M/S. NARAYAN ORGANICS PVT LTD, G.I.D.C....

M/S. NARAYAN ORGANICS PVT LTD, G.I.D.C. ANKLESHWAR, GUJARAT

M/s. Jyoti Om Chemical Research Centre Pvt Ltd 13

ANNEXURE-I PROPOSED TERMS OF REFERENCE

Standard TOR of MoEF&CC for organic sector will be followed.

In exercis~ of the power conferred under section-25of the Water (Pr~"~'1~j9:~.:<.lndControl of pollution) Act-1974, under section·21 of the Air (Prevention and Control of Pollution)Act-198! and Authorization under "Hazardous Waste (Management, Handling & Trans·boundary Movement) Rule-2008.n

iNO' GPCB/ANK-C~&A- 377 (4)/ ID-26102l-('''1{,,) {"

CCA NO: AWH-63764

,r:r'i~'DT: < ., 1~ t(

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And whereas Board has received consolidated application dated 29/4/2014 and inwardno. 80600 for the consolidated consent and authorization (CC& A renewal) of this Board underthe provisions / rules of the aforesaid Acts Consent & Authorization is hereby granted as under.

CONSENT AND AUTHORISATION:

(Under the provisibns / rules of the aforesaid environmental acts)

To.~ARAYAN ORGANICS PVT.LTD .•

PLOT NO: 1107/~& 2,GIDC ESTATE ANKLESHWAR,DIST: BHARUCH.

ConsentOi"der No. ~ AWH- 63764, date of Issue 28/7/2014.The: consent' under Water Act-1974; The consent linder' Ail' Att' .:.;'1981'& 'AUthbtl.zati'6t1under Environment (Protection) Act, 1986 shall be valid up to 11/4/2019 to operateindustrial plant for manufacture of the following products: .

a) Domestic: 1.5 KL/day( b) Industrial: 41 KL/day

3.2 The quantity of total waste water generation shall not exceed 37.0 KL/day. (Break up asbelow).

a) Domestic: - 1.3 KL/dayb) Industrial: ,2,0 ~~/d.~yAmn;t,o.J.l:ical_Nitrogen &.C_~~~~Y.t8.,.;"

i stream & 17 KI/Day diluted process stream.3.3 Sewage shall be disposed ofthmugh septic tank/soak pit system ~

Page!

r" ..- ...I Clean Gujarat Green Gujarat

ISO - 9001 - 2008 & ISO - 14001 - 2004 Certified Organisation

User

Typewritten Text

ANNEXURE-II CCA

3.4 The unit shall affix of water meters as per Section 4 (1) of the water (Prevention andControl of ?ollution) Cess Act - 1977 for the purpose of measuring and recording thequantity of water consumed 'at such places as,may be required, within·15daY~',;andjt,·-- :···~.';:':~~1t;shall be prksumed that the quantity indicated by the meter has been consumed by the •.)industry uIhil the contrary is proved.

3.5 TRADE EFFLUENT,3.5.1 The Geherated 17 KL/Day dilute process stream industrial waste water shall

confirnl to thefollowing standards.

PARAMETERS PERMISSIBLE LIMITH , 5.5 to 8.5

Temnerature 40"CColour (ot.co.scale 100 unitsTotal Suspended Solids 100 m ITotal dissolved solids 2100 m IBOD 3 days at 27°C 30 m ICOD 100 m IOil and Grease 10 m IPhenolicComoounds 1 m ISulphides 0.5 m IAmmonical Nitrogen 50 m IChlorides 600 m ISulohates 1000 m ICyanides' 0.2 m IFlourides 1.5 m IInsecticid es /Pesticides AbsentHexavel€\flt Chromium 0.1 m ITotal Chromium 2.0 m ICODDer . 2 m INickel 3 m IZinc 5 m IMercury; 0.01 m ILead i 0.1 m IArsenic 0.2 m ICadmium 2.0 m IBio-assay test 90 % Survival of fish after

96 hours in 100 % effluent.

3.5,2 The effluent conforming to the above standards shall be discharged in to G.I.D.C.underground drainage system and conveyed to FETP which ultimately leads to deep Seafor final disposal through BEAlLpipeline.

3.5.3 The appliq.nt shall have to make storage facilities to store the effluent for at least 48hours in an impervious acid proof brick lining tank/HDPE tank.

3.5.4 The appli~ant shall have to keep accurate records of quality & quantity of effluentdischarged: to FETP on day-to-day basis. Separate logbook shall be maintained forrecording t!te data & shall be made available for inspection as & when asked.

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,3.5.5 The generated 20 KL/day waste water from Ammonical Nitrogen bearing stream shall

send to MAs. Enviro Technology Limited (ETL) as per agreement made with respectiveauthority at Ankleshwar. (Other conditions relating to CETP member is as under.)

a. The applicant shall be required-to make-storage-fa.cilities to store the·effluent f-or~at-least 48 hours by providing acid proof brick lined impervious tanks/HDPE tanks.

b. The applicant shall make fIxed arrangement for loading the effluent from theircollection tanks to the tanker of ETL The unit shall not keep any by-pass line orsystemior loose or flexible pipe line for loading the effluent into the tanker ofETL.

c. Leachate from the hazardous solid waste, if any shall also be connected into acollection tank through leachate collection facilities and shall be conveyedalong with industrial effluent to the CETP ofETL.

d. Magnetic flow meters shall be installed at the inlet & outlet of effluent collectiontanks/ETP to measure the quantity of effluent lifted into the tanker ofETL.

e. The 17 KL/Day of industrial effluent shall have to be conveyed by ETL. In nocircumstances the effluent either treated or untreated shall be discharged into GIDCdrain o~ anywhere else.Disposal system for storm water shall be provided separately. In no circumstancesstorm water shall be mixed with the industrial effluent.

g. The ap.plicant shall be responsible for loading its effluent into the tankers oft..he ETLfor traqsporting the effluent. Due care shall be taken to avoid any leakage or spillageof effluent during loading the tanker.

h. If the effluent contains heavy metals, phenols & cyanide, the ETL member unit shallhave t~ treat the effluent within its premises to conform to the followingstandards (Whichever applicable).

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GPCB

GUJARAT POLLUTION CONTROL BOARDPARYAVARAN BHAVAN

Sector-10-A, Gandhinagar-382 021 .Website

PARAMETERS

Zinc ZnTotal ChromiumNickel NiMercu HC anide as CNPesticidesPhenolic Com oundsLead PbCo er CuHexavalent·ChromiumCadmium CdArsenic AsSelenium

I ~~~

MI IBLE LIMIT

5.0 m I2.0 m I3.0 m I

0.01 m I0.2 ill IAbsent1.0 ill

0.1 m

3.0 m

O.l-m1.0 m

0.2 m

0.05 ill I

I ;:~~o:'j~ ¥Page 3

Clean Gujarat Green GujaratISO - 9001 - 2008 & ISO - 14001 - 2004 Certified Organisation

III Free ACi.dity

Ammoma

The applicant- shall keep accurate' records 'of "g'lla'ndt}'product, quantity of water consumption, quantity of effluentconsumption of electricity on day to day basis and required to submit thecompli¢d record of one month to GPCB & ETL on or, before fifth day of thesucceeqing month.

j. In case of shut-down of plant for more than three days for any reason, the ETLunit member shall intimate to ETL authority & GPCBwell in advance for the betteroperation & management ofeETP,

k. The applicant shall either stop or curtail its production activities if the effluent isnot adequately treated by the CErp of ETL to conform to the standards specifiedby G,P,c.B.

I. The authorized representative of ETL shall have right of entry at any time forthe purpose of inspection and monitoring the effluent collection facilities/ETP (ifrequired) of the applicant.

m. In case of incinerators, the flow measuring devices for mother liquor/toxiceffluent/Non-biodegradable effluent light diesel oil, Furnace oil, etc. Le. fuelused f9r" combustion, ,air llsedfort;~mb~stion"shall be, separately provideq,lncine~tor temperature recording d~vices as well as ga~eous 'flow '~e~~~ri'~gdevices. for scrubber shall also be provided. These data of temperature & flowshould, be recorded every day & submitted to GPCB& ETLon monthly basis.The G1DCdrainage connection given by the GIDCfor discharge of industrial effluentshall be disconnected & the outlet shall be sealed.

o. If the ETL authority terminates the membership of CETP, the ETL member unitshall have to close down the manufacturing activities/industrial operation of theproces~ plant immediately until the ETLmembership is resumed.

p. The applicant shall also comply with the General Condition (Whichever applicablefrom No.1 to 25) attached herewith.

q. The applicant shall put up at the entrance a board displaying ETL membershipnumber & date of joining of ETL, the name of unit, particulars of the products/proces~ and the name of proprietor/partners /directors of the unit and theelectricity consumer number as on the record ofGEB.

r. The Enrironmental Management Unit/Cell shall be setup to ensure implementationon and monitoring of environment safeguards and other conditions stipulated bystatutoty, authorities. The Environmental Manage~ent Cell.j ,Unit.,.s-Pa.lU!jJ::~pUy,report to the Chief Executive of the organization and shall work as a focal point forinternalizing environmental issued. These Cells also coordinate the exercise ofenvironmental audit and preparation of environmental statements.

s. The Eqvironmental audit shall be out yearly and the environmental statementspertain~jng to the previous year shall be submitting to this State Board latest by 30th

September every year.t The Board reserves the right to revoke and/or revoke the consent and / or make

modifiqations in the con~itions which it seems fit in accor,dance with proyisions ofWater {\ct-1974. "+

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GUJARAT POLLUTION CONTROL BOARDPARYAVARA,N BHAVAN .•. '.' "

Sector-lO-A, Gandl1ina~r'3$2~1~'Website: wwwgpcb,gov,in";,"

In cas~ of change of ownership/management the name and address of the newownertiP/partners/~irectors!~roP_detor should immedi~tely beBoard'

i.

The applicant shall have to submit EVERYMONTH the certified copies(endorsed by ETL) regarding the quantity of industrial effluent (No. of Tankers)delivered per month to CETP of ETL.

w. Unit h~ve to modify / improve performance of existing Effluent treatment facilitiesfor efficiency & adequacy in order to comply with prescribed standards in respectsof effective operation of effluent treatment plant with regards to notification No.P/111(3) Board's standardsj33129 dated 30th October 2001 in fight of High Court inSCANd, 4473 of97 dated 21/02/99,

4. CONDITIONS UNDER THE AIR ACT,4.1 The following shall be used as fuel in the boiler:

Sr; No.FuelNatural Gas

4.2 The applicant IshaB install & operate comprehensive adequate air pollution in order toachieve prescribed norms control system so as to achieve standards.

,4.3 The flue gas ~mission through stack attached to boiler shall conform to the following

standards:

Stack Stack Attached To Stack Height Parameter PermissibleNo. in Meter Limit1- Boiler 0+ TFH 30 Particulate matter 150mg/NM'2 Hot Air Generator 12 50, 100 ppm

NO, 50 oom

4.4 The Process emission through various stacks/vent of reactors, process, vessel shallconform to th~ following standards:

Sr, APCM Stack Air Pollution Control Parameter PermissibleNo attached Height Measures Limit

to1 Glass Line 12 Water Scruber + Ammonia 175 mg/NM3

Reactor 3 Venturi ScrubberNos.

2 Reactor for Not Condensor for Not NotAmmonium Applicable recovery steam to get Applicable Applicable

Sulphate DMWater for reuse

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Clean Gujarat Green GujaratISO - 9001 -2008 & ISO - 14001 - 2004 Certified Organisation

4.5 The concentration of the following parameters'in the ambient air within the premises of theindustry shall pot exceed the limits specified hereunder.

PARAMETERS PERMISSIBLE LIMIT

Suspended Particulate Matter(PMlO) 100 Microgram/M3

RSPM(PM,,) 60 Microgram/M3

SO, 80 Microgram/M3

NO, 80 Microgram/M3

4.6 The applicant shall operate industrial plant / air pollution control equipment very efficiently

and continuously so that the gaseous emission always conforms to the standards specified

in condition no. 4.3 & 4.4 above.

4.7 The consent to operate the industrial plant shall lapse if at any time the parameters of the

gaseous emission are not within the tolerance limits specified in the condition no. 4.3 & 4.5

above.

4.8 The applicant shall provide portholes, ladder, platform etc at chimney(s) for monitoring the

air emissions and the same shall be open for inspection to/and for use of Board's staff. The

chimney(s) vJnts attached to various sources of emission'shall btdlesigT:1ed by numbers

such as S-l, S-2, etc. and these shall be painted/displayed to facilitate identification.

4.9 The Industry shall take adequate measures for control of noise levels from its own sources

within the premises so as to maintain ambient air quality standards in respect of noise to

less than 75 dB(a) during day time and 70 dB (A) during night time. Daytime is reckoned in

between 6a.m( andl0 p.m. and nighttime is reckoned between 10 p.rn. and 6 a.m.

5. GENERALCONDITIONS, -

5.1 Any change in personnel, equipment or working conditions as mentioned in the consents

form/order should immediately be intimated to this Board.

5.2 Applicant shall'also comply with the general conditions given in annexure 1.

5. AUTHORl~ATION FOR THE MANAGEMENT& HANDLING OF HAZARDOUS WASTESForm-2 (5•• rule 3 (c)& 5 (5))

Page 6

Sr, Type of Waste Quantity/ Schedule· I FacilityNo, Month

1 ETP 51uqge 80MT 26,2 Collection, Storage, withinI factory premises and

Transportation and finaldisposal at common TSDF byNEPL Ahmedabad.

2 Used on: 0.05 Lit 5,1 Collection, Storage, withinfactory premises andTransportation and sale toauthorized traders.

3 P.P. Bags: 40.00 Nos. 333 Collection, Storage,Bags/Drums Decontamination.

---"~~~GPCB

I!GUJARAT POLLUTION CONTROL BOARD

PARYAVARAf':J~I-jAVAN,,~,icSettor-10-A, GariOhinagar-3-82"O~1;"i1;i"

Website: wWW-9Pcb_90v_in -

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6.2 ~he a?~lic~~~f~.a.l.l.~nl~ s~ll..~.m~.~~.i~~".~~rbonatesolution to below mentioned industriesfor the recyclingj reuse/re-processing purpose.

1 Total generated quantity of Ammonium Sell to Mis Nirma Limited, ChemicalCarbonate:400 MTfMonth Complex, Vilt: Kalatalav ..Ta: Bhavnagar,

Dist: Bhavnagar!lll

M/s DeW ltd(-soda ash division)., Nr." Railway·· Station, Dhrangadhra, Dist:

Surendranagar

6.3 Ammonium Carbonate should be transported through only designated tanker number by thereceptor unit ~ith GPS from the generator to the above mentioned units.

6.4 For the transportation, labeling and handling of the Ammonium Carbonate solution GPSenabling systelU along with online manifest system through XGNshall use & put in placewhile transpo~tion througJ1.cl~dica_te9.v:el1it;:lesconforming Motor Vehicle Act as amendedfrom time to time.

6.5 The compiled ~data shall be submitted to the concerned Regional office of GPCB forverification at the end of every month.

6.6 The applicant as receptor/generator shall operate adequate EMS regularly & efficiently thecondition laid out by GPCB/CPCB/MoEF from time to time.

Page 7

, Clean Gujarat Green GujaratISO - 9001 - ,2008 & ISO - 14001 - 2004 Certified Organisation

6.7 The applicant shall have to provide flow meter to the out let point of the storage facility ofAmmonium Carbonate and maintain record for utilization of Ammonium Carbonate.

6.8 The applicant ilS receptor/generator shall strictly observe and comply with duly notarizedundertaking a~submitted to the Board.

6.9 In case of anyiviolation of the pennission can be withdrawn at any pointprior intimation.

6.10 Any type of violation under the provisions of Water Act- 1974, all concernreceptor/generator will be held responsible & suitable action may be initiated without priorintimation.

6.11 The authorization is granted to operate a facility as above.6.12 The authorization shall be in force for a period up to 11/4/2019.6.13 The authorization is subject to the conditions stated below and such other conditions as

may be specified in the rules from time to time under the Environment (Protection) Act-1986.

7. ADDITIONAL CONDITIONS UNDER WATER ACT-1974 read with EPA-19B6.Amendment to CCA Order under Water Act4 1974 Condition No. of subConditions 1.to 8 as under:

The Applicant ?s a Generator shall strictly adhere to & Comply with the HazardousWaste ( Management , Handling & Transboundry Movement Rules 2008 as aprecautionary principle for segregation at source, onsite dedicated storage and onword transportation to the actual user only. ;_ .,::,,,,"1"

ii. The Applicant i as a Generator shall have to supply only Ammonium carbonatescrubbing solution to the Magnesium Carbonate Manufacturing units situated atBhavnagar district only. .

iii. For the transportation, packing, Labeling and handling of the Ammonium carbonate (Scrubber Solution) GPS ( Global Positioning System) enabling system along withonline manifest system through XGN shall use & put in place while transportationthrough dedicated vehicles conforming Motor Vehicle Act as amended from time totime.

iv. The complied data shall be submitted by them to'the'concernedRegiona16fflces'ofCPCB for verification at the end of every month.

v. In the event of non requirement of ammonium carbonate solution by the MagnesiumCarbonate Manufacturing units. The applicant will treat it in their own in-house facilityand in no case~diverted it to any other party/ industry / outside the factory premisesby any means: Separate datal record shall be maintained and submitted to theconcerned GPeB regional office.

vi. The applicant '.will operate adequate EMS ( Environmental Management System)regularly & efficiently and effluent conforming to the. discharge norms will ,OJ;dY,1J~discharged through designated outlet and as per the conditions laid out byGPCB/CPCB/MOEF from time to time.

vii. The applicant Iwill strictly observe and comply with duly notarized undertakingsubmitted to this Board vide letter dated 27/5/2011.

iGUJARAT POLLUTION CONTROL~QARO, .. <iii.[. . . PARYAVA'RA1lBAAV'A~'"I Sector-lO-A, Gandhinagar-382 021,'

, Website: www.gpcb.gov.in

viii, The applicant shall have to supply only Ammonium Carbonate Scrubber solution to theMagnesium Carbonate Industries situated at. Bhavnagar district, who

iX.~:I~~5~C~~4pJ:;:~~~~:~~O;\t~~sp~~~~~·~~s:"6t~;t-~~-l~t,1974 all concernAssociations / ~eceptor / Generator will be held responsible & suitable action may beinitiated without prior intimation for this purpose.

x. The permissio~ is valid only for Trial run purpose of recycling / reuse subject tocompliance of: dully notarized undertaking and commitment given to this boardRegular permission shall be accorded only after receiving detail project report fromthe reputed Govt. agencies like CSMCRI, GCPC as assured by the industrial associationsfor this purpos~.

8. TERMS AND CDNDITIONS OF AUTHORISATION,

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~~~GPCB

7.1 The applicant shall comply with the provisions of the Environment (Protection) Act - 1986and the rules made there under.

7.2 The authorization shall be produced for inspection at the request of an officer authorized bythe Gujarat Pol!utionControl Board.

7.3 The persons authorized shall not rent, lend, sell, and transfer of otherwise transport thehazardous wastes without obtaining prior permission of the Gujarat Pollution Control Board.

7.4 Any unauthoriZed change in personnel, equipment or working conditions as mentioned inthe authorization order by the persons authorized shall constitute a breach of thisauthorization.

7.5 It is the duty of the authorized person to take prior permission of the Gujarat PollutionControl Board to close down the facility.

7.6 An application;for the renewal of an authorization shall be made as laid down in rule 5 (6)(ii),

7.7 Industry shall have to display the relevant information with regard to hazardous waste asindicated in the Court's order in W.P. No. 657 0£1995 dated 14th October 2003.

7.8 Industry shaU1have to display on-line data outside the main factory gate with regard toand nature of hazardous chemicals being handled in the plant, including waste water andair emission a~d solid hazardous waste generated within the factory premises.

7.9 Industry shall :have to manage waste oil, discarded containers etc., process waste as perAmended Rul~s - 2003 and shall apply Authorization for all applicable waste as perAmended Rules-2003 with 15 days.

7.10 Industry shall1submit annual report within 15 days and sub sequently by 31st January everyYear.

For and on behalf ofGUJARAT POLLUTION CONTROL BOARD

~,~

SENIOR ENVIRONMENTAL SCIENTIST-' " ' .. ",.,.,

Page 9

Clean Gujarat Green GujaratISO - 9001 ,2008 & ISO - 14001 - 2004 Certified Organisation

http://www.gpcb.gov.in

GUJARAT POLLUTION CONTROL BOARDPARYAVARAN BHAVAN

Sector-l O-A, Gandllinagar-382 021,

Website www.gpcb.gov.ln

•

~""~GPCB Consent to Establish (NOC)

NO: GPCBfANK-CCA-377f511JD-z610Z I

TO,M/s. NARAYAN ORGANICS PVT. LTD.,PLOT NO, 1107/1 & 2,GIDC ESTATE ANKLESHWAR,DIST: BHARUCH

SUB: Consent to Establish-Amendment (NOC) under Section 25 afWater Act 1974 and Section 21 ofAirAet1981

REF: Your application No. 84326 dated 31/08/2014.

Dear Sir,

Without prejudice to the powers of this Board under the Water (Prevention andControl of Pollution) Act-1974, the Air Act-198! and the Environment (Protection) Act-1986and without reducing your responsibilities under the said Acts in any way, this is to informyou that this Board has No Objection to setting up of an industrial plant at PLOT NO: 1107/1 &

2"GIDC ESTATE ANKLESHWAR-, DIST. BHARUCH for installation ofsoJid fuel based boiler.The Validity period of the NOCwiJI be valid up to 28/07/2020.Specific Condition:

1. Unit shall strictly follow the fuel conversion guideline framed by Board.2. After commencement of new solid fuel based boiler, Old Natural Gas fired

boiler/HAG shall be removed and Natural Gas connection shall be surrender.3. Unit shall follow coal - handling guideline.4. Unit shall strictly follow the fly ash notification - 2011.

1. Following shall be used as fuel in the 8aHer"! Furnace

QUANTITY6000 kg/day

2. The flue gas emission from the stake-;'ttached to Boiler shall conform to the followingstandards:

Sr. No. Stack Attached to Stack-Air Pollution Parameter Permissible

Height control Device Limitin Meter

L Boiler fSTPH) 30 Multi Cyclone SPM 100 mg/NW2, Thermic Fluid Heater 30 Separator + Bag S02 100 ppmSO

(20 Lackcal) Filter + Water NO, ppmScrubber

Unit shall comply with undertaking submitted on dated 14/07/2015.All otber conditions of eCA Order NO: 63764 issued vide letter NO: GPCB/ANK-CCA-377(4)/10-26102/229415 dated 22/10/2014 shall remain unchanged.

For and on behalf ofGUlARAT POLLUTION CONTRO BOARD------)vV--- I(

(T.B.SHAH)ENVIRONMENTAL ENGlNEER

Clean Gujarat Green Gujarat .ISO - 9001 - 2CJ08 & ISO - 14001 - 2004 Certified Organisation

Outward No:327818,18/09/2015

http://www.gpcb.gov.ln

User

Typewritten Text

CTE-AMENDMENT

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ANNEX

15

XURE-III



ANNEXURE-IV

LIST OF DIRECTORS

Sr. No.

Name Present Residential Address Designation Contact No.

1. Mr. Dahyabhai Patel 10 Vrundavan Bunglow part 3, Thaltej Shilaj Road, Thaltej, Ahmedabad 380054

Director 9824032335

2. Mr. Mehul Patel 10 Vrundavan Bunglow part 3, Thaltej Shilaj Road, Thaltej, Ahmedabad 380054

Director 9913701477

3. Mr. Purav Patel 10 Vrundavan Bunglow part 3, Thaltej Shilaj Road, Thaltej, Ahmedabad 380054

Director 9662007431



ANNEXURE-V

LIST OF EXISTING & PROPOSED PRODUCTS AND THEIR PRODUCTION CAPACITY

Sr. No.

Name of Products Existing Capacity as per

CCA-63764 MT/M

Proposed Products

MT/M

Total Capacity after Expansion

MT/M

1. CPC Blue (Pigment) 90 610 700 By-Product Ammonium Sulphate 158 42 200 Ammonium Carbonate solution* 400 300 700

Total 648 952 1600 *Note- Ammonium carbonate is classified as hazardous waste in CCA. Now the unit has obtained letter from MoEF&CC clarifying that ammonium carbonate solution is by-product and could be given to actual users. Letter attached as an Annexure-XIV.

ANNEXURE-VI

LIST OF PROPOSED RAW MATERIALS Sr. No.

Product Total Quantity after Expansion (MT/Month)

Name of the raw material Total Quantity after Expansion (MT/Month)

1. CPC Blue

700 Phthalic Anhydride 770 TG Urea 980 Cuprous Chloride 140 Catalyst-Ammonium Molybdate 2 Solvent ( ONT/ DCT/ NB/Hysol-P )

50

Spent Sulfuric Acid (22%)* 1946 Total 3916

By-Product 3. Ammonium

Sulphate 200 Ammonium Carbonate solution 702

Acidic M.L. from CPC Plant 1614

TOTAL 2316

3. Ammonium Carbonate Solution

700 From scrubbing of ammonia gas and carbon di oxide during manufacturing process

--

TOTAL 1600 *Spent Sulphuric Acid (22%) From Alpha Blue pigment manufacturers.

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18

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Material Balance:

Input Kg. Output Kg.Phthalic Anhydride 1100 Ammonia 253Urea 1400 Carbon Dioxide 327Cuprous Chloride 200 Nitrogen Gas 8Ammonium Molybdate 3 Reaction Mass 3265Recovered Solvent 1127solvent (ONT/NB/DCT/HYSOL-P)

23

TOTAL 3853 TOTAL 3853

Input Kg. Output Kg.Reaction Mass 3265 Reaction Mass 2138

ONT recovery (Reuse in next batch) 1127TOTAL 3265 TOTAL 3265

Input Kg Output Kg.Mass 2138 Reaction Mass 6918Spent Acid ( from Alpha blue (20-22%))

2780

Steam 500Reused water (Filter part-1) 1500TOTAL 6918 TOTAL 6918

Input Kg. Output Kg.

Reaction Mass6918

Filter part-1 (to be reused in above step)

1500

Filter part-2 (Use in Ammonium Sulphate Plant)

2300

CPC crude wet cake 3118TOTAL 6918 TOTAL 6918

Input Kg. Input Kg.water from MEE codensate 2500 CPC crude wet cake 3118Water (2nd wash from RO recycle)

5400Effluent (To ETP- MEE)

2000

CPC crude wet cake 3118 Effluent (To ETP-RO) 5900TOTAL 11018 TOTAL 11018

Input Kg. Output Kg.Mass 3118 Wet cake 3158Fresh Water 2600 Effluent to ETP 2600Caustic 40TOTAL 5758 TOTAL 5758

Input Kg. Output Kg.Mass 3158 Evaporation loss 2158

Product 1000TOTAL 3158 TOTAL 3158

Input Kg Output KgWater 1520 Water loss 100

Ammonia 253.00

CO2 327TOTAL 2100 TOTAL 2100

FILTER PRESS

DRYING

MASS BALANCE ACROSS SCRUBBER

GLASS LINE REACTOR

FILTER PRESS

RVD-DISTILATION

MSRL BRICK LINE VESSEL

FILTER PRESS

2000SCRUBBER

Ammonium Carbonate solution



2. AMMONIUM SULPHATE

Manufacturing Process:

Take remaining ammonium carbonate solution from scrubber and acidic mother liquor from CPC Blue are

mixed in the reactor. Carbon dioxide gas and water vapors are librated due to stirring and ammonium

sulphate solution is formed. Ammonium sulfate solution is sent to multi effect evaporator (4FC+ATFD).

Pure ammonium sulfate will be generated from MEE and condensate water will be reused in

manufacturing process of CPC.

Chemical Reaction:

NH4)2CO3 + H2SO4 (NH4)2 SO4 + H2O + CO2

96 98 132 18 44 Material Balance:

Input Kg Output Kg

Ammonium Carbonate solution 1000 Water loss 100Mother liquor from CPC Plant 2300 CO2 to Atm. 350


Input Kg Output KgAmmonium Sulphate Solution (10%)

2850Water Recycle to CPC purification process

2565

Ammonium Sulphate Dry powder 285


2850

Reactor

MEE

Ammonium Sulphate Solution (10%)

Ammonium carbonate

Spent Sulphuric acid

Ammonium Sulphate

Water Carbon dioxide



ANNEXURE-VIII WATER CONSUMPTION AND WASTEWATER GENERATION WATER CONSUMPTION

Sr. No.

Category Existing water consumption in KL/day as per CCA-AWH-643764

Proposed water consumption in KL/day

Total water consumption in KL/day

Fresh Fresh RecycledA Domestic 1.5 2 0 3.5 B Industrial B1 Process 23 73 0 96 B2 Washing 7 3 0 10 B3 Cooling 1.5 5 0 6.5 B4 Boiler 4 40 0 44 B5 Gardening 1 1 0 2 B6 Scrubber 5 0 0 5 C Water Recycled 0 0 196.5 196.5 D Water from Raw

Materials 0 0 52 52

Total (B) 41.5 122 163.5 Total (A+B) 43 124 167 Total (A+B+C+D) 43 372.5 415.5

WASTEWATER GENERATION

Sr. No.

Category Existing Waste water generation in KL/day as per CCA-AWH-643764

Proposed waste water generation in KL/day

Total wastewater water generation in KL/day

1. Domestic 1.3 1.7 3 2. Industrial 2.1 Process 29 14 43 2.2 Washing 7 3 10 2.3 Cooling 0.5 1.5 2 2.4 Boiler 0.5 3.5 4 Total

(Industrial ) 37 22 59

Total (Domestic + Industrial )

38.3 23.7 62

Water that will be recycled

0 196.5 196.5

Spray drier 0 23.7 23.7 Water to NCTL 38.3 0 38.3



TOTAL WATER BALANCE

TOTAL WATE REQUIREMENT

415.5 KLD

(167 KLD (Fresh) + 166 KLD (From RO and MEE) + 52 KLD (From Raw Material) + 30.5

KLD (Water recovered from ammonium sulphate))

Gardening (2 KLD)

Domestic (3.5

Soak Pit (3KLD)

Cooling Tower

Boiler (44 KLD)

Blow Down (4 KLD)

Blow Down (2 KLD)

Washing (10 KLD)

Washing (10 KLD)

Ammonium

Carbonate

Scrubber (35.5

Process (314 KLD)

(96 KLD (Fresh) +52 KLD (from raw

material) +166 KLD (RO and MEE))

Effluent Generation (43 KLD)

RO, MEE & Ammonium

sulphate plant (221 KLD)

Drying

loss (50

Effluent Treatment Plant (62 KLD)

Final Disposal at NCTL

(38.3 KLD)

To Recycle

(196.5 KLD)

MEE Salt

(24.5KLD)

Spray Drier (23.7 KLD)



ANNEXURE-IX EFFLUENT TREATMENT PLANT EXISTING EFFLUENT TREATMENT PLANT

Effluent from process, are segregated into two different streams one is 20 KLD of ammonical nitrogen

and containing streams and another is 17 KLD of diluted process stream. The diluted process stream of

17 KLD is treated to norms prescribed by GPCB and discharged to NCTL. The process stream of 20 KLD

of ammonical nitrogen and containing stream is discharged to ETL (Ankleshwar).

Sewage of 1.3 KLD is discharged to septic tank.

PROPOSED EFFLUENT TREATMENT PLANT

Effluent from process, boiler, cooling tower, overflow of septic tank will be treated in effluent treatment

plant and treated effluent is sent to NCTL for further treatment. However effluent coming from process of

CPC plant having concentrated stream (ML) and dilute stream. Both will be segregated in separate

collection tanks after that they will be treated in RO followed by MEE.

MEE Treatment

Mother liquor consists maximum pollution loads having high acidic, COD and Ammonical nitrogen. It

will be treated with sodium sulide to remove copper and copper sludge will be sent to GPCB authorized

recyclers. After that it will be sent to Ammonium Sulphate plant where it will be Neutralized with Process

generated Ammonium Carbonate solution. So 10% solution of ammonium sulfate is generated. It will

further sent to MEE followed by ATFD which gives Ammonium Sulfate crystal. Ammonium sulfate will

be sold to the market.

RO Treatment

Dilute stream having only 3-4% acidic in nature. It will be Neutralized with Hydrated lime and then

filtered in the high pressure filter press to achieve max solid contain in gypsum Sludge. It will be further

sent to RO Unit where Nano filtration treatment took place to remove all organic and inorganics dissolved

salts. High concentrated RO Reject will be sent to MEE and Low TDS RO permeate will be reused the

process. Alkali (Last Wash) effluent having minimum pollution load will be treated with Ferrous sulfate

to achieve pH and further send to sand and carbon filter to achieve prescribed outlet norms. And then it

will be discharged to NCT.

Spray Drier

Excess effluent in proposed project will be spray dried, hence keeping the existing effluent discharge to

NCTL.



EXISTING ETP EQUIPMENTS Sr. No.

Name of the equipments Nos Size/Capacity

1 Collection Tanks 2 40 KL Each 2 Neutralizer Vessel (MSRLBL) 2 15 KL 3 Clarifier 1 10 KL 4 Filter press for Sludge removal 2 48”X48” (62

plastes 5 Ammonia Stripping Tower 1 20m3/hr 6 pH adjustment Vessel( Ferrus

treatment) 1 20 KL

7 Aeration 1 250 KL 8 Sand Filter 1 5 KL 9 Carbon Filter 1 5 KL

PROPOSED ADDITIONAL ETP EQUIPMENTS Sr. No.

Name of the Equipments Nos Size/Capacity

1 Collection tanks for Concentrated Stream

1 40 KL

2 Collection tank for Dilute Stream 1 40 KL 3 Neutralizer 1 50 KL 4 MEE (MULTI EFFECT

EVAPORATORS) 1 150 KLD

5 ATFD ( Agitated thin film dryer) 1 10 KLD 6 RO ( Nano Filtration technology) 1 200 KLD 7 Holding Tank 1 100 KL 8 Final Discharge Tank 1 10 KL 9 Spray Drier 1 100 KLD

M/s. Jy

EFFL

Jyoti Om Chemical R

LUENT TREA

Research Centre Pvt L

ATMENT PLAN

M/S. NA

Ltd

NT DIAGRAM

ARAYAN ORGANIC

M (EXISTING)

CS PVT LTD, G.I.D.

)

.C. ANKLESHWAR

R, GUJARAT

25



EFFLUENT TREATMENT PLANT (PROPOSED)

Concentrated Stream

Neutralization Tank

RO

MEE +ATFD CPC Plant

Ammonium Sulphate Crystals

Ammonium Sulphate Plant

Filter press

Gypsum/Solid waste to TSDF

Permeate

MEE

Hydrated Lime Dilute Stream

Collection Tank

Reject Collection

Tank of Recycled

water

MEE Salt to TSDF

Copper Removal

Sodium Sulfide

Copper Sludge



ANNEXURE-X DETAILS OF ENERGY AND FUEL CONSUMPTION

DETAILS OF ENERGY CONSUMPTION

Sr. No.

Electricity Quantity as per current

Quantity as per proposed expansion

Total Quantity after expansion

1. Electricity connected load 1300 KVA 1000 KVA 2300 KVA

DETAILS OF FUEL CONSUMPTION

Sr. No.

Fuel Quantity as per current

CCA No. AWH-63764

Quantity as per CTE-

Amendment-72205

Quantity as per proposed expansion

Total Quantity after expansion

1. Natural Gas 2300 m3/day -2300 m3/day 0 0 2. Imported Coal 0 6 MT/Day 14 MT/Day 20 MT/Day 3. Diesel 0 0 100 liter/hr. 100 liter/hr.



ANNEXURE-XI DETAILS OF FLUE GAS AND PROCESS GAS EMISSIONS DETAILS OF FLUE GAS EMISSION

Existing Flue Gas Emission as per CTE amendment-72205 Sr. No.

Stack attached to

Stack Height

(m)

Type of fuel

Fuel consumption

Type of

emission

Permissible limit

APCM

1. Boiler (5 TPH)

30 Imported Coal

6 MT/Day SPM SO2

NO2

150 mg/Nm3

100 ppm 50 ppm

Multi cyclone separator+ Bag filter+

Water scrubber 2. Thermic

Fluid Heater (20 Lakh Kcal)

30 Imported Coal

SPM SO2

NO2

150 mg/Nm3

100 ppm 50 ppm

Proposed Flue Gas Emission 1. Boiler

(5 TPH) 30 Imported

Coal 10 MT/Day

SPM SO2

NO2

150 mg/Nm3

100 ppm 50 ppm

Multi cyclone separator+ Bag filter+ Water scrubber 2. Thermic

Fluid Heater (20 Lakh Kcal)

30 Imported Coal

SPM SO2

NO2

150 mg/Nm3

100 ppm 50 ppm

3. Coal fired HAG (25 lakh kcal) for spray drier

30 ImportedCoal

4 MT/Day SPM SO2

NO2

150 mg/Nm3

100 ppm 50 ppm

Multi cyclone separator+ Bag filter+

Water scrubber

4. D.G. Set (1000 kVA)

15 Diesel 100 liter/hr. SPM SO2

NO2

150 mg/Nm3

100 ppm 50 ppm

--



DETAILS OF PROCESS GAS EMISSION

Existing Process Gas Emission as per CCA-63794 Sr. No.

Stack Attached To

Stack Height(m)

Air Pollution Control System

Parameter Permissible Limit

1. Glass line reactor (3

Nos.) 12

Water Scrubber + Venturi Scrubber

Ammonia 175 mg/Nm3

2. Reactor for Ammonium

Sulphate

Not applicable

Condensor for reactor steam to

get DM water for reuse

Not applicable

Not Applicable

Proposed Process Emission

1. Glass line reactor (5

Nos.) 12

Two stage Water Scrubber + Acid

Scrubber Ammonia

175 mg/Nm3

2. Spin Flash

Drier 30 Bag filter PM

150 mg/Nm3

3. Spray Drier 30 Cyclone separator

PM 150 mg/Nm3



ANNEXURE-XII DETAILS OF HAZARDOUS WASTE GENERATION

Sr. No.

Type of Waste

Category Existing Quality As per CCA

No. AWH-69573

Proposed Quality

Quantity after

Expansion

Mode of Disposal

1. ETP sludge/ Gypsum sludge

35.3

80 MT/M 620 MT/M 700 MT/M

Collection, Storage, Transportation, Disposal at by Cement factory or TSDF site authorized by the GPCB.

2. MEE salt 0 100 MT/M 100 Collection, Storage, Transportation, Disposal to TSDF site authorized by the GPCB.

3. Copper Sludge

8.2 0 50 MT/M 50 MT/M Collection, Storage, Transportation, Disposal to GPCB authorized copper recyclers.

4. Used Oil 5.1 0.05 Lit/M 499.95 Lit/M

500 Lit/M Collection, Storage, Transportation, Disposal at by Selling registered refiners.

5. PP Bags/Drums

33.3 40

Nos./M

5000

Nos./M

5040 Nos./M

Collection, Storage, Transportation, Disposal at by Selling to authorize recycler.

6. Spent Carbon

28.3 0 5 MT/Y 5 MT/Y Collection, Storage, transportation, sent for co-processing

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ANNEXURE-XIV

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