE) (240 μg/m3), n-hexane (150 μg/m3), cyclohexane (130 μg/m3), cis-1,2-Dichloroethene (65 μg/m3) and 1,1-Dichloroethene (44 μg/m3).

Figure 5 Historical Influent VOC Concentrations in Vapor

Notes:

1. Monthly data collected over a 24 month period beginning in July 2014. Concentration values reflected on the figure represent samples collected during monthly monitoring events.

2. Plant influent vapor was not analyzed in July 2014 and November 2015.

3. The trend line represents a linear regression of 22 data points from samples collected during monthly monitoring events. The trend line is a best-fit representation of the data and serves as a forecasting tool; it is not intended to represent the mean value of all samples collected.

8/6/14 9/3/14 12/3/14

4/6/16 11/3/14

1/21/15

2/12/15

3/5/15 4/14/15

5/15/15

6/1/15

7/23/15

8/11/15

10/1/14 10/23/15

12/3/15

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2/15/16 6/14/16

0

10000

20000

30000

40000

50000

60000

70000

Jul-14 Oct-14 Feb-15 May-15 Aug-15 Nov-15 Mar-16 Jun-16

VTS

In

flu

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t C

on

cen

trat

ion

(µ

g/L)

Sample Date (Plant Vapor)

Historical Influent VOC Concentrations



4.2 PROCESS VAPOR EFFLUENT (SP-208) DISCUSSION

Plant air effluent is not formally permitted but does comply with SCAQMD permit guidance for human health risk assessment. Tier 2 Screening Risk Assessment for the Pemaco Site was formerly conducted using risk assessment methods prescribed in the 2005 SCAQMD Risk Assessment Procedures (SCAQMD, 2005). Updated risk assessment procedures which utilize revised risk assessment methodologies were introduced by SCAQMD in June 20151 (SCAQMD, 2015). Details regarding the updated methodologies and the effect on risk modeling for Site vapor effluent are discussed in the Technical Memorandum, Update to the Human Health Risk Screening Procedures for Treatment Vapor Effluent, Pemaco Superfund Site, Maywood, California (OTIE, 2016c). A Tier 2 Screening Risk Assessment Report based on the 2015 SCAQMD procedures is included in Attachment 5 and demonstrates plant vapor emission compliance with the 2015 SCAQMD permit guidance. The Tier 2 Screening Risk Assessment Report was generated using the SCAQMD Risk Tool (V1.02) Microsoft excel spreadsheet distributed on the SCAQMD website (SCAQMD, 2016).

A summary of the results from the Tier 2 Air Screening Risk Assessment is presented in Table 3. The maximum incremental cancer risk (MICR) associated with potential exposure to toxic air contaminants (TACs) is roughly three orders of magnitude less than the U.S. EPA acceptable cancer risk of “one in a million” (1 x 10-6) for both residential and worker receptors. Calculated non-cancer hazard indices (chronic hazard index [HIc], acute hazard index [HIa], and 8-hour chronic hazard index [HI8]) associated with potential exposure to TACs are less than the established limit of one.

Table 3 Summary of Tier 2 Screening Risk Assessment Health Risk Values

Maximum Individual Cancer Risk (MICR)

Chronic Hazard Index (HIc)

Acute Hazard Index (HIa)

8-Hour Chronic Hazard Index (HI8)

Receptor1 Resident Worker Resident Worker Resident Worker Resident Worker

Maximum Health Risk Value

5.17E-09

2.09E-09 1.29E-06 6.29E-06 2.05E-08 5.91E-08 0.00 0.00

Notes:

1. Health risk values are calculated for residential receptors at a distance of 75 meters from the plant vapor effluent stack and for commercial (worker) receptors at a distance of 25 meters from the plant vapor effluent stack.

2. Health risk values were calculated with the SCAQMD Risk Tool (V1.02) (SCAQMD, 2016) using analytical data from the June 14, 2016 vapor effluent sample. The full Tier 2 Screening Risk Assessment Report is provided in Attachment 5.

Destruction removal efficiency (DRE) is typically calculated to evaluate the performance of the VGAC and the vapor conditioning package. The DRE equals the mass difference between the influent and effluent divided by the total mass in the influent. The sum of VOCs detected in the influent was 2031 μg/m3; the sum of VOCs detected in the effluent was 37 μg/m3. The resulting DRE of 98% for June 2016 is above average and higher than the previous month (76%), representing the continued return to typical operational values following abnormally low DRE values for the months of March and April (-315% and -38%, respectively). The increased DRE value is a response to VGAC changeout that was performed on May 10, 2016. OTIE oversaw replacement of spent carbon in one of the 4,000-pound VGAC vessels (T-

1 The Pemaco Final Remedial Design Report (TN&A, 2006) indicated that the VTS will meet the substantive

requirements of the SCAQMD Risk Assessment Procedures for Rules 1401 and 212, Version 7.0 (SCAQMD, 2005). Monthly plant vapor effluent monitoring is evaluated according to the June 2015 updated SCAQMD Risk Assessment Procedures for Rules 1401, 1401.1 and 212, Version 8.0 (SCAQMD, 2015) in order to document that continued operation of the VTS is protective of human health.



301) by subcontractor Prominent Systems. The work was documented in Weekly Quality Control Field Report #379 and will be discussed further in the Second Quarter Operations and Maintenance Report.

5.0 CONCLUSIONS During the month of June, the GTS achieved an uptime of 86% and the VTS achieved an uptime

of 55%;

June ‘A’ Zone groundwater elevation measurements were collected approximately two months following shutdown of the ‘A’ Zone groundwater extraction wells. Elevation trends will be evaluated following additional rounds of monthly gauging;

Results of the June 2016 plant water and vapor sampling conducted on June 14, 2016 confirmed compliance with LACSD permit limits and 2005 SCAQMD permit guidance;

Concentrations of VOCs in influent water and vapor samples were generally within the range of typical concentrations detected during previous monthly sampling events;

The LGAC performance is satisfactory because the LACSD permit limits were satisfied and filter vessels continue to operate with acceptable head loss; and

Vapor effluent VOC concentrations and DRE values returned to satisfactory levels during the June monthly sampling event following changeout of the VGAC on May 10, 2016.

6.0 REFERENCES Earth Tech, Inc. 2007. SCAQMD – Tier 2 Toxic Air Contaminant Emissions Modeling, Pemaco Superfund

Site, 5050 East Slauson Avenue, Maywood, California. February.

Oneida Total Integrated Enterprises (OTIE). 2015. Final Sampling and Analysis Plan (Field Sampling Plan

and Quality Assurance Project Plan), Long-Term Response Action for the Pemaco Remedial

Action. September.

_____. 2016a. Draft Semiannual Groundwater Monitoring Report, December 2015 Monitoring Event for

the Pemaco Superfund Site Treatment Plant, Maywood, California. April.

_____. 2016b. 2nd Quarter 2016 Industrial Wastewater Self-Monitoring Report for the Pemaco Superfund

Site Treatment Plant, Maywood, California. July 1.

_____. 2016c. Technical Memorandum, Update to the Human Health Risk Screening Procedures for

Treatment Plant Vapor Effluent, Pemaco Superfund Site, Maywood, California. July 15.

South Coast Air Quality Management District (SCAQMD). 2005. Risk Assessment Procedures for Rules

1401 and 212 Version 7.0, Permit Application Package “L” Rules 1401 and 212 Version 7.0.

July 1.

_____. 2015. Risk Assessment Procedures for Rules 1401, 1401.1 and 212. Version 8.0. June 5.



_____. 2016. Rule 1401 Risk Assessment Program, Risk Tool (V1.02), Version 8.0 & Attachment M,

Revision March 2016. Available online at http://www.aqmd.gov/home/permits/risk-assessment.

Accessed 4 April 2016.

United States Environmental Protection Agency (U.S. EPA). 2005. Record of Decision, Pemaco Maywood

Superfund Site, Maywood, California. EPA ID: CAD980737092. January 13.

FIGURES (AFTER TEXT)

Figure 1 Exposition ‘A’ Zone Hydrograph

ATTACHMENTS

Attachment 1 June 2016 ‘A’ Zone Groundwater Gauging Results

Attachment 2 Lab Report from Eurofins CalScience, Inc. – SP-201 VOC & 1,4-dioxane analysis; SP-209 1,4-dioxane analysis

Attachment 3 Lab Report from Eurofins CalScience, Inc. – SP-209 VOC analysis

Attachment 4 Lab Report from ALS Environmental

Attachment 5 Tier 2 Screening Risk Assessment Report (Version 8.0 & Attachment M, Revision March 2016) – Risk Tool (V1.02)

http://www.aqmd.gov/home/permits/risk-assessment

FIGURE 1

Exposition 'A' Zone Hydrograph

67

69

71

73

75

77

79

81

7/15/2015 9/3/2015 10/23/2015 12/12/2015 1/31/2016 3/21/2016 5/10/2016 6/29/2016 8/18/2016

Groundwater Elevation (feet ab

ove

mean

sea level)

Date Gauged

Figure 1Exposition 'A' Zone Hydrograph

Pemaco Superfund Site, Maywood, California

DA‐01DA‐02DA‐03DA‐04DA‐05DA‐06DA‐07DA‐08DA‐09DA‐10DA‐11DA‐12MW‐01‐80MW‐03‐70MW‐04‐75MW‐07‐75MW‐08‐70MW‐09‐70MW‐10‐75MW‐12‐70MW‐14‐80MW‐19‐70MW‐20‐70MW‐21‐80MW‐22‐75MW‐26‐75MW‐27‐70MW‐36‐80MW‐37‐80MW‐38‐80RW‐01‐70Dry

'A' Zone extraction wells shut down (4/28/2016)

Notes:1. Data points are not shown when the groundwater elevations could not be determined due to the presence of a dedicated sampling pump.2. "Dry" data points are displayed at the elevation of the bottom of the screened interval.


ATTACHMENT 1

June 2016 'A' Zone Groundwater Gauging Results

Attachment1June2016'A'ZoneGroundwaterGaugingResultsPemacoSuperfundSite,Maywood,California

Depth to

Water

(ft btoc)

Groundwater

Elevation

(ft amsl)

Depth to

Water

(ft btoc)

Groundwater

Elevation

(ft amsl)

1 MW‐01‐80 Monitoring A Zone 59 ‐ 79 75.48 73.08 75.61 72.95 ‐0.13

2 MW‐03‐70 Monitoring A Zone 60 ‐ 70 Dry ‐‐ Dry ‐‐ ‐‐3 MW‐04‐75 Monitoring A Zone 65 ‐ 75 70.75 75.32 71.54 74.53 ‐0.79


5 MW‐08‐70 Monitoring A Zone 63 ‐ 68 * ‐‐ * ‐‐ ‐‐6 MW‐09‐70 Monitoring A Zone 65 ‐ 70 * ‐‐ * ‐‐ ‐‐7 MW‐10‐75 Monitoring A Zone 68 ‐ 73 67.73 72.89 * ‐‐ ‐‐8 MW‐12‐70 Monitoring A Zone 65 ‐ 70 * ‐‐ * ‐‐ ‐‐9 MW‐14‐80 Monitoring A Zone 76 ‐ 81 75.67 73.88 75.8 73.75 ‐0.13

10 MW‐19‐70 Monitoring A Zone 62 ‐ 67 Dry ‐‐ Dry ‐‐ ‐‐11 MW‐20‐70 Monitoring A Zone 63 ‐ 68 Dry ‐‐ Dry ‐‐ ‐‐12 MW‐21‐80 Monitoring A Zone 68 ‐ 78 74.16 74.23 74.25 74.14 ‐0.09

13 MW‐22‐75 Monitoring A Zone 69 ‐ 74 Dry ‐‐ Dry ‐‐ ‐‐14 MW‐26‐75 Monitoring A Zone 65 ‐ 75 * ‐‐ 74.07 72.03 ‐‐15 MW‐27‐70 Monitoring A Zone 60 ‐ 70 Dry ‐‐ Dry ‐‐ ‐‐16 RW‐01‐70 Monitoring A Zone 55 ‐ 70 Dry ‐‐ 67.79 78.52 2.21

17 WW‐MW‐30A Monitoring A Zone 61 ‐ 66 NM ‐‐ 65.69 75.15 ‐‐18 MW‐36‐80 Monitoring A Zone 67.5 ‐ 77.5 69.15 74.83 69.34 74.64 ‐0.19


20 MW‐38‐80 Monitoring A Zone 67.5 ‐ 77.5 69.51 73.02 69.62 72.91 ‐0.11

21 DA‐01 Extraction A Zone 61 ‐ 76 68.11 72.60 70.85 69.86 ‐2.74



24 DA‐04 Extraction A Zone 56 ‐ 66 Dry ‐‐ Dry ‐‐ ‐‐25 DA‐05 Extraction A Zone 68 ‐ 78 * ‐‐ 70.35 70.96 ‐‐26 DA‐06 Extraction A Zone 60 ‐ 70 Dry ‐‐ Dry ‐‐ ‐‐27 DA‐07 Extraction A Zone 61 ‐ 71 Dry ‐‐ Dry ‐‐ ‐‐28 DA‐08 Extraction A Zone 65 ‐ 75 * ‐‐ 67.61 73.02 ‐‐29 DA‐09 Extraction A Zone 66 ‐ 76 Dry ‐‐ Dry ‐‐ ‐‐20 DA‐10 Extraction A Zone 66 ‐ 76 Dry ‐‐ Dry ‐‐ ‐‐21 DA‐11 Extraction A Zone 64 ‐ 74 NM ‐‐ Dry ‐‐ ‐‐32 DA‐12 Extraction A Zone 66 ‐ 76 65.58 78.04 69.38 74.24 ‐3.8

Notes:

1) Gauging data from the December 2015 semiannual groundwater monitoring event under dynamic (pumping) conditions.

3) "*" indicates the water level could not be determined due to the presence of an in‐well pump.

Acronyms: amsl = above mean sea level; btoc = below top of casing; ft = feet; NM = not measured; "‐‐" = not available.

Change in GW

Elevation

2) Gauging data from June 21, 2016 under static (non‐pumping) conditions. 'A' Zone groundwater extraction wells were shut down on April 28,2016.

Well ID Well Type

Associated

Zone

December 4, 20151

Screen

Interval

(ft btoc)

June 21, 20162

OTIE Page 1 of 1

ATTACHMENT 2

Lab Report from Eurofins CalScience, Inc. SP‐201 VOC & 1,4‐dioxane analysis

SP‐209 1,4‐dioxane analysis

WORK ORDER NUMBER: 16-06-0992

Analytical Report ForClient: OTIE

Client Project Name: Pemaco - Quarterly / 2014166Attention: Orval Osborne

317 East Main StreetVentura, CA 93001-2624

Approved for release on by:Virendra PatelProject Manager

AIR SOIL WATER MARINE CHEMISTRY

Eurofins Calscience, Inc. (Calscience) certifies that the test results provided in this report meet all NELAC requirements for parameters for which accreditation isrequired or available. Any exceptions to NELAC requirements are noted in the case narrative. The original report of subcontracted analyses, if any, is attached tothis report. The results in this report are limited to the sample(s) tested and any reproduction thereof must be made in its entirety. The client or recipient of thisreport is specifically prohibited from making material changes to said report and, to the extent that such changes are made, Calscience is not responsible, legally orotherwise. The client or recipient agrees to indemnify Calscience for any defense to any litigation which may arise.

06/28/2016

Page 1 of 23

mailto:[email protected]

https://www.calscience.com/clientwebaccess/login.aspx

Contents

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Client Project Name: Pemaco - Quarterly / 2014166

Work Order Number: 16-06-0992

1 Work Order Narrative. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

2 Sample Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

3 QC Association Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

4 Detections Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

5 Client Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75.1 EPA 8260 SIM 1,4-Dioxane (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75.2 EPA 8260B Volatile Organics (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

6 Quality Control Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126.1 MS/MSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126.2 LCS/LCSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

7 Sample Analysis Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

8 Glossary of Terms and Qualifiers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

9 Chain-of-Custody/Sample Receipt Form. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

Page 2 of 23

Condition Upon Receipt: Samples were received under Chain-of-Custody (COC) on 06/14/16. They were assigned to Work Order 16-06-0992. Unless otherwise noted on the Sample Receiving forms all samples were received in good condition and within the

recommended EPA temperature criteria for the methods noted on the COC. The COC and Sample Receiving Documents are

integral elements of the analytical report and are presented at the back of the report. Holding Times: All samples were analyzed within prescribed holding times (HT) and/or in accordance with the Calscience Sample Acceptance

Policy unless otherwise noted in the analytical report and/or comprehensive case narrative, if required. Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15

minutes (40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being

received outside of the stated holding time unless received at the laboratory within 15 minutes of the collection time. Quality Control: All quality control parameters (QC) were within established control limits except where noted in the QC summary forms or

described further within this report. Subcontractor Information: Unless otherwise noted below (or on the subcontract form), no samples were subcontracted. Additional Comments: Air - Sorbent-extracted air methods (EPA TO-4A, EPA TO-10, EPA TO-13A, EPA TO-17): Analytical results are converted from

mass/sample basis to mass/volume basis using client-supplied air volumes. Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC

results are always reported on a wet weight basis.

Work Order Narrative


Work Order: 16-06-0992 Page 1 of 1

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Sample Identification Lab Number Collection Date and Time Number ofContainers

Matrix

SP-201-20160614 16-06-0992-1 06/14/16 07:30 15 Aqueous

SP-209-20160614 16-06-0992-2 06/14/16 08:30 10 Aqueous

Sample Summary


Client: OTIE

317 East Main Street

Ventura, CA 93001-2624

Work Order: 16-06-0992

Project Name: Pemaco - Quarterly / 2014166

PO Number:

Date/TimeReceived:

06/14/16 12:30

Number ofContainers:

25

Attn: Orval Osborne

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Client Sample ID Method Name Type Ext Name Instrument MS/MSD/SDP LCS/LCSD

SP-201-20160614 EPA 8260 SIM 1,4-Dioxane EPA 5030C GC/MS M 160615S023 160615L049

SP-201-20160614 EPA 8260B Volatile Organics EPA 5030C GC/MS PP 160615S004 160615L014

SP-209-20160614 EPA 8260 SIM 1,4-Dioxane EPA 5030C GC/MS M 160615S023 160615L049

QC Association Summary



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Subcontracted analyses, if any, are not included in this summary.

SP-201-20160614 (16-06-0992-1)

1,4-Dioxane 8.2 1.0 ug/L EPA 8260 SIM EPA 5030C

c-1,2-Dichloroethene 6.6 1.0 ug/L EPA 8260B EPA 5030C

Trichloroethene 80 1.0 ug/L EPA 8260B EPA 5030C

SP-209-20160614 (16-06-0992-2)

1,4-Dioxane 5.2 1.0 ug/L EPA 8260 SIM EPA 5030C

Detections Summary


Client: OTIE




Project Name: Pemaco - Quarterly / 2014166

Received: 06/14/16

Attn: Orval Osborne Page 1 of 1

Client SampleID

Analyte Result Qualifiers RL Units Method Extraction

* MDL is shown

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Client Sample Number Lab SampleNumber

Date/TimeCollected

Matrix Instrument DatePrepared

Date/TimeAnalyzed

QC Batch ID

SP-201-20160614 16-06-0992-1-A 06/14/1607:30

Aqueous GC/MS M 06/15/16 06/15/1614:20

160615L049

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

1,4-Dioxane 8.2 1.0 0.35 1.00

Surrogate Rec. (%) Control Limits Qualifiers

1,4-Dichlorobutane 106 80-120

SP-209-20160614 16-06-0992-2-D 06/14/1608:30

Aqueous GC/MS M 06/15/16 06/15/1614:49

160615L049



1,4-Dioxane 5.2 1.0 0.35 1.00



Method Blank 099-16-536-77 N/A Aqueous GC/MS M 06/15/16 06/15/1613:51

160615L049



1,4-Dioxane ND 1.0 0.35 1.00



Analytical Report


OTIE



Date Received: 06/14/16


Preparation: EPA 5030C

Method: EPA 8260 SIM

Units: ug/L

Project: Pemaco - Quarterly / 2014166 Page 1 of 1

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-201-20160614 16-06-0992-1-A 06/14/1607:30

Aqueous GC/MS PP 06/15/16 06/15/1611:02

160615L014



Acetone ND 20 10 1.00

Benzene ND 0.50 0.14 1.00

Bromobenzene ND 1.0 0.30 1.00

Bromochloromethane ND 1.0 0.48 1.00

Bromodichloromethane ND 1.0 0.21 1.00

Bromoform ND 1.0 0.50 1.00

Bromomethane ND 10 3.9 1.00

2-Butanone ND 10 4.4 1.00

n-Butylbenzene ND 1.0 0.23 1.00

sec-Butylbenzene ND 1.0 0.25 1.00

tert-Butylbenzene ND 1.0 0.28 1.00

Carbon Disulfide ND 10 4.1 1.00

Carbon Tetrachloride ND 0.50 0.23 1.00

Chlorobenzene ND 1.0 0.17 1.00

Chloroethane ND 5.0 2.3 1.00

Chloroform ND 1.0 0.46 1.00

Chloromethane ND 10 3.5 1.00

2-Chlorotoluene ND 1.0 0.24 1.00


Dibromochloromethane ND 1.0 0.25 1.00

1,2-Dibromo-3-Chloropropane ND 5.0 1.2 1.00

1,2-Dibromoethane ND 1.0 0.36 1.00

Dibromomethane ND 1.0 0.46 1.00

1,2-Dichlorobenzene ND 1.0 0.46 1.00



Dichlorodifluoromethane ND 1.0 0.46 1.00

1,1-Dichloroethane ND 1.0 0.28 1.00


1,1-Dichloroethene ND 1.0 0.43 1.00

c-1,2-Dichloroethene 6.6 1.0 0.48 1.00

t-1,2-Dichloroethene ND 1.0 0.37 1.00

1,2-Dichloropropane ND 1.0 0.42 1.00


Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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1,1-Dichloropropene ND 1.0 0.46 1.00

c-1,3-Dichloropropene ND 0.50 0.25 1.00

t-1,3-Dichloropropene ND 0.50 0.25 1.00

Ethylbenzene ND 1.0 0.14 1.00

2-Hexanone ND 10 4.2 1.00

Isopropylbenzene ND 1.0 0.58 1.00

p-Isopropyltoluene ND 1.0 0.16 1.00

Methylene Chloride ND 10 3.8 1.00

4-Methyl-2-Pentanone ND 10 4.4 1.00

Naphthalene ND 10 5.0 1.00

n-Propylbenzene ND 1.0 0.17 1.00

Styrene ND 1.0 0.17 1.00

1,1,1,2-Tetrachloroethane ND 1.0 0.40 1.00


Tetrachloroethene ND 1.0 0.39 1.00

Toluene ND 1.0 0.24 1.00

1,2,3-Trichlorobenzene ND 1.0 0.51 1.00


1,1,1-Trichloroethane ND 1.0 0.30 1.00

1,1,2-Trichloro-1,2,2-Trifluoroethane ND 10 3.9 1.00


Trichloroethene 80 1.0 0.37 1.00

Trichlorofluoromethane ND 10 3.3 1.00

1,2,3-Trichloropropane ND 5.0 0.64 1.00

1,2,4-Trimethylbenzene ND 1.0 0.36 1.00


Vinyl Acetate ND 10 5.6 1.00

Vinyl Chloride ND 0.50 0.30 1.00

p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00

Methyl-t-Butyl Ether (MTBE) ND 1.0 0.31 1.00


1,4-Bromofluorobenzene 103 80-120

Dibromofluoromethane 106 78-126

1,2-Dichloroethane-d4 103 75-135

Toluene-d8 102 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

Method Blank 099-14-001-20630 N/A Aqueous GC/MS PP 06/15/16 06/15/1610:33

160615L014




Benzene ND 0.50 0.14 1.00





























c-1,2-Dichloroethene ND 1.0 0.48 1.00




Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Styrene ND 1.0 0.17 1.00




Toluene ND 1.0 0.24 1.00






Trichloroethene ND 1.0 0.37 1.00







p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00






Toluene-d8 102 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed MS/MSD Batch Number

SP-201-20160614 Sample Aqueous GC/MS M 06/15/16 06/15/16 14:20 160615S023

SP-201-20160614 Matrix Spike Aqueous GC/MS M 06/15/16 06/15/16 15:18 160615S023

SP-201-20160614 Matrix Spike Duplicate Aqueous GC/MS M 06/15/16 06/15/16 15:47 160615S023

Parameter SampleConc.

SpikeAdded

MSConc.

MS%Rec.

MSDConc.

MSD%Rec.

%Rec. CL RPD RPD CL Qualifiers

1,4-Dioxane 8.158 20.00 26.69 93 28.93 104 70-130 8 0-20

Quality Control - Spike/Spike Duplicate


OTIE








RPD: Relative Percent Difference. CL: Control Limits

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SP-201-20160614 Sample Aqueous GC/MS M 06/15/16 06/15/16 14:20 160615S023

SP-201-20160614 Matrix Spike Aqueous GC/MS M 06/15/16 06/15/16 15:18 160615S023

SP-201-20160614 Matrix Spike Duplicate Aqueous GC/MS M 06/15/16 06/15/16 15:47 160615S023

Parameter Spike Added MS Conc. MS %Rec. MSD Conc. MSD %Rec. %Rec. CL Qualifiers

1,4-Dichlorobutane 8.000 7.671 96 8.510 106 80-120

Spike/Spike Duplicate - Surrogate


OTIE









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SP-201-20160614 Sample Aqueous GC/MS PP 06/15/16 06/15/16 11:02 160615S004

SP-201-20160614 Matrix Spike Aqueous GC/MS PP 06/15/16 06/15/16 11:32 160615S004

SP-201-20160614 Matrix Spike Duplicate Aqueous GC/MS PP 06/15/16 06/15/16 12:02 160615S004


SpikeAdded

MSConc.

MS%Rec.

MSDConc.

MSD%Rec.


Benzene ND 50.00 54.00 108 53.18 106 74-122 2 0-21

Carbon Tetrachloride ND 50.00 73.38 147 73.03 146 60-144 0 0-21 3

Chlorobenzene ND 50.00 51.56 103 51.24 102 73-120 1 0-22

1,2-Dibromoethane ND 50.00 53.44 107 52.59 105 80-122 2 0-20

1,2-Dichlorobenzene ND 50.00 49.16 98 49.84 100 70-120 1 0-26

1,2-Dichloroethane ND 50.00 54.29 109 54.23 108 64-142 0 0-20

1,1-Dichloroethene ND 50.00 62.58 125 63.27 127 52-136 1 0-21

Ethylbenzene ND 50.00 53.55 107 52.11 104 77-125 3 0-24

Toluene ND 50.00 56.10 112 54.90 110 72-126 2 0-23

Trichloroethene 79.84 50.00 133.2 107 133.2 107 74-128 0 0-22

Vinyl Chloride ND 50.00 53.64 107 53.08 106 67-133 1 0-20

p/m-Xylene ND 100.0 102.1 102 99.62 100 63-129 2 0-25

o-Xylene ND 50.00 53.27 107 52.70 105 62-128 1 0-24

Methyl-t-Butyl Ether (MTBE) ND 50.00 50.62 101 51.02 102 68-134 1 0-21



OTIE






Method: EPA 8260B



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SP-201-20160614 Sample Aqueous GC/MS PP 06/15/16 06/15/16 11:02 160615S004

SP-201-20160614 Matrix Spike Aqueous GC/MS PP 06/15/16 06/15/16 11:32 160615S004

SP-201-20160614 Matrix Spike Duplicate Aqueous GC/MS PP 06/15/16 06/15/16 12:02 160615S004

Parameter Spike Added MS Conc. MS %Rec. MSD Conc. MSD %Rec. %Rec. CL Qualifiers

1,4-Bromofluorobenzene 50.00 51.37 103 50.77 102 80-120

Dibromofluoromethane 50.00 53.35 107 53.52 107 78-126

1,2-Dichloroethane-d4 50.00 52.01 104 52.51 105 75-135

Toluene-d8 50.00 51.61 103 50.33 101 80-120

Spike/Spike Duplicate - Surrogate


OTIE






Method: EPA 8260B



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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed LCS Batch Number

099-16-536-77 LCS Aqueous GC/MS M 06/15/16 06/15/16 12:46 160615L049

Parameter Spike Added Conc. Recovered LCS %Rec. %Rec. CL Qualifiers

1,4-Dioxane 20.00 18.81 94 80-120

Quality Control - LCS


OTIE









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099-16-536-77 LCS Aqueous GC/MS M 06/15/16 06/15/16 12:46 160615L049

Parameter Spike Added LCS Conc. LCS %Rec. %Rec. CL Qualifiers

1,4-Dichlorobutane 8.000 7.608 95 80-120

LCS Only - Surrogate


OTIE









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Total number of LCS compounds: 14

Total number of ME compounds: 0

Total number of ME compounds allowed: 1

LCS ME CL validation result: Pass


099-14-001-20630 LCS Aqueous GC/MS PP 06/15/16 06/15/16 09:34 160615L014

Parameter Spike Added Conc. Recovered LCS %Rec. %Rec. CL ME CL Qualifiers

Benzene 50.00 51.38 103 80-120 73-127

Carbon Tetrachloride 50.00 67.39 135 67-139 55-151

Chlorobenzene 50.00 50.02 100 78-120 71-127

1,2-Dibromoethane 50.00 52.86 106 80-120 73-127

1,2-Dichlorobenzene 50.00 48.99 98 63-129 52-140

1,2-Dichloroethane 50.00 52.98 106 70-130 60-140

1,1-Dichloroethene 50.00 57.05 114 66-126 56-136

Ethylbenzene 50.00 50.26 101 80-123 73-130

Toluene 50.00 52.54 105 80-120 73-127

Trichloroethene 50.00 53.58 107 80-122 73-129

Vinyl Chloride 50.00 46.81 94 70-130 60-140

p/m-Xylene 100.0 96.98 97 75-123 67-131

o-Xylene 50.00 50.87 102 74-122 66-130

Methyl-t-Butyl Ether (MTBE) 50.00 49.97 100 69-129 59-139



OTIE






Method: EPA 8260B



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099-14-001-20630 LCS Aqueous GC/MS PP 06/15/16 06/15/16 09:34 160615L014

Parameter Spike Added LCS Conc. LCS %Rec. %Rec. CL Qualifiers

1,4-Bromofluorobenzene 50.00 51.51 103 80-120

Dibromofluoromethane 50.00 52.13 104 78-126

1,2-Dichloroethane-d4 50.00 51.18 102 75-135

Toluene-d8 50.00 50.71 101 80-120

LCS Only - Surrogate


OTIE






Method: EPA 8260B



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Method Extraction Chemist ID Instrument Analytical Location

EPA 8260 SIM EPA 5030C 486 GC/MS M 2

EPA 8260B EPA 5030C 927 GC/MS PP 2

Sample Analysis Summary Report



Location 2: 7445 Lampson Avenue, Garden Grove, CA 92841

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Qualifiers Definition

* See applicable analysis comment.

< Less than the indicated value.

> Greater than the indicated value.

1 Surrogate compound recovery was out of control due to a required sample dilution. Therefore, the sample data was reported without furtherclarification.

2 Surrogate compound recovery was out of control due to matrix interference. The associated method blank surrogate spike compound wasin control and, therefore, the sample data was reported without further clarification.

3 Recovery of the Matrix Spike (MS) or Matrix Spike Duplicate (MSD) compound was out of control due to suspected matrix interference. Theassociated LCS recovery was in control.

4 The MS/MSD RPD was out of control due to suspected matrix interference.

5 The PDS/PDSD or PES/PESD associated with this batch of samples was out of control due to suspected matrix interference.

6 Surrogate recovery below the acceptance limit.

7 Surrogate recovery above the acceptance limit.

B Analyte was present in the associated method blank.

BU Sample analyzed after holding time expired.

BV Sample received after holding time expired.

CI See case narrative.

E Concentration exceeds the calibration range.

ET Sample was extracted past end of recommended max. holding time.

HD The chromatographic pattern was inconsistent with the profile of the reference fuel standard.

HDH The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but heavier hydrocarbonswere also present (or detected).

HDL The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but lighter hydrocarbons werealso present (or detected).

J Analyte was detected at a concentration below the reporting limit and above the laboratory method detection limit. Reported value isestimated.

JA Analyte positively identified but quantitation is an estimate.

ME LCS Recovery Percentage is within Marginal Exceedance (ME) Control Limit range (+/- 4 SD from the mean).

ND Parameter not detected at the indicated reporting limit.

Q Spike recovery and RPD control limits do not apply resulting from the parameter concentration in the sample exceeding the spikeconcentration by a factor of four or greater.

SG The sample extract was subjected to Silica Gel treatment prior to analysis.

X % Recovery and/or RPD out-of-range.

Z Analyte presence was not confirmed by second column or GC/MS analysis.

Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC results arereported on a wet weight basis.

Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15 minutes(40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being received outside of thestated holding time unless received at the laboratory within 15 minutes of the collection time.

A calculated total result (Example: Total Pesticides) is the summation of each component concentration and/or, if "J" flags are reported,estimated concentration. Component concentrations showing not detected (ND) are summed into the calculated total result as zeroconcentrations.

Glossary of Terms and Qualifiers



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Return to Contents

Page 22 of 23

Chain of Custody Report To:

Contact: Orval Osborne Company: OTIE fQTJ~ Address: 317 East Main Street Ventura, CA 93001

~ OTIE

Phone: (805) 585-4313 Fax: (805) 585-2111

317 East Main Street Ventura, CA 93001 Phone: (805) 585-2110 Fax: (805) 585-2111

E-Mail: [email protected]

Sampler Name: Brian Hendron

Project Name: Pemaco - Quarterly (not LACSD)

Project Location: 5973 S. District Blvd Ma"""OOd CA 90270

Lab PM: Virendra Patel, CalScience 714-895-5494

\ Signature:~'u..\--

Project N urrlbe! : -zo 14166

Date Requested (without rush surcharge): email: end of month

Laboratory MS

ID MSD

Client Sample ID

Sampling Date Time

M t X

SP-201-20160614 6/14/16 0730 w

SP-209-20160614 6/14/16 0830 w

'

I I

G 0 cc,

a N

b ~ (.J 0 >

X X X

Q) ~

a; ::i: x-.Q er,> ao

I (!) '<tN - ()() ...-~

X X

Bil1To:

Contact: -------------

Company: ------------

Address: - - -----------

Phone:-------------

Fax: ------------ --

PO#: _____ _ Quote: _____ _

• ' ' ','' '

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RELINQUISHED ~ '\ • L ' D' - COMPANY __,.,,_,.,--~ -uu. ~IUfJ/,fA.,,-, 'f')j /(--.,

DATE(,,.., I \J JI(,., TIME COMPANY

IP-, l 2. t...() RELINOU !SHED BY

WW = Wastewater W =Water S = Soil SL = Sludge MS = Miscellaneous OL =Oil A = Air

Matrix Key SE = Sediment SO= Solid

COMPANY

OS = Drum Solid DL = Drum Liquid L = Leachate WI = Wipe o-___ _ _

DATE I

Container Key 1. Plastic 2. VOAVial 3. Sterile Plastic 4. Amber Glass 5 Wldemouth Glass 6 . Other

TIME COMPANY

Preservative Key COMMENTS: OTIE-specific EDDs needed 1. HCI, Cool to 4° 1.4-Dioxane: 1 uo/L RL 2. H2S04, Coo Ito 4° 3. HN03, Cool to 4' Levet 3 data oackaoe. Report to MDL (J-flao) 4. NaOH, Cool to 4' 5. Na OH/Zn Acetate. Cool to 4 ' 6. Cool to 4°

7. None

..

~=~dz~; ;r1in~iii:wt Package Se~f~<;I ?i ::'Slijipl&S.,~eaJep-

1 .· Y'E!S No Yes No ' , ...... -:-· ' ·-;--.

·-'•R~~f~~~~~Q····i~•·,.·C: ::~11~~;:t~f~•·•• __ .•.· .... ·· , ..• ;··./).•.\·•' • '. '">'i '•.--'·· .•. ___ .. .:.-. ,"}.:.,.,.,/••· .. ,•· ' ',' :. '

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Ye~· ·No c86,·not_._pr~s~.nt. ·.

Additional Analyses I Remarks

pH sample taken onsite at 0830 = 7.57

.·

/ DATE

~ I i'-'I lt <:? TIME

I "'2--"'7D (DATE TIME

Date Receiverl I I

Courier: Hand DelivereQ

Bill of Lading:

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. .: .• I .

.;:; eurofins : WORK ORDER NUMBER: 16-06- 0 C, q 2...-Calscience

SAMPLE RECEIPT CHECKLIST

CLIENT: ___ o_i-__. ...... 1_e_· ---------

COOLER _f_ OF /

DATE: 06 / /'f I 2016

TEMPERATO'RE: (Criteria: o.b0c...: 6.0~C; not frozen except sediment/tissue)

Thermometer ID: SC2A (CF: 0.0°C); Temperature (w/o CF): 3 C -=,- 0c (w/ CF): --:; • 7 °c;ri~k O Sample

D Sample(s) outside temperature criteria (PM/APM contacted by: __ __,)

D Sample(s) outside temperature criteria butreceived on ice/chilled on same day of sampling

D Sample(s) received at ambient temperature; placed on ice for transport by courier

Ambient Temperature: D Air D Filter

C0STODY SEAL: .

Cooler D Present and Intact

Sample(s) D Present and Intact

SAMPLE CONDITION:

D Present but Not Intact


~tPresent

~Present

ON/A

D NIA

Chain·of ·CL!stody (COC) document(s) received with samples ...... ... ...... .... .. . .. .. . ... ... .... ... ....... ... .

COC document(s) received complete ......................................... . ......... ... .......................... .

D Sampling date D Sampling time D Matrix D Number of containers

D No analysis requested D Not relinquished D No relinquished date D No relinquished time

Sampler's name indicated on COC .... ................ .. ............ .. . ....... .... ..... . ... ...... ... .. .... .. ... . ..... .

Sample container label(s) consistent with COC ..... . ....... ....... . ... ........ . ..... . ... ..... ... . ....... .. ....... . .

Sample container(s) intact and in good condition .. . ...... ... ...... ... .... .. . .. .... ...... ... .. ..... .............. ..

Proper containers for analyses requested .... ....... . ....... .. . ..... ... ................ .. ... ........ . ..... . .... .... .

Sufficient volume/mass for analyses requested .. ....... ... . .. . ... . . .. ... ..... ..... .... .. .... .. ... . .. ...... ... .... . .

Samples received within holding time .. . ...... ... ... ........... .... ... ........ . ............ .. ............. . .. ... .... ..

Aqueous samples for certain analyses received within 15-minute holding time

Checked by:

Checked by:

Checked by:

Yes

~ }if

No

0

D

D

D

D

D

D

D

B?_k

~~ y'Jk

NIA

0

D

D

D

D

D

D

D

D pH D Residual Chlorine D Dissolved Sulfide D Dissolved Oxygen . . .. . . . . . . . . .. .. . . . .. . . . . . . . . . D D Z) Proper preservation chemical(s) noted on COC and/or sample container ..... . ........ .... .. . ............... ~ D D

Unpreserved aqueous sample(s) received for certain analyses

D Volatile Organics D TotalMetals O Dissolved Metals

Container.(s) for certain analysis free of headspace .... .. ....... .. ..... .. ... .. ... ..... ...... . ... ........ . ..... .. ..

~atile Organics D Dissolved:Gases (RSK-175) D Dissolved Oxygen (SM_4500)

D Carbon Dioxide (SM 4500)' DFerrous Iron (SM 3500) D Hydrogen Sulfide (Hach}

Tedlar™ bag(s) free ofcond~r::isation ... ... ..... . ... ... ... ... ... .. . ... .. . .. . ... ... ... .... .. ... .. .... ....... .. ... ... ... D D

D

µ/ /

CONTAINER TYPEi.:.,iY 10 (Trip Blank Lot Number: ___ ___ )

Aqueous: D VOA~~OAh D VOAna2 D 100PJ O 100PJna2 D 125AGB O 125AGBh D 125AGBp D 125PB

0 125PBznna O 250AGB D-250CGB O 250CGBs O 250PB D 250PBn O 500AGB D 500AGJ D SOOAGJs

D 500PB 01AGB O 1AGBna2 01AGBs D 1PB D 1PBna O D D D _ _ _

Solid: D 4ozCGJ D 8ozCGJ D 16ozCGJ D Sleeve L__) D Encores® (___J D TerraCores® L__J D __ _

Air: D Tedlar™ D Canister O Sorbent Tube D PUF D Other Matrix ( ): D D ---Container: A = Amber, B = Bottle, C = Clear, E = Envelope, G = Glass, J = Jar, P = Plastic, and Z = Ziploc/Resealable Bag h PreservaUve: b = buffered, f = filtered, h = HCI; n = HN03, na = NaOH, na2 = Na2S20 3, p = H3PQ4, Labeled/Checked by: d-

s = H2S0 4, u = ultra-pure,znna = Zn(CH3C02)2 + NaOH Reviewed by: ...t.14-

2015-04-10 Revision

t .

ATTACHMENT 3

Lab Report from Eurofins CalScience, Inc.

SP‐209 VOC analysis

WORK ORDER NUMBER: 16-06-0991

Analytical Report ForClient: OTIE

Client Project Name: Pemaco - LACSD / 2014166Attention: Orval Osborne

317 East Main StreetVentura, CA 93001-2624

Approved for release on by:Virendra PatelProject Manager

AIR SOIL WATER MARINE CHEMISTRY

Eurofins Calscience, Inc. (Calscience) certifies that the test results provided in this report meet all NELAC requirements for parameters for which accreditation isrequired or available. Any exceptions to NELAC requirements are noted in the case narrative. The original report of subcontracted analyses, if any, is attached tothis report. The results in this report are limited to the sample(s) tested and any reproduction thereof must be made in its entirety. The client or recipient of thisreport is specifically prohibited from making material changes to said report and, to the extent that such changes are made, Calscience is not responsible, legally orotherwise. The client or recipient agrees to indemnify Calscience for any defense to any litigation which may arise.

06/22/2016

Page 1 of 29

mailto:[email protected]

https://www.calscience.com/clientwebaccess/login.aspx

Contents


Client Project Name: Pemaco - LACSD / 2014166

Work Order Number: 16-06-0991

1 Work Order Narrative. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

2 Sample Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

3 QC Association Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

4 Detections Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

5 Client Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75.1 EPA 410.4 Chemical Oxygen Demand (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . 75.2 SM 2540 D Total Suspended Solids (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . 85.3 SM 4500 H+ B pH (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95.4 EPA 625 Semi-Volatile Organics (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105.5 EPA 8260B Volatile Organics (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

6 Quality Control Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186.1 MS/MSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186.2 Sample Duplicate. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196.3 LCS/LCSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

7 Sample Analysis Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

8 Glossary of Terms and Qualifiers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27

9 Chain-of-Custody/Sample Receipt Form. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

Page 2 of 29

Condition Upon Receipt: Samples were received under Chain-of-Custody (COC) on 06/14/16. They were assigned to Work Order 16-06-0991. Unless otherwise noted on the Sample Receiving forms all samples were received in good condition and within the

recommended EPA temperature criteria for the methods noted on the COC. The COC and Sample Receiving Documents are

integral elements of the analytical report and are presented at the back of the report. Holding Times: All samples were analyzed within prescribed holding times (HT) and/or in accordance with the Calscience Sample Acceptance

Policy unless otherwise noted in the analytical report and/or comprehensive case narrative, if required. Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15

minutes (40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being

received outside of the stated holding time unless received at the laboratory within 15 minutes of the collection time. Quality Control: All quality control parameters (QC) were within established control limits except where noted in the QC summary forms or

described further within this report. Subcontractor Information: Unless otherwise noted below (or on the subcontract form), no samples were subcontracted. Additional Comments: Air - Sorbent-extracted air methods (EPA TO-4A, EPA TO-10, EPA TO-13A, EPA TO-17): Analytical results are converted from

mass/sample basis to mass/volume basis using client-supplied air volumes. Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC

results are always reported on a wet weight basis.

Work Order Narrative



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Sample Identification Lab Number Collection Date and Time Number ofContainers

Matrix

SP-209-20160614 16-06-0991-1 06/14/16 08:30 7 Aqueous

SP-209-20160614 (comp) 16-06-0991-2 06/14/16 08:30 2 Aqueous

Sample Summary


Client: OTIE




Project Name: Pemaco - LACSD / 2014166

PO Number:

Date/TimeReceived:

06/14/16 12:30

Number ofContainers:

9

Attn: Orval Osborne

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Client Sample ID Method Name Type Ext Name Instrument MS/MSD/SDP LCS/LCSD

SP-209-20160614 EPA 625 Semi-Volatile Organics EPA 625 GC/MS TT *2 160620L02

SP-209-20160614 EPA 8260B Volatile Organics EPA 5030C GC/MS V V 160614S020 160614L051

SP-209-20160614 SM 4500 H+ B pH N/A PH 1 G0614PHD1 *4

SP-209-20160614(comp)

EPA 410.4 Chemical Oxygen Demand N/A UV 4 G0615ODD2 G0615ODB2

SP-209-20160614(comp)

SM 2540 D Total Suspended Solids N/A N/A G0618TSSD1 G0618TSSL1

QC Association Summary



2 = Limited sample received, no MS/MSD performed

4 = Per the method, no associated matrix QC

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Subcontracted analyses, if any, are not included in this summary.

SP-209-20160614 (16-06-0991-1)

1,1-Dichloroethane 1.5 1.0 ug/L EPA 8260B EPA 5030C

Chloroform 1.1 1.0 ug/L EPA 8260B EPA 5030C

Trichloroethene 0.42 J 0.37* ug/L EPA 8260B EPA 5030C

Vinyl Chloride 0.45 J 0.30* ug/L EPA 8260B EPA 5030C

c-1,2-Dichloroethene 6.3 1.0 ug/L EPA 8260B EPA 5030C

pH 7.45 BV,BU 0.01 pH units SM 4500 H+ B N/A

SP-209-20160614 (comp) (16-06-0991-2)

Chemical Oxygen Demand 5.7 5.0 mg/L EPA 410.4 N/A

Detections Summary


Client: OTIE




Project Name: Pemaco - LACSD / 2014166

Received: 06/14/16

Attn: Orval Osborne Page 1 of 1

Client SampleID

Analyte Result Qualifiers RL Units Method Extraction

* MDL is shown

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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-209-20160614 (comp) 16-06-0991-2-A 06/14/1608:30

Aqueous UV 4 N/A 06/16/1612:00

G0615ODB2



Chemical Oxygen Demand 5.7 5.0 3.0 1.00

Method Blank 099-12-243-1648 N/A Aqueous UV 4 N/A 06/16/1612:00

G0615ODB2



Chemical Oxygen Demand ND 5.0 3.0 1.00

Analytical Report


OTIE





Preparation: N/A

Method: EPA 410.4

Units: mg/L

Project: Pemaco - LACSD / 2014166 Page 1 of 1


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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-209-20160614 (comp) 16-06-0991-2-B 06/14/1608:30

Aqueous N/A 06/18/16 06/18/1614:00

G0618TSSL1



Solids, Total Suspended ND 1.0 0.83 1.00

Method Blank 099-09-010-7770 N/A Aqueous N/A 06/18/16 06/18/1614:00

G0618TSSL1



Solids, Total Suspended ND 1.0 0.83 1.00

Analytical Report


OTIE





Preparation: N/A

Method: SM 2540 D

Units: mg/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-209-20160614 16-06-0991-1-G 06/14/1608:30

Aqueous PH 1 N/A 06/14/1617:38

G0614PHD1



pH 7.45 0.01 0.01 1.00 BV,BU

Analytical Report


OTIE





Preparation: N/A

Method: SM 4500 H+ B

Units: pH units



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-209-20160614 16-06-0991-1-F 06/14/1608:30

Aqueous GC/MS TT 06/20/16 06/20/1617:37

160620L02



N-Nitrosodimethylamine ND 9.5 3.0 1.00

Phenol ND 9.5 2.0 1.00

Bis(2-Chloroethyl) Ether ND 24 2.3 1.00

2-Chlorophenol ND 9.5 2.2 1.00

Bis(2-Chloroisopropyl) Ether ND 9.5 3.1 1.00

N-Nitroso-di-n-propylamine ND 9.5 2.2 1.00

Hexachloroethane ND 9.5 2.9 1.00

Nitrobenzene ND 24 2.9 1.00

Isophorone ND 9.5 2.4 1.00

2-Nitrophenol ND 9.5 2.5 1.00

2,4-Dimethylphenol ND 9.5 2.3 1.00

Bis(2-Chloroethoxy) Methane ND 9.5 2.4 1.00

2,4-Dichlorophenol ND 9.5 2.4 1.00


Naphthalene ND 9.5 2.7 1.00

Hexachloro-1,3-Butadiene ND 9.5 2.8 1.00

4-Chloro-3-Methylphenol ND 9.5 2.3 1.00

Hexachlorocyclopentadiene ND 24 6.6 1.00

2,4,6-Trichlorophenol ND 9.5 2.4 1.00

2-Chloronaphthalene ND 9.5 2.6 1.00

Dimethyl Phthalate ND 9.5 2.5 1.00

Acenaphthylene ND 9.5 2.8 1.00

Acenaphthene ND 9.5 2.7 1.00

2,4-Dinitrophenol ND 48 13 1.00

4-Nitrophenol ND 9.5 1.5 1.00

2,4-Dinitrotoluene ND 9.5 2.2 1.00

2,6-Dinitrotoluene ND 9.5 2.2 1.00

Diethyl Phthalate ND 9.5 2.6 1.00

4-Chlorophenyl-Phenyl Ether ND 9.5 2.5 1.00

Fluorene ND 9.5 2.6 1.00

4,6-Dinitro-2-Methylphenol ND 48 14 1.00

N-Nitrosodiphenylamine ND 9.5 2.6 1.00

4-Bromophenyl-Phenyl Ether ND 9.5 2.6 1.00

Hexachlorobenzene ND 9.5 2.9 1.00

Analytical Report


OTIE





Preparation: EPA 625

Method: EPA 625

Units: ug/L



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Pentachlorophenol ND 24 4.4 1.00

Phenanthrene ND 9.5 2.8 1.00

Anthracene ND 9.5 2.9 1.00

Di-n-Butyl Phthalate ND 9.5 2.8 1.00

Fluoranthene ND 9.5 3.0 1.00

Benzidine ND 48 6.2 1.00

Pyrene ND 9.5 2.8 1.00

Butyl Benzyl Phthalate ND 9.5 2.4 1.00

3,3'-Dichlorobenzidine ND 24 2.5 1.00

Benzo (a) Anthracene ND 9.5 4.4 1.00

Bis(2-Ethylhexyl) Phthalate ND 9.5 3.0 1.00

Chrysene ND 9.5 2.7 1.00

Di-n-Octyl Phthalate ND 9.5 2.4 1.00

Benzo (k) Fluoranthene ND 9.5 3.1 1.00

Benzo (b) Fluoranthene ND 9.5 2.2 1.00

Benzo (a) Pyrene ND 9.5 2.3 1.00

Benzo (g,h,i) Perylene ND 9.5 2.4 1.00

Indeno (1,2,3-c,d) Pyrene ND 9.5 2.0 1.00

Dibenz (a,h) Anthracene ND 9.5 2.4 1.00

1,2-Diphenylhydrazine ND 9.5 1.7 1.00


2-Fluorophenol 60 15-138

Phenol-d6 39 17-141

Nitrobenzene-d5 86 56-123

2-Fluorobiphenyl 73 45-120

2,4,6-Tribromophenol 88 32-143

p-Terphenyl-d14 88 46-133

Analytical Report


OTIE






Method: EPA 625

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

Method Blank 099-15-026-342 N/A Aqueous GC/MS TT 06/20/16 06/20/1616:33

160620L02



N-Nitrosodimethylamine ND 10 3.2 1.00

Phenol ND 10 2.1 1.00

Bis(2-Chloroethyl) Ether ND 25 2.5 1.00

2-Chlorophenol ND 10 2.3 1.00

Bis(2-Chloroisopropyl) Ether ND 10 3.2 1.00

N-Nitroso-di-n-propylamine ND 10 2.4 1.00

Hexachloroethane ND 10 3.0 1.00

Nitrobenzene ND 25 3.0 1.00

Isophorone ND 10 2.5 1.00

2-Nitrophenol ND 10 2.6 1.00

2,4-Dimethylphenol ND 10 2.4 1.00

Bis(2-Chloroethoxy) Methane ND 10 2.5 1.00

2,4-Dichlorophenol ND 10 2.5 1.00

1,2,4-Trichlorobenzene ND 10 2.8 1.00


Hexachloro-1,3-Butadiene ND 10 2.9 1.00

4-Chloro-3-Methylphenol ND 10 2.4 1.00

Hexachlorocyclopentadiene ND 25 6.9 1.00

2,4,6-Trichlorophenol ND 10 2.5 1.00

2-Chloronaphthalene ND 10 2.8 1.00

Dimethyl Phthalate ND 10 2.6 1.00

Acenaphthylene ND 10 2.9 1.00

Acenaphthene ND 10 2.8 1.00

2,4-Dinitrophenol ND 50 13 1.00

4-Nitrophenol ND 10 1.6 1.00

2,4-Dinitrotoluene ND 10 2.3 1.00

2,6-Dinitrotoluene ND 10 2.4 1.00

Diethyl Phthalate ND 10 2.8 1.00

4-Chlorophenyl-Phenyl Ether ND 10 2.7 1.00

Fluorene ND 10 2.7 1.00

4,6-Dinitro-2-Methylphenol ND 50 14 1.00

N-Nitrosodiphenylamine ND 10 2.8 1.00

4-Bromophenyl-Phenyl Ether ND 10 2.7 1.00

Hexachlorobenzene ND 10 3.1 1.00

Analytical Report


OTIE






Method: EPA 625

Units: ug/L



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Pentachlorophenol ND 25 4.6 1.00

Phenanthrene ND 10 2.9 1.00

Anthracene ND 10 3.0 1.00

Di-n-Butyl Phthalate ND 10 2.9 1.00

Fluoranthene ND 10 3.1 1.00

Benzidine ND 50 6.5 1.00

Pyrene ND 10 3.0 1.00

Butyl Benzyl Phthalate ND 10 2.5 1.00

3,3'-Dichlorobenzidine ND 25 2.6 1.00

Benzo (a) Anthracene ND 10 4.7 1.00

Bis(2-Ethylhexyl) Phthalate ND 10 3.2 1.00

Chrysene ND 10 2.8 1.00

Di-n-Octyl Phthalate ND 10 2.5 1.00

Benzo (k) Fluoranthene ND 10 3.2 1.00

Benzo (b) Fluoranthene ND 10 2.3 1.00

Benzo (a) Pyrene ND 10 2.4 1.00

Benzo (g,h,i) Perylene ND 10 2.5 1.00

Indeno (1,2,3-c,d) Pyrene ND 10 2.1 1.00

Dibenz (a,h) Anthracene ND 10 2.5 1.00

1,2-Diphenylhydrazine ND 10 1.8 1.00


2-Fluorophenol 63 15-138

Phenol-d6 41 17-141

Nitrobenzene-d5 89 56-123

2-Fluorobiphenyl 80 45-120

2,4,6-Tribromophenol 88 32-143

p-Terphenyl-d14 89 46-133

Analytical Report


OTIE






Method: EPA 625

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-209-20160614 16-06-0991-1-A 06/14/1608:30

Aqueous GC/MS V V 06/14/16 06/15/1602:04

160614L051








1,1-Dichloroethane 1.5 1.0 0.28 1.00























Benzene ND 0.50 0.14 1.00






Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Chloroform 1.1 1.0 0.46 1.00









Styrene ND 1.0 0.17 1.00


Toluene ND 1.0 0.24 1.00


Trichloroethene 0.42 1.0 0.37 1.00 J



Vinyl Chloride 0.45 0.50 0.30 1.00 J


c-1,2-Dichloroethene 6.3 1.0 0.48 1.00



o-Xylene ND 1.0 0.23 1.00





p/m-Xylene ND 1.0 0.30 1.00


2-Chloroethyl Vinyl Ether ND 50 16 1.00





Toluene-d8 99 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

Method Blank 099-14-001-20628 N/A Aqueous GC/MS V V 06/14/16 06/15/1600:42

160614L051































Benzene ND 0.50 0.14 1.00






Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Styrene ND 1.0 0.17 1.00


Toluene ND 1.0 0.24 1.00


Trichloroethene ND 1.0 0.37 1.00





c-1,2-Dichloroethene ND 1.0 0.48 1.00



o-Xylene ND 1.0 0.23 1.00





p/m-Xylene ND 1.0 0.30 1.00


2-Chloroethyl Vinyl Ether ND 50 16 1.00





Toluene-d8 99 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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16-06-1006-1 Sample Aqueous GC/MS V V 06/14/16 06/15/16 01:37 160614S020

16-06-1006-1 Matrix Spike Aqueous GC/MS V V 06/14/16 06/15/16 04:49 160614S020

16-06-1006-1 Matrix Spike Duplicate Aqueous GC/MS V V 06/14/16 06/15/16 05:17 160614S020


SpikeAdded

MSConc.

MS%Rec.

MSDConc.

MSD%Rec.


1,1-Dichloroethene ND 50.00 60.38 121 60.95 122 52-136 1 0-21

1,2-Dibromoethane ND 50.00 51.76 104 49.45 99 80-122 5 0-20

1,2-Dichlorobenzene ND 50.00 49.69 99 48.70 97 70-120 2 0-26

1,2-Dichloroethane ND 50.00 48.52 97 47.16 94 64-142 3 0-20

Benzene ND 50.00 55.17 110 55.76 112 74-122 1 0-21

Carbon Tetrachloride ND 50.00 51.01 102 50.91 102 60-144 0 0-21

Chlorobenzene ND 50.00 51.67 103 50.91 102 73-120 1 0-22

Ethylbenzene ND 50.00 53.24 106 52.10 104 77-125 2 0-24

Toluene ND 50.00 55.62 111 54.72 109 72-126 2 0-23

Trichloroethene ND 50.00 53.20 106 51.80 104 74-128 3 0-22

Vinyl Chloride ND 50.00 49.14 98 51.55 103 67-133 5 0-20

o-Xylene ND 50.00 53.24 106 53.03 106 62-128 0 0-24

p/m-Xylene ND 100.0 109.4 109 108.7 109 63-129 1 0-25

Methyl-t-Butyl Ether (MTBE) ND 50.00 51.43 103 51.23 102 68-134 0 0-21

Tert-Butyl Alcohol (TBA) ND 250.0 228.0 91 215.4 86 65-143 6 0-30

Diisopropyl Ether (DIPE) ND 50.00 54.72 109 55.41 111 61-139 1 0-20

Ethyl-t-Butyl Ether (ETBE) ND 50.00 45.41 91 46.67 93 64-136 3 0-20

Tert-Amyl-Methyl Ether (TAME) ND 50.00 43.53 87 43.69 87 67-133 0 0-20

Ethanol ND 500.0 572.3 114 608.4 122 34-178 6 0-58



OTIE






Method: EPA 8260B



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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed Duplicate Batch Number

16-06-1094-1 Sample Aqueous UV 4 N/A 06/16/16 12:00 G0615ODD2

16-06-1094-1 Sample Duplicate Aqueous UV 4 N/A 06/16/16 12:00 G0615ODD2

Parameter Sample Conc. DUP Conc. RPD RPD CL Qualifiers

Chemical Oxygen Demand 13.36 12.67 5 0-25

Quality Control - Sample Duplicate


OTIE





Preparation: N/A

Method: EPA 410.4



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16-06-0978-2 Sample Aqueous N/A 06/18/16 00:00 06/18/16 14:00 G0618TSSD1

16-06-0978-2 Sample Duplicate Aqueous N/A 06/18/16 00:00 06/18/16 14:00 G0618TSSD1


Solids, Total Suspended 558.0 538.0 4 0-20



OTIE





Preparation: N/A

Method: SM 2540 D



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SP-209-20160614 Sample Aqueous PH 1 N/A 06/14/16 17:38 G0614PHD1

SP-209-20160614 Sample Duplicate Aqueous PH 1 N/A 06/14/16 17:38 G0614PHD1


pH 7.450 7.440 0 0-25



OTIE





Preparation: N/A

Method: SM 4500 H+ B



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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed LCS/LCSD Batch Number

099-12-243-1648 LCS Aqueous UV 4 N/A 06/16/16 12:00 G0615ODB2

099-12-243-1648 LCSD Aqueous UV 4 N/A 06/16/16 12:00 G0615ODB2

Parameter Spike Added LCS Conc. LCS%Rec.

LCSD Conc. LCSD%Rec.


Chemical Oxygen Demand 20.00 18.23 91 17.54 88 80-120 4 0-20

Quality Control - LCS/LCSD


OTIE





Preparation: N/A

Method: EPA 410.4



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099-09-010-7770 LCS Aqueous N/A 06/18/16 06/18/16 14:00 G0618TSSL1

099-09-010-7770 LCSD Aqueous N/A 06/18/16 06/18/16 14:00 G0618TSSL1

Parameter Spike Added LCS Conc. LCS%Rec.

LCSD Conc. LCSD%Rec.


Solids, Total Suspended 100.0 95.00 95 96.00 96 80-120 1 0-20



OTIE





Preparation: N/A

Method: SM 2540 D



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099-15-026-342 LCS Aqueous GC/MS TT 06/20/16 06/20/16 16:52 160620L02

099-15-026-342 LCSD Aqueous GC/MS TT 06/20/16 06/20/16 17:14 160620L02

Parameter SpikeAdded

LCS Conc. LCS%Rec.

LCSDConc.

LCSD%Rec.

%Rec. CL ME CL RPD RPD CL Qualifiers

Phenol 100.0 43.56 44 42.97 43 12-151 0-174 1 0-23

2-Chlorophenol 100.0 83.68 84 84.69 85 45-135 30-150 1 0-18

N-Nitroso-di-n-propylamine 100.0 87.19 87 87.39 87 52-128 39-141 0 0-13

1,2,4-Trichlorobenzene 100.0 80.92 81 82.86 83 42-120 29-133 2 0-21

Naphthalene 100.0 83.30 83 85.17 85 21-133 2-152 2 0-20

4-Chloro-3-Methylphenol 100.0 89.15 89 89.95 90 20-150 0-172 1 0-40

Dimethyl Phthalate 100.0 84.20 84 86.57 87 0-112 0-131 3 0-20

Acenaphthylene 100.0 83.27 83 85.98 86 33-145 14-164 3 0-20

Acenaphthene 100.0 86.64 87 88.89 89 51-137 37-151 3 0-11

4-Nitrophenol 100.0 44.58 45 46.76 47 20-150 0-172 5 0-40

2,4-Dinitrotoluene 100.0 88.36 88 90.39 90 25-143 5-163 2 0-36

Fluorene 100.0 83.85 84 86.04 86 59-121 49-131 3 0-20

Pentachlorophenol 100.0 80.01 80 82.66 83 20-150 0-172 3 0-40

Pyrene 100.0 85.04 85 86.75 87 45-135 30-150 2 0-20

Butyl Benzyl Phthalate 100.0 85.15 85 88.72 89 0-152 0-177 4 0-20



OTIE






Method: EPA 625



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099-14-001-20628 LCS Aqueous GC/MS V V 06/14/16 06/14/16 23:47 160614L051

Parameter Spike Added Conc. Recovered LCS %Rec. %Rec. CL ME CL Qualifiers

1,1-Dichloroethene 50.00 59.37 119 66-126 56-136

1,2-Dibromoethane 50.00 50.33 101 80-120 73-127

1,2-Dichlorobenzene 50.00 48.55 97 63-129 52-140

1,2-Dichloroethane 50.00 47.51 95 70-130 60-140

Benzene 50.00 53.96 108 80-120 73-127

Carbon Tetrachloride 50.00 48.83 98 67-139 55-151

Chlorobenzene 50.00 50.22 100 78-120 71-127

Ethylbenzene 50.00 52.00 104 80-123 73-130

Toluene 50.00 53.25 107 80-120 73-127

Trichloroethene 50.00 50.57 101 80-122 73-129

Vinyl Chloride 50.00 50.14 100 70-130 60-140

o-Xylene 50.00 52.99 106 74-122 66-130

p/m-Xylene 100.0 106.8 107 75-123 67-131

Methyl-t-Butyl Ether (MTBE) 50.00 47.90 96 69-129 59-139

Tert-Butyl Alcohol (TBA) 250.0 230.4 92 69-129 59-139

Diisopropyl Ether (DIPE) 50.00 53.55 107 68-128 58-138

Ethyl-t-Butyl Ether (ETBE) 50.00 46.82 94 63-135 51-147

Tert-Amyl-Methyl Ether (TAME) 50.00 44.46 89 67-133 56-144

Ethanol 500.0 681.2 136 42-168 21-189



OTIE






Method: EPA 8260B



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Method Extraction Chemist ID Instrument Analytical Location

EPA 410.4 N/A 1067 UV 4 1

EPA 625 EPA 625 923 GC/MS TT 1

EPA 8260B EPA 5030C 1073 GC/MS V V 2

SM 2540 D N/A 1009 N/A 1

SM 4500 H+ B N/A 650 PH 1 1

Sample Analysis Summary Report



Location 1: 7440 Lincoln Way, Garden Grove, CA 92841

Location 2: 7445 Lampson Avenue, Garden Grove, CA 92841

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Qualifiers Definition

* See applicable analysis comment.

< Less than the indicated value.

> Greater than the indicated value.

1 Surrogate compound recovery was out of control due to a required sample dilution. Therefore, the sample data was reported without furtherclarification.

2 Surrogate compound recovery was out of control due to matrix interference. The associated method blank surrogate spike compound wasin control and, therefore, the sample data was reported without further clarification.

3 Recovery of the Matrix Spike (MS) or Matrix Spike Duplicate (MSD) compound was out of control due to suspected matrix interference. Theassociated LCS recovery was in control.

4 The MS/MSD RPD was out of control due to suspected matrix interference.

5 The PDS/PDSD or PES/PESD associated with this batch of samples was out of control due to suspected matrix interference.

6 Surrogate recovery below the acceptance limit.

7 Surrogate recovery above the acceptance limit.

B Analyte was present in the associated method blank.

BU Sample analyzed after holding time expired.

BV Sample received after holding time expired.

CI See case narrative.

E Concentration exceeds the calibration range.

ET Sample was extracted past end of recommended max. holding time.

HD The chromatographic pattern was inconsistent with the profile of the reference fuel standard.

HDH The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but heavier hydrocarbonswere also present (or detected).

HDL The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but lighter hydrocarbons werealso present (or detected).

J Analyte was detected at a concentration below the reporting limit and above the laboratory method detection limit. Reported value isestimated.

JA Analyte positively identified but quantitation is an estimate.

ME LCS Recovery Percentage is within Marginal Exceedance (ME) Control Limit range (+/- 4 SD from the mean).

ND Parameter not detected at the indicated reporting limit.

Q Spike recovery and RPD control limits do not apply resulting from the parameter concentration in the sample exceeding the spikeconcentration by a factor of four or greater.

SG The sample extract was subjected to Silica Gel treatment prior to analysis.

X % Recovery and/or RPD out-of-range.

Z Analyte presence was not confirmed by second column or GC/MS analysis.

Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC results arereported on a wet weight basis.

Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15 minutes(40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being received outside of thestated holding time unless received at the laboratory within 15 minutes of the collection time.

A calculated total result (Example: Total Pesticides) is the summation of each component concentration and/or, if "J" flags are reported,estimated concentration. Component concentrations showing not detected (ND) are summed into the calculated total result as zeroconcentrations.

Glossary of Terms and Qualifiers



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Return to Contents

Page 28 of 29

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Page 29 of 29~:: eurofins WORK ORDER NUMBER: 16--06- Oqvl i i

Ca!science SAMPLE RECEIPT CHECKLIST COOLER _j_ OF I

{YT t£ CLIENT:--------------------- DATE: 06 / !:f:_ / 2016

TEMPERATURE: (Criteria: 0.0°C - 6.0°C, noffrozen except sediment/tissue)

Thermometer ID: SC2A (CF: 0.0°C); Temperature (w/o CF): '3 . 4 °c (w/ CF): ~ . C, °C;~~ D Sample

D Sample(s) outside temperature criteria (PM/APM contacted by: )

D Sample(s) outside temperature criteria bufreceived on ice/chilled on same day of sampling

D Sample(s) received at ambient temperature; placed on ice for transport by courier

Ambient Temperature: D Air D Filter

CUSTODY SEAL:

Cooler

Sample(s)

0 Present and Intact

D Present and Intact

SAMPLE CONDITION:


D Present but Not Intact ·.

/~Present

~ot Present

D N/A

D NIA

Chain-of-Custody (COC) document(s) received with samples ............. ...... ............................... .

COC document(s) received complete ....................................................... .. .... .. ..... . ........... .

D Sampling date O Sampling time O Matrix D Number of containers

D No analysis requested D Not relinquished D No relinquished date D No relinquished time

Sampler's name indicated on COC ................................. ................................................. ..

Sample container label(s) consistent with COC . .. ... .... . . .. ..... ...... .. . ... .. . .... . ..... . ..... . ...... .. ......... .

Sample container(s) intact and in good condition ... ..... . .. ... . .. .... .. ... . . .. . .. . .. .... .. ... .. . .. .. .. .. ....... .. .

Proper containers for analyses requested ........ . ... .... .. .. ..... .. . ... .. ... . .. ... .. . ... ... .. . ...... .... .. .. ..... ..

Sufficient volume/mass for analyses requested .. . ... .. .... .. ........... .. .... .. ................. ... .............. ..

Samples received within holding time ..................... ............... . ........ .. . .. ................... ......... . ..

Checked by: g-;b

Checked by: ~6 Checked by: h,e;

Yes No NIA

~ 0 0

0 0

.

~ 0 0 j!J D D

D"'" D D

~ D D -~ D D

~ D 0

Aqueous samples for certain analyses received within 15-minute holding time

~H D Residual Chlorine D Dissolved Sulfide D Dissolved Oxygen ..... . ... ....... ......... .. . .. D ~ D

Proper preservation chemical(s) noted on COC and/or sample container ..... . ......... .... ... ...... .. ... . ..

Unpreserved aqueous sample(s) received for certain analyses

.,9"101atile Organics D Total Metals D Dissolved Metals

Container(s) for certain analysis free of headspace ... .. . .. .. .. . .. . .. .. . ............ ... ................ .. ........ .

~olatile Organics O Dissolved Gases (RSK-175) D Dissolved Oxygen (SM 4500)

D Carbon Dioxide (SM 4500) D Ferrous Iron (SM 3500) D Hydrogen Sulfide (Hach)

~

f?/

Tedlar™ bag(s) free of condensation ... ... ... ... ... ... . .. ... .. . . .. .. . ... .. . ... ... ... ... ... ... ... ... ... ... ... ... ... .. . D

D D

D D

D ;a'/

CONTAINER T~E: (Trip Blank Lot Number: __ _,,,.,<"'-·---,)

Aqueous: 0VO~ D VOAh D VOAna. 2 D 100PJ O 100PJna2 0125AGB D 125AGBh D 125AGBp ~5PB

D 125PBznnt'o 250AGB D 250CGB ~sotG~ D 250PB· D 250PBn D 500AGB D 500AGJ D 50DAGYs1J

D 500PB ~~Ga D lAGBna2 D 1AGBs ..0"'-if;°~ D 1 PBna D D D D ---

Solid: D 4ozCGJ D 8ozCGJ D 16ozCGJ D Sleeve(_) D EnCores® (_) D TerraCores® (..__) D __ _

Air: D Tedlar™ D Canister D Sorbent Tube D PUF D Other Matrix< ): D D __ _

Container: A= Amber, B = Bottle, C = Clear, E = Envelope, G = Glass, J = Jar, P = Plastic, and Z = Ziploc/Resealable Bag

Preservative: b = buffered, f = filtered, h = HCI, n = HNOs, na = NaOH, na2 = Na2S203, p = HsP04, Labeled/Checked by: N s = H2S04, u = ultra-pure, znna = Zn(CHsC02)2 + NaOH Reviewed by: /7 V

I ' iJ

2015-04-10 Revision

t

ATTACHMENT 4

Lab Report from ALS Environmental

2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com

R I G H T S O L U T I O N S | R I G H T P A R T N E R

LABORATORY REPORT

June 29, 2016

Orval Osborne Oneida Total Integrated Enterprises (OTIE) 317 E. Main St. Ventura, CA 93001

RE: Pemaco Plant Vapor Monitoring

Dear Orval:

Enclosed are the results of the samples submitted to our laboratory on June 14, 2016. For your reference, these analyses have been assigned our service request number P1603010.

All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein.

If you have any questions, please call me at (805) 526-7161.

Respectfully submitted,

ALS | Environmental

Kelly Horiuchi Laboratory Director

1 of 113

http://www.alsglobal.com/


kelly.horiuchi

Kelly



Client: Oneida Total Integrated Enterprises (OTIE) Service Request No: P1603010 Project: Pemaco Plant Vapor Monitoring _______________________________________________________________________________

CASE NARRATIVE

The samples were received intact under chain of custody on June 14, 2016 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the samples at the time of sample receipt.

Volatile Organic Compound Analysis

The samples were analyzed for volatile organic compounds in accordance with EPA Method TO-15 from the Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA/625/R-96/010b), January, 1999. This procedure is described in laboratory SOP VOA-TO15. The analytical system was comprised of a gas chromatograph / mass spectrometer (GC/MS) interfaced to a whole-air preconcentrator. This method is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP, LLC accreditation. Any analytes flagged with an X are not included on the NELAP or DoD-ELAP accreditation.

The containers were cleaned, prior to sampling, down to the method reporting limit (MRL) reported for this project. Please note, projects which require reporting below the MRL could have results between the MRL and method detection limit (MDL) that are biased high. ______________________________________________________________________________________

The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report.

Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory.

2 of 113




ALS Environmental – Simi Valley

CERTIFICATIONS, ACCREDITATIONS, AND REGISTRATIONS

Agency Web Site Number

AIHA-LAP, LLC http://www.aihaaccreditedlabs.org 101661

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0694

PJLA (DoD ELAP)

http://www.pjlabs.com/search-accredited-labs 65818

(Testing) Florida DOH (NELAP)

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E871020

Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

2014025

Minnesota DOH (NELAP)

http://www.health.state.mn.us/accreditation 977273

New Jersey DEP (NELAP)

http://www.nj.gov/dep/oqa/ CA009

New York DOH (NELAP)

http://www.wadsworth.org/labcert/elap/elap.html 11221

Oregon PHD (NELAP)

http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx

4068-003

Pennsylvania DEP http://www.depweb.state.pa.us/labs 68-03307

(Registration) Texas CEQ (NELAP)

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704413-

15-6 Utah DOH (NELAP)

http://www.health.utah.gov/lab/labimp/certification/index.html CA01627201

5-5

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C946

Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website.

Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification.

3 of 113


http://www.aihaaccreditedlabs.org/

http://www.azdhs.gov/lab/license/env.htm

http://www.pjlabs.com/search-accredited-labs

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.health.state.mn.us/accreditation

http://www.nj.gov/dep/oqa/

http://www.wadsworth.org/labcert/elap/elap.html



http://www.depweb.state.pa.us/labs

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html

http://www.health.utah.gov/lab/labimp/certification/index.html

http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html


P1603010_Detail Summary_1606280830_RG.xls - DETAIL SUMMARY

Client: Oneida Total Integrated Enterprises (OTIE) Service Request: P1603010Project ID: Pemaco Plant Vapor Monitoring

Date Received: 6/14/2016Time Received: 12:30

Client Sample ID Lab Code MatrixDate

CollectedTime

CollectedContainer

IDPi1

(psig)Pf1

(psig)

SP-106-20160614 P1603010-001 Air 6/14/2016 08:00 1BV06400 -0.13 6.97 XSP-104-20160614 P1603010-002 Air 6/14/2016 09:00 1BV06401 -0.09 6.47 X

P

DETAIL SUMMARY REPORT

TO-1

5 - V

OC

Can

s

4 of 113

5 o

f 11

3

.~ '(3

ALS Environmental 2~5 Perft Center Drive, Suit& A

Simi V•lloy, CA 9306$

TEL: (806) si:e-11e1 • FAX: (00S) $.26•72211

LA80AA,,.......f l.,Llc11 :

OTIE ,ux~ess:

•

317 E. Main Street Ventura CA 93001

TEC F"A.X: E.f\&I\IL

......... , Pemaeo - Plant Vaoor Monltorlna

PROJECT CO-ITA.CT:

Orval Osborne SIJ.'JR.ER(S): (SIG~IA.1~&)

Rrfan HP.nrfmn

p H,13 '11 JI/

CHAIN OF CUSTODY RECORD DATE: 6/14/2016 ____ _:._--..:c.;_.;.._ __ _

PAGE: ___ .,:1 ___ OF ___ ..:.1 __ _

; P.O.NO.: ···

2014166

[jM~ooioF COEL T LOG cooe ''~® .. ~:!l~!P,'.l;"" .;;;;; ::

··.;;:;:.·:·····

805.585.4313 805.585.2111 oosbd-·""'otie.com DD DD /,j,~~;(;; ......•... itt ' ',~~; ··················································

TURH""vUNU IIMl::

0SAMEDAY D24HR n 48HR 072HR D 5 DAYS Ii) 10 DAYS ,, REQUESTED ANALYSIS

SPECl.\1. ~EQUIRS"Ftt16 (ACOfflONAL COSTS IM.Y APPL 'I')

D D D : SF1::Cl"1. lliSTRUCTIONS

Please report EDDs in both ppmv and mglm3 "

"' c. SP-108 started at -30.18 -6 SP-104 etarted at -30.18

.. l~bs1;~ no:- ~

~19'd Point Nema SAMPLING MATRJ co,n. ll SA/111'1.EID

,t!J.IM?c DATE. TIME X ~ CONTAINER TYPE

IT SP-106·20160614 Vapor SP·106 06/14/16 8:00 air 1 X Bot1_1e 1BVOl>400

SP-104·20160614 Vape>r SP•104 06/14/16 9:00 ~ir 1 X Bottle 1BV06401

2nd V•pcSr sample> after carbo<l chan11e out. L .. d veoo,el& cMng&(I from T-301 to T·S02. which changed the lag sample port from SP·10a to SP-106. Sam,:i~ w.H c.o!leet(;d

'·' from the &ffh.M)(lt GAC v&Hel T~01.

,,,

' ' ReH~lilshad t,,: (Signstvnt)

\!.'-: j /tJ)u;,..--Racel\lad b)': (SignSNra) 0

l l 1;J/& Ttne:

' -r~~s ...... ,,_/ fl ~ .11"\ Rellnql.ishsd tr,: (Sigmffln) Reoeiv9d by: (SignSNre)

I Dste: nne:

~r~ /\ - ,,.! . /_ ,, 1/,- // r2_,b.. Relinqui6httl Dy: (Si$Mb.fe) Reocivcd by: (Si$1l3t1>tte) C,me: limit:

6/29/16 10:26 AMP1603010_Oneida Total Integrated Enterprises (OTIE)_Pemaco Plant Vapor Monitoring.xls - Page 1 of 1

ALS EnvironmentalSample Acceptance Check Form

Client: Oneida Total Integrated Enterprises (OTIE) Work order: P1603010Project: Pemaco Plant Vapor MonitoringSample(s) received on: 6/14/16 Date opened: 6/14/16 by: KKELPE

Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of

compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP.Yes No N/A

1 Were sample containers properly marked with client sample ID? 2 Did sample containers arrive in good condition? 3 Were chain-of-custody papers used and filled out? 4 Did sample container labels and/or tags agree with custody papers? 5 Was sample volume received adequate for analysis? 6 Are samples within specified holding times? 7 Was proper temperature (thermal preservation) of cooler at receipt adhered to?

8 Were custody seals on outside of cooler/Box/Container? Location of seal(s)? Sealing Lid?

Were signature and date included? Were seals intact?

9 Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?

10 Tubes: Are the tubes capped and intact? 11 Badges: Are the badges properly capped and intact?

Are dual bed badges separated and individually capped and intact?

Lab Sample ID Container Required Received Adjusted VOA HeadspaceDescription pH * pH pH (Presence/Absence) Comments

1.0 L Bottle-Vac™1.0 L Bottle-Vac™

RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4)

Explain any discrepancies: (include lab sample ID numbers):

Do containers have appropriate preservation, according to method/SOP or Client specified information?

Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it?

Receipt / Preservation

P1603010-001.01P1603010-002.01

6 of 113

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603010_TO15_1606221211_SC.xls - Sample

ALS ENVIRONMENTAL

RESULTS OF ANALYSISPage 1 of 3

Client: Oneida Total Integrated Enterprises (OTIE)SP-106-20160614 ALS Project ID: P1603010

ALS Sample ID: P1603010-001

Test Code: EPA TO-15 Modified Date Collected: 6/14/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 6/14/16Analyst: Wida Ang Date Analyzed: 6/21/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.40 Liter(s)Test Notes: Container ID: 1BV06400

Initial Pressure (psig): -0.13 Final Pressure (psig): 6.97

Canister Dilution Factor: 1.49

CAS # Compound MRL MDL MRL MDL Dataµg/m³ µg/m³ ppbV ppbV Qualifier

115-07-1 Propene ND 1.9 0.52 ND 1.1 0.3075-71-8 Dichlorodifluoromethane (CFC 12) 1.8 1.9 0.63 0.36 0.38 0.13 J74-87-3 Chloromethane ND 1.9 0.56 ND 0.90 0.27

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 1.9 0.71 ND 0.27 0.10

75-01-4 Vinyl Chloride 1.7 1.9 0.63 0.65 0.73 0.25 J106-99-0 1,3-Butadiene ND 1.9 0.82 ND 0.84 0.3774-83-9 Bromomethane ND 1.9 0.71 ND 0.48 0.1875-00-3 Chloroethane ND 1.9 0.63 ND 0.71 0.2464-17-5 Ethanol 18 19 3.0 9.8 9.9 1.6 J75-05-8 Acetonitrile ND 1.9 0.67 ND 1.1 0.40107-02-8 Acrolein ND 7.5 0.63 ND 3.3 0.2867-64-1 Acetone 4.8 19 2.9 2.0 7.8 1.2 J75-69-4 Trichlorofluoromethane ND 1.9 0.63 ND 0.33 0.1167-63-0 2-Propanol (Isopropyl Alcohol) ND 19 1.6 ND 7.6 0.64107-13-1 Acrylonitrile ND 1.9 0.63 ND 0.86 0.2975-35-4 1,1-Dichloroethene ND 1.9 0.63 ND 0.47 0.1675-09-2 Methylene Chloride ND 1.9 0.63 ND 0.54 0.18107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 1.9 0.60 ND 0.60 0.1976-13-1 Trichlorotrifluoroethane ND 1.9 0.63 ND 0.24 0.08375-15-0 Carbon Disulfide ND 19 0.56 ND 6.0 0.18156-60-5 trans-1,2-Dichloroethene ND 1.9 0.71 ND 0.47 0.1875-34-3 1,1-Dichloroethane ND 1.9 0.60 ND 0.46 0.151634-04-4 Methyl tert-Butyl Ether ND 1.9 0.63 ND 0.52 0.18108-05-4 Vinyl Acetate ND 19 2.4 ND 5.3 0.6978-93-3 2-Butanone (MEK) 0.95 19 0.78 0.32 6.3 0.27 J

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.J = The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL.

ResultppbV

Resultµg/m³

Client Sample ID:Client Project ID: Pemaco Plant Vapor Monitoring

7 of 113


ALS ENVIRONMENTAL




Test Code: EPA TO-15 Modified Date Collected: 6/14/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 6/14/16Analyst: Wida Ang Date Analyzed: 6/21/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.40 Liter(s)Test Notes:Container ID: 1BV06400




156-59-2 cis-1,2-Dichloroethene ND 1.9 0.60 ND 0.47 0.15141-78-6 Ethyl Acetate ND 3.7 1.3 ND 1.0 0.36110-54-3 n-Hexane ND 1.9 0.56 ND 0.53 0.1667-66-3 Chloroform ND 1.9 0.63 ND 0.38 0.13109-99-9 Tetrahydrofuran (THF) ND 1.9 0.75 ND 0.63 0.25107-06-2 1,2-Dichloroethane ND 1.9 0.60 ND 0.46 0.1571-55-6 1,1,1-Trichloroethane ND 1.9 0.63 ND 0.34 0.1271-43-2 Benzene ND 1.9 0.60 ND 0.58 0.1956-23-5 Carbon Tetrachloride ND 1.9 0.56 ND 0.30 0.089110-82-7 Cyclohexane ND 3.7 1.1 ND 1.1 0.3178-87-5 1,2-Dichloropropane ND 1.9 0.60 ND 0.40 0.1375-27-4 Bromodichloromethane ND 1.9 0.56 ND 0.28 0.08379-01-6 Trichloroethene ND 1.9 0.52 ND 0.35 0.097123-91-1 1,4-Dioxane ND 1.9 0.60 ND 0.52 0.1780-62-6 Methyl Methacrylate ND 3.7 1.2 ND 0.91 0.28142-82-5 n-Heptane ND 1.9 0.63 ND 0.45 0.1510061-01-5 cis-1,3-Dichloropropene ND 1.9 0.52 ND 0.41 0.11108-10-1 4-Methyl-2-pentanone ND 1.9 0.60 ND 0.45 0.1510061-02-6 trans-1,3-Dichloropropene ND 1.9 0.60 ND 0.41 0.1379-00-5 1,1,2-Trichloroethane ND 1.9 0.60 ND 0.34 0.11108-88-3 Toluene 1.1 1.9 0.63 0.30 0.49 0.17 J591-78-6 2-Hexanone ND 1.9 0.60 ND 0.45 0.15124-48-1 Dibromochloromethane ND 1.9 0.60 ND 0.22 0.070106-93-4 1,2-Dibromoethane ND 1.9 0.60 ND 0.24 0.078123-86-4 n-Butyl Acetate ND 1.9 0.60 ND 0.39 0.13


ppbV

Pemaco Plant Vapor Monitoring

Resultµg/m³

Result

Client Sample ID:Client Project ID:

8 of 113


ALS ENVIRONMENTAL




Test Code: EPA TO-15 Modified Date Collected: 6/14/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 6/14/16Analyst: Wida Ang Date Analyzed: 6/21/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.40 Liter(s)Test Notes: Container ID: 1BV06400



MRL MDL MRL MDL Data CAS # Compound µg/m³ µg/m³ ppbV ppbV Qualifier

111-65-9 n-Octane ND 1.9 0.67 ND 0.40 0.14127-18-4 Tetrachloroethene ND 1.9 0.52 ND 0.27 0.077108-90-7 Chlorobenzene ND 1.9 0.60 ND 0.40 0.13100-41-4 Ethylbenzene 0.85 1.9 0.60 0.19 0.43 0.14 J179601-23-1 m,p-Xylenes 1.2 3.7 1.1 0.28 0.86 0.26 J75-25-2 Bromoform ND 1.9 0.56 ND 0.18 0.054100-42-5 Styrene ND 1.9 0.56 ND 0.44 0.1395-47-6 o-Xylene 0.64 1.9 0.56 0.15 0.43 0.13 J111-84-2 n-Nonane ND 1.9 0.56 ND 0.36 0.1179-34-5 1,1,2,2-Tetrachloroethane ND 1.9 0.56 ND 0.27 0.08198-82-8 Cumene 1.5 1.9 0.56 0.30 0.38 0.11 J80-56-8 alpha-Pinene 0.82 1.9 0.52 0.15 0.33 0.094 J103-65-1 n-Propylbenzene ND 1.9 0.60 ND 0.38 0.12622-96-8 4-Ethyltoluene ND 1.9 0.60 ND 0.38 0.12108-67-8 1,3,5-Trimethylbenzene ND 1.9 0.60 ND 0.38 0.1295-63-6 1,2,4-Trimethylbenzene ND 1.9 0.56 ND 0.38 0.11100-44-7 Benzyl Chloride ND 1.9 0.41 ND 0.36 0.079541-73-1 1,3-Dichlorobenzene ND 1.9 0.56 ND 0.31 0.093106-46-7 1,4-Dichlorobenzene ND 1.9 0.52 ND 0.31 0.08795-50-1 1,2-Dichlorobenzene ND 1.9 0.56 ND 0.31 0.0935989-27-5 d-Limonene 1.3 1.9 0.52 0.23 0.33 0.094 J96-12-8 1,2-Dibromo-3-chloropropane ND 1.9 0.37 ND 0.19 0.038120-82-1 1,2,4-Trichlorobenzene ND 1.9 0.60 ND 0.25 0.08091-20-3 Naphthalene 0.80 1.9 0.67 0.15 0.36 0.13 J87-68-3 Hexachlorobutadiene ND 1.9 0.52 ND 0.17 0.049


µg/m³

Client Project ID:

ppbV

Client Sample ID:

ResultResult


9 of 113

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603010_TO15_1606221211_SC.xls - Sample (2)

ALS ENVIRONMENTAL




Test Code: EPA TO-15 Modified Date Collected: 6/14/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: 6/14/16Analyst: Wida Ang Date Analyzed: 6/21/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.20 Liter(s)Test Notes: 0.050 Liter(s)Container ID: 1BV06401




115-07-1 Propene ND 3.6 1.0 ND 2.1 0.5975-71-8 Dichlorodifluoromethane (CFC 12) 2.0 3.6 1.2 0.41 0.73 0.25 J74-87-3 Chloromethane ND 3.6 1.1 ND 1.8 0.53


75-01-4 Vinyl Chloride 3.0 3.6 1.2 1.2 1.4 0.48 J106-99-0 1,3-Butadiene ND 3.6 1.6 ND 1.6 0.7274-83-9 Bromomethane ND 3.6 1.4 ND 0.93 0.3575-00-3 Chloroethane ND 3.6 1.2 ND 1.4 0.4764-17-5 Ethanol 16 36 5.8 8.3 19 3.1 J75-05-8 Acetonitrile ND 3.6 1.3 ND 2.2 0.78107-02-8 Acrolein ND 15 1.2 ND 6.3 0.5467-64-1 Acetone 35 36 5.6 15 15 2.4 J75-69-4 Trichlorofluoromethane ND 3.6 1.2 ND 0.65 0.2267-63-0 2-Propanol (Isopropyl Alcohol) ND 36 3.0 ND 15 1.2107-13-1 Acrylonitrile ND 3.6 1.2 ND 1.7 0.5775-35-4 1,1-Dichloroethene 44 3.6 1.2 11 0.91 0.3175-09-2 Methylene Chloride ND 3.6 1.2 ND 1.0 0.35107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 3.6 1.2 ND 1.2 0.3776-13-1 Trichlorotrifluoroethane ND 3.6 1.2 ND 0.47 0.1675-15-0 Carbon Disulfide ND 36 1.1 ND 12 0.35156-60-5 trans-1,2-Dichloroethene 3.5 3.6 1.4 0.89 0.91 0.35 J75-34-3 1,1-Dichloroethane 8.8 3.6 1.2 2.2 0.90 0.291634-04-4 Methyl tert-Butyl Ether ND 3.6 1.2 ND 1.0 0.34108-05-4 Vinyl Acetate ND 36 4.7 ND 10 1.378-93-3 2-Butanone (MEK) 3.8 36 1.5 1.3 12 0.52 J



ResultppbV

Resultµg/m³


10 of 113


ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene 65 3.6 1.2 16 0.91 0.29141-78-6 Ethyl Acetate ND 7.3 2.5 ND 2.0 0.70110-54-3 n-Hexane 150 3.6 1.1 41 1.0 0.3167-66-3 Chloroform 15 3.6 1.2 3.1 0.74 0.25109-99-9 Tetrahydrofuran (THF) 2.7 3.6 1.5 0.93 1.2 0.49 J107-06-2 1,2-Dichloroethane ND 3.6 1.2 ND 0.90 0.2971-55-6 1,1,1-Trichloroethane 12 3.6 1.2 2.2 0.66 0.2371-43-2 Benzene 17 3.6 1.2 5.3 1.1 0.3656-23-5 Carbon Tetrachloride ND 3.6 1.1 ND 0.58 0.17110-82-7 Cyclohexane 130 7.3 2.1 39 2.1 0.6178-87-5 1,2-Dichloropropane ND 3.6 1.2 ND 0.78 0.2575-27-4 Bromodichloromethane ND 3.6 1.1 ND 0.54 0.1679-01-6 Trichloroethene 1,200 15 4.1 220 2.7 0.76 D123-91-1 1,4-Dioxane ND 3.6 1.2 ND 1.0 0.3280-62-6 Methyl Methacrylate ND 7.3 2.2 ND 1.8 0.55142-82-5 n-Heptane 42 3.6 1.2 10 0.88 0.3010061-01-5 cis-1,3-Dichloropropene ND 3.6 1.0 ND 0.80 0.22108-10-1 4-Methyl-2-pentanone ND 3.6 1.2 ND 0.88 0.2810061-02-6 trans-1,3-Dichloropropene ND 3.6 1.2 ND 0.80 0.2679-00-5 1,1,2-Trichloroethane ND 3.6 1.2 ND 0.66 0.21108-88-3 Toluene ND 3.6 1.2 ND 0.96 0.33591-78-6 2-Hexanone ND 3.6 1.2 ND 0.89 0.28124-48-1 Dibromochloromethane ND 3.6 1.2 ND 0.43 0.14106-93-4 1,2-Dibromoethane ND 3.6 1.2 ND 0.47 0.15123-86-4 n-Butyl Acetate ND 3.6 1.2 ND 0.76 0.24

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.J = The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL.D = The reported result is from a dilution.


Resultµg/m³

Result


ppbV

11 of 113


ALS ENVIRONMENTAL








111-65-9 n-Octane 6.8 3.6 1.3 1.5 0.78 0.28127-18-4 Tetrachloroethene 240 3.6 1.0 35 0.53 0.15108-90-7 Chlorobenzene ND 3.6 1.2 ND 0.79 0.25100-41-4 Ethylbenzene 2.1 3.6 1.2 0.48 0.83 0.27 J179601-23-1 m,p-Xylenes ND 7.3 2.2 ND 1.7 0.5075-25-2 Bromoform ND 3.6 1.1 ND 0.35 0.11100-42-5 Styrene ND 3.6 1.1 ND 0.85 0.2695-47-6 o-Xylene ND 3.6 1.1 ND 0.83 0.25111-84-2 n-Nonane ND 3.6 1.1 ND 0.69 0.2179-34-5 1,1,2,2-Tetrachloroethane ND 3.6 1.1 ND 0.53 0.1698-82-8 Cumene 1.3 3.6 1.1 0.27 0.74 0.22 J80-56-8 alpha-Pinene ND 3.6 1.0 ND 0.65 0.18103-65-1 n-Propylbenzene 3.9 3.6 1.2 0.79 0.74 0.24622-96-8 4-Ethyltoluene ND 3.6 1.2 ND 0.74 0.24108-67-8 1,3,5-Trimethylbenzene ND 3.6 1.2 ND 0.74 0.2495-63-6 1,2,4-Trimethylbenzene 4.5 3.6 1.1 0.92 0.74 0.22100-44-7 Benzyl Chloride ND 3.6 0.80 ND 0.70 0.15541-73-1 1,3-Dichlorobenzene ND 3.6 1.1 ND 0.60 0.18106-46-7 1,4-Dichlorobenzene ND 3.6 1.0 ND 0.60 0.1795-50-1 1,2-Dichlorobenzene ND 3.6 1.1 ND 0.60 0.185989-27-5 d-Limonene ND 3.6 1.0 ND 0.65 0.1896-12-8 1,2-Dibromo-3-chloropropane ND 3.6 0.72 ND 0.38 0.074120-82-1 1,2,4-Trichlorobenzene ND 3.6 1.2 ND 0.49 0.1691-20-3 Naphthalene 21 3.6 1.3 4.0 0.69 0.2587-68-3 Hexachlorobutadiene ND 3.6 1.0 ND 0.34 0.095


ResultResultµg/m³

Client Project ID:

ppbV

Client Sample ID:Pemaco Plant Vapor Monitoring

12 of 113

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603010_TO15_1606221211_SC.xls - MBlank

ALS ENVIRONMENTAL


Client: Oneida Total Integrated Enterprises (OTIE)Method Blank ALS Project ID: P1603010

ALS Sample ID: P160621-MB Test Code: EPA TO-15 Modified Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: NAAnalyst: Wida Ang Date Analyzed: 6/21/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



115-07-1 Propene ND 0.50 0.14 ND 0.29 0.08175-71-8 Dichlorodifluoromethane (CFC 12) ND 0.50 0.17 ND 0.10 0.03474-87-3 Chloromethane ND 0.50 0.15 ND 0.24 0.073


75-01-4 Vinyl Chloride ND 0.50 0.17 ND 0.20 0.067106-99-0 1,3-Butadiene ND 0.50 0.22 ND 0.23 0.09974-83-9 Bromomethane ND 0.50 0.19 ND 0.13 0.04975-00-3 Chloroethane ND 0.50 0.17 ND 0.19 0.06464-17-5 Ethanol ND 5.0 0.80 ND 2.7 0.4275-05-8 Acetonitrile ND 0.50 0.18 ND 0.30 0.11107-02-8 Acrolein ND 2.0 0.17 ND 0.87 0.07467-64-1 Acetone ND 5.0 0.77 ND 2.1 0.3275-69-4 Trichlorofluoromethane ND 0.50 0.17 ND 0.089 0.03067-63-0 2-Propanol (Isopropyl Alcohol) ND 5.0 0.42 ND 2.0 0.17107-13-1 Acrylonitrile ND 0.50 0.17 ND 0.23 0.07875-35-4 1,1-Dichloroethene ND 0.50 0.17 ND 0.13 0.04375-09-2 Methylene Chloride ND 0.50 0.17 ND 0.14 0.049107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 0.50 0.16 ND 0.16 0.05176-13-1 Trichlorotrifluoroethane ND 0.50 0.17 ND 0.065 0.02275-15-0 Carbon Disulfide ND 5.0 0.15 ND 1.6 0.048156-60-5 trans-1,2-Dichloroethene ND 0.50 0.19 ND 0.13 0.04875-34-3 1,1-Dichloroethane ND 0.50 0.16 ND 0.12 0.0401634-04-4 Methyl tert-Butyl Ether ND 0.50 0.17 ND 0.14 0.047108-05-4 Vinyl Acetate ND 5.0 0.65 ND 1.4 0.1878-93-3 2-Butanone (MEK) ND 5.0 0.21 ND 1.7 0.071

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.

Client Sample ID:Client Project ID: Pemaco Plant Vapor Monitoring

ResultppbV

Resultµg/m³

13 of 113


ALS ENVIRONMENTAL



ALS Sample ID: P160621-MB

Test Code: EPA TO-15 Modified Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date Received: NAAnalyst: Wida Ang Date Analyzed: 6/21/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



156-59-2 cis-1,2-Dichloroethene ND 0.50 0.16 ND 0.13 0.040141-78-6 Ethyl Acetate ND 1.0 0.35 ND 0.28 0.097110-54-3 n-Hexane ND 0.50 0.15 ND 0.14 0.04367-66-3 Chloroform ND 0.50 0.17 ND 0.10 0.035109-99-9 Tetrahydrofuran (THF) ND 0.50 0.20 ND 0.17 0.068107-06-2 1,2-Dichloroethane ND 0.50 0.16 ND 0.12 0.04071-55-6 1,1,1-Trichloroethane ND 0.50 0.17 ND 0.092 0.03171-43-2 Benzene ND 0.50 0.16 ND 0.16 0.05056-23-5 Carbon Tetrachloride ND 0.50 0.15 ND 0.080 0.024110-82-7 Cyclohexane ND 1.0 0.29 ND 0.29 0.08478-87-5 1,2-Dichloropropane ND 0.50 0.16 ND 0.11 0.03575-27-4 Bromodichloromethane ND 0.50 0.15 ND 0.075 0.02279-01-6 Trichloroethene ND 0.50 0.14 ND 0.093 0.026123-91-1 1,4-Dioxane ND 0.50 0.16 ND 0.14 0.04480-62-6 Methyl Methacrylate ND 1.0 0.31 ND 0.24 0.076142-82-5 n-Heptane ND 0.50 0.17 ND 0.12 0.04110061-01-5 cis-1,3-Dichloropropene ND 0.50 0.14 ND 0.11 0.031108-10-1 4-Methyl-2-pentanone ND 0.50 0.16 ND 0.12 0.03910061-02-6 trans-1,3-Dichloropropene ND 0.50 0.16 ND 0.11 0.03579-00-5 1,1,2-Trichloroethane ND 0.50 0.16 ND 0.092 0.029108-88-3 Toluene ND 0.50 0.17 ND 0.13 0.045591-78-6 2-Hexanone ND 0.50 0.16 ND 0.12 0.039124-48-1 Dibromochloromethane ND 0.50 0.16 ND 0.059 0.019106-93-4 1,2-Dibromoethane ND 0.50 0.16 ND 0.065 0.021123-86-4 n-Butyl Acetate ND 0.50 0.16 ND 0.11 0.034


ppbV


Resultµg/m³


Result

14 of 113


ALS ENVIRONMENTAL



ALS Sample ID: P160621-MB




111-65-9 n-Octane ND 0.50 0.18 ND 0.11 0.039127-18-4 Tetrachloroethene ND 0.50 0.14 ND 0.074 0.021108-90-7 Chlorobenzene ND 0.50 0.16 ND 0.11 0.035100-41-4 Ethylbenzene ND 0.50 0.16 ND 0.12 0.037179601-23-1 m,p-Xylenes ND 1.0 0.30 ND 0.23 0.06975-25-2 Bromoform ND 0.50 0.15 ND 0.048 0.015100-42-5 Styrene ND 0.50 0.15 ND 0.12 0.03595-47-6 o-Xylene ND 0.50 0.15 ND 0.12 0.035111-84-2 n-Nonane ND 0.50 0.15 ND 0.095 0.02979-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.15 ND 0.073 0.02298-82-8 Cumene ND 0.50 0.15 ND 0.10 0.03180-56-8 alpha-Pinene ND 0.50 0.14 ND 0.090 0.025103-65-1 n-Propylbenzene ND 0.50 0.16 ND 0.10 0.033622-96-8 4-Ethyltoluene ND 0.50 0.16 ND 0.10 0.033108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.16 ND 0.10 0.03395-63-6 1,2,4-Trimethylbenzene ND 0.50 0.15 ND 0.10 0.031100-44-7 Benzyl Chloride ND 0.50 0.11 ND 0.097 0.021541-73-1 1,3-Dichlorobenzene ND 0.50 0.15 ND 0.083 0.025106-46-7 1,4-Dichlorobenzene ND 0.50 0.14 ND 0.083 0.02395-50-1 1,2-Dichlorobenzene ND 0.50 0.15 ND 0.083 0.0255989-27-5 d-Limonene ND 0.50 0.14 ND 0.090 0.02596-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.099 ND 0.052 0.010120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.16 ND 0.067 0.02291-20-3 Naphthalene ND 0.50 0.18 ND 0.095 0.03487-68-3 Hexachlorobutadiene ND 0.50 0.14 ND 0.047 0.013


ResultppbV


Resultµg/m³


15 of 113

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603010_TO15_1606221211_SC.xls - Surrogates

ALS ENVIRONMENTAL

SURROGATE SPIKE RECOVERY RESULTSPage 1 of 1

Client: Oneida Total Integrated Enterprises (OTIE)ALS Project ID: P1603010

Test Code: EPA TO-15 ModifiedInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Date(s) Collected: 6/14/16Analyst: Wida Ang Date(s) Received: 6/14/16Sample Type: 1.0 L Bottle-Vac™(s) Date(s) Analyzed: 6/21/16Test Notes:

Client Sample ID ALS Sample ID Acceptance DataLimits Qualifier

P160621-MB 70-130 P160621-LCS 70-130 P1603010-001 70-130 P1603010-002 70-130

Surrogate percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly from the on-column percent recovery.

9710799107

RecoveredPercent

94

SP-104-20160614

RecoveredRecoveredPercent

Method Blank105

Percent

93

9594

98Lab Control Sample106102

Client Project ID:

SP-106-20160614

1,2-Dichloroethane-d4 BromofluorobenzeneToluene-d8


16 of 113

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603010_TO15_1606221211_SC.xls - LCS

ALS ENVIRONMENTAL

LABORATORY CONTROL SAMPLE SUMMARYPage 1 of 3

Client: Oneida Total Integrated Enterprises (OTIE)Lab Control Sample ALS Project ID: P1603010

ALS Sample ID: P160621-LCS


CAS # Compound Data Qualifier

115-07-1 Propene 87 49-13175-71-8 Dichlorodifluoromethane (CFC 12) 88 65-11774-87-3 Chloromethane 106 48-132

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) 92 65-122

75-01-4 Vinyl Chloride 96 65-128106-99-0 1,3-Butadiene 102 62-14374-83-9 Bromomethane 111 65-13075-00-3 Chloroethane 99 69-12664-17-5 Ethanol 98 57-12675-05-8 Acetonitrile 95 51-134107-02-8 Acrolein 90 55-14667-64-1 Acetone 83 57-12075-69-4 Trichlorofluoromethane 80 59-13967-63-0 2-Propanol (Isopropyl Alcohol) 102 59-129107-13-1 Acrylonitrile 99 64-13675-35-4 1,1-Dichloroethene 102 72-12375-09-2 Methylene Chloride 103 63-117107-05-1 3-Chloro-1-propene (Allyl Chloride) 100 50-14176-13-1 Trichlorotrifluoroethane 95 68-11875-15-0 Carbon Disulfide 80 55-143156-60-5 trans-1,2-Dichloroethene 100 69-12975-34-3 1,1-Dichloroethane 92 66-1221634-04-4 Methyl tert-Butyl Ether 92 55-128108-05-4 Vinyl Acetate 102 66-14078-93-3 2-Butanone (MEK) 94 62-127

Laboratory Control Sample percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly.

212216

196198

10601,040206220

214 1931,080216

891

188

202

173

µg/m³

191210

425

ALSAcceptance

166

% RecoverySpike AmountLimits

212

225200998

198977

206

170µg/m³

211


200

202

204200

196188


Result

219228

218

210

222

209

210

212216 220

167220

210 209

418

17 of 113


ALS ENVIRONMENTAL





CAS # Compound Data Qualifier

156-59-2 cis-1,2-Dichloroethene 98 65-125141-78-6 Ethyl Acetate 96 64-132110-54-3 n-Hexane 84 58-12667-66-3 Chloroform 90 68-117109-99-9 Tetrahydrofuran (THF) 96 64-123107-06-2 1,2-Dichloroethane 91 63-12471-55-6 1,1,1-Trichloroethane 94 68-12071-43-2 Benzene 85 61-11056-23-5 Carbon Tetrachloride 92 65-137110-82-7 Cyclohexane 93 68-12278-87-5 1,2-Dichloropropane 95 67-12275-27-4 Bromodichloromethane 98 71-12479-01-6 Trichloroethene 93 71-121123-91-1 1,4-Dioxane 103 67-12280-62-6 Methyl Methacrylate 100 76-130142-82-5 n-Heptane 90 67-12510061-01-5 cis-1,3-Dichloropropene 102 73-131108-10-1 4-Methyl-2-pentanone 100 66-13210061-02-6 trans-1,3-Dichloropropene 101 76-13579-00-5 1,1,2-Trichloroethane 100 73-121108-88-3 Toluene 89 67-117591-78-6 2-Hexanone 98 59-128124-48-1 Dibromochloromethane 105 73-132106-93-4 1,2-Dibromoethane 95 73-128123-86-4 n-Butyl Acetate 97 61-136


178

207

220

212

218

216210

201

Client Sample ID:

218

Client Project ID:

µg/m³Spike Amount


428 409

µg/m³214

216

ALS

202212

AcceptanceLimits

% RecoveryResult

220220

210

220230

213

220

226

195215

218

216 195213208

218

230

213

224

206

192

424216

394

210 198

220194214

226

422 423

216217

211

18 of 113


ALS ENVIRONMENTAL





CAS # Compound DataQualifier

111-65-9 n-Octane 92 67-124127-18-4 Tetrachloroethene 91 65-126108-90-7 Chlorobenzene 91 68-120100-41-4 Ethylbenzene 92 69-123179601-23-1 m,p-Xylenes 91 67-12575-25-2 Bromoform 93 68-153100-42-5 Styrene 103 68-13295-47-6 o-Xylene 91 67-124111-84-2 n-Nonane 90 60-13079-34-5 1,1,2,2-Tetrachloroethane 98 72-12898-82-8 Cumene 92 67-12480-56-8 alpha-Pinene 97 67-129103-65-1 n-Propylbenzene 89 67-125622-96-8 4-Ethyltoluene 90 66-128108-67-8 1,3,5-Trimethylbenzene 90 65-12595-63-6 1,2,4-Trimethylbenzene 93 62-134100-44-7 Benzyl Chloride 101 74-145541-73-1 1,3-Dichlorobenzene 94 63-133106-46-7 1,4-Dichlorobenzene 98 62-12995-50-1 1,2-Dichlorobenzene 94 62-1345989-27-5 d-Limonene 109 66-13796-12-8 1,2-Dibromo-3-chloropropane 95 71-147120-82-1 1,2,4-Trichlorobenzene 97 60-14591-20-3 Naphthalene 104 56-15887-68-3 Hexachlorobutadiene 90 56-139


202

192

208


428

192

208

228222

223

223

206

207227

214203

229210218230

230218

210204

228220218

218

210

205191

220

214

200

182

208

229

212 205

210

204

212391

183202220

214

ALSAcceptance

Limits% Recovery

191183

Spike Amount

194

201

Client Project ID:Client Sample ID:

Resultµg/m³µg/m³

19 of 113

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603010_TO15_1606221211_SC.xls - ISS

ALS ENVIRONMENTAL


Client: Oneida Total Integrated Enterprises (OTIE) ALS Project ID: P1603010Pemaco Plant Vapor Monitoring

Internal Standard Area and RT Summary

Test Code: EPA TO-15 ModifiedInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS8 Lab File ID: 06211604.DAnalyst: Wida Ang Date Analyzed: 6/21/16Sample Type: 1.0 L Bottle-Vac™(s) Time Analyzed: 08:48

Test Notes:

IS1 (BCM) IS2 (DFB) IS3 (CBZ)AREA # RT # AREA # RT # AREA # RT #

24 Hour Standard 122789 8.80 561009 10.54 238359 14.57 Upper Limit 171905 9.13 785413 10.87 333703 14.90 Lower Limit 73673 8.47 336605 10.21 143015 14.24

Client Sample ID01 Method Blank 119667 8.79 572010 10.53 233457 14.5702 Lab Control Sample 123341 8.81 563067 10.54 244725 14.5703 SP-106-20160614 120413 8.80 587916 10.54 249725 14.5704 SP-104-20160614 122169 8.80 552749 10.54 239859 14.5705 SP-104-20160614 (Dilution) 116987 8.80 522407 10.54 230814 14.57060708091011121314151617181920

IS1 (BCM) = BromochloromethaneIS2 (DFB) = 1,4-DifluorobenzeneIS3 (CBZ) = Chlorobenzene-d5

AREA UPPER LIMIT = 140% of internal standard areaAREA LOWER LIMIT = 60% of internal standard areaRT UPPER LIMIT = 0.33 minutes of internal standard RTRT LOWER LIMIT = 0.33 minutes of internal standard RT

# Column used to flag values outside QC limits with an I.I = Internal standard not within the specified limits.

Client Project ID:

20 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211613.D Acq On : 21 Jun 2016 14:19 Operator: WA Sample : P1603010-001 (400mL) Misc : S29-06151601 ALS Vial : 9 Sample Multiplier: 1 Quant Time: Jun 21 17:08:24 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.80 130 120413 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.54 114 587916 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 14.57 82 249725 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 201804 11.909 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.28% 57) Toluene-d8 (SS2) 12.77 98 611749 12.381 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.04% 73) Bromofluorobenzene (SS3) 16.07 174 239404 13.380 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 107.04% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. d 3) Dichlorodifluoromethan... 4.05 85 11994 0.480 ng 97 4) Chloromethane 4.24 50 867 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 4.52 62 6715 0.449 ng 93 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 5.37 45 41809 4.934 ng 99 11) Acetonitrile 5.61 41 70 N.D. 12) Acrolein 5.75 56 444 N.D. 13) Acetone 5.86 58 12210 1.302 ng 95 14) Trichlorofluoromethane 0.00 101 0 N.D. 15) 2-Propanol (Isopropanol) 6.16 45 4229 0.146 ng 73 16) Acrylonitrile 0.00 53 0 N.D. 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 0.00 59 0 N.D. d 19) Methylene Chloride 0.00 84 0 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 0.00 151 0 N.D. 22) Carbon Disulfide 0.00 76 0 N.D. d 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. d 24) 1,1-Dichloroethane 0.00 63 0 N.D. 25) Methyl tert-Butyl Ether 7.89 73 575 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 8.27 72 1897 0.254 ng # 51 28) cis-1,2-Dichloroethene 0.00 61 0 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 8.87 57 693 N.D. 32) Chloroform 0.00 83 0 N.D. 34) Tetrahydrofuran (THF) 9.29 72 796 0.111 ng # 43 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 10.23 78 3688 N.D. 42) Carbon Tetrachloride 0.00 117 0 N.D. 43) Cyclohexane 0.00 84 0 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 0.00 63 0 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. 47) Trichloroethene 0.00 130 0 N.D. 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 11.23 57 915 N.D.

R8061516.M Tue Jun 21 17:18:07 2016 Page: 1

21 of 113

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Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211613.D Acq On : 21 Jun 2016 14:19 Operator: WA Sample : P1603010-001 (400mL) Misc : S29-06151601 ALS Vial : 9 Sample Multiplier: 1 Quant Time: Jun 21 17:08:24 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 11.45 71 853 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 12.87 91 14134 0.300 ng 89 59) 2-Hexanone 13.12 43 1735 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 13.71 43 1208 N.D. 63) n-Octane 0.00 57 0 N.D. 64) Tetrachloroethene 0.00 166 0 N.D. 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 15.00 91 12396 0.227 ng 97 67) m- & p-Xylenes 15.16 91 14266 0.326 ng 97 68) Bromoform 0.00 173 0 N.D. 69) Styrene 15.54 104 1241 N.D. 70) o-Xylene 15.64 91 7859 0.171 ng 95 71) n-Nonane 15.85 43 3139 0.112 ng 95 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 16.21 105 23874 0.401 ng 96 75) alpha-Pinene 16.59 93 6297 0.221 ng # 1 76) n-Propylbenzene 16.71 91 2180 N.D. 77) 3-Ethyltoluene 16.81 105 3024 N.D. 78) 4-Ethyltoluene 16.84 105 1626 N.D. 79) 1,3,5-Trimethylbenzene 16.92 105 1936 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. 81) 2-Ethyltoluene 17.10 105 1724 N.D. 82) 1,2,4-Trimethylbenzene 17.31 105 4708 0.096 ng 90 83) n-Decane 0.00 57 0 N.D. d 84) Benzyl Chloride 17.41 91 531 N.D. 85) 1,3-Dichlorobenzene 17.53 146 1598 N.D. 86) 1,4-Dichlorobenzene 17.53 146 1598 N.D. 87) sec-Butylbenzene 17.72 105 3647 N.D. 88) 4-Isopropyltoluene (p-... 0.00 119 0 N.D. d 89) 1,2,3-Trimethylbenzene 17.72 105 3647 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 17.85 68 5485 0.344 ng 98 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. d 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 19.57 128 13131 0.216 ng 100 96) n-Dodecane 0.00 57 0 N.D. d 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 17.31 119 1131 N.D. 100) n-Butylbenzene 18.12 91 932 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Tue Jun 21 17:18:07 2016 Page: 2

22 of 113

Quantitation Report (QT Reviewed)

Data File: I:\MS08\Data\2016_06\21\06211613.D Acq On : 21 Jun 2016 14:19 Operator: WA Sample : P1603010-001 (400mL) Misc : S29-06151601 ALS Vial : 9 Sample Multiplier: 1

Quant Time: Jun 21 17:08:24 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

2.2e+07

2.3e+07

2.4e+07

2.5e+07

2.6e+07

2.7e+07

2.8e+07

2.9e+07

3e+07

Time-->

Abundance TIC: 06211613.D\data.ms

Nap

htha

lene

,T

d-Li

mon

ene,

T

1,2,

4-Tr

imet

hylb

enze

ne,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene,

TTo

luen

e-d8

(SS2

),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Tetra

hydr

ofur

an (T

HF)

,T

Brom

ochl

orom

etha

ne (I

S1),I

R

2-Bu

tano

ne (M

EK),T

2-Pr

opan

ol (I

sopr

opan

ol),T

Acet

one,

T

Etha

nol,T

Viny

l Chl

orid

e,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8061516.M Tue Jun 21 17:18:08 2016 Page: 3

23 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211613.D Acq On : 21 Jun 2016 14:19 Operator: WA Sample : P1603010-001 (400mL) Misc : S29-06151601 ALS Vial : 9 Sample Multiplier: 1 Quant Time: Jun 21 17:08:24 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.80 130 120413 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.54 114 587916 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 14.57 82 249725 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 201804 11.909 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.28% 57) Toluene-d8 (SS2) 12.77 98 611749 12.381 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.04% 73) Bromofluorobenzene (SS3) 16.07 174 239404 13.380 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 107.04% Target Compounds Qvalue 3) Dichlorodifluoromethan... 4.05 85 11994 0.480 ng 97 6) Vinyl Chloride 4.52 62 6715 0.449 ng 93 10) Ethanol 5.37 45 41809 4.934 ng 99 13) Acetone 5.86 58 12210 1.302 ng 95 15) 2-Propanol (Isopropanol) 6.16 45 4229 0.146 ng 73 27) 2-Butanone (MEK) 8.27 72 1897 0.254 ng # 51 34) Tetrahydrofuran (THF) 9.29 72 796 0.111 ng # 43 58) Toluene 12.87 91 14134 0.300 ng 89 66) Ethylbenzene 15.00 91 12396 0.227 ng 97 67) m- & p-Xylenes 15.16 91 14266 0.326 ng 97 70) o-Xylene 15.64 91 7859 0.171 ng 95 71) n-Nonane 15.85 43 3139 0.112 ng 95 74) Cumene 16.21 105 23874 0.401 ng 96 75) alpha-Pinene 16.59 93 6297 0.221 ng # 1 82) 1,2,4-Trimethylbenzene 17.31 105 4708 0.096 ng 90 91) d-Limonene 17.85 68 5485 0.344 ng 98 95) Naphthalene 19.57 128 13131 0.216 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Tue Jun 21 17:08:40 2016 Page: 1

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widayati.ang

Wida Ang




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

2.2e+07

2.3e+07

2.4e+07

2.5e+07

2.6e+07

2.7e+07

2.8e+07

2.9e+07

3e+07

Time-->


Nap

htha

lene

,T

d-Li

mon

ene,

T

1,2,

4-Tr

imet

hylb

enze

ne,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene,

TTo

luen

e-d8

(SS2

),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Tetra

hydr

ofur

an (T

HF)

,T

Brom

ochl

orom

etha

ne (I

S1),I

R

2-Bu

tano

ne (M

EK),T

2-Pr

opan

ol (I

sopr

opan

ol),T

Acet

one,

T

Etha

nol,T

Viny

l Chl

orid

e,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,T

R8061516.M Tue Jun 21 17:08:41 2016 Page: 2

25 of 113

#3Dichlorodifluoromethane (CFC 12)Concen: 0.48 ng RT: 4.05 min Scan# 85Delta R.T. 0.055 minLab File: 06211613.DAcq: 21 Jun 2016 14:19

Tgt Ion: 85 Resp: 11994Ion Ratio Lower Upper 85 100 87 34.1 12.4 52.4 101 9.2 0.0 30.0 103 5.5 0.0 26.5

Ref

Raw

Sub

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->

Abundance Scan 74 (3.987 min): 06151636.D\data.ms (-65) (-)85

50 10135 6642 120

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->

Abundance Scan 85 (4.047 min): 06211613.D\data.ms29

44

8537 10166

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


4385

10166

3.95 4.00 4.05 4.100

1000

2000

3000

4000

Time-->

Abundance 4.047

#6Vinyl ChlorideConcen: 0.45 ng RT: 4.52 min Scan# 171Delta R.T. 0.033 minLab File: 06211613.DAcq: 21 Jun 2016 14:19

Tgt Ion: 62 Resp: 6715Ion Ratio Lower Upper 62 100 64 27.6 11.6 51.6

Ref

Raw

Sub

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


35 47 59 655031 38

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


32 44

35 41

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


29

4432

35 414.45 4.50 4.55 4.60

0

500

1000

1500

2000

2500

Time-->

Abundance 4.518

06211613.D R8061516.M Tue Jun 21 17:08:41 2016 Page 3

26 of 113

#10EthanolConcen: 4.93 ng RT: 5.37 min Scan# 329Delta R.T. -0.070 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 4733

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341

5.20 5.40 5.600

2000

4000

6000

8000

10000

Time-->

Abundance 5.374

#13AcetoneConcen: 1.30 ng RT: 5.86 min Scan# 420Delta R.T. -0.016 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


58

3937 41 6045 5254

30 35 40 45 50 55 60 650

50

m/z-->


58

394137

30 35 40 45 50 55 60 650

50

m/z-->


58

3937 41

5.80 5.90 6.000

5000

10000

15000

Time-->

Abundance

5.864

06211613.D R8061516.M Tue Jun 21 17:08:42 2016 Page 4

27 of 113

#152-Propanol (Isopropanol)Concen: 0.15 ng RT: 6.16 min Scan# 476Delta R.T. -0.022 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


41 593833 53

25 30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


8141

25 30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


8141

6.10 6.15 6.20 6.250

500

1000

1500

Time-->

Abundance 6.165

#272-Butanone (MEK)Concen: 0.25 ng RT: 8.27 min Scan# 867Delta R.T. 0.005 minLab File: 06211613.DAcq: 21 Jun 2016 14:19

Tgt Ion: 72 Resp: 1897Ion Ratio Lower Upper 72 100 43 562.2 418.5 458.5#

Ref

Raw

Sub

35 40 45 50 55 60 65 70 75 800

50

m/z-->


725753

35 40 45 50 55 60 65 70 75 800

50

m/z-->


7257

35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

57

8.20 8.25 8.300

1000

2000

3000

Time-->

Abundance

8.268

06211613.D R8061516.M Tue Jun 21 17:08:42 2016 Page 5

28 of 113

#34Tetrahydrofuran (THF)Concen: 0.11 ng RT: 9.29 min Scan# 1057Delta R.T. 0.016 minLab File: 06211613.DAcq: 21 Jun 2016 14:19

Tgt Ion: 72 Resp: 796Ion Ratio Lower Upper 72 100 71 109.4 74.0 114.0 42 393.0 243.0 283.0#

Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


7239

45 55 6836 49

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


7139

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


7139

9.25 9.300

500

1000

Time-->

Abundance

9.290

#58TolueneConcen: 0.30 ng RT: 12.87 min Scan# 1722Delta R.T. -0.005 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


6539 5145 8574

30 40 50 60 70 80 90 1000

50

m/z-->


6539 50 9877

30 40 50 60 70 80 90 1000

50

m/z-->


6539 50 9877

12.80 12.900

2000

4000

6000

Time-->

Abundance12.868

06211613.D R8061516.M Tue Jun 21 17:08:42 2016 Page 6

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#66EthylbenzeneConcen: 0.23 ng RT: 15.00 min Scan# 2118Delta R.T. -0.000 minLab File: 06211613.DAcq: 21 Jun 2016 14:19

Tgt Ion: 91 Resp: 12396Ion Ratio Lower Upper 91 100106 34.4 12.8 52.8

Ref

Raw

Sub

30 40 50 60 70 80 90 100 1100

50

m/z-->


106

51 776539 84 97

30 40 50 60 70 80 90 100 1100

50

m/z-->


106

6551 7739

30 40 50 60 70 80 90 100 1100

50

m/z-->


106

6551 7739

14.90 15.00 15.100

2000

4000

Time-->

Abundance14.998

#67m- & p-XylenesConcen: 0.33 ng RT: 15.16 min Scan# 2149Delta R.T. -0.022 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

30 40 50 60 70 80 90 100 1100

50

m/z-->


106

7739 51 65 84 97

30 40 50 60 70 80 90 100 1100

50

m/z-->


106

775139 65

30 40 50 60 70 80 90 100 1100

50

m/z-->


106

775139 65

15.10 15.15 15.20 15.250

1000

2000

3000

4000

5000

Time-->

Abundance15.165

06211613.D R8061516.M Tue Jun 21 17:08:43 2016 Page 7

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#70o-XyleneConcen: 0.17 ng RT: 15.64 min Scan# 2238Delta R.T. -0.005 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


106

775139 65 119129 166

40 60 80 100 120 140 1600

50

m/z-->


106

775139 61

40 60 80 100 120 140 1600

50

m/z-->


106

775139 61

15.60 15.65 15.700

1000

2000

3000

Time-->

Abundance15.644

#71n-NonaneConcen: 0.11 ng RT: 15.85 min Scan# 2276Delta R.T. -0.005 minLab File: 06211613.DAcq: 21 Jun 2016 14:19

Tgt Ion: 43 Resp: 3139Ion Ratio Lower Upper 43 100 57 82.8 62.1 102.1 85 24.8 12.7 52.7

Ref

Raw

Sub

30 40 50 60 70 80 90 1001101201301401501601700

50

m/z-->

Abundance Scan 2276 (15.848 min): 06151636.D\data.ms (-2261) (-)43 57

8571

99 128113 169

30 40 50 60 70 80 90 1001101201301401501601700

50

m/z-->


8571

30 40 50 60 70 80 90 1001101201301401501601700

50

m/z-->


8571

15.80 15.85 15.900

500

1000

1500

Time-->

Abundance15.848

06211613.D R8061516.M Tue Jun 21 17:08:43 2016 Page 8

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#74CumeneConcen: 0.40 ng RT: 16.21 min Scan# 2343Delta R.T. -0.011 minLab File: 06211613.DAcq: 21 Jun 2016 14:19

Tgt Ion:105 Resp: 23874Ion Ratio Lower Upper105 100120 26.4 8.4 48.4

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


1207751 9139 63 98 113

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


1207751 9139 65

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


1207751 9139 65

16.15 16.20 16.25 16.300

5000

10000

Time-->

Abundance16.208

#75alpha-PineneConcen: 0.22 ng RT: 16.59 min Scan# 2414Delta R.T. -0.005 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


7739 121105 1366753

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


77

1191053951 67 136

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


77

1191053951 67 136

16.55 16.60 16.650

1000

2000

3000

4000

Time-->

Abundance

16.590

06211613.D R8061516.M Tue Jun 21 17:08:43 2016 Page 9

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#821,2,4-TrimethylbenzeneConcen: 0.10 ng RT: 17.31 min Scan# 2548Delta R.T. -0.005 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


91

1347741 51 65

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


119

55 9141 7969 134

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


120

977955 6739 138

17.25 17.30 17.350

1000

2000

3000

Time-->

Abundance17.311

#91d-LimoneneConcen: 0.34 ng RT: 17.85 min Scan# 2649Delta R.T. -0.005 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 140 1500

50

m/z-->


93

79 11139 53 121 136

102

30 40 50 60 70 80 90 100 110 120 130 140 1500

50

m/z-->


93

41 7953121 136107

30 40 50 60 70 80 90 100 110 120 130 140 1500

50

m/z-->


93

53121 1367939 107

17.80 17.85 17.900

1000

2000

3000

Time-->

Abundance17.855

06211613.D R8061516.M Tue Jun 21 17:08:44 2016 Page 10

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#95NaphthaleneConcen: 0.22 ng RT: 19.57 min Scan# 2968Delta R.T. -0.000 minLab File: 06211613.DAcq: 21 Jun 2016 14:19


Ref

Raw

Sub

40 60 80 100 120 140 160 180 2000

50

m/z-->


1025743 75 87 114 140 170 207

40 60 80 100 120 140 160 180 2000

50

m/z-->


10257 20743 75

40 60 80 100 120 140 160 180 2000

50

m/z-->


10251 63 7739 207

19.50 19.55 19.60 19.650

2000

4000

6000

Time-->

Abundance19.571

06211613.D R8061516.M Tue Jun 21 17:08:44 2016 Page 11

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Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211615.D Acq On : 21 Jun 2016 15:30 Operator: WA Sample : P1603010-002 (200mL) Misc : S29-06151601 ALS Vial : 10 Sample Multiplier: 1 Quant Time: Jun 21 17:17:01 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.80 130 122169 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.54 114 552749 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 14.57 82 239859 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 201842 11.740 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 93.92% 57) Toluene-d8 (SS2) 12.77 98 578154 12.183 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.44% 73) Bromofluorobenzene (SS3) 16.07 174 230455 13.409 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 107.28% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. d 3) Dichlorodifluoromethan... 4.03 85 7136 0.281 ng # 90 4) Chloromethane 4.23 50 614 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 4.50 62 6355 0.419 ng 100 7) 1,3-Butadiene 0.00 54 0 N.D. d 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 5.37 45 18610 2.165 ng 92 11) Acetonitrile 5.64 41 1254 N.D. 12) Acrolein 0.00 56 0 N.D. d 13) Acetone 5.84 58 46306 4.867 ng # 1 14) Trichlorofluoromethane 6.04 101 3470 0.152 ng 99 15) 2-Propanol (Isopropanol) 0.00 45 0 N.D. d 16) Acrylonitrile 0.00 53 0 N.D. d 17) 1,1-Dichloroethene 6.67 96 59258 6.065 ng 92 18) 2-Methyl-2-Propanol (t... 0.00 59 0 N.D. d 19) Methylene Chloride 0.00 84 0 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. d 21) Trichlorotrifluoroethane 7.07 151 705 N.D. 22) Carbon Disulfide 0.00 76 0 N.D. d 23) trans-1,2-Dichloroethene 7.70 61 7808 0.489 ng 95 24) 1,1-Dichloroethane 7.88 63 25376 1.215 ng 96 25) Methyl tert-Butyl Ether 7.97 73 710 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. d 27) 2-Butanone (MEK) 8.26 72 3941 0.521 ng # 89 28) cis-1,2-Dichloroethene 8.65 61 136832 8.999 ng 95 29) Diisopropyl Ether 0.00 87 0 N.D. d 30) Ethyl Acetate 0.00 61 0 N.D. d 31) n-Hexane 8.87 57 381907 20.117 ng 99 32) Chloroform 8.91 83 40606 2.098 ng 94 34) Tetrahydrofuran (THF) 9.28 72 2746 0.377 ng # 83 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 9.61 62 1335 N.D. 38) 1,1,1-Trichloroethane 9.83 97 30617 1.670 ng 98 39) Isopropyl Acetate 0.00 61 0 N.D. d 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 10.24 78 99124 2.340 ng 100 42) Carbon Tetrachloride 10.37 117 547 N.D. 43) Cyclohexane 10.49 84 329675 18.549 ng 99 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 0.00 63 0 N.D. d 46) Bromodichloromethane 0.00 83 0 N.D. d 47) Trichloroethene 11.18 130 1900245 155.424 ng 99 48) 1,4-Dioxane 0.00 88 0 N.D. d 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D. d

R8061516.M Tue Jun 21 17:17:44 2016 Page: 1

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Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211615.D Acq On : 21 Jun 2016 15:30 Operator: WA Sample : P1603010-002 (200mL) Misc : S29-06151601 ALS Vial : 10 Sample Multiplier: 1 Quant Time: Jun 21 17:17:01 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. d 51) n-Heptane 11.46 71 62898 5.770 ng 99 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. d 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. d 58) Toluene 12.87 91 6308 0.139 ng 97 59) 2-Hexanone 0.00 43 0 N.D. d 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 13.70 43 1035 N.D. 63) n-Octane 13.80 57 9207 0.936 ng 97 64) Tetrachloroethene 13.95 166 506184 33.073 ng 99 65) Chlorobenzene 0.00 112 0 N.D. d 66) Ethylbenzene 15.00 91 15133 0.289 ng 96 67) m- & p-Xylenes 15.18 91 4097 0.098 ng 93 68) Bromoform 0.00 173 0 N.D. 69) Styrene 15.54 104 826 N.D. 70) o-Xylene 15.64 91 2247 N.D. 71) n-Nonane 0.00 43 0 N.D. d 72) 1,1,2,2-Tetrachloroethane 15.64 83 902 N.D. 74) Cumene 16.21 105 10583 0.185 ng 98 75) alpha-Pinene 0.00 93 0 N.D. d 76) n-Propylbenzene 16.70 91 37267 0.536 ng 91 77) 3-Ethyltoluene 16.79 105 1161 N.D. 78) 4-Ethyltoluene 16.85 105 1506 N.D. 79) 1,3,5-Trimethylbenzene 16.92 105 2389 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. d 81) 2-Ethyltoluene 17.10 105 4347 N.D. 82) 1,2,4-Trimethylbenzene 17.31 105 29292 0.623 ng 89 83) n-Decane 0.00 57 0 N.D. d 84) Benzyl Chloride 0.00 91 0 N.D. d 85) 1,3-Dichlorobenzene 0.00 146 0 N.D. 86) 1,4-Dichlorobenzene 0.00 146 0 N.D. 87) sec-Butylbenzene 0.00 105 0 N.D. d 88) 4-Isopropyltoluene (p-... 0.00 119 0 N.D. d 89) 1,2,3-Trimethylbenzene 0.00 105 0 N.D. d 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. d 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. d 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. d 95) Naphthalene 19.57 128 170191 2.917 ng # 46 96) n-Dodecane 0.00 57 0 N.D. d 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 0.00 119 0 N.D. d 100) n-Butylbenzene 0.00 91 0 N.D. d -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Tue Jun 21 17:17:44 2016 Page: 2

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

2.2e+07

2.3e+07

2.4e+07

2.5e+07

2.6e+07

Time-->


Nap

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lene

,T

1,2,

4-Tr

imet

hylb

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then

e,T

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tano

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hlor

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ns-1

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ichl

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then

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uoro

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(CFC

12)

,T

R8061516.M Tue Jun 21 17:17:44 2016 Page: 3

37 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211615.D Acq On : 21 Jun 2016 15:30 Operator: WA Sample : P1603010-002 (200mL) Misc : S29-06151601 ALS Vial : 10 Sample Multiplier: 1 Quant Time: Jun 21 17:17:01 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.80 130 122169 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.54 114 552749 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 14.57 82 239859 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 201842 11.740 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 93.92% 57) Toluene-d8 (SS2) 12.77 98 578154 12.183 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.44% 73) Bromofluorobenzene (SS3) 16.07 174 230455 13.409 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 107.28% Target Compounds Qvalue 3) Dichlorodifluoromethan... 4.03 85 7136 0.281 ng # 90 6) Vinyl Chloride 4.50 62 6355 0.419 ng 100 10) Ethanol 5.37 45 18610 2.165 ng 92 13) Acetone 5.84 58 46306 4.867 ng # 1 14) Trichlorofluoromethane 6.04 101 3470 0.152 ng 99 17) 1,1-Dichloroethene 6.67 96 59258 6.065 ng 92 23) trans-1,2-Dichloroethene 7.70 61 7808 0.489 ng 95 24) 1,1-Dichloroethane 7.88 63 25376 1.215 ng 96 27) 2-Butanone (MEK) 8.26 72 3941 0.521 ng # 89 28) cis-1,2-Dichloroethene 8.65 61 136832 8.999 ng 95 31) n-Hexane 8.87 57 381907 20.117 ng 99 32) Chloroform 8.91 83 40606 2.098 ng 94 34) Tetrahydrofuran (THF) 9.28 72 2746 0.377 ng # 83 38) 1,1,1-Trichloroethane 9.83 97 30617 1.670 ng 98 41) Benzene 10.24 78 99124 2.340 ng 100 43) Cyclohexane 10.49 84 329675 18.549 ng 99 47) Trichloroethene 11.18 130 1900245 155.424 ng 99 51) n-Heptane 11.46 71 62898 5.770 ng 99 58) Toluene 12.87 91 6308 0.139 ng 97 63) n-Octane 13.80 57 9207 0.936 ng 97 64) Tetrachloroethene 13.95 166 506184 33.073 ng 99 66) Ethylbenzene 15.00 91 15133 0.289 ng 96 67) m- & p-Xylenes 15.18 91 4097 0.098 ng 93 74) Cumene 16.21 105 10583 0.185 ng 98 76) n-Propylbenzene 16.70 91 37267 0.536 ng 91 82) 1,2,4-Trimethylbenzene 17.31 105 29292 0.623 ng 89 95) Naphthalene 19.57 128 170191 2.917 ng # 46 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

2.2e+07

2.3e+07

2.4e+07

2.5e+07

2.6e+07

Time-->


Nap

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,T

1,2,

4-Tr

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(CFC

12)

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R8061516.M Tue Jun 21 17:17:12 2016 Page: 2

39 of 113

#3Dichlorodifluoromethane (CFC 12)Concen: 0.28 ng RT: 4.03 min Scan# 82Delta R.T. 0.038 minLab File: 06211615.DAcq: 21 Jun 2016 15:30

Tgt Ion: 85 Resp: 7136Ion Ratio Lower Upper 85 100 87 30.5 12.4 52.4 101 0.0 0.0 30.0 103 0.0 0.0 26.5

Ref

Raw

Sub

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


50 10135 6642 120

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


44

8537 101

20 30 40 50 60 70 80 90 100 110 1200

50

m/z-->


43

85101

3.95 4.00 4.05 4.100

1000

2000

3000

Time-->

Abundance 4.031

#6Vinyl ChlorideConcen: 0.42 ng RT: 4.50 min Scan# 168Delta R.T. 0.016 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


35 47 59 655031 38

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->

Abundance Scan 168 (4.502 min): 06211615.D\data.ms6229 43

3239

47 57

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


4329

32 39 47 57

4.45 4.50 4.550

1000

2000

3000

Time-->

Abundance 4.502

06211615.D R8061516.M Tue Jun 21 17:17:12 2016 Page 3

40 of 113

#10EthanolConcen: 2.16 ng RT: 5.37 min Scan# 329Delta R.T. -0.070 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 4733

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341

24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341

5.20 5.30 5.40 5.50 5.600

1000

2000

3000

4000

5000

Time-->

Abundance 5.374

#13AcetoneConcen: 4.87 ng RT: 5.84 min Scan# 416Delta R.T. -0.038 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


58

36

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


58

6736 85 117

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


58

6736 85 1175.80 5.85

0

200000

400000

600000

800000

1000000

Time-->

Abundance

5.842

06211615.D R8061516.M Tue Jun 21 17:17:13 2016 Page 4

41 of 113

#14TrichlorofluoromethaneConcen: 0.15 ng RT: 6.04 min Scan# 452Delta R.T. 0.011 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


6635 47 82 11774

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


436658

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


436658

6.00 6.05 6.100

500

1000

1500

Time-->

Abundance 6.036

#171,1-DichloroetheneConcen: 6.06 ng RT: 6.67 min Scan# 570Delta R.T. -0.006 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 8270

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 8241

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 82

6.60 6.70 6.800

10000

20000

30000

40000

Time-->

Abundance

6.670

06211615.D R8061516.M Tue Jun 21 17:17:13 2016 Page 5

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#23trans-1,2-DichloroetheneConcen: 0.49 ng RT: 7.70 min Scan# 761Delta R.T. -0.016 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

4735

30 40 50 60 70 80 90 1000

50

m/z-->


96

4735

30 40 50 60 70 80 90 1000

50

m/z-->


96

4735

7.60 7.65 7.70 7.75 7.800

1000

2000

3000

Time-->

Abundance 7.698

#241,1-DichloroethaneConcen: 1.21 ng RT: 7.88 min Scan# 795Delta R.T. -0.027 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


83 9835 48 5741 73

30 40 50 60 70 80 90 1000

50

m/z-->


63

45 83 985735

30 40 50 60 70 80 90 1000

50

m/z-->


63

45 83 985735

7.80 7.90 8.000

2000

4000

6000

8000

10000

Time-->

Abundance 7.881

06211615.D R8061516.M Tue Jun 21 17:17:13 2016 Page 6

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#272-Butanone (MEK)Concen: 0.52 ng RT: 8.26 min Scan# 866Delta R.T. -0.000 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725753

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


725739

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

57

8.20 8.25 8.30 8.350

2000

4000

6000

Time-->

Abundance

8.263

#28cis-1,2-DichloroetheneConcen: 9.00 ng RT: 8.65 min Scan# 938Delta R.T. -0.027 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 70

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47 72

30 40 50 60 70 80 90 1000

50

m/z-->


96

35 47

8.60 8.70 8.800

20000

40000

60000

Time-->

Abundance 8.650

06211615.D R8061516.M Tue Jun 21 17:17:14 2016 Page 7

44 of 113

#31n-HexaneConcen: 20.12 ng RT: 8.87 min Scan# 979Delta R.T. -0.000 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


57

8770 102

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

867149 79 130

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


41

867150 12879

8.80 8.90 9.000

50000

100000

150000

Time-->

Abundance 8.871

#32ChloroformConcen: 2.10 ng RT: 8.91 min Scan# 987Delta R.T. -0.038 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


4735

120

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


4735 57 11872 130

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


4735 57 11870 130

8.85 8.90 8.95 9.000

5000

10000

15000

Time-->

Abundance 8.914

06211615.D R8061516.M Tue Jun 21 17:17:14 2016 Page 8

45 of 113

#34Tetrahydrofuran (THF)Concen: 0.38 ng RT: 9.28 min Scan# 1056Delta R.T. 0.011 minLab File: 06211615.DAcq: 21 Jun 2016 15:30

Tgt Ion: 72 Resp: 2746Ion Ratio Lower Upper 72 100 71 103.4 74.0 114.0 42 297.4 243.0 283.0#

Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


7239

45 55 6836 49

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


7239

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


7239

9.25 9.30 9.350

1000

2000

3000

Time-->

Abundance

9.285

#381,1,1-TrichloroethaneConcen: 1.67 ng RT: 9.83 min Scan# 1157Delta R.T. -0.011 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61

11735 8247 70

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61

4385 11935 69

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


61

1178535 47

9.75 9.80 9.85 9.900

5000

10000

Time-->

Abundance 9.828

06211615.D R8061516.M Tue Jun 21 17:17:15 2016 Page 9

46 of 113

#41BenzeneConcen: 2.34 ng RT: 10.24 min Scan# 1233Delta R.T. -0.011 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


5139 7463 7136 6048

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


5139 74635643

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


5139 7463564310.20 10.30

0

10000

20000

30000

40000

Time-->

Abundance10.237

#43CyclohexaneConcen: 18.55 ng RT: 10.49 min Scan# 1280Delta R.T. -0.011 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


41

69

50 7763

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


41

69

50 63 77 114

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


41

69

50 1146310.40 10.50 10.60

0

50000

100000

150000

Time-->

Abundance

10.490

06211615.D R8061516.M Tue Jun 21 17:17:15 2016 Page 10

47 of 113

#47TrichloroetheneConcen: 155.42 ng RT: 11.18 min Scan# 1408Delta R.T. -0.011 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

35 47 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

4735 8270

11.10 11.20 11.30 11.400

200000

400000

600000

800000

Time-->

Abundance11.178

#51n-HeptaneConcen: 5.77 ng RT: 11.46 min Scan# 1460Delta R.T. -0.000 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


7157

1008550 6337 77

30 40 50 60 70 80 90 1000

50

m/z-->


7157

1008550 6337

30 40 50 60 70 80 90 1000

50

m/z-->


7157

10085

11.40 11.45 11.500

10000

20000

30000

Time-->

Abundance11.458

06211615.D R8061516.M Tue Jun 21 17:17:15 2016 Page 11

48 of 113

#58TolueneConcen: 0.14 ng RT: 12.87 min Scan# 1722Delta R.T. -0.006 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


6539 5145 8574

30 40 50 60 70 80 90 1000

50

m/z-->


43

7157 85 986550

30 40 50 60 70 80 90 1000

50

m/z-->


43

7157 85 986550

12.80 12.85 12.90 12.950

1000

2000

3000

Time-->

Abundance12.868

#63n-OctaneConcen: 0.94 ng RT: 13.80 min Scan# 1895Delta R.T. -0.011 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


855771

11498 129 164

40 60 80 100 120 140 1600

50

m/z-->


855771

16612911496

40 60 80 100 120 140 1600

50

m/z-->


855771

16612911496

13.75 13.80 13.850

1000

2000

3000

4000

5000

Time-->

Abundance

13.798

06211615.D R8061516.M Tue Jun 21 17:17:16 2016 Page 12

49 of 113

#64TetrachloroetheneConcen: 33.07 ng RT: 13.95 min Scan# 1924Delta R.T. -0.000 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


129

9447 5935 82

11772

40 60 80 100 120 140 1600

50

m/z-->


129

9447 59 8235 11770

40 60 80 100 120 140 1600

50

m/z-->


129

9447 59 8235 11772

13.90 14.000

50000

100000

150000

200000

250000

Time-->

Abundance13.954

#66EthylbenzeneConcen: 0.29 ng RT: 15.00 min Scan# 2118Delta R.T. -0.000 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


106

51 776539 84 98

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


10655 7041 77 84 98 12663

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


106

51 7865 9844 126

14.90 15.000

2000

4000

6000

Time-->

Abundance14.998

06211615.D R8061516.M Tue Jun 21 17:17:16 2016 Page 13

50 of 113

#67m- & p-XylenesConcen: 0.10 ng RT: 15.18 min Scan# 2152Delta R.T. -0.006 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 1100

50

m/z-->


106

7739 51 65 84 97

30 40 50 60 70 80 90 100 1100

50

m/z-->


91578570

1069751 77

30 40 50 60 70 80 90 100 1100

50

m/z-->


91578571

1069751 77

15.10 15.15 15.20 15.250

500

1000

1500

Time-->

Abundance15.181

#74CumeneConcen: 0.19 ng RT: 16.21 min Scan# 2344Delta R.T. -0.006 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


1207751 9139 63

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


43

70 85 97 105 120 142

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


43

70 85 97 105 120 142

16.15 16.20 16.250

2000

4000

Time-->

Abundance16.214

06211615.D R8061516.M Tue Jun 21 17:17:16 2016 Page 14

51 of 113

#76n-PropylbenzeneConcen: 0.54 ng RT: 16.70 min Scan# 2435Delta R.T. -0.000 minLab File: 06211615.DAcq: 21 Jun 2016 15:30

Tgt Ion: 91 Resp: 37267Ion Ratio Lower Upper 91 100120 23.0 5.3 45.3 65 18.3 0.0 31.1

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


12065 785139 105

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


9141

11183 120 14099

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


11170

12055 78 10338

16.60 16.70 16.800

5000

10000

15000

20000

Time-->

Abundance16.703

#821,2,4-TrimethylbenzeneConcen: 0.62 ng RT: 17.31 min Scan# 2548Delta R.T. -0.006 minLab File: 06211615.DAcq: 21 Jun 2016 15:30


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


91

1347741 51 65

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


41 6983 140

111125 154

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


4169 83 140

112 125 15417.25 17.30 17.35

0

5000

10000

15000

Time-->

Abundance17.311

06211615.D R8061516.M Tue Jun 21 17:17:17 2016 Page 15

52 of 113

#95NaphthaleneConcen: 2.92 ng RT: 19.57 min Scan# 2968Delta R.T. -0.000 minLab File: 06211615.DAcq: 21 Jun 2016 15:30

Tgt Ion:128 Resp: 170191Ion Ratio Lower Upper128 100129 31.5 0.0 31.0#

Ref

Raw

Sub

40 60 80 100 120 140 160 180 2000

50

m/z-->


1025743 75 87 114 140 170 207

40 60 80 100 120 140 160 180 2000

50

m/z-->


12869 81 95

109 151 166

182 207

40 60 80 100 120 140 160 180 2000

50

m/z-->


551668167 95 15141 109

182

19.50 19.55 19.60 19.650

20000

40000

60000

80000

Time-->

Abundance19.571

06211615.D R8061516.M Tue Jun 21 17:17:17 2016 Page 16

53 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211616.D Acq On : 21 Jun 2016 16:03 Operator: WA Sample : P1603010-002dil (50mL) Misc : S29-06151601 ALS Vial : 10 Sample Multiplier: 1 Quant Time: Jun 21 17:20:27 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.80 130 116987 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.54 114 522407 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 14.57 82 230814 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 187383 11.382 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 91.04% 57) Toluene-d8 (SS2) 12.77 98 556241 12.180 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.44% 73) Bromofluorobenzene (SS3) 16.07 174 225365 13.627 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 109.04% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. d 3) Dichlorodifluoromethan... 4.01 85 1792 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 0.00 62 0 N.D. d 7) 1,3-Butadiene 0.00 54 0 N.D. d 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 5.40 45 4105 0.499 ng 93 11) Acetonitrile 0.00 41 0 N.D. 12) Acrolein 0.00 56 0 N.D. d 13) Acetone 0.00 58 0 N.D. d 14) Trichlorofluoromethane 6.02 101 722 N.D. 15) 2-Propanol (Isopropanol) 6.18 45 1099 N.D. 16) Acrylonitrile 0.00 53 0 N.D. d 17) 1,1-Dichloroethene 6.67 96 14172 1.515 ng 94 18) 2-Methyl-2-Propanol (t... 6.79 59 442 N.D. 19) Methylene Chloride 0.00 84 0 N.D. 20) 3-Chloro-1-propene (Al... 6.86 41 1095 N.D. 21) Trichlorotrifluoroethane 0.00 151 0 N.D. 22) Carbon Disulfide 7.07 76 3342 N.D. 23) trans-1,2-Dichloroethene 7.70 61 1622 0.106 ng 99 24) 1,1-Dichloroethane 7.88 63 5948 0.297 ng 95 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. d 27) 2-Butanone (MEK) 8.28 72 610 N.D. 28) cis-1,2-Dichloroethene 8.65 61 33340 2.290 ng 96 29) Diisopropyl Ether 0.00 87 0 N.D. d 30) Ethyl Acetate 0.00 61 0 N.D. d 31) n-Hexane 8.87 57 94098 5.176 ng 99 32) Chloroform 8.91 83 10061 0.543 ng 99 34) Tetrahydrofuran (THF) 9.31 72 573 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. 38) 1,1,1-Trichloroethane 9.82 97 7624 0.440 ng 98 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 10.23 78 26367 0.658 ng 100 42) Carbon Tetrachloride 0.00 117 0 N.D. 43) Cyclohexane 10.48 84 81214 4.835 ng 92 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 0.00 63 0 N.D. d 46) Bromodichloromethane 0.00 83 0 N.D. d 47) Trichloroethene 11.17 130 463125 40.080 ng 99 48) 1,4-Dioxane 0.00 88 0 N.D. d 49) 2,2,4-Trimethylpentane... 11.22 57 3725 N.D.

R8061516.M Tue Jun 21 17:20:59 2016 Page: 1

54 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211616.D Acq On : 21 Jun 2016 16:03 Operator: WA Sample : P1603010-002dil (50mL) Misc : S29-06151601 ALS Vial : 10 Sample Multiplier: 1 Quant Time: Jun 21 17:20:27 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. d 51) n-Heptane 11.45 71 15611 1.515 ng 99 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 12.51 97 748 N.D. 58) Toluene 12.87 91 1706 N.D. 59) 2-Hexanone 0.00 43 0 N.D. d 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 13.61 43 723 N.D. 63) n-Octane 13.80 57 2095 0.221 ng 97 64) Tetrachloroethene 13.95 166 125502 8.521 ng 99 65) Chlorobenzene 0.00 112 0 N.D. d 66) Ethylbenzene 15.00 91 3596 N.D. 67) m- & p-Xylenes 15.19 91 1165 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 0.00 104 0 N.D. 70) o-Xylene 15.65 91 550 N.D. 71) n-Nonane 15.84 43 981 N.D. 72) 1,1,2,2-Tetrachloroethane 15.65 83 563 N.D. 74) Cumene 16.21 105 2908 N.D. 75) alpha-Pinene 16.59 93 1029 N.D. 76) n-Propylbenzene 16.70 91 10928 0.163 ng 88 77) 3-Ethyltoluene 16.91 105 542 N.D. 78) 4-Ethyltoluene 16.91 105 542 N.D. 79) 1,3,5-Trimethylbenzene 16.91 105 542 N.D. 80) alpha-Methylstyrene 17.06 118 982 N.D. 81) 2-Ethyltoluene 17.10 105 1175 N.D. 82) 1,2,4-Trimethylbenzene 17.31 105 7388 0.163 ng 90 83) n-Decane 0.00 57 0 N.D. d 84) Benzyl Chloride 17.41 91 1199 N.D. 85) 1,3-Dichlorobenzene 0.00 146 0 N.D. 86) 1,4-Dichlorobenzene 0.00 146 0 N.D. 87) sec-Butylbenzene 0.00 105 0 N.D. d 88) 4-Isopropyltoluene (p-... 17.72 119 2704 N.D. 89) 1,2,3-Trimethylbenzene 17.72 105 3108 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. d 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. d 94) 1,2,4-Trichlorobenzene 19.46 180 1496 N.D. 95) Naphthalene 19.57 128 41150 0.733 ng # 39 96) n-Dodecane 0.00 57 0 N.D. d 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 17.31 119 2977 N.D. 100) n-Butylbenzene 0.00 91 0 N.D. d -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Tue Jun 21 17:20:59 2016 Page: 2

55 of 113


Data File: I:\MS08\Data\2016_06\21\06211616.D Acq On : 21 Jun 2016 16:03 Operator: WA Sample : P1603010-002dil (50mL) Misc : S29-06151601 ALS Vial : 10 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

Time-->


Nap

htha

lene

,T

1,2,

4-Tr

imet

hylb

enze

ne,T

n-Pr

opyl

benz

ene,

T

Brom

oflu

orob

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ne (S

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Tetra

chlo

roet

hene

,Tn-

Oct

ane,

T

Tolu

ene-

d8 (S

S2),S

n-H

epta

ne,T

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

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ene,

T

1,1,

1-Tr

ichl

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than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

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orof

orm

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

1,1-

Dic

hlor

oeth

ane,

Ttra

ns-1

,2-D

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then

e,T

1,1-

Dic

hlor

oeth

ene,

T

Etha

nol,T

R8061516.M Tue Jun 21 17:21:00 2016 Page: 3

56 of 113

Quantitation Report (Qedit)

Data File: I:\MS08\Data\2016_06\21\06211616.D Acq On : 21 Jun 2016 16:03 Operator: WA Sample : P1603010-002dil (50mL) Misc : S29-06151601 ALS Vial : 10 Sample Multiplier: 1


10.20 10.30 10.40 10.50 10.60 10.70 10.80 10.90 11.00 11.10 11.20 11.30 11.40 11.50 11.60 11.70 11.80 11.90 12.00 12.10 12.20

0

50000

100000

150000

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350000

Time-->

Abundance Ion 129.90 (129.60 to 130.60): 06211616.D\data.ms

11.173

||

|

|

|

|

|

| |||||

|

Ion 131.90 (131.60 to 132.60): 06211616.D\data.ms

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145

100000

200000

m/z-->


60134

47 9935 826550 70 85554138 8874 137

25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145

5000

m/z-->


60134

35 9947 8882655743 705038 74

TIC: 06211616.D\data.ms

0.00 0.00 0.00

0.00 0.00 0.00

131.90 97.60 96.90

129.90 100 100

Ion Exp% Act%

response 463125

11.173min (-0.016) 40.08ng

(47) Trichloroethene (T)

R8061516.M Tue Jun 21 17:20:47 2016 Page: 1

57 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211605.D Acq On : 21 Jun 2016 9:20 Operator: WA Sample : MB R8062116_1000mL Misc : S29-06151601_AS00703 ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jun 21 09:59:46 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.79 130 119667 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.53 114 572010 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 14.57 82 233457 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 195776 11.626 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 93.04% 57) Toluene-d8 (SS2) 12.77 98 589137 12.755 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.00% 73) Bromofluorobenzene (SS3) 16.07 174 221806 13.260 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 106.08% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. 3) Dichlorodifluoromethan... 0.00 85 0 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 0.00 62 0 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 5.41 45 1020 0.121 ng 89 11) Acetonitrile 5.67 41 341 N.D. 12) Acrolein 0.00 56 0 N.D. 13) Acetone 5.91 58 592 N.D. 14) Trichlorofluoromethane 0.00 101 0 N.D. 15) 2-Propanol (Isopropanol) 6.20 45 50 N.D. 16) Acrylonitrile 0.00 53 0 N.D. 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 0.00 59 0 N.D. 19) Methylene Chloride 0.00 84 0 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 0.00 151 0 N.D. 22) Carbon Disulfide 7.09 76 3250 N.D. 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. 24) 1,1-Dichloroethane 0.00 63 0 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 0.00 61 0 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 0.00 57 0 N.D. 32) Chloroform 0.00 83 0 N.D. 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 0.00 56 0 N.D. 41) Benzene 10.23 78 787 N.D. 42) Carbon Tetrachloride 0.00 117 0 N.D. 43) Cyclohexane 0.00 84 0 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 0.00 63 0 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. 47) Trichloroethene 0.00 130 0 N.D. 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D.

R8061516.M Tue Jun 21 11:09:02 2016 Page: 1

58 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211605.D Acq On : 21 Jun 2016 9:20 Operator: WA Sample : MB R8062116_1000mL Misc : S29-06151601_AS00703 ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jun 21 09:59:46 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 0.00 71 0 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 0.00 91 0 N.D. 59) 2-Hexanone 0.00 43 0 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 0.00 43 0 N.D. 63) n-Octane 0.00 57 0 N.D. 64) Tetrachloroethene 0.00 166 0 N.D. 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 0.00 91 0 N.D. 67) m- & p-Xylenes 0.00 91 0 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 0.00 104 0 N.D. 70) o-Xylene 0.00 91 0 N.D. 71) n-Nonane 0.00 43 0 N.D. 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 0.00 105 0 N.D. 75) alpha-Pinene 0.00 93 0 N.D. 76) n-Propylbenzene 0.00 91 0 N.D. 77) 3-Ethyltoluene 16.87 105 592 N.D. 78) 4-Ethyltoluene 16.87 105 592 N.D. 79) 1,3,5-Trimethylbenzene 16.87 105 592 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. 81) 2-Ethyltoluene 0.00 105 0 N.D. 82) 1,2,4-Trimethylbenzene 0.00 105 0 N.D. 83) n-Decane 0.00 57 0 N.D. 84) Benzyl Chloride 0.00 91 0 N.D. 85) 1,3-Dichlorobenzene 0.00 146 0 N.D. 86) 1,4-Dichlorobenzene 0.00 146 0 N.D. 87) sec-Butylbenzene 0.00 105 0 N.D. 88) 4-Isopropyltoluene (p-... 0.00 119 0 N.D. 89) 1,2,3-Trimethylbenzene 0.00 105 0 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 19.60 128 2207 N.D. 96) n-Dodecane 0.00 57 0 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. 99) tert-Butylbenzene 0.00 119 0 N.D. 100) n-Butylbenzene 0.00 91 0 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Tue Jun 21 11:09:02 2016 Page: 2

59 of 113


Data File: I:\MS08\Data\2016_06\21\06211605.D Acq On : 21 Jun 2016 9:20 Operator: WA Sample : MB R8062116_1000mL Misc : S29-06151601_AS00703 ALS Vial : 1 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

enze

ne-d

5 (IS

3),IR

Tolu

ene-

d8 (S

S2),S

1,4-

Difl

uoro

benz

ene

(IS2)

,IR

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Brom

ochl

orom

etha

ne (I

S1),I

R

Etha

nol,T

R8061516.M Tue Jun 21 11:09:02 2016 Page: 3

60 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211606.D Acq On : 21 Jun 2016 9:52 Operator: WA Sample : LCS R8062116_25ng Misc : S29-06151601/S29-06131603 (7/11) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jun 21 11:09:51 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.81 130 123341 12.500 ng -0.01 37) 1,4-Difluorobenzene (IS2) 10.54 114 563067 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 244725 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.49 65 203814 11.742 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 93.92% 57) Toluene-d8 (SS2) 12.77 98 595352 12.296 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.40% 73) Bromofluorobenzene (SS3) 16.07 174 229285 13.076 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 104.64% Target Compounds Qvalue 2) Propene 3.88 42 310063 21.305 ng 99 3) Dichlorodifluoromethan... 3.99 85 530855 20.724 ng 100 4) Chloromethane 4.19 50 362235 26.363 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.35 135 271049 23.451 ng 100 6) Vinyl Chloride 4.47 62 365991 23.885 ng 99 7) 1,3-Butadiene 4.65 54 297012 26.212 ng 97 8) Bromomethane 4.96 94 243478 28.101 ng 97 9) Chloroethane 5.17 64 220828 24.691 ng 99 10) Ethanol 5.40 45 1060300 122.162 ng 99 11) Acetonitrile 5.59 41 563596 25.256 ng 99 12) Acrolein 5.71 56 166797 24.160 ng 99 13) Acetone 5.85 58 1069994 111.400 ng 90 14) Trichlorofluoromethane 6.01 101 496508 21.591 ng 100 15) 2-Propanol (Isopropanol) 6.15 45 1580003 53.163 ng 98 16) Acrylonitrile 6.35 53 383491 26.138 ng 99 17) 1,1-Dichloroethene 6.67 96 270673 27.440 ng 92 18) 2-Methyl-2-Propanol (t... 6.75 59 1591799 52.636 ng 98 19) Methylene Chloride 6.81 84 268100 28.517 ng 96 20) 3-Chloro-1-propene (Al... 6.91 41 473122 27.333 ng 98 21) Trichlorotrifluoroethane 7.07 151 266763 26.217 ng 98 22) Carbon Disulfide 7.05 76 931260 20.906 ng 99 23) trans-1,2-Dichloroethene 7.70 61 420323 26.086 ng 97 24) 1,1-Dichloroethane 7.90 63 515770 24.453 ng 100 25) Methyl tert-Butyl Ether 7.94 73 921386 24.786 ng 100 26) Vinyl Acetate 8.04 86 399042 132.611 ng # 86 27) 2-Butanone (MEK) 8.25 72 196324 25.693 ng 93 28) cis-1,2-Dichloroethene 8.66 61 409912 26.702 ng 98 29) Diisopropyl Ether 8.85 87 244653 24.981 ng # 92 30) Ethyl Acetate 8.85 61 193932 51.120 ng 100 31) n-Hexane 8.87 57 426449 22.250 ng 98 32) Chloroform 8.93 83 494156 25.285 ng 99 34) Tetrahydrofuran (THF) 9.26 72 194958 26.499 ng 95 35) Ethyl tert-Butyl Ether 9.33 87 377480 25.121 ng 97 36) 1,2-Dichloroethane 9.59 62 411555 24.215 ng 100 38) 1,1,1-Trichloroethane 9.83 97 461463 24.707 ng 99 39) Isopropyl Acetate 10.13 61 336281 56.081 ng # 92 40) 1-Butanol 10.14 56 654079 60.751 ng 96 41) Benzene 10.24 78 1033923 23.956 ng 100 42) Carbon Tetrachloride 10.37 117 413122 26.335 ng 99 43) Cyclohexane 10.49 84 891417 49.237 ng 99 44) tert-Amyl Methyl Ether 10.76 73 862878 25.513 ng 98 45) 1,2-Dichloropropane 10.97 63 277161 25.733 ng 98 46) Bromodichloromethane 11.13 83 395616 26.640 ng 100 47) Trichloroethene 11.18 130 312187 25.066 ng 98 48) 1,4-Dioxane 11.15 88 237641 27.178 ng 98 49) 2,2,4-Trimethylpentane... 11.23 57 1250336 24.409 ng 97

R8061516.M Tue Jun 21 11:10:05 2016 Page: 1

61 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211606.D Acq On : 21 Jun 2016 9:52 Operator: WA Sample : LCS R8062116_25ng Misc : S29-06151601/S29-06131603 (7/11) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jun 21 11:09:51 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.33 100 247349 52.830 ng 97 51) n-Heptane 11.45 71 270783 24.387 ng 100 52) cis-1,3-Dichloropropene 11.95 75 442303 26.656 ng 100 53) 4-Methyl-2-pentanone 11.97 58 279989 27.555 ng 95 54) trans-1,3-Dichloropropene 12.42 75 432989 26.667 ng 100 55) 1,1,2-Trichloroethane 12.59 97 264875 26.988 ng 99 58) Toluene 12.87 91 1122113 24.317 ng 99 59) 2-Hexanone 13.08 43 731248 26.885 ng 98 60) Dibromochloromethane 13.26 129 340731 28.811 ng 99 61) 1,2-Dibromoethane 13.50 107 313911 25.906 ng 98 62) n-Butyl Acetate 13.67 43 817948 27.520 ng 99 63) n-Octane 13.80 57 243776 24.302 ng 98 64) Tetrachloroethene 13.95 166 357178 22.873 ng 99 65) Chlorobenzene 14.62 112 786783 25.142 ng 100 66) Ethylbenzene 14.99 91 1339165 25.038 ng 100 67) m- & p-Xylenes 15.18 91 2095098 48.872 ng 100 68) Bromoform 15.25 173 319308 26.468 ng 100 69) Styrene 15.53 104 853471 28.589 ng 99 70) o-Xylene 15.64 91 1075735 23.930 ng 100 71) n-Nonane 15.85 43 628776 22.874 ng 98 72) 1,1,2,2-Tetrachloroethane 15.61 83 480945 25.571 ng 100 74) Cumene 16.21 105 1395178 23.926 ng 100 75) alpha-Pinene 16.59 93 714786 25.629 ng 96 76) n-Propylbenzene 16.70 91 1618499 22.798 ng 99 77) 3-Ethyltoluene 16.80 105 1429603 25.307 ng 100 78) 4-Ethyltoluene 16.84 105 1317211 23.969 ng 100 79) 1,3,5-Trimethylbenzene 16.91 105 1171904 24.012 ng 99 80) alpha-Methylstyrene 17.06 118 640945 27.512 ng 99 81) 2-Ethyltoluene 17.10 105 1330364 24.180 ng 100 82) 1,2,4-Trimethylbenzene 17.31 105 1208724 25.209 ng 100 83) n-Decane 17.41 57 624847 23.360 ng 99 84) Benzyl Chloride 17.43 91 1088864 27.913 ng 100 85) 1,3-Dichlorobenzene 17.45 146 720160 26.697 ng 100 86) 1,4-Dichlorobenzene 17.52 146 715706 25.393 ng 100 87) sec-Butylbenzene 17.57 105 1523794 24.537 ng 100 88) 4-Isopropyltoluene (p-... 17.72 119 1507882 24.418 ng 99 89) 1,2,3-Trimethylbenzene 17.71 105 1245617 24.790 ng 99 90) 1,2-Dichlorobenzene 17.84 146 687424 25.806 ng 99 91) d-Limonene 17.85 68 447600 28.674 ng 100 92) 1,2-Dibromo-3-Chloropr... 18.26 157 276420 25.942 ng 94 93) n-Undecane 18.61 57 657097 24.128 ng 100 94) 1,2,4-Trichlorobenzene 19.46 180 598847 27.831 ng 99 95) Naphthalene 19.57 128 1690889 28.402 ng 99 96) n-Dodecane 19.58 57 676871 27.090 ng 99 97) Hexachlorobutadiene 19.90 225 401918 25.877 ng 99 98) Cyclohexanone 15.32 55 430054 27.664 ng 98 99) tert-Butylbenzene 17.31 119 1215531 24.576 ng 100 100) n-Butylbenzene 18.12 91 1218291 25.744 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Tue Jun 21 11:10:05 2016 Page: 2

62 of 113


Data File: I:\MS08\Data\2016_06\21\06211606.D Acq On : 21 Jun 2016 9:52 Operator: WA Sample : LCS R8062116_25ng Misc : S29-06151601/S29-06131603 (7/11) ALS Vial : 1 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

4600000

4800000

5000000

5200000

Time-->


Hex

achl

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Response Factor Report Instrument #MS08

Method Path : I:\MS08\Methods\ Method File : R8061516.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Jun 16 07:00:20 2016 Response Via : Initial Calibration

Calibration Files 0.08=06151630.D 0.10=06151631.D 0.20=06151632.D 0.40=06151633.D 1.0 =06151634.D 5.0 =06151635.D 25 =06151636.D 50 =06151637.D 100 =06151638.D

Compound 0.08 0.10 0.20 0.40 1.0 5.0 25 50 100 Avg %RSD --------------------------------------------------------------------------------------------

1) IR Bromochloromethane... ----------------ISTD--------------------- 2) T Propene 1.499 1.499 1.344 1.397 1.516 1.396 1.422 1.454 1.747 1.475 7.94 3) T Dichlorodifluo... 2.674 2.525 2.565 2.575 2.906 2.674 2.652 2.480 2.313 2.596 6.26 4) T Chloromethane 1.100 1.282 1.420 1.468 1.886 1.632 1.472 1.346 0.928 1.392 20.13 5) T 1,2-Dichloro-1... 1.105 1.051 1.126 1.113 1.296 1.155 1.161 1.275 1.260 1.171 7.34 6) T Vinyl Chloride 1.313 1.353 1.643 1.586 1.611 1.681 1.683 1.553 9.96 7) T 1,3-Butadiene 0.782 0.981 1.077 1.075 1.228 1.146 1.372 1.333 1.342 1.148 16.90 8) T Bromomethane 0.553 0.710 0.741 0.828 1.004 0.949 1.055 1.053 1.011 0.878 20.35 9) T Chloroethane 0.773 0.829 0.999 0.934 0.955 0.942 0.913 0.906 8.61 10) T Ethanol 0.675 0.828 0.817 0.900 1.034 0.929 0.947 0.923 0.865 0.880 11.50 11) T Acetonitrile 1.767 1.861 2.068 2.326 2.611 2.454 2.478 2.453 2.335 2.262 13.02 12) T Acrolein 0.587 0.675 0.782 0.744 0.720 0.713 0.677 0.700 8.90 13) T Acetone 1.077 1.135 1.078 1.074 1.008 0.907 0.872 0.834 0.776 0.973 13.21 14) T Trichlorofluor... 2.225 2.402 2.379 2.379 2.502 2.355 2.331 2.240 2.162 2.331 4.49 15) T 2-Propanol (Is... 2.462 2.852 3.025 3.130 3.673 3.400 3.379 3.040 2.146 3.012 15.82 16) T Acrylonitrile 1.155 1.248 1.628 1.569 1.652 1.606 1.551 1.487 13.43 17) T 1,1-Dichloroet... 0.767 0.932 0.909 0.969 1.165 1.056 1.085 1.074 1.040 1.000 11.89 18) T 2-Methyl-2-Pro... 2.832 2.974 3.144 3.164 3.683 3.392 3.303 2.992 2.099 3.065 14.42 19) T Methylene Chlo... 0.743 0.636 0.914 0.919 1.161 1.048 1.073 1.057 1.024 0.953 17.80 20) T 3-Chloro-1-pro... 1.411 1.572 1.779 1.789 1.966 1.931 1.832 1.754 11.28 21) T Trichlorotrifl... 0.939 0.955 1.060 1.003 1.137 1.047 1.057 1.052 1.030 1.031 5.80 22) T Carbon Disulfide 5.017 4.626 4.746 4.354 4.388 4.318 4.153 4.515 6.58 23) T trans-1,2-Dich... 1.173 1.293 1.623 1.636 1.917 1.768 1.831 1.770 1.686 1.633 15.11 24) T 1,1-Dichloroet... 2.007 1.952 2.157 2.112 2.397 2.188 2.205 2.170 2.051 2.138 6.09 25) T Methyl tert-Bu... 3.437 3.587 3.680 3.730 4.297 3.836 3.915 3.811 3.614 3.767 6.52 26) T Vinyl Acetate 0.219 0.275 0.310 0.318 0.333 0.345 0.335 0.305 14.55 27) T 2-Butanone (MEK) 0.664 0.761 0.834 0.798 0.790 0.802 0.771 0.774 6.96 28) T cis-1,2-Dichlo... 1.354 1.181 1.490 1.625 1.745 1.671 1.709 1.660 1.569 1.556 11.90 29) T Diisopropyl Ether 0.950 0.866 0.977 1.033 1.143 0.993 1.001 1.009 0.962 0.993 7.45 30) T Ethyl Acetate 0.333 0.340 0.423 0.396 0.407 0.410 0.382 0.384 9.16 31) T n-Hexane 1.883 1.979 2.085 2.038 2.196 1.926 1.797 1.861 1.716 1.942 7.69 32) T Chloroform 1.872 1.851 1.935 1.995 2.213 2.020 2.045 1.987 1.908 1.981 5.52 33) S 1,2-Dichloroet... 1.722 1.760 1.766 1.787 1.797 1.849 1.785 1.729 1.637 1.759 3.37 34) T Tetrahydrofura... 0.628 0.676 0.815 0.778 0.781 0.787 0.753 0.746 9.09 35) T Ethyl tert-But... 1.245 1.579 1.392 1.567 1.727 1.566 1.578 1.555 1.497 1.523 8.92 36) T 1,2-Dichloroet... 1.523 1.591 1.664 1.728 1.976 1.826 1.822 1.744 1.629 1.722 8.07

37) IR 1,4-Difluorobenzen... ----------------ISTD---------------------38) T 1,1,1-Trichlor... 0.365 0.408 0.389 0.411 0.467 0.428 0.442 0.418 0.403 0.415 7.13 39) T Isopropyl Acetate 0.084 0.117 0.130 0.136 0.162 0.143 0.146 0.143 0.137 0.133 16.42 40) T 1-Butanol 0.155 0.186 0.251 0.269 0.279 0.272 0.260 0.239 20.22 41) T Benzene 1.143 1.149 0.995 0.893 0.995 0.869 0.865 0.869 0.844 0.958 12.51 42) T Carbon Tetrach... 0.294 0.305 0.347 0.333 0.387 0.359 0.382 0.369 0.357 0.348 9.26

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Method Path : I:\MS08\Methods\ Method File : R8061516.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS)43) T Cyclohexane 0.378 0.395 0.403 0.404 0.449 0.399 0.407 0.397 0.385 0.402 5.00 44) T tert-Amyl Meth... 0.681 0.669 0.726 0.749 0.842 0.774 0.804 0.775 0.738 0.751 7.39 45) T 1,2-Dichloropr... 0.215 0.209 0.237 0.241 0.276 0.243 0.247 0.245 0.238 0.239 8.13 46) T Bromodichlorom... 0.250 0.306 0.306 0.315 0.375 0.346 0.367 0.356 0.346 0.330 11.99 47) T Trichloroethene 0.269 0.241 0.283 0.264 0.301 0.274 0.284 0.286 0.285 0.276 6.22 48) T 1,4-Dioxane 0.182 0.171 0.214 0.196 0.201 0.199 0.196 0.194 7.20 49) T 2,2,4-Trimethy... 1.078 1.117 1.149 1.125 1.272 1.140 1.173 1.120 1.061 1.137 5.35 50) T Methyl Methacr... 0.083 0.087 0.111 0.108 0.112 0.114 0.112 0.104 12.49 51) T n-Heptane 0.212 0.237 0.257 0.258 0.284 0.242 0.243 0.247 0.238 0.247 7.96 52) T cis-1,3-Dichlo... 0.252 0.291 0.346 0.344 0.431 0.401 0.425 0.419 0.407 0.368 17.45 53) T 4-Methyl-2-pen... 0.177 0.199 0.247 0.237 0.248 0.242 0.230 0.226 12.05 54) T trans-1,3-Dich... 0.260 0.294 0.381 0.378 0.417 0.403 0.390 0.360 16.42 55) T 1,1,2-Trichlor... 0.175 0.162 0.222 0.205 0.258 0.229 0.244 0.236 0.231 0.218 14.54

56) IR Chlorobenzene-d5 (... ----------------ISTD---------------------57) S Toluene-d8 (SS2) 2.498 2.503 2.481 2.488 2.444 2.455 2.453 2.447 2.488 2.473 0.94 58) T Toluene 2.219 2.365 2.440 2.409 2.506 2.291 2.358 2.306 2.321 2.357 3.65 59) T 2-Hexanone 1.120 1.266 1.537 1.490 1.508 1.434 1.371 1.389 10.83 60) T Dibromochlorom... 0.420 0.492 0.536 0.564 0.673 0.647 0.707 0.693 0.705 0.604 17.38 61) T 1,2-Dibromoethane 0.551 0.581 0.650 0.620 0.651 0.636 0.643 0.619 6.22 62) T n-Butyl Acetate 1.150 1.335 1.682 1.659 1.679 1.593 1.529 1.518 13.39 63) T n-Octane 0.395 0.508 0.500 0.501 0.580 0.526 0.544 0.534 0.524 0.512 9.90 64) T Tetrachloroethene 0.807 0.755 0.816 0.804 0.836 0.768 0.795 0.790 0.808 0.798 3.06 65) T Chlorobenzene 1.553 1.465 1.624 1.596 1.731 1.564 1.637 1.604 1.611 1.598 4.48 66) T Ethylbenzene 2.780 2.424 2.629 2.753 2.972 2.724 2.847 2.744 2.714 2.732 5.48 67) T m- & p-Xylenes 2.215 2.043 2.217 2.112 2.351 2.171 2.236 2.189 2.172 2.190 3.89 68) T Bromoform 0.475 0.504 0.624 0.632 0.695 0.684 0.699 0.616 14.91 69) T Styrene 1.166 1.309 1.366 1.431 1.701 1.638 1.740 1.685 1.689 1.525 13.76 70) T o-Xylene 2.152 2.257 2.224 2.309 2.522 2.288 2.368 2.270 2.275 2.296 4.50 71) T n-Nonane 1.369 1.311 1.417 1.393 1.573 1.431 1.469 1.374 1.299 1.404 5.94 72) T 1,1,2,2-Tetrac... 0.717 0.841 0.880 0.981 1.077 1.028 1.072 1.024 1.026 0.961 12.71 73) S Bromofluoroben... 0.913 0.900 0.889 0.903 0.886 0.902 0.904 0.879 0.884 0.896 1.25 74) T Cumene 2.751 2.834 2.841 2.928 3.276 3.044 3.156 3.002 2.975 2.978 5.56 75) T alpha-Pinene 1.347 1.225 1.406 1.328 1.530 1.484 1.550 1.486 1.465 1.425 7.50 76) T n-Propylbenzene 3.978 3.404 3.496 3.541 3.929 3.642 3.714 3.530 3.401 3.626 5.82 77) T 3-Ethyltoluene 2.661 2.613 2.669 2.913 3.267 2.890 3.148 2.905 2.900 2.885 7.63 78) T 4-Ethyltoluene 2.667 2.774 2.855 2.786 2.930 2.862 2.867 2.814 2.709 2.807 2.95 79) T 1,3,5-Trimethy... 2.556 2.520 2.387 2.389 2.685 2.488 2.559 2.446 2.408 2.493 3.95 80) T alpha-Methylst... 0.990 1.030 1.245 1.207 1.325 1.269 1.263 1.190 10.77 81) T 2-Ethyltoluene 2.680 2.586 2.725 2.824 3.163 2.837 2.945 2.796 2.738 2.810 5.95 82) T 1,2,4-Trimethy... 2.160 2.236 2.391 2.329 2.717 2.494 2.645 2.535 2.534 2.449 7.55 83) T n-Decane 1.257 1.282 1.322 1.384 1.531 1.444 1.454 1.349 1.274 1.366 6.89 84) T Benzyl Chloride 1.477 1.883 2.020 2.270 2.169 2.135 1.992 14.31 85) T 1,3-Dichlorobe... 1.229 1.133 1.365 1.353 1.512 1.425 1.500 1.429 1.456 1.378 9.13 86) T 1,4-Dichlorobe... 1.220 1.369 1.354 1.426 1.601 1.464 1.568 1.486 1.469 1.440 8.03 87) T sec-Butylbenzene 3.021 2.886 3.084 3.222 3.538 3.258 3.358 3.141 3.039 3.172 6.20 88) T 4-Isopropyltol... 2.810 2.806 2.969 2.991 3.513 3.301 3.432 3.269 3.297 3.154 8.40 89) T 1,2,3-Trimethy... 2.250 2.361 2.543 2.498 2.815 2.641 2.772 2.605 2.613 2.566 7.04 90) T 1,2-Dichlorobe... 1.101 1.271 1.353 1.374 1.494 1.387 1.456 1.390 1.419 1.361 8.52 91) T d-Limonene 0.593 0.575 0.684 0.746 0.937 0.902 0.971 0.905 0.863 0.797 18.99 92) T 1,2-Dibromo-3-... 0.460 0.544 0.555 0.593 0.559 0.553 0.544 8.18 93) T n-Undecane 1.226 1.184 1.322 1.409 1.587 1.521 1.544 1.403 1.323 1.391 10.13 94) T 1,2,4-Trichlor... 0.839 0.993 0.984 1.028 1.184 1.178 1.282 1.195 1.210 1.099 13.11

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Method Path : I:\MS08\Methods\ Method File : R8061516.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS)95) T Naphthalene 2.292 2.325 2.633 2.898 3.269 3.280 3.722 3.493 3.457 3.041 17.29 96) T n-Dodecane 0.962 1.042 1.166 1.305 1.515 1.483 1.462 1.320 1.231 1.276 15.31 97) T Hexachlorobuta... 0.687 0.720 0.723 0.791 0.854 0.833 0.871 0.826 0.835 0.793 8.40 98) T Cyclohexanone 0.609 0.745 0.886 0.868 0.849 0.811 0.789 0.794 11.94 99) T tert-Butylbenzene 2.269 2.495 2.501 2.393 2.703 2.545 2.672 2.561 2.598 2.526 5.32

100) T n-Butylbenzene 2.028 2.166 2.429 2.440 2.708 2.563 2.642 2.438 2.341 2.417 8.99 ----------------------------------------------------------------------------(#) = Out of Range

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1ng/L Std. ID:

4ng/L Std. ID: S29-05241612

20ng/L Std. ID: S29-05241610

200ng/L Std. ID: S29-05241606

Dilution Factors: 5 50 250 1000 4 4 4 4 20 200 200 200 200

Source Std. Injection (L): 0.020 0.025 0.050 0.100 0.050 0.025 0.125 0.25 0.50

Compounds mg/m3

200ng/L 20ng/L 4ng/L 1ng/L ICAL Points: 0.08ng 0.1ng 0.2ng 0.4ng 1ng 5ng 25ng 50ng 100ng

Propene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Dichlorodifluoromethane 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100Chloromethane 0.98 196 19.6 3.92 0.98 0.0784 0.098 0.196 0.392 0.98 4.90 24.50 49.0 98Freon-114 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Vinyl Chloride 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 1001,3-Butadiene 1.06 212 21.2 4.24 1.06 0.0848 0.106 0.212 0.424 1.06 5.30 26.50 53.0 106Bromomethane 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100Chloroethane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 101Ethanol 5.06 1012 101.2 20.24 5.06 0.4048 0.506 1.012 2.024 5.06 25.30 126.50 253.0 506Acetonitrile 1.02 204 20.4 4.08 1.02 0.0816 0.102 0.204 0.408 1.02 5.10 25.50 51.0 102Acrolein 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Acetone 5.37 1074 107.4 21.48 5.37 0.4296 0.537 1.074 2.148 5.37 26.85 134.25 268.5 537Trichlorofluoromethane 0.99 198 19.8 3.96 0.99 0.0792 0.099 0.198 0.396 0.99 4.95 24.75 49.5 99Isopropanol 2.09 418 41.8 8.36 2.09 0.1672 0.209 0.418 0.836 2.09 10.45 52.25 104.5 209Acrylonitrile 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 1031,1-Dichloroethene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107tert-Butanol 2.09 418 41.8 8.36 2.09 0.1672 0.209 0.418 0.836 2.09 10.45 52.25 104.5 209Methylene Chloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Allyl Chloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Trichlorotrifluoroethane 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Carbon Disulfide 0.98 196 19.6 3.92 0.98 0.0784 0.098 0.196 0.392 0.98 4.90 24.50 49.0 98trans-1,2-Dichloroethene 1.06 212 21.2 4.24 1.06 0.0848 0.106 0.212 0.424 1.06 5.30 26.50 53.0 1061,1-Dichloroethane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Methyl tert-Butyl Ether 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105Vinyl Acetate 5.07 1014 101.4 20.28 5.07 0.4056 0.507 1.014 2.028 5.07 25.35 126.75 253.5 5072-Butanone 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107cis-1,2-Dichloroethene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Diisopropyl Ether 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Ethyl Acetate 2.12 424 42.4 8.48 2.12 0.1696 0.212 0.424 0.848 2.12 10.60 53.00 106.0 212n-Hexane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Chloroform 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Tetrahydrofuran 1.02 204 20.4 4.08 1.02 0.0816 0.102 0.204 0.408 1.02 5.10 25.50 51.0 102Ethyl tert-Butyl Ether 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1051,2-Dichloroethane 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1051,1,1-Trichloroethane 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Isopropyl Acetate 2.21 442 44.2 8.84 2.21 0.1768 0.221 0.442 0.884 2.21 11.05 55.25 110.5 2211-Butanol 2.26 452 45.2 9.04 2.26 0.1808 0.226 0.452 0.904 2.26 11.30 56.50 113.0 226Benzene 1.11 222 22.2 4.44 1.11 0.0888 0.111 0.222 0.444 1.11 5.55 27.75 55.5 111Carbon Tetrachloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Cyclohexane 2.09 418 41.8 8.36 2.09 0.1672 0.209 0.418 0.836 2.09 10.45 52.25 104.5 209tert-Amyl Methyl Ether 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dichloropropane 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105Bromodichloromethane 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Trichloroethene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 1031,4-Dioxane 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Isooctane 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Methyl Methacrylate 2.08 416 41.6 8.32 2.08 0.1664 0.208 0.416 0.832 2.08 10.40 52.00 104.0 208n-Heptane 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107

Primary Source Standards Concentrations (Working & Initial Calibration)

Working STD

Conc.(ng/L):

Primary Working Standards

Q:\TO15 Std. Concentrations\MS08 Std. Conc\2016\R8061516.M\ICAL Conc. (Primary Source)

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1ng/L Std. ID:

4ng/L Std. ID: S29-05241612

20ng/L Std. ID: S29-05241610

200ng/L Std. ID: S29-05241606



Compounds mg/m3



Working STD

Conc.(ng/L):


cis-1,3-Dichloropropene 1.12 224 22.4 4.48 1.12 0.0896 0.112 0.224 0.448 1.12 5.60 28.00 56.0 112



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1ng/L Std. ID:

4ng/L Std. ID: S29-05241612

20ng/L Std. ID: S29-05241610

200ng/L Std. ID: S29-05241606



Compounds mg/m3



Working STD

Conc.(ng/L):


4-Methyl-2-pentanone 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108trans-1,3-Dichloropropene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 1071,1,2-Trichloroethane 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105Toluene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1052-Hexanone 1.11 222 22.2 4.44 1.11 0.0888 0.111 0.222 0.444 1.11 5.55 27.75 55.5 111Dibromochloromethane 1.10 220 22.0 4.40 1.10 0.0880 0.110 0.220 0.440 1.10 5.50 27.50 55.0 1101,2-Dibromoethane 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107n-Butyl Acetate 1.11 222 22.2 4.44 1.11 0.0888 0.111 0.222 0.444 1.11 5.55 27.75 55.5 111n-Octane 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Tetrachloroethene 0.99 198 19.8 3.96 0.99 0.0792 0.099 0.198 0.396 0.99 4.95 24.75 49.5 99Chlorobenzene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Ethylbenzene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105m-&p-Xylene 2.08 416 41.6 8.32 2.08 0.1664 0.208 0.416 0.832 2.08 10.40 52.00 104.0 208Bromoform 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Styrene 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108o-Xylene 1.02 204 20.4 4.08 1.02 0.0816 0.102 0.204 0.408 1.02 5.10 25.50 51.0 102n-Nonane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 1011,1,2,2-Tetrachloroethane 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100Cumene 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 101alpha-Pinene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103n-Propylbenzene 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 1003-Ethyltoluene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1044-Ethyltoluene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1051,3,5-Trimethylbenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104alpha-Methylstyrene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 1032-Ethyltoluene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2,4-Trimethylbenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104n-Decane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 101Benzyl Chloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 1081,3-Dichlorobenzene 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 1081,4-Dichlorobenzene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105sec-Butylbenzene 1.06 212 21.2 4.24 1.06 0.0848 0.106 0.212 0.424 1.06 5.30 26.50 53.0 106p-Isopropyltoluene 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 1001,2,3-Trimethylbenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dichlorobenzene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107d-Limonene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dibromo-3-chloropropane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104n-Undecane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 1011,2,4-Trichlorobenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Naphthalene 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100n-Dodecane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Hexachloro-1,3-butadiene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Methacrylonitrile 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Cyclohexanone 1.12 224 22.4 4.48 1.12 0.0896 0.112 0.224 0.448 1.12 5.60 28.00 56.0 112tert-Butylbenzene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105n-Butylbenzene 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108



Version: 0

69

of 1

13

Calibration Status Report Instrument #MS08

Method : I:\MS08\Methods\R8061516.M (RTE Integrator) Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration

# ID Conc ISTD Path\File Conc -- ---- ---- ---- ------------------------------------------------- 1 0.08 0 13 I:\MS08\Data\2016_06\15\06151630.D 2 0.10 0 13 I:\MS08\Data\2016_06\15\06151631.D 3 0.20 0 13 I:\MS08\Data\2016_06\15\06151632.D 4 0.40 0 13 I:\MS08\Data\2016_06\15\06151633.D 5 1.0 1 13 I:\MS08\Data\2016_06\15\06151634.D 6 5.0 5 13 I:\MS08\Data\2016_06\15\06151635.D 7 25 26 13 I:\MS08\Data\2016_06\15\06151636.D 8 50 52 13 I:\MS08\Data\2016_06\15\06151637.D 9 100 103 13 I:\MS08\Data\2016_06\15\06151638.D

# ID Update Time Quant Time Acquisition Time -- -- -------------------- ----------------- --------------------- 1 0.08 Jun 16 06:58 2016 Jun 16 06:43 2016 15 Jun 2016 23:59 2 0.10 Jun 16 06:58 2016 Jun 16 06:39 2016 16 Jun 2016 00:32 3 0.20 Jun 16 06:59 2016 Jun 16 06:39 2016 16 Jun 2016 1:05 4 0.40 Jun 16 06:59 2016 Jun 16 06:39 2016 16 Jun 2016 1:38 5 1.0 Jun 16 06:59 2016 Jun 16 06:39 2016 16 Jun 2016 2:10 6 5.0 Jun 16 06:59 2016 Jun 16 06:39 2016 16 Jun 2016 2:43 7 25 Jun 16 06:59 2016 Jun 16 06:40 2016 16 Jun 2016 3:16 8 50 Jun 16 07:00 2016 Jun 16 06:40 2016 16 Jun 2016 3:48 9 100 Jun 16 07:00 2016 Jun 16 06:40 2016 16 Jun 2016 4:21

R8061516.M Thu Jun 16 07:38:17 2016

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Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151630.D Acq On : 15 Jun 2016 23:59 Operator: WA Sample : 0.08ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:43:55 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:38:49 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.79 130 102793 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.53 114 487989 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 199946 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 176971 11.138 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 89.12% 57) Toluene-d8 (SS2) 12.77 98 499545 13.822 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 110.56% 73) Bromofluorobenzene (SS3) 16.07 174 182491 12.323 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 98.56% Target Compounds Qvalue 2) Propene 3.94 42 1016 0.070 ng # 86 3) Dichlorodifluoromethan... 4.03 85 1759 0.075 ng # 54 4) Chloromethane 4.25 50 709 0.046 ng # 43 5) 1,2-Dichloro-1,1,2,2-t... 4.38 135 749 0.067 ng # 42 6) Vinyl Chloride 4.53 62 788 0.053 ng # 43 7) 1,3-Butadiene 4.69 54 545 0.047 ng # 59 8) Bromomethane 5.00 94 364m 0.043 ng 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 5.39 45 2246 0.249 ng 88 11) Acetonitrile 5.64 41 1186 0.047 ng 96 12) Acrolein 5.74 56 49 0.007 ng # 14 13) Acetone 5.87 58 3805 0.446 ng 94 14) Trichlorofluoromethane 6.04 101 1449 0.074 ng 89 15) 2-Propanol (Isopropanol) 6.16 45 3385 0.111 ng 82 16) Acrylonitrile 6.39 53 54 0.004 ng # 8 17) 1,1-Dichloroethene 6.68 96 540 0.058 ng 87 18) 2-Methyl-2-Propanol (t... 6.77 59 3894 0.139 ng 82 19) Methylene Chloride 6.80 84 528 0.048 ng 100 20) 3-Chloro-1-propene (Al... 6.92 41 598 0.036 ng # 43 21) Trichlorotrifluoroethane 7.08 151 667 0.075 ng 98 22) Carbon Disulfide 7.08 76 4260 0.104 ng # 73 23) trans-1,2-Dichloroethene 7.71 61 818 0.054 ng # 17 24) 1,1-Dichloroethane 7.89 63 1373 0.070 ng # 43 25) Methyl tert-Butyl Ether 7.97 73 2374 0.070 ng # 52 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 8.66 61 953 0.064 ng 84 29) Diisopropyl Ether 8.88 87 675 0.075 ng # 90 30) Ethyl Acetate 8.66 61 953 0.269 ng # 10 31) n-Hexane 8.87 57 1288 0.070 ng # 85 32) Chloroform 8.91 83 1318 0.075 ng 85 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 9.34 87 860 0.063 ng 90 36) 1,2-Dichloroethane 9.58 62 1052 0.070 ng # 42 38) 1,1,1-Trichloroethane 9.82 97 1174 0.076 ng # 65 39) Isopropyl Acetate 10.15 61 583 0.105 ng # 37 40) 1-Butanol 0.00 56 0 N.D. 41) Benzene 10.23 78 3961 0.107 ng 97 42) Carbon Tetrachloride 10.36 117 992 0.077 ng 96 43) Cyclohexane 10.48 84 2465 0.152 ng 86 44) tert-Amyl Methyl Ether 10.77 73 2211 0.075 ng # 68 45) 1,2-Dichloropropane 10.97 63 705 0.074 ng # 13 46) Bromodichloromethane 11.12 83 834 0.066 ng # 18 47) Trichloroethene 11.18 130 866 0.081 ng # 74 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 11.23 57 3469 0.074 ng 92

R8061516.M Thu Jun 16 06:48:59 2016 Page: 1

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Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151630.D Acq On : 15 Jun 2016 23:59 Operator: WA Sample : 0.08ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:43:55 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:38:49 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 11.45 71 708 0.073 ng # 79 52) cis-1,3-Dichloropropene 11.97 75 880 0.061 ng # 43 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 12.60 97 574 0.065 ng # 7 58) Toluene 12.87 91 2981 0.081 ng 98 59) 2-Hexanone 0.00 43 0 N.D. 60) Dibromochloromethane 13.28 129 591 0.065 ng # 11 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 13.71 43 1143 0.047 ng # 43 63) n-Octane 13.81 57 520 0.059 ng # 49 64) Tetrachloroethene 13.95 166 1022 0.089 ng 99 65) Chlorobenzene 14.62 112 2126 0.088 ng 99 66) Ethylbenzene 15.00 91 3735 0.090 ng 91 67) m- & p-Xylenes 15.18 91 5896 0.176 ng 85 68) Bromoform 0.00 173 0 N.D. 69) Styrene 15.55 104 1611 0.066 ng 83 70) o-Xylene 15.65 91 2809 0.080 ng 94 71) n-Nonane 15.85 43 1769 0.078 ng # 67 72) 1,1,2,2-Tetrachloroethane 15.63 83 918 0.060 ng 97 74) Cumene 16.21 105 3555 0.079 ng 90 75) alpha-Pinene 16.59 93 1776 0.078 ng # 43 76) n-Propylbenzene 16.71 91 5091 0.095 ng # 80 77) 3-Ethyltoluene 16.81 105 3542 0.081 ng 91 78) 4-Ethyltoluene 16.85 105 3583 0.085 ng 95 79) 1,3,5-Trimethylbenzene 16.92 105 3401 0.090 ng 90 80) alpha-Methylstyrene 17.06 118 1115 0.056 ng 88 81) 2-Ethyltoluene 17.10 105 3566 0.083 ng 96 82) 1,2,4-Trimethylbenzene 17.31 105 2875 0.077 ng 95 83) n-Decane 17.41 57 1625 0.074 ng # 71 84) Benzyl Chloride 17.45 91 1406 0.044 ng # 53 85) 1,3-Dichlorobenzene 17.46 146 1698 0.081 ng 97 86) 1,4-Dichlorobenzene 17.52 146 1639 0.074 ng 91 87) sec-Butylbenzene 17.57 105 4098 0.086 ng 95 88) 4-Isopropyltoluene (p-... 17.72 119 3596 0.075 ng 96 89) 1,2,3-Trimethylbenzene 17.72 105 2994 0.078 ng 97 90) 1,2-Dichlorobenzene 17.85 146 1508 0.074 ng 95 91) d-Limonene 17.86 68 789 0.053 ng 86 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 18.61 57 1584 0.069 ng # 76 94) 1,2,4-Trichlorobenzene 19.47 180 1116 0.064 ng # 82 95) Naphthalene 19.59 128 2933 0.055 ng # 71 96) n-Dodecane 19.59 57 1280 0.060 ng # 72 97) Hexachlorobutadiene 19.91 225 941 0.081 ng 98 98) Cyclohexanone 15.34 55 787 0.062 ng # 18 99) tert-Butylbenzene 17.31 119 3049 0.080 ng 95 100) n-Butylbenzene 18.13 91 2803 0.075 ng 92 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

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Data File: I:\MS08\Data\2016_06\15\06151630.D Acq On : 15 Jun 2016 23:59 Operator: WA Sample : 0.08ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

Time-->


Hex

achl

orob

utad

iene

,TN

apht

hale

ne,T

n-D

odec

ane,

T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T

n-Bu

tylb

enze

ne,T

d-Li

mon

ene,

T1,

2-D

ichl

orob

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ne,T

1,2,

3-Tr

imet

hylb

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ne,T

4-Is

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pylto

luen

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,Tse

c-Bu

tylb

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ne,T

1,4-

Dic

hlor

oben

zene

,T1,

3-D

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ne,T

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ide,

Tn-

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luen

e,T

alph

a-M

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3,5-

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lben

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Ethy

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Prop

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a-Pi

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ne-d

5 (IS

3),IR

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hene

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Oct

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ne,T

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TTo

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(SS2

),S1,

1,2-

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ane,

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cis-

1,3-

Dic

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2,2,

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l Alc

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then

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Prop

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(Iso

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R8061516.M Thu Jun 16 06:48:59 2016 Page: 3

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4.00 4.10 4.20 4.30 4.40 4.50 4.60 4.70 4.80 4.90 5.00 5.10 5.20 5.30 5.40 5.50 5.60 5.70 5.80 5.90

0

100

200

300

400

Time-->


|||||

|

Ion 95.90 (95.60 to 96.60): 06151630.D\data.ms

-9 -8 -7 -6 -5 -4 -3 -2 -1 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 190

20

40

60

80

m/z-->

Abundance Scan 251 (4.954 min): 06151630.D\data.ms


0.00 0.00 0.00

0.00 0.00 0.00

95.90 93.50 0.00#

93.90 100 0.00

Ion Exp% Act%

response 0

4.954min (-4.954) 0.00ng

(8) Bromomethane (T)

R8061516.M Thu Jun 16 06:43:47 2016 Page: 1

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4.00 4.10 4.20 4.30 4.40 4.50 4.60 4.70 4.80 4.90 5.00 5.10 5.20 5.30 5.40 5.50 5.60 5.70 5.80 5.90

0

100

200

300

400

Time-->


5.003

|||||

|

Ion 95.90 (95.60 to 96.60): 06151630.D\data.ms

84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 1050

50

100

150

200

250

m/z-->


96


0.00 0.00 0.00

0.00 0.00 0.00

95.90 93.50 0.00#

93.90 100 100

Ion Exp% Act%

response 364

5.003min (+0.048) 0.04ng m

(8) Bromomethane (T)

R8061516.M Thu Jun 16 06:44:02 2016 Page: 1

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widayati.ang

MP

widayati.ang

Wida Ang

simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151631.D Acq On : 16 Jun 2016 00:32 Operator: WA Sample : 0.10ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:39:51 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.79 130 96678 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.53 114 460647 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 190722 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 170178 11.388 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 91.12% 57) Toluene-d8 (SS2) 12.77 98 477422 13.848 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 110.80% 73) Bromofluorobenzene (SS3) 16.07 174 171674 12.153 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.20% Target Compounds Qvalue 2) Propene 3.92 42 1194 0.087 ng # 79 3) Dichlorodifluoromethan... 4.02 85 1953 0.089 ng # 85 4) Chloromethane 4.24 50 972 0.066 ng # 43 5) 1,2-Dichloro-1,1,2,2-t... 4.38 135 837 0.079 ng # 42 6) Vinyl Chloride 4.53 62 738 0.053 ng # 43 7) 1,3-Butadiene 4.69 54 804 0.074 ng # 54 8) Bromomethane 4.99 94 549 0.069 ng 95 9) Chloroethane 5.20 64 529 0.066 ng # 43 10) Ethanol 5.39 45 3240 0.382 ng 83 11) Acetonitrile 5.64 41 1468 0.062 ng 89 12) Acrolein 5.75 56 62 0.010 ng 77 13) Acetone 5.86 58 4714 0.588 ng 91 14) Trichlorofluoromethane 6.02 101 1839 0.100 ng 84 15) 2-Propanol (Isopropanol) 6.15 45 4610 0.160 ng 86 16) Acrylonitrile 6.37 53 49 0.004 ng # 8 17) 1,1-Dichloroethene 6.68 96 771 0.088 ng 99 18) 2-Methyl-2-Propanol (t... 6.77 59 4807 0.182 ng 83 19) Methylene Chloride 6.79 84 531 0.052 ng # 66 20) 3-Chloro-1-propene (Al... 6.91 41 1002 0.065 ng # 43 21) Trichlorotrifluoroethane 7.07 151 798 0.095 ng 91 22) Carbon Disulfide 7.08 76 4532 0.118 ng # 73 23) trans-1,2-Dichloroethene 7.71 61 1060 0.075 ng 83 24) 1,1-Dichloroethane 7.88 63 1570 0.085 ng # 43 25) Methyl tert-Butyl Ether 7.97 73 2913 0.091 ng # 52 26) Vinyl Acetate 8.04 86 629 0.235 ng # 1 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 8.64 61 977 0.070 ng 98 29) Diisopropyl Ether 8.86 87 723 0.085 ng # 82 30) Ethyl Acetate 8.64 61 977 0.293 ng # 10 31) n-Hexane 8.87 57 1592 0.092 ng # 86 32) Chloroform 8.91 83 1532 0.093 ng 95 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 9.34 87 1282 0.100 ng # 86 36) 1,2-Dichloroethane 9.59 62 1292 0.091 ng # 42 38) 1,1,1-Trichloroethane 9.82 97 1550 0.106 ng # 69 39) Isopropyl Acetate 10.14 61 956 0.183 ng # 91 40) 1-Butanol 10.20 56 582 0.061 ng # 79 41) Benzene 10.23 78 4701 0.135 ng 92 42) Carbon Tetrachloride 10.37 117 1215 0.100 ng 96 43) Cyclohexane 10.48 84 3045 0.199 ng 87 44) tert-Amyl Methyl Ether 10.76 73 2564 0.092 ng 97 45) 1,2-Dichloropropane 10.96 63 808 0.090 ng # 13 46) Bromodichloromethane 11.14 83 1205 0.101 ng 85 47) Trichloroethene 11.18 130 914 0.090 ng 94 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 11.23 57 4239 0.096 ng 99

R8061516.M Thu Jun 16 06:52:53 2016 Page: 1

76 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151631.D Acq On : 16 Jun 2016 00:32 Operator: WA Sample : 0.10ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:39:51 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 11.45 71 934 0.102 ng # 76 52) cis-1,3-Dichloropropene 11.96 75 1201 0.088 ng # 43 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 12.44 75 690 0.054 ng # 43 55) 1,1,2-Trichloroethane 12.59 97 626 0.075 ng # 7 58) Toluene 12.87 91 3789 0.108 ng 97 59) 2-Hexanone 13.14 43 572 0.027 ng # 27 60) Dibromochloromethane 13.25 129 825 0.095 ng 93 61) 1,2-Dibromoethane 13.51 107 628 0.077 ng 93 62) n-Butyl Acetate 13.72 43 1280 0.055 ng # 43 63) n-Octane 13.80 57 798 0.096 ng # 63 64) Tetrachloroethene 13.96 166 1141 0.104 ng 90 65) Chlorobenzene 14.62 112 2392 0.104 ng 95 66) Ethylbenzene 15.00 91 3884 0.098 ng 95 67) m- & p-Xylenes 15.18 91 6483 0.202 ng 98 68) Bromoform 15.25 173 653 0.081 ng # 28 69) Styrene 15.54 104 2157 0.092 ng 87 70) o-Xylene 15.64 91 3512 0.105 ng 89 71) n-Nonane 15.84 43 2020 0.093 ng 96 72) 1,1,2,2-Tetrachloroethane 15.62 83 1283 0.087 ng 91 74) Cumene 16.21 105 4367 0.101 ng 95 75) alpha-Pinene 16.58 93 1925 0.089 ng 99 76) n-Propylbenzene 16.71 91 5194 0.101 ng # 87 77) 3-Ethyltoluene 16.81 105 4147 0.099 ng 94 78) 4-Ethyltoluene 16.84 105 4444 0.110 ng 83 79) 1,3,5-Trimethylbenzene 16.91 105 3998 0.111 ng 93 80) alpha-Methylstyrene 17.07 118 1220 0.065 ng # 81 81) 2-Ethyltoluene 17.10 105 4103 0.100 ng 99 82) 1,2,4-Trimethylbenzene 17.31 105 3548 0.099 ng 99 83) n-Decane 17.41 57 1975 0.094 ng 94 84) Benzyl Chloride 17.45 91 1829 0.060 ng # 53 85) 1,3-Dichlorobenzene 17.46 146 1867 0.093 ng 93 86) 1,4-Dichlorobenzene 17.52 146 2194 0.103 ng 96 87) sec-Butylbenzene 17.57 105 4668 0.102 ng 97 88) 4-Isopropyltoluene (p-... 17.72 119 4281 0.093 ng 98 89) 1,2,3-Trimethylbenzene 17.73 105 3746 0.102 ng 100 90) 1,2-Dichlorobenzene 17.85 146 2075 0.107 ng 97 91) d-Limonene 17.86 68 912 0.065 ng 91 92) 1,2-Dibromo-3-Chloropr... 18.26 157 531 0.075 ng # 55 93) n-Undecane 18.61 57 1824 0.084 ng 98 94) 1,2,4-Trichlorobenzene 19.47 180 1575 0.095 ng # 78 95) Naphthalene 19.58 128 3547 0.070 ng # 71 96) n-Dodecane 19.59 57 1653 0.081 ng # 76 97) Hexachlorobutadiene 19.91 225 1176 0.106 ng 97 98) Cyclohexanone 15.34 55 851 0.071 ng # 71 99) tert-Butylbenzene 17.31 119 3997 0.110 ng 93 100) n-Butylbenzene 18.13 91 3570 0.101 ng 91 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Thu Jun 16 06:52:53 2016 Page: 2

77 of 113




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

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ane,

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2-D

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mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

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orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

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ltolu

ene,

Tal

pha-

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hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

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ne,T

Cum

ene,

TBr

omof

luor

oben

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(SS3

),Sn-

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ane,

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ne,T

1,1,

2,2-

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chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

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ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

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one,

TTo

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e,T

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than

e,T

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e,T

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odic

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ther

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ther

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l Ace

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ichl

oroe

than

e,T

trans

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T

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bon

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ulfid

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),TTr

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eton

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lein

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l Chl

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than

e ,T

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hlor

odifl

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e,T

R8061516.M Thu Jun 16 06:52:54 2016 Page: 3

78 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151632.D Acq On : 16 Jun 2016 1:05 Operator: WA Sample : 0.20ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:39:53 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.79 130 94409 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.53 114 441948 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 184462 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 166688 11.423 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 91.36% 57) Toluene-d8 (SS2) 12.77 98 457641 13.725 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 109.84% 73) Bromofluorobenzene (SS3) 16.07 174 163997 12.003 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 96.00% Target Compounds Qvalue 2) Propene 3.92 42 2091 0.157 ng 88 3) Dichlorodifluoromethan... 4.02 85 3874 0.180 ng # 90 4) Chloromethane 4.23 50 2102 0.147 ng # 43 5) 1,2-Dichloro-1,1,2,2-t... 4.38 135 1752 0.170 ng 100 6) Vinyl Chloride 4.51 62 1984 0.145 ng 96 7) 1,3-Butadiene 4.67 54 1724 0.162 ng 84 8) Bromomethane 4.99 94 1119 0.144 ng 83 9) Chloroethane 5.20 64 1180 0.151 ng # 43 10) Ethanol 5.37 45 6241 0.753 ng 99 11) Acetonitrile 5.64 41 3187 0.139 ng 85 12) Acrolein 5.72 56 948 0.153 ng 90 13) Acetone 5.86 58 8748 1.117 ng 99 14) Trichlorofluoromethane 6.02 101 3558 0.198 ng 95 15) 2-Propanol (Isopropanol) 6.14 45 9550 0.340 ng 96 16) Acrylonitrile 6.37 53 1797 0.134 ng 94 17) 1,1-Dichloroethene 6.68 96 1469 0.173 ng 90 18) 2-Methyl-2-Propanol (t... 6.75 59 9927 0.385 ng 90 19) Methylene Chloride 6.79 84 1491 0.149 ng 87 20) 3-Chloro-1-propene (Al... 6.91 41 2302 0.152 ng 85 21) Trichlorotrifluoroethane 7.07 151 1730 0.211 ng 94 22) Carbon Disulfide 7.07 76 7427 0.198 ng # 73 23) trans-1,2-Dichloroethene 7.70 61 2599 0.187 ng 75 24) 1,1-Dichloroethane 7.88 63 3388 0.188 ng 92 25) Methyl tert-Butyl Ether 7.96 73 5836 0.187 ng 96 26) Vinyl Acetate 8.04 86 1676 0.640 ng # 47 27) 2-Butanone (MEK) 8.26 72 1074 0.174 ng # 49 28) cis-1,2-Dichloroethene 8.64 61 2408 0.177 ng 96 29) Diisopropyl Ether 8.86 87 1594 0.192 ng 99 30) Ethyl Acetate 8.87 61 1066 0.328 ng 82 31) n-Hexane 8.86 57 3276 0.194 ng # 88 32) Chloroform 8.91 83 3127 0.195 ng 100 34) Tetrahydrofuran (THF) 9.28 72 968 0.152 ng # 74 35) Ethyl tert-Butyl Ether 9.34 87 2208 0.177 ng 91 36) 1,2-Dichloroethane 9.58 62 2639 0.190 ng 94 38) 1,1,1-Trichloroethane 9.82 97 2835 0.202 ng 91 39) Isopropyl Acetate 10.13 61 2027 0.404 ng 99 40) 1-Butanol 10.17 56 2478 0.272 ng # 80 41) Benzene 10.23 78 7813 0.234 ng 98 42) Carbon Tetrachloride 10.36 117 2650 0.228 ng 98 43) Cyclohexane 10.48 84 5956 0.406 ng 96 44) tert-Amyl Methyl Ether 10.76 73 5342 0.201 ng 94 45) 1,2-Dichloropropane 10.96 63 1760 0.203 ng 94 46) Bromodichloromethane 11.14 83 2312 0.203 ng 97 47) Trichloroethene 11.18 130 2058 0.211 ng 90 48) 1,4-Dioxane 11.16 88 1388 0.201 ng 85 49) 2,2,4-Trimethylpentane... 11.23 57 8366 0.198 ng 97

R8061516.M Thu Jun 16 06:54:13 2016 Page: 1

79 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151632.D Acq On : 16 Jun 2016 1:05 Operator: WA Sample : 0.20ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:39:53 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.34 100 1227 0.316 ng 91 51) n-Heptane 11.44 71 1944 0.220 ng 98 52) cis-1,3-Dichloropropene 11.95 75 2737 0.209 ng 82 53) 4-Methyl-2-pentanone 11.98 58 1349 0.156 ng # 67 54) trans-1,3-Dichloropropene 12.43 75 1968 0.160 ng # 43 55) 1,1,2-Trichloroethane 12.60 97 1651 0.206 ng 97 58) Toluene 12.87 91 7560 0.223 ng 96 59) 2-Hexanone 13.10 43 3670 0.182 ng 74 60) Dibromochloromethane 13.26 129 1739 0.208 ng 99 61) 1,2-Dibromoethane 13.51 107 1741 0.220 ng 93 62) n-Butyl Acetate 13.70 43 3766 0.168 ng # 80 63) n-Octane 13.80 57 1521 0.188 ng 94 64) Tetrachloroethene 13.95 166 2384 0.225 ng 97 65) Chlorobenzene 14.62 112 5128 0.231 ng 98 66) Ethylbenzene 15.00 91 8148 0.213 ng 95 67) m- & p-Xylenes 15.18 91 13613 0.440 ng 95 68) Bromoform 15.25 173 1501 0.194 ng 87 69) Styrene 15.54 104 4353 0.192 ng 97 70) o-Xylene 15.64 91 6695 0.207 ng 94 71) n-Nonane 15.84 43 4223 0.202 ng 97 72) 1,1,2,2-Tetrachloroethane 15.62 83 2597 0.183 ng 95 74) Cumene 16.21 105 8468 0.203 ng 97 75) alpha-Pinene 16.59 93 4274 0.205 ng 88 76) n-Propylbenzene 16.70 91 10319 0.208 ng 96 77) 3-Ethyltoluene 16.81 105 8192 0.203 ng 99 78) 4-Ethyltoluene 16.84 105 8847 0.226 ng 100 79) 1,3,5-Trimethylbenzene 16.92 105 7326 0.211 ng 91 80) alpha-Methylstyrene 17.06 118 3010 0.165 ng 93 81) 2-Ethyltoluene 17.10 105 8364 0.211 ng 97 82) 1,2,4-Trimethylbenzene 17.31 105 7340 0.212 ng 99 83) n-Decane 17.41 57 3942 0.194 ng 93 84) Benzyl Chloride 17.44 91 4318 0.145 ng 88 85) 1,3-Dichlorobenzene 17.46 146 4352 0.224 ng 96 86) 1,4-Dichlorobenzene 17.52 146 4195 0.204 ng 100 87) sec-Butylbenzene 17.57 105 9647 0.219 ng 98 88) 4-Isopropyltoluene (p-... 17.71 119 8763 0.197 ng 99 89) 1,2,3-Trimethylbenzene 17.71 105 7807 0.220 ng 100 90) 1,2-Dichlorobenzene 17.85 146 4274 0.227 ng 97 91) d-Limonene 17.85 68 2099 0.154 ng 95 92) 1,2-Dibromo-3-Chloropr... 18.26 157 1222 0.179 ng 84 93) n-Undecane 18.61 57 3942 0.187 ng 97 94) 1,2,4-Trichlorobenzene 19.47 180 3019 0.189 ng 98 95) Naphthalene 19.58 128 7770 0.158 ng 95 96) n-Dodecane 19.58 57 3580 0.181 ng 97 97) Hexachlorobutadiene 19.91 225 2284 0.213 ng 97 98) Cyclohexanone 15.33 55 2014 0.173 ng 94 99) tert-Butylbenzene 17.31 119 7751 0.221 ng 96 100) n-Butylbenzene 18.12 91 7741 0.226 ng 92 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Thu Jun 16 06:54:13 2016 Page: 2

80 of 113




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

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2,4-

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hlor

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Buty

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e),T

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hylb

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Tal

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Tal

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Cum

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Non

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To-

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chlo

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ne,T

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p-X

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Ethy

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zene

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l Ace

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rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Amyl

Met

hyl E

ther

,T1,

4-D

ifluo

robe

nzen

e (IS

2),IR

Cyc

lohe

xane

,TC

arbo

n Te

trach

lorid

e,T

Benz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T2-

Buta

none

(MEK

),TVi

nyl A

ceta

te,T

Met

hyl t

ert-B

utyl

Eth

er,T

1,1-

Dic

hlor

oeth

ane,

Ttra

ns-1

,2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8061516.M Thu Jun 16 06:54:13 2016 Page: 3

81 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151633.D Acq On : 16 Jun 2016 1:38 Operator: WA Sample : 0.40ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:39:55 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.79 130 92737 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.53 114 438636 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 180766 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 165766 11.565 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 92.48% 57) Toluene-d8 (SS2) 12.77 98 449757 13.765 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 110.08% 73) Bromofluorobenzene (SS3) 16.07 174 163279 12.195 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.60% Target Compounds Qvalue 2) Propene 3.91 42 4271 0.326 ng 96 3) Dichlorodifluoromethan... 4.01 85 7642 0.362 ng # 96 4) Chloromethane 4.22 50 4268 0.304 ng 89 5) 1,2-Dichloro-1,1,2,2-t... 4.36 135 3402 0.336 ng 92 6) Vinyl Chloride 4.49 62 4014 0.299 ng 92 7) 1,3-Butadiene 4.66 54 3380 0.324 ng 95 8) Bromomethane 4.98 94 2456 0.322 ng 97 9) Chloroethane 5.19 64 2486 0.324 ng 98 10) Ethanol 5.35 45 13512 1.660 ng 94 11) Acetonitrile 5.58 41 7042 0.312 ng 94 12) Acrolein 5.72 56 2143 0.351 ng 78 13) Acetone 5.84 58 17111 2.224 ng 96 14) Trichlorofluoromethane 6.01 101 6988 0.397 ng 99 15) 2-Propanol (Isopropanol) 6.13 45 19415 0.704 ng 99 16) Acrylonitrile 6.34 53 3814 0.290 ng 95 17) 1,1-Dichloroethene 6.67 96 3077 0.368 ng 92 18) 2-Methyl-2-Propanol (t... 6.74 59 19621 0.774 ng 97 19) Methylene Chloride 6.79 84 2945 0.299 ng 87 20) 3-Chloro-1-propene (Al... 6.91 41 5038 0.339 ng 88 21) Trichlorotrifluoroethane 7.07 151 3214 0.399 ng 95 22) Carbon Disulfide 7.06 76 13453 0.365 ng 91 23) trans-1,2-Dichloroethene 7.69 61 5146 0.378 ng 92 24) 1,1-Dichloroethane 7.88 63 6518 0.368 ng 99 25) Methyl tert-Butyl Ether 7.95 73 11624 0.380 ng 99 26) Vinyl Acetate 8.03 86 4134 1.607 ng # 85 27) 2-Butanone (MEK) 8.25 72 2417 0.399 ng # 63 28) cis-1,2-Dichloroethene 8.64 61 5159 0.387 ng 99 29) Diisopropyl Ether 8.85 87 3312 0.406 ng 100 30) Ethyl Acetate 8.85 61 2140 0.670 ng 100 31) n-Hexane 8.86 57 6291 0.379 ng 95 32) Chloroform 8.91 83 6334 0.401 ng 96 34) Tetrahydrofuran (THF) 9.28 72 2046 0.328 ng # 80 35) Ethyl tert-Butyl Ether 9.33 87 4883 0.399 ng 97 36) 1,2-Dichloroethane 9.58 62 5384 0.395 ng 97 38) 1,1,1-Trichloroethane 9.82 97 5947 0.427 ng 98 39) Isopropyl Acetate 10.13 61 4221 0.847 ng 98 40) 1-Butanol 10.16 56 5914 0.654 ng 83 41) Benzene 10.23 78 13911 0.420 ng 98 42) Carbon Tetrachloride 10.36 117 5048 0.437 ng 95 43) Cyclohexane 10.48 84 11848 0.813 ng 98 44) tert-Amyl Methyl Ether 10.76 73 10932 0.414 ng 99 45) 1,2-Dichloropropane 10.96 63 3552 0.413 ng 92 46) Bromodichloromethane 11.12 83 4736 0.418 ng 100 47) Trichloroethene 11.17 130 3822 0.395 ng 97 48) 1,4-Dioxane 11.16 88 2592 0.378 ng 95 49) 2,2,4-Trimethylpentane... 11.22 57 16259 0.387 ng 99

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82 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151633.D Acq On : 16 Jun 2016 1:38 Operator: WA Sample : 0.40ng TO-15 ICAL Std Misc : S29-06151601/S29-05241612 (6/22) ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 16 06:39:55 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.33 100 2539 0.658 ng 92 51) n-Heptane 11.45 71 3876 0.443 ng 98 52) cis-1,3-Dichloropropene 11.95 75 5403 0.416 ng 98 53) 4-Methyl-2-pentanone 11.97 58 3024 0.352 ng 89 54) trans-1,3-Dichloropropene 12.43 75 4422 0.362 ng 88 55) 1,1,2-Trichloroethane 12.59 97 3019 0.380 ng 98 58) Toluene 12.87 91 14629 0.440 ng 95 59) 2-Hexanone 13.09 43 8128 0.411 ng 90 60) Dibromochloromethane 13.26 129 3590 0.437 ng 92 61) 1,2-Dibromoethane 13.50 107 3597 0.465 ng 93 62) n-Butyl Acetate 13.68 43 8569 0.391 ng 97 63) n-Octane 13.80 57 2984 0.377 ng 93 64) Tetrachloroethene 13.95 166 4604 0.444 ng 96 65) Chlorobenzene 14.62 112 9880 0.455 ng 96 66) Ethylbenzene 15.00 91 16719 0.446 ng 99 67) m- & p-Xylenes 15.18 91 25411 0.837 ng 99 68) Bromoform 15.25 173 3117 0.410 ng 94 69) Styrene 15.54 104 8939 0.403 ng 98 70) o-Xylene 15.64 91 13626 0.431 ng 94 71) n-Nonane 15.85 43 8140 0.398 ng 98 72) 1,1,2,2-Tetrachloroethane 15.62 83 5673 0.408 ng 100 74) Cumene 16.21 105 17104 0.418 ng 98 75) alpha-Pinene 16.59 93 7910 0.386 ng 93 76) n-Propylbenzene 16.70 91 20483 0.421 ng 99 77) 3-Ethyltoluene 16.80 105 17527 0.443 ng 96 78) 4-Ethyltoluene 16.84 105 16922 0.441 ng 97 79) 1,3,5-Trimethylbenzene 16.91 105 14370 0.423 ng 100 80) alpha-Methylstyrene 17.06 118 6138 0.343 ng 97 81) 2-Ethyltoluene 17.10 105 16986 0.438 ng 99 82) 1,2,4-Trimethylbenzene 17.31 105 14012 0.412 ng 97 83) n-Decane 17.41 57 8085 0.407 ng 97 84) Benzyl Chloride 17.44 91 9229 0.317 ng 98 85) 1,3-Dichlorobenzene 17.45 146 8450 0.444 ng 98 86) 1,4-Dichlorobenzene 17.52 146 8660 0.430 ng 99 87) sec-Butylbenzene 17.57 105 19755 0.457 ng 97 88) 4-Isopropyltoluene (p-... 17.72 119 17300 0.397 ng 97 89) 1,2,3-Trimethylbenzene 17.71 105 15026 0.431 ng 97 90) 1,2-Dichlorobenzene 17.84 146 8504 0.461 ng 93 91) d-Limonene 17.85 68 4489 0.337 ng 99 92) 1,2-Dibromo-3-Chloropr... 18.26 157 2768 0.413 ng 94 93) n-Undecane 18.61 57 8232 0.399 ng 97 94) 1,2,4-Trichlorobenzene 19.46 180 6183 0.395 ng 96 95) Naphthalene 19.58 128 16763 0.348 ng 96 96) n-Dodecane 19.58 57 7849 0.404 ng 97 97) Hexachlorobutadiene 19.91 225 4893 0.467 ng 99 98) Cyclohexanone 15.33 55 4826 0.422 ng 98 99) tert-Butylbenzene 17.31 119 14534 0.423 ng 97 100) n-Butylbenzene 18.12 91 15241 0.454 ng 97 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Thu Jun 16 06:55:13 2016 Page: 2

83 of 113




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Amyl

Met

hyl E

ther

,T1,

4-D

ifluo

robe

nzen

e (IS

2),IR

Cyc

lohe

xane

,TC

arbo

n Te

trach

lorid

e,T

Benz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,Tn-H

exan

e,T

Ethy

l Ace

tate

,TD

iisop

ropy

l Eth

er,T

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8061516.M Thu Jun 16 06:55:14 2016 Page: 3

84 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151634.D Acq On : 16 Jun 2016 2:10 Operator: WA Sample : 1.0ng TO-15 ICAL Std Misc : S29-06151601/S29-05241610 (6/22) ALS Vial : 15 Sample Multiplier: 1 Quant Time: Jun 16 06:39:57 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.79 130 88509 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.53 114 407941 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 174100 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 159023 11.624 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 92.96% 57) Toluene-d8 (SS2) 12.77 98 425472 13.520 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 108.16% 73) Bromofluorobenzene (SS3) 16.07 174 154292 11.965 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.76% Target Compounds Qvalue 2) Propene 3.90 42 11054 0.884 ng 98 3) Dichlorodifluoromethan... 4.00 85 20577 1.020 ng 98 4) Chloromethane 4.20 50 13085 0.977 ng 97 5) 1,2-Dichloro-1,1,2,2-t... 4.36 135 9455 0.977 ng 94 6) Vinyl Chloride 4.48 62 11637 0.909 ng 96 7) 1,3-Butadiene 4.65 54 9220 0.927 ng 95 8) Bromomethane 4.96 94 7106 0.976 ng 95 9) Chloroethane 5.17 64 7142 0.974 ng 100 10) Ethanol 5.35 45 37043 4.768 ng 97 11) Acetonitrile 5.57 41 18855 0.875 ng 99 12) Acrolein 5.70 56 5926 1.018 ng 96 13) Acetone 5.84 58 38320 5.219 ng 99 14) Trichlorofluoromethane 6.01 101 17542 1.043 ng 99 15) 2-Propanol (Isopropanol) 6.12 45 54362 2.065 ng 97 16) Acrylonitrile 6.33 53 11870 0.945 ng 96 17) 1,1-Dichloroethene 6.65 96 8829 1.106 ng 100 18) 2-Methyl-2-Propanol (t... 6.71 59 54509 2.254 ng 98 19) Methylene Chloride 6.78 84 8880 0.944 ng 98 20) 3-Chloro-1-propene (Al... 6.90 41 13601 0.959 ng 96 21) Trichlorotrifluoroethane 7.06 151 8698 1.133 ng 97 22) Carbon Disulfide 7.05 76 32931 0.936 ng 96 23) trans-1,2-Dichloroethene 7.69 61 14387 1.107 ng 99 24) 1,1-Dichloroethane 7.88 63 17651 1.043 ng 98 25) Methyl tert-Butyl Ether 7.95 73 31946 1.095 ng 99 26) Vinyl Acetate 8.02 86 11127 4.532 ng # 88 27) 2-Butanone (MEK) 8.24 72 6322 1.094 ng # 76 28) cis-1,2-Dichloroethene 8.65 61 13220 1.039 ng 97 29) Diisopropyl Ether 8.85 87 8740 1.123 ng 99 30) Ethyl Acetate 8.85 61 6353 2.083 ng 100 31) n-Hexane 8.85 57 16174 1.022 ng 99 32) Chloroform 8.91 83 16765 1.113 ng 98 34) Tetrahydrofuran (THF) 9.27 72 5888 0.988 ng # 90 35) Ethyl tert-Butyl Ether 9.33 87 12837 1.099 ng 97 36) 1,2-Dichloroethane 9.58 62 14691 1.129 ng 97 38) 1,1,1-Trichloroethane 9.82 97 15708 1.213 ng 98 39) Isopropyl Acetate 10.13 61 11664 2.518 ng 98 40) 1-Butanol 10.14 56 18520 2.201 ng 85 41) Benzene 10.23 78 36037 1.169 ng 100 42) Carbon Tetrachloride 10.37 117 13644 1.271 ng 100 43) Cyclohexane 10.48 84 30650 2.262 ng 99 44) tert-Amyl Methyl Ether 10.75 73 28583 1.164 ng 98 45) 1,2-Dichloropropane 10.96 63 9474 1.186 ng 96 46) Bromodichloromethane 11.12 83 13111 1.245 ng 98 47) Trichloroethene 11.17 130 10129 1.127 ng 99 48) 1,4-Dioxane 11.15 88 7551 1.183 ng 97 49) 2,2,4-Trimethylpentane... 11.22 57 42754 1.094 ng 99

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widayati.ang

Wida Ang


R8061516.M Thu Jun 16 06:55:55 2016 Page: 2

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,2,

3-Tr

imet

hylb

enze

ne,T

4-Is

opro

pylto

luen

e (p

-Cym

ene)

,Tse

c-Bu

tylb

enze

ne,T

1,4-

Dic

hlor

oben

zene

,T1,

3-D

ichl

orob

enze

ne,T

Benz

yl C

hlor

ide,

Tn-

Dec

ane,

T1,

2,4-

Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Amyl

Met

hyl E

ther

,T1,

4-D

ifluo

robe

nzen

e (IS

2),IR

Cyc

lohe

xane

,TC

arbo

n Te

trach

lorid

e,T

Benz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,Tn-

Hex

ane,

TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),TVi

nyl A

ceta

te,T

Met

hyl t

ert-B

utyl

Eth

er,T

1,1-

Dic

hlor

oeth

ane,

Ttra

ns-1

,2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAcet

one,

TAc

role

in,T

Acet

onitr

ile,T

Etha

nol,T

Chl

oroe

than

e,T

Brom

omet

hane

,T1,

3-Bu

tadi

ene,

TVi

nyl C

hlor

ide,

T1,

2-D

ichl

oro-

1,1,

2,2-

tetra

fluor

oeth

ane

,TC

hlor

omet

hane

,TD

ichl

orod

ifluo

rom

etha

ne (C

FC 1

2),T

Prop

ene,

T

R8061516.M Thu Jun 16 06:55:56 2016 Page: 3

87 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151635.D Acq On : 16 Jun 2016 2:43 Operator: WA Sample : 5.0ng TO-15 ICAL Std Misc : S29-06151601/S29-05241610 (6/22) ALS Vial : 15 Sample Multiplier: 1 Quant Time: Jun 16 06:39:59 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.80 130 88456 12.500 ng -0.01 37) 1,4-Difluorobenzene (IS2) 10.54 114 411736 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 14.57 82 175146 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 163517 11.960 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.68% 57) Toluene-d8 (SS2) 12.77 98 430071 13.584 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 108.64% 73) Bromofluorobenzene (SS3) 16.07 174 158010 12.180 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.44% Target Compounds Qvalue 2) Propene 3.88 42 50858 4.068 ng 98 3) Dichlorodifluoromethan... 3.99 85 94617 4.695 ng 99 4) Chloromethane 4.19 50 56576 4.225 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.35 135 42088 4.352 ng 98 6) Vinyl Chloride 4.47 62 56115 4.387 ng 97 7) 1,3-Butadiene 4.64 54 42984 4.323 ng 98 8) Bromomethane 4.95 94 33562 4.612 ng 99 9) Chloroethane 5.16 64 33360 4.553 ng 100 10) Ethanol 5.36 45 166377 21.428 ng 100 11) Acetonitrile 5.57 41 88569 4.111 ng 100 12) Acrolein 5.70 56 28168 4.843 ng 100 13) Acetone 5.83 58 172399 23.492 ng 98 14) Trichlorofluoromethane 6.01 101 82493 4.908 ng 100 15) 2-Propanol (Isopropanol) 6.12 45 251442 9.557 ng 98 16) Acrylonitrile 6.33 53 57171 4.554 ng 98 17) 1,1-Dichloroethene 6.65 96 39987 5.013 ng 98 18) 2-Methyl-2-Propanol (t... 6.72 59 250812 10.378 ng 98 19) Methylene Chloride 6.78 84 40050 4.260 ng 100 20) 3-Chloro-1-propene (Al... 6.90 41 68354 4.824 ng 99 21) Trichlorotrifluoroethane 7.06 151 39993 5.211 ng 99 22) Carbon Disulfide 7.04 76 150965 4.295 ng 98 23) trans-1,2-Dichloroethene 7.69 61 66301 5.104 ng 99 24) 1,1-Dichloroethane 7.88 63 80504 4.759 ng 100 25) Methyl tert-Butyl Ether 7.93 73 142502 4.886 ng 100 26) Vinyl Acetate 8.02 86 57091 23.266 ng # 92 27) 2-Butanone (MEK) 8.24 72 30215 5.231 ng # 92 28) cis-1,2-Dichloroethene 8.65 61 63267 4.975 ng 99 29) Diisopropyl Ether 8.84 87 37930 4.878 ng # 92 30) Ethyl Acetate 8.84 61 29698 9.742 ng 97 31) n-Hexane 8.86 57 70870 4.482 ng 99 32) Chloroform 8.91 83 76476 5.080 ng 99 34) Tetrahydrofuran (THF) 9.26 72 28081 4.713 ng 100 35) Ethyl tert-Butyl Ether 9.33 87 58194 4.984 ng 99 36) 1,2-Dichloroethane 9.58 62 67856 5.219 ng 99 38) 1,1,1-Trichloroethane 9.82 97 72522 5.547 ng 99 39) Isopropyl Acetate 10.12 61 51957 11.113 ng 96 40) 1-Butanol 10.13 56 100141 11.791 ng 97 41) Benzene 10.23 78 158910 5.105 ng 99 42) Carbon Tetrachloride 10.37 117 63918 5.900 ng 100 43) Cyclohexane 10.48 84 137421 10.050 ng 97 44) tert-Amyl Methyl Ether 10.75 73 132554 5.350 ng 99 45) 1,2-Dichloropropane 10.96 63 42059 5.215 ng 99 46) Bromodichloromethane 11.12 83 61043 5.742 ng 99 47) Trichloroethene 11.17 130 46549 5.131 ng 99 48) 1,4-Dioxane 11.14 88 34863 5.411 ng 97 49) 2,2,4-Trimethylpentane... 11.23 57 193394 4.901 ng 99

R8061516.M Thu Jun 16 06:56:33 2016 Page: 1

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widayati.ang

Wida Ang


R8061516.M Thu Jun 16 06:56:33 2016 Page: 2

89 of 113




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,Tn-

Dec

ane,

T1,

2,4-

Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Amyl

Met

hyl E

ther

,T1,

4-D

ifluo

robe

nzen

e (IS

2),IR

Cyc

lohe

xane

,TC

arbo

n Te

trach

lorid

e,T

Benz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,Tn-

Hex

ane,

TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAcet

onitr

ile,T

Etha

nol,T

Chl

oroe

than

e,T

Brom

omet

hane

,T1,

3-Bu

tadi

ene,

TVi

nyl C

hlor

ide,

T1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8061516.M Thu Jun 16 06:56:34 2016 Page: 3

90 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151636.D Acq On : 16 Jun 2016 3:16 Operator: WA Sample : 25ng TO-15 ICAL Std Misc : S29-06151601/S29-05241606 (6/22) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 16 06:40:01 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.81 130 94998 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 10.54 114 435606 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 14.57 82 188347 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.49 65 169544 11.547 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 92.40% 57) Toluene-d8 (SS2) 12.77 98 461985 13.570 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 108.56% 73) Bromofluorobenzene (SS3) 16.07 174 170216 12.202 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 97.60% Target Compounds Qvalue 2) Propene 3.87 42 278356 20.734 ng 100 3) Dichlorodifluoromethan... 3.99 85 503916 23.281 ng 100 4) Chloromethane 4.19 50 273989 19.052 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.35 135 227122 21.869 ng 100 6) Vinyl Chloride 4.47 62 306063 22.278 ng 100 7) 1,3-Butadiene 4.64 54 276344 25.880 ng 100 8) Bromomethane 4.95 94 200518 25.659 ng 100 9) Chloroethane 5.17 64 183303 23.293 ng 100 10) Ethanol 5.40 45 910003 109.131 ng 100 11) Acetonitrile 5.59 41 480149 20.753 ng 100 12) Acrolein 5.71 56 146331 23.425 ng 100 13) Acetone 5.85 58 889333 112.841 ng 100 14) Trichlorofluoromethane 6.01 101 438491 24.294 ng 100 15) 2-Propanol (Isopropanol) 6.15 45 1341961 47.494 ng 100 16) Acrylonitrile 6.34 53 323195 23.971 ng 100 17) 1,1-Dichloroethene 6.66 96 220576 25.751 ng 100 18) 2-Methyl-2-Propanol (t... 6.75 59 1311647 50.535 ng 100 19) Methylene Chloride 6.80 84 220177 21.804 ng 100 20) 3-Chloro-1-propene (Al... 6.91 41 403479 26.513 ng 100 21) Trichlorotrifluoroethane 7.07 151 216920 26.318 ng 100 22) Carbon Disulfide 7.05 76 816983 21.641 ng 100 23) trans-1,2-Dichloroethene 7.70 61 368817 26.438 ng 100 24) 1,1-Dichloroethane 7.89 63 435796 23.989 ng 100 25) Methyl tert-Butyl Ether 7.94 73 780965 24.935 ng 100 26) Vinyl Acetate 8.03 86 321018 121.813 ng 100 27) 2-Butanone (MEK) 8.24 72 160526 25.877 ng 100 28) cis-1,2-Dichloroethene 8.66 61 347365 25.433 ng 100 29) Diisopropyl Ether 8.85 87 205330 24.586 ng 100 30) Ethyl Acetate 8.85 61 163859 50.051 ng 100 31) n-Hexane 8.87 57 355071 20.908 ng 100 32) Chloroform 8.93 83 415694 25.712 ng 100 34) Tetrahydrofuran (THF) 9.26 72 151415 23.662 ng 100 35) Ethyl tert-Butyl Ether 9.33 87 314776 25.105 ng 100 36) 1,2-Dichloroethane 9.59 62 363404 26.026 ng 100 38) 1,1,1-Trichloroethane 9.83 97 396365 28.655 ng 100 39) Isopropyl Acetate 10.13 61 281079 56.828 ng 100 40) 1-Butanol 10.14 56 549945 61.203 ng 100 41) Benzene 10.24 78 836653 25.407 ng 100 42) Carbon Tetrachloride 10.37 117 359676 31.382 ng 100 43) Cyclohexane 10.49 84 740847 51.212 ng 100 44) tert-Amyl Methyl Ether 10.75 73 728308 27.784 ng 100 45) 1,2-Dichloropropane 10.97 63 225978 26.484 ng 100 46) Bromodichloromethane 11.13 83 341688 30.377 ng 100 47) Trichloroethene 11.18 130 254873 26.555 ng 100 48) 1,4-Dioxane 11.15 88 189481 27.797 ng 100 49) 2,2,4-Trimethylpentane... 11.23 57 1052221 25.206 ng 100

R8061516.M Thu Jun 16 06:57:02 2016 Page: 1

91 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151636.D Acq On : 16 Jun 2016 3:16 Operator: WA Sample : 25ng TO-15 ICAL Std Misc : S29-06151601/S29-05241606 (6/22) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 16 06:40:01 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.33 100 202994 52.993 ng 100 51) n-Heptane 11.45 71 226987 26.121 ng 100 52) cis-1,3-Dichloropropene 11.95 75 415049 32.177 ng 100 53) 4-Methyl-2-pentanone 11.97 58 232937 27.337 ng 100 54) trans-1,3-Dichloropropene 12.42 75 388367 32.023 ng 100 55) 1,1,2-Trichloroethane 12.59 97 222825 28.207 ng 100 58) Toluene 12.87 91 932699 26.953 ng 100 59) 2-Hexanone 13.07 43 630374 30.592 ng 100 60) Dibromochloromethane 13.26 129 292948 34.256 ng 100 61) 1,2-Dibromoethane 13.50 107 262446 32.546 ng 100 62) n-Butyl Acetate 13.67 43 702035 30.742 ng 100 63) n-Octane 13.80 57 211093 25.611 ng 100 64) Tetrachloroethene 13.95 166 296504 27.419 ng 100 65) Chlorobenzene 14.62 112 659882 29.141 ng 100 66) Ethylbenzene 14.99 91 1126100 28.843 ng 100 67) m- & p-Xylenes 15.17 91 1752201 55.418 ng 100 68) Bromoform 15.25 173 280091 35.378 ng 100 69) Styrene 15.53 104 707938 30.619 ng 100 70) o-Xylene 15.64 91 909697 27.598 ng 100 71) n-Nonane 15.85 43 558985 26.199 ng 100 72) 1,1,2,2-Tetrachloroethane 15.61 83 403745 27.864 ng 100 74) Cumene 16.21 105 1200557 28.150 ng 100 75) alpha-Pinene 16.59 93 601531 28.194 ng 100 76) n-Propylbenzene 16.70 91 1398873 27.576 ng 100 77) 3-Ethyltoluene 16.80 105 1233454 29.898 ng 100 78) 4-Ethyltoluene 16.84 105 1133840 28.388 ng 100 79) 1,3,5-Trimethylbenzene 16.91 105 1002406 28.299 ng 100 80) alpha-Methylstyrene 17.06 118 513977 27.536 ng 100 81) 2-Ethyltoluene 17.10 105 1153648 28.523 ng 100 82) 1,2,4-Trimethylbenzene 17.31 105 1036044 29.269 ng 100 83) n-Decane 17.41 57 553112 26.701 ng 100 84) Benzyl Chloride 17.43 91 923648 30.481 ng 100 85) 1,3-Dichlorobenzene 17.46 146 610057 30.738 ng 100 86) 1,4-Dichlorobenzene 17.52 146 620185 29.582 ng 100 87) sec-Butylbenzene 17.57 105 1340908 29.767 ng 100 88) 4-Isopropyltoluene (p-... 17.72 119 1292763 28.507 ng 100 89) 1,2,3-Trimethylbenzene 17.71 105 1086053 29.925 ng 100 90) 1,2-Dichlorobenzene 17.84 146 586721 30.517 ng 100 91) d-Limonene 17.85 68 380538 27.385 ng 100 92) 1,2-Dibromo-3-Chloropr... 18.26 157 232424 33.264 ng 100 93) n-Undecane 18.61 57 587467 27.302 ng 100 94) 1,2,4-Trichlorobenzene 19.46 180 502262 30.812 ng 100 95) Naphthalene 19.57 128 1401960 27.928 ng 100 96) n-Dodecane 19.58 57 572870 28.314 ng 100 97) Hexachlorobutadiene 19.91 225 351082 32.141 ng 100 98) Cyclohexanone 15.32 55 358324 30.097 ng 100 99) tert-Butylbenzene 17.31 119 1056871 29.523 ng 100 100) n-Butylbenzene 18.12 91 1074955 30.724 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Thu Jun 16 06:57:02 2016 Page: 2

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Data File: I:\MS08\Data\2016_06\15\06151636.D Acq On : 16 Jun 2016 3:16 Operator: WA Sample : 25ng TO-15 ICAL Std Misc : S29-06151601/S29-05241606 (6/22) ALS Vial : 16 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

4600000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,Tn-

Dec

ane,

T1,

2,4-

Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Amyl

Met

hyl E

ther

,T1,

4-D

ifluo

robe

nzen

e (IS

2),IR

Cyc

lohe

xane

,TC

arbo

n Te

trach

lorid

e,T

Benz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,Tn-

Hex

ane,

TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEtha

nol,T

Chl

oroe

than

e,T

Brom

omet

hane

,T1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8061516.M Thu Jun 16 06:57:02 2016 Page: 3

93 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151637.D Acq On : 16 Jun 2016 3:48 Operator: WA Sample : 50ng TO-15 ICAL Std Misc : S29-06151601/S29-05241606 (6/22) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 16 06:40:03 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.81 130 107238 12.500 ng 0.00 37) 1,4-Difluorobenzene (IS2) 10.55 114 500091 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 14.57 82 215035 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.50 65 185456 11.189 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 89.52% 57) Toluene-d8 (SS2) 12.78 98 526259 13.539 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 108.32% 73) Bromofluorobenzene (SS3) 16.07 174 189105 11.873 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 94.96% Target Compounds Qvalue 2) Propene 3.88 42 642320 42.383 ng 99 3) Dichlorodifluoromethan... 3.99 85 1063837 43.540 ng 99 4) Chloromethane 4.20 50 565847 34.856 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.35 135 563503 48.065 ng 100 6) Vinyl Chloride 4.47 62 720991 46.489 ng 99 7) 1,3-Butadiene 4.65 54 606280 50.298 ng 98 8) Bromomethane 4.96 94 451551 51.188 ng 100 9) Chloroethane 5.17 64 408079 45.938 ng 99 10) Ethanol 5.42 45 2003479 212.841 ng 100 11) Acetonitrile 5.61 41 1073429 41.100 ng 99 12) Acrolein 5.72 56 327351 46.422 ng 99 13) Acetone 5.86 58 1920736 215.892 ng 93 14) Trichlorofluoromethane 6.02 101 951189 46.684 ng 99 15) 2-Propanol (Isopropanol) 6.16 45 2725182 85.441 ng 100 16) Acrylonitrile 6.36 53 709748 46.633 ng 99 17) 1,1-Dichloroethene 6.67 96 493111 50.997 ng 95 18) 2-Methyl-2-Propanol (t... 6.76 59 2682344 91.549 ng 98 19) Methylene Chloride 6.81 84 489784 42.968 ng 99 20) 3-Chloro-1-propene (Al... 6.92 41 894489 52.070 ng 99 21) Trichlorotrifluoroethane 7.07 151 487561 52.402 ng 99 22) Carbon Disulfide 7.05 76 1815164 42.594 ng 100 23) trans-1,2-Dichloroethene 7.71 61 804626 51.096 ng 98 24) 1,1-Dichloroethane 7.90 63 968210 47.214 ng 100 25) Methyl tert-Butyl Ether 7.95 73 1716514 48.551 ng 100 26) Vinyl Acetate 8.05 86 750068 252.133 ng # 84 27) 2-Butanone (MEK) 8.25 72 368260 52.589 ng 95 28) cis-1,2-Dichloroethene 8.67 61 761680 49.402 ng 100 29) Diisopropyl Ether 8.85 87 467303 49.567 ng # 92 30) Ethyl Acetate 8.86 61 373168 100.975 ng 99 31) n-Hexane 8.87 57 830233 43.307 ng 100 32) Chloroform 8.94 83 912052 49.974 ng 100 34) Tetrahydrofuran (THF) 9.27 72 344331 47.667 ng 97 35) Ethyl tert-Butyl Ether 9.34 87 700433 49.487 ng 98 36) 1,2-Dichloroethane 9.60 62 785324 49.823 ng 99 38) 1,1,1-Trichloroethane 9.83 97 862044 54.285 ng 99 39) Isopropyl Acetate 10.13 61 631520 111.215 ng # 93 40) 1-Butanol 10.15 56 1229381 119.175 ng 97 41) Benzene 10.24 78 1930557 51.066 ng 100 42) Carbon Tetrachloride 10.38 117 797043 60.575 ng 99 43) Cyclohexane 10.49 84 1660108 99.959 ng 98 44) tert-Amyl Methyl Ether 10.76 73 1611411 53.546 ng 98 45) 1,2-Dichloropropane 10.97 63 515547 52.630 ng 99 46) Bromodichloromethane 11.14 83 762946 59.082 ng 99 47) Trichloroethene 11.18 130 589696 53.518 ng 100 48) 1,4-Dioxane 11.15 88 429304 54.858 ng 100 49) 2,2,4-Trimethylpentane... 11.23 57 2307721 48.153 ng 98

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Wida Ang


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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Amyl

Met

hyl E

ther

,T1,

4-D

ifluo

robe

nzen

e (IS

2),IR

Cyc

lohe

xane

,TC

arbo

n Te

trach

lorid

e,T

Benz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,Tn-

Hex

ane,

TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAcet

onitr

ile,T

Etha

nol,T

Chl

oroe

than

e,T

Brom

omet

hane

,T1,

3-Bu

tadi

ene,

TVi

nyl C

hlor

ide,

T1,

2-D

ichl

oro-

1,1,

2,2-

tetra

fluor

oeth

ane

,TC

hlor

omet

hane

,TD

ichl

orod

ifluo

rom

etha

ne (C

FC 1

2),T

Prop

ene,

T

R8061516.M Thu Jun 16 06:57:27 2016 Page: 3

96 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151638.D Acq On : 16 Jun 2016 4:21 Operator: WA Sample : 100ng TO-15 ICAL Std Misc : S29-06151601/S29-05241606 (6/22) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 16 06:40:05 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 06:39:09 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.82 130 119012 12.500 ng 0.02 37) 1,4-Difluorobenzene (IS2) 10.55 114 548080 12.500 ng 0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 228359 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.51 65 194844 10.592 ng 0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 84.72% 57) Toluene-d8 (SS2) 12.78 98 568207 13.765 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 110.16% 73) Bromofluorobenzene (SS3) 16.08 174 201877 11.936 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 95.52% Target Compounds Qvalue 2) Propene 3.88 42 1713529 101.880 ng 99 3) Dichlorodifluoromethan... 3.99 85 2202085 81.209 ng 100 4) Chloromethane 4.20 50 865860 48.060 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.36 135 1235633 94.968 ng 100 6) Vinyl Chloride 4.49 62 1602490 93.106 ng 99 7) 1,3-Butadiene 4.66 54 1354197 101.232 ng 95 8) Bromomethane 4.97 94 962757 98.341 ng 98 9) Chloroethane 5.19 64 877626 89.021 ng 98 10) Ethanol 5.44 45 4166277 398.820 ng 99 11) Acetonitrile 5.63 41 2267362 78.224 ng 100 12) Acrolein 5.73 56 689801 88.145 ng 100 13) Acetone 5.88 58 3966744 401.755 ng 87 14) Trichlorofluoromethane 6.02 101 2038228 90.140 ng 100 15) 2-Propanol (Isopropanol) 6.19 45 4269553 120.617 ng 100 16) Acrylonitrile 6.37 53 1521287 90.065 ng 99 17) 1,1-Dichloroethene 6.68 96 1059099 98.694 ng 93 18) 2-Methyl-2-Propanol (t... 6.78 59 4177519 128.474 ng 99 19) Methylene Chloride 6.82 84 1052969 83.236 ng 96 20) 3-Chloro-1-propene (Al... 6.93 41 1883933 98.817 ng 97 21) Trichlorotrifluoroethane 7.08 151 1059020 102.560 ng 97 22) Carbon Disulfide 7.06 76 3875427 81.942 ng 100 23) trans-1,2-Dichloroethene 7.71 61 1701495 97.360 ng 96 24) 1,1-Dichloroethane 7.91 63 2030871 89.237 ng 99 25) Methyl tert-Butyl Ether 7.95 73 3612982 92.082 ng 100 26) Vinyl Acetate 8.06 86 1615934 489.453 ng # 64 27) 2-Butanone (MEK) 8.26 72 785106 101.024 ng # 91 28) cis-1,2-Dichloroethene 8.68 61 1598472 93.419 ng 97 29) Diisopropyl Ether 8.87 87 989105 94.535 ng # 77 30) Ethyl Acetate 8.87 61 770931 187.968 ng 95 31) n-Hexane 8.87 57 1698833 79.849 ng 99 32) Chloroform 8.95 83 1944036 95.982 ng 99 34) Tetrahydrofuran (THF) 9.27 72 731740 91.277 ng 96 35) Ethyl tert-Butyl Ether 9.34 87 1496703 95.283 ng 95 36) 1,2-Dichloroethane 9.60 62 1628236 93.080 ng 100 38) 1,1,1-Trichloroethane 9.84 97 1819864 104.567 ng 99 39) Isopropyl Acetate 10.14 61 1328763 213.515 ng # 85 40) 1-Butanol 10.17 56 2578747 228.092 ng 94 41) Benzene 10.25 78 4108667 99.164 ng 100 42) Carbon Tetrachloride 10.38 117 1691637 117.306 ng 99 43) Cyclohexane 10.50 84 3526710 193.759 ng 95 44) tert-Amyl Methyl Ether 10.76 73 3365591 102.043 ng 98 45) 1,2-Dichloropropane 10.98 63 1095464 102.039 ng 99 46) Bromodichloromethane 11.14 83 1623860 114.740 ng 100 47) Trichloroethene 11.19 130 1289220 106.760 ng 100 48) 1,4-Dioxane 11.16 88 926905 108.073 ng 98 49) 2,2,4-Trimethylpentane... 11.24 57 4793385 91.261 ng 97

R8061516.M Thu Jun 16 06:57:52 2016 Page: 1

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Wida Ang


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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T1,

2,3-

Trim

ethy

lben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Amyl

Met

hyl E

ther

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ifluo

robe

nzen

e (IS

2),IR

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lohe

xane

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n Te

trach

lorid

e,T

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ene,

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nol,T

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ropy

l Ace

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ane,

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ichl

oroe

than

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ane-

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S1),S

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l ter

t-But

yl E

ther

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drof

uran

(TH

F),T

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orm

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ane,

TEt

hyl A

ceta

te,T

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opro

pyl E

ther

,TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-Pr

opan

ol (I

sopr

opan

ol),T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

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ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R8061516.M Thu Jun 16 06:57:52 2016 Page: 3

99 of 113

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151639.D Acq On : 16 Jun 2016 4:53 Operator: WA Sample : 25ng TO-15 ICV Std Misc : S29-06151601/S29-06131603 (7/11) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jun 16 07:16:41 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.81 130 123548 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.54 114 571341 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 14.57 82 239875 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.49 65 205101 11.797 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 94.40% 57) Toluene-d8 (SS2) 12.77 98 599570 12.633 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.04% 73) Bromofluorobenzene (SS3) 16.07 174 214728 12.493 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.92% Target Compounds Qvalue 2) Propene 3.87 42 325361 22.319 ng 98 3) Dichlorodifluoromethan... 3.98 85 552386 21.528 ng 100 4) Chloromethane 4.18 50 414884 30.144 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.34 135 318780 27.534 ng 100 6) Vinyl Chloride 4.46 62 436127 28.415 ng 99 7) 1,3-Butadiene 4.64 54 355407 31.313 ng 97 8) Bromomethane 4.94 94 263688 30.382 ng 99 9) Chloroethane 5.16 64 238112 26.579 ng 99 10) Ethanol 5.39 45 1179858 135.709 ng 100 11) Acetonitrile 5.58 41 608897 27.241 ng 99 12) Acrolein 5.71 56 181107 26.189 ng 99 13) Acetone 5.84 58 1156245 120.178 ng 88 14) Trichlorofluoromethane 6.00 101 516521 22.423 ng 100 15) 2-Propanol (Isopropanol) 6.14 45 1733099 58.217 ng 98 16) Acrylonitrile 6.34 53 417544 28.412 ng 100 17) 1,1-Dichloroethene 6.65 96 287115 29.058 ng 92 18) 2-Methyl-2-Propanol (t... 6.74 59 1715453 56.630 ng 99 19) Methylene Chloride 6.79 84 287484 30.527 ng 97 20) 3-Chloro-1-propene (Al... 6.91 41 507823 29.289 ng 98 21) Trichlorotrifluoroethane 7.06 151 278517 27.326 ng 100 22) Carbon Disulfide 7.04 76 987562 22.132 ng 100 23) trans-1,2-Dichloroethene 7.70 61 447816 27.746 ng 96 24) 1,1-Dichloroethane 7.89 63 548822 25.976 ng 100 25) Methyl tert-Butyl Ether 7.93 73 980302 26.327 ng 99 26) Vinyl Acetate 8.03 86 423783 140.597 ng # 86 27) 2-Butanone (MEK) 8.24 72 212117 27.713 ng # 91 28) cis-1,2-Dichloroethene 8.66 61 434631 28.264 ng 98 29) Diisopropyl Ether 8.85 87 256243 26.120 ng # 95 30) Ethyl Acetate 8.85 61 206914 54.451 ng 98 31) n-Hexane 8.86 57 438116 22.821 ng 100 32) Chloroform 8.92 83 522000 26.664 ng 100 34) Tetrahydrofuran (THF) 9.26 72 206573 28.031 ng 97 35) Ethyl tert-Butyl Ether 9.33 87 404452 26.870 ng 96 36) 1,2-Dichloroethane 9.59 62 432507 25.405 ng 99 38) 1,1,1-Trichloroethane 9.82 97 481728 25.418 ng 99 39) Isopropyl Acetate 10.12 61 362091 59.511 ng # 92 40) 1-Butanol 10.13 56 721390 66.032 ng 94 41) Benzene 10.24 78 1094792 24.999 ng 100 42) Carbon Tetrachloride 10.37 117 436009 27.392 ng 99 43) Cyclohexane 10.48 84 950515 51.741 ng 98 44) tert-Amyl Methyl Ether 10.75 73 929048 27.071 ng 98 45) 1,2-Dichloropropane 10.96 63 295867 27.072 ng 99 46) Bromodichloromethane 11.13 83 421035 27.942 ng 100 47) Trichloroethene 11.18 130 330046 26.117 ng 100 48) 1,4-Dioxane 11.14 88 254959 28.736 ng 99 49) 2,2,4-Trimethylpentane... 11.23 57 1347342 25.922 ng 96

R8061516.M Thu Jun 16 07:35:55 2016 Page: 1

100 of 113

widayati.ang

Wida Ang

Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\15\06151639.D Acq On : 16 Jun 2016 4:53 Operator: WA Sample : 25ng TO-15 ICV Std Misc : S29-06151601/S29-06131603 (7/11) ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jun 16 07:16:41 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.33 100 267500 56.307 ng 97 51) n-Heptane 11.45 71 286572 25.435 ng 99 52) cis-1,3-Dichloropropene 11.95 75 480770 28.554 ng 100 53) 4-Methyl-2-pentanone 11.97 58 299833 29.081 ng 96 54) trans-1,3-Dichloropropene 12.42 75 467001 28.345 ng 99 55) 1,1,2-Trichloroethane 12.59 97 286279 28.746 ng 100 58) Toluene 12.87 91 1203399 26.606 ng 99 59) 2-Hexanone 13.07 43 789045 29.597 ng 98 60) Dibromochloromethane 13.26 129 364342 31.431 ng 99 61) 1,2-Dibromoethane 13.50 107 333818 28.106 ng 99 62) n-Butyl Acetate 13.67 43 889375 30.528 ng 98 63) n-Octane 13.80 57 263219 26.771 ng 99 64) Tetrachloroethene 13.95 166 375155 24.510 ng 99 65) Chlorobenzene 14.62 112 843169 27.488 ng 99 66) Ethylbenzene 14.99 91 1421558 27.116 ng 99 67) m- & p-Xylenes 15.17 91 2238765 53.279 ng 99 68) Bromoform 15.25 173 337861 28.572 ng 100 69) Styrene 15.53 104 920989 31.474 ng 99 70) o-Xylene 15.64 91 1150392 26.108 ng 100 71) n-Nonane 15.85 43 682048 25.314 ng 98 72) 1,1,2,2-Tetrachloroethane 15.61 83 516302 28.006 ng 100 74) Cumene 16.21 105 1493424 26.129 ng 100 75) alpha-Pinene 16.59 93 759030 27.766 ng 97 76) n-Propylbenzene 16.70 91 1728968 24.846 ng 99 77) 3-Ethyltoluene 16.80 105 1525913 27.558 ng 100 78) 4-Ethyltoluene 16.84 105 1408088 26.141 ng 100 79) 1,3,5-Trimethylbenzene 16.91 105 1252955 26.191 ng 99 80) alpha-Methylstyrene 17.06 118 685467 30.018 ng 100 81) 2-Ethyltoluene 17.10 105 1433755 26.586 ng 100 82) 1,2,4-Trimethylbenzene 17.31 105 1294909 27.552 ng 99 83) n-Decane 17.41 57 670675 25.580 ng 100 84) Benzyl Chloride 17.43 91 1162748 30.410 ng 100 85) 1,3-Dichlorobenzene 17.46 146 762695 28.845 ng 100 86) 1,4-Dichlorobenzene 17.52 146 759221 27.481 ng 100 87) sec-Butylbenzene 17.57 105 1633055 26.828 ng 100 88) 4-Isopropyltoluene (p-... 17.72 119 1614485 26.673 ng 98 89) 1,2,3-Trimethylbenzene 17.71 105 1323085 26.864 ng 99 90) 1,2-Dichlorobenzene 17.84 146 731349 28.010 ng 99 91) d-Limonene 17.85 68 483926 31.628 ng 100 92) 1,2-Dibromo-3-Chloropr... 18.26 157 289549 27.724 ng 95 93) n-Undecane 18.61 57 700350 26.237 ng 100 94) 1,2,4-Trichlorobenzene 19.46 180 623551 29.565 ng 99 95) Naphthalene 19.57 128 1801829 30.878 ng 100 96) n-Dodecane 19.58 57 716013 29.236 ng 99 97) Hexachlorobutadiene 19.91 225 412399 27.089 ng 99 98) Cyclohexanone 15.32 55 468754 30.763 ng 97 99) tert-Butylbenzene 17.31 119 1295645 26.726 ng 100 100) n-Butylbenzene 18.12 91 1295595 27.931 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Thu Jun 16 07:35:55 2016 Page: 2

101 of 113


Data File: I:\MS08\Data\2016_06\15\06151639.D Acq On : 16 Jun 2016 4:53 Operator: WA Sample : 25ng TO-15 ICV Std Misc : S29-06151601/S29-06131603 (7/11) ALS Vial : 1 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.000

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400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

3800000

4000000

4200000

4400000

4600000

4800000

5000000

5200000

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Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

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hlor

oben

zene

,Tn-U

ndec

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2-D

ibro

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3-C

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opro

pane

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Buty

lben

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onen

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ropy

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imet

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ne,T

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ltolu

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Tal

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hyls

tyre

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imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

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ne,T

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ene,

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omof

luor

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(SS3

),Sn-

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ane,

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ne,T

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chlo

roet

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p-X

ylen

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lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

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chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

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than

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rom

ochl

orom

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ne,T

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one,

TTo

luen

e,T

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ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

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trans

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-Dic

hlor

opro

pene

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4-M

ethy

l-2-p

enta

none

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s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

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hyl M

etha

cryl

ate,

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lpen

tane

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octa

ne),T

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hlor

oeth

ene,

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ne,T

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odic

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omet

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l Ace

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T

R8061516.M Thu Jun 16 07:35:56 2016 Page: 3

102 of 113

Page 1 of 2 I:\MS08\0-Instrument Info\0-Security Certificates\ICV_07141501_REV1.CRT 6/16/2016 7:36 AM

INITIAL CALIBRATION VERIFICATION CHECK SHEET

Data File Name: 06151639.D Acq. Method File: TO15.M

Data File Path: I:\MS08\Data\2016_06\15\ Sample Name: 25ng TO-15 ICV Std

Operator: WA Misc Info: S29-06151601/S29-06131603 (

Date Acquired: 6/16/2016 4:53 Instrument Name: Instrument #MS08

Compound Ret. Amt. Spike % Lower Upper * OR

# Name Time (ng) Amt.(ng) Rec. Limit Limit Fail

2) Propene 3.87 22.3 24.50 91 70 130 *3) Dichlorodifluoromethane (CFC 12 3.98 21.5 23.50 91 70 130 *

4) Chloromethane 4.18 30.1 25.00 120 70 130 *

5) 1,2-Dichloro-1,1,2,2-tetrafluoroeth 4.34 27.5 25.50 108 70 130 *

6) Vinyl Chloride 4.46 28.4 25.00 114 70 130 *

7) 1,3-Butadiene 4.64 31.3 25.75 122 70 130 *

8) Bromomethane 4.94 30.4 25.25 120 70 130 *

9) Chloroethane 5.16 26.6 25.00 106 70 130 *

10) Ethanol 5.39 136 124.75 109 70 130 *

11) Acetonitrile 5.58 27.2 26.50 103 70 130 *

12) Acrolein 5.71 26.2 26.75 98 70 130 *

13) Acetone 5.84 120 134.75 89 70 130 *

14) Trichlorofluoromethane 6.00 22.4 27.00 83 70 130 *

15) 2-Propanol (Isopropanol) 6.14 58.2 52.25 111 70 130 *

16) Acrylonitrile 6.34 28.4 26.50 107 70 130 *

17) 1,1-Dichloroethene 6.65 29.1 27.00 108 70 130 *

18) 2-Methyl-2-Propanol (tert-Butyl Alco 6.74 56.6 50.00 113 70 130 *19) Methylene Chloride 6.79 30.5 27.75 110 70 130 *

20) 3-Chloro-1-propene (Allyl Chlorid 6.91 29.3 27.25 108 70 130 *

21) Trichlorotrifluoroethane 7.06 27.3 27.50 99 70 130 *

22) Carbon Disulfide 7.04 22.1 26.25 84 70 130 *

23) trans-1,2-Dichloroethene 7.70 27.7 26.25 106 70 130 *

24) 1,1-Dichloroethane 7.89 26.0 26.50 98 70 130 *

25) Methyl tert-Butyl Ether 7.93 26.3 27.00 97 70 130 *

26) Vinyl Acetate 8.03 141 129.75 109 70 130 *

27) 2-Butanone (MEK) 8.24 27.7 27.50 101 70 130 *

28) cis-1,2-Dichloroethene 8.66 28.3 27.25 104 70 130 *

29) Diisopropyl Ether 8.85 26.1 27.00 97 70 130 *30) Ethyl Acetate 8.85 54.5 53.50 102 70 130 *31) n-Hexane 8.86 22.8 26.50 86 70 130 *

32) Chloroform 8.92 26.7 28.00 95 70 130 *

34) Tetrahydrofuran (THF) 9.26 28.0 27.50 102 70 130 *35) Ethyl tert-Butyl Ether 9.33 26.9 26.75 101 70 130 *36) 1,2-Dichloroethane 9.59 25.4 26.75 95 70 130 *

38) 1,1,1-Trichloroethane 9.82 25.4 26.25 97 70 130 *

39) Isopropyl Acetate 10.12 59.5 57.25 104 70 130 *40) 1-Butanol 10.13 66.0 51.25 129 70 130 *41) Benzene 10.24 25.0 28.25 88 70 130 *

42) Carbon Tetrachloride 10.37 27.4 28.75 95 70 130 *

43) Cyclohexane 10.48 51.7 53.00 98 70 130 *44) tert-Amyl Methyl Ether 10.75 27.1 26.75 101 70 130 *

45) 1,2-Dichloropropane 10.96 27.1 27.00 100 70 130 *

46) Bromodichloromethane 11.13 27.9 27.25 102 70 130 *

47) Trichloroethene 11.18 26.1 27.00 97 70 130 *

48) 1,4-Dioxane 11.14 28.7 26.25 109 70 130 *

49) 2,2,4-Trimethylpentane (Isooctane) 11.23 25.9 26.75 97 70 130 *

103 of 113

widayati.ang

Wida Ang

Page 2 of 2 I:\MS08\0-Instrument Info\0-Security Certificates\ICV_07141501_REV1.CRT 6/16/2016 7:36 AM

INITIAL CALIBRATION VERIFICATION CHECK SHEET

Data File Name: 06151639.D Acq. Method File: TO15.M

Data File Path: I:\MS08\Data\2016_06\15\ Sample Name: 25ng TO-15 ICV Std

Operator: WA Misc Info: S29-06151601/S29-06131603 (

Date Acquired: 6/16/2016 4:53 Instrument Name: Instrument #MS08

Compound Ret. Amt. Spike % Lower Upper * OR

# Name Time (ng) Amt.(ng) Rec. Limit Limit Fail

50) Methyl Methacrylate 11.33 56.3 52.75 107 70 130 *51) n-Heptane 11.45 25.4 27.00 94 70 130 *52) cis-1,3-Dichloropropene 11.95 28.6 26.00 110 70 130 *

53) 4-Methyl-2-pentanone 11.97 29.1 27.50 106 70 130 *

54) trans-1,3-Dichloropropene 12.42 28.3 26.25 108 70 130 *

55) 1,1,2-Trichloroethane 12.59 28.7 27.00 106 70 130 *

58) Toluene 12.87 26.6 27.25 98 70 130 *

59) 2-Hexanone 13.07 29.6 27.50 108 70 130 *

60) Dibromochloromethane 13.26 31.4 27.50 114 70 130 *

61) 1,2-Dibromoethane 13.50 28.1 27.25 103 70 130 *

62) n-Butyl Acetate 13.67 30.5 28.25 108 70 130 *

63) n-Octane 13.80 26.8 26.25 102 70 130 *64) Tetrachloroethene 13.95 24.5 25.25 97 70 130 *

65) Chlorobenzene 14.62 27.5 27.50 100 70 130 *

66) Ethylbenzene 14.99 27.1 27.25 99 70 130 *

67) m- & p-Xylenes 15.17 53.3 53.50 100 70 130 *

68) Bromoform 15.25 28.6 28.50 100 70 130 *

69) Styrene 15.53 31.5 27.75 114 70 130 *

70) o-Xylene 15.64 26.1 26.25 99 70 130 *

71) n-Nonane 15.85 25.3 25.50 99 70 130 *

72) 1,1,2,2-Tetrachloroethane 15.61 28.0 26.25 107 70 130 *

74) Cumene 16.21 26.1 26.00 100 70 130 *

75) alpha-Pinene 16.59 27.8 26.50 105 70 130 *

76) n-Propylbenzene 16.70 24.8 25.50 97 70 130 *77) 3-Ethyltoluene 16.80 27.6 26.75 103 70 130 *78) 4-Ethyltoluene 16.84 26.1 26.75 98 70 130 *

79) 1,3,5-Trimethylbenzene 16.91 26.2 26.75 98 70 130 *

80) alpha-Methylstyrene 17.06 30.0 26.25 114 70 130 *81) 2-Ethyltoluene 17.10 26.6 26.75 99 70 130 *82) 1,2,4-Trimethylbenzene 17.31 27.6 27.25 101 70 130 *

83) n-Decane 17.41 25.6 26.25 98 70 130 *84) Benzyl Chloride 17.43 30.4 27.50 111 70 130 *

85) 1,3-Dichlorobenzene 17.46 28.8 28.50 101 70 130 *

86) 1,4-Dichlorobenzene 17.52 27.5 26.00 106 70 130 *

87) sec-Butylbenzene 17.57 26.8 27.25 98 70 130 *88) 4-Isopropyltoluene (p-Cymene) 17.72 26.7 26.00 103 70 130 *89) 1,2,3-Trimethylbenzene 17.71 26.9 26.50 102 70 130 *90) 1,2-Dichlorobenzene 17.84 28.0 27.50 102 70 130 *

91) d-Limonene 17.85 31.6 26.25 120 70 130 *

92) 1,2-Dibromo-3-Chloropropane 18.26 27.7 27.25 102 70 130 *

93) n-Undecane 18.61 26.2 25.25 104 70 130 *94) 1,2,4-Trichlorobenzene 19.46 29.6 28.75 103 70 130 *

95) Naphthalene 19.57 30.9 27.25 113 70 130 *

96) n-Dodecane 19.58 29.2 27.25 107 70 130 *97) Hexachlorobutadiene 19.91 27.1 28.75 94 70 130 *98) Cyclohexanone 15.32 30.8 27.50 112 70 130 *99) tert-Butylbenzene 17.31 26.7 26.75 100 70 130 *

100) n-Butylbenzene 18.12 27.9 28.00 100 70 130 *

Bold = 75 Compound List

* = Pass

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Evaluate Continuing Calibration Report Data File: I:\MS08\Data\2016_06\21\06211604.D Acq On : 21 Jun 2016 8:48 Operator: WA Sample : CCV R8062116_5ng Misc : S29-06151601/S29-06081607 (7/7) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 21 09:59:08 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 1 IR Bromochloromethane (IS1) 1.000 1.000 0.0 139 -0.03 2 T Propene 1.475 1.287 12.7 128 0.00 3 T Dichlorodifluoromethane (CF 2.596 2.243 13.6 116 0.00 4 T Chloromethane 1.392 1.254 9.9 107 -0.02 5 T 1,2-Dichloro-1,1,2,2-tetraf 1.171 1.081 7.7 130 0.00 6 T Vinyl Chloride 1.553 1.473 5.2 129 -0.02 7 T 1,3-Butadiene 1.148 1.081 5.8 131 -0.02 8 T Bromomethane 0.878 0.944 -7.5 138 -0.02 9 T Chloroethane 0.906 0.888 2.0 132 -0.02 10 T Ethanol 0.880 0.849 3.5 127 -0.08 11 T Acetonitrile 2.262 2.254 0.4 127 -0.06 12 T Acrolein 0.700 0.629 10.1 117 -0.03 13 T Acetone 0.973 0.838 13.9 128 -0.05 14 T Trichlorofluoromethane 2.331 2.041 12.4 120 -0.02 15 T 2-Propanol (Isopropanol) 3.012 2.823 6.3 115 -0.06 16 T Acrylonitrile 1.487 1.474 0.9 130 -0.04 17 T 1,1-Dichloroethene 1.000 0.992 0.8 130 -0.02 18 T 2-Methyl-2-Propanol (tert-B 3.065 2.803 8.5 115 -0.06 19 T Methylene Chloride 0.953 0.987 -3.6 131 -0.04 20 T 3-Chloro-1-propene (Allyl C 1.754 1.586 9.6 123 -0.03 21 T Trichlorotrifluoroethane 1.031 0.966 6.3 128 -0.02 22 T Carbon Disulfide 4.515 4.073 9.8 130 -0.02 23 T trans-1,2-Dichloroethene 1.633 1.561 4.4 123 -0.03 24 T 1,1-Dichloroethane 2.138 1.944 9.1 123 -0.03 25 T Methyl tert-Butyl Ether 3.767 3.452 8.4 125 -0.02 26 T Vinyl Acetate 0.305 0.267 12.5 116 -0.04 27 T 2-Butanone (MEK) 0.774 0.751 3.0 131 -0.03 28 T cis-1,2-Dichloroethene 1.556 1.481 4.8 123 -0.03 29 T Diisopropyl Ether 0.993 0.905 8.9 127 -0.02 30 T Ethyl Acetate 0.384 0.368 4.2 129 -0.03 31 T n-Hexane 1.942 1.770 8.9 128 -0.01 32 T Chloroform 1.981 1.786 9.8 123 -0.03 33 S 1,2-Dichloroethane-d4(SS1) 1.759 1.615 8.2 121 -0.02 34 T Tetrahydrofuran (THF) 0.746 0.698 6.4 125 -0.01 35 T Ethyl tert-Butyl Ether 1.523 1.418 6.9 126 -0.02 36 T 1,2-Dichloroethane 1.722 1.510 12.3 115 -0.02 37 IR 1,4-Difluorobenzene (IS2) 1.000 1.000 0.0 136 -0.02 38 T 1,1,1-Trichloroethane 0.415 0.384 7.5 122 -0.02 39 T Isopropyl Acetate 0.133 0.133 0.0 127 -0.02 40 T 1-Butanol 0.239 0.248 -3.8 126 -0.04 41 T Benzene 0.958 0.818 14.6 128 -0.02 42 T Carbon Tetrachloride 0.348 0.322 7.5 122 -0.02 43 T Cyclohexane 0.402 0.376 6.5 128 -0.02 44 T tert-Amyl Methyl Ether 0.751 0.713 5.1 125 -0.01 45 T 1,2-Dichloropropane 0.239 0.229 4.2 129 -0.02 46 T Bromodichloromethane 0.330 0.314 4.8 124 -0.02 47 T Trichloroethene 0.276 0.261 5.4 130 -0.02 48 T 1,4-Dioxane 0.194 0.184 5.2 128 -0.02 49 T 2,2,4-Trimethylpentane (Iso 1.137 1.062 6.6 127 -0.01 50 T Methyl Methacrylate 0.104 0.103 1.0 130 -0.02 51 T n-Heptane 0.247 0.229 7.3 129 -0.01 52 T cis-1,3-Dichloropropene 0.368 0.364 1.1 124 -0.01 53 T 4-Methyl-2-pentanone 0.226 0.218 3.5 126 -0.02 54 T trans-1,3-Dichloropropene 0.360 0.341 5.3 123 -0.01

R8061516.M Tue Jun 21 11:08:34 2016 Page: 1

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Evaluate Continuing Calibration Report Data File: I:\MS08\Data\2016_06\21\06211604.D Acq On : 21 Jun 2016 8:48 Operator: WA Sample : CCV R8062116_5ng Misc : S29-06151601/S29-06081607 (7/7) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 21 09:59:08 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 55 T 1,1,2-Trichloroethane 0.218 0.210 3.7 125 -0.01 56 IR Chlorobenzene-d5 (IS3) 1.000 1.000 0.0 136 0.00 57 S Toluene-d8 (SS2) 2.473 2.457 0.6 136 0.00 58 T Toluene 2.357 2.137 9.3 127 -0.01 59 T 2-Hexanone 1.389 1.319 5.0 121 -0.02 60 T Dibromochloromethane 0.604 0.611 -1.2 129 -0.01 61 T 1,2-Dibromoethane 0.619 0.571 7.8 126 0.00 62 T n-Butyl Acetate 1.518 1.426 6.1 117 0.00 63 T n-Octane 0.512 0.486 5.1 126 -0.01 64 T Tetrachloroethene 0.798 0.713 10.7 126 0.00 65 T Chlorobenzene 1.598 1.456 8.9 127 0.00 66 T Ethylbenzene 2.732 2.483 9.1 124 0.00 67 T m- & p-Xylenes 2.190 1.959 10.5 123 -0.01 68 T Bromoform 0.616 0.588 4.5 127 -0.01 69 T Styrene 1.525 1.542 -1.1 128 -0.01 70 T o-Xylene 2.296 2.069 9.9 123 -0.01 71 T n-Nonane 1.404 1.243 11.5 118 0.00 72 T 1,1,2,2-Tetrachloroethane 0.961 0.939 2.3 124 -0.01 73 S Bromofluorobenzene (SS3) 0.896 0.932 -4.0 141 0.00 74 T Cumene 2.978 2.760 7.3 123 -0.01 75 T alpha-Pinene 1.425 1.364 4.3 125 0.00 76 T n-Propylbenzene 3.626 3.293 9.2 123 0.00 77 T 3-Ethyltoluene 2.885 2.616 9.3 123 0.00 78 T 4-Ethyltoluene 2.807 2.564 8.7 122 -0.01 79 T 1,3,5-Trimethylbenzene 2.493 2.239 10.2 122 0.00 80 T alpha-Methylstyrene 1.190 1.236 -3.9 139 -0.01 81 T 2-Ethyltoluene 2.810 2.579 8.2 124 0.00 82 T 1,2,4-Trimethylbenzene 2.449 2.228 9.0 122 -0.01 83 T n-Decane 1.366 1.249 8.6 118 -0.01 84 T Benzyl Chloride 1.992 1.780 10.6 120 -0.01 85 T 1,3-Dichlorobenzene 1.378 1.269 7.9 121 -0.01 86 T 1,4-Dichlorobenzene 1.440 1.306 9.3 121 -0.01 87 T sec-Butylbenzene 3.172 2.913 8.2 122 -0.01 88 T 4-Isopropyltoluene (p-Cymen 3.154 2.927 7.2 121 -0.01 89 T 1,2,3-Trimethylbenzene 2.566 2.311 9.9 119 -0.01 90 T 1,2-Dichlorobenzene 1.361 1.238 9.0 121 -0.01 91 T d-Limonene 0.797 0.881 -10.5 133 0.00 92 T 1,2-Dibromo-3-Chloropropane 0.544 0.499 8.3 122 0.00 93 T n-Undecane 1.391 1.305 6.2 117 0.00 94 T 1,2,4-Trichlorobenzene 1.099 1.007 8.4 116 0.00 95 T Naphthalene 3.041 2.791 8.2 116 0.00 96 T n-Dodecane 1.276 1.264 0.9 116 0.00 97 T Hexachlorobutadiene 0.793 0.735 7.3 120 0.00 98 T Cyclohexanone 0.794 0.768 3.3 120 -0.02 99 T tert-Butylbenzene 2.526 2.276 9.9 122 -0.01 100 T n-Butylbenzene 2.417 2.240 7.3 119 0.00 -------------------------------------------------------------------------- (#) = Out of Range SPCC's out = 0 CCC's out = 0

R8061516.M Tue Jun 21 11:08:34 2016 Page: 2

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Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211604.D Acq On : 21 Jun 2016 8:48 Operator: WA Sample : CCV R8062116_5ng Misc : S29-06151601/S29-06081607 (7/7) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 21 09:59:08 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.80 130 122789 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.54 114 561009 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 14.57 82 238359 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.48 65 198287 11.475 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 91.84% 57) Toluene-d8 (SS2) 12.77 98 585625 12.418 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 99.36% 73) Bromofluorobenzene (SS3) 16.07 174 222052 13.002 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 104.00% Target Compounds Qvalue 2) Propene 3.88 42 65120 4.495 ng 98 3) Dichlorodifluoromethan... 3.99 85 110145 4.319 ng 99 4) Chloromethane 4.18 50 60363 4.413 ng 98 5) 1,2-Dichloro-1,1,2,2-t... 4.35 135 54702 4.754 ng 100 6) Vinyl Chloride 4.46 62 72327 4.741 ng 100 7) 1,3-Butadiene 4.64 54 56300 4.991 ng 98 8) Bromomethane 4.95 94 46381 5.377 ng 99 9) Chloroethane 5.16 64 44059 4.948 ng 100 10) Ethanol 5.36 45 210908 24.409 ng 100 11) Acetonitrile 5.57 41 112906 5.082 ng 100 12) Acrolein 5.70 56 33076 4.812 ng 97 13) Acetone 5.83 58 221004 23.113 ng 91 14) Trichlorofluoromethane 6.01 101 99259 4.336 ng 100 15) 2-Propanol (Isopropanol) 6.13 45 289817 9.795 ng 99 16) Acrylonitrile 6.33 53 74564 5.105 ng 99 17) 1,1-Dichloroethene 6.65 96 52113 5.307 ng 92 18) 2-Methyl-2-Propanol (t... 6.72 59 287725 9.557 ng 98 19) Methylene Chloride 6.78 84 52379 5.596 ng 93 20) 3-Chloro-1-propene (Al... 6.90 41 84119 4.882 ng 98 21) Trichlorotrifluoroethane 7.06 151 51258 5.060 ng 97 22) Carbon Disulfide 7.04 76 196045 4.421 ng 99 23) trans-1,2-Dichloroethene 7.69 61 81288 5.068 ng 96 24) 1,1-Dichloroethane 7.88 63 99286 4.728 ng 99 25) Methyl tert-Butyl Ether 7.93 73 178016 4.810 ng 99 26) Vinyl Acetate 8.02 86 66473 22.190 ng # 94 27) 2-Butanone (MEK) 8.24 72 39451 5.186 ng 97 28) cis-1,2-Dichloroethene 8.65 61 77838 5.093 ng 97 29) Diisopropyl Ether 8.84 87 48018 4.925 ng 99 30) Ethyl Acetate 8.84 61 38363 10.158 ng 98 31) n-Hexane 8.86 57 90389 4.737 ng 99 32) Chloroform 8.92 83 93886 4.825 ng 100 34) Tetrahydrofuran (THF) 9.26 72 34965 4.774 ng 94 35) Ethyl tert-Butyl Ether 9.33 87 73111 4.887 ng 97 36) 1,2-Dichloroethane 9.58 62 77862 4.602 ng 100 38) 1,1,1-Trichloroethane 9.82 97 88771 4.770 ng 99 39) Isopropyl Acetate 10.12 61 66194 11.080 ng # 94 40) 1-Butanol 10.13 56 125686 11.717 ng 97 41) Benzene 10.23 78 203819 4.740 ng 100 42) Carbon Tetrachloride 10.37 117 77951 4.987 ng 99 43) Cyclohexane 10.48 84 176416 9.780 ng 99 44) tert-Amyl Methyl Ether 10.75 73 166311 4.935 ng 98 45) 1,2-Dichloropropane 10.96 63 54057 5.037 ng 97 46) Bromodichloromethane 11.12 83 75483 5.102 ng 99 47) Trichloroethene 11.17 130 60413 4.869 ng 99 48) 1,4-Dioxane 11.14 88 44580 5.117 ng 99 49) 2,2,4-Trimethylpentane... 11.23 57 245522 4.811 ng 95

R8061516.M Tue Jun 21 11:08:24 2016 Page: 1

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Quantitation Report (QT Reviewed) Data File: I:\MS08\Data\2016_06\21\06211604.D Acq On : 21 Jun 2016 8:48 Operator: WA Sample : CCV R8062116_5ng Misc : S29-06151601/S29-06081607 (7/7) ALS Vial : 16 Sample Multiplier: 1 Quant Time: Jun 21 09:59:08 2016 Quant Method : I:\MS08\Methods\R8061516.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Thu Jun 16 07:00:20 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.32 100 48090 10.309 ng 97 51) n-Heptane 11.45 71 54908 4.963 ng 99 52) cis-1,3-Dichloropropene 11.94 75 91485 5.534 ng 100 53) 4-Methyl-2-pentanone 11.96 58 52933 5.229 ng 96 54) trans-1,3-Dichloropropene 12.42 75 81873 5.061 ng 99 55) 1,1,2-Trichloroethane 12.59 97 49557 5.068 ng 99 58) Toluene 12.86 91 213927 4.760 ng 100 59) 2-Hexanone 13.07 43 139616 5.270 ng 99 60) Dibromochloromethane 13.25 129 64125 5.567 ng 98 61) 1,2-Dibromoethane 13.50 107 58303 4.940 ng 99 62) n-Butyl Acetate 13.67 43 150874 5.212 ng 99 63) n-Octane 13.80 57 47724 4.885 ng 99 64) Tetrachloroethene 13.95 166 67342 4.428 ng 99 65) Chlorobenzene 14.62 112 148575 4.875 ng 100 66) Ethylbenzene 14.99 91 248544 4.771 ng 100 67) m- & p-Xylenes 15.18 91 388465 9.304 ng 100 68) Bromoform 15.24 173 59996 5.106 ng 100 69) Styrene 15.53 104 158787 5.461 ng 99 70) o-Xylene 15.64 91 201196 4.595 ng 99 71) n-Nonane 15.85 43 119721 4.472 ng 98 72) 1,1,2,2-Tetrachloroethane 15.61 83 89514 4.886 ng 98 74) Cumene 16.21 105 265788 4.680 ng 99 75) alpha-Pinene 16.59 93 133974 4.932 ng 100 76) n-Propylbenzene 16.70 91 313937 4.540 ng 98 77) 3-Ethyltoluene 16.80 105 259355 4.714 ng 100 78) 4-Ethyltoluene 16.84 105 256722 4.796 ng 100 79) 1,3,5-Trimethylbenzene 16.91 105 222062 4.671 ng 100 80) alpha-Methylstyrene 17.06 118 121416 5.351 ng 92 81) 2-Ethyltoluene 17.10 105 255763 4.773 ng 100 82) 1,2,4-Trimethylbenzene 17.31 105 220915 4.730 ng 100 83) n-Decane 17.40 57 120321 4.618 ng 99 84) Benzyl Chloride 17.43 91 183307 4.825 ng 100 85) 1,3-Dichlorobenzene 17.45 146 130638 4.972 ng 100 86) 1,4-Dichlorobenzene 17.52 146 130749 4.763 ng 100 87) sec-Butylbenzene 17.56 105 294430 4.868 ng 99 88) 4-Isopropyltoluene (p-... 17.71 119 279070 4.640 ng 99 89) 1,2,3-Trimethylbenzene 17.71 105 229150 4.682 ng 99 90) 1,2-Dichlorobenzene 17.84 146 126277 4.867 ng 100 91) d-Limonene 17.85 68 87329 5.744 ng 99 92) 1,2-Dibromo-3-Chloropr... 18.26 157 49498 4.769 ng 96 93) n-Undecane 18.61 57 125651 4.737 ng 100 94) 1,2,4-Trichlorobenzene 19.46 180 99839 4.764 ng 100 95) Naphthalene 19.57 128 266108 4.589 ng 99 96) n-Dodecane 19.58 57 125327 5.150 ng 100 97) Hexachlorobutadiene 19.90 225 75022 4.959 ng 99 98) Cyclohexanone 15.32 55 81999 5.416 ng 97 99) tert-Butylbenzene 17.31 119 227897 4.731 ng 99 100) n-Butylbenzene 18.12 91 230604 5.003 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R8061516.M Tue Jun 21 11:08:24 2016 Page: 2

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Data File: I:\MS08\Data\2016_06\21\06211604.D Acq On : 21 Jun 2016 8:48 Operator: WA Sample : CCV R8062116_5ng Misc : S29-06151601/S29-06081607 (7/7) ALS Vial : 16 Sample Multiplier: 1


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R8061516.M Tue Jun 21 11:08:25 2016 Page: 3

109 of 113

BFB

Data Path : I:\MS08\Data\2016_06\15\ Data File : 06151629.D Acq On : 15 Jun 2016 23:27 Operator : WA Sample : 12.5ng TO-15 BFB Std Misc : S29-06151601 ALS Vial : 1 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS08\Methods\R8061516.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Jun 16 07:00:20 2016

14.20 14.40 14.60 14.80 15.00 15.20 15.40 15.60 15.80 16.00 16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.000

100000

200000

300000

400000

500000

600000

Time-->


30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

20000

40000

60000

80000

100000

m/z-->

Abundance Average of 16.069 to 16.079 min.: 06151629.D\data.ms (-)17495

75

50

6937 61 878156 14145 117104 130 148 155135 169161

AutoFind: Scans 2317, 2318, 2319; Background Corrected with Scan 2309

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 19.0 | 18923 | PASS || 75 | 95 | 30 | 66 | 50.5 | 50347 | PASS || 95 | 95 | 100 | 100 | 100.0 | 99768 | PASS || 96 | 95 | 5 | 9 | 6.4 | 6384 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 102.1 | 101824 | PASS || 175 | 174 | 4 | 9 | 8.0 | 8174 | PASS || 176 | 174 | 93 | 101 | 97.0 | 98800 | PASS || 177 | 176 | 5 | 9 | 6.5 | 6417 | PASS |----------------------------------------------------------------------

R8061516.M Thu Jun 16 10:28:56 2016 Page: 1

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Wida Ang

BFB

Data Path : I:\MS08\Data\2016_06\21\ Data File : 06211604.D Acq On : 21 Jun 2016 8:48 Operator : WA Sample : CCV R8062116_5ng Misc : S29-06151601/S29-06081607 (7/7) ALS Vial : 16 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS08\Methods\R8061516.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Thu Jun 16 07:00:20 2016

14.20 14.40 14.60 14.80 15.00 15.20 15.40 15.60 15.80 16.00 16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.000

100000

200000

300000

400000

500000

600000

700000

800000

Time-->


30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

20000

40000

60000

80000

100000

120000

m/z-->

Abundance Average of 16.069 to 16.079 min.: 06211604.D\data.ms (-)174

95

75

5069

37 61 878156 14345 117 130106 148 155137111 161

AutoFind: Scans 2317, 2318, 2319; Background Corrected with Scan 2307

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 18.3 | 20517 | PASS || 75 | 95 | 30 | 66 | 49.7 | 55685 | PASS || 95 | 95 | 100 | 100 | 100.0 | 111968 | PASS || 96 | 95 | 5 | 9 | 6.6 | 7339 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 105.2 | 117789 | PASS || 175 | 174 | 4 | 9 | 8.1 | 9516 | PASS || 176 | 174 | 93 | 101 | 96.6 | 113765 | PASS || 177 | 176 | 5 | 9 | 6.7 | 7622 | PASS |----------------------------------------------------------------------

R8061516.M Tue Jun 21 11:08:07 2016 Page: 1

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Date/Time File Name Sample ID Misc Info Operator Vial Comment

29 6/15/16 23:27 06151629.D 12.5ng TO-15 BFB Std S29-06151601 WA 1 Passed

30 6/15/16 23:59 06151630.D 0.08ng TO-15 ICAL Std S29-06151601/S29-05241612 (6/22) WA 14






36 6/16/16 3:16 06151636.D 25ng TO-15 ICAL Std S29-06151601/S29-05241606 (6/22) WA 16



39 6/16/16 4:53 06151639.D 25ng TO-15 ICV Std S29-06151601/S29-06131603 (7/11) WA 1 Passed

40 6/16/16 5:26 06151640.D 25ng TO-15 ICV Std S29-06151601/S29-06131603 (7/11) WA 1 Passed

Saved as R8061516.M; Exception for low levwl: for VC, chloroethane, allyl chloride, 1,2-dibromoethane from 0.2ng --> 100ng

All other compounds good for low level compounds.

Injection Log

Directory: J:\MS08\Data\2016_06\15\

C:\Documents and Settings\widayati.ang\Desktop\Copy of TO17 Run Log Page 1 of 1

112 of 113

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Date/Time File Name Sample ID Misc Info Operator Vial Comment

1 6/21/16 7:11 06211601.D System S29-06151601/S29-05241603 (6/22) WA 15

2 6/21/16 7:43 06211602.D CCVx R8062116_5ng S29-06151601/S29-05241603 (6/22) WA 15 low-pressure

3 6/21/16 8:15 06211603.D CCV C8062116_25ng S29-06151601/S29-06071603 (7/6) WA 1 Passed

4 6/21/16 8:48 06211604.D CCV R8062116_5ng S29-06151601/S29-06081607 (7/7) WA 16 Passed

5 6/21/16 9:20 06211605.D MB R8062116_1000mL S29-06151601_AS00703 WA 1 Passed

6 6/21/16 9:52 06211606.D LCS R8062116_25ng S29-06151601/S29-06131603 (7/11) WA 1 Passed

7 6/21/16 11:05 06211607.D P1603038-004dil (40mL) S29-06151601 WA 8

8 6/21/16 11:37 06211608.D P1603044-001 (25mL) S29-06151601 WA 11 wrong pos.

9 6/21/16 12:09 06211609.D P1603033-001 (100mL) S29-06151601 WA 5

10 6/21/16 12:42 06211610.D P1603033-001dup (100mL) S29-06151601 WA 5 Passed for dup

11 6/21/16 13:14 06211611.D P1603033-002 (100mL) S29-06151601 WA 6

12 6/21/16 13:46 06211612.D P1603044-001 (25mL) S29-06151601 WA 7

13 6/21/16 14:19 06211613.D P1603010-001 (400mL) S29-06151601 WA 9

14 6/21/16 14:57 06211614.D P1603044-001dil (5.0mL) S29-06151601 WA 4

15 6/21/16 15:30 06211615.D P1603010-002 (200mL) S29-06151601 WA 10

16 6/21/16 16:03 06211616.D P1603010-002dil (50mL) S29-06151601 WA 10

17 6/21/16 16:35 06211617.D P1603013-002 (2.0mL) S29-06151601 WA 4

18 6/21/16 17:07 06211618.D P1603013-001 (25mL)PF2 S29-06151601 WA 10

19 6/21/16 17:40 06211619.D P1603039-001 (1000mL) S29-06151601 WA 2

20 6/21/16 18:13 06211620.D P1603039-002 (1000mL) S29-06151601 WA 3

21 6/21/16 18:45 06211621.D P1602993-001 (400mL) S29-06151601 WA 11

22 6/21/16 19:18 06211622.D P1602994-001 (400mL) S29-06151601 WA 12

23 6/21/16 19:50 06211623.D LCSD R8062116_25ng S29-06151601/S29-06131603 (7/11) WA 1 Passed

Injection Log

Directory: I:\MS08\Data\2016_06\21\

J:\EXCEL\REPORT\TO15\Msd08\MS08day\2016\06\D08062116 Page 1 of 1113 of 113

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ATTACHMENT 5 Tier 2 Screening Risk Assessment Report

(Version 8.0 & Attachment M, Revision March 2016) - Risk Tool (V1.02)

TIER 2 SCREENING RISK ASSESSMENT REPORT(Version 8.0 & Attachment M, Revision Mar 2016 ) - RiskTool (V1.02)

A/N: 123456 Application deemed complete date: 4/1/2016Fac: emaco Superfund Site

2. Tier 2 Data

Equipment Type Other No T-BACTOperation Schedule 24 hours/day; 7 days/week; 52 weeks/yearStack Height 25 ftDistance - Residential 75 mDistance - Commercial 25 mMeteorological Station Pico Rivera

Dispersion Factors tables Point SourceFor Chronic X/Q Table 3For Acute X/Q max Table 6

Dilution Factors

ReceptorΧ/Q

(µg/m³)/(tons/yr)X/Qmax

(µg/m³)/(lbs/hr)Residential 5.234 175.963Commercial - Worker 25.453 507.650

Adjustment and Intake FactorsResidential Worker

Year of Exposure 30Combined Exposure Factor (CEF) - Table 9.1 & 9.2 676.63 56.26

Worker Adjustment Factor (WAF) - Table 10 1 1.00

Tier 2 Report - SCAQMD 2015 Risk Calculator_June16

Page 1 of 11 7/21/2016

A/N: 123456 04/01/16

3. Rule 1401 Compound Data

CompoundR1 -

Uncontrolled (lbs/hr)

R2 - Controlled

(lbs/hr)

CP(mg/kg-day)¯¹

MPMICR

Resident

MP MICR

Worker

MPChronic Resident

MP Chronic Worker

RELChronic(µg/m³)

REL8-hr Chronic

(µg/m³)

RELAcute

(µg/m³)MWAF

1.00 1.00 1.00 1.00 1.00E+03 6.80E+04 15.70E-03 1.00 1.00 1.00 1.00 1

1.00 1.00 1.00 1.00 7.00E+01 17.20E-02 1.00 1.00 1.00 1.00 4.00E+02 14.00E-02 1.00 1.00 1.00 1.00 8.00E+02 12.70E-02 1.00 1.00 1.00 1.00 3.00E+03 3.00E+03 1

5.65E-07 5.65E-07 1.00 1.00 1.00 1.00 1.30E+04 11.00 1.00 1.00 1.00 3.50E-01 7.00E-01 2.50E+00 1

1.00E-01 1.00 1.00 1.00 1.00 3.00E+00 3.00E+00 2.70E+01 11.00 1.00 1.00 1.00 8.00E+02 6.20E+03 1

1.50E-01 1.00 1.00 1.00 1.00 4.00E+01 1.90E+03 11.90E-02 1.00 1.00 1.00 1.00 3.00E+02 1.50E+02 1

5.05E-07 5.05E-07 8.70E-03 1.00 1.00 1.00 1.00 2.00E+03 13.50E-03 1.00 1.00 1.00 1.00 4.00E+02 1.40E+04 1

1.00 1.00 1.00 1.00 7.00E+03 14.75E-07 4.75E-07 1.20E-01 1.00 1.00 1.00 1.00 9.00E+00 1

1.00 1.00 1.00 1.00 3.00E+03 11.00 1.00 1.00 1.00 9.00E+02 2.10E+04 1

2.10E-02 1.00 1.00 1.00 1.00 3.50E+01 2.00E+04 16.54E-07 6.54E-07 1.00 1.00 1.00 1.00 3.00E+02 3.70E+04 1

7.00E-03 1.00 1.00 1.00 1.00 6.00E+02 11.00 1.00 1.00 1.00 2.00E+02 1

1.01E-06 1.01E-06 2.70E-01 1.00 1.00 1.00 1.00 1.80E+05 13.80E-07 3.80E-07 1.00 1.00 1.00 1.00 7.00E+02 2.20E+04 17.13E-07 7.13E-07 1.00 1.00 1.00 1.00 7.00E+02 2.20E+04 1

Application deemed complete date:

StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene

ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)

1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)


Page 2 of 11 7/21/2016

A/N: 123456 04/01/164. Emission Calculations

Compound R1 (lbs/hr) R2 (lbs/hr) R2 (lbs/yr) R2 (tons/yr)

5.65E-07 5.65E-07 4.93E-03 2.47E-06

5.05E-07 5.05E-07 4.41E-03 2.21E-06

4.75E-07 4.75E-07 4.15E-03 2.08E-06

6.54E-07 6.54E-07 5.71E-03 2.86E-06

1.01E-06 1.01E-06 8.83E-03 4.41E-063.80E-07 3.80E-07 3.32E-03 1.66E-067.13E-07 7.13E-07 6.23E-03 3.12E-06

Total 4.30E-06 4.30E-06 3.76E-02 1.88E-05


Vinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)

Propylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl Acetate

Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalene

p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon Disulfide

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)


Page 3 of 11 7/21/2016

TIER 2 RESULTS A/N: 123456 Application deemed complete date: 04/01/16

5a. MICRMICR Resident = CP (mg/(kg-day))^-1 * Q (ton/yr) * (X/Q) Resident * CEF Resident * MP Resident * 1e-6 * MWAFMICR Worker = CP (mg/(kg-day))^-1 * Q (ton/yr) * (X/Q) Worker * CEF Worker* MP Worker* WAF Worker* 1e-6 * MWAF

Compound Residential Commercial

6.80E-11 2.75E-11

8.83E-10 3.57E-10 NO

4.22E-09 1.71E-09

No Cancer Burden, MICR<1.0E-6

Total 5.17E-09 2.09E-09PASS PASS

X/Q for one-in-a-million (µg/m³)/(tons/yr):New Distance at which MICR is 1 in a million (m):

Cancer Burden:

Vinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)

NaphthalenePropylene (Propene)

StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethylene

Carbon Disulfide

5b. Cancer Burden Calculation? NO

Zone Impact Area (km²):Population (7000 person/km²):

Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-Hexane

Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzene

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)


Page 4 of 11 7/21/2016

6. Hazard Index A/N: 123456 04/01/16HIA = [Q(lb/hr) * (X/Q)max * MWAF ]/ Acute RELHIC = [Q(ton/yr) * (X/Q) * MP * MWAF] / Chronic RELHIC 8-hr= [Q(ton/yr) * (X/Q) * WAF * MWAF] / 8-hr Chronic REL

Acute Chronic 8-hr Chronic Acute Pass/Fail

Chronic Pass/Fail

8-hr Chronic Pass/Fail

Alimentary system (liver) - AL 2.81E-08 Pass Pass PassBones and teeth - BN Pass Pass PassCardiovascular system - CV Pass Pass PassDevelopmental - DEV 8.97E-09 2.70E-07 Pass Pass PassEndocrine system - END 2.81E-08 Pass Pass PassEye 5.03E-08 1.74E-07 Pass Pass PassHematopoietic system - HEM Pass Pass PassImmune system - IMM Pass Pass PassKidney - KID 2.81E-08 Pass Pass PassNervous system - NS 3.71E-08 4.16E-07 Pass Pass PassReproductive system - REP 8.97E-09 2.70E-07 Pass Pass PassRespiratory system - RES 5.91E-08 6.29E-06 Pass Pass PassSkin Pass Pass Pass


Target Organs


Page 5 of 11 7/21/2016

A/N: 123456 04/01/166a. Hazard Index Acute - ResidentHIA = [Q(lb/hr) * (X/Q)max resident * MWAF] / Acute REL

HIA - ResidentialCompound AL CV DEV EYE HEM IMM NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone) 7.64E-09 7.64E-09AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 3.11E-09 3.11E-09 3.11E-09 3.11E-09 3.11E-09TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene) 9.88E-10 9.88E-10 9.88E-10o-Xylene 3.04E-09 3.04E-09 3.04E-09Xylenes (Mixed Isomers) 5.70E-09 5.70E-09 5.70E-09

Total 3.11E-09 2.05E-08 1.28E-08 3.11E-09 2.05E-08



Page 6 of 11 7/21/2016

6a. Hazard Index Acute - Worker A/N: 123456 04/01/16HIA = [Q(lb/hr) * (X/Q)max Worker * MWAF] / Acute REL

HIA - CommercialCompound AL CV DEV EYE HEM IMM NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone) 2.20E-08 2.20E-08AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 8.97E-09 8.97E-09 8.97E-09 8.97E-09 8.97E-09TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene) 2.85E-09 2.85E-09 2.85E-09o-Xylene 8.78E-09 8.78E-09Xylenes (Mixed Isomers) 1.65E-08 1.65E-08 1.65E-08

Total 8.97E-09 5.03E-08 3.71E-08 8.97E-09 5.91E-08



Page 7 of 11 7/21/2016

A/N: 123456 04/01/166b. Hazard Index Chronic - ResidentHIC = [Q(ton/yr) * (X/Q) Resident * MP Chronic Resident * MWAF] / Chronic REL

HIC - ResidentialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl Benzene 5.77E-09 5.77E-09 5.77E-09 5.77E-09 5.77E-09Methylene Chloride (Dichloromethane)n-HexaneNaphthalene 1.21E-06Propylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 4.98E-08 4.98E-08 4.98E-08 4.98E-08TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-Xylene 1.24E-08 1.24E-08 1.24E-08Xylenes (Mixed Isomers) 2.33E-08 2.33E-08 2.33E-08

Total 5.77E-09 5.56E-08 5.77E-09 3.57E-08 5.77E-09 8.55E-08 5.56E-08 1.29E-06



Page 8 of 11 7/21/2016

A/N: 123456 04/01/166b. Hazard Index Chronic - WorkerHIC = [Q(ton/yr) * (X/Q) * MP Chronic Worker * MWAF] / Chronic REL

HIC - CommercialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl Benzene 2.81E-08 2.81E-08 2.81E-08 2.81E-08 2.81E-08Methylene Chloride (Dichloromethane)n-HexaneNaphthalene 5.87E-06Propylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)Toluene 2.42E-07 2.42E-07 2.42E-07 2.42E-07TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-Xylene 6.04E-08 6.04E-08 6.04E-08Xylenes (Mixed Isomers) 1.13E-07 1.13E-07 1.13E-07

Total 2.81E-08 2.70E-07 2.81E-08 1.74E-07 2.81E-08 4.16E-07 2.70E-07 6.29E-06



Page 9 of 11 7/21/2016

6c. 8-hour Hazard Index Chronic - Resident A/N: 123456 04/01/16HIC 8-hr = [Q(ton/yr) * (X/Q) Resident * WAF Resident * MWAF] / 8-hr Chronic REL

HIC - ResidentialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)

Total



Page 10 of 11 7/21/2016

A/N: 123456 04/01/166c. 8-hour Hazard Index Chronic - Worker HIC 8-hr = [Q(ton/yr) * (X/Q) Worker * WAF Worker * MWAF] / 8-hr Chronic REL

HIC - CommercialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)

Total



Page 11 of 11 7/21/2016

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