MORPHISTO GmbH Safety Data Sheet · 2021. 1. 18. · 1,5-pentanedial) May cause an allergic skin...

according to Regulation (EC) No 1907/2006

Safety Data SheetMORPHISTO GmbH

Glutaraldehyd Lösung 3%ig, wässrig

Revision date: 17.07.2014 Product code: 12389.xxxxx Page 1 of 9

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Fixierung von Gewebeproben. Use as laboratory reagent. The product is intended for research, analysis and

scientific education.

Not known

Uses advised against

1.3. Details of the supplier of the safety data sheet

MORPHISTO GmbHCompany name:

Street: Weismüllerstr. 45

Place: D-60314 Frankfurt am Main

Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64

[email protected]:

http://www.morphisto.deInternet:

Poison Information Center Mainz, Germany, Tel: +49(0)6131/192401.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008

Hazard categories:

Skin corrosion/irritation: Skin Irrit. 2

Serious eye damage/eye irritation: Eye Dam. 1

Respiratory or skin sensitisation: Resp. Sens. 1

Respiratory or skin sensitisation: Skin Sens. 1

Specific target organ toxicity - single exposure: STOT SE 3

Hazard Statements:

Causes skin irritation.

Causes serious eye damage.

May cause allergy or asthma symptoms or breathing difficulties if inhaled .

May cause an allergic skin reaction.

May cause respiratory irritation.

2.2. Label elements

Regulation (EC) No. 1272/2008

Hazard components for labellingglutaral; glutaraldehyde; 1,5-pentanedial

Signal word: Danger

Pictograms:

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled .

Hazard statements

Print date: 13.02.2020GB - ENRevision No: 1,20

mailto:[email protected]

http://http://www.morphisto.de





H335 May cause respiratory irritation.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P285 In case of inadequate ventilation wear respiratory protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER/doctor.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor.

Precautionary statements

No information available.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

wässrige LösungChemical characterization

Hazardous components

QuantityChemical nameCAS No

EC No Index No REACH No

GHS Classification

1 - < 5 %111-30-8 glutaral; glutaraldehyde; 1,5-pentanedial

203-856-5 605-022-00-X

Acute Tox. 2, Acute Tox. 3, Skin Corr. 1B, Resp. Sens. 1, Skin Sens. 1A, STOT SE 3, Aquatic

Acute 1, Aquatic Chronic 2; H330 H301 H314 H334 H317 H335 H400 H411 EUH071

Full text of H and EUH statements: see section 16.

Further Information

Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article

59 (REACH)

SECTION 4: First aid measures

4.1. Description of first aid measures

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data

sheet if possible).

General information

Provide fresh air. Immediately call a POISON CENTER/doctor/.?. Put victim at rest, cover with a blanket and

keep warm.In case of breathing difficulties administer oxygen. In case of irregular breathing or respiratory

arrest provide artificial respiration.

After inhalation

Beschmutzte, getränkte Kleidung sofort ausziehen. Bei Hautreizungen Arzt aufsuchen.After contact with skin,

wash immediately with: Water and soap.

After contact with skin

In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids

apart. Subsequently consult an ophthalmologist.

After contact with eyes

Rinse mouth thoroughly with water. Immediately call a POISON CENTER/doctor/.?. Let water be drunken in

little sips (dilution effect). Do NOT induce vomiting.

After ingestion






4.2. Most important symptoms and effects, both acute and delayed


4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

The product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.

Suitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2).

In case of fire: Wear self-contained breathing apparatus.

5.3. Advice for firefighters

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Provide adequate ventilation.

@1501.B150087

Do not breathe gas/fumes/vapour/spray.

Wear personal protection equipment. (See section 8. )

Discharge into the environment must be avoided.6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

Treat the recovered material as prescribed in the section on waste disposal .

Mit Wasser nachwischen.

6.3. Methods and material for containment and cleaning up

See protective measures under point 7 and 8.

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

@1501.B150087

Wear suitable protective clothing. ( See section 8. )

Provide adequate ventilation as well as local exhaustion at critical locations.

Use extractor hood (laboratory).

Advice on safe handling

No special fire protection measures are necessary.

Advice on protection against fire and explosion

Conditions to avoid: Generation/formation of aerosols

Further information on handling

7.2. Conditions for safe storage, including any incompatibilities

Keep locked up. Keep container tightly closed and in a well-ventilated place. Recommended storage

temperature: 12°-28°C

Requirements for storage rooms and vessels

Do not store together with: Food and fodder Explosive substances. Infectious substances. Radioactive

Hints on joint storage






substances. Substances which in contact with water, emit flammable gases.

Keep/Store only in original container. Ensure adequate ventilation of the storage area. Store small packages in

a suitable, robust cabinet.

Further information on storage conditions

7.3. Specific end use(s)


SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin

TWA (8 h)0.05Glutaraldehyde111-30-8 0.2 WEL

STEL (15 min)0.05 0.2 WEL

8.2. Exposure controls

Provide adequate ventilation as well as local exhaustion at critical locations. Use extractor hood (laboratory).

refer to chapter 7. No further action is necessary.

Appropriate engineering controls

Always close containers tightly after the removal of product. When using do not eat, drink, smoke, sniff. Wash

hands before breaks and after work. Remove contaminated clothing immediatley and dispose off safely . Wash

contaminated clothing prior to re-use. Used working clothes should not be worn outside the work area. Street

clothing should be stored seperately from work clothing.

Protective and hygiene measures

Suitable eye protection: Tightly sealed safety glasses. DIN EN 166

Eye/face protection

Pull-over gloves of rubber. EN ISO 374

Suitable material:

(penetration time (maximum wearing period): >= 8 Stunden):

CR (polychloroprenes, Chloroprene rubber). (0,5 mm)

NBR (Nitrile rubber). (0,35 mm)

FKM (fluororubber). (0,4 mm)

PVC (Polyvinyl chloride). (0,5 mm)

Butyl rubber. (0,5 mm)

Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them

before taking off and air them well.

Hand protection

Suitable protective clothing: Lab apron.

Skin protection

Respiratory protection necessary at:

exceeding exposure limit values

aerosol or mist generation.

Insufficient ventilation.

insufficient absorbtion.

Suitable respiratory protective equipment:

Respiratory protection






gas filtering equipment (EN 141). Filtertyp : A

@1501.B015774

Environmental exposure controls

colourless

liquidPhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

characteristic stingingOdour:

pH-Value (at 20 °C): 5-6

Changes in the physical state

100 °CInitial boiling point and boiling range:

none

Explosive properties

none

Oxidizing properties

Density: 1,03 g/cm³

Water solubility: completely miscible

3,00 % - @1501.B150227Solvent content:

9.2. Other information


SECTION 10: Stability and reactivity

10.1. Reactivity


10.2. Chemical stability

Stable under normal storage and handling conditions.

10.3. Possibility of hazardous reactions


Keep away from heat.

10.4. Conditions to avoid

Reducing agent. Amines.

10.5. Incompatible materials

Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2).

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution


Acute toxicity

Based on available data, the classification criteria are not met.






Chemical nameCAS No

SourceSpeciesDoseExposure route Method

111-30-8 glutaral; glutaraldehyde; 1,5-pentanedial

RatLD50 200

mg/kgECHA Dossieroral

RabbitLD50 > 2000

mg/kgECHA Dossierdermal

inhalation vapour ATE 0,5 mg/l

inhalation (4 h) aerosol LC50 0,28 mg/l Rat ECHA Dossier

Causes skin irritation.

Causes serious eye damage.

Irritant effect on the eye: irritant.

Irritant effect on the skin: irritant.

Irritation and corrosivity

Sensitising effects

May cause allergy or asthma symptoms or breathing difficulties if inhaled . (glutaral; glutaraldehyde;

1,5-pentanedial)

May cause an allergic skin reaction. (glutaral; glutaraldehyde; 1,5-pentanedial)

Respiratory or skin sensitisation:

People who suffer from skin sensitazion problems, asthma, allergies, chronic or recurring respiratory illnesses

should not be deployed in any process using this preparation.

Carcinogenic/mutagenic/toxic effects for reproduction


Keine signifikante Hinweise vorhanden

STOT-single exposure

May cause respiratory irritation. (glutaral; glutaraldehyde; 1,5-pentanedial)


There are no data available on the preparation/mixture itself.

STOT-repeated exposure

Aspiration hazard


There are no data available on the preparation/mixture itself.

Specific effects in experiment on an animal

SECTION 12: Ecological information

12.1. Toxicity

CAS No Chemical name

[h] | [d]Aquatic toxicity Dose SourceSpecies Method

glutaral; glutaraldehyde; 1,5-pentanedial111-30-8

Acute fish toxicity 96 h ECHA DossierLC50 13 mg/l Lepomis macrochirus

Acute algae toxicity 72 h ECHA DossierErC50 0,6 - 1,2

mg/l

@1201.B120239

Acute crustacea toxicity 48 h ECHA DossierEC50 5,5 mg/l Daphnia magna

Fish toxicity NOEC 1,6 mg/l 97 d Oncorhynchus mykiss ECHA Dossier

Crustacea toxicity NOEC 5 mg/l 21 d daphnia magna ECHA Dossier

12.2. Persistence and degradability






CAS No Chemical name

SourceValueMethod d

Evaluation

glutaral; glutaraldehyde; 1,5-pentanedial111-30-8

OECD 306 0 % 70 ECHA Dossier

Not easily bio-degradable (according to OECD-criteria).

12.3. Bioaccumulative potential

Partition coefficient n-octanol/water

Log PowChemical nameCAS No

111-30-8 -0,36glutaral; glutaraldehyde; 1,5-pentanedial


12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment


Do not allow uncontrolled discharge of product into the environment.

Further information

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations

Dispose of waste according to applicable legislation. Consult the local waste disposal expert about waste

disposal.

List of Wastes Code - residues/unused products

160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and

discarded chemicals; laboratory chemicals, consisting of or containing hazardous substances,

including mixtures of laboratory chemicals; hazardous waste

List of Wastes Code - used product

WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and

discarded chemicals; laboratory chemicals, consisting of or containing hazardous substances,

including mixtures of laboratory chemicals; hazardous waste

160506

List of Wastes Code - contaminated packaging

WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND

PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately

collected municipal packaging waste); packaging containing residues of or contaminated by

hazardous substances; hazardous waste

150110

Non-contaminated packages may be recycled.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

Nicht eingeschränkt14.2. UN proper shipping name:

Inland waterways transport (ADN)

14.2. UN proper shipping name: Nicht eingeschränkt

Marine transport (IMDG)

Nicht eingeschränkt14.2. UN proper shipping name:

Air transport (ICAO-TI/IATA-DGR)






Nicht eingeschränkt

Other applicable information (air transport)

14.5. Environmental hazards

noENVIRONMENTALLY HAZARDOUS:

14.6. Special precautions for user

Refer to section 6-8

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not relevant

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

3 %; VOC Directive 2004/42/EC: 30,9 g/l2004/42/EC (VOC):

Additional information

The preparation is dangerous in the sense of Directive 1999/45/EC.

This preparation is hazardous in the sense of regulation (EC) No 1272/2008 [GHS].

Not subject to regulation 96/82/EC.

National regulatory information

Observe restrictions to employment for juvenils according to the 'juvenile

work protection guideline' (94/33/EC). Observe employment restrictions

under the Maternity Protection Directive (92/85/EEC) for expectant or

nursing mothers. Observe employment restrictions for women of

child-bearing age.

Employment restrictions:

1 - slightly water contaminatingWater contaminating class (D):

Causes allergic hypersensitivity reactions.Skin resorption/Sensitization:

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes

Änderungen:

03.04.2010 Rev.1.0 Neuerstellung

08.04.2010 Rev.1.01 Änderung in Kapitel 15

12.04.2011 Rev. 1.1 Umstellung auf EU VO 453 Anhang I

17.07.2014 Rev 1.2 Revision

Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route ( European Agreement

concerning the

RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer

(Regulations

Concerning the International Transport of Dangerous Goods by Rail )

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)

ICAO: International Civil Aviation Organization

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

OSHA: Occupational Safety and Health Administration






LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent

NOEL: No observed effect level

NOAEL: No observed adverse effect level

LOAEL: Lowest observed adverse effect level

NOAEC: No observed adverse effect level

LOAEC: Lowest observed adverse effect concentration

DNEL: Derived No Effect Level

PNEC: predicted no effect concentration

TSCA: Toxic Substances Control Act

IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER

NTP: National Toxicology Program

SARA: Superfund Amendments and Reauthorization Act

GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)

PBT: Persistent bioaccumulative toxic

SVHC: substance of very high concern

H301 Toxic if swallowed.

H314 Causes severe skin burns and eye damage.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H330 Fatal if inhaled.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled .

H335 May cause respiratory irritation.

H400 Very toxic to aquatic life.

H411 Toxic to aquatic life with long lasting effects.

EUH071 Corrosive to the respiratory tract.

Relevant H and EUH statements (number and full text)

Die Angaben stützen sich auf den heutigen Stand unserer Kenntnisse , sie stellen jedoch keine

Zusicherung von Produkteigenschaften dar und begründen kein vertragliches Rechtsverhältnis.

The above information describes exclusively the safety requirements of the product and is based on our

present-day knowledge. The information is intended to give you advice about the safe handling of the product

named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be

transferred to other products. In the case of mixing the product with other products or in the case of

processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

Bestehende Gesetze und Bestimmungen sind vom Empfänger unserer Produkte in eigener Verantwortung zu

beachten.

Further Information

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety

data sheet.)


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MORPHISTO GmbH Safety Data Sheet · 2021. 1. 18. · 1,5-pentanedial) May cause an allergic skin...

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