TRADE NAME (as labeled) Aluminum Oxide Abrasive Wheel MANUFACTURER’S NAME: Pearl Abrasive Company Address (complete mailing address) 6210 South Garfield Avenue Commerce, CA 90040 Phone number for additional Information: (562) 927-5561 Date prepared or revised: January 1, 2011 _____________________II. HAZARDOUS INGREDIENTS_____________________
Chemical Names CAS Numbers Percent* Exposure limits in air (give units) ACGIH TLV OSHA PEL OTHER (SPECIFY) Aluminum Oxide 1344-28-1 40-50 10mg/m3 10mg/m3 ______________ Resin (phenolic) N.A. 15-60 NAIF NAIF ______________ Glass Fiber Reinforcement N.A. 1-7 10mg/m3 NAIF ______________
The use of this product generates dust, particulate, and fumes, both from this product and from the material being abraded. It is important that this MSDS, and also the safety precautions on MSDS for the material being abraded, be reviewed and used.
Vapor Density (air = 1) N.A. Melting point or range, ºF N.A. Specific Gravity 2-4 Boiling point of range, ºF N.A. Solubility Water Negligible Evaporation rate (butyl acetate = 1) N.A. Vapor Pressure, mmHg at 20ºC N.A. Appearance and Odor No odor when not in use. HOW TO DETECT THIS SUBSTANCE* (warming properties of substance as a gas, vapor, Dust, or mist) Product may give off a phenolic odor during use. * Note a required category NOTE: all required categories should be addressed. If any item is not applicable, or no information is available, the space must be marked to indicate that. This voluntary form is provided by CAL/OSHA to assist MSDS preparers and users. Any format may be used as long as it contains all the information.
NAIF – NO APPLICABLE INFORMATION FOUND
N.A. – NOT APPLICABLE
_______________________________IV. FIRE AND EXPLOSION_________________________
Flash Point, ºF (give method) N.A. Auto ignition temperature, ºF N.A. Flammable limits in air, volume % lower level (LEL) N.A. Upper Level (UEL) N.A. Fire extinguishing materials: xx water spray xx carbon dioxide other xx foam xx dry chemical Specific firefighting procedures: Wear self contained breathing apparatus. Unusual fire and explosion hazards: None __________________________V. HEALTH HAZARD INFO.___________________ SYMPTOMS OF OVEREXPOSURE for each potential route of exposure. Inhaled: Coughing may result with exposure to dust. Contact with skin or eyes: Dust may cause Irritation of skin and eyes. Absorbed through skin: N.A. Swallowed: N.A. ______________________________________________________________________________________ HEALTH EFFECTS OR RISKS FROM EXPOSURE. Explain in lay terms. Attach extra pages if more space is needed Acute: During use (grinding) coughing and shortness of breath may occur. May cause irritation to eyes. Chronic: Repeated use (grinding) may affect breathing capacity. ______________________________________________________________________________________ FIRST AID: EMERGENCY PROCEDURES Eye Contact: Wash with large amounts of water. If Irritation persists, obtain first aid and medical Assistance. Skin Contact: Wash affected areas with soap and water. Inhaled: Remove to fresh air. Swallowed: N.A. ______________________________________________________________________________________ SUSPECTED CANCER AGENT? xx NO: This product’s Ingredients are not found in the lists below. YES: _______Federal OSHA ________NTP ___________IARC California employers using Cal/OSHA-registered carcinogens must register with Cal/OSHA. The Cal/OSHA and Federal OSHA carcinogen lists are similar. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Personnel with breathing difficulties, may experience increased shortness of breath.
Stability: xx stable unstable Incompatibility (materials to avoid): None Hazardous decomposition products (including combustion products): During use, fire may generate CO, CO2, Nox and other toxic gases Hazardous Polymerization: May occur xx Will not occur Conditions to avoid: None ______________VII. SPILL, LEAK AND DISPOSAL PROCEDURES___________
Spill response procedures (include employee protection measures): Use cleanup procedure to prevent spreading of dust. Preparing wastes for disposal (container types, neutralization, etc.) Disposal of waste in a manner consistent with applicable federal, state and local laws. NOTE: Byproducts of use need to be disposed of lawfully. NOTE: Dispose of all waste accordance with the federal, state and local regulations _________________VIII. SPECIAL HANDLING INFORMATION______________
Ventilation and engineering controls: Employ adequate ventilation. See OSHA 29 CFR 1910.94 and 29 CFR 1910.100 Respiratory protection (type): Employ toxic dust respirator. Eye Protection (type): Employ safety goggles. Gloves (specify material): Use gloves for general hand protection. Other clothing equipment: Wear flame retardant clothing. Grinding or cutting may cause elevated sound levels, use ear protection during operation. Work practices, hygienic practices: N.A. Other handling/storage requirement: N.A. Protective measures during maintenance of contaminated equipment. Use respiratory and eye protection.
SMAW - Low-Hydrogen Electrodes.
Air Liquide Canada Inc. 1250, René-Lévesque West, Suite 1700, Montreal, QC H3B 5E6
1-514-878-1667
Material Safety Data Sheet - MSDS
Supplier
Description
In case of emergency
Section 1. Chemical Product and Company Identification
:: Date of issue :
Generic Code : AL-J-002-0:01/15/2011
Product nameBlueshield:
EXCELARC 18;LA 7018;LA 18 LMP;LA 18 PLUS;LA 18 PLUS LMP;NUCLEARC LA 7018;LA 7028;LA 18 PLUS COMPLETE;
Carcinogenic effects(*): Classified 2B by IARC [Titanium dioxide]. Classified None. by NIOSH [Titanium dioxide]. Classified A4 byACGIH [Titanium dioxide]. Classified A4 by ACGIH, 3 by IARC [Calcium fluoride]. Classified A4 by ACGIH [Zirconium]. ClassifiedA4 by ACGIH [Aluminum Oxide]. Classified 1 by NTP, + by NIOSH Silica crystalline quartz Classified A2 by ACGIH, 2A by IARCSilica crystalline quartz Classified + by NIOSH [Nickel]. Classified 2B by IARC, Classified 2 by NTP [Nickel]. Classified A5 byACGIH [Nickel].MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.
Dermal contact. Eye contact. Inhalation.
Emergency overview
Medical conditions aggravatedby over-exposure
Repeated exposure to the fumes emitted while using this material may produce general deterioration of health.
Section 2. Hazards Identification
Routes of entry
Potential acute health effects
Potential chronic health effects
Hazardous by the following route of exposure: of inhalation (lung irritant).
Very hazardous by the following route of exposure: of eye contact (irritant). Inflammation of the eye is characterized by redness,watering and itching.
Since the product (welding fumes) is a gas and that it is mostly probable that it will be inhaled more than ingested, please considerfirst to look at the preventive measures in case of inhalation.
Hazardous by the following route of exposure: of skin contact (corrosive, irritant, sensitizer). Skin contact may produce burns. Skininflammation is characterized by itching, scaling, reddening or, occasionally, blistering.
Eyes
Skin
Inhalation
Ingestion
Physical state and Appearance Solid.:
:
:
:
:
:
:
:
:
(*) See Abbreviations (section 16).
Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use only withadequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keepcontainer tightly closed. Use personal protective equipment as required. Wash thoroughly after handling.
WARNING!
MAY BE HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGICSKIN REACTION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER HAZARD - CONTAINSMATERIAL WHICH CAN CAUSE CANCER.
These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
ELECTRIC SHOCK can kill.FUMES AND GASES can be dangerous to your health.ARC RAYS can injure eyes and burn skin.
Iron 7439-89-6 45 - 70 Not regulated.Titanium dioxide 13463-67-7 0.1 - 15 Not regulated.Calcium Carbonate 471-34-1 0.01 - 15 Not regulated.Calcium fluoride 7789-75-5 0.01 - 10 UN1740Zirconium 7440-67-7 0.01 - 6 UN2858Manganese 7439-96-5 0.01 - 4 Not regulated.Ferrosilicon 8049-17-0 0.01 - 2.5 UN1408Aluminum Oxide 1344-28-1 0.01 - 2 Not regulated.Silica, Crystalline - Quartz 14808-60-7 0.1 - 1 Not regulated.Nickel 7440-02-0 0.01 - 0.5 Not regulated.
Section 3. Composition, Information on Ingredients
Name CAS # % by weight UN number
See Section 8 for Exposure Limits of the oxides found in the welding fumes.
The fumes emitted by the electrodes, in use, are hazardous. This MSDS is written for workers using these electrodes.
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Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Ifpotentially dangerous quantities of this material have been swallowed, call a physician immediately.
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 20 minutes.Get medical attention immediately.
Wash with soap and water. Get medical attention if irritation develops.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Section 4. First Aid MeasuresEye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Non-flammable. Emits toxic fumes when heated.
Use extinguishing media suitable for surrounding materials.
Non-explosive in the presence of the following materials or conditions: open flames, sparks and static discharge, heat and shocksand mechanical impacts.
Section 5. Fire Fighting MeasuresFlammability of the product
Explosibility
Fire-fighting media andinstructions
::
:
Use appropriate tools to transfer the spilled solid to a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority requirements.
Section 6. Accidental Release MeasuresSmall/Large Spill and Leak :
All filler metals in their original, unopened containers should be kept in a relatively dry storage area at temperatures between 15°C(60°F) and 30°C (80°F) and 50% maximum relative humidity.
Avoid breathing dusts, vapors or fumes from burning materials. Use only with adequate ventilation. Avoid contact with eyes, skinand clothing. Do not ingest. Keep container closed. Wash thoroughly after handling.
Section 7. Handling and StorageHandling
Storage :
:
Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminantsbelow any recommended or statutory limits. If user operations generate dust, fumes or mist, use ventilation to keep exposure toairborne contaminants below the exposure limit.
Section 8. Exposure Controls, Personal ProtectionEngineering controls
Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear a canister breathing apparatus (respirator) or asupplied-air respirator, when required, to weld in a confined space or when room exhaust or ventilation does not keep exposurebelow the acceptable values.
Safety glasses with side shields. Face shield with radiation shielding.
Full suit. (Fire resistant.)
Gloves. (Fire resistant.)
Metal cap, safety boots.
Personal protection
Eyes
Body
Respiratory
Hands
Feet
:
:
:
:
:
:
Occupational exposure limits
Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
[3]Skin sensitizationForm: [a]Respirable dust [b]Total dust [c]total dust [d]Total dust. [e]Al [f]fume [g]Respirable fraction; see Appendix C [h]Respirable particulate[i]Respirable [j]Respirable fraction: means that size fraction of the airborne particulate deposited in the gas-exchange region of the respiratory tract andcollected during air sampling with a particle size-selective device that, (a) meets the ACGIH particle size–selective sampling criteria for airborneparticulate matter; and (b) has the cut point of 4 µm at 50 per cent collection efficiency. [k]Respirable dust. [l]Inhalable fraction. See Appendix C,paragraph A. Inhalable Particulate Mass TLVs (IPM–TLVs) for those materials that are hazardous when deposited anywhere in the respiratory tract.[m]Inhalable fraction: means that size fraction of the airborne particulate deposited anywhere in the respiratory tract and collected during air sampling witha particle size-selective device that, (a) meets the ACGIH particle size-selective sampling criteria for airborne particulate matter; and (b) has the cut pointof 100 µm at 50 per cent collection efficiency. [n]Inhalable particle.Notes: [A]as Mn [B]as Zr [C]as F [D]as fluoride [E]as Ni
Solid.
1540 to 2030°C (2804 to 3686°F)
Not available.
Easily soluble in the following materials: Methanol, acetone.Insoluble in the following materials: cold water, hot water.
Odorless.
Reddish-brown. Grayish-white.
Melting/freezing point
Section 9. Physical and Chemical PropertiesPhysical state and Appearance
Specific gravity
Solubility
Odor
Color
:
:
::::
The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur.
Metallic oxides. Carbon oxides (CO, CO2). Arc radiation can support the production of ozone and nitrogen oxides.
Section 10. Stability and ReactivityStability and reactivity
Hazardous decompositionproducts
Hazardous polymerization
::
:
Section 11. Toxicological InformationAdditional Toxicity data
Acute exposure to welding fumes may result in discomfort such as: dizziness, nause or dryness of nose, throat or the eyes.
CARCINOGENIC EFFECTS: See Section 2.Contains material which causes damage to the following organs: blood, kidneys, lungs, upper respiratory tract, skin, central nervoussystem (CNS), eye, lens or cornea.
Chronic effects and other toxiceffects on humans
:
Calcium carbonate LD50 Oral Rat 6450 mg/kg -Manganese LD50 Oral Rat 9 g/kg -calcium fluoride LD50 Oral Rat 4250 mg/kg -
Product/ingredient name Result Species Dose Exposure
Decomposition products may include the following materials: carbon oxides (CO, CO2), halogenated compounds. Some metallicoxides.
Section 12. Ecological Information
Products of degradation :
Ecotoxicity data
Iron Acute LC50 33000 to 100000 ug/L Marine water Crustaceans - Crangon crangon 48 hoursAcute LC50 0.56 ppm Fresh water Fish - Cyprinus carpio - Juvenile
(Fledgling, Hatchling, Weanling) - 3.5 cm96 hours
Titanium dioxide Acute LC50 5.5 ppm Fresh water Daphnia - Daphnia magna - Juvenile(Fledgling, Hatchling, Weanling) - <24hours
48 hours
Acute LC50 >1000000 ug/L Marine water Fish - Fundulus heteroclitus 96 hoursChronic NOEC 1 ppm Fresh water Daphnia - Daphnia magna - Juvenile
(Fledgling, Hatchling, Weanling) - <24hours
48 hours
Calcium carbonate Acute LC50 >56000000 ug/L Fresh water Fish - Gambusia affinis - Adult 96 hoursManganese Acute EC50 40000 ug/L Fresh water Daphnia - Daphnia magna 48 hours
Chronic NOEC 28000 ug/L Fresh water Daphnia - Daphnia magna 48 hoursNickel Acute EC50 1000 ug/L Marine water Daphnia - Daphnia magna - <24 hours 48 hours
Acute LC50 47.5 ng/L Fresh water Fish - Heteropneustes fossilis 96 hours
Product/ingredient name SpeciesResult Exposure
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Waste must be disposed of in accordance with federal, state and local environmental control regulations. Recycle, if possible.Waste information
Section 13. Disposal Considerations
Consult your local or regional authorities.:
Section 14. Transport Information
No transport class is found applicable to this product.
U.S. Federal regulations
Irritating materialSensitizing materialCarcinogenTarget organ effects
HCS Classification
Section 15. Regulatory Information
TSCA 8(a) IUR: Partial exemptionUnited States inventory (TSCA 8b): All components are listed or exempted.
State regulations
CEPA Toxic substances: The following components are listed: Calcium fluorideCanadian ARET: None of the components are listed.Canadian NPRI: The following components are listed: Calcium fluoride; Manganese;Aluminum OxideAlberta Designated Substances: None of the components are listed.Ontario Designated Substances: None of the components are listed.Quebec Designated Substances: None of the components are listed.
WHMIS (Canada)
Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).
WARNING: This product contains a chemical known to the State of California to cause cancer.
These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
The following components are listed: TITANIUM DIOXIDE; ALUMINUM OXIDE; MANGANESE;ZIRCONIUM
Massachusetts :
New York : The following components are listed: Nickel
New Jersey : The following components are listed: TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2); ALUMINUMOXIDE; alpha-ALUMINA; FERROSILICON; FERROCERIUM; MANGANESE; ZIRCONIUM;SILICA, QUARTZ; QUARTZ (SiO2); NICKEL
Pennsylvania : The following components are listed: TITANIUM OXIDE (TIO2); ALUMINUM OXIDE (AL2O3);MANGANESE; ZIRCONIUM; QUARTZ (SIO2); NICKEL
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the informationrequired by the Controlled Products Regulations.
Clean Water Act (CWA) 307: Copper; Nickel
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Titanium dioxide; calcium fluoride; Zirconium; Manganese; FERROSILICON;aluminium oxide; Calcium carbonateSARA 311/312 MSDS distribution - chemical inventory - hazard identification: Iron: Fire hazard; Titanium dioxide: Immediate(acute) health hazard; calcium fluoride: Immediate (acute) health hazard; Zirconium: Fire hazard; Manganese: reactive, Immediate(acute) health hazard, Delayed (chronic) health hazard; FERROSILICON: Fire hazard, reactive; aluminium oxide: Immediate(acute) health hazard; Calcium carbonate: Immediate (acute) health hazard
Section 16. Other Information
References
Hazardous Material Information System (U.S.A.)
National Fire Protection Association (U.S.A.)
Label requirements :
:
: Health: 2* Fire: 0 Reactivity: 0
: Health: 2 Fire: 0 Reactivity: 0 Other: None
- 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names,PG. - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version 2005. - CRC Handbook ofchemistry and physics, 67th edition. CRC Press inc., Boca Raton, Florida. - Manufacturer's Material Safety Data Sheet. ANSIZ400.1, MSDS Standard, 2004. ANSI Z49.1 Safety in Welding and Cutting, The American Welding Society, P.O. Box 351040,Miami, FL 33135. Canadian Standard Association, CSA W117.2, Code for Safety in Welding and Cutting, 2003.
See Section 2.
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Notice to reader
THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE USED BY PROPERLY TRAINED ANDQUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION. THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINEDARE DERIVED FROM SOURCES WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, AIR LIQUIDE CANADA INC. MAKES NO REPRESENTATION AND GIVESNO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS AND ASSUMES NO LIABILITY FOR DAMAGES ORLOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE, WHETHER PROPER OR IMPROPER.
Date of previous issue
Version :
:Responsible name :
Abbreviations and acronyms : ACGIH: American Conference of Governmental Industrial Hygiene.ACGIH-A1-Confirmed Human Carcinogen.ACGIH A2--Suspected Human Carcinogen.ACGIH-A3-Animal Carcinogen.ACGIH-A4-Not Classifiable as a Human Carcinogen.ACGIH-A5-Not suspected as a Human Carcinogen.IARC: International Agency for Research on Cancer.IARC 1: Proven.IARC 2B: Possible for human.IARC 3: Not classifiable for human.NIOSH: National Institute of Occupational Safety and Health.NIOSH +: Proven.NIOSH: None.European Union3: Possible for human.NTP: National Toxicology program.NTP 2: Reasonably Anticipated to be human carcinogens.
SECTION III -- FIRE AND EXPLOSION HAZARD DATANON-FLAMMABLE:WELDING ARC AND SPARKS CAN IGNITE COMBUSTABLES AND FLAMMABLE PRODUCTSSEE Z49.1 REFERENCED IN SECTION VI
TELEPHONE NUMBER: SIZE:
DATE PREPARED: CLASSIFICATION
SUPPLIER NAME: PRODUCT TYPE:
ADDRESS: TRADE NAME:
FOR HIGH TENSILE STRENGTH STEEL
MATERIAL SAFETY DATA SHEET
SECTION IV -- HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: MAXIMUM FUME EXPOSURE 5.0 mg/m3
EFFECT OF OVEREXPOSURE: WELDING FUME MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS,
NAUSEA OR IRRITATION OF NOSE, THROAT OR EYES
ARC RAYS CAN INJURE EYES AND BURN SKIN, ELECTRIC SHOCK CAN KILL
EMERGENCY AND FIRST AID PROCEDURES: CALL FOR MEDICAL AID. IF BREATHING IS DIFFICULT
GIVE OXYGEN. IN ALL CASES CALL A PHYSICIAN
SECTION V -- REACTIVITY DATAUNSTABLE CONDITIONS TO AVOID
STABLE NOT NECESSARY
INCOMPATABILITY (MATERIALS TO AVOID): NOT NECESSARY
HAZARDOUS DECOMPOSITION PRODUCTS: WELDING FUMES AND GASES CANNOT BE CLASSIFIED SIMPLY
THE COMPOSITION AND QUANTITY OF BOTH ARE DEPENDANT ON THE METAL BEING WELDING, THE PROCESS,
ELECTRODES USED AND PROCEDURE
MAY OCCUR CONDITIONS TO AVOID
WILL NOT OCCUR NOT NECESSARY
SECTION VI -- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIALS ARE RELEASED OR SPILLED: NOT NECESSARY
WASTE DISPOSAL METHOD: USE SCRAP DISPOSAL IN AN ENVIRONMENTALLY ACCEPTALBE MANNER
ACCORDING TO LOCAL REGULATIONS UNLESS OTHERWISE NOTED.
SECTION VII -- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: USE RESPIRABLE FUME RESPIRATOR WHEN WELDING IN CONFINED SPACE
USE ENOUGH VENTILATION: EXHAUST AT THE ARC, OR BOTH, TO KEEP FUMES AND GASES AWAY FROM YOUR
BREATHING ZONE AND THE GENERAL AREA.
PROTECTIVE GLOVES: YES, WHEN WELDING EYE PROTECTION: SHIELD NECESSARY WHEN WELDING
OTHER PROTECTIVE EQUIPMENT: MAY INCLUDE ARM PROTECTORS, APRONS, SHOULDER PROTECTION, HATS,
AND DARK SUBSTANTIAL CLOTHING. DO NOT ALLOW LIVE ELECTRODES TO CONTACT SKIN.
SECTION VIII -- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HAULING AND STORING: KEEP DRY
OTHER PRECAUTIONS: READ AND UNDERSTAND THE MANUFACTURER'S INTSRUCTION AND THE
PRECAUTIONARY LABEL ON THE PRODUCT
HAZARDOUS POLYMERIZATION
STABILITY •
•
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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751P.O. Box 2219 Telephone 614-790-3333Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274-
5263)
Product name CSW 311
Product code 34463Product Use Description No data
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid, light yellow
WARNING! REDUCES BLOOD'S OXYGEN-CARRYING CAPACITY. MAY CAUSE EYE IRRITATION. HARMFUL IF SWALLOWED. HARMFUL IF INHALED.
Eye contactCan cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes.
Skin contactUnlikely to cause skin irritation or injury.
IngestionSwallowing this material may be harmful.
InhalationBreathing of vapor or mist is possible. Breathing this material may be harmful. Symptoms are
not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).
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Aggravated Medical ConditionPreexisting disorders of the following organs (or organ systems) may be aggravated by exposure
to this material:, Skin, lung (for example, asthma-like conditions), Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias.
Lowered blood pressure, Shortness of breath, May cause methemoglobinemia, a blood abnormality that may cause headache, difficulty breathing, lightheadedness, weakness, confusion, rapid heart rate and cyanosis (lack of oxygen in the tissues causing blue-colored skin and nails).
Target OrgansNo data
CarcinogenicityBased on the available information, this material cannot be classified with regard to
carcinogenicity. This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA).
Reproductive hazardBased on the available information, risk to the fetus from maternal exposure to this material
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If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.
SkinFirst aid is not normally required. However, it is recommended that exposed areas be cleaned by
washing with soap and water.
IngestionSeek medical attention. If individual is drowsy or unconscious, do not give anything by mouth;
place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
InhalationIf symptoms develop, immediately move individual away from exposure and into fresh air. Seek
immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
Notes to physicianHazards: Overexposure to this product (or a component) may cause methemoglobinemia,
which in sufficient concentration causes cyanosis. Severe cyanosis may require intravenous injection of methylene blue. Methylene blue is contraindicated if the patient has confirmed or suspected glucose-6-phosphate dehydrogenase deficiency.
Treatment: No information available.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing mediaDry chemical, Carbon dioxide (CO2), Water spray
Precautions for fire-fightingWear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Use
water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes.
NFPA Flammable and Combustible Liquids Classification
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Combustible Liquid Class IIIB
6. ACCIDENTAL RELEASE MEASURES
Personal precautionsFor personal protection see section 8. Persons not wearing protective equipment should be
excluded from area of spill until clean-up has been completed.
Environmental precautionsPrevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter
drains. Do not flush into surface water or sanitary sewer system.
Methods for cleaning upKeep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand,
Other informationComply with all applicable federal, state, and local regulations.
7. HANDLING AND STORAGE
HandlingContainers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
StorageStore in a cool, dry, ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure GuidelinesContains no substances with occupational exposure limit values.
General adviceThese recommendations provide general guidance for handling this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities.
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Exposure controlsProvide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure
below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects.
Eye protectionWear chemical splash goggles when there is the potential for exposure of the eyes to liquid,
vapor or mist.
Skin and body protection
Wear normal work clothing including long pants, long-sleeved shirts and foot covering to prevent direct contact of the product with the skin. Launder clothing before reuse. If skin irritation develops, contact your facility health and safety professional or your local safety equipment supplier to determine the proper personal protective equipment for your use.Wear resistant gloves (consult your safety equipment supplier).
Respiratory protectionA NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air-purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state liquidForm no data availableColour light yellow Odour no data availableBoiling point/boiling range 212 °F / 100 °C @ 1,013.33 hPa Calculated Phase
Transition Liquid/GasMelting point/range 21.2 °F / -6.0 °C
Sublimation point no data availablepH 10.3 Flash point 200.1 °F / 93.4 °C
Calculated Flash Point
Page 5 / 11
Page: 6SAFETY DATA SHEET Revision Date: 01/28/2011
Print Date: 3/14/2011MSDS Number: R0314076
CSW 311 34463
Version: 2.9
Ignition temperature no data availableEvaporation rate (>)1 Ethyl EtherLower explosion limit/Upper explosion limit no data availableParticle size no data availableVapour pressure 23.333 hPa @ 68 °F / 20 °C Calculated Vapor
PressureRelative vapour density no data availableDensity 1.15 g/cm3 @ 77 °F / 25 °C
9.57 lb/gal @ 77 °F / 25 °CBulk density No dataWater solubility no data availableSolubility(ies) no data availablePartition coefficient: n-octanol/water no data availablelog Pow no data availableAutoignition temperature no data availableViscosity, dynamic no data availableViscosity, kinematic no data availableSolids in Solution no data availableDecomposition temperature no data availableBurning number no data availableDust explosion constant no data availableMinimum ignition energy no data available
10. STABILITY AND REACTIVITY
StabilityStable.
Conditions to avoidDo not allow evaporation to dryness., Exposure to moisture.
SODIUM METABORATE TETRAHYDRATE : no data available
Acute dermal toxicitySODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
12. ECOLOGICAL INFORMATION
BiodegradabilitySODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
BioaccumulationSODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
Ecotoxicity effects
Toxicity to fish
Page 7 / 11
Page: 8SAFETY DATA SHEET Revision Date: 01/28/2011
Print Date: 3/14/2011MSDS Number: R0314076
CSW 311 34463
Version: 2.9
SODIUM NITRITE : 96 h static test LC 50 Danio rerio (zebra fish): 130.00 mg/l 96 h flow-through test LC 50 Fathead minnow (Pimephales promelas): 2.35 - 3.81 mg/l 96 h flow-through test LC 50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 0.09 - 0.13 mg/l 96 h LC 50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 0.15 - 0.20 mg/l Method: Flow through; Mortality
SODIUM METABORATE TETRAHYDRATE : no data available
Toxicity to daphnia and other aquatic invertebrates.SODIUM NITRITE : 96 h static test LC 50 Water flea (Daphnia magna):
8.30 mg/l
SODIUM METABORATE TETRAHYDRATE : no data available
Toxicity to algae
SODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
Toxicity to bacteriaSODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
Biochemical Oxygen Demand (BOD)SODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
Chemical Oxygen Demand (COD)SODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
Additional ecological informationSODIUM NITRITE : no data available
SODIUM METABORATE TETRAHYDRATE : no data available
Page 8 / 11
Page: 9SAFETY DATA SHEET Revision Date: 01/28/2011
Print Date: 3/14/2011MSDS Number: R0314076
CSW 311 34463
Version: 2.9
13. DISPOSAL CONSIDERATIONS
Waste disposal methodsDispose of in accordance with all applicable local, state and federal regulations. For assistance
with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at 800-637-7922.
14. TRANSPORT INFORMATION
REGULATIONID NUMBER
PROPER SHIPPING NAME *HAZARD CLASS
SUBSIDIARY HAZARDS
PACKING GROUP
MARINE POLLUTANT / LTD. QTY.
U.S. DOT - ROADNA 3082 Other regulated substances,
liquid, n.o.s. (SODIUM NITRITE)
9 III
U.S. DOT - RAILNA 3082 Other regulated substances,
liquid, n.o.s. (SODIUM NITRITE)
9 III
U.S. DOT - INLAND WATERWAYSNA 3082 Other regulated substances,
liquid, n.o.s. (SODIUM NITRITE)
9 III
TRANSPORT CANADA - ROADNot dangerous goods
TRANSPORT CANADA - RAILNot dangerous goods
TRANSPORT CANADA - INLAND WATERWAYSNot dangerous goods
INTERNATIONAL MARITIME DANGEROUS GOODS
Page 9 / 11
Page: 10SAFETY DATA SHEET Revision Date: 01/28/2011
Print Date: 3/14/2011MSDS Number: R0314076
CSW 311 34463
Version: 2.9
Not dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGONot dangerous goods
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGERNot dangerous goods
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES
Not dangerous goods*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.
15. REGULATORY INFORMATION
WHMIS ClassificationD1B Toxic Material Causing Immediate and Serious Toxic Effects
D2B Toxic Material Causing Other Toxic Effects
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
Canadian National Pollutant Release Inventory (NPRI)SODIUM NITRITE 20.00 %
Notification statusUS. Toxic Substances Control Act y (positive listing)Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)
y (positive listing)
Australia. Industrial Chemical (Notification and Assessment) Act
n (Negative listing)
New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand
y (positive listing)
Japan. Kashin-Hou Law List y (positive listing)
Page 10 / 11
Page: 11SAFETY DATA SHEET Revision Date: 01/28/2011
Print Date: 3/14/2011MSDS Number: R0314076
CSW 311 34463
Version: 2.9
Korea. Toxic Chemical Control Law (TCCL) List y (positive listing)Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act
y (positive listing)
China. Inventory of Existing Chemical Substances y (positive listing)
The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751).
Page 11 / 11
Page: 1SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751P.O. Box 2219 Telephone 614-790-3333Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274-
5263)
Product name CSW 600
Product code 34779Product Use Description No data
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid, light yellow
DANGER! MAY CAUSE RESPIRATORY TRACT IRRITATION. HARMFUL IF SWALLOWED. CAUSES SEVERE BURNS OF THE EYES AND SKIN.
Potential Health Effects
Exposure routesInhalation, Skin contact
Eye contactCan cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of
eyes. Can injure the cornea and cause blindness.
Skin contactCan cause permanent skin damage. Symptoms may include redness, burning, and swelling of
skin, burns, and other skin damage.
IngestionSwallowing this material may be harmful or fatal. Symptoms may include severe stomach and
intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and shock may occur as a result of severe tissue injury.
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Page: 2SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
InhalationBreathing this material may be harmful or fatal. Symptoms may include severe irritation and
burns to the nose, throat, and respiratory tract.
Aggravated Medical ConditionPreexisting disorders of the following organs (or organ systems) may be aggravated by exposure
to this material:, skin, lung (for example, asthma-like conditions)Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin, lung (for example, asthma-like conditions), Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias.
SymptomsSigns and symptoms of exposure to this material through breathing, swallowing, and/or passage
of the material through the skin may include:, irritation (nose, throat, airways)Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Lowered blood pressure, Shortness of breath, May cause methemoglobinemia, a blood abnormality that may cause headache, difficulty breathing, lightheadedness, weakness, confusion, rapid heart rate and cyanosis (lack of oxygen in the tissues causing blue-colored skin and nails).
Target OrgansNo data
CarcinogenicityBased on the available information, this material cannot be classified with regard to
carcinogenicity. This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA).
Reproductive hazardBased on the available information, risk to the fetus from maternal exposure to this material
Page: 3SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
TRIPOTASSIUM PHOSPHATE 7778-53-2 >=1.5-<5%
4. FIRST AID MEASURES
EyesIf material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes
while holding eyelids apart. If symptoms develop as a result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention.
SkinImmediately flush skin with water for at least 15 minutes while removing contaminated clothing
and shoes. Seek immediate medical attention. Wash clothing before reuse and discard contaminated shoes.
IngestionSeek immediate medical attention. Do not induce vomiting. Vomiting will cause further
damage to the mouth and throat. If individual is conscious and alert, immediately rinse mouth with water and give milk or water to drink. If possible, do not leave individual unattended.
InhalationIf symptoms develop, immediately move individual away from exposure and into fresh air. Seek
immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
Notes to physicianHazards: Overexposure to this product (or a component) may cause methemoglobinemia,
which in sufficient concentration causes cyanosis. Severe cyanosis may require intravenous injection of methylene blue. Methylene blue is contraindicated if the patient has confirmed or suspected glucose-6-phosphate dehydrogenase deficiency.
Treatment: No information available.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing mediaWater spray, Carbon dioxide (CO2), Dry chemical
Hazardous combustion products
Page 3 / 11
Page: 4SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
May form:, carbon dioxide and carbon monoxide, Phosphorus compounds carbon dioxide and carbon monoxide, nitrogen compounds, nitrogen oxides (NOx)
Precautions for fire-fightingWear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).
6. ACCIDENTAL RELEASE MEASURES
Personal precautionsNo data
Environmental precautionsPrevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper
authorities as required, that a spill has occurred.
Methods for cleaning upPersons not wearing protective equipment should be excluded from area of spill until clean-up
has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. Absorb liquid on vermiculite, floor absorbent or other absorbent material.
7. HANDLING AND STORAGE
HandlingContainers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
StorageStore in a cool, dry, ventilated area, away from incompatible substances.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure GuidelinesContains no substances with occupational exposure limit values.
General adviceThese recommendations provide general guidance for handling this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect
Page 4 / 11
Page: 5SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities.
Exposure controlsProvide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure
below TLV(s).
Eye protectionChemical splash goggles and face shield (8" min.) in compliance with OSHA regulations are
advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist.)
Skin and body protection
To prevent skin contact, wear impervious clothing and boots.Wear resistant gloves such as:NeopreneNitrile rubberpolyvinyl chloridePolyethylene
Respiratory protectionIf workplace exposure limit(s) of product or any component is exceeded (see exposure
guidelines), a NIOSH-approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state liquidForm no data availableColour light yellow Odour no data availableBoiling point/boiling range no data availableMelting point/range 14 °F / -10 °C
Sublimation point no data availablepH 12.5 Flash point
Page 5 / 11
Page: 6SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
not applicableIgnition temperature no data availableEvaporation rate no data availableLower explosion limit/Upper explosion limit no data availableParticle size no data availableVapour pressure no data availableRelative vapour density no data availableDensity 1.116 g/cm3 @ 77 °F / 25 °C
9.310 lb/gal @ 77 °F / 25 °CBulk density No dataWater solubility completely solubleSolubility(ies) no data availablePartition coefficient: n-octanol/water no data availablelog Pow no data availableAutoignition temperature no data availableViscosity, dynamic no data availableViscosity, kinematic no data availableSolids in Solution no data availableDecomposition temperature no data availableBurning number no data availableDust explosion constant no data availableMinimum ignition energy no data available
10. STABILITY AND REACTIVITY
StabilityStable.
Conditions to avoidDo not allow evaporation to dryness., Exposure to moisture.
BiodegradabilitySODIUM NITRITE : no data available
TRIPOTASSIUM PHOSPHATE : no data available
BioaccumulationSODIUM NITRITE : no data available
Page 7 / 11
Page: 8SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
TRIPOTASSIUM PHOSPHATE : no data available
Ecotoxicity effects
Toxicity to fishSODIUM NITRITE : 96 h static test LC 50 Danio rerio (zebra fish): 130.00
mg/l 96 h flow-through test LC 50 Fathead minnow (Pimephales promelas): 2.35 - 3.81 mg/l 96 h flow-through test LC 50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 0.09 - 0.13 mg/l 96 h LC 50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 0.15 - 0.20 mg/l Method: Flow through; Mortality
TRIPOTASSIUM PHOSPHATE : no data available
Toxicity to daphnia and other aquatic invertebrates.SODIUM NITRITE : 96 h static test LC 50 Water flea (Daphnia magna):
8.30 mg/l
TRIPOTASSIUM PHOSPHATE : no data available
Toxicity to algae
SODIUM NITRITE : no data available
TRIPOTASSIUM PHOSPHATE : no data available
Toxicity to bacteriaSODIUM NITRITE : no data available
TRIPOTASSIUM PHOSPHATE : no data available
Biochemical Oxygen Demand (BOD)SODIUM NITRITE : no data available
TRIPOTASSIUM PHOSPHATE : no data available
Chemical Oxygen Demand (COD)SODIUM NITRITE : no data available
TRIPOTASSIUM PHOSPHATE : no data available
Page 8 / 11
Page: 9SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
Additional ecological informationSODIUM NITRITE : no data available
TRIPOTASSIUM PHOSPHATE : no data available
13. DISPOSAL CONSIDERATIONS
Waste disposal methodsDispose of in accordance with all applicable local, state and federal regulations. For assistance
with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at 800-637-7922.
14. TRANSPORT INFORMATION
REGULATIONID NUMBER
PROPER SHIPPING NAME *HAZARD CLASS
SUBSIDIARY HAZARDS
PACKING GROUP
MARINE POLLUTANT / LTD. QTY.
U.S. DOT - ROADUN 1760 Corrosive liquids, n.o.s.
(SODIUM NITRITE)8 II
U.S. DOT - RAILUN 1760 Corrosive liquids, n.o.s.
(SODIUM NITRITE)8 II
U.S. DOT - INLAND WATERWAYSUN 1760 Corrosive liquids, n.o.s.
(SODIUM NITRITE)8 II
TRANSPORT CANADA - ROADUN 1760 CORROSIVE LIQUID, N.O.S.
(SODIUM NITRITE)8 II
TRANSPORT CANADA - RAILUN 1760 CORROSIVE LIQUID, N.O.S.
(SODIUM NITRITE)8 II
Page 9 / 11
Page: 10SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
TRANSPORT CANADA - INLAND WATERWAYSUN 1760 CORROSIVE LIQUID, N.O.S.
(SODIUM NITRITE)8 II
INTERNATIONAL MARITIME DANGEROUS GOODSUN 1760 CORROSIVE LIQUID, N.O.S.
(SODIUM NITRITE)8 II
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGOUN 1760 Corrosive liquid, n.o.s. (SODIUM
NITRITE)8 II
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGERUN 1760 Corrosive liquid, n.o.s. (SODIUM
NITRITE)8 II
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTESUN 1760 LIQUIDO CORROSIVO, N.E.P.
(SODIUM NITRITE)8 II
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.
15. REGULATORY INFORMATION
WHMIS ClassificationD1B Toxic Material Causing Immediate and Serious Toxic Effects
E Corrosive Material
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
Canadian National Pollutant Release Inventory (NPRI)SODIUM NITRITE 9.99 %
Page 10 / 11
Page: 11SAFETY DATA SHEET Revision Date: 01/31/2011
Print Date: 3/14/2011MSDS Number: R0374522
CSW 600 34779
Version: 2.5
Notification statusKorea. Toxic Chemical Control Law (TCCL) List y (positive listing)China. Inventory of Existing Chemical Substances y (positive listing)Australia. Industrial Chemical (Notification and Assessment) Act
y (positive listing)
Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act
y (positive listing)
US. Toxic Substances Control Act y (positive listing)EU. EINECS y (positive listing)Japan. Kashin-Hou Law List n (Negative listing)Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)
The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751).
Page 11 / 11
Econosol
Sn97/Cu3
Econosol
SolderingRemelting
In Canada:AIM9100 Henri Bourassa EastMontreal, QCH1E 2S4(514) 494-2000
In the United States:AIM25 Kenney DriveCranston, RI(800) CALL-AIM
CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.
:
:
:
:
:
:
Medical conditionsaggravated by over-exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.
:
Odor : Odorless.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).
2 .
Tin 7440-31-5 97Copper 7440-50-8 3
Composition/information on ingredientsName CAS number %
3 .
Page: 1/86/17/2010.
Econosol
Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Get medicalattention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of waterfor at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash clothing before reuse. Cleanshoes thoroughly before reuse. Get medical attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.
First aid measuresEye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
4 .
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It maybe dangerous to the person providing aid to give mouth-to-mouth resuscitation.
May be combustible at high temperature.
Decomposition products may include the following materials:metal oxide/oxides
Use an extinguishing agent suitable for the surrounding fire.
Massive metal is nonflammable.
Fire-fighting measuresFlammability of the product
Products of combustion
Extinguishing media
Special remarks on firehazards
Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.
No specific fire or explosion hazard.
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
:
:
5 .
Special exposure hazards :
None known.
Suitable :
Not suitable :
No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Provide adequate ventilation.Wear appropriate respirator when ventilation is inadequate. Put on appropriate personalprotective equipment (see section 8).
Move containers from spill area. Approach release from upwind. Prevent entry intosewers, water courses, basements or confined areas. Vacuum or sweep up materialand place in a designated, labeled waste container. Dispose of via a licensed wastedisposal contractor. Note: see section 1 for emergency contact information and section13 for waste disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).
Personal precautions :
Methods for cleaning up :
6 .
Page: 2/86/17/2010.
Econosol
Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination.
Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Do not ingest. Avoid contact with eyes, skin and clothing. Keep in the original containeror an approved alternative made from a compatible material, kept tightly closed when notin use. Empty containers retain product residue and can be hazardous. Do not reusecontainer.
Handling and storageHandling
Storage
:
:
7 .
Tin ACGIH TLV (United States, 1/2005).TWA: 2 mg/m³ 8 hour(s). Form: All forms
NIOSH REL (United States, 12/2001). Notes: Note: The REL and PELalso apply to other inorganic tin compounds (as Sn) except tinoxides.
Copper ACGIH TLV (United States, 1/2005). Notes: Adopted Valuesenclosed are those for which changes are proposed. Consult theNotice of Intended Changes for current proposal. See Notice ofIntended changes.
TWA: 1 mg/m³ 8 hour(s). Form: All forms
NIOSH REL (United States, 12/2001). Notes: Note: The REL and PELalso apply to other copper compounds (as Cu) except Copperfumes.
TWA: 1 mg/m³ 10 hour(s). Form: Dusts and Mists
OSHA PEL (United States, 8/1997).TWA: 1 mg/m³ 8 hour(s). Form: Dusts and Mists
ACGIH TLV (United States, 1/2005). Notes: Substances for whichthe TLV is higher than the OSHA Permissible Exposure Limit (PEL)
Exposure controls/personal protectionProduct name Exposure limits
8 .
Page: 3/86/17/2010.
Econosol
Exposure controls/personal protection8 .and/or the NIOSH Recommended Exposure Limit (REL). See CFR58(124) :36338-33351, June 30, 1993, for revised OSHA PEL.Adopted Values enclosed are those for which changes areproposed. Consult the Notice of Intended Changes for currentproposal. See Notice of Intended changes.
TWA: 0.2 mg/m³ 8 hour(s). Form: Fume
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.
Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.
Personal protection
Eyes
Skin
Respiratory
Consult local authorities for acceptable exposure limits.
:
:
:
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.
Hands :
Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product contains ingredientswith exposure limits, use process enclosures, local exhaust ventilation or otherengineering controls to keep worker exposure below any recommended or statutorylimits.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.
Solid.
Not dispersible in the following materials: cold water, hot water, methanol, diethyl ether,n-octanol and acetone.
Insoluble in the following materials: cold water, hot water, methanol, diethyl ether, n-octanol and acetone.
Odorless.
Silver-grey.
Physical and chemical propertiesPhysical state
Dispersibility properties
Solubility
Odor
Color
:
:
:
:
:
9 .
The product is stable.
Reactive or incompatible with the following materials: oxidizing materials, acids andmoisture.
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
Stable in normal conditions. Over melting point, will emit toxic metallic oxides.
Stability and reactivityStability and reactivity
Conditions of instability
Incompatibility with varioussubstances
Hazardous decompositionproducts
Hazardous polymerization
:
:
:
:
:
10 .
Non-flammable in the presence of the following materials or conditions: open flames,sparks and static discharge, heat, shocks and mechanical impacts, oxidizing materialsand reducing materials.Massive metal is nonflammable.
Conditions of reactivity :
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Econosol
Stability and reactivity10 .Non-explosive in the presence of the following materials or conditions: open flames,sparks and static discharge, heat and shocks and mechanical impacts.
Toxicological information
Specific effects
Carcinogenic effects No known significant effects or critical hazards.
Mutagenic effects No known significant effects or critical hazards.
Teratogenicity /Reproductive toxicity
No known significant effects or critical hazards.
Very hazardous by the following route of exposure: of ingestion, of inhalation.Hazardous by the following route of exposure: of skin contact (irritant, sensitizer), of eyecontact (irritant).
CARCINOGENIC EFFECTS: Classified None. by NIOSH [TIN]. Classified None. byNIOSH [COPPER].Contains material which causes damage to the following organs: kidneys, lungs, liver,upper respiratory tract, skin, eye, lens or cornea.
Fumes and dust may irritate eyes, digestive system and respiratory tract.MOLTEN METAL can cause severe BURNS!
Overexposure to fumes may cause irritation to the respiratory tract, digestive system andto the eyes. Overexposure to tin oxide fumes may result in benigne pneumoconiosis(stannosis). Repeated and prolonged contact may cause skin irritation, dermatitisand/or an allergic skin reaction (sensitization) in susceptible individuals..
Chronic effects on humans
Other toxic effects onhumans
Special remarks on chroniceffects on humans
Special remarks on othertoxic effects on humans
:
:
:
:
:
:
:
11 .
Sensitization
Ingestion No known significant effects or critical hazards.
Inhalation No known significant effects or critical hazards.
Eyes No known significant effects or critical hazards.
:
:
:
Skin : No known significant effects or critical hazards.
The products of degradation are more toxic than the product itself.
Ecological information
Toxicity of the products ofbiodegradation
Ecotoxicity data
Copper Daphnia magna (EC50)Daphnia magna (EC50)Daphnia magna (EC50)Pimephales promelas (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)
Environmental precautions : No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products viaa licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.
Waste disposal
Disposal considerations:
13 .
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Econosol
Disposal considerations13 .Disposal should be in accordance with applicable regional, national and local laws and regulations. Localregulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based oncharacteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is theresponsibility of the waste generator to determine the toxicity and physical properties of the material generated todetermine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.
Transport information
- -DOT Classification
TDG Classification -
- -
Notregulated.
- -
ADR/RID Class - - -
IMDG Class - - -
-Notregulated.
IATA-DGR Class -
Regulatoryinformation
UN number Proper shippingname
Class PG* Label Additionalinformation
-
Notregulated.
Notregulated.
-
-
-
Notregulated.
-
14 .
PG* : Packing group
Target organ effectsHCS Classification
Regulatory information
U.S. Federal regulations United States inventory (TSCA 8b): Not determined.
Clean Water Act (CWA) 307: COPPER
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: TIN; COPPERSARA 311/312 MSDS distribution - chemical inventory - hazard identification: TIN:Immediate (acute) health hazard; COPPER: Immediate (acute) health hazard
:
SARA 313
:
United States
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
15 .
COPPER 7440-50-8 3
COPPER 7440-50-8 3
Form R - Reportingrequirements
Supplier notification
:
:
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Econosol
Regulatory information15 .Connecticut Carcinogen Reporting: None of the components are listed.Connecticut Hazardous Material Survey: None of the components are listed.Florida substances: None of the components are listed.Illinois Chemical Safety Act: None of the components are listed.Illinois Toxic Substances Disclosure to Employee Act: None of the components arelisted.Louisiana Reporting: None of the components are listed.Louisiana Spill: None of the components are listed.Massachusetts Spill: None of the components are listed.Massachusetts Substances: None of the components are listed.Michigan Critical Material: None of the components are listed.Minnesota Hazardous Substances: None of the components are listed.New Jersey Hazardous Substances: None of the components are listed.New Jersey Spill: None of the components are listed.New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.New York Acutely Hazardous Substances: None of the components are listed.New York Toxic Chemical Release Reporting: None of the components are listed.Pennsylvania RTK Hazardous Substances: None of the components are listed.Rhode Island Hazardous Substances: None of the components are listed.
State regulations
CEPA Toxic substances: None of the components are listed.Canadian ARET: None of the components are listed.Canadian NPRI: None of the components are listed.Alberta Designated Substances: None of the components are listed.Ontario Designated Substances: None of the components are listed.Quebec Designated Substances: None of the components are listed.
Australia inventory (AICS): Not determined.China inventory (IECSC): Not determined.Japan inventory: Not determined.Korea inventory: Not determined.New Zealand Inventory of Chemicals (NZIoC): Not determined.Philippines inventory (PICCS): Not determined.
WHMIS (Canada) Not controlled under WHMIS (Canada).
International regulations
International lists
:
:
:
Canada
S24- Avoid contact with skin.S37- Wear suitable gloves.
R36/38- Irritating to eyes and skin.R43- May cause sensitization by skin contact.
Risk phrases
EU regulations
Safety phrases
:
:
Hazard symbol or symbols :
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulationsand the MSDS contains all the information required by the Controlled Products Regulations.
Other information
Hazardous MaterialInformation System (U.S.A.)
1
0
0
E
*Health
Fire hazard
Reactivity
Personal protection
CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.Label requirements :
:
16 .
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Econosol
Other information16 .
-ALL INGREDIENTS WITH SUSCEPTIBLE HAZARDS THAT ARE PRESENT IN ACONCENTRATION GREATER THAN 1 % ( GREATER THAN 0.1 % FORCARCINOGENS ) HAVE BEEN DISCLOSED IN THIS SAFETY DOCUMENT.
-ACGIH, Threshold Limit Values, 1994-1995. -Canada Gazette Part II, Vol. 122, No. 2Registration SOR/88-64 31 December, 1987 Hazardous Products Act "IngredientDisclosure List". -CFR29, OSHA's Permissible Exposure Limits, revision July, 1993. -CFR29, part 1910.1200, Hazard Communication. -CHEMTOX database -Components'manufacturer's Material Safety Data Sheet. -CRC Handbook of chemistry and physics,67 th edition, CRC Press inc., Boca Raton, Florida. -CSST (Comission de Santé etSécurité au Travail), document #RT-12: Classification of Certain Chemical Substances. -IATA, Dangerous Goods Regulations, 37th edition (January 1, 1996) -NFPA, FireProtection Guide to Chemical Hazards, 11th edition. -NIOSH, Pocket Guide to ChemicalHazards, revision June 1994. Sigma-Alrich handbook of fine chemicals, 1998 -TSCA(Toxic Substance Contral Act), Chemical Substance Inventory List, 1985.
References
Other specialconsiderations
00
1
National Fire ProtectionAssociation (U.S.A.)
Health
Special
Instability
Flammability
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.
CSA E4313 Prepared by The Lincoln Electric Company, Cleveland, Ohio, USA
(216) 481-8100, on the date shown above.
Section III - Hazardous Ingredients (1) I M P O R T A N T ! This section covers the materials from which this product is manufactured. The fumes and gases produced during welding with the normal use of this product are covered by Section VII; see it for industrial hygiene information. CAS Number shown is representative for the ingredients listed. All ingredients listed may not be present in all sizes. (1) The term “hazardous” in “Hazardous Ingredients” should be interpreted as a term required and defined in the Hazardous Products Act and does
not necessarily imply the existence of any hazard.
Ingredients: CAS No. Wt. % TLV mg/m3
LD50 (Route/Species)
LC50 mg/m3 (Route/Species)
Titanium dioxides 13463-67-7 10-30 10 Not Available Not Available
Iron 7439-89-6 5-10 10* Not Available Not Available
Mineral silicates 1332-58-7 5-10 5** 590 g/kg LDLo (oral/rat) reproductive
Not Available
Silicates and other binders 1344-09-8 1-5 10* 1153 mg/kg (oral/rat)
Not Available
Limestone and/or calcium carbonate 1317-65-3 1-5 10* Not Available Not Available
Iron oxides 65996-74-9 0.1-1 5 Not Available Not Available
Silicon and/or silicon alloys and compounds (as Si) 7440-21-3 0.1-1 10* Not Available Not Available
Carbon steel core wire 7439-89-6 60-100 10* Not Available Not Available
Notes: (*) Not listed. The ACGIH guideline for total particulate is 10 milligrams
per cubic meter. TLV value for iron oxide is 5 milligrams per cubic meter.
(**) As respirable dust.
(LDLo, LCLo) Lowest published toxic concentration. (#) Crystalline silica (quartz) is on the IARC (International
Agency for Research on Cancer) and NTP (National Toxicology Program) lists as posing a carcinogenic risk to humans.
Section IV - Physical Data Physical data such as odor, vapor pressure, density, evaporation rate and freezing or boiling points are not listed as they are not applicable to this product and its use.
Section V - Hazard Data Non Flammable; Welding arc and sparks can ignite combustibles and flammable products. See CSA W117.2 Section 9.7 as referenced in Section VIII. Product is inert, no special handling or spill procedures required. Rev 9/07 (CONTINUED ON SIDE TWO)
Product: Fleetweld 37+
Date: 6/20/2012
Section VI - Health Hazard Data and Toxicological Properties Acute Lethality Values: LC50 means the concentration of a substance in air that when administered by means of inhalation over a specified length of time in an animal assay, is expected to cause the death of 50% of a defined animal population.
LD50 means the single dose of a substance that, when administered by a defined route in an animal assay, is expected to cause the death of 50% of a defined animal population.
Threshold Limit Value: The ACGIH recommended general limit for Welding Fume NOS - (Not Otherwise Specified) is 5 mg/m3. The TLV-TWA is the time-weighted average concentration for a normal 8-hour workday and a 40 hour workweek, to which nearly all workers may be repeatedly exposed, day after day, without adverse effect. See Section VII for specific fume constituents which may modify this TLV. Threshold Limit Values are figures published by the American Conference of Government Industrial Hygienists. Effects of Overexposure: Electric arc welding may create one or more of the following health hazards: Fumes and Gases can be dangerous to your health. Common entry is by inhalation. Other possible routes are skin contact and ingestion. Short-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or
irritation of nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g. asthma, emphysema).
Long-term (chronic) overexposure to welding fumes can lead to siderosis (iron deposits in lung) and may affect pulmonary function.
Manganese overexposure can affect the central nervous system, resulting in impaired speech and movement. Bronchitis and some lung fibrosis have been reported. Respiratory exposure to the crystalline silica present in this welding electrode is not anticipated during normal use. Respiratory overexposure to airborne crystalline silica is known to cause silicosis, a form of disabling pulmonary fibrosis which can be progressive and may lead to death. Crystalline silica is on the IARC (International Agency for Research on Cancer) and NTP (National Toxicology Program) lists as posing a cancer risk to humans. Titanium dioxide is listed by the IARC (International Agency for Research on Cancer) as a Group 2B carcinogen (possibly carcinogenic to humans based on animal studies).
Arc Rays can injure eyes and burn skin. Skin cancer has been reported. Electric Shock can kill. If welding must be performed in damp locations or with wet clothing, on metal structures or when in cramped positions such as sitting, kneeling or lying, or if there is a high risk of unavoidable or accidental contact with workpiece, use the following equipment: Semiautomatic DC Welder, DC Manual (Stick) Welder, or AC Welder with Reduced Voltage Control.
Section VII - Reactivity Data Hazardous Decomposition Products: Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedure and electrodes used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being welded (such as paint, plating, or galvanizing), the number of welders and the volume of the worker area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities.)
When the electrode is consumed, the fume and gas decomposition products generated are different in percent and form from the ingredients listed in Section III. Decomposition products of normal operation include those originating from the volatilization, reaction, or oxidation of the materials shown in Section III, plus those from the base metal and coating, etc., as noted above.
Reasonably expected fume constituents of this product would include: Primarily iron oxide; secondarily complex oxides of
managenese, potassium, silicon, titanium.
Maximum fume exposure guideline for this product is 4.0 milligrams per cubic meter. Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. Determine the composition and quantity of fumes and gases to which workers are exposed by taking an air sample from inside the welder's helmet if worn or in the worker's breathing zone. Improve ventilation if exposures are not below limits. See ANSI/AWS F1.1, F1.2, F1.3 and F1.5, available from the American Welding Society, 550 N.W. LeJeune Road, Miami, FL 33126.
Section VIII - Preventive Measures and Precautions for Safe Handling and Use Read and understand the manufacturer's instruction and the precautionary label on the product. Request Lincoln Safety Publication E205. See Canadian Standards Association Standard CSA-W117.2 "Safety in Welding, Cutting, and Allied Processes" published by the Canadian Standards Association, 178 Rexdale Blvd., Rexdale, Ontario M9W1R3 for more details on many of the following: Ventilation: Use enough ventilation, local exhaust at the arc, or both to keep the fumes and gases from the worker's breathing zone and the general area. Train the welder to keep his head out of the fumes. Keep exposure as low as possible. Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding in confined space or general work area when local exhaust or ventilation does not keep exposure below TLV. Eye Protection: Wear helmet or use face shield with filter lens shade number 12 or darker. Shield others by providing screens and flash goggles. Protective Clothing: Wear hand, head, and body protection which help to prevent injury from radiation, sparks and electrical shock. See W117.2. At a minimum this includes welder's gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the welder not to permit electrically live parts or electrodes to contact skin . . . or clothing or gloves if they are wet. Insulate from work and ground. Disposal Information: Discard any product, residue, disposable container, or liner as ordinary waste in an environmentally acceptable manner according to Federal, State and Local regulations unless otherwise noted. No applicable ecological information available.
Section IX - Emergency and First Aid Procedures
Call for medical aid. Employ first aid techniques recommended by the Canadian Red Cross. IF BREATHING IS DIFFICULT give oxygen. IF NOT BREATHING employ CPR (Cardiopulmonary Resuscitation) techniques. IN CASE OF ELECTRICAL SHOCK, turn off power and follow recommended treatment. In all cases call a physician.
GLENGARRY CHEMICALS LTD. MATERIAL SAFETY33 Melford Drive, Unit 6 DATA SHEETScarborough, ON M1B 2G6
Phone: 416-757-1333 Fax: 416-757-9793
Emergency Telephone Numbers:
CANUTEC: 1-613-996-6666
POISON CONTROL CENTRE: 1-800-268-9017
W.H.M.I.S. CLASSIFICATION: C,D1A,D2A
SECTION I PRODUCT INFORMATION
Product Name : CLN-1010 CLEANER
Product Use : Pre-Service Cleaner
Chemical Family : Mixture
Chemical Formula : Mixture
SECTION II HAZARDOUS INGREDIENTS
COMPONENTS Wt / Wt LD50 HAZARD CAS NO.
% Oral-rat
Sodium Nitrite 1 to 10 180 mg/Kg
SECTION III PHYSICAL STATE
Appearance and Physical State : Clear straw coloured liquid
Odour : None Boiling Point (oC) : > 100 C
Specific Gravity (water = 1) : 1.00 - 1.05 Freezing Point (oC) : ~ 0
Vapour Pressure (mm Hg) : Not Available % Volatile ( by weight) : 60 - 100
Vapour Density (air = 1) : Not Available pH Product : 8.5 - 9.5
Evaporation Rate : Not Available pH 1% Solution :
Solubility in Water : Miscible Coefficient of Water/Oil Distribution : Not Available
SECTION IV FIRE AND EXPLOSION HAZARD DATA
Flammability: Non-Flammable
Upper Explosive Limit : Not Applicable Lower Explosive Limit : Not Applicable
Flash Point : Not Applicable
Means of Extinction: Appropriate for surrounding materials.
Special Procedures :
SECTION V HEALTH HAZARD DATA
A - EFFECTS OF ACUTE OVEREXPOSUREEYES:
SKIN:
INHALATION:
INGESTION:
B - EFFECTS OF CHRONIC OVEREXPOSURE
Product is not volatile, however mists may be irritating.
May cause marked irritation of the mouth, throat, esophagus, and stomach. Ingestion of large amounts
can result in acute toxic effects with nausea, methemoglobinemia, cyanosis(bluish discoloration of skin),
marked reduction in blood pressure, with collapse, coma, and possible death.
Nitrites may cause reproductive and fetal effects. Laboratory experiments have shown nitrites to have mutagenic effects.
Animal studies with nitrites have reported the development of tumors. Chronic exposures to corrosive materials may
cause dermatitis.
Toxic and strong oxidizer 7632-00-0
Causes irritation, redness and pain.
May cause irritation.
Self contained breathing apparatus and protective clothing should be worn in fighting all
fires involving chemicals.
CLN-1010 CLEANER Page 1 of 2
SECTION VI EMERGENCY AND FIRST AID
EYES:
SKIN:
INHALATION:
INGESTION:
SECTION VII TOXICOLOGICAL DATA
Exposure Limits:
Carcinogenicity:
Reproductive Effects:Mutagenic Effects:Teratogenic Effects:Sensitization:Routes of Entry:
SECTION VIII SPILL OR LEAK PROCEDURES
Steps To Be Taken In Case Material Is Spilled Or Released:
Disposal Procedures:
SECTION IX PROTECTION INFORMATIONEngineering Controls: Local Exhaust.Respiratory Protection: Not normally required.Protective Clothing: Chemical resistant Gloves, apron or impervious protective clothing.Eye Protection: Chemical safety goggles.Other Protective Equipment: Eye Wash Station and Safety Shower.
SECTION X REACTIVITY DATAStability: Stable.Conditions to Avoid: Incompatable materials, exposure to air and excessive heat, ignition sources.Hazardous Polymerization: Will Not Occur.Incompatibility to Other Substances:
Do not mix with strong acids or oxidizers. Avoid contact with combustible materials, ammonium compounds, reducing
agents, thiocyanates, and thiosulphate, chlorates, permanganates and cyanides.
The information supplied above is presented in good faith and has been derived from sources believed to be reliable. However, no
warranty, express or implied, is extended regarding its accuracy or the results to be obtained from its use. Products supplied by our
company are sold under the condition that liability for any personal injury or damage whatsoever to any property real or personal arising
from the handling or use will, in all cases, remain with the handler or user.
Ingestion, Inhalation, Skin and eye absorption.
Follow your local, provincial, and federal government chemical disposal regulations.
Avoid storage at high temperatures and store away from strong acids and strong oxidizers. Keep containers closed when
not in use. Use appropriate safety equipment, and exercise normal "good" industrial hygiene and housekeeping practices.
Thermal decomposition products are toxic and may include nitrogen dioxide and oxides of sodium.
Wear protective equipment. Contain the spill and soak up with an absorbent material. Collect for disposal.
Packing Group:
Not Available.
Ingredients are not listed as carcinogen by ACGIH,or NTP. IARC list sodium nitrite as 2A -
Group 2A: Probably carcinogenic to humans. Under certain conditions nitrite compounds
may react with secondary amines to form potentially carcinogenic nitrosamines.
Immediately wash the affected areas with plenty of water. If irritation, redness or burning sensation
develops obtain medical advice.
See Section V(B)
No information is available.
See Section V(B)See Section V(B)
Remove to fresh air.
Do not attempt to give anything by mouth to an unconscious person. If person is alert and not convulsing
rinse mouth out and give large quantities of water to dilute. Do not induce vomiting unless directed to do so
by medical personnel. Seek medical attention immediately.
Wash with copious amount of cold water for at least 20 minutes keeping eyelids open. If irritation persists,
repeat flushing and obtain medical attention immediately.
CLN-1010 CLEANER Page 2 of 2
Handy Hi-Temp Flux, Boron-modified Material Safety Data Sheet 1. Product and Company Identification ------------------------------------- Suppliers --------- Lucas Milhaupt, Inc. Lucas-Milhaupt Toronto 5656 South Pennsylvania Avenue 290 Carlingview Drive Cudahy, WI 53110 Rexdale, ON M9W5G1 Canada Telephone: 414-769-6000 Telephone: 416-675-1860 www.lucasmilhaupt.com www.lucasmilhaupt.com Manufacturer ------------ Lucas-Milhaupt, Inc. 5656 South Pennsylvania Avenue Cudahy, WI 53110 USA Telephone: 414-769-6000 www.lucasmilhaupt.com Emergency Phone Number ---------------------- Chemtrec: 800-424-9300 Issue Date: 04/16/2012 Product Name: Handy Hi-Temp Flux, Boron-modified MSDS Number: 12 Product Code: 73-260; 73-261 2. Composition/Information on Ingredients ----------------------------------------- Ingredient Name CAS Number % --------------------------------------------- Boron 7440-42-8 1-5 Potassium fluoride 7789-23-3 <15 Potassium pentaborate 11128-29-3 <75 3. Hazards Identification ------------------------- Primary Routes(s) of Entry -------------------------- Ingestion; Inhalation Eye Hazards ----------- This product can cause eye irritation, or injury upon prolonged contact. Skin Hazards ------------ This product may produce irritation, particularly on abraded skin. Prolonged exposure may cause dermatitis. Ingestion Hazards -----------------
Some components of this product are potentially toxic if ingested, and may cause one or more of these symptoms and effects: nausea, vomiting, diarrhea, abdominal pain, gastrointestinal irritation, convulsions, tachycardia, cramps, and central nervous system depression. Inhalation Hazards ------------------ Inhalation of the components and decomposition products of this product does not pose a significant risk to health when the product is used in accordance with instructions and appropriate protective measures (see Section #8). The components/decomposition products may cause one or more of the following symptoms and effects if exposure is excessively high and/or prolonged. Acute exposure: Irritation to the nose, throat, and respiratory tract; cough, nose bleeds, nausea, vomiting, chest tightness, chills, fever, tearing, pneumonitis, and pulmonary edema. Chronic exposure: Abdominal pain and cramps, liver and kidney damage, impaired pulmonary function, and fluorosis (a disease characterized by mottled teeth, osteosclerosis, and pain and loss of mobility in joints). 4. First Aid Measures --------------------- Eye --- Flush affected areas with water for at least 15 minutes. Seek medical assistance if necessary. Skin ---- Remove contaminated clothing. Wash affected area with large quantities of water for at least five minutes. Seek medical attention if necessary. Launder or dry-clean clothing before reuse. Ingestion --------- If subject is conscious, induce vomiting. If unconscious or convulsive, seek immediate medical assistance. Never attempt to give anything by mouth to an unconscious or convulsive person. Inhalation ---------- If signs and symptoms of toxicity are observed, remove subject from area, administer oxygen, and seek medical attention. Keep the subject warm and at rest. Perform artificial respiration if breathing has stopped. Note to Physician ----------------- Depending upon the dose, the component potassium fluoride may be toxic. Its concentration in the product is <150 gm/kg. Treat fluoride intoxication symptomatically. Intoxication may occur by ingestion and/or inhalation. No components are absorbed through the skin, although irritation or dermatitis may occur. 5. Fire Fighting Measures ------------------------- Flash Point: N/Appl. Autoignition Point: N/Appl.
Flammability Class: N/Appl. Lower Explosive Limit: N/Appl. Upper Explosive Limit: N/Appl. Fire and Explosion Hazards -------------------------- This product is non-flammable and non-explosive. If it is present in a fire or explosion, potential decomposition byproducts may include boron oxide, boron trifluoride, and hydrogen fluoride. Fire Fighting Instructions -------------------------- If fighting a fire in which this product is present, wear a self-contained breathing apparatus with full facepiece operated in pressure-demand or other positive pressure mode. 6. Accidental Release Measures ------------------------------ Isolate spilled product and transfer to impervious containers. Avoid contact with skin, eyes, and mucous membranes. Wear appropriate protective equipment (e.g., gloves, chemical goggles) during cleanup and disposal. 7. Handling and Storage ----------------------- Handling Precautions -------------------- Avoid contact with skin and clothing. Storage Precautions ------------------- Store in a cool place away from incompatible materials (see Section #10). Work/Hygienic Practices ----------------------- To minimize ingestion, wash hands and face before eating, drinking, applying cosmetics, or using tobacco. 8. Exposure Controls/Personal Protection ---------------------------------------- Engineering Controls -------------------- Use appropriate ventilation (e.g., dilution, local exhaust) adequate to maintain concentrations of all components and their byproducts to within their applicable standards. Eye/Face Protection ------------------- Wear eye protection adequate to prevent eye contact with the product and injury from the hazards of brazing. Plastic-frame spectacles with side shields and filter lenses (shade #3 or #4) are recommended. Skin Protection --------------- Wear appropriate protective gloves and clothing to prevent skin injuries from the hazards of brazing and/or for prolonged or repeated contact with the product. Avoid flammable fabrics.
Respiratory Protection ---------------------- If an exposure level exceeds an applicable exposure standard, use a NIOSH approved respirator having a configuration (type of facepiece, filter media, assigned protection factor, etc.) appropriate to the concentration of the contaminant(s)generated. For guidance on selection and use of respirators, consult American National Standard Z88.2 (ANSI, New York, NY 10036 USA). Ingredient(s) - Exposure Limits ------------------------------- Boron No ACGIH TLV(s) No OSHA PEL(s) Potassium fluoride ACGIH TLV: 2.5 mg/m3 TWA (as F-) OSHA PEL: 2.5 mg/m3 TWA (as F-) Potassium pentaborate No ACGIH TLV(s) No OSHA PEL(s) 9. Physical and Chemical Properties ----------------------------------- Appearance: Brown paste Odor: odorless Chemical Type: mixture Physical State: solid Boiling Point: >212F./>100C. Specific Gravity: ca. 1.7 pH Factor: ca. 9.0 Solubility (H2O): soluble Other physical properties (odor threshold, evaporation rate, vapor pressure, vapor density, oil-water partition coefficient, percent volatiles, percent VOCs) are not applicable to this product. 10. Stability and Reactivity ---------------------------- Stability: stable Hazardous Polymerization: will not occur Conditions to Avoid ------------------- Some components of product may decompose at elevated temperatures. Incompatible Materials ---------------------- Acetic anhydride; alkali and alkali earth metals; zirconium; platinum; bromine trifluoride. Hazardous Decomposition Products -------------------------------- Boron oxide, boron trifluoride, and/or hydrogen fluoride. 11. Toxicological Information ----------------------------- Carcinogenicity --------------- The product contains no chemicals classified as potential or demonstrated
carcinogens by IARC, NTP, or OSHA. Reproductive Effects -------------------- In animal feeding studies, borate salts have demonstrated adverse effects on fertility in females and testicular effects in males. Under representative conditions of occupational exposure to borate compounds, adverse reproductive effects in humans have not been observed. Mutagenicity ------------ Inorganic fluoride compounds have been demonstrated to induce mutagenic changes in mammalian cell in culture. The significance of these findings to human health risks is unknown. Conditions Aggravated By Overexposure ------------------------------------- Pre-existing pulmonary diseases (e.g., bronchitis, asthma) may be aggravated by inhalation overexposure. Chronic overexposure by ingestion or inhalation may aggravate diseases of the liver, kidneys, and the skeletal, nervous, and gastrointestinal systems. Ingredient(s) - Toxicological Data ---------------------------------- Boron LD50: 650 mg/kg (oral/rat) LC50: No data available Potassium fluoride LD50: 245mg/kg (oral/rat) LC50: No data available Potassium pentaborate LD50: No data available LC50: No data available 12. Ecological Information -------------------------- In its intended manner of use, this product should not be released into the environment, and adverse effects on ecosystems are not anticipated under recommended conditions of use, storage, and disposal. 13. Disposal Considerations --------------------------- Dispose of unused or unusable product in accordance with applicable Federal, State/Provincial, and local regulations. 14. Transport Information ------------------------- This product is not a Hazardous Substance or dangerous goods per USDOT, TDG (Canada), IATA, or IMO regulations. 15. Regulatory Information -------------------------- TSCA Information ---------------- All components of these products are listed on the EPA’s TSCA Inventory SARA Hazard Classes -------------------
Acute Health Hazard; Chronic Health Hazard SARA Section313 Notification ----------------------------- This product contains no ingredients in concentrations greater than 1% (for carcinogens 0.1%) regulated under Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 or 40 CFR 372. Canadian Regulatory Information ------------------------------- All components of these products are listed on either the Domestic Substances List (DSL) or the Nondomestic Substances List (NDSL) WHMIS Class(es) and Division(s): D1B, D2A, D2B Component(s) on Ingredients Disclosure List: Fluoride compounds, inorganic, n.o.s. 16. Other Information --------------------- HMIS Ratings ------------ Health - 3* Flammability - 0 Physical Hazard - 0 PPE - see Note Note: Lucas-Milhaupt, Inc. and Lucas-Milhaupt Toronto recommend use of safety glasses and protective gloves (Personal Protection Index "B") as standard PPE. HMIS recommends that its ratings be used only in conjunction with a fully implemented HMIS program, and that specific PPE codes be created by the user, who is familiar with the actual conditions under which the product is used. We cannot anticipate every condition of the product's use, and it is the user's responsibility to evaluate the hazards pertinent to its specific operations, and to determine the specific PPE required. NFPA Ratings ------------ Health - 3 Flammability - 0 Reactivity – 0 Revision/Preparer Information ----------------------------- This MSDS supersedes a previous MSDS dated 6/15/2009. Disclaimer ---------- Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s). Lucas Milhaupt, Inc. Lucas-Milhaupt Toronto
Appearance / Physical state: Grey paste Odour: Mild odour. Specific gravity (at 20ºC): 1.3 – 1.4 VOC Content: 53.0 g/L. Vapour pressure (at 20ºC): Not applicable. Vapour density: Not applicable. Evaporation rate: Not determined. Boiling point: Not determined. Freezing point: Not determined. pH: Not determined. Coefficient of H20 / oil distrib: Not determined. Solubility in water: Not easily mixed.
FIRE AND EXPLOSION DATA
Flash point / Method: Not applicable. Flammable limits: Not applicable. Conditions of flammability: Not determined. Auto-ignition temperature: Not applicable. Means of extinction: As appropriate for surrounding fire (e.g. Water, CO2, Dry Chemical, Foam). Special fire fighting procedures:
None known. A NIOSH-approved self-contained breathing apparatus (SCBA) should be worn when fighting fires involving chemicals.
Hazardous combustion products:
None known. Thermal decomposition products can be formed; e.g. CO and CO2.
Sensitivity to mechanical impact / static discharge:
Not susceptible to mechanical impact or to a static discharge.
Thermal decomposition products can be formed; e.g. CO and CO2.
TOXICOLOGICAL PROPERTIES
Likely routes of exposure: None known Skin contact Skin absorption Eye contact Inhalation Exposure limits: See “Ingredients” section above. Chronic effects of exposure: None known. Synergistic materials: None known.
Acute effects of exposure: Eyes: No effects expected. Skin: Prolonged and repeated contact can cause skin sensitization with some individuals (e.g. rash, itching, reddening). Inhalation: No ill effects expected. Ingestion: Effects of ingestion have not been determined. No ill effects expected. NOTE: Reaction with air and moisture during the curing process can release trace amounts of methyl ethyl ketoxime (MEKO). MEKO can be irritating to the eyes, skin and respiratory tract. The body easily metabolizes MEKO; therefore, no lasting or adverse effects are expected.
MSDS 283C, Page 2 of 2
FIRST AID MEASURES
Eyes: Flush with plenty of water. Call a physician if symptoms occur. Skin: Wash with soap and water. Seek medical attention if any effects persist. Inhalation: No ill effects expected. Should discomfort occur, move to fresh air. Ingestion: Do not induce vomiting unless directed to by a physician. Contact a Physician immediately. Other: Referral to a physician is recommended if there is any question about the seriousness of the
injury/exposure
PREVENTIVE MEASURES
Engineering controls: General (natural or mechanically induced fresh air movements). Eye protection: Safety glasses with side shields recommended. Skin protection: Impermeable gloves recommended. Respiratory protection: None normally required. Other: No additional measures are normally required. Handling procedures and equipment:
For industrial use only. Use with adequate ventilation. Keep container closed when not in use. Avoid prolonged or repeated contact with the skin. Practice good hygiene; i.e., wash after using and before eating or smoking.
Storage requirements: Keep out of reach of children. Store in a cool dry area. Keep from freezing. Store between 5º and 25º C.
Spill, leak or release: Wear appropriate personal protective equipment. Allow to cure, scrape up and place in a salvage container for proper disposal. See disposal guidelines below.
Waste disposal: No known restrictions. Consult with regulatory agencies or your corporate personnel for disposal methods that comply with local, provincial, and federal safety, health and environmental regulations.
Special shipping instructions: Avoid temperature extremes. Keep from freezing.
REGULATORY INFORMATION
WHMIS classification: D2B HMIS codes: Health 1, Flammability 0, Reactivity 0, PPE B (glasses, gloves) TDG shipping name: Not regulated.
PREPARATION INFORMATION / CONTACTS
Prepared by: Hilti, Inc., Tulsa, OK USA
Date of Preparation: May 23,2012
Emergency phone number:
1 800 424 9300
Customer Service: Hilti (Canada) Corporation, Mississauga, Ontario; 1 800 363 4458 Health / Safety contacts: Hilti, Inc., Tulsa, OK USA; 1 800 879 6000, Jerry Metcalf (x1003704) Abbreviations used: N/E = None Established. N/Ap = Not Applicable. N/Av = Not Available. HMIS: Hazardous
Materials Identification System The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or warranty of any kind expressed or implied is made with respect to the information provided.
Specific gravity (at 20ºC): 1.55 VOC Content: 71.0 g/L
Vapour pressure (at 20ºC): Not applicable. Vapour density: Not applicable. Evaporation rate: Not determined. Boiling point: Not determined.
Freezing point: Not determined. pH: Not determined. Coefficient of H20 / oil distrib: Not determined. Solubility in water: Miscible.
FIRE AND EXPLOSION DATA
Flash point / Method: Nonflammable. Flammable limits: Not applicable.
Conditions of flammability: Not applicable. Auto-ignition temperature: Not applicable. Means of extinction: Not applicable. As appropriate for surrounding fire (e.g. Water, CO2, Dry Chemical, Foam).
Special fire fighting procedures:
None known. A NIOSH-approved self-contained breathing apparatus (SCBA) should be worn when fighting fires involving chemicals.
Hazardous combustion products:
Not determined.
Sensitivity to mechanical impact / static discharge:
Not susceptible to mechanical impact or to a static discharge.
Acute effects of exposure: Eyes – Slightly alkaline material; can cause irritation but injury is unlikely. Skin - Can cause irritation with some individuals. Inhalation - No effects expected. Ingestion - Not a likely route of exposure. Effects of ingestion have not been determined.
Chronic effects of exposure: None known.
Synergistic materials: None known.
FIRST AID MEASURES
Eyes: Flush immediately with plenty of water. Call a physician if symptoms occur.
Skin: Wash with soap and water. Seek medical attention if any effects persist.
Inhalation: No ill effects expected. Should discomfort occur, move to fresh air.
Ingestion: Do not induce vomiting unless directed by a Physician. Contact a Physician immediately.
Other: Referral to a physician is recommended if there is any question about the seriousness of the injury/exposure
PREVENTIVE MEASURES
Engineering controls: General (natural or mechanically induced fresh air movements).
Eye protection: Safety glasses with side shields recommended.
Skin protection: Impermeable gloves recommended.
Respiratory protection: None normally required.
Other: No additional measures are normally required.
Handling procedures and equipment:
For industrial use only. Keep container sealed when not in use to prevent curing of the product. Avoid contact with the eyes and skin. Practice good hygiene; i.e. wash after using and before eating or smoking.
Storage requirements: Keep out of reach of children. Store in a cool dry area. Keep from freezing. Shelf life is one year from date of manufacture if stored between 40° and 77° F (5 - 25° C).
Spill, leak or release: Immediately wipe away spilled material before it hardens. Place in a container for proper disposal in accordance with all applicable local, state, or federal requirements.
Waste disposal: Consult with regulatory agencies or your corporate personnel for disposal methods that comply with local, provincial, and federal safety, health and environmental regulations.
Special shipping instructions: Avoid temperature extremes. Keep from freezing.
REGULATORY INFORMATION
WHMIS classification: D2B
HMIS codes: Health 0, Flammability 0, Reactivity 0, PPE B (glasses, gloves)
The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or warranty of any kind expressed or implied is made with respect to the information provided.
Appearance / Physical state: Blank brass cartridges. Odour: Not applicable. Specific gravity (at 20ºC): Not applicable. Odour threshold: Not applicable. Vapour pressure (at 20ºC): Not applicable. Vapour density: Not applicable. Evaporation rate: Not applicable. Boiling point: Not applicable. Freezing point: Not applicable. pH: Not applicable. Coefficient of H20 / oil distrib: Not applicable. Solubility in water: Not applicable.
FIRE AND EXPLOSION DATA
Flash point / Method: Not applicable. Flammable limits: Not applicable. Conditions of flammability: Not applicable. Auto-ignition temperature: Not applicable. Means of extinction: Water. Special fire fighting procedures:
Flood area with water or keep cartridges cool with water spray.
Hazardous combustion products:
Oxides of nitrogen, oxides of carbon, oxides of lead, metallic lead and acrid fumes.
Sensitivity to mechanical impact / static discharge:
Susceptible to mechanical impact.
REACTIVITY DATA
Stability: Explosive material. Conditions of reactivity: Explosive material. Incompatible materials: Strong acids and oxidizing materials. Conditions to avoid: Acids, excess heat, crushing and electrical currents. Hazardous decomposition products:
Oxides of nitrogen, oxides of carbon, oxides of lead, metallic lead and acrid fumes.
TOXICOLOGICAL PROPERTIES
Routes of exposure: N/Ap Skin contact Skin absorption Eye contact Inhalation Ingestion Exposure limits: See “Ingredients” section above. Acute effects of exposure: Excessive exposure to gases might cause irritation to the eyes, skin, and respiratory system.
Adverse health effects are not expected from acute exposure to fumes and gases; however, adequate ventilation, personal protective equipment, and/or good personal hygiene practices are essential to keep exposure to a minimum.
Chronic effects of exposure: Chronic (long-term) overexposure to lead can result in damage to blood-forming, nervous, urinary and reproductive systems. Organic lead compounds are not classified by IARC or NTP as carcinogens. Lead styphnate is converted to metallic lead and lead oxide during combustion. Metallic lead and lead oxide have not been tested adequately. A study by Goyer and Rhyne (1973) concluded that "there is no evidence that lead produces cancer in man".
Synergistic materials: None known.
MSDS 101C, Page 2 of 2
FIRST AID MEASURES
Eyes: If irritation occurs, flush with plenty of water. Consult a physician if symptoms persist. Skin: Practice good hygiene; i.e. wash with soap and water after using and before meals. Inhalation: Move victim to fresh air. Get medical attention if symptoms persist. Ingestion: Get immediate medical attention. Other: Seek prompt medical attention if physical injury occurs from pins, rivets, debris, etc. For bleeding
wounds, place a clean cloth or similar absorbent material on the wound and apply firm pressure. Elevate the wound and transport immediately to a medical facility.
PREVENTIVE MEASURES
Engineering controls: General (i.e., natural or mechanically induced fresh air movements). Eye protection: Suitable safety glasses with side-shields, or safety goggles. Skin protection: Cleaning powder actuated tools can result in some exposure to lead compounds. Impermeable
gloves are recommended for cleaning, otherwise wash hands thoroughly when finished and before eating or smoking.
Respiratory protection: Not normally required. Where air movement is inadequate to maintain exposure below recommended levels, wear a high efficiency particulate respirator.
Other: Hearing protection should be worn when firing powder actuated tools Handling procedures and equipment:
For industrial use only. Keep out of reach of children. Use with adequate ventilation. Use only in powder actuated tools designed to handle these boosters. All employees should be familiarized with the safe operating procedures and requirements for powder operated tools as described in ANSI A10.3. Practice good hygiene; i.e. wash after using and before eating or smoking.
Storage requirements: Store in a cool dry place. Do not crush or drop. Keep away from excessive heat (such as extremely hot surfaces and flames), electrical current, strong acids and oxidizers.
Spill, leak or release: Not applicable. Waste disposal: Misfires should be stored in a closed container until disposal or as otherwise required by local,
state, and provincial safety, health and environmental regulations. The recommended disposal method is in a burner specifically designed to destroy ammunition. Consult with regulatory agencies or your corporate personnel for disposal methods that comply with local, provincial, and federal safety, health and environmental regulations.
Special shipping instructions: None known.
REGULATORY INFORMATION
WHMIS classification: None (Exempt - Explosives) HMIS codes: Health 1, Flammability 1, Reactivity 3, PPE B (Glasses with side-shields, Gloves) ICAO/IATA Shipping Name: Cartridges, power device, Class 1.4S, UN0323 TDG shipping name: Cartridges, power device, Class 1.4S, UN0323 DOT shipping name: Consumer commodity, ORM-D
PREPARATION INFORMATION / CONTACTS
Prepared by: Hilti, Inc., Tulsa, OK USA
Date of Preparation: April 11, 2011
Emergency phone number:
1 800 424 9300
Customer Service: Hilti (Canada) Corporation, Mississauga, Ontario; 1 800 363 4458 Health / Safety contacts: Hilti, Inc., Tulsa, OK USA; 1 800 879 6000, Jerry Metcalf (x1003704) Abbreviations used: N/E = None Established. N/A = Not Applicable. N/Av = Not Available. (S) indicates exposure
should be controlled for the cutaneous routes including the mucous membranes, eyes, and skin. Airborne exposures as well as direct contact must be considered. IARC: International Agency for Research on Cancer. HMIS: Hazardous Materials Identification System
The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or warranty of any kind expressed or implied is made with respect to the information provided.
Appearance / Physical state: Red paste. Odour: Odourless.
Specific gravity (at 20ºC): 1.5 VOC Content: 75.0 g/L
Vapour pressure (at 20ºC): 23 mbar Vapour density: Not applicable. Evaporation rate: Not determined. Boiling point: Not determined.
Freezing point: Not determined. pH: Not determined. Coefficient of H20 / oil distrib: Not determined. Solubility in water: Soluble.
FIRE AND EXPLOSION DATA
Flash point / Method: Nonflammable. Flammable limits: Not applicable.
Conditions of flammability: Not applicable. Auto-ignition temperature: Not applicable. Means of extinction: As appropriate for surrounding fire (e.g. Water, CO2, Dry Chemical, Foam).
Special fire fighting procedures:
None known. A NIOSH-approved self-contained breathing apparatus (SCBA) should be worn when fighting fires involving chemicals.
Hazardous combustion products:
Thermal decomposition products such as oxides of carbon and nitrogen can be produced under fire conditions. See below.
Sensitivity to mechanical impact / static discharge:
Not susceptible to mechanical impact or to a static discharge.
REACTIVITY DATA
Stability: Stable. Conditions of reactivity: None known.
Incompatible materials: Strong acids, peroxides and oxidizing agents.
Hazardous decomposition products:
None known. Thermal decomposition can yield CO and CO2.
Acute effects of exposure: Eyes: Can cause irritation or watering but injury is unlikely. Skin: Prolonged or repeated contact can cause irritation. Inhalation: No effects expected. Ingestion: Not a likely route of exposure. Considered to have a low acute oral toxicity.
Chronic effects of exposure: None known.
Synergistic materials: None known.
MSDS 259C, Page 2 of 2
FIRST AID MEASURES
Eyes: Flush with plenty of water. Contact a physician if symptoms occur.
Skin: Wash with soap and water. Seek medical attention if any effects persist.
Inhalation: No ill effects expected. Should discomfort occur, move to fresh air.
Ingestion: Do not induce vomiting unless directed by a Physician. Contact a physician immediately.
Other: Referral to a physician is recommended if there is any question about the seriousness of the injury/exposure
PREVENTATIVE MEASURES
Engineering controls: General (natural or mechanically induced fresh air movements).
Eye protection: Safety glasses with side shields are recommended.
Skin protection: Impermeable gloves recommended.
Respiratory protection: None normally required.
Other: No additional measures are normally required.
Handling procedures and equipment:
For industrial use only. Keep out of reach of children. Keep container closed when not in use. Do not get into the eyes. Avoid prolonged or repeated contact with the skin. Practice good hygiene; i.e., wash after using and before eating or smoking.
Storage requirements: Store in a cool dry area. Keep from freezing. Store between 5º and 25º C.
Spill, leak or release: Immediately wipe away spilled material before it hardens. Place in a container for proper disposal in accordance with all applicable local, state, or federal requirements.
Waste disposal: Consult with regulatory agencies or your corporate personnel for disposal methods that comply with local, provincial, and federal safety, health and environmental regulations.
Special shipping instructions: Avoid temperature extremes. Keep from freezing.
REGULATORY INFORMATION
WHMIS classification: D2A, D2B
HMIS codes: Health 1, Flammability 0, Reactivity 0, PPE A
Health / Safety contacts: Hilti, Inc., Tulsa, OK USA; 1 800 879 6000, Jerry Metcalf (x71003704)
Abbreviations used: N/E = None Established. N/A = Not Applicable. N/Av = Not Available. R = as “respirable fraction”. IARC: International Agency for Research on Cancer. HMIS: Hazardous Materials Identification System
The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or warranty of any kind expressed or implied is made with respect to the information provided.
Product name: HIT- HY150 MAX Description: Methacrylate resin and hardener. Part A is in the large tube; Part B is in the small tube. Supplier: Hilti, Inc. P.O. Box 21148, Tulsa, OK 74121 Emergency # (Chem-Trec.): 1 800 424 9300 (USA, PR, Virgin Islands, Canada); 001 703 527 3887 (other countries)
INGREDIENTS AND EXPOSURE LIMITS Ingredients: CAS Number: TLV: PEL: STEL: Part A: Quartz sand 14808-60-7 0.025 mg/m3 (R) 10 mg/m3(R)
%SiO2 + 2 NE
1,4 Butanediol Dimethacrylate 2082-81-7 NE NE NE Part B: Quartz sand 14808-60-7 0.025 mg/m3 (R) 10 mg/m3(R)
%SiO2 + 2 NE Aluminum oxide 001344-28-1 1 mg/m3 (R) 5 mg/m3(R) NE
Dibenzoyl peroxide 00094-36-0 5 mg/m3 5 mg/m3 NE Amorphous silica 07631-86-9 NE NE NE Abbreviations: NJ TSRN indicates New Jersey Trade Secret Registry Number. (R) indicates “as respirable dust”. (N) indicates “as nuisance dust”. PEL = OSHA Permissible Exposure Limit. TLV = ACGIH Threshold Limit Value. STEL = Short Term Exposure Limit (15 minute time-weighted average). NE = None Established. mppcf = million particles per cubic foot. (M) = Mist
PHYSICAL DATA
Appearance and Odor: Gray paste. Ester-like odor. VOC Content: 7.0 g/l Boiling Point: Not determined Vapor Pressure (@68 º F) 0 mm Hg Vapor Density: (air = 1) Not determined Odor Threshold Not determined Evaporation Rate: Not determined Solubility in Water: Insoluble Specific Gravity: 1.8 pH: 6-7
FIRE AND EXPLOSION HAZARD DATA
Flash Point: 228° F Flammable Limits: Not determined Extinguishing Media: CO2, Dry Chemical, Foam, Water spray Special Fire Fighting Procedures:
Use a self-contained breathing apparatus when fighting fires involving chemicals.
Unusual Fire and Explosion Hazards:
None known. Thermal decomposition products can be formed.
REACTIVITY DATA
Stability: Dibenzoyl peroxide decomposes (non-violently) at 150º F. Ignition does not occur due to the water content (> 5%).
Hazardous Polymerization: Will not occur.
Incompatibility: Strong acids and oxidizing agents. Do not store in direct sunlight.
Decomposition Products: Thermal decomposition can yield CO, CO2 and NOx. Conditions to Avoid: Avoid temperature extremes which could shorten the shelf-life of this product; i.e. below 41º F
freezing and above 77º F. (See handling and storage requirements).
HEALTH HAZARD DATA
Known Hazards: Eye and skin irritation. Possible sensitizer. Signs and Symptoms of Exposure:
Eyes: can cause irritation. Skin: Prolonged and repeated contact can cause irritation. An allergic skin reaction (sensitization e.g. rash, itching, reddening) can occur with some individuals. Inhalation: Possible irritation. Ingestion: Not a likely route of exposure.
Routes of Exposure: Contact. Inhalation. Carcinogenicity: IARC classifies crystalline silica (quartz sand) as a Gp I carcinogen based upon evidence among
workers in industries where there has been long-term and chronic exposure (via inhalation) to silica dust; e.g. mining, quarry, stone crushing, refractory brick and pottery workers. This product does not pose a dust hazard; therefore, this classification is not relevant.
Medical Conditions Aggravated by Exposure:
Eye, skin, and respiratory conditions.
MSDS 306, Page 2 of 2
EMERGENCY AND FIRST AID PROCEDURES
Eyes: Flush with plenty of water. Contact a physician if symptoms occur. Skin: Wash with soap and water. Inhalation: Move victim to fresh air. Call a physician if symptoms persist. Ingestion: Contact a physician immediately. Do not induce vomiting unless directed by a physician. Other: Referral to a physician is recommended if there is any question about the seriousness of the
injury/exposure.
CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENT
Ventilation: General (natural or mechanically induced fresh air movements). Eye Protection: Safety glasses. Skin Protection: Nitrile gloves recommended.
Respiratory Protection: None normally required. Where ventilation is inadequate to control vapors, use a NIOSH-approved respirator with organic vapor cartridges. If dusts are generated during demolition or removal, wear an appropriate dust mask or respirator.
PRECAUTIONS FOR SAFE HANDLING AND USE
Handling and Storing Precautions:
Store in a cool, dry area preferably between 41º and 77º F. Do not store in direct sunlight. Keep away from open flames, heat sources and sparks. Avoid prolonged or repeated contact. Use with adequate ventilation. Always wash thoroughly after handling chemical products. For industrial use only. Keep out of reach of children.
Spill Procedures: Take up with an absorbent material and place in a container for proper disposal.
REGULATORY INFORMATION
Hazard Communication: This MSDS has been prepared in accordance with the federal OSHA Hazard Communication Standard. 29 CFR 1910.1200.
HMIS Codes: Health 1, Flammability 1, Reactivity 0, PPE B DOT Shipping Name: Not regulated IATA / ICAO Shipping Name: Not regulated TSCA Inventory Status: All other chemical components listed on TSCA inventory. SARA Title III, Section 313: This product contains 5 - 10% Benzoyl peroxide (CAS #94-36-0) which is subject to reporting
under Section 313 of SARA Title III (40 CFR Part 372). EPA Waste Code(s): Not regulated by EPA as a hazardous waste Waste Disposal Methods: Consult with regulatory agencies or your corporate personnel for disposal methods that comply
with local, state, and federal safety, health and environmental regulations.
The information and recommendations contained herein are based upon data believed to be correct; however, no guarantee or warranty of any kind expressed or implied is made with respect to the information provided.
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
IPEX SYS 15 GRY One Step HVY Low VOC Cement for PVC Plastic Pipe
Low VOC Solvent Cement for PVC Plastic Pipe
IPEX Inc. MANUFACTURER: IPS Corporation
807 Pharmacy Avenue 17109 South Main Street, Carson, CA 90248-3127
Scarborough, Ontario M1L 3K2, CAN P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight
Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate
Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-Serious
PPE B 4-Severe
Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up: Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:
Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm
Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm
20 ppm 50 ppm 50 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
GHS CLASSIFICATION:
Environmental
Category 2B
IPEX SYS 15 GRY One Step HVY Low VOC Cement for PVC Plastic Pipe
Physical
Hazard Statements
REACH
Cyclohexanone
Precautionary Statements
PRODUCT NAME:
PRODUCT USE:
DISTRIBUTOR:
Health
Component
Filename: IPEX SYS 15 One Step GRY HVY_LoVoc_1-12.xls Page 1 of 2 1/4/2012 11:17 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010IPEX SYS 15 GRY One Step HVY Low VOC Cement for PVC Plastic Pipe
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Gray, heavy syrupy liquid
Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 66°C (151°F) to 156°C (313°F)
Boiling Point: 66°C (151°F) Based on first boiling component: THF Evaporation Rate: > 1.0 (BUAC = 1)
Flash Point: -20°C (-4°F) TCC based on THF Flammability: Category 2
Specific Gravity: 0.963 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone
Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 11.8% based on THF
Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 129 mm Hg @ 20°C (68°F)based on THF
Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2 (Air = 1)
Decomposition Temperature: Not Applicable Other Data: Viscosity: Heavy bodied
VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable
Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.
Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known
Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l.
Degradability: Biodegradable
Bioaccumulation: Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONSFollow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives
Hazard Class: 3
Secondary Risk: None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
Packing Group: PG II
Label Required: Class 3 Flammable Liquid
Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3
SHIPPING NAME: ADHESIVES
UN NUMBER/PACKING GROUP: UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R11: Highly flammable.
R20: Harmful by inhalation. R66: Repeated exposure may cause skin dryness or cracking
R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.
S25: Avoid contact with eyes. S46: If swallowed, seek medical advise immediately and show this container or label.
SECTION 16 - OTHER INFORMATION Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
E-mail address: <[email protected]> Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 1/4/2012 / Updated GHS Standard Format
Intended Use of Product: Solvent Cement for PVC Plastic Pipe
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Reproductive Effects
Not Established Not EstablishedNot Established Not EstablishedNot Established
Sensitization to Product
EXCEPTION for Ground Shipping
Teratogenicity
TDG INFORMATION
Synergistic ProductsMutagenicity Embryotoxicity
Not Established
Filename: IPEX SYS 15 One Step GRY HVY_LoVoc_1-12.xls Page 2 of 2 1/4/2012 11:17 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
IPEX SYS 15 GRY One Step MED Low VOC Cement for PVC Plastic Pipe
Low VOC Solvent Cement for PVC Plastic Pipe
IPEX Inc. MANUFACTURER: IPS Corporation
807 Pharmacy Avenue 17109 South Main Street, Carson, CA 90248-3127
Scarborough, Ontario M1L 3K2, CAN P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight
Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate
Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-Serious
PPE B 4-Severe
Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up: Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:
Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm
Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm
20 ppm 50 ppm 50 ppm
Acetone 500 ppm 750 ppm 1000 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
IPEX SYS 15 GRY One Step MED Low VOC Cement for PVC Plastic Pipe
PRODUCT NAME:
PRODUCT USE:
SUPPLIER:
GHS CLASSIFICATION:
Health Environmental Physical
Category 2B
Hazard Statements Precautionary Statements
REACH
Component
Cyclohexanone
Filename: IPEX SYS 15 One Step GRY MED_LoVoc_1-12.xls Page 1 of 2 1/4/2012 11:17 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010IPEX SYS 15 GRY One Step MED Low VOC Cement for PVC Plastic Pipe
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Gray, medium syrupy liquid
Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 56°C (133°F) to 156°C (313°F)
Boiling Point: 56°C (133°F) Based on first boiling component: Acetone Evaporation Rate: > 1.0 (BUAC = 1)
Flash Point: -20°C (-4°F) TCC based on Acetone Flammability: Category 2
Specific Gravity: 0.955 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone
Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 12.8% based on Acetone
Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 190 mm Hg @ 20°C (68°F) Acetone
Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2.0 (Air = 1)
Decomposition Temperature: Not Applicable Other Data: Viscosity: Medium bodied
VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable
Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.
Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known
Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l.
Degradability: Biodegradable
Bioaccumulation: Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONSFollow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives
Hazard Class: 3
Secondary Risk: None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
Packing Group: PG II
Label Required: Class 3 Flammable Liquid
Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3
SHIPPING NAME: ADHESIVES
UN NUMBER/PACKING GROUP: UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R11: Highly flammable. R66: Repeated exposure may cause skin dryness or cracking
R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S2: Keep out of the reach of children S25: Avoid contact with eyes.
S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.
SECTION 16 - OTHER INFORMATION Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
E-mail address: <[email protected]> Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 1/4/2012 / Updated GHS Standard Format
Intended Use of Product: Solvent Cement for PVC Plastic Pipe
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product
EXCEPTION for Ground Shipping
TDG INFORMATION
Synergistic Products
Not Established Not Established Not Established Not Established Not Established Not Established
Filename: IPEX SYS 15 One Step GRY MED_LoVoc_1-12.xls Page 2 of 2 1/4/2012 11:17 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: OCT 2010
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
IPEX 636 CLR Low VOC Primer for PVC and CPVC Plastic Pipe
Low VOC Primer for PVC and CPVC Plastic Pipe
IPEX Inc. MANUFACTURER: IPS Corporation
807 Pharmacy Avenue 17109 South Main Street, Carson, CA 90248-3127
Scarborough, Ontario M1L 3K2, CAN P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight
Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate
Combustion Products: Oxides of carbon and smoke Reactivity 0 0 3-Serious
PPE B 4-Severe
Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up: Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 44°C (111°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:
Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm
Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm
20 ppm 50 ppm 50 ppm
Acetone 500 ppm 750 ppm 1000 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
IPEX 636 CLR Low VOC Primer for PVC and CPVC Plastic Pipe
PRODUCT NAME:
PRODUCT USE:
SUPPLIER:
GHS CLASSIFICATION:
Health Environmental Physical
Category 2B
Hazard Statements Precautionary Statements
REACH
Component
Cyclohexanone
Filename: IPEX 636 CLR PR_LoVoc_1-12.xls Page 1 of 2 1/4/2012 11:23 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: OCT 2010IPEX 636 CLR Low VOC Primer for PVC and CPVC Plastic Pipe
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, thin liquid
Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 56°C (133°F) to 156°C (313°F)
Boiling Point: 56°C (133°F) Based on first boiling component: Acetone Evaporation Rate: > 1.0 (BUAC = 1)
Flash Point: -20°C (-4°F) TCC based on Acetone Flammability: Category 2
Specific Gravity: 0.858 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone
Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 12.8% based on Acetone
Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 190 mm Hg @ 20°C (68°F) Acetone
Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2.0 (Air = 1)
Decomposition Temperature: Not Applicable Other Data: Viscosity: Water-thin
VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 550 g/l.
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable
Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon and smoke.
Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.
Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R11: Highly flammable.
R20: Harmful by inhalation. R66: Repeated exposure may cause skin dryness or cracking
R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.
S25: Avoid contact with eyes. S46: If swallowed, seek medical advise immediately and show this container or label.
SECTION 16 - OTHER INFORMATION Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
E-mail address: <[email protected]> Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 1/4/2012 / Updated GHS Standard Format
Intended Use of Product: Primer for PVC and CPVC Plastic Pipe
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product
EXCEPTION for Ground Shipping
TDG INFORMATION
Synergistic Products
Not Established Not Established Not Established Not Established Not Established Not Established
Filename: IPEX 636 CLR PR_LoVoc_1-12.xls Page 2 of 2 1/4/2012 11:23 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
IPEX 636 ORG Low VOC Cement for CPVC Plastic Pipe
Low VOC Solvent Cement for CPVC Plastic Pipe
IPEX Inc. MANUFACTURER: IPS Corporation
807 Pharmacy Avenue 17109 South Main Street, Carson, CA 90248-3127
Scarborough, Ontario M1L 3K2, CAN P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight
Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate
Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-Serious
PPE B 4-Severe
Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up: Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 33°C (90°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:
Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm
Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm
20 ppm 50 ppm 50 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
IPEX 636 ORG Low VOC Cement for CPVC Plastic Pipe
PRODUCT NAME:
PRODUCT USE:
SUPPLIER:
GHS CLASSIFICATION:
Health Environmental Physical
Category 2B
Hazard Statements Precautionary Statements
REACH
Component
Cyclohexanone
Filename: IPEX 636 ORG_LoVoc_1-12.xls Page 1 of 2 1/4/2012 11:23 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010IPEX 636 ORG Low VOC Cement for CPVC Plastic Pipe
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Orange, heavy syrupy liquid
Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 66°C (151°F) to 156°C (313°F)
Boiling Point: 66°C (151°F) Based on first boiling component: THF Evaporation Rate: > 1.0 (BUAC = 1)
Flash Point: -20°C (-4°F) TCC based on THF Flammability: Category 2
Specific Gravity: 0.995 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone
Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 11.8% based on THF
Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 129 mm Hg @ 20°C (68°F)based on THF
Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: <2 (Air = 1)
Decomposition Temperature: Not Applicable Other Data: Viscosity: Heavy bodied
VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 490 g/l.
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable
Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.
Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known
Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 490 g/l.
Degradability: Biodegradable
Bioaccumulation: Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONSFollow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives
Hazard Class: 3
Secondary Risk: None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
Packing Group: PG II
Label Required: Class 3 Flammable Liquid
Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3
SHIPPING NAME: ADHESIVES
UN NUMBER/PACKING GROUP: UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R11: Highly flammable. R66: Repeated exposure may cause skin dryness or cracking
R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S2: Keep out of the reach of children S25: Avoid contact with eyes.
S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.
SECTION 16 - OTHER INFORMATION Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
E-mail address: <[email protected]> Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 1/4/2012 / Updated GHS Standard Format
Intended Use of Product: Solvent Cement for CPVC Plastic Pipe
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product
EXCEPTION for Ground Shipping
TDG INFORMATION
Synergistic Products
Not Established Not Established Not Established Not Established Not Established Not Established
Filename: IPEX 636 ORG_LoVoc_1-12.xls Page 2 of 2 1/4/2012 11:23 AM
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight
Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate
Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-Serious
PPE B 4-Severe
Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up: Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:
Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm
Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm
20 ppm 50 ppm 50 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
Category 2B
Hazard Statements Precautionary Statements
REACH
Component
Cyclohexanone
IPEX 636 Transistion Low VOC Plastic Pipe Cement
PRODUCT NAME:
PRODUCT USE:
GHS CLASSIFICATION:
Health Environmental Physical
Filename: IPEX 636 TRAN_LoVoc_1-12.xls Page 1 of 2 1/4/2012 11:22 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010IPEX 636 Transistion Low VOC Plastic Pipe Cement
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, medium syrupy liquid
Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 66°C (151°F) to 156°C (313°F)
Boiling Point: 66°C (151°F) Based on first boiling component: THF Evaporation Rate: > 1.0 (BUAC = 1)
Flash Point: -20°C (-4°F) TCC based on THF Flammability: Category 2
Specific Gravity: 0.934 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone
Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 11.8% based on THF
Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 129 mm Hg @ 20°C (68°F)based on THF
Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2 (Air = 1)
Decomposition Temperature: Not Applicable Other Data: Viscosity: Medium bodied
VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 490 g/l.
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable
Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.
Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known
Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 490 g/l.
Degradability: Biodegradable
Bioaccumulation: Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONSFollow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives
Hazard Class: 3
Secondary Risk: None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
Packing Group: PG II
Label Required: Class 3 Flammable Liquid
Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3
SHIPPING NAME: ADHESIVES
UN NUMBER/PACKING GROUP: UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R11: Highly flammable.
R20: Harmful by inhalation. R66: Repeated exposure may cause skin dryness or cracking
R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.
S25: Avoid contact with eyes. S46: If swallowed, seek medical advise immediately and show this container or label.
SECTION 16 - OTHER INFORMATION Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
E-mail address: <[email protected]> Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 1/4/2012 / Updated GHS Standard Format
Intended Use of Product: Solvent cement for PVC / CPVC
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
EXCEPTION for Ground Shipping
TDG INFORMATION
Synergistic Products
Not Established Not Established Not Established Not Established Not Established Not Established
Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product
Filename: IPEX 636 TRAN_LoVoc_1-12.xls Page 2 of 2 1/4/2012 11:22 AM
IPEX Inc. 3 Place du Commerce, Suite101, Île-des-Soeurs, Verdun, PQ, Canada H3E 1H7 � (514) 769-2200 FAX (514) 769-1672
PVC PIPE LUBRICANT
LETTER OF COMPLIANCE
Scope:
This letter of compliance covers IPEX Inc. requirements for PVC Pipe Lubricant used in the joining
of PVC pipe and gasketed bells.
Some physical properties of IPEX PVC Pipe Lubricant are;
- does not freeze and is workable at temperatures to -18°C
- is water soluble
- is non-toxic
- small amounts of lubricant in water will not impart any off odour or taste to that water
- does not support bacterial growth
- does not have any deteriorating effects on rubber gaskets or pipe
Material:
IPEX PVC Pipe Lubricant complies with ANSI/NSF 61. - “Drinking Water System Components –
Health Effects” and thus is listed with NSF for potable water service.
IPEX’s PVC Pipe Lubricant is a potassium soap, that being the saponification of potassium
hydroxide and an organic oil. All ingredients and suppliers used in the manufacturing of IPEX’s PVC
Pipe Lubricant are approved by NSF. The manufacturing facilities for this lubricant are randomly
inspected by NSF at least once a year. Because of the chemical nature this lubricant it is impossible to
get bacterial contamination from that source. The lubricant is bacteria static. The lubricant will not
diminish; deplete the chlorine content during potable water pipe flush.
MSDS Sheet:
Attached to this letter is a Material Safety Data Sheet (MSDS) for IPEX’s PVC Pipe Lubricant.
This MSDS should be studied carefully by all personnel using this product so that they become aware
of the hazards, if any, of the product involved.
Color Coding:
IPEX PVC Pipe Lubricant is a light amber coloured paste with a faint pine odour.
Yours truly,
Frank Yorio
Senior Vice President, Operations
Issue Date: 2009-03-31
IPEX PVC PIPE LUBRICANT MATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEETMaterial :
SECTION 1 - MATERIAL IDENTIFICATION AND USE
Manufacturer's Name Suppliers Name
BioCANlubr icantsBioCANlubr icantsa div. of 2125278 Ontario Ltd. a div. of 2125278 Ontario Ltd.
Suppliers AddressManufacturer's Street Address100 Wilkinson Road, Unit 12 100 Wilkinson Road, Unit 12
Manufacturer's City Suppliers CityBRAMPTON BRAMPTON
Manfacturer's Province Suppliers ProvinceONTARIOONTARIO
Manufacturer's Postal Code Suppliers Postal CodeL6T 4Y9 L6T 4Y9
Vapour Pressure (mm) Vapour Density (Air=1) Evaporation Rate Boiling Point ('C) Pour Point('C)not applicable not applicable not applicable 100 ' below -22'
Density (g/ml)pHCoeffecient of water/oil distribution % Volatile (by volume) Solubility in Water (20'C)8.8 to 9.4not applicable not applicable 100 %
SECTION IV - FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability If yes, under what conditions:
XYES NO
Means of ExtinctionUse extinguishing media appropiate for surrounding fire.
Special Proceduresnot applicable
Flashpoint ('C) and method Upper explosion limit (% by volume) Lower explosion limit (% by volume)not applicable not applicable not applicable
Sensitivity to Static Discharge Explosive Power Rate of BurningExplosion DataSensitivity to Chemical Impact not applicablenot applicable not applicable
not applicable
SECTION V - REACTIVE DATA
Chemical Stability If no, under which conditions?XYES NO
Incompatibility to other substances If so, which ones?
XYES NO
Chemical Stability
Reactivity and under what conditionsnot applicable
Leaks and Spill ProcedureSpills are slippery and could cause skidding of personel and or equipment. Material can be used if not contaminatedwith foreign substances
Waste DisposalIncineration or sanitary landfill in accordance with government regulations.
Handling Procedure and Equipmentnot applicable
Storage Requirementsnot applicable
Special Shipping Information
SECTION V111 - FIRST AID MEASURESSkin
Rinse with water.
EyeRinse with water.
Inhalationnot applicable
Ingestion Drink 2 glasses of water, induce vomiting.
General advisenot applicable
SECTION IX - PREPARATION OF M.S.D.S.Additional Information / Commentsnot applicableSources Used
Prepared by A.J. HOOD DatePhone number SEPTEMBER 27, 2007
CAS #
G.P. PIPE LUBRICANT PASTE is an NSF certified product which conforms to the requirements of theNational Sanitation Foundation, Standard 61 and therefore is certified for use with potable water piping.
G.P. CHEMICALS SUBAQUEOUS LUBRICANT is an NSF certified product which conforms tothe requirements of the National Sanitation Foundation, Standard 61 and therefore is certified for
use with potable water piping.
IPEX PVC LUBRICANT LIQUID is an NSF certified product which conforms to the requirements of theNational Sanitation Foundation, Standard 61 and therefore is certified for use with potable water piping.
416-884-1635
IPEX PVC PIPE LUBRICANT MATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEETMaterial :
SECTION 1 - MATERIAL IDENTIFICATION AND USE
Manufacturer's Name Suppliers Name
BioCANlubr icantsBioCANlubr icantsa div. of 2125278 Ontario Ltd. a div. of 2125278 Ontario Ltd.
Suppliers AddressManufacturer's Street Address100 Wilkinson Road, Unit 12 100 Wilkinson Road, Unit 12
Manufacturer's City Suppliers CityBRAMPTON BRAMPTON
Manfacturer's Province Suppliers ProvinceONTARIOONTARIO
Manufacturer's Postal Code Suppliers Postal CodeL6T 4Y9 L6T 4Y9
Vapour Pressure (mm) Vapour Density (Air=1) Evaporation Rate Boiling Point ('C) Pour Point('C)not applicable not applicable not applicable 100 ' below -22'
Density (g/ml)pHCoeffecient of water/oil distribution % Volatile (by volume) Solubility in Water (20'C)8.8 to 9.4not applicable not applicable 100 %
SECTION IV - FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability If yes, under what conditions:
XYES NO
Means of ExtinctionUse extinguishing media appropiate for surrounding fire.
Special Proceduresnot applicable
Flashpoint ('C) and method Upper explosion limit (% by volume) Lower explosion limit (% by volume)not applicable not applicable not applicable
Sensitivity to Static Discharge Explosive Power Rate of BurningExplosion DataSensitivity to Chemical Impact not applicablenot applicable not applicable
not applicable
SECTION V - REACTIVE DATA
Chemical Stability If no, under which conditions?XYES NO
Incompatibility to other substances If so, which ones?
XYES NO
Chemical Stability
Reactivity and under what conditionsnot applicable
Leaks and Spill ProcedureSpills are slippery and could cause skidding of personel and or equipment. Material can be used if not contaminatedwith foreign substances
Waste DisposalIncineration or sanitary landfill in accordance with government regulations.
Handling Procedure and Equipmentnot applicable
Storage Requirementsnot applicable
Special Shipping Information
SECTION V111 - FIRST AID MEASURESSkin
Rinse with water.
EyeRinse with water.
Inhalationnot applicable
Ingestion Drink 2 glasses of water, induce vomiting.
General advisenot applicable
SECTION IX - PREPARATION OF M.S.D.S.Additional Information / Commentsnot applicableSources Used
Prepared by A.J. HOOD DatePhone number SEPTEMBER 27, 2007
CAS #
G.P. PIPE LUBRICANT PASTE is an NSF certified product which conforms to the requirements of theNational Sanitation Foundation, Standard 61 and therefore is certified for use with potable water piping.
G.P. CHEMICALS SUBAQUEOUS LUBRICANT is an NSF certified product which conforms tothe requirements of the National Sanitation Foundation, Standard 61 and therefore is certified for
use with potable water piping.
IPEX PVC LUBRICANT LIQUID is an NSF certified product which conforms to the requirements of theNational Sanitation Foundation, Standard 61 and therefore is certified for use with potable water piping.
416-884-1635
IPEX PVC PIPE LUBRICANT MATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEETMaterial :
SECTION 1 - MATERIAL IDENTIFICATION AND USE
Manufacturer's Name Suppliers Name
BioCANlubr icantsBioCANlubr icantsa div. of 2125278 Ontario Ltd. a div. of 2125278 Ontario Ltd.
Suppliers AddressManufacturer's Street Address100 Wilkinson Road, Unit 12 100 Wilkinson Road, Unit 12
Manufacturer's City Suppliers CityBRAMPTON BRAMPTON
Manfacturer's Province Suppliers ProvinceONTARIOONTARIO
Manufacturer's Postal Code Suppliers Postal CodeL6T 4Y9 L6T 4Y9
Vapour Pressure (mm) Vapour Density (Air=1) Evaporation Rate Boiling Point ('C) Pour Point('C)not applicable not applicable not applicable 100 ' below -22'
Density (g/ml)pHCoeffecient of water/oil distribution % Volatile (by volume) Solubility in Water (20'C)8.8 to 9.4not applicable not applicable 100 %
SECTION IV - FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability If yes, under what conditions:
XYES NO
Means of ExtinctionUse extinguishing media appropiate for surrounding fire.
Special Proceduresnot applicable
Flashpoint ('C) and method Upper explosion limit (% by volume) Lower explosion limit (% by volume)not applicable not applicable not applicable
Sensitivity to Static Discharge Explosive Power Rate of BurningExplosion DataSensitivity to Chemical Impact not applicablenot applicable not applicable
not applicable
SECTION V - REACTIVE DATA
Chemical Stability If no, under which conditions?XYES NO
Incompatibility to other substances If so, which ones?
XYES NO
Chemical Stability
Reactivity and under what conditionsnot applicable
Leaks and Spill ProcedureSpills are slippery and could cause skidding of personel and or equipment. Material can be used if not contaminatedwith foreign substances
Waste DisposalIncineration or sanitary landfill in accordance with government regulations.
Handling Procedure and Equipmentnot applicable
Storage Requirementsnot applicable
Special Shipping Information
SECTION V111 - FIRST AID MEASURESSkin
Rinse with water.
EyeRinse with water.
Inhalationnot applicable
Ingestion Drink 2 glasses of water, induce vomiting.
General advisenot applicable
SECTION IX - PREPARATION OF M.S.D.S.Additional Information / Commentsnot applicableSources Used
Prepared by A.J. HOOD DatePhone number SEPTEMBER 27, 2007
CAS #
G.P. PIPE LUBRICANT PASTE is an NSF certified product which conforms to the requirements of theNational Sanitation Foundation, Standard 61 and therefore is certified for use with potable water piping.
G.P. CHEMICALS SUBAQUEOUS LUBRICANT is an NSF certified product which conforms tothe requirements of the National Sanitation Foundation, Standard 61 and therefore is certified for
use with potable water piping.
IPEX PVC LUBRICANT LIQUID is an NSF certified product which conforms to the requirements of theNational Sanitation Foundation, Standard 61 and therefore is certified for use with potable water piping.
416-884-1635
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
IPEX SYS 636 GRY Low VOC Cement for PVC Plastic Pipe
Low VOC Solvent Cement for PVC Plastic Pipe
IPEX Inc. MANUFACTURER: IPS Corporation
807 Pharmacy Avenue 17109 South Main Street, Carson, CA 90248-3127
Scarborough, Ontario M1L 3K2, CAN P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight
Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate
Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-Serious
PPE B 4-Severe
Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up: Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:
Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm
Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm
20 ppm 50 ppm 50 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
IPEX SYS 636 GRY Low VOC Cement for PVC Plastic Pipe
PRODUCT NAME:
PRODUCT USE:
SUPPLIER:
GHS CLASSIFICATION:
Health Environmental Physical
Category 2B
Hazard Statements Precautionary Statements
REACH
Component
Cyclohexanone
Filename: IPEX SYS 636 GRY_LoVoc_1-12.xls Page 1 of 2 1/4/2012 11:14 AM
IPEX GHS SAFETY DATA SHEETDate Revised: JAN 2012
Supersedes: JAN 2010IPEX SYS 636 GRY Low VOC Cement for PVC Plastic Pipe
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Gray, medium syrupy liquid
Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 66°C (151°F) to 156°C (313°F)
Boiling Point: 66°C (151°F) Based on first boiling component: THF Evaporation Rate: > 1.0 (BUAC = 1)
Flash Point: -20°C (-4°F) TCC based on THF Flammability: Category 2
Specific Gravity: 0.9611 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone
Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 11.8% based on THF
Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 129 mm Hg @ 20°C (68°F)based on THF
Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2 (Air = 1)
Decomposition Temperature: Not Applicable Other Data: Viscosity: Medium bodied
VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable
Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.
Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known
Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l.
Degradability: Biodegradable
Bioaccumulation: Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONSFollow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives
Hazard Class: 3
Secondary Risk: None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
Packing Group: PG II
Label Required: Class 3 Flammable Liquid
Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3
SHIPPING NAME: ADHESIVES
UN NUMBER/PACKING GROUP: UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R11: Highly flammable.
R20: Harmful by inhalation. R66: Repeated exposure may cause skin dryness or cracking
R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.
S25: Avoid contact with eyes. S46: If swallowed, seek medical advise immediately and show this container or label.
SECTION 16 - OTHER INFORMATION Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
E-mail address: <[email protected]> Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 1/4/2012 / Updated GHS Standard Format
Intended Use of Product: Solvent Cement for PVC Plastic Pipe
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product
EXCEPTION for Ground Shipping
TDG INFORMATION
Synergistic Products
Not Established Not Established Not Established Not Established Not Established Not Established
Filename: IPEX SYS 636 GRY_LoVoc_1-12.xls Page 2 of 2 1/4/2012 11:14 AM
GHS SAFETY DATA SHEETDate Revised: JAN 2013
Supersedes: DEC 2011
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
WELD-ON® 810™ Low VOC 2-Component Adhesive Kit
2-Component Kit, Low VOC Adhesive for for bonding large diameter PVC and CPVC pipe and fittings; also bonds ABS, Styrene, Acrylic, FRP
(fiberglass-reinforced polyester), aluminum (non-anodized), other metals, concrete, clay and other materials to themselves or to dissimilar materials.
MANUFACTURER: IPS Corporation
600 Ellis Road, Durham,NC 27703 - USA
P.O. Box 12729, Research Triangle Park, NC 27709 - USA
Tel. 1-919-598-2400
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
*Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
Engineering Controls: Use local exhaust as needed.
Monitoring: Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Avoid contact with eyes, wear splashproof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,
Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Use in a well-ventilated room. Use local exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above. With normal use, the Exposure Limit Value will not usually be reached.
When limits approached, use respiratory protection equipment.
Category 2B
Hazard Statements Precautionary Statements
Component
GHS CLASSIFICATION:
Health Environmental Physical
WELD-ON® 810™ Low VOC 2-Component Adhesive
PRODUCT NAME:
PRODUCT USE:
SUPPLIER:
FileName: W-O810LoVOC_1-13.xls Page 1 of 2 FOR REVIEW 1/14/2013 9:34 AM
GHS SAFETY DATA SHEETDate Revised: JAN 2013
Supersedes: DEC 2011WELD-ON® 810™ Low VOC 2-Component Adhesive
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: "A" White, viscous liquid; "B" Clear, syrupy liquid
Odor: "A" Acrid odor, "B" Ketone Odor Threshold: "A" 0.75 ppm (MMA)
P.H.: Not Applicable "B" 5.4 ppm (MEK)
Boiling Point: "A" -100.5°C (212.9°F) Based on first boiling component: MMA Evaporation Rate: "A" > 1.0 (BUAC = 1), "B" <1
"B" 180C (175°F) based on MEK Flammability: "A" Category 2, "B" Category 4
Flash Point: "A" 10.6°C (51°F) T.C.C. based on MMA Flammability Limits: LEL: "A" 1.6, "B" - 1.8
Specific Gravity: "A" 1.053 @23°C (73°F), "B" 0.950 @23°C (73°F) UEL: "A" 12.5, "B" - 11.5
Solubility: "A" Slight in Water (MMA); "B" 27.5%/MEK @ 20°C (68°F) Vapour Pressure: "A"-29 mm Hg @ 20°C (68°F)
Auto-ignition Temperature: "A" 421°C (789.8°F): MMA, "B" 404°C (759°F): MEK "B"-71. mm Hg for MEK
Decomposition Temperature: "A" - N/A, "B" - N/A Vapour Density: "A" > 3 Air = 1), "B" - N/E
VOC Content: "A" < 50 g/l mixed, "B" N/E Other Data: Viscosity: Thick syrupy liquid
SECTION 10 - STABILITY AND REACTIVITY Stability: Stable
Hazardous decomposition products: None in normal use. Oxides of carbon, oxides of nitrogen, hydrogen chloride, hydrocarbons,
acrid smoke and toxic gases upon combustion.
Conditions to avoid: Keep away from direct sunlight, heat, temperatures above 29°C (85°F), sparks, open flame and other ignition sources.
Incompatible Materials: Reducing and oxidizing agents and metal contaminants
SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.
SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None known
Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 50 g/l
Degradability: Not Established
BioAccumulation: Not Established
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS Follow local and national regulations. Consult local disposal expert.
SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives
Hazard Class: 3
Secondary Risk None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
Packing Group: PG II
Label Required: Class 3 Flammable Liquid
Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3
SHIPPING NAME: ADHESIVES
UN NUMBER/PACKING GROUP: UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)
Risk Phrases: R-11 Highly Flammable
R-20 Harmful by inhalation R-36/37/38 Irritating to eyes, respiratory system and skin
R-21 Harmful if contact with skin
R-22 Harmful if swallowed R-43 May cause sensitization by skin contact.
Safety Phrases: S-2 Keep out of reach of children S-24/25 Avoid contact with skin and eyes.
S-7 Keep container tightly closed when not in use S-29 Do not empty into drains
S-9 Keep container in a well-ventilated place S-37 Wear suitable gloves
S-15/16 Keep away from heat and sources of ignition. No smoking S-51 Use only in well ventilated areas
S-23 Do not breathe vapor
SECTION 16 - OTHER INFORMATION Specification Information:
Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European
E-mail address: <[email protected]> Directive on RoHS (Restriction of Hazardous Substances).
Training necessary: Yes, training in practices and procedures contained in product literature.
Reissue date / reason for reissue: 1/14/2013 / Updated GHS Standard Format
Intended Use of Product: Reactive acrylic adhesive bonding/cementing plastics and other substrates
Not recommended for use on PTFE, Silicone, Polypropylene, Polyethylene and other Polyolefin's or joints with an interference fit.
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
EXCEPTION for Ground Shipping
TDG INFORMATION
Synergistic Products
Not Established Not Established Not Established Not Established Not Established Not Established
Reproductive Effects Teratogenicity Mutagenicity Embryotyxicity Sensitization to Product
FileName: W-O810LoVOC_1-13.xls Page 2 of 2 FOR REVIEW 1/14/2013 9:34 AM
MATERIAL SAFETY DATA SHEET HMIS CODES:H F R P0 2 0 A
May be used to comply with OSHA’s HazardCommunication Standard, 29 CFR 1910.1200. Standardmust be consulted for specific requirements.
U.S. Department of LaborOccupational Safety and Health Administrator
Route(s) of Entry: Inhalation? YES Skin? YES Ingestion? YES
Health Hazards (Acute and Chronic): N/A
Carcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO
Signs and Symptoms of Exposure: INHALATION: POSSIBLE DIZZINESS IF USED IN CONFINED AREA. SKIN: MAY CAUSE MILD IRRITATION TOSENSITIVE SKIN.
Medical Conditions Generally Aggravated by Exposure: NONE KNOWN
Emergency and First Aid Procedures:EYE CONTACT: FLUSH EYES WITH WATER. SKIN CONTACT: WASH SKIN WITH SOAP AND WATER. WASHCLOTHING BEFORE REUSE. INHALATION: MOVE TO WELL VENTILATED AREA. INGESTION: CALLPHYSICIAN.
Section VII - Precautions for Safe Handling and Use
Steps to Be Taken in Case Material is Released or Spilled: NORMAL GOOD HOUSEKEEPING PROCEDURES.
Waste Disposal Method: DISPOSE OF ACCORDING TO FEDERAL, STATE, AND LOCAL REGULATIONS.
Precautions to Be Taken in Handling and Storing: STORE AWAY FROM HEAT OR OPEN FLAME. CLOSE CONTAINER AFTER USE.
Other Precautions: WEAR PROTECTIVE GLOVES TO PREVENT POSSIBLE SKIN ABSORPTION AND DERMATITIS. KEEP OUTOF REACH OF CHILDREN.
Section VIII - Control Measures
Respiratory Protection (Specify Type): AVOID BREATHING OF FUMES. IF USED IN A CONFINED AREA, A RESPIRATOR MAY BE NECESSARY.
Ventilation:Local Exhaust: NORMAL VENTILATION IS ADEQUATE. Special: N/A
Mechanical (General): N/A. Other: N/A
Protective Gloves: MAY BE NECESSARY FOR SENSITIVESKIN.
Eye Protection: KEEP OUT OF EYES. WEAR PROTECTIVE GOGGLES WHERENECESSARY.
Other Protective Clothing or Equipment: N/A
Work/Hygienic Practices: WASH UP WITH SOAP AND WATER AFTER USE.Page 2
CSA E4918-1 Prepared by The Lincoln Electric Company, Cleveland, Ohio, USA
(216) 481-8100, on the date shown above.
Section III - Hazardous Ingredients (1) I M P O R T A N T ! This section covers the materials from which this product is manufactured. The fumes and gases produced during welding with the normal use of this product are covered by Section VII; see it for industrial hygiene information. CAS Number shown is representative for the ingredients listed. All ingredients listed may not be present in all sizes. (1) The term “hazardous” in “Hazardous Ingredients” should be interpreted as a term required and defined in the Hazardous Products Act and does
not necessarily imply the existence of any hazard.
Ingredients: CAS No. Wt. % TLV mg/m3
LD50 (Route/Species)
LC50 mg/m3 (Route/Species)
Iron 7439-89-6 10-30 10* Not Available Not Available
Limestone and/or calcium carbonate 1317-65-3 10-30 10* Not Available Not Available
Titanium dioxides 13463-67-7 1-5 10 Not Available Not Available
Carbon steel core wire 7439-89-6 30-60 10* Not Available Not Available
Notes: (*) Not listed. The ACGIH guideline for total particulate is 10 milligrams
per cubic meter. TLV value for iron oxide is 5 milligrams per cubic meter.
(**) As respirable dust.
(LDLo, LCLo) Lowest published toxic concentration. (#) Crystalline silica (quartz) is on the IARC (International
Agency for Research on Cancer) and NTP (National Toxicology Program) lists as posing a carcinogenic risk to humans.
Section IV - Physical Data Physical data such as odor, vapor pressure, density, evaporation rate and freezing or boiling points are not listed as they are not applicable to this product and its use.
Section V - Hazard Data Non Flammable; Welding arc and sparks can ignite combustibles and flammable products. See CSA W117.2 Section 9.7 as referenced in Section VIII. Product is inert, no special handling or spill procedures required. Rev 9/07 (CONTINUED ON SIDE TWO)
Product: Excalibur 7018-1 MR
Date: 1/21/2013
Section VI - Health Hazard Data and Toxicological Properties Acute Lethality Values: LC50 means the concentration of a substance in air that when administered by means of inhalation over a specified length of time in an animal assay, is expected to cause the death of 50% of a defined animal population.
LD50 means the single dose of a substance that, when administered by a defined route in an animal assay, is expected to cause the death of 50% of a defined animal population.
Threshold Limit Value: The ACGIH recommended general limit for Welding Fume NOS - (Not Otherwise Specified) is 5 mg/m3. The TLV-TWA is the time-weighted average concentration for a normal 8-hour workday and a 40 hour workweek, to which nearly all workers may be repeatedly exposed, day after day, without adverse effect. See Section VII for specific fume constituents which may modify this TLV. Threshold Limit Values are figures published by the American Conference of Government Industrial Hygienists. Effects of Overexposure: Electric arc welding may create one or more of the following health hazards: Fumes and Gases can be dangerous to your health. Common entry is by inhalation. Other possible routes are skin contact and ingestion. Short-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or
irritation of nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g. asthma, emphysema).
Long-term (chronic) overexposure to welding fumes can lead to siderosis (iron deposits in lung) and may affect pulmonary function.
Manganese overexposure can affect the central nervous system, resulting in impaired speech and movement. Bronchitis and some lung fibrosis have been reported. Repeated exposure to fluorides may cause excessive calcification of the bone and calcification of ligaments of the ribs, pelvis and spinal column. May cause skin rash. Respiratory exposure to the crystalline silica present in this welding electrode is not anticipated during normal use. Respiratory overexposure to airborne crystalline silica is known to cause silicosis, a form of disabling pulmonary fibrosis which can be progressive and may lead to death. Crystalline silica is on the IARC (International Agency for Research on Cancer) and NTP (National Toxicology Program) lists as posing a cancer risk to humans. Titanium dioxide is listed by the IARC (International Agency for Research on Cancer) as a Group 2B carcinogen (possibly carcinogenic to humans based on animal studies).
Arc Rays can injure eyes and burn skin. Skin cancer has been reported. Electric Shock can kill. If welding must be performed in damp locations or with wet clothing, on metal structures or when in cramped positions such as sitting, kneeling or lying, or if there is a high risk of unavoidable or accidental contact with workpiece, use the following equipment: Semiautomatic DC Welder, DC Manual (Stick) Welder, or AC Welder with Reduced Voltage Control.
Section VII - Reactivity Data Hazardous Decomposition Products: Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedure and electrodes used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being welded (such as paint, plating, or galvanizing), the number of welders and the volume of the worker area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities.)
When the electrode is consumed, the fume and gas decomposition products generated are different in percent and form from the ingredients listed in Section III. Decomposition products of normal operation include those originating from the volatilization, reaction, or oxidation of the materials shown in Section III, plus those from the base metal and coating, etc., as noted above.
Reasonably expected fume constituents of this product would include: Primarily iron oxide and fluorides; secondarily complex oxides of manganese, potassium, silicon and sodium. Maximum fume exposure guideline for this product (based on manganese content) is 4.0 milligrams per cubic meter.
Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. Determine the composition and quantity of fumes and gases to which workers are exposed by taking an air sample from inside the welder's helmet if worn or in the worker's breathing zone. Improve ventilation if exposures are not below limits. See ANSI/AWS F1.1, F1.2, F1.3 and F1.5, available from the American Welding Society, 550 N.W. LeJeune Road, Miami, FL 33126.
Section VIII - Preventive Measures and Precautions for Safe Handling and Use Read and understand the manufacturer's instruction and the precautionary label on the product. Request Lincoln Safety Publication E205. See Canadian Standards Association Standard CSA-W117.2 "Safety in Welding, Cutting, and Allied Processes" published by the Canadian Standards Association, 178 Rexdale Blvd., Rexdale, Ontario M9W1R3 for more details on many of the following: Ventilation: Use enough ventilation, local exhaust at the arc, or both to keep the fumes and gases from the worker's breathing zone and the general area. Train the welder to keep his head out of the fumes. Keep exposure as low as possible. Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding in confined space or general work area when local exhaust or ventilation does not keep exposure below TLV. Eye Protection: Wear helmet or use face shield with filter lens shade number 12 or darker. Shield others by providing screens and flash goggles. Protective Clothing: Wear hand, head, and body protection which help to prevent injury from radiation, sparks and electrical shock. See W117.2. At a minimum this includes welder's gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the welder not to permit electrically live parts or electrodes to contact skin . . . or clothing or gloves if they are wet. Insulate from work and ground. Disposal Information: Discard any product, residue, disposable container, or liner as ordinary waste in an environmentally acceptable manner according to Federal, State and Local regulations unless otherwise noted. No applicable ecological information available.
Section IX - Emergency and First Aid Procedures
Call for medical aid. Employ first aid techniques recommended by the Canadian Red Cross. IF BREATHING IS DIFFICULT give oxygen. IF NOT BREATHING employ CPR (Cardiopulmonary Resuscitation) techniques. IN CASE OF ELECTRICAL SHOCK, turn off power and follow recommended treatment. In all cases call a physician.
Masters Cutting Oil
MATERIAL SAFETY DATA SHEET ================================================================================
SECTION I - PRODUCT IDENTIFICATION ================================================================================ Product name: MASTERS CUTTING OIL Product use: Thread Cutting Lubricant Chemical family: Hydrocarbon Cutting Oil Supplier / Manufacturer name and address: G.F. THOMPSON CO. LTD. 620 Steven Court Newmarket, Ontario L3Y 6Z2 Tel.: 905-898-2557 Emergency Tel. #: WHMIS CLASS: Not Controlled 416-786-4336 ================================================================================
SECTION II - HAZARDOUS INGREDIENTS ================================================================================ Ingredients CAS# No Hazardous Ingredients found in this product ================================================================================
SECTION III - PHYSICAL DATA ================================================================================ Physical State: Liquid Odour and appearance: Clear Golden to amber solution with petroleum odour. Specific gravity: 0.89 Vapor pressure (mm Hg @ 20°C): <0.1 Boiling point: Not Determined pH: Not Applicable Vapor density (Air = 1) : >1.0 Evaporation rate (BuAc = 1): Not Determined Freezing Point: Not Determined Solubility in water: Insoluble VOC’s: NONE *This product contains no ingredient meeting the US EPA definition of VOC. (see miscellaneous information)
SECTION IV - FIRE AND EXPLOSION DATA ================================================================================ Conditions of flammability: Will burn at temperatures above the Flash Point Extinguishing Media: Small fire – use dry powder
Large fire – use water spray, fog or foam. Do not use water jet. Flash point (Method) : >180° C / 356° F COC Upper flammable limit %: Not determined Lower flammable limit %: Not determined Hazardous Combustion Products: Oxides of Carbon and sulfur in cases of incomplete combustion,
smoke and fumes. Unusual Fire and Explosion Hazard: None known * * * NFPA CLASSIFICATION * * Health - 1 Fire - 1 Reactivity 0 ================================================================================
SECTION V - REACTIVITY DATA ================================================================================ Stability: Stable. Incompatible materials: Strong oxidizing agents: Peroxides, Chlorine, Strong Acids, etc. Hazardous Polymerization: Material is not known to polymerize. Hazardous Decomposition: Oxides of Carbon and Sulfides. ================================================================================
SECTION VI – HEALTH HAZARD INFORMATION ================================================================================
*** Routes of entry *** Inhalation: No acute effects are expected. Skin: Prolonged or repeated contact with skin may cause dryness or
mild irritation Eyes: This product can cause redness, irritation or a burning sensation. Ingestion: Small amounts ingested incidental to normal handling are not
likely to cause injury, large amounts ingested may cause injury ================================================================================
SECTION VII - FIRST AID ================================================================================ Inhalation: If breathing is difficult, remove victim to fresh air, give artificial
respiration if not breathing. Skin: Remove contaminated clothing. Wash skin thoroughly with soap
and water or waterless hand cleaner. If irritation occurs, get medical attention.
Eyes: In case of contact, check and remove any contact lenses, flush eyes with large amounts of water for at least 20 minutes. Get medical attention.
Ingestion: Do not induce vomiting unless instructed to do so by a doctor. Get medical attention.
SECTION VIII - PREVENTIVE MEASURES ================================================================================ Spill, leak or release: If material is spilled or released to the atmosphere, steps should
be taken to prevent discharges to streams or sewer systems. Spills or releases should be reported, if required, to the appropriate local, provincial and federal regulatory agencies.
Waste disposal: Clean up action should be carefully planned and executed.
Shipment, storage and / or disposal of waste materials are regulated and action to handle or dispose of spilled or released materials must meet all local, provincial and federal rules.
Storage: Protect against physical damage. Separate from oxidizing materials. Store in cool, well ventilated area of non-combustible construction away from possible sources of ignition.
*** PROTECTIVE EQUIPMENT ***
Respiratory protection: Not required under normal OSHA PEL. Use NIOSH approved
respirators to prevent over-exposure. Ventilation: Use explosive proof ventilation as required to control vapour
concentration. Protective gloves: Nitrile gloves provide best protection to hands and arms. Eye protection: Safety glasses with side shields or goggles. Personal Hygiene: Wear effective plant clothing. Contaminated clothing should be
removed and washed in soap and water. Cleanse skin thoroughly with soap and water before meals. Shower and eyewash facilities should be accessible.
Miscellaneous Information ================================================================================ This product is formulated without the use of VOC’s, and further there are no VOC’s in this product. The EPA definition of a VOC (1997) is: “Volatile organic compounds (VOC) means any compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, which participates in atmospheric photochemical reactions” In all metalwork fluids containing amines, there is a potential for forming nitrosamine, which are animal carcinogens. Therefore, no nitrates or related nitrosamine agents should be added to such composition. ================================================================================
Additional Notes ================================================================================ Prepared by: G. F. THOMPSON CO. LTD. Telephone: 905-898-2557 Preparation date: January 1, 2011
MASTERS Grit Cloth Page 1 of 3
MATERIAL SAFETY DATA SHEET ================================================================================
SECTION I - PRODUCT IDENTIFICATION ================================================================================ Product name: MASTERS GRIT CLOTH Product use: For cleaning copper pipes, tubing and fittings. Supplier name and address: Manufacturer name and address: G.F. THOMPSON CO. LTD. Refer to supplier 620 Steven Court, Unit #11 Newmarket, Ontario L3Y 6Z2 Emergency Phone #: WHMIS CLASS: D2B Mon – Fri, 7:30 am to 5:00 pm EST 905-898-2557 800-499-3673 (toll free) 24 hr Emergency Tel: 905-252-4793
SECTION III - PHYSICAL DATA ================================================================================ Physical State: Solid. Odour and appearance: Cloth coated with abrasive material. Odour threshold: n/av Specific gravity: n/av Coefficient of water/oil distribution: n/av Vapour pressure (mm Hg): n/av Boiling point: n/av Freezing point: n/av pH: n/ap Vapour density (Air = 1): n/av Evaporation rate (BuAc = 1): n/av Volatiles, %: n/av Solubility in water: Variable ================================================================================
SECTION IV - FIRE AND EXPLOSION DATA ================================================================================ Conditions of flammability: Backing and resin binder will burn.
MASTERS Grit Cloth Page 2 of 3
Means of extinction: Carbon dioxide, dry chemical, foam or water fog may be used to extinguish fire. Sensitivity to mechanical impact/static discharge: Not susceptible to mechanical impact. Insensitive to static discharge. Flash point (Method): n/ap Upper flammable limit %: n/ap Lower flammable limit %: n/ap Auto-ignition temperature: n/ap Special fire fighting procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Cool exposed containers with water spray. Hazardous combustion products: Refer to "Hazardous Decomposition Products" ================================================================================
SECTION V - REACTIVITY DATA ================================================================================ Stability: Stable. Incompatible materials: n/av Conditions of reactivity: Hazardous polymerization will not occur. Hazardous decomposition products: Thermal decomposition could produce carbon monoxide, carbon dioxide and decomposing resin fumes. ================================================================================
SECTION VI - TOXICOLOGICAL PROPERTIES ================================================================================
*** Routes of exposure and acute/chronic effects *** Exposure limit (ACGIH-TLV-TWA): Aluminum oxide 10 mg/m3 Inhalation: Inhalation of dust may cause coughing, shortness of breath. Skin: Abrasion. Eyes: Dust may irritate. Ingestion: Unlikely route of entry, however harmful if dust is swallowed. Chronic effects: Breathing of dust may affect breathing capacity. Carcinogenicity: Ingredient(s) are not listed by IARC or ACGIH as carcinogenic. Reproductive effects, Teratogenicity, Mutagenicity: None known. Name of Toxicologically Synergistic Products: n/av ================================================================================
SECTION VII FIRST AID ================================================================================ Inhalation: Remove to fresh air. Get medical attention if needed. Eyes: Immediately flush eyes with large amounts of water for at least 15 minutes lifting upper and lower lids. Get prompt medical attention. Skin: For abrasions, treat symptomatically. Ingestion: Unlikely route of entry. Consult a physician if problems arise. ================================================================================
SECTION VIII - PREVENTIVE MEASURES ================================================================================ Spill, leak or release: Normal clean-up procedures (vacuum to prevent airborne dust particles). Waste disposal: Dispose of in accordance with federal, provincial and local regulations.
*** PROTECTIVE EQUIPMENT ***
MASTERS Grit Cloth Page 3 of 3
Respiratory protection: Use NIOSH approved respirator as needed for dusty conditions. Ventilation: General, local exhaust recommended. Protective gloves: Recommended - Leather Eye protection: Safety glasses/goggles or face shield to protect against dust. Other protective equipment: No special clothing required. Long sleeves recommended to minimize dust contact. Other requirements: Remove clothing and launder before reuse if contaminated with product. Wash hands with soap and water if contact with product occurs or before eating, drinking, smoking, or using toilet facilities.
*** STORAGE & HANDLING ***
Storage and handling conditions: Avoid excessive heat. Store out of direct sunlight in a dry area. Special Shipping Information: TDG - Not regulated. ================================================================================ Additional notes or references : Abbreviations :
n/av : not available n/ap : not applicable IARC : International Agency for Research on Cancer ACGIH : American Conference of Governmental Industrial Hygienists TLV : Threshold Limit Values NIOSH: National Institute of Occupational Safety and Health TDG : Transportation of Dangerous Goods Act
References :
1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 1994-95. 2. International Agency for Research on Cancer Monographs, Supplement 7, 1988. 3. N. Irving Sax. Dangerous Properties of Industrial Materials, Seventh Edition. 4. Canadian Centre for Occupational Health and Safety. Cheminfo Database. 5. N. Irving Sax, Richard J. Lewis, Sr. Hawley's Condensed Chemical Dictionary, Eleventh Edition.
================================================================================SECTION IX PREPARATION INFORMATION
SECTION III - PHYSICAL DATA ================================================================================== Physical state, odour and appearance: Medium grey, paste. Odour of alcohol. Freezing / melting point: 65.6 – 187.8
================================================================================== SECTION IV - FIRE AND EXPLOSION DATA
================================================================================== Conditions of flammability: Combustible. Product may be ignited by heat, sparks and flame. Flash point (Method): 63°C / 145.4
oF (Closed Cup)
Auto-ignition temperature: N/Av Upper flammable limit %: N/Av Lower flammable limit %: N/Av Means of extinction: Dry chemical is preferred. Additional types include alcohol foam, carbon dioxide and water fog. Do not use water jet, as this may spread burning material. Sensitivity to mechanical impact/static discharge: N/Av. Special fire fighting procedures: Firefighters should wear proper full protective equipment and self-contained breathing apparatus. Move containers from fire area if it can be done without risk. Water spray may only be useful in cooling equipment and containers exposed to heat and flame. Unusual fire and explosion hazards: Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Hazardous combustion products: Toxic lead oxides, carbon oxides and other irritating fumes and smoke. ==================================================================================
SECTION V - REACTIVITY DATA ================================================================================== Stability: Stable under the recommended storage and handling conditions prescribed. Hazardous polymerization will not occur. Incompatible materials: Strong oxidizers (e.g. Chlorine, Peroxides, etc.), acids, bases. Conditions of reactivity: Stable under ambient pressure and temperature. Avoid heat, sparks and flames. Hazardous decomposition products: None known. Refer to Section IV for ‘Hazardous combustion products’. ==================================================================================
SECTION VI - TOXICOLOGICAL PROPERTIES ==================================================================================
***Routes of exposure and acute effects*** Exposure limit: ACGIH-TLV: Lead – 0.05 mg/m
3; n-Butyl alcohol – 20 ppm.
OSHA-PEL: Lead – 50 μg/m3
(Final rule limit); n-Butyl alcohol – 100 ppm. Routes of exposure: Skin contact, eye contact, inhalation and ingestion. Irritancy of product: Mild skin irritant, severe eye irritant. Inhalation: Harmful if inhaled. Inhalation may cause nose, throat and respiratory tract irritation. Symptoms may include headache, nausea, vomiting, dizziness and other central nervous system effects. This product contains lead. Inhalation of lead fumes, mists or vapours may cause cumulative effects, which develop slowly over time and resemble chronic overexposure. Symptoms of overexposure to lead may include nausea, headache, fatigue, cramps, vomiting, diarrhea, constipation, confusion, convulsions, anemia and muscular weakness. Skin: May cause mild irritation. Can be absorbed through open wounds or cuts, causing lead poisoning (effects similar to those listed for Inhalation). Eyes: May cause severe irritation. Ingestion: Harmful if ingested. May cause irritation to the mouth, throat and stomach. Symptoms may include joint pain, a metallic taste in the mouth and other symptoms similar to those listed for inhalation. Chronic effects: Prolonged or repeated skin contact may cause severe drying and cracking of the skin (dermatitis). Chronic overexposure to lead may cause long-term toxicity or plumbism. Plumbism may include central nervous system effects, peripheral nervous system effects, digestive system effects (e.g. inflammation of stomach, blue ‘lead line’ on the gums), kidney damage, blood system effects and reproductive system effects. Carcinogenicity: Contains Lead. Lead is classified as carcinogenic by IARC (Group 2B) and ACGIH (Group A3). . Reproductive effects, Teratogenicity, Mutagenicity: Contains Lead. Lead may cause reproductive, teratogenic and mutagenic (reproductive and non-reproductive cells) effects. Sensitization to material: None known. Synergistic materials: N/Av. Conditions aggravated by exposure: Pre-existing skin, eye and respiratory disorders.
MASTERS METALLIC COMPOUND Page 3 of 4
================================================================================== SECTION VII - FIRST AID
================================================================================== Inhalation: Immediately remove victim to fresh air. Obtain medical attention. Skin contact: Immediately wash skin with soap and plenty of water, while removing contaminated
clothing. Obtain medical attention if irritation persists. Eye contact: Immediately flush eyes thoroughly with water for at least fifteen minutes. Do not rub
eyes. Obtain medical attention. Ingestion: Do not induce vomiting. Call physician or Poison Control Centre immediately (e.g.
Hospital for Sick Children, Poison Control Centre. Toronto, Ontario. Telephone: 416-598-5900). ==================================================================================
SECTION VIII - PREVENTIVE MEASURES ================================================================================== Spill, leak or release: Restrict access to area until completion of clean-up. Ensure clean-up is conducted by
trained personnel only. All persons dealing with clean-up should wear the appropriate chemically resistant equipment. Eliminate all sources of heat and flame. Ventilate area of release. Stop leak if you can do so without risk. Absorb or wipe up with non-combustible, inert absorbent material. Place contaminated absorbent material into suitable containers for later disposal (see below). Clean spill area. Keep out of waterways. Notify the appropriate authorities as required.
Waste disposal: Handle according to recommendations listed below. Dispose in accordance with all applicable government regulations.
***PROTECTIVE EQUIPMENT***
Respiratory protection: None required under normal use. For prolonged exposure or if the TLV is exceeded, wear NIOSH-approved respirators.
Ventilation: Use in well ventilated area. General ventilation should be sufficient under normal use. Local exhaust ventilation may be necessary for prolonged exposures or if the product is being heated.
Protective gloves: Gloves impervious to the material, must be worn. Advice should be sought from glove suppliers.
Eye protection: Safety goggles, to prevent product from entering the eyes. Other protective equipment: An eyewash station and safety shower should be made available in the immediate working area. Other equipment, including resistant apron, may be required according to workplace standards.
*** STORAGE & HANDLING ***
Storage and handling conditions: Handling: Wear appropriate chemically protective equipment. Use in a well ventilated area. Avoid
inhalation and ingestion of product, and activities that generate dust or fume. Avoid contact with skin, eyes, and clothing. Do not eat, drink or smoke in work areas. Keep away from heat, sparks and flame. Keep away from acids and incompatible materials. Keep container tightly closed when not in use. Wash thoroughly after handling.
Storage: Store in a cool, dry, well-ventilated area away from incompatibles (refer to Section V), heat and flame. Practice good housekeeping procedures to prevent accumulation of dust or refuse.
Special Shipping Information - Transportation of Dangerous Goods Regulations (TDGR): This material, as supplied, is not regulated for transport by ground within Canada.
MASTERS METALLIC COMPOUND Page 4 of 4
=========================================================================================== SECTION IX - PREPARATION INFORMATION =========================================================================================== Prepared by: G.F. THOMPSON CO. LTD. Preparation date: December 1, 2012 Additional notes or references: Legend: ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstract Service HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit RTECs: Registry of Toxic Effects of Chemical Substances TLV: Threshold Limit Values WHMIS: Workplace Hazardous Materials Information System
References: 1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 2005.
2. International Agency for Research on Cancer Monographs, searched 2006. 3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2006 (Chempendium
and RTECs). 4. Material Safety Data Sheet from manufacturer.
MASTERS NO LEAK Page 1 of 4
MATERIAL SAFETY DATA SHEET ==================================================================================
SECTION I - PRODUCT IDENTIFICATION ================================================================================== Product name: MASTERS NO-LEAK Product use: Pipe thread and gasket sealant. Supplier name and address: Manufacturer name and address: G.F. THOMPSON CO. LTD. Refer to supplier. 620 Steven Court Newmarket, Ontario L3Y 6Z2 WHMIS CLASS: B3, D2A, D2B Emergency Phone #: Mon – Fri, 7:30 am to 5:00 pm EST 905-898-2557 800-499-3673 (toll free) 24 hr Emergency Tel: 905-252-4793 HMIS Rating: * - Chronic hazard 0 - Minimal 1 – Slight 2 - Moderate 3 - Serious 4 – Severe Health: *2 Flammability: 2 Reactivity: 0 ==================================================================================
SECTION II - INGREDIENTS ==================================================================================
SECTION III - PHYSICAL DATA ================================================================================== Physical state, odour and appearance: Light brown paste. Odour of alcohol. Freezing / melting point: 66 – 160
oC / 150 - 320
oF (emulsion range)
Evaporation rate (n-Butyl acetate = 1): N/Av Volatile, % by volume: <50 Odour threshold: N/Av Solubility in water: Insoluble Specific gravity: 1.6 pH: N/Av. Boiling point: N/Av Vapour pressure (mmHg): N/Av Vapour density (Air = 1): N/Av Coefficient of water/oil distribution: N/Av Viscosity: N/Av VOC: 46.9g/l, 3.4%
MASTERS NO LEAK Page 2 of 4
================================================================================== SECTION IV - FIRE AND EXPLOSION DATA
================================================================================== Conditions of flammability: Combustible. Product may be ignited by heat, sparks and flame. Flash point (Method): 47°C / 116.6
oF (Closed Cup) Auto-ignition temperature: N/Av
Upper flammable limit %: N/Av Lower flammable limit %: N/Av Means of extinction: Dry chemical, foam, carbon dioxide and water fog. Do not use water jet, as this may spread burning material. Sensitivity to mechanical impact/static discharge: N/Av. Special fire fighting procedures: Firefighters should wear proper full protective equipment and self-contained breathing apparatus. Move containers from fire area if it can be done without risk. Water spray may only be useful in cooling equipment and containers exposed to heat and flame. Unusual fire and explosion hazards: Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Hazardous combustion products: Carbon oxides, unburned alcohol and other irritating fumes and smoke. ==================================================================================
SECTION V - REACTIVITY DATA ================================================================================== Stability: Stable under the recommended storage and handling conditions prescribed. Hazardous polymerization will not occur. Incompatible materials: Strong oxidizers (e.g. Chlorine, Peroxides, etc.), acids. Conditions of reactivity: Stable under ambient pressure and temperature. Avoid heat, sparks and flames. Hazardous decomposition products: None known. Refer to Section IV for ‘Hazardous combustion products’. ==================================================================================
SECTION VI - TOXICOLOGICAL PROPERTIES ==================================================================================
***Routes of exposure and acute effects*** Exposure limit: ACGIH-TLV: n-Butyl alcohol – 20 ppm; Silica, quartz – 0.05 mg/m
Respirable Silica, quartz – 10 mg/m3 / (%SiO2 +2). Routes of exposure: Skin contact, eye contact, inhalation and ingestion. Irritancy of product: Mild skin irritant, severe eye irritant. Inhalation: Harmful if inhaled. Inhalation may cause nose, throat and respiratory tract irritation. Symptoms may include headache, nausea, vomiting, dizziness and other central nervous system effects. Skin: May cause mild irritation. Eyes: May cause severe irritation. Ingestion: Harmful if ingested. May cause irritation to the mouth, throat and stomach. Symptoms may include headache, nausea, vomiting, dizziness and other central nervous system effects. Chronic effects: Prolonged or repeated skin contact may cause severe drying and cracking of the skin (dermatitis). Chronic inhalation of silica dusts can cause scarring of the lungs, a disease called silicosis. However, due to the physical state and intended use of the product, silicosis is not expected under normal conditions of use. Carcinogenicity: Contains Silica, quartz. Silica, quartz is classified as carcinogenic by IARC (Group 1) and ACGIH (Group A2). . Reproductive effects, Teratogenicity, Mutagenicity: None known. Sensitization to material: None known. Synergistic materials: N/Av. Conditions aggravated by exposure: Pre-existing skin, eye and respiratory disorders.
MASTERS NO LEAK Page 3 of 4
================================================================================== SECTION VII - FIRST AID
================================================================================== Inhalation: Remove victim to fresh air. Obtain medical attention. Skin contact: Wash skin with soap and plenty of water, while removing contaminated clothing. Obtain medical attention if irritation persists. Eye contact: Immediately flush eyes thoroughly with water for at least fifteen minutes. Do not rub eyes. Obtain medical attention. Ingestion: Do not induce vomiting. Obtain medical attention. Never give anything by mouth to an unconscious or convulsing person. ==================================================================================
SECTION VIII - PREVENTIVE MEASURES ================================================================================== Spill, leak or release: Restrict access to area until completion of clean-up. Ensure clean-up is conducted by trained personnel only. All persons dealing with clean-up should wear the appropriate chemically resistant equipment. Eliminate all sources of heat and flame. Ventilate area of release. Stop leak if you can do so without risk. Absorb or wipe up with non-combustible, inert absorbent material. Place contaminated absorbent material into suitable containers for later disposal (see below). Clean spill area. Keep out of waterways. Notify the appropriate authorities as required. Waste disposal: Handle according to recommendations listed below. Dispose in accordance with all applicable government regulations.
***PROTECTIVE EQUIPMENT***
Respiratory protection: None required under normal use. For prolonged exposure or if the TLV is exceeded, wear NIOSH-approved respirators. Ventilation: Use in well ventilated area. General ventilation should be sufficient under normal use. Local exhaust ventilation may be necessary for prolonged exposures or if the product is being heated. Protective gloves: Gloves impervious to the material, must be worn. Advice should be sought from glove suppliers. Eye protection: Safety goggles, to prevent product from entering the eyes. Other protective equipment: An eyewash station and safety shower should be made available in the immediate working area. Other equipment may be required according to workplace standards.
*** STORAGE & HANDLING ***
Storage and handling conditions: Handling: Wear appropriate chemically protective equipment. Use in a well ventilated area. Avoid inhaling vapours or fumes. Avoid contact with skin, eyes, and clothing. Avoid and control operations that create dusty atmospheres. Keep away from heat, sparks and flame. Keep away from acids and incompatible materials. Keep container tightly closed when not in use. Wash thoroughly after handling. Storage: Store in a cool, dry, well-ventilated area away from incompatibles (refer to Section V), heat and flame. No smoking in the area. Inspect periodically for damage or leaks. Special Shipping Information - Transportation of Dangerous Goods Regulations (TDGR): Shipping Name: BUTANOLS UN No.: UN1120 Primary Class(es): 3 Subsidiary Class(es): None Packing Group: III Other Shipping Information: For shipments by ground within Canada only, the Flammable Liquids General
Exemption may apply. Under the TDGR, refer to Section 1.33 for additional exemption information, if shipping under this exemption. For other shipments by ground for Canada, the Limited Quantity / Consumer Commodity Exemption may apply for containers which hold 5 litres or less of the material. Under the TDGR, refer to Section 1.17 for additional exemption information, if shipping under this exemption.
MASTERS NO LEAK Page 4 of 4
=========================================================================================== SECTION IX - PREPARATION INFORMATION =========================================================================================== Prepared by: G.F. THOMPSON CO. LTD. Preparation date: December 1, 2012 Additional notes or references: Legend: ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstract Service HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit RTECs: Registry of Toxic Effects of Chemical Substances TLV: Threshold Limit Values WHMIS: Workplace Hazardous Materials Information System
References: 1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 2005. 2. International Agency for Research on Cancer Monographs, searched 2006. 3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2006 (Chempendium
and RTECs). 4. Material Safety Data Sheet from manufacturer.
MASTERS ORANGE T-TAPE Page 1 of 3
MATERIAL SAFETY DATA SHEET ================================================================================
SECTION I - PRODUCT IDENTIFICATION ================================================================================ Product name: MASTERS ORANGE T-TAPE Product use: Thread Sealing Tape Supplier name and address: Manufacturer name and address: G.F. THOMPSON CO. LTD. Refer to supplier 620 Steven Court, Newmarket, Ontario L3Y 6Z2 Tel.: 905-898-2557 Emergency Tel. #: WHMIS CLASS: Not WHMIS REGULATED Mon – Fri, 7:30 am to 5:00 pm EST 905-898-2557 800-499-3673 (toll free) 24 hr Emergency Tel: 905-252-4793 ================================================================================
SECTION II - HAZARDOUS INGREDIENTS ================================================================================ These products consist of Polytetrafluoroethylene. Do not contain any hazardous ingredients. We do not consider the products hazardous under normal conditions of use. Hazardous Mixtures of Other Liquids, Solids or Gases ----------------------------------------------------------------------------------------------------------------------------------------- The finished polymerized compound is inert under ordinary conditions. ================================================================================
SECTION III - PHYSICAL DATA ================================================================================ Physical State: Tape Odour and appearance: Soft, odourless, pliable film, pinkish orange in colour. Specific gravity (H2O=1): 1.65 Vapour pressure (mm Hg): N/Ap Boiling Point: N/Ap Vapour density (Air = 1): N/Ap Solubility in water: Insoluble Melting Point: 327º C VOC: <0.5%
MASTERS ORANGE T-TAPE Page 2 of 3
================================================================================ SECTION IV - FIRE AND EXPLOSION DATA
================================================================================ Means of extinction: Water, foam, carbon dioxide or dry chemical. Flash point (Method): N/Ap Upper flammable limit %: N/Ap Lower flammable limit %: N/Ap Special Fire Fighting Procedures: PTFE tapes will not burn (rated 94 v-0 by UL) without an
external source of fuel. In extreme fire situations, protection from hydrogen fluoride fumes should be employed.
Unusual Fire and Explosion Hazards: PTFE tapes will burn in an atmosphere of 100% oxygen if ignition source is present. ================================================================================
SECTION V - REACTIVITY DATA ================================================================================ Stability: Stable. Avoid heating over 500º F without adequate ventilation. Incompatible materials: Molten alkali metals, fluorine and certain fluorine bearing
compounds. Conditions of reactivity: Temperature above 250º C without adequate ventilation. Hazardous decomposition products: On burning, Hydrogen Fluoride, Carbonyl Fluoride and
Perfluorocarbon Olefins. Hazardous Polymerization: Will not occur. ================================================================================
SECTION VI - TOXICOLOGICAL PROPERTIES ================================================================================
*** Routes of exposure and acute/chronic effect *** Threshold Limit Value: n/ap Effects of Overexposure: Overexposure to the thermal decomposition products can induce flu-like
symptoms (chills, fever, cough and malaise). This is usually a temporary condition. Contact a physician if symptoms persist.
SECTION VII - FIRST AID ================================================================================ Inhalation: N/Ap Skin: N/Ap Eyes: N/Ap Ingestion: N/Ap Remove to fresh air, contact physician if victim is unconscious, exhibits breathing difficulty or if recovery is not prompt. ================================================================================
SECTION VIII - PREVENTIVE MEASURES ================================================================================ Waste disposal: (1) Landfill. (2) Complete combustion and removal of gaseous
products by alkaline scrubbing. Disposal methods must conform to Local, Provincial and State laws.
*** PROTECTIVE EQUIPMENT ***
Respiratory protection: No special requirement under normal conditions.
MASTERS ORANGE T-TAPE Page 3 of 3
Ventilation: Local Exhaust: No special requirement under normal conditions. Avoid contaminating tobacco with waste particles.
Protective gloves: Not required Eye protection: Not required under normal use. Other protective equipment: N/Ap
*** STORAGE & HANDLING *** Storage and handling conditions: Store in a clean, dry place away from highly flammable materials. Normal wash up after handling is recommended prior to any other activities. Other precautions: When exposed to elevated temperatures (250ºC) toxic fumes evolve. Care should be taken to avoid contaminating tobacco and other smoking materials. ================================================================================
SECTION IX - PREPARATION INFORMATION ================================================================================ Prepared by: G. F. THOMPSON CO. LTD. Preparation date: December 1, 2012 =
MASTERS PRO-DOPE Page 1 of 3
MATERIAL SAFETY DATA SHEET ======================================================================================
SECTION I - PRODUCT IDENTIFICATION ====================================================================================== Product name: MASTERS PRO-DOPE Product use: Thread sealing compound. Supplier name and address: Manufacturer name and address: G.F. THOMPSON CO. LTD. Refer to supplier. 620 Steven Court Newmarket, Ontario L3Y 6Z2
Emergency Tel:
Mon – Fri, 7:30 am to 5:00 pm EST 905-898-2557 800-499-3673 (toll free) 24 hr Emergency Tel: 905-252-4793
SECTION III - PHYSICAL DATA ====================================================================================== Physical state, odour and appearance: Solid paste. Slight alcohol odour. Evaporation rate (n-Butyl acetate = 1): N/Av Freezing / melting point: N/Av Volatile, % by volume: 10 Odour threshold: N/Av Solubility in water: Slightly soluble Specific gravity: 1.41 pH: N/Av. Boiling point: N/Av Vapour pressure (mmHg): N/Av Vapour density (Air = 1): N/Av Coefficient of water/oil distribution: N/Av Viscosity: N/Av VOC: 345.6 g/l, 25.4% ======================================================================================
SECTION IV - FIRE AND EXPLOSION DATA ====================================================================================== Conditions of flammability: Flammable solid, due to organic solvent content. Product may be ignited by heat, sparks and flame. Flash point (Method): 25°C / 77oF (Method not known) Auto-ignition temperature: N/Av Upper flammable limit %: N/Av Lower flammable limit %: N/Av Means of extinction: Dry chemical, foam, carbon dioxide and water fog. Do not use water jet, as this may spread burning material. Sensitivity to mechanical impact/static discharge: N/Av.
MASTERS PRO-DOPE Page 2 of 3
Special fire fighting procedures: Firefighters should wear proper full protective equipment and self-contained breathing apparatus. Move containers from fire area if it can be done without risk. Water spray may only be useful in cooling equipment and containers exposed to heat and flame. Unusual fire and explosion hazards: Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Hazardous combustion products: Carbon oxides and other irritating fumes and smoke. ======================================================================================
SECTION V - REACTIVITY DATA ====================================================================================== Stability: Stable under the recommended storage and handling conditions prescribed. Hazardous polymerization will not occur. Incompatible materials: Strong oxidizers (e.g. Chlorine, Peroxides, etc.). Conditions of reactivity: Stable under ambient pressure and temperature. Avoid heat, sparks and flames. Hazardous decomposition products: None known. Refer to Section IV for ‘Hazardous combustion products’. ======================================================================================
SECTION VI - TOXICOLOGICAL PROPERTIES ====================================================================================== ***Routes of exposure and acute effects*** Exposure limit: ACGIH-TLV: Ethylene glycol n-butyl ether – 20 ppm; Isopropyl alcohol – 200 ppm.
OSHA-PEL: Ethylene glycol n-butyl ether – 50 ppm (skin); Isopropyl alcohol – 400 ppm. Routes of exposure: Skin contact, skin absorption, eye contact, inhalation and ingestion. Irritancy of product: Moderate to severe. Inhalation: Harmful if inhaled. Inhalation may cause nose, throat and respiratory tract irritation. Symptoms may include headache, nausea, vomiting, other central nervous system effects and blood system effects (red blood cell fragility and hemoglobinuria). Skin: May cause moderate to severe irritation. Product could be absorbed if left on the skin and cause headache, nausea, vomiting, other central nervous system effects and blood system effects (red blood cell fragility and hemoglobinuria). Eyes: May cause severe irritation. Ingestion: Harmful if ingested. May cause irritation to the mouth, throat and stomach. Symptoms may include headache, nausea, vomiting, diarrhea, other central nervous system effects and possibly blood system effects (red blood cell fragility and hemoglobinuria). Chronic effects: Prolonged or repeated skin contact may cause severe drying and cracking of the skin (dermatitis). Prolonged or repeated inhalation may cause severe toxicity to the blood system. At higher concentrations, prolonged inhalation may cause liver damage. Carcinogenicity: Contains Ethylene glycol n-butyl ether. Ethylene glycol n-butyl ether is classified as a confimed animal carcinogen with unknown relevance to humans by ACGIH (Group A3). None of the listed ingredients are classified as carcinogenic by IARC. Reproductive effects, Teratogenicity, Mutagenicity: Contains Isopropyl alcohol. Isopropyl alcohol may cause fetotoxic effects, based on animal data. Sensitization to material: None known. Synergistic materials: N/Av. Conditions aggravated by exposure: Pre-existing skin, eye and respiratory disorders. ======================================================================================
SECTION VII - FIRST AID ====================================================================================== Inhalation: Immediately remove victim to fresh air. Obtain medical attention. Skin contact: Immediately wash skin with mild soap and plenty of water, while removing contaminated clothing. Obtain medical attention immediately. Eye contact: Immediately flush eyes thoroughly with water for at least fifteen minutes. Do not rub eyes. Obtain medical attention immediately. Ingestion: Do not induce vomiting. Obtain medical attention immediately. Never give anything by mouth to an unconscious or convulsing person. ======================================================================================
SECTION VIII - PREVENTIVE MEASURES ======================================================================================
MASTERS PRO-DOPE Page 3 of 3
Spill, leak or release: Restrict access to area until completion of clean-up. Ensure clean-up is conducted by trained personnel only. All persons dealing with clean-up should wear the appropriate chemically resistant equipment. Eliminate all sources of heat and flame. Ventilate area of release. Stop leak if you can do so without risk. Scrape up into suitable containers, using method that does not generate sparks. Place any recovered material in closed, labelled containers for recycling or disposal (see below).Clean spill area. Keep out of waterways. Notify the appropriate authorities as required. Waste disposal: Handle according to recommendations listed below. Dispose in accordance with all applicable government regulations. ======================================================================================
SECTION VIII - PREVENTIVE MEASURES Continued ======================================================================================
***PROTECTIVE EQUIPMENT*** Respiratory protection: None required under normal use. For prolonged exposure or if the TLV is exceeded, wear NIOSH-approved respirators. Ventilation: Use in well ventilated area. General ventilation should be sufficient under normal use. Local exhaust ventilation may be necessary for prolonged exposures or if the product is being heated. Protective gloves: Gloves impervious to the material, must be worn. Advice should be sought from glove suppliers. Eye protection: Safety goggles, to prevent product from entering the eyes. Other protective equipment: An eyewash station and safety shower should be made available in the immediate working area. Other equipment may be required according to workplace standards.
*** STORAGE & HANDLING *** Storage and handling conditions: Handling: Wear appropriate chemically protective equipment. Use in a well ventilated area. Avoid inhaling vapours or fumes. Avoid contact with skin, eyes, and clothing. Avoid and control operations that create dusty atmospheres. Keep away from heat, sparks and flame. Ground all equipment during handling. Keep away from incompatible materials. Keep container tightly closed when not in use. Wash thoroughly after handling. Storage: Store in a cool, dry, well-ventilated area away from incompatibles (refer to Section V), heat and flame. No smoking in the area. Inspect periodically for damage or leaks. Special Shipping Information - Transportation of Dangerous Goods Regulations (TDGR): Refer to the supplier for shipping information. =============================================================================================== SECTION IX - PREPARATION INFORMATION =============================================================================================== Prepared by: G. F. Thompson Co. Ltd Telephone No.: 905-898-2557 Preparation date: December 1, 2012
Additional notes or references: Legend: ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Service HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit RTECs: Registry of Toxic Effects of Chemical Substances TLV: Threshold Limit Values WHMIS: Workplace Hazardous Materials Information System
References: 1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 2005. 2. International Agency for Research on Cancer Monographs, searched 2006.
3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2006 (Chempendium and RTECs).
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751 P.O. Box 2219 Telephone 614-790-3333 Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274-
5263)
Product name MOLYFILM 315
Product code 36000
2. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid DANGER! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. CAUSES SEVERE BURNS OF THE EYES AND SKIN. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. Potential Health Effects Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure the cornea and cause blindness. Skin contact Can cause permanent skin damage. Symptoms may include redness, burning, and swelling of skin, burns, and other skin damage. Skin absorption of this material (or a component) may be increased through injured skin. Ingestion
Swallowing this material may be harmful or fatal. Symptoms may include severe stomach and intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and shock may occur as a result of severe tissue injury. Inhalation
Breathing of vapor or mist is possible. Breathing this material may be harmful or fatal. Symptoms may include severe irritation and burns to the nose, throat, and respiratory tract. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.). Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, lung (for example, asthma-like conditions), Liver, Kidney, spleen, bone, Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen, such as chronic lung disease, coronary artery disease or anemias. Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, discomfort in the chest, Weakness, pain in the abdomen and lower back, coma Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, anemia, bone damage, spleen damage, kidney damage, liver damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, central nervous system effects, joint pain (gout), liver abnormalities Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA). Reproductive hazard Based on the available information, risk to the fetus from maternal exposure to this material cannot be assessed.
4. FIRST AID MEASURES Eyes If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes while holding eyelids apart. If symptoms develop as a result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention. Skin Immediately flush skin with water for at least 15 minutes while removing contaminated clothing and shoes. Seek immediate medical attention. Wash clothing before reuse and discard contaminated shoes. Ingestion Seek immediate medical attention. Do not induce vomiting. Vomiting will cause further damage to the mouth and throat. If individual is conscious and alert, immediately rinse mouth with water and give milk or water to drink. If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Notes to physician Hazards: No information available. Treatment: No information available.
Suitable extinguishing media Dry chemical, Carbon dioxide (CO2), Water spray Hazardous combustion products boron oxides, molybdenum fumes, Sodium oxides, Sulphur oxides Precautions for fire-fighting Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Use water spray to cool fire exposed containers and structures until fire is out if it can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes.
6. ACCIDENTAL RELEASE MEASURES Personal precautions For personal protection see section 8. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent spreading over a wide area (e.g. by containment or oil barriers). Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Other information Comply with all applicable federal, state, and local regulations.
7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage
CAD MB OEL time weighted average 2 mg/m3 Inhalable fraction. CAD MB OEL Short term exposure limit 6 mg/m3 Inhalable fraction. CAD ON OEL time weighted average 2 mg/m3 Inhalable fraction. CAD ON OEL Short term exposure limit 6 mg/m3 Inhalable fraction.
SODIUM MOLYBDATE 7631-95-0 CAD BC OEL time weighted average 0.5 mg/m3 Respirable. OEL (QUE) time weighted average 5 mg/m3 CAD AB OEL time weighted average 0.5 mg/m3 Respirable. CAD MB OEL time weighted average 0.5 mg/m3 Respirable fraction. CAD ON OEL time weighted average 0.5 mg/m3 Respirable fraction.
General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Exposure controls Mechanical ventilation systems used to ventilate corrosive storage or process areas must be designed with components that are corrosion resistant. Eye protection Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Wear chemical splash goggles and face shield when there is potential for exposure of the eyes or face to liquid, vapor or mist. Maintain eye wash station in immediate work area. Skin and body protection Wear appropriate chemical impervious clothing and boots whenever there is potential for skin contact with product. Launder clothing before reuse. Maintain safety shower at all locations where skin contact could occur. Contact your local safety equipment supplier to assist the facility in determining proper selection of personal protective equipment for the applications/operations present at your facility. Wear resistant gloves (consult your safety equipment supplier). Discard gloves that show tears, pinholes, or signs of wear.
Respiratory protection A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air-purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Boiling point/boiling range 212 °F / 100 °C @ 1,013.33 hPa Calculated Phase
Transition Liquid/Gas pH 12 - 13.4 Flash point
does not flash Vapour pressure 23.333 hPa @ 68 °F / 20 °C Calculated Vapor
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.
15. REGULATORY INFORMATION WHMIS Classification E Corrosive Material WHMIS Ingredient Disclosure List IDL: No component is listed on the WHMIS ingredients disclosure list. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Canadian National Pollutant Release Inventory (NPRI) Canadian National Pollutant Release Inventory (NPRI): No component is listed on NPRI.
Notification statusUS. Toxic Substances Control Act y (positive listing) Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)
q (quantity restricted)
Australia. Industrial Chemical (Notification and Assessment) Act
n (Negative listing)
New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand
n (Negative listing)
Japan. Kashin-Hou Law List n (Negative listing) Korea. Toxic Chemical Control Law (TCCL) List n (Negative listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act
n (Negative listing)
China. Inventory of Existing Chemical Substances n (Negative listing)
Flammability 0 -- Physical hazards 0 Instability -- Specific Hazard -- -- 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751).
MSDS No: OTH090E10 Issue Date: 15 Jun 2010 Page: 1 of 4
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: OATEY PIPE/GASKET LUBE Product No.: 30600, 30601 Product Use: Lubricant for bell joint pipe gaskets. Formula: See Section 2. Synonyms: Pipe lubricant. Firm Name & OATEY CO. 4700 West 160th Street P.O . Box 35906 Cleveland, Mailing Address: Ohio 44135, U.S.A. http: //www.oatey.com Oatey Phone Number: (216) 267-7100 or (800) 321-953 2 Emergency Phone For Emergency First Aid call 1-877 -740-5015. For Numbers: chemical transportation emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the U.S. 1-703-527-3887. Prepared By: Corporate Director – Safety and Enviro nmental Compliance Preparation Date: June 15, 2010 SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS Blend of soap and non-toxic ingredients: INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER: Potassium soap Conf. 61790-44-1 None None None of fatty acid Mica Conf. 12001-26-2 3 mg/m3 20 mppcf None Propylene Glycol Conf. 57-55-6 None None None Conf. = Confidential OSHA Hazard Classification: Not hazardous SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Amber paste with bland odor. May cause mild eye and skin irritation. SECTION 4 FIRST AID MEASURES CALL 1-877-740-5015 or 1-303-623-5716 COLLECT Skin: Remove contaminated clothing immediately. Was h all exposed areas with soap and water. Get medical attention if irritatio n develops. Eyes: If material gets into eyes or if fumes cause irritation, immediately
flush eyes with plenty of water until chemical is removed. If irritation persists, get medical attention immedia tely.
Inhalation: Not expected to be a normal route of ex posure. Ingestion: Drink water and call a poison control ce nter or physician immediately. Avoid alcoholic beverages. Never give anything by mouth to an unconscious person. SECTION 5 FIRE FIGHTING MEASURES Flashpoint / Method: > 220 Deg. F / > 104 Deg. C Flammability: LEL = Not determined, UEL = Not deter mined. Extinguishing Use water, water fog, alcohol foam, c arbon dioxide or dry Media: chemical to extinguish. Special Fire Firefighters should wear positive pres sure self-contained Fighting breathing apparatus and full protective c lothing for fires in Procedure: areas where chemicals are used or stored Unusual Fire and Explosion Hazards: None Hazardous Decomposition
MSDS No: OTH090E10 Issue Date: 15 Jun 2010 Page: 2 of 4 Products: None SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or This product is a biodegradable soap. For large spills, dike far ahead Leak of spill for later disposal. For cleanup, pla ce bulk material into Procedures: drums. Take up with sand or other absor bing material and place in a clean, dry, leakproof container. Then rinse any re maining material to sewage treatment system, in accordance with any ap plicable regulations. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothin g. Wash thoroughly after handling. Do not eat, drink or smoke in the work a rea. Storage: No special precautions are required. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Provide general or local exhaust venti lation systems. Respiratory Normally not necessary. If respirators are used, OSHA requires a Protection: written respiratory program that includ es at least medical certification, training, fit-testing, periodic env ironmental monitoring, maintenance, inspection, cleaning, and convenient sanitary storage areas. Skin Wear chemically protective gloves to prevent p rolonged or repeated Protection: skin contact. Eye Wear protective eyeglasses or chemical safety g oggles, per OSHA eye Protection: and face protection regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protec tion must be warn instead of, or in conjunction with contact lenses. Other: Eye wash and safety shower should be availab le. Launder contaminated clothing and equipment before reuse. Remove materi al from shoes and PPE after use. Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: >220 Degrees F / 105 Degrees C Melting Point: < 32 Degrees F / 0 Degrees C Vapor Pressure: Not determined Vapor Density: Not determined Volatile Components: 55% Solubility In Water: Complete pH: 11 Specific Gravity: 1.0 Evaporation Rate: Not determined Appearance: Amber paste Odor: Bland Will Dissolve In: Water Material Is: Paste SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: Reactive alloys like aluminum, brass, bronze. Hazardous Thermal oxidative decomposition can produ ce oxides of carbon Decomposition and nitrogen. Products: Incompatibility/ Materials To Avoid: Strong oxidizing agents. Hazardous Polymerization: Will not occur.
MSDS No: OTH090E10 Issue Date: 15 Jun 2010 Page: 3 of 4 SECTION 11 TOXICOLOGICAL INFORMATION Inhalation: Not a likely route of entry. Skin: Slight skin irritant if allowed to remain in contact. Eye: Slight eye irritant. Ingestion: None known. Chronic Toxicity: None known. Toxicity Data: Propylene glycol: Oral toxicity LD50 (rat): >20,000 mg/kg Dermal toxicity LD50 (rabbit): >10,000 mg/kg Sensitization: None of the components are known to cause sensitization. Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by NTP, IARC or OSHA. Mutagenicity: None known. Reproductive Toxicity: None known. Medical Conditions Aggravated By Exposure: None known. SECTION 12 ECOLOGICAL INFORMATION Soaps are known to be biodegradable. Information: Make sure that use of this product com plies with local VOC emission regulations, where they exist. VOC Level: Not known. SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose in accordance with current local, state and federal regulations RCRA Hazardous Waste Number: Not applicable EPA Hazardous Waste ID Number: Not applicable EPA Hazard Waste Class: Not applicable
MSDS No: OTH090E10 Issue Date: 15 Jun 2010 Page: 4 of 4 SECTION 14 TRANSPORT INFORMATION DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) Proper Shipping Name: Not hazardous under DOT tran sportation. Hazard Class/Packing Group: Not applicable UN/NA Number: Not applicable Hazard Labels: IMDG Proper Shipping Name: Not applicable Hazard Class/Packing Group: Not applicable UN Number: Not applicable Label: Not applicable SECTION 15 REGULATORY INFORMATION Hazard Category for Section None 311/312: Section 302 Extremely This product does not contain any chemicals regulated Hazardous Substances (TPQ): under SARA Section 302. Section 313 Toxic Chemicals: This product does not contain any chemicals regulated under SARA Section 313. CERCLA 103 Reportable Report spills required under federal, state and local Quantity: regulations. California Proposition 65: This product does not co ntain any chemicals subject to the California Proposition 65 regulation. TSCA Inventory: All components of this product are on the TSCA Inventory or are exempt. Canadian WHIMS Classification: Not a controlled pr oduct. This product has been classified in accordance with the hazard criteria o f the Controlled Products Regulations (CPR) and the M SDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal: Health: 1 Flammability: 1 Rea ctivity: 0 Special: None HMIS Hazard Signal: Health: 1 Flammability: 1 Rea ctivity: 0 PPE: B Disclaimer: The information herein has been compiled from sourc es believed to be reliable, up-to-date, and is accurate to the best of our knowled ge. However, Oatey cannot give any guarantees regarding information from other sou rces, and expressly does not make warranties, nor assumes any liability for its use.
MSDS No: SOL235C8
Issue Date: 26 May 2011
Page: 1 of 5
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: OATEY #5 PASTE FLUX
Product No.: 48420, 48421, 48422, 48423, 48307
Product Use: Flux for soldering.
Formula: See Section 2
Synonyms: Flux for Soldering Copper Pipe
Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
The information herein has been compiled from sources believed to be reliable, up-
to-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
MSDS No: OTH010C8 Issue Date: 12 Mar 2011 Page: 1 of 5
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: OATEY PIPE SEAL Product No.: 30614 Product Use: Caulking lead substitute for cast iron soil pipe joints Formula: See Section 2 Synonyms: Soil pipe seal Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland, Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com Oatey Phone Number: (216) 267-7100 or (800) 321-9532 Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For Numbers: chemical transportation emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the U.S. 1-703-527-3887. Prepared By: Corporate Director – Safety and Environmental Compliance Preparation Date: March 12, 2011
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER: Kaolin Clay 40 – 70% 1332-58-7 2 mg/m3 15 mg/m3 None (total dust) Methyl Ethyl Ketone 15 - 40% 78-93-3 200 ppm 200 ppm None 300 ppm STEL Vinyl Chloride 7 - 13% 25085-82-9 None None None Acetate Resin Established Established Amorphous Silica 1 - 5% 112945-52-5 10 mg/m3 20 mppcf None (Non-hazardous) Gray Pigment 0.1 – 1% Not None None None (Non-hazardous) Available Established Established OSHA Hazard Classification: Flammable, irritant, organ effects
SECTION 3 HAZARDS IDENTIFICATION
Emergency Overview: Heavy gray paste with a ketone odor. Extremely flammable liquid and vapor. Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory irritation and central nervous system effects. Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney or liver disorders. Aspiration hazard. May be fatal if swallowed. Symptoms may be delayed.
SECTION 4 FIRST AID MEASURES
CALL 1-303-623-5716 COLLECT Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical attention if irritation develops. Remove dried cement with Oatey Plumber's Hand Cleaner or baby oil. Eyes: If material gets into eyes or if fumes cause irritation, immediately
flush eyes with plenty of water until chemical is removed. If irritation persists, get medical attention immediately.
Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes difficult, administer oxygen. Administer artificial respiration if breathing has stopped. Seek immediate medical attention.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything
by mouth to a person who is unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center, or hospital emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment center or hospital.
MSDS No: OTH010C8 Issue Date: 12 Mar 2011 Page: 2 of 5
SECTION 5 FIRE FIGHTING MEASURES
Flashpoint / Method: 52 Degrees F. (11 Degrees C) / PMCC Flammability: LEL = 2.0 % Volume, UEL = 12.0 % Volume Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire Media: exposed container with water. Water may be ineffective as an extinguishing agent. Special Fire Firefighters should wear positive pressure self-contained Fighting breathing apparatus and full protective clothing for fires in Procedure: areas where chemicals are used or stored Unusual Fire and Extremely flammable liquid. Keep away from heat and all Explosion sources of ignition including sparks, flames, lighted Hazards: cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ignition source and flash back. Hazardous Combustion will produce toxic and irritating vapors including Decomposition carbon monoxide and carbon dioxide. Products:
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Remove all sources of ignition and ventilate area. Stop leak if it Leak can be done without risk. Personnel cleaning up the spill should Procedures: wear appropriate personal protective equipment, including respirators if vapor concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material. Put absorbent material in covered, labeled metal containers. Prevent liquid from entering watercourses, sewers and natural waterways. Report releases to authorities as required. See Section 13 for disposal information.
SECTION 7 HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after handling. Do not eat, drink or smoke in the work area. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas. Keep containers closed when not in use. Storage: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in use. Other: "Empty" containers retain product residue and can be hazardous. Follow all MSDS precautions in handling empty containers. Do not cut or weld on or near empty or full containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at the point of use below recommended exposure limits. If used in enclosed area, use exhaust fans. Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of solvent vapors are not exposed to electrical fixtures or hot surfaces. Respiratory For operations where the exposure limit may be exceeded, a NIOSH Protection: approved organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. Skin Rubber gloves are suitable for normal use of the product. For long Protection: exposures chemical resistant gloves may be required such as 4H(tm) or Silver Shield(tm) to avoid prolonged skin contact. Eye Safety glasses with side shields or safety goggles. Protection:
MSDS No: OTH010C8 Issue Date: 12 Mar 2011 Page: 3 of 5 SECTION 8 (Continued) Other: Eye wash and safety shower should be available.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 178 Degrees F / 81 Degrees C Melting Point: Not applicable Vapor Pressure: Not determined Vapor Density: (Air = 1) 2.5 Volatile Components: 23-27% Solubility In Water: Negligible pH: Not applicable Specific Gravity: 0.87 +/- 0.02 @ 20 Degrees C Evaporation Rate: Not determined Appearance: Heavy Gray Paste Odor: Sharp-penetrating odor Will Dissolve In: Acetone or Methyl Ethyl Ketone Material Is: Paste
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable. Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition. Hazardous Combustion will produce toxic and irritating vapors Decomposition including carbon monoxide and carbon dioxide. Products: Incompatibility/ Oxidizing agents, alkalis, amines, ammonia, acids, chlorine Materials To Avoid: compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber. Hazardous Will not occur. Polymerization:
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness, dullness, nausea, shortness of breath and vomiting. High concentrations may cause central nervous system depression, narcosis and unconsciousness. May cause kidney, liver and lung damage. Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone may be absorbed through the skin causing effects similar to those listed under inhalation. Eye: Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes. May cause eye damage. Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea. Aspiration during swallowing or vomiting can cause chemical pneumonia and lung damage. May cause kidney and liver damage. Chronic Prolonged or repeated overexposure cause dermatitis and damage Toxicity: to the kidney, liver, lungs and central nervous system. Toxicity Data: Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg Inhalation rat LC50: 23,500 mg/m3/8 hours Skin rabbit LD50: 6,480 mg/kg Sensitization: None of the components are known to cause sensitization.
MSDS No: OTH010C8 Issue Date: 12 Mar 2011 Page: 4 of 5 SECTION 11 (Continued) Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA. Mutagenicity: Methyl ethyl ketone is generally thought not to be mutagenic. Reproductive Methyl ethyl ketone has been shown to cause embryofetal toxicity Toxicity: and birth defects in laboratory animals. Medical Persons with pre-existing skin, lung, kidney or liver disorders Conditions may be at increased risk from exposure to this product. Aggravated By Exposure:
SECTION 12 ECOLOGICAL INFORMATION
This product is not expected to be toxic to aquatic organisms. Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L. VOC This product emits VOC's (volatile organic compounds) in its use. Information: Make sure that use of this product complies with local VOC emission regulations, where they exist. VOC Level: Not determined.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal regulations. RCRA Hazardous Waste Number: U159 EPA Hazardous Waste ID Number: D001, D035, F005 EPA Hazard Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
SECTION 14 TRANSPORT INFORMATION
DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) Proper Shipping Name: Consumer Commodity Adhesives Hazard Class/Packing Group: ORM-D 3, PGIII UN/NA Number: None UN1133 Hazard Labels: None Flammable Liquid IMDG Proper Shipping Name: Adhesives Adhesives Hazard Class/Packing Group: 3, III 3, III UN Number: UN1133 UN1133 Label: None (Limited Quantities Class 3 (Flammable are excepted Liquid) from labeling) 2004 North American Emergency Response Guidebook Number: 127 or 128
MSDS No: OTH010C8 Issue Date: 12 Mar 2011 Page: 5 of 5
SECTION 15 REGULATORY INFORMAITON
Hazard Category for Section Acute Health, Chronic Health, Flammable 311/312: Section 302 Extremely This product does not contain chemicals regulated Hazardous Substances (TPQ): under SARA Section 302. Section 313 Toxic Chemicals: This product does not contain chemicals subject to SARA Title III Section 313 Reporting Requirements. CERCLA 103 Reportable Spills of this product over the RQ (reportable Quantity: quantity) must be reported to the National Response Center. The RQ for the product, based on the RQ for Methyl Ethyl Ketone (32% maximum) of 5,000 lbs, is 15,625 lbs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. California Proposition 65: This product does not contain any chemicals subject to the California Proposition 65 regulation. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Canadian WHIMS Classification: Class B, Division 2; Class D, Division 2, Subdivision A; Class D, Division 2, Subdivision B. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the best of our knowledge. However, Oatey cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its use.
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: OATEY PLUMBER’S PUTTY Product No.: 48003, 48004 Product Use: Stainless fixture setting compound. Formula: See SECTION 2 Synonyms: Putty. Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland, Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com Oatey Phone Number: (216) 267-7100 or (800) 321-9532 Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For Numbers: chemical transportation emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the US: 1-703-527-3887. Prepared By: Corporate Director – Safety and Environmental Compliance Preparation Date: April 15, 2008 SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER: Limestone 60 - 90% 1317-65-3 10 mg/M3 15 mg/M3 None (Total dust) Hydrocarbon oil 10 - 30% 64742-52-5 5 mg/M3 5 mg/M3 None Talc 1 - 5% 14807-96-6 2 mg/M3 2 mg/M3 None Clay 1 – 5% 68953-58-2 10 mg/M3 10 mg/M3 None OSHA Hazard Classification: Not hazardous SECTION 3 HAZARDS IDENTIFICATION Emergency Overview: White putty with a mild petroleum odor. May cause mechanical irritation of the eyes. SECTION 4 FIRST AID MEASURES CALL 1-303-623-5716 COLLECT Skin: Wash all exposed areas with soap and water. Eyes: If material gets into eyes or if fumes cause irritation, immediately
flush eyes with plenty of water until chemical is removed. If irritation persists, get medical attention immediately.
Inhalation: Not a likely route of entry. Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician. SECTION 5 FIRE FIGHTING MEASURES Flashpoint / Method: Not applicable Flammability: LEL = ND, UEL = ND Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire Media: exposed container with water. Water may be ineffective as an extinguishing agent. Special Fire As appropriate for surrounding fire. Fighting Procedure: Unusual Fire and None Explosion Hazards: Hazardous Combustion will produce toxic and irritating vapors including Decomposition carbon monoxide and carbon dioxide. Products:
MSDS No: OTH050C8 Issue Date: 15 Apr 2008 Page: 2 of 4 SECTION 6 ACCIDENTAL RELEASE MEASURES Spill or Sweep up dried material and dispose of with ordinary trash. Leak Procedures: SECTION 7 HANDLING AND STORAGE Handling: No special handling required. Wash thoroughly after handling. Use good hygiene practices. Storage: Store in a cool, dry area. Other: None. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Use with adequate ventilation. Respiratory If putty dries and becomes dusty, wear a dust respirator Protection: during clean-up. Skin Gloves are not normally required. Protection: Eye Safety glasses with side shields are recommended. Protection: Other: Eye wash should be available. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: Not applicable Melting Point: Not applicable Vapor Pressure: Not determined Vapor Density: Not determined Volatile Components: Not determined Solubility In Water: Negligible. pH: Not applicable Specific Gravity: 2.0 @ 20 Degrees C Evaporation Rate: Not applicable Appearance: White Putty Odor: Petroleum odor Will Dissolve In: Not determined Material Is: Putty SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: Avoid heat, flames and other sources of ignition. Hazardous Combustion will produce toxic and irritating vapors Decomposition including carbon monoxide and carbon dioxide. Products: Incompatibility/ Strong oxidizing agents. Materials To Avoid: Hazardous Will not occur. Polymerization:
MSDS No: OTH050C8 Issue Date: 15 Apr 2008 Page: 3 of 4 SECTION 11 TOXICOLOGICAL INFORMATION Inhalation: Not a likely route of entry. Skin: May cause mild irritation. Prolonged and repeated contact may cause dermatitis. Eye: Contact may cause irritation. Ingestion: Swallowing may cause a laxative effect including cramps and diarrhea. Chronic Prolonged or repeated overexposure cause dermatitis. Toxicity: Toxicity Data: Not available Sensitization: None of the components are known to cause sensitization. Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA. Mutagenicity: None of the components are known to be mutagenic. Reproductive None of the components are known to be toxic to reproduction. Toxicity: Medical None known. Conditions Aggravated By Exposure: SECTION 12 ECOLOGICAL INFORMATION No ecotoxicological information known. VOC This product has very low VOC level. Information: SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose in accordance with current local, state and federal regulations. RCRA Hazardous Waste Number: Not a hazardous waste. EPA Hazardous Waste ID Number: Not a hazardous waste. EPA Hazard Waste Class: Not a hazardous waste. SECTION 14 TRANSPORT INFORMATION DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) Proper Shipping Name: Not regulated. Not regulated. Hazard Class/Packing Group: None None UN/NA Number: None None Hazard Labels: None None IMDG Proper Shipping Name: Not regulated Hazard Class/Packing Group: None UN Number: None Label: None 2004 North American Emergency Response Guidebook Number: None
MSDS No: OTH050C8 Issue Date: 15 Apr 2008 Page: 4 of 4 SECTION 15 REGULATORY INFORMATION Hazard Category for Section Not hazardous. Section 302 Extremely This product does not contain chemicals regulated Hazardous Substances (TPQ): under SARA Section 302. Section 313 Toxic Chemicals: This product does not contain any chemicals regulated under SARA Title III Section 313. CERCLA 103 Reportable This product does not contain any chemicals regulated Quantity: under CERCLA. California Proposition 65: This product does not contain any chemicals subject To California Proposition 65 regulation. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Canadian WHIMS Classification: Not a controlled product. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 Special: None HMIS Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 PPE: A Disclaimer: The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the best of our knowledge. However, Oatey cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its use.
MATERIAL SAFETY DATA SHEET PRODUCT INFORMATION
Product Name: PIPE MATE (INHIBITED PROPYLENE GLYCOL) HD6905 Vendor Name & Address: HOOD CHEMICAL
295 ALLIANCE ROAD #14 MILTON ON L9T 4W8 905-876-0707
TDG Hazard Classification: NOT REGULATED TOXICOLOGICAL DATA
PHYSICAL/CHEMICAL PROPERTIES Appearance: PINK LIQUID Odour: ODOURLESS Boiling Point: 370°F 188°C Vapour Pressure: 0.22 mmHg @ 20°C Vapour Density (Air=1): 2.62 Solubility in Water: COMPLETE Specific Gravity: 1.0380 (20/20C), 68°F
FIRE AND EXPLOSION HAZARD Flash Point: 214°F 101°C Method Used: TAG, Closed Cup Flammable Limits (% in air) LFL: 2.3% UFL: 13.7% Extinguishing Media: WATER FOG, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire & Explosion Hazards: NOT AVAILABLE Fire Fighting Equipment: WEAR POSITIVE-PRESSURE, SELF-CONTAINED BREATHING
APPARATUS. Hazardous Decomposition : PROPIONALDEHYDE, CARBON MONOXIDE IN THE
PRESENCE OF LIMITED OXYGEN IN A FIRE SITUATION REACTIVITY DATA
Stability: STABLE UNDER NORMAL STORAGE CONDITIONSIncompatibility: (SPECIFIC MATERIALS TO AVOID) - OXIDIZING MATERIAL Hazardous Polymerization: WILL NOT OCCUR
HEALTH HAZARD DATA Eye Contact: MAY CAUSE SLIGHT TRANSIENT (TEMPORARY) EYE
IRRITATION. CORNEAL INJURY IS UNLIKELY Skin Contact: PROLONGED CONTACT IS ESSENTIALLY NON IRRITATING
TO SKIN. REPEATED EXPOSURE MAY CAUSE SLIGHT FLAKING, TENDERNESS, AND SOFTENING OF SKIN.
Skin Absorption: A SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO
RESULT IN THE MATERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. THE LD50 FOR SKIN ABSORPTION IN RABBITS IS >10g/kg.
Ingestion: SINGLE DOSE ORAL TOXICITY IS LOW. THE ORAL LD50 FOR RATS IS 21-33.7 G/KG. * NO HAZARDS ANTICIPATED FROM INGESTION INCIDENTAL TO INDUSTRIAL
EXPOSURE.
Inhalation: A SINGLE PROLONGED (HOURS) INHALATION EXPOSURE IS NOT LIKELY TO CAUSE ADVERSE EFFECTS. MISTS ARE NOT LIKELY TO BE HAZARDOUS.
Systemic & Other Effects: REPEATED EXCESSIVE INGESTION MAY CAUSE CENTRAL
NERVOUS SYSTEM EFFECTS. DID NOT CAUSE CANCER IN PAGE TWO PIPE MATE (PROPYLENE GLYCOL)
LONG-TERM ANIMAL STUDIES. BIRTH DEFECTS ARE UNLIKELY. EXPOSURES HAVING NO ADVERSE EFFECTS ON THE MOTHER SHOULD HAVE NO EFFECT ON THE FETUS. IN ANIMAL STUDIES, HAS BEEN SHOWN NOT TO INTERFERE WITH REPRODUCTION. RESULTS OF IN VITRO (“TEST TUBE”) MUTAGENICITY TESTS HAVE BEEN NEGATIVE. RESULTS OF MUTAGENICITY TEST IN ANIMALS HAVE BEEN NEGATIVE. PRECAUTION FOR SAFE HANDLING AND USE
Ventilation: GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT Respiratory Protection: WHEN AIRBORN EXPOSURE GUIDELINES AND/OR COMFORT
LEVELS MAY BE EXCEEDED, USE AN APPROVED AIR-PURIFYING RESPIRATOR.
Skin Protection: USE IMPERVIOUS GLOVES WHEN PROLONGED OR FREQUENTLY REPEATED CONTACT COULD OCCUR.
Eye Protection: USE SAFEY GLASSES. WHERE CONTACT WITH LIQUIDS IS LIKELY, CHEMICAL GOGGLES AR RECOMMENDED BECAUSE EYE CONTACT WITH THIS MATERIAL MAY CAUSE PAIN, EVEN THOUGH IT IS UNLIKELY TO CAUSE INJURY.
Action To Take For Spills/Leak: SMALL SPILLS: COVER WITH ABSORBENT MATERIAL, SOAK UP AND SWEEP INTO A DRUM LARGE SPILLS: DIKE AROUND SPILL AND PUMP INTO SUITABLE CONTAINERS.
Disposal Method: REPROCESS OR BURN IN AN APPROVED INCINERATOR IN ACCORDANCE WITH FEDERAL, PROVINCIAL AND LOCAL REQUIREMENTS.
EMERGENCY FIRST AID PROCEDURES Eye: IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES. Skin: WASH OFF IN FLOWING WATER OR SHOWER Inhalation: NO ADVERSE EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE Note to Physician: NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED
ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF
THE PATIENT PREPARATION INFORMATION
Prepared by: LAB PERSONNEL Date Revised: JANUARY 2011 DISCLAIMER OF LIABILITY:The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the material are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage
or expense arising out of or in any way connected with the handling, storage, use or disposal of the material. This MSDS was prepared and is to be used only for this material. If the material is used as a component in another material, this MSDS information may not be applicable. This document is generated for the purpose of distributing health, safety, and environmental data. It is not a specification sheet nor should any displayed date be construed as a specification. Some of the information presented and conclusions drawn herein are from sources other than direct test data on the material itself.
MATERIAL SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No 1907/2006, ISO 11014-1 and ANSI Z400.1 _________________________________________________________________________________________
Page 1 of 5
Rev. number: MSDS 04_rev.1 - 01/2012 Date: 11th January 2012
Application: GAS METAL ARC WELDING Standards: EN ISO 14341-A:11(*) EN ISO 14341-A:08 AWS A5.18:05 CSA W48:06 Classification: G 42 4 M21 3Si1/ G 42 4 C1 3Si1 G 42 4 M/3 C G3Si1 ER70S-6 B-G 49A 5 C G6
2. HAZARDS IDENTIFICATION Emergency Overview: Metal wire or rods in varying colors. This product is normally not considered hazardous as shipped. Gloves should be worn when handling to prevent cuts and abrasions. This product contains nickel, which is classified as a skin sensitizer and a suspect carcinogen. In the form that nickel is present in this product it does not contribute to a hazard classification of the product. Skin contact is normally no hazard but should be avoided to prevent possible allergic reactions. Persons with a pacemaker should not go near welding or cutting operations until they have consulted their doctor and obtained information from the manufacturer of the device. When this product is used in a welding process, the most important hazards are welding fumes, heat, radiation and electric shock. Fumes: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness
or irritation of the nose, throat or eyes. Chronic overexposure to welding fumes may affect pulmonary function. Prolonged inhalation of nickel and chromium compounds above safe exposure limits can cause cancer. Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible damage to the central nervous system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and spastic gait.
Heat: Spatter and melting metal can cause burn injuries and start fires. Radiation: Arc rays can severely damage eyes or skin. Electricity: Electric shock can kill.
3.COMPOSITION/INFORMATION ON INGREDIENTS This product is a continuous solid metal wire. Wire Composition Weight % CAS# EINECS# Hazard
class.1 IARC2 NTP3 OSHA
List4 Chromium <1 7440-47-3 231-157-5 No - - - Copper <1 7440-50-8 231-159-6 No - - - Iron >90 7439-89-6 231-096-4 No - - - Manganese 1-2 7439-96-5 231-105-1 No - - - Molybdenum <1 7439-98-7 231-107-2 No - - - Nickel <1 7440-02-0 231-111-4 Xn; R40-43 2B S - Silicon 1-2 7440-21-3 231-130-8 No - - - (1) Hazard Classification according to European Council Directive 67/548/EEC, for R-phrases see Section 16. (2) Evaluation according to the International Agency for Research on Cancer. 1-Carcinogenic to humans. 2A-Probably carcinogenic to humans. 2B-Possibly carcinogenic to humans. (3) Classification according to the 11th Report on Carcinogens, published by the US National ToxicologyProgram. K- Known to be a Human Carcinogen. S- Suspect Carcinogen. (4) Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA)
MATERIAL SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No 1907/2006, ISO 11014-1 and ANSI Z400.1 _________________________________________________________________________________________
Page 2 of 5
4. FIRST AID MEASURES Inhalation: If breathing has stopped, perform artificial respiration and obtain medical assistance immediately! If
breathing is difficult, provide fresh air and call physician. Eye contact: For radiation burns due to arc flash, see physician. To remove dusts or fumes flush with water for at
least fifteen minutes. If irritation persists, obtain medical assistance. Skin contact: For skin burns from arc radiation, promptly flush with cold water. Get medical attention for burns or
irritations that persist. To remove dust or particles wash with mild soap and water. Electric shock: Disconnect and turn off the power. Use a nonconductive material to pull victim away from contact with
live parts or wires. If not breathing, begin artificial respiration, preferably mouth-to-mouth. If no detectable pulse, begin Cardio Pulmonary Resuscitation (CPR). Immediately call a physician.
General: Move to fresh air and call for medical aid.
5. FIRE FIGHTING MEASURES No specific recommendations for welding consumables. Welding arcs and sparks can ignite combustible and flammable materials. Use the extinguishing media recommended for burning materials and fire situation. Wear self-contained breathing apparatus as fumes or vapors may be harmful.
6. ACCIDENTAL RELEASE MEASURES Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed into a container. Wear proper protective equipment while handling these materials. Do not discard as refuse. Personal precautions: refer to section 8. Environmental precautions: refer to section 13.
7. HANDLING AND STORAGE Handling: Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid
exposure to dust. Do not ingest. Some individuals can develop an allergic reaction to certain materials. Retain all warning and identity labels.
Storage: Keep separate from chemical substances like acids and strong bases,which could cause chemical
reactions.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Avoid exposure to welding fumes, radiation, spatter, electric shock, heated materials and dust. Engineering measures:
Ensure sufficient ventilation, local exhaust, or both, to keep welding fumes and gases from breathing zone and general area. Keep working place and protective clothing clean and dry. Train welders to avoid contact with live electrical parts and insulate conductive parts. Check condition of protective clothing and equipment on a regular basis.
Personal protective equipment:
Use respirator or air supplied respirator when welding or brazing in a confined space, or where local exhaust or ventilation is not sufficient to keep exposure values within safe limits. Use special care when welding painted or coated steels since hazardous substances from the coating may be emitted. Wear hand, head, eyes, ear and body protection like welders gloves, helmet or face shield with filter lens, safety boots, apron, arm and shoulder protection. Keep protective clothing clean and dry.
Use industrial hygiene monitoring equipment to ensure that exposure does not exceed applicable national exposure limits. The following limits can be used as guidance. Unless noted, all values are for 8 hour time weighted averages (TWA). For information about welding fume analysis refer to Section 10. Substance CAS# ACGIH TLV 1 mg/m3 OSHA PEL 2 mg/m3
MATERIAL SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No 1907/2006, ISO 11014-1 and ANSI Z400.1 _________________________________________________________________________________________
Page 3 of 5
Chromium 7440-47-3 0,5 1 Copper 7440-50-8 1(d&m), 0,2(f) 1(d&m), 0,1(f) Iron 7439-89-6 5** 10(f) Manganese 7439-96-5 0,2 5(ceil) Molybdenum 7439-98-7 3**, 10*** 15* Nickel 7440-02-0 1,5*** 1 Silicon 7440-21-3 - 15*, 5 ** (1) Threshold Limit Values according to American Conference of Governmental Industrial Hygienists,2008 (2) Permissible Exposure Limits according to the Occupational Safety & Health Administration (USA). (3) *Total dust, **Respirable fraction, ***Inhalable fraction.(f) fume, (d) dust, (m) mist, (ceil) ceiling.
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Solid, non-volatile with varying color Melting point: >1000°C / >1800°F
10. STABILITY AND REACTIVITY General: This product is only intended for normal welding purposes Stability: This product is stable under normal conditions. Reactivity: Contact with chemical substances like acids or strong bases could cause generation of gas. When this product is used in a welding process, hazardous decomposition products would include those from the volatilization, reaction or oxidation of the materials listed in section 3 and those from the base metal and coating. The amount of fumes generated from this product varies with welding parameters and dimensions, but is generally no more than 5 to 10 g/kg consumable. Fumes from this product contain compounds of the following chemical elements. The rest is not analyzed, according to available standards. Fume analysis: Fe Mn Si Pb Cu Ni Cr weight % less than 60 10 5 0.2 1 0.1 0.1 Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds found in Section 8. A significant amount of the chromium in the fumes can be hexavalent chromium, which has a very low exposure limit in some countries. Manganese and nickel have low exposure limits, in some countries, that may be easily exceeded. Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around the welding area can be affected by the welding process and influence the composition and quantity of fumes and gases produced.
11. TOXICOLOGICAL INFORMATION Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding fumes is difficult because of varying base materials, coatings, air contamination and processes. The International Agency for Research on Cancer has classified welding fumes as possibly carcinogenic to humans (Group 2B). Acute toxicity: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea,
dryness or irritation of the nose, throat or eyes.
Chronic toxicity: Overexposure to welding fumes may affect pulmonary function. Prolonged inhalation of nickel and chromium compounds above safe exposure limits can cause cancer. Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible damage to the central nervous system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and spastic gait.
MATERIAL SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No 1907/2006, ISO 11014-1 and ANSI Z400.1 _________________________________________________________________________________________
Page 4 of 5
12. ECOLOGICAL INFORMATION Welding consumables and materials could degrade/weather into components originating from the consumables or from the materials used in the welding process. Avoid exposure to conditions that could lead to accumulation in soils or groundwater.
13. DISPOSAL CONSIDERATIONS Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal and local regulations. Use recycling procedures if available. USA RCRA: Unused products or product residue containing chromium is considered hazardous waste if discarded, RCRA ID Characteristic Toxic Hazardous Waste D007. Residues from welding consumables and processes could degrade and accumulate in soils and groundwater.
14. TRANSPORT INFORMATION No international regulations or restrictions are applicable.
15. REGULATORY INFORMATION Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety instructions on the label. Observe any federal and local regulations. Take precautions when welding and protect yourself and others. WARNING: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate ventilation. ELECTRIC SHOCK can kill. ARC RAYS and SPARKS can injure eyes and burn skin. Wear correct hand, head, eye and body protection. Canada: WHMIS classification: Class D; Division 2, Subdivision A Canadian Environmental Protection Act (CEPA):
All constituents of this product are on the Domestic Substance List (DSL). USA: Under the OSHA Hazard Communication Standard, this product is considered hazardous.
This product contains or produces a chemical known to the state of California to cause cancer and birth defects (or other reproductive harm). (California Health & Safety Code § 25249.5 et seq.) United States EPA Toxic Substance Control Act: All constituents of this product are on the TSCA inventory list or are excluded from listing. CERCLA/SARA Title III Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs):
Ingredient name RQ (lb) TPQ (lb) Product is a solid solution in the form of a solid article. - -
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center and to your Local Emergency Planning Committee. Section 311 Hazard Class As shipped: Immediate In use: Immediate delayed EPCRA/SARA Title III 313 Toxic Chemicals The following metallic components are listed as SARA 313 “Toxic Chemicals” and potential subject to annual SARA 313 reporting. See Section 3 for weight percent.
MATERIAL SAFETY DATA SHEET
This Safety Data Sheet complies with Regulation (EC) No 1907/2006, ISO 11014-1 and ANSI Z400.1 _________________________________________________________________________________________
Page 5 of 5
Ingredient name Disclosure threshold Chromium 1.0% de minimis concentration Manganese 1.0% de minimis concentration Nickel 0.1% de minimis concentration Copper 1.0% de minimis concentration
16. OTHER INFORMATION
This Safety Data Sheet has been revised due to modifications to several paragraphs and/or new format.
USA:
Refer to American National Standard Z49.1 "Safety in Welding and Cutting", ANSI/AWS F1.5 “ Methods for Sampling and Analyzing Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles Generated by Welding and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American Welding Society, 550 North Le Jeune Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from AWS at www.aws.org OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government Printing Office, Superintendent of Documents, P.O. Box 371954, Pittsburgh, PA 15250-7954 American Conference of Governmental Hygienists (ACGIH), Threshold Limit Values and Biological Exposure Indices, 6500 Glenway Ave.,Cincinnati, Ohio 45211, USA. NFPA 51B “Standard for Fire Prevention During Welding, Cutting and Other Hot Work” published by the National Fire Protection Association, 1 Batterymarch Park, Quincy, MA 02169
UK: WMA Publication 236 and 237, "Hazards from Welding fume”, ”The arc welder at work, some general
aspects of health and safety". Germany: Unfallverhütungsvorschrift BGV D1, "Schweißen, Schneiden und verwandte Verfahren".
Canada: CSA Standard CAN/CSA-W117.2-01 “Safety in Welding, Cutting and Allied Processes”
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
R-phrases: R40 - Limited evidence of a carcinogenic effect.
R43 - May cause sensitization by skin contact.
SIDERGAS requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should:
• notify its employees, agents and contractors of the information on this MSDS and any product hazards/safety information.
• furnish this same information to each of its customers for the product. • request such customers to notify employees and customers for the same product hazards and safety information.
The information herein is given in good faith and based on technical data that SIDERGAS believes to be reliable. Since the conditions of use is outside our control, we assume no liability in connection with any use of this information and no warranty, expressed or implied is given. For additional information contact SIDERGAS at Phone No. + 39 045 6862044 or e-mail at: [email protected]
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------3 PRIMER (PVC & CPVC Primer). PRODUCT USES-----------------------Primer used with PVC and CPVC Solvent Cements. CHEMICAL FAMILY--------------------Solvent Blend.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------Tetrahydrofuran can be absorbed through the skin resulting in toxic effects. INHALATION-------------------As described below. INHALATION CHRONIC-----------Can cause damage to the respiratory system. Can cause headache, dizziness and nausea. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. EYE CONTACT------------------Causes eye burns. Severe irritation, redness, watering and blurred vision. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system, respiratory system, lungs, eyes, skin, gastro-intestinal tract, liver, spleen and kidneys. May cause nausea, headache, dizziness and drowsiness. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET 3 PRIMER
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EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back. SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------12.50. LOWER FLAMMABLE LIMIT (% VOL)------11.60. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Hydrogen Chloride. SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Prevent run-off into drains, sewers and other waterways. Use a non-combustible absorbent inorganic material. Ventilate. Eliminate all sources of ignition. Contain spill with dike to prevent entry into sewers and waterways. For large quantities contact the Environmental Authorities.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid prolonged or repeated skin contact. Handle away from all sources of ignition. Ventilate adequately and wear appropriate breathing apparatus. STORAGE NEEDS----------------------Store in a dry, well ventilated area. Store in a cool area, away from all sources of heat and ignition. Keep container closed and out of reach from children and pets when not in use.
MATERIAL SAFETY DATA SHEET 3 PRIMER
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SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:--------------- EYE/TYPE---------------------Safely goggles. RESPIRATORY/TYPE-------------Wear a NIOSH/MSHA approved air supply respirator. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not available. FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Strong solvent odour. SPECIFIC GRAVITY-------------------0.84 - 0.88. ODOUR THRESHOLD (ppm)--------------25 ppm. VAPOUR PRESSURE--------------------145 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)-------------2.50. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not available. SOLUBILITY IN WATER (% W/W)--------Slightly. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not available. MOLECULAR WEIGHT-------------------
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Ammonia. Do NOT mix with nitrites. Strong acids and strong bases. REACTIVITY CONDITIONS--------------Thermal. HAZARDOUS PRODUCTS OF--------------Hydrogen Chloride. Oxides of Carbon (CO and DECOMPOSITION C02). Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------50 ppm for Toluene.200 ppm for Methyl Ethyl Ketone.200 ppm for Tetrahydrofuran. IRRITANCY OF MATERIAL--------------Irritant upon prolonged exposure. Eye irritant. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Not available. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET 3 PRIMER
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SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 409 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 1 litre - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - FLAMMABLE LIQUIDS N.O.S.(TETRAHYDROFURAN) CLASS 3. (B)--------------------------------(B) In containers over 1 litre - FLAMMABLE LIQUIDS N.O.S. (TETRAHYDROFURAN) CLASS 3 UN1993 P.G. II.
SECTION 15: REGULATORY INFORMATION WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------3V PRIMER (PVC & CPVC Primer). PRODUCT USES-----------------------Primer used with PVC and CPVC Solvent Cements. CHEMICAL FAMILY--------------------Solvent Blend.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------Tetrahydrofuran can be absorbed through the skin resulting in toxic effects. INHALATION-------------------As described below. INHALATION CHRONIC-----------Can cause damage to the respiratory system. Can cause headache, dizziness and nausea. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. EYE CONTACT------------------Causes eye burns. Severe irritation, redness, watering and blurred vision. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system, respiratory system, lungs, eyes, skin, gastro-intestinal tract, liver, spleen and kidneys. May cause nausea, headache, dizziness and drowsiness. Prolonged or repeated skin contact may cause drying or cracking of the skin.
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Ref: 00000026 Preparation Date : April.23.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back. SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------12.50. LOWER FLAMMABLE LIMIT (% VOL)------11.60. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Hydrogen Chloride. SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Prevent run-off into drains, sewers and other waterways. Use a non-combustible absorbent inorganic material. Ventilate. Eliminate all sources of ignition. Contain spill with dike to prevent entry into sewers and waterways. For large quantities contact the Environmental Authorities.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid prolonged or repeated skin contact. Handle away from all sources of ignition. Ventilate adequately and wear appropriate breathing apparatus. STORAGE NEEDS----------------------Store in a dry, well ventilated area. Store in a cool area, away from all sources of heat and ignition. Keep container closed and out of reach from children and pets when not in use.
MATERIAL SAFETY DATA SHEET 3V PRIMER
Page : 3
Ref: 00000026 Preparation Date : April.23.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:--------------- EYE/TYPE---------------------Safely goggles. RESPIRATORY/TYPE-------------Wear a NIOSH/MSHA approved air supply respirator. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not available. FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Strong solvent odour. SPECIFIC GRAVITY-------------------0.84 - 0.88. ODOUR THRESHOLD (ppm)--------------25 ppm. VAPOUR PRESSURE--------------------145 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)-------------2.50. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not available. SOLUBILITY IN WATER (% W/W)--------Slightly. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not available. MOLECULAR WEIGHT-------------------
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Ammonia. Do NOT mix with nitrites. Strong acids and strong bases. REACTIVITY CONDITIONS--------------Thermal. HAZARDOUS PRODUCTS OF--------------Hydrogen Chloride. Oxides of Carbon (CO and DECOMPOSITION C02). Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------50 ppm for Toluene.200 ppm for Methyl Ethyl Ketone.200 ppm for Tetrahydrofuran. IRRITANCY OF MATERIAL--------------Irritant upon prolonged exposure. Eye irritant. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Not available. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET 3V PRIMER
Page : 4
Ref: 00000026 Preparation Date : April.23.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 409 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 1 litre - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - FLAMMABLE LIQUIDS N.O.S.(TETRAHYDROFURAN) CLASS 3. (B)--------------------------------(B) In containers over 1 litre - FLAMMABLE LIQUIDS N.O.S. (TETRAHYDROFURAN) CLASS 3 UN1993 P.G. II.
SECTION 15: REGULATORY INFORMATION WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------ABS 55Y (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Acrylonitrile-Butadiene Styrene.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------Not applicable. INHALATION-------------------As described below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness .May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. If not removed promptly, it will injure the eye tissue and may cause permanent eye damage. EFFECTS OF ACUTE EXPOSURE---------- EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET ABS 55Y SOLVENT CEMENT
Page : 2
Ref: 0000100E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back. back. SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -4ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------480ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.50. LOWER FLAMMABLE LIMIT (% VOL)------1.80. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Traces of monomers. Oxides of Carbon (CO and CO2). Hydrogen Cyanide. SENSITIVITY TO MECHANICAL----------Not available. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Small spills can be wiped. Large spills must be collected for disposal. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away
MATERIAL SAFETY DATA SHEET ABS 55Y SOLVENT CEMENT
Page : 3
Ref: 0000100E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Aromatic Solvent odour. SPECIFIC GRAVITY-------------------0.86 - 0.90. ODOUR THRESHOLD (ppm)--------------25 ppm. VAPOUR PRESSURE--------------------22 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------1.80 (NBUAC = 1). BOILING POINT (deg C)--------------110ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Styrene and Acrylonitrile monomer. Oxides DECOMPOSITION of Carbon (CO and C02). Toxic fumes. Smoke.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. Residual amounts of Acrylonitrile and Styrene monomer may be present in decomposition but not in normal use. These are both suspected carcinogens.
MATERIAL SAFETY DATA SHEET ABS 55Y SOLVENT CEMENT
Page : 4
Ref: 0000100E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 580 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION--------------In containers up to 5 litres - shipped as CONSUMER
COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is
furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
MATERIAL SAFETY DATA SHEET ABS 55Y-LV SOLVENT CEMENT
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------ABS 55Y-LV (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Acrylonitrile-Butadiene Styrene.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------Not applicable. INHALATION-------------------As described below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness .May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. If not removed promptly, it will injure the eye tissue and may cause permanent eye damage. EFFECTS OF ACUTE EXPOSURE---------- EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET ABS 55Y-LV SOLVENT CEMENT
Page : 2
Ref: 0000100E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back. back. SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -4ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------480ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.50. LOWER FLAMMABLE LIMIT (% VOL)------1.80. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Traces of monomers. Oxides of Carbon (CO and CO2). Hydrogen Cyanide. SENSITIVITY TO MECHANICAL----------Not available. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Small spills can be wiped. Large spills must be collected for disposal. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away
MATERIAL SAFETY DATA SHEET ABS 55Y-LV SOLVENT CEMENT
Page : 3
Ref: 0000100E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Aromatic Solvent odour. SPECIFIC GRAVITY-------------------0.86 - 0.90. ODOUR THRESHOLD (ppm)--------------25 ppm. VAPOUR PRESSURE--------------------22 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------1.80 (NBUAC = 1). BOILING POINT (deg C)--------------110ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Styrene and Acrylonitrile monomer. Oxides DECOMPOSITION of Carbon (CO and C02). Toxic fumes. Smoke.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. Residual amounts of Acrylonitrile and Styrene monomer may be present in decomposition but not in normal use. These are both suspected carcinogens.
MATERIAL SAFETY DATA SHEET ABS 55Y-LV SOLVENT CEMENT
Page : 4
Ref: 0000100E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 311 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION--------------In containers up to 5 litres - shipped as CONSUMER
COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is
furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------ABS 66Y (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Acrylonitrile-Butadiene Styrene.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
METHYL ETHYL KETONE 60 – 80 78-93-3 2737 mg/kg 23500 mg/m3 8 Hours 200 ppm Oral (Rat) Inhalation (Rat) ABS POLYMER 20 - 30 9003-56-9 Not Available Not Available
Not Available
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------Not applicable. INHALATION-------------------As described below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness .May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. If not removed promptly, it will injure the eye tissue and may cause permanent eye damage. EFFECTS OF ACUTE EXPOSURE---------- EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET ABS 66Y SOLVENT CEMENT
Page : 2
Ref: 0000101E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back. back. SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -4ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------480ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.50. LOWER FLAMMABLE LIMIT (% VOL)------1.80. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Traces of monomers. Oxides of Carbon (CO and CO2). Hydrogen Cyanide. SENSITIVITY TO MECHANICAL----------Not available. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Small spills can be wiped. Large spills must be collected for disposal. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated
MATERIAL SAFETY DATA SHEET ABS 66Y SOLVENT CEMENT
Page : 3
Ref: 0000101E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
area. Keep container closed and out of reach from children and pets when not in use.
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Aromatic Solvent odour. SPECIFIC GRAVITY-------------------0.86 - 0.90. ODOUR THRESHOLD (ppm)--------------25 ppm. VAPOUR PRESSURE--------------------22 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------1.80 (NBUAC = 1). BOILING POINT (deg C)--------------110ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Styrene and Acrylonitrile monomer. Oxides DECOMPOSITION of Carbon (CO and C02). Toxic fumes. Smoke.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. Residual amounts of Acrylonitrile and Styrene monomer may be present in decomposition but not in normal use. These are both suspected carcinogens. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse
MATERIAL SAFETY DATA SHEET ABS 66Y SOLVENT CEMENT
Page : 4
Ref: 0000101E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 600 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 5 litres - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. (B)--------------------------------(B) In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------CLEANER 33. CHEMICAL FAMILY--------------------Solvent Blend. PRODUCT USES-----------------------Cleaning solvent.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------Not available. INHALATION-------------------See "EFFECTS OF CHRONIC EXPOSURE", below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness. May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are moderately irritating to the eyes. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------Product is believed to have low toxicity for other chronic exposures. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET CLEANER 33
Page : 2
Ref: 00000296 Preparation Date : April.23.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Flammable liquid. Fire hazard when exposed to heat, flame or temperatures above the flash point. Vapours are heavier than air and may travel to a source of ignition and flash-back. SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.80. LOWER FLAMMABLE LIMIT (% VOL)------2.20. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Toxic fumes. SENSITIVITY TO MECHANICAL----------Not available. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Small spills can be wiped. Large spills must be collected for disposal. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store in a cool area, away from all sources of heat and ignition. Keep container closed and out of reach from children and pets when not in use. Store in a dry, well ventilated area.
MATERIAL SAFETY DATA SHEET CLEANER 33
Page : 3
Ref: 00000296 Preparation Date : April.23.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------If used indoors on a continuous basis or if the TLV is exceeded, the use of a cartridge type respirator (NIOSH/MSHA approved) is recommended. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Solvent odour. SPECIFIC GRAVITY-------------------0.80 - 0.90. ODOUR THRESHOLD (ppm)--------------Not available. VAPOUR PRESSURE--------------------145 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Oxides of Carbon (CO and C02). Toxic DECOMPOSITION fumes. Smoke.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------No information is available and no adverse carcinogenic effects are anticipated. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------No information is available and no adverse reproductive effects are anticipated. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET CLEANER 33
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Ref: 00000296 Preparation Date : April.23.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 508 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (1)--------------------------------(1e) In containers up to 1 litre - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - FLAMMABLE LIQUIDS N.O.S. (TOLUENE) Class 3. (2)--------------------------------(2e) In containers over 1 litre - Flammable Liquids N.O.S. (Toluene Class 3 UN1993 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency. PREPARED BY:---------------------- Technical Service Department, Sluyter Company Ltd. (905)475-6011
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------CPVC 77 Solvent Cement. PRODUCT USES-----------------------For solvent welding CPVC pipes and fittings. CHEMICAL FAMILY--------------------CPVC based Solvent Cement.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------No data available. INHALATION-------------------See "EFFECTS OF CHRONIC EXPOSURE", below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness. Can cause damage to the respiratory system. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------Prolonged or repeated skin contact may cause drying or cracking of the skin. May cause damage to the central nervous system.
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. Get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention.
MATERIAL SAFETY DATA SHEET CPVC 77
Page : 2
Ref: 0000108E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back. SPECIAL PROCEDURES-----------------Self contained breathing apparatus and protective clothing is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5°C TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321°C. UPPER FLAMMABLE LIMIT (% VOL)------11.80. LOWER FLAMMABLE LIMIT (% VOL)------11.60. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Carbon Dioxide. Carbon Monoxide. Smoke. SENSITIVITY TO MECHANICAL----------Yes. IMPACT SENSITIVITY TO STATIC--------------Yes. DISCHARGE SENSITIVITY TO MECHANICAL---------- IMPACT
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Large spills must be collected for disposal. Small spills can be wiped. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------If used indoors on a continuous basis or if the TLV is exceeded, the use of a cartridge type respirator (NIOSH/MSHA approved) is recommended. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Wear adequate protective clothing.
MATERIAL SAFETY DATA SHEET CPVC 77
Page : 3
Ref: 0000108E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Ketone odour. SPECIFIC GRAVITY-------------------0.90 - 1.00. ODOUR THRESHOLD (ppm)--------------Not available. VAPOUR PRESSURE--------------------145 mmHg @ 20°C. VAPOUR DENSITY (AIR=1)-------------> 1.00. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65°C. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- < 0°C. MELTING POINT (deg C)--------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Avoid high temperatures. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Oxides of Carbon (CO and C02). Toxic fumes. Smoke. DECOMPOSITION
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Eye irritant. Skin irritant. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------No information is available and no adverse carcinogenic effects are anticipated. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 600 grams/litre (SCAQMD Test Method 316A)
MATERIAL SAFETY DATA SHEET CPVC 77
Page : 4
Ref: 0000108E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A) In containers up to 5 litres - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. (B) In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G.II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
MATERIAL SAFETY DATA SHEET IPEX 100T PRIMER (Low VOC)
Page : 1
Ref: 00000318 Preparation Date : January.03.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SLUYTER COMPANY LTD.
375 Steelcase Road East Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011 Fax (905) 475-3119
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------IPEX 100T PRIMER . MANUFACTURED FOR-------------------Ipex Electrical Inc. 2441 Royal Windsor Drive, Mississauga, ON L5J 4C7 PRODUCT USES-----------------------Primer used with PVC Solvent Cements. CHEMICAL FAMILY--------------------Solvent Blend.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------Tetrahydrofuran can be absorbed through the skin resulting in toxic effects. INHALATION-------------------As described below. INHALATION CHRONIC-----------Can cause damage to the respiratory system. Can cause headache, dizziness and nausea. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. EYE CONTACT------------------Causes eye burns. Severe irritation, redness, watering and blurred vision. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system, respiratory system, lungs, eyes, skin, gastro-intestinal tract, liver, spleen and kidneys. May cause nausea, headache, dizziness and drowsiness. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET IPEX 100T PRIMER (Low VOC)
Page : 2
Ref: 00000318 Preparation Date : January.03.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back. SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------12.50. LOWER FLAMMABLE LIMIT (% VOL)------11.60. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Hydrogen Chloride. SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Prevent run-off into drains, sewers and other waterways. Use a non-combustible absorbent inorganic material. Ventilate. Eliminate all sources of ignition. Contain spill with dike to prevent entry into sewers and waterways. For large quantities contact the Environmental Authorities.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid prolonged or repeated skin contact. Handle away from all sources of ignition. Ventilate adequately and wear appropriate breathing apparatus. STORAGE NEEDS----------------------Store in a dry, well ventilated area. Store
MATERIAL SAFETY DATA SHEET IPEX 100T PRIMER (Low VOC)
Page : 3
Ref: 00000318 Preparation Date : January.03.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
in a cool area, away from all sources of heat and ignition. Keep container closed and out of reach from children and pets when not in use.
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:--------------- EYE/TYPE---------------------Safely goggles. RESPIRATORY/TYPE-------------Wear a NIOSH/MSHA approved air supply respirator. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not available. FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Strong solvent odour. SPECIFIC GRAVITY-------------------0.84 - 0.88. ODOUR THRESHOLD (ppm)--------------25 ppm. VAPOUR PRESSURE--------------------145 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)-------------2.50. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not available. SOLUBILITY IN WATER (% W/W)--------Slightly. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not available. MOLECULAR WEIGHT-------------------
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Ammonia. Do NOT mix with nitrites. Strong acids and strong bases. REACTIVITY CONDITIONS--------------Thermal. HAZARDOUS PRODUCTS OF--------------Hydrogen Chloride. Oxides of Carbon (CO and DECOMPOSITION C02). Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------50 ppm for Toluene.200 ppm for Methyl Ethyl Ketone.200 ppm for Tetrahydrofuran. IRRITANCY OF MATERIAL--------------Irritant upon prolonged exposure. Eye irritant. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Not available. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET IPEX 100T PRIMER (Low VOC)
Page : 4
Ref: 00000318 Preparation Date : January.03.2013
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 409 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 1 litre - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - FLAMMABLE LIQUIDS N.O.S.(TETRAHYDROFURAN) CLASS 3. (B)--------------------------------(B) In containers over 1 litre - FLAMMABLE LIQUIDS N.O.S. (TETRAHYDROFURAN) CLASS 3 UN1993 P.G. II.
SECTION 15: REGULATORY INFORMATION WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
MATERIAL SAFETY DATA SHEET PVC S40-LV SOLVENT CEMENT
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------PVC S40-LV (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Poly Vinyl Chloride based cement.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------No data available. INHALATION-------------------See "EFFECTS OF CHRONIC EXPOSURE", below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness. May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET PVC S40-LV SOLVENT CEMENT
Page : 2
Ref: 0000102E Preparation Date : February.02.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.80. LOWER FLAMMABLE LIMIT (% VOL)------2.20. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Carbon Dioxide. Carbon Monoxide. Hydrogen Chloride. Smoke. SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Large spills must be collected for disposal. Small spills can be wiped. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and
MATERIAL SAFETY DATA SHEET PVC S40-LV SOLVENT CEMENT
Page : 3
Ref: 0000102E Preparation Date : February.02.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Ketone odour. SPECIFIC GRAVITY-------------------0.90 - 1.00. ODOUR THRESHOLD (ppm)--------------Not available. VAPOUR PRESSURE--------------------145 mm Hg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Carbon Dioxide. Carbon Monoxide. Hydrogen DECOMPOSITION Chloride. Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET PVC S40-LV SOLVENT CEMENT
Page : 4
Ref: 0000102E Preparation Date : February.02.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 475 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 5 litres - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. (B)--------------------------------(B) In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
MATERIAL SAFETY DATA SHEET PVC S-40 SOLVENT CEMENT
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------PVC S-40 (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Poly Vinyl Chloride based cement.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------No data available. INHALATION-------------------See "EFFECTS OF CHRONIC EXPOSURE", below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness. May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET PVC S-40 SOLVENT CEMENT
Page : 2
Ref: 0000102E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.80. LOWER FLAMMABLE LIMIT (% VOL)------2.20. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Carbon Dioxide. Carbon Monoxide. Hydrogen Chloride. Smoke. SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Large spills must be collected for disposal. Small spills can be wiped. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
MATERIAL SAFETY DATA SHEET PVC S-40 SOLVENT CEMENT
Page : 3
Ref: 0000102E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Ketone odour. SPECIFIC GRAVITY-------------------0.90 - 1.00. ODOUR THRESHOLD (ppm)--------------Not available. VAPOUR PRESSURE--------------------145 mm Hg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Carbon Dioxide. Carbon Monoxide. Hydrogen DECOMPOSITION Chloride. Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET PVC S-40 SOLVENT CEMENT
Page : 4
Ref: 0000102E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 550 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 5 litres - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. (B)--------------------------------(B) In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
MATERIAL SAFETY DATA SHEET PVC S-80 SOLVENT CEMENT
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------PVC S-80 (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Poly Vinyl Chloride based cement.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------No data available. INHALATION-------------------See "EFFECTS OF CHRONIC EXPOSURE", below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness. May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET PVC S-80 SOLVENT CEMENT
Page : 2
Ref: 0000103E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.80. LOWER FLAMMABLE LIMIT (% VOL)------2.20. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Carbon Dioxide. Carbon Monoxide. Hydrogen Chloride. Smoke SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Large spills must be collected for disposal. Small spills can be wiped. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
MATERIAL SAFETY DATA SHEET PVC S-80 SOLVENT CEMENT
Page : 3
Ref: 0000103E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Ketone odour. SPECIFIC GRAVITY-------------------0.90 - 1.00. ODOUR THRESHOLD (ppm)--------------Not available. VAPOUR PRESSURE--------------------145 mm Hg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Carbon Dioxide. Carbon Monoxide. Hydrogen DECOMPOSITION Chloride. Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET PVC S-80 SOLVENT CEMENT
Page : 4
Ref: 0000103E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 650 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 5 litres - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. (B)--------------------------------(B) In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
MATERIAL SAFETY DATA SHEET PVC S-92 SOLVENT CEMENT
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------PVC S-92 (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Poly Vinyl Chloride based cement.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------No data available. INHALATION-------------------See "EFFECTS OF CHRONIC EXPOSURE", below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness. May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET PVC S-92 SOLVENT CEMENT
Page : 2
Ref: 0000104E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.80. LOWER FLAMMABLE LIMIT (% VOL)------2.20. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Carbon Dioxide. Carbon Monoxide. Hydrogen Chloride. Smoke. SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Large spills must be collected for disposal. Small spills can be wiped. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
MATERIAL SAFETY DATA SHEET PVC S-92 SOLVENT CEMENT
Page : 3
Ref: 0000104E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Clear Liquid. ODOUR------------------------------Ketone odour. SPECIFIC GRAVITY-------------------0.90 - 1.00. ODOUR THRESHOLD (ppm)--------------Not available. VAPOUR PRESSURE--------------------145 mmHg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Carbon Dioxide. Carbon Monoxide. Hydrogen DECOMPOSITION Chloride. Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET PVC S-92 SOLVENT CEMENT
Page : 4
Ref: 0000104E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly.
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (1)--------------------------------(1a) In containers up to 5 litres - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. (2)--------------------------------(2a) In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER-----------------------SLUYTER COMPANY LTD. 375 Steelcase Road East Markham, Ontario L3R 1G3 Canada Tel (905) 475-6011 PRODUCT NAME-----------------------PVC/DWV (Solvent Cement). PRODUCT USES-----------------------For welding plastic pipes and fittings. CHEMICAL FAMILY--------------------Poly Vinyl Chloride based cement.
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
SECTION 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY:-------------------- SKIN CONTACT-----------------Can cause moderate skin irritation, defatting and dermatitis. SKIN ABSORPTION--------------No data available. INHALATION-------------------See "EFFECTS OF CHRONIC EXPOSURE", below. INHALATION CHRONIC-----------Breathing of high vapour concentrations could cause dizziness, headache or even unconsciousness. May be anesthetic which could result in other central nervous system effects. INGESTION--------------------Can cause gastro-intestinal irritation, nausea, vomiting and diarrhea. Small amounts of liquid aspirated into respiratory system could cause severe health effects (e.g. Bronchopneumonia or Pulmonary Edema). EYE CONTACT------------------Contains materials that are severely irritating to the eyes. EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section. EFFECTS OF CHRONIC EXPOSURE--------May cause damage to the central nervous system. Prolonged or repeated skin contact may cause drying or cracking of the skin.
MATERIAL SAFETY DATA SHEET PVC/DWV SOLVENT CEMENT
Page : 2
Ref: 000106E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 04: FIRST AID MEASURES EYE CONTACT------------------------Check for and remove any contact lenses. Immediately flush with water for a minimum of 20 minutes and get medical attention. SKIN CONTACT-----------------------Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if irritation occurs or persists. INHALATION-------------------------Remove patient to fresh air. If not breathing, trained personnel should administer artificial respiration. Get medical attention. INGESTION--------------------------Do NOT induce vomiting. Get immediate medical attention. ADDITIONAL INFORMATION-------------Contact your local poison control centre.
SECTION 05: FIRE FIGHTING MEASURES FLAMMABILITY-----------------------Flammable. UNDER WHAT CONDITIONS--------------Extremely flammable liquid. Dangerous fire hazard when exposed to heat, flame or temperatures above the flash point. As vapours are heavier than air, they may travel to a source of ignition and flash back SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is required for fire fighting personnel. Use water spray to cool fire exposed surfaces and to protect personnel. FLASH POINT (METHOD)--------------- -5ºC TAG Closed Cup. AUTO IGNITION TEMPERATURE----------321ºC. UPPER FLAMMABLE LIMIT (% VOL)------11.80. LOWER FLAMMABLE LIMIT (% VOL)------2.20. EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical. HAZARDOUS COMBUSTION PRODUCTS------Carbon Dioxide. Carbon Monoxide. Hydrogen Chloride. Smoke. SENSITIVITY TO MECHANICAL----------Unknown. IMPACT SENSITIVITY TO STATIC--------------May be sensitive. DISCHARGE
SECTION 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition, open flames, sparks and heaters. Wear protective gear (See SECTION 8).Large spills must be collected for disposal. Small spills can be wiped. Use a non-combustible absorbent inorganic material. Prevent run-off into drains, sewers and other waterways.
SECTION 07: HANDLING AND STORAGE HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing vapours. Use adequate ventilation. Keep away from heat, sparks and open flame. STORAGE NEEDS----------------------Store away from all sources of heat and ignition. Store in well ventilated area. Keep container closed and out of reach from children and pets when not in use.
MATERIAL SAFETY DATA SHEET PVC/DWV SOLVENT CEMENT
Page : 3
Ref: 000106E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION PROTECTIVE EQUIPMENT:-------------- EYE/TYPE---------------------Safety glasses. RESPIRATORY/TYPE-------------None required for normal use if adequate ventilation is maintained. Use NIOSH/MSHA approved respirator if the TLV is exceeded. GLOVES/ TYPE-----------------Wear impervious gloves (Neoprene or Rubber). CLOTHING/TYPE----------------Not applicable. FOOTWEAR/TYPE----------------Not applicable. OTHER/TYPE-------------------Eye bath and safety shower. VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof) ventilation to keep vapour levels well below the TLV.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE---------------------Liquid. ODOUR------------------------------Ketone odour. SPECIFIC GRAVITY-------------------0.90 - 1.00. ODOUR THRESHOLD (ppm)--------------Not available. VAPOUR PRESSURE--------------------145 mm Hg @ 20ºC. VAPOUR DENSITY (AIR=1)------------- >1.00. EVAPORATION RATE-------------------6.00 (NBUAC = 1). BOILING POINT (deg C)--------------65ºC. pH---------------------------------Not applicable. SOLUBILITY IN WATER (% W/W)--------Negligible. COEFFICIENT OF WATER\OIL-----------Not available. DISTRIBUTION FREEZING POINT--------------------- <0ºC. MELTING POINT (deg C)--------------Not applicable. MOLECULAR WEIGHT-------------------Not applicable.
SECTION 10: STABILITY AND REACTIVITY INCOMPATIBILITY--------------------Strong acids and strong bases. Chlorinated solvents. Oxidizing agents. REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame. HAZARDOUS PRODUCTS OF--------------Carbon Dioxide. Carbon Monoxide. Hydrogen DECOMPOSITION Chloride. Peroxides.
SECTION 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2. IRRITANCY OF MATERIAL--------------Moderate. SENSITIZING CAPABILITY OF----------Not available. MATERIAL CARCINOGENICITY OF MATERIAL--------Reversible liver damage at high dosages is possible. TERATOGENICITY---------------------No information is available and no adverse teratogenicity effects are anticipated. MUTAGENICITY-----------------------No information is available and no adverse mutagenicity effects are anticipated. REPRODUCTIVE EFFECTS---------------Not available. SYNERGISTIC MATERIALS--------------Not available.
MATERIAL SAFETY DATA SHEET PVC/DWV SOLVENT CEMENT
Page : 4
Ref: 000106E Preparation Date : August.31.2011
EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed to enter drinking water intakes. Product has an unaesthetic appearance and can be a nuisance. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds and rivers. BIODEGRADABILITY-------------------Not available. The solvent portion of this product is biodegradable and vaporizes rapidly. VOC INFORMATION--------------------This product emits VOC’s (volatile organic compounds in
use. Always ensure that the use of this product complies with local VOC Emission Regulations, where they exist. The VOC level is 550 grams/litre (SCAQMD Test Method 316A)
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL---------------------Spilled material and water rinses are classified as chemical waste. To be disposed of in accordance with current Local, Provincial and Federal regulations.
SECTION 14: TRANSPORT INFORMATION T.D.G. CLASSIFICATION-------------- (A)--------------------------------(A) In containers up to 5 litres - shipped as CONSUMER COMMODITY. If the shipment exceeds 500 kg in weight, shipped as CONSUMER COMMODITY - ADHESIVES CLASS 3. (B)--------------------------------(B) In containers over 5 litres - ADHESIVES CLASS 3 UN1133 P.G. II.
SECTION 15: REGULATORY INFORMATION CPR COMPLIANCE---------------------This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION---------------Class B Div.2 Flammable Liquid Class D Div.2B Toxic Material.
SECTION 16: OTHER INFORMATION IMPORTANT:-------------------------The information on this Material Safety Data Sheet is furnished without warranty, expressed or implied. All the information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations for the accuracy or sufficiency.
Material Safety Data SheetSn-Pb RMA
1 . Product and company identificationCommon name : Sn-Pb RMA
Product type : Cored wire.
Synonym : FOR ALL ALLOYS (Sn-Pb) RMA
Material uses : Soldering.
Validation date : 3/15/2013.
Contacts : In Canada:AIM9100 Henri Bourassa EastMontreal, QCH1E 2S4(514) 494-2000
In the United States:AIM25 Kenney DriveCranston, RI(800) CALL-AIM
In case of emergency : INFOTRACNorth America: (800) 535-5053International: (352) 323-3500
2 . Hazards identificationPhysical state : Solid.
Odor : Odorless.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Emergency overview : CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCERHAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
Avoid exposure - obtain special instructions before use. Contains material that cancause target organ damage. Contains material which can cause cancer. Risk of cancerdepends on duration and level of exposure.
Potential acute health effects
Eyes : No known significant effects or critical hazards.
Skin : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Medical conditionsaggravated by over-exposure
: Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.
See toxicological information (section 11)
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3 . Composition/information on ingredientsName CAS number %Tin 7440-31-5 1 - 99Lead 7439-92-1 1 - 99Rosin 8050-09-7 1.5 - 3.5
4 . First aid measuresEye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash clothing before reuse. Cleanshoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Get medicalattention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it issuspected that fumes are still present, the rescuer should wear an appropriate mask orself-contained breathing apparatus. It may be dangerous to the person providing aid togive mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with waterbefore removing it, or wear gloves.
5 . Fire-fighting measuresFlammability of the product : May be combustible at high temperature.
Products of combustion : Decomposition products may include the following materials:metal oxide/oxides
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.
No specific fire or explosion hazard.
Special protectiveequipment for fire-fighters
: Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special remarks on firehazards
: Metallic part of product is nonflammable. The core may burn if exposed to direct flame.
Special remarks onexplosion hazards
: No additional remark.
6 . Accidental release measuresPersonal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Provide adequate ventilation.Wear appropriate respirator when ventilation is inadequate. Put on appropriate personalprotective equipment (see Section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).
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6 . Accidental release measuresMethods for cleaning up : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Vacuum or sweep up materialand place in a designated, labeled waste container. Dispose of via a licensed wastedisposal contractor. Note: see section 1 for emergency contact information and section13 for waste disposal.
7 . Handling and storageHandling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Do not get in eyes or on skin or clothing. Do not ingest. If during normal use thematerial presents a respiratory hazard, use only with adequate ventilation or wearappropriate respirator. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Empty containers retainproduct residue and can be hazardous. Do not reuse container.
Storage : Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination.
8 . Exposure controls/personal protectionProduct name Exposure limits
Tin ACGIH TLV (United States, 1/2005).TWA: 2 mg/m³ 8 hour(s). Form: All forms
NIOSH REL (United States, 12/2001). Notes: Note: The REL and PELalso apply to other inorganic tin compounds (as Sn) except tinoxides.
Rosin NIOSH REL (United States, 12/2001). Notes: Note: Carcinogenic inthe presence of formaldehyde, acetaldehyde, or malonaldehyde.See Appendix C (Aldehydes) See Appendix A - NIOSH PotentialOccupational Carcinogen
TWA: 0.1 mg/m³ 10 hour(s). Form: All forms
OSHA PEL 1989 (United States, 3/1989).TWA: 0.1 mg/m³ 8 hour(s). Form: All forms
Consult local authorities for acceptable exposure limits.
Engineering measures : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure toairborne contaminants below any recommended or statutory limits.
Personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.
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8 . Exposure controls/personal protectionSkin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handlingthis product.
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.
9 . Physical and chemical propertiesPhysical state : Solid.
Color : Silver-grey.
Odor : Odorless.
Melting/freezing point : Not available
Vapor pressure : Not available
Evaporation rate : not available
Dispersibility properties : Not dispersible in the following materials: cold water, hot water, methanol, diethyl ether,n-octanol and acetone.
Solubility : Partially soluble in the following materials: methanol.Insoluble in the following materials: cold water, hot water, diethyl ether, n-octanol andacetone.
10 . Stability and reactivityStability and reactivity : The product is stable.
Conditions of instability : Stable in normal conditions. Over melting point, toxic metallic oxides may be evolved.A small amount of organic fumes may also be evolved.
Incompatibility with varioussubstances
: Reactive or incompatible with the following materials: oxidizing materials, metals, acidsand moisture.
Hazardous decompositionproducts
: Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions of reactivity : Combustible in presence of open flames.Non-flammable in presence of shocks, of oxidizing materials, of reducing materials, ofcombustible materials, of organic materials, of metals, of acids, of alkalis, of moisture.
Non-explosive in the presence of the following materials or conditions: open flames,sparks and static discharge, heat and shocks and mechanical impacts.
11 . Toxicological informationChronic effects on humans : CARCINOGENIC EFFECTS: Classified A3 (Proven for animals.) by ACGIH, 2B (
Possible for humans.) by IARC [LEAD]. Classified 2 (Reasonably anticipated to behuman carcinogens.) by NTP [LEAD]. Classified None. by NIOSH [LEAD]. ClassifiedNone. by NIOSH [TIN].Contains material which causes damage to the following organs: blood, kidneys, lungs,the nervous system, the reproductive system, spleen, brain, digestive system,gastrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye,lens or cornea, thyroid.
: Fumes and/or dusts produced by this product may be hazardous in case of ingestion, ofinhalation.This product may be hazardous in case of skin contact (irritant, sensitizer), of eyecontact (irritant).
Special remarks on toxicityto animals
: No additional remark.
Special remarks on chroniceffects on humans
: Human: LEAD crosses the placental barrier.CHRONIC OVEREXPOSURE EFFECTS; Increase of LEAD LEVEL in blood, musclesoreness, metallic taste, abdominal cramps, headaches.
Overexposure to tin oxide fumes may result in benigne pneumoconiosis (stannosis).
(Note: the above statements apply to ingested and/or inhaled particles)
Special remarks on othertoxic effects on humans
: Fumes may irritate eyes, digestive system and respiratory tract.MOLTEN METAL can cause severe BURNS! Inhalation of smoke and fumes, at hightemperatures, may cause an asthmatic reaction in some individuals.
Specific effects
Carcinogenic effects : Contains material which can cause cancer. Risk of cancer depends on duration andlevel of exposure.
Mutagenic effects : No known significant effects or critical hazards.
Teratogenicity /Reproductive toxicity
: No known significant effects or critical hazards.
Sensitization
Ingestion : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Eyes : No known significant effects or critical hazards.
Skin : No known significant effects or critical hazards.
12 . Ecological informationEcotoxicity data
Product/ingredient name Species Period ResultLead Oncorhynchus mykiss (LC50)
Environmental precautions : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
Products of degradation : Some metallic oxides.
Toxicity of the products ofbiodegradation
: The products of degradation are more toxic than the product itself.
13 . Disposal considerationsWaste disposal : The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products viaa licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.
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13 . Disposal considerationsDisposal should be in accordance with applicable regional, national and local laws and regulations. Localregulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based oncharacteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is theresponsibility of the waste generator to determine the toxicity and physical properties of the material generated todetermine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.
14 . Transport informationRegulatoryinformation
UN number Proper shippingname
Class PG* Label Additionalinformation
DOT Classification Not regulated.
- - - -
TDG Classification Not regulated.
- - - -
ADR/RID Class Not available. - - - -
IMDG Class Not regulated.
- - - -
IATA-DGR Class Not regulated.
- - - -
PG* : Packing group
15 . Regulatory informationUnited States
HCS Classification : CarcinogenTarget organ effects
U.S. Federal regulations : TSCA 6 proposed risk management: LEADUnited States inventory (TSCA 8b): Not determined.TSCA 12(b) annual export notification: LEAD
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: TIN; LEAD; rosinSARA 311/312 MSDS distribution - chemical inventory - hazard identification: TIN:Immediate (acute) health hazard; LEAD: Delayed (chronic) health hazard; rosin:Immediate (acute) health hazard, Delayed (chronic) health hazard
Clean Water Act (CWA) 307: LEAD
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 313
Product name CAS number ConcentrationForm R - Reportingrequirements
: LEAD 7439-92-1 57.72 - 59.88
Supplier notification : LEAD 7439-92-1 57.72 - 59.88
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
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15 . Regulatory informationState regulations : Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.Florida substances: None of the components are listed.Illinois Chemical Safety Act: None of the components are listed.Illinois Toxic Substances Disclosure to Employee Act: None of the components arelisted.Louisiana Reporting: None of the components are listed.Louisiana Spill: None of the components are listed.Massachusetts Spill: None of the components are listed.Massachusetts Substances: None of the components are listed.Michigan Critical Material: None of the components are listed.Minnesota Hazardous Substances: None of the components are listed.New Jersey Hazardous Substances: None of the components are listed.New Jersey Spill: None of the components are listed.New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.New York Acutely Hazardous Substances: None of the components are listed.New York Toxic Chemical Release Reporting: None of the components are listed.Pennsylvania RTK Hazardous Substances: None of the components are listed.Rhode Island Hazardous Substances: None of the components are listed.
WARNING: This product contains a chemical known to the State of California to causecancer and birth defects or other reproductive harm.
Ingredient name Cancer Reproductive No significant risklevel
Maximumacceptable dosagelevel
LEAD Yes. Yes. 15 μg/day (ingestion)0.0005 μg/day (inhalation)
Yes.
Canada
WHMIS (Canada) : Class D-2A: Material causing other toxic effects (Very toxic).
CEPA Toxic substances: None of the components are listed.Canadian ARET: None of the components are listed.Canadian NPRI: None of the components are listed.Alberta Designated Substances: None of the components are listed.Ontario Designated Substances: None of the components are listed.Quebec Designated Substances: None of the components are listed.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulationsand the MSDS contains all the information required by the Controlled Products Regulations.
EU regulations
Hazard symbol or symbols :
Risk phrases : R20/22- Harmful by inhalation and if swallowed.R36/38- Irritating to eyes and skin.R42/43- May cause sensitization by inhalation and skin contact.R33- Danger of cumulative effects.R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
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15 . Regulatory informationSafety phrases : S2- Keep out of the reach of children.
S22- Do not breathe dust.S24- Avoid contact with skin.S29- Do not empty into drains.S37- Wear suitable gloves.S45- In case of accident or if you feel unwell, seek medical advice immediately (show thelabel where possible).S61- Avoid release to the environment. Refer to special instructions/safety data sheet.S63- In case of accident by inhalation: remove casualty to fresh air and keep at rest.
International regulations
International lists : Australia inventory (AICS): Not determined.China inventory (IECSC): Not determined.Japan inventory: Not determined.Korea inventory: Not determined.New Zealand Inventory of Chemicals (NZIoC): Not determined.Philippines inventory (PICCS): Not determined.
16 . Other informationLabel requirements : CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER
HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
Hazardous MaterialInformation System (U.S.A.)
: * 2Health
1Fire hazard
0Reactivity
Personal protection
National Fire ProtectionAssociation (U.S.A.)
:Flammability1
2 0Health Instability
Special
References : -ACGIH, Threshold Limit Values, 1994-1995. -Canada Gazette Part II, Vol. 122, No. 2Registration SOR/88-64 31 December, 1987 Hazardous Products Act "IngredientDisclosure List". -CFR29, OSHA's Permissible Exposure Limits, revision July, 1993. -CFR29, part 1910.1200, Hazard Communication. -CHEMTOX database -Components'manufacturer's Material Safety Data Sheet. -CRC Handbook of chemistry and physics,67 th edition, CRC Press inc., Boca Raton, Florida. -CSST (Comission de Santé et Sécurité au Travail), document #RT-12: Classification of Certain Chemical Substances. -IATA, Dangerous Goods Regulations, 37th edition (January 1, 1996) -NFPA, FireProtection Guide to Chemical Hazards, 11th edition. -NIOSH, Pocket Guide to ChemicalHazards, revision June 1994. Sigma-Alrich handbook of fine chemicals, 1998 -TSCA (Toxic Substance Contral Act), Chemical Substance Inventory List, 1985.
Other specialconsiderations
: -ALL INGREDIENTS WITH SUSCEPTIBLE HAZARDS THAT ARE PRESENT IN ACONCENTRATION GREATER THAN 1 % (GREATER THAN 0.1 % FORCARCINOGENS) HAVE BEEN DISCLOSED IN THIS SAFETY DOCUMENT.
Date of printing : 3/15/2013.
: 3/15/2013.Date of issue
Version : 3
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.
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FICHE SIGNALÉTIQUE / MATERIAL SAFETY DATA SHEET Conforme à la loi sur les Produits Dangeureux concernant le Système d'Information sur les Matières Dangereuses Utilisées au Travail (SIMDUT) Complies with the Federal Hazardous Products Act concerning the Workplace Hazardous Material Information System
(WHMIS)
SECTION 1 - RENSEIGNEMENTS SUR LE PRODUIT / PRODUCT IDENTI FICATION
SECTION 3 - INGREDIENTS DANGEREUX / HAZARDOUS INGREDIENTS INGREDIENT Note: Les ingrédients cités ci-dessous sont un secret commercial. Ces informations sont pour référence seulement et ne peuvent pas être transférées sans le consentement écrit de SODEL LTÉE Note: The ingredients listed below are classified as trade secret. This information is for reference only and under no circumstance be transferred without prior written approval from SODEL LTD. .
GAMMES DE CONCENTRATION
/ RANGES OF
CONCENTRATION
NUMERO
D'ENREGISREMENT
CAS ** / NUMÉRO
D'ENREGISTREMENT CAS **
LIMITE
D'EXPOSITION /
EXPOSURE LIMIT
(mg/m3)
ACGIH TLV***/
CAHIG SEA***
1993/94
Chrome / Chromium Nickel Manganèse / Manganese
10 – 30 7 – 13 1 – 5
7440-47-3 7440-02-0 7439-96-5
0,5 1 5
* Les concentrations des ingrédients (en % du poids) sont présentées tel que proposé par le Règlement sur les Produits Contrôlés de la
Loi sur les Produits Dangereux. ** Le numéro d'enregistrement CAS est un numéro d'identification attribué à une substance chimique par la Chemical Abstracts Service
Division de l'American Chemical Society. *** Les Seuils d'Exposition Admissible (SEA) sont publiés par la "American Conference of Governmental Industrial Hygienists" (ACGIH).
La limite normale recommandée par la ACGIH pour les fumées provenant des procédés de soudage (non autrement classifiée) est de 5 mg/m
3. La ACGIH 1993-94 stipule que les Seuils d'Exposition Admissibles (SEA) devraient être considérés comme des guides pour
le contrôle des conditions potentiellement dangereuses pour la santé et ne devraient pas être considérés comme des lignes de démarcation entre les concentrations sûres et les concentration dangereuses.
* The concentrations of the ingredients (in weight %) are indicated as proposed by the Controlled Products Regulations of the Hazardous Product Act. ** The CAS registry number is an identification number assigned to a chemical substance by the Chemical Abstracts Service Division of
the American Chemical Society. *** The Threshold Limit Values (TLV) are published by the American Conference of Governmental Industrial Hygienists (ACGIH). The
recommended general limit for welding fumes (not otherwise classified) is 5 mg/m3. The ACGIH 1993-94 states that the Threshold
Limit Values (TLV) should be used as guides in the control of potential health hazards and should not be used as fine lines between safe and dangerous concentrations.
SECTION 4 - CARACTÉRISTIQUE PHYSIQUES ET CHIMIQUES ÉTAT PHYSIQUE: Solide APPARENCE :Métallique ODEUR: Inodore SECTION 5 - RISQUES D'INCENDIE ET D'EXPLOSION Les baguettes et électrodes de soudure, telles qu'expédiés, sont ininflammables, non-explosives et essentiellement inertes. SECTION 6 - RÉACTIVITÉ PRODUITS DE DÉCOMPOSITION DANGEREUX Les fumées et les gaz de soudage ne peuvent pas être classifiés facilement. Leurs compositions ainsi que leurs quantités dépendent en partie du métal soudé, du procédé, des procédures ainsi que des électrodes utilisées. FUMÉES: Les éléments constituants des émanations de fumées incluent généralement les éléments et l'ensemble des oxydes et/ou fluorures de: Chrome (Cr), Fer (Fe), Manganèse (Mn) and Nickel (Ni). GAZ: Les principales émissions sont le monoxyde de carbone et le dioxyde de carbone (CO et CO2). La présence d'autres gaz est normalement faible. Si les symptômes en indique le besoin, vérifier pour l'ozone (O3) et pour les oxydes d'azote (NOx) et/ou les fluorures (F
-). L'utilisation de l'argon (Ar)
comme gaz de protection peut produire plus d'ozone (O3) et d'oxydes d'azote (NOx) que lors que le dioxyde de carbone (CO2) gazeux augmente l'émission de fumées. En plus de l'ozone (O3) et des oxydes d'azote (NOx), la chaleur et le rayonnement générés par le procédé de soudage peut provoquer une modification chimique dangereuse des substances qui peuvent être introduites dans l'environnement du soudage: le phosgène (COCl2) et le chlorure d'hydrogène (HCl) sont des gaz très toxiques qui peuvent se former par la décomposition des vapeurs d'hydrocarbures chlorés (solvants utilisés pour dégraisser) lorsqu'elles sont mises en présence du rayonnement ultraviolet de l'arc de soudage. Pour les métaux d'apport en acier doux et plusieurs faiblement alliés, les limites acceptables pour les fumées totales (ACGIH TLV-TWA de 5 mg/m
3)
seront excédées avant celles des éléments individuels. Ce n'est pas le cas pour les métaux d'apport en acier inoxydable et autres hautement alliés et les non-ferreux. SECTION 7 - PROPRIÉTÉS TOXICOLOGIQUES /DONNÉES SUR LES DANGERS POUR LA SANTÉ PREMIÈRE VOIE D'ABSORPTION: Voies respiratoires. EFFETS POTENTIELS SUR LA SANTÉ RÉSULTANT DE SUREXPOSITIONS EXCESSIVES: l'aggravation de problèmes respiratoires ou allergiques pré- existants peut survenir chez certains travailleurs. LES FUMÉES ET LES GAZ PEUVENT ÊTRE DANGEREUX POUR VOTRE SANTÉ LA SUREXPOSITION A COURT TERME (AIGUE) à des fumées de soudage (ACGIH 1993-94 TLV-TWA de 5 mg/m
3) peut occasionner des
malaises tels que l'irritation de la peau, des yeux et des voies respiratoires, la toux, la fièvre, des frissons, des maux de tête, des vomissements, des difficultés respiratoires et une pneumonite chimique. LA SUREXPOSITION A LONG TERME (CHRONIQUE) peut occasionner l'irritation et la corrosion des voies respiratoires, de la sensibilisation pulmonaire et cutanée, des tremblements, la faiblesse musculaire et une affectation du système nerveux central. CANCÉROGÉNICITÉ Les composés du chrome (VI) et du nickel sont reconnus comme étant cancérogènes par le Centre International de Recherche sur le Cancer et l'ACGIH, principalement pour les poumons et les voies respiratoires.
SECTION 8 - PREMIERS SOINS ET TRAITEMENTS D'URGENCE INHALATION - SUREXPOSITION: Déplacer la victime dans un endroit bien ventilé. Appeler pour de l'aide médicale (médecin). Utiliser les techniques de premiers soins recommandées par la Croix Rouge ou l'Ambulance Saint-Jean. Donner la respiration artificielle ou de l'oxygène si nécessaire. CONTACT AVEC LA PEAU: Laver minutieusement avec de l'eau savonneuse les mains et autres parties affectées pour enlever tous les résidus. S'il y a des rougeurs ou des brûlures, consulter un médecin. CONTACT AVEC LES YEUX: Rincer abondamment les yeux avec de l'eau claire pendant 15 minutes pour enlever tous les résidus. Demander rapidement l'avis d'un médecin. INGESTION: Appeler un médecin et/ou le Centre Anti-Poison le plus près. Donner les ingrédients listés à la Section 3. SECTION 9 - MESURES PRÉVENTIVES PRÉCAUTIONS POUR L'UTILISATION ET LA MANUTENTION SÉCURITAIRES / MESURES DE CONTRÔLE APPLICABLES Lire et comprendre les instructions du fabricant ainsi que l'étiquette de précautions sur le produit. (Voir ACNOR W117.2 "Règles de sécurité en soudage, coupages et procédés" publié par l'Association Canadienne de Normalisation pour des informations complémentaires). PROTECTION RESPIRATOIRE - Utiliser un respirateur approuvé par l'ACNOR si vous travaillez dans un endroit restreint ou lorsque la ventilation ne peut maintenir les expositions sous le seuil d'exposition admissible. (Se référer à ACNOR Z94.4 "Choix, entretien et utilisation des respirateurs"). VENTILATION - Utiliser une ventilation générale suffisante et une élimination à la source de l'arc pour enlever les gaz et les fumées dans la zone de respiration du travailleur et de son environnement. Enseigner aux travailleurs à garder la tête hors des fumées et des gaz de soudage. PROTECTION DES YEUX - Porter un casque de soudeur ou utiliser une visière avec verre filtreur. Fournir des écrans protecteurs ainsi que des lunettes protectrices si nécessaire, pour protéger les autres travailleurs. Il est d'usage de débuter avec un verre au degré de filtration très élevé pour voir la zone de soudage. Puis réduire l'indice du degré de filtration, vous permettant à la fois une bonne protection et une bonne vision de la zone de soudage. AUTRES ÉQUIPEMENTS PROTECTEURS - Afin d'éviter toutes blessures provenant du rayonnement, d'étincelles ou des flammes, il est recommandé de porter des vêtements de protection pour les mains, la tête et le corps (Voir ACNOR W117.2). Une protection minimale inclus le port de gants, un écran protecteur, un masque de soudeur et peut également inclure des protecteurs pour les bras, un tablier, un casque, un protecteur pour les épaules ainsi que le port d'un vêtement solide et de couleur foncée. Enseigner aux travailleurs à ne pas toucher aux accessoires électriques sous tension et à s'isoler électriquement de la pièce à souder et de la mise à terre. Des protections additionnelles peuvent être nécessaires pour prévenir le contact avec la peau et les yeux des décapants et aides chimiques. PROCÉDURE DE NETTOYAGE - DÉVERSEMENTS OU FUITES - Ne s'applique pas en général. MÉTHODE D'ÉLIMINATION DES DÉCHETS - Se débarrasser des déchets industriels de manière à protéger l'environnement. Se débarrasser de tous produits, résidus, contenants jetable ou sacs de déchets de façon à protéger l'environnement tout en respectant les lois municipales et gouvernementales.
SECTION 4 - PHYSICAL/CHEMICAL CHARACTERISTICS PHYSICAL STATE: Solid APPEARANCE: Metallic ODOUR: Odourless SECTION 5 - FIRE AND EXPLOSION HAZARD DATA Welding rods and electrodes, as shipped, are non-flammable, non-explosive and essentially non-reactive. SECTION 6 - REACTIVITY DATA HAZARDOUS DECOMPOSITION PRODUCTS Welding fumes and gases can not be classified simply. The composition and quantity of both are dependent upon the alloy being welded and the process and welding product used. FUMES: Reasonably expected constituents of the fumes would include elemental elements and oxides and/or fluorides combinations of: Chromium (Cr), Iron (Fe), Manganese (Mn) and Nickel (Ni). GASES: The main gaseous emissions are carbon monoxide and carbon dioxide (CO and CO2). The presence of other gases is normally low. If any symptoms indicate the need, check for ozone (O3) and for oxides of nitrogen (NOx) and/or fluorides (F
-). Use of argon (Ar) as shielding gases
may produce more ozone (O3) and nitrogen oxides (NOx) than when carbon dioxide (CO2) gas is used. Carbon dioxide (CO2) gases, however, will enhance fume emission. Besides ozone and nitrogen oxides the heat and radiation generated by the welding processes can cause hazardous chemical changes to those substances that may be introduced into the welding environment: Phosgene (COCl2 ) and hydrogen chloride (HCl) are highly toxic gases that can form from the decomposition of chlorinated hydrocarbon vapours (degreasing solvents) in the presence of ultraviolet radiation from the welding arc. With mild steel and many low alloy consumables, the acceptable limit for total fumes (ACGIH TLV-TWA of 5 mg/m
3) will be exceeded before those
for individual elements. This is not the case for stainless steel and other high alloy and nonferrous consumables. SECTION 7 - TOXICOLOGICAL PROPERTIES / HEALTH HAZARD INFORMATION PRIMARY ROUTES OF ENTRY: Respiratory tract. POTENTIAL HEALTH EFFECTS RESULTING FROM EXCESSIVE OVEREXPOSURE: aggravation of pre-existing respiratory or allergic conditions may occur in some workers. FUMES AND GASES CAN BE DANGEROUS TO YOUR HEALTH SHORT TERM (ACUTE) OVEREXPOSURE to welding fumes (ACGIH 1993-94 TLV-TWA of 5 mg/m
3) may lead to the irritation of the skin, eyes
and respiratory tract, coughing, fever, shivers, headaches, vomiting, breathing difficulties and a chemical pneumonitis. LONG TERM (CHRONIC) OVEREXPOSURE may lead to the irritation and corrosion of the respiratory tract, sensitization of the pulmonary and cutaneous systems, tremors, muscular weakness and problems to the central nervous system. CARCINOGENICITY The chrome (VI) and nickel composites are considered by the International Agency for Research on Cancer and by the ACGIH to be known or probable human carcinogens especially to the lungs and respiratory tract.
SECTION 8 - EMERGENCY AND FIRST AID MEASURES INHALATION OVEREXPOSURE: Move victim to a well ventilated area. Call for medical aid (physician). Employ first-aid techniques recommended by Red Cross or St-John's Ambulance. Apply artificial respiration/oxygen if necessary. SKIN CONTACT: Thoroughly wash hands or affected areas with soap and water to remove all residue. If rash or burn, consult physician. EYE CONTACT: Thoroughly flush eyes with water for at least 15 minutes to remove all residue. Obtain prompt medical advise. INGESTION: Call a physician and/or local Poison Control Centre. Advise of ingredients listed in Section 3. SECTION 9 - PREVENTIVE MEASURES PRECAUTIONS FOR SAFE HANDLING, USE AND APPLICABLE CONTROL MEASURES Read and understand the manufacturer's instructions and the precautionary label on the product. (See CSA W117.2 "Code for Safety in Welding and Cutting" published by Canadian Standards Association). RESPIRATORY PROTECTION - Use a CSA approved respirator when working in confined space or where local exhaust or ventilation does not keep exposure below the recommended exposure limit. (Refer to CSA Z94.4 "Selection, Care and Use of Respirators"). VENTILATION - Use enough general ventilation and local exhaust at the work site to keep the fumes, gases and dusts from the worker's breathing zone and the general area. Train the worker to keep his head out of the fumes. EYE PROTECTION - Wear helmet or use face shield with filter lens. Provide protection screens and flash goggles, if necessary, to shield others. As a rule, start with a shade that is too dark to see the work zone. Then go to the next lighter shade which gives sufficient view of the weld zone. OTHER PROTECTIVE EQUIPMENT - Wear hand, head and body protection which helps to prevent injury from radiation, sparks and flames. (See CSA W117.2.) At a minimum, this includes gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the worker not to touch live electrical parts and to insulate himself from work and ground. Additional protection for fluxes and chemicals aids may be required to prevent skin or eye contact. PROCEDURE FOR CLEAN-UP OF SPILLS - Generally not applicable. WASTE DISPOSAL METHOD - Prevent waste from contaminating surrounding environment. Discard any product, residue, disposable container or liner in an environmentally acceptable manner in full compliance with federal provincial and local regulations.
STANLEY CHALKS MSDS PAGE 1 OF 8
MATERIAL SAFETY DATA SHEET Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards and European Union Standards
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): STANLEY CHALKS SYNONYMS: Stanley Black Chalk; Stanley Blue Chalk Stanley Red Chalk; Stanley White Chalk CHEMICAL NAME/CLASS: Calcium Carbonate/Pigment/Silica Mixtures PRODUCT USE: Chalks MANUFACTURER'S NAME: STANLEY WORKS ADDRESS: 480 Myrtle Street New Britain, CT 06053 BUSINESS PHONE: 1-800-262-2161
SUPPLIER/IMPORTER'S NAME (Europe): ADDRESS: EMERGENCY PHONE: BUSINESS PHONE:
EMERGENCY PHONE: 800-424-9300 (CHEMTREC) U.S., Canada, Puerto Rico. U.S. Virgin Islands 01-703-527-3887 (outside areas above, call collect) DATE OF PREPARATION: December 11, 2007 DATE OF REVISION: July 29, 2010 NOTE: This product has been classified in accordance with the hazard criteria of the CPR. All WHMIS (Controlled Products Regulations), European Union [Regulation (EC) 1907/2006 Annex II] required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.
2. HAZARD IDENTIFICATION EU LABELING/CLASSIFICATION: These products do not meet the definition of any hazard class, as defined by European Union Council Directives.
EU CLASSIFICATION: Not applicable. EU RISK PHRASES: Not applicable.
See Section 16 for full text of Ingredient Risk and Safety Phrases
EMERGENCY OVERVIEW: Product Description: These products are colored, finely powdered, odorless chalks. Health Hazards: Inhalation of dusts from this product may irritate the respiratory system. Skin and eye contact may cause mechanical abrasion. These chalks contain Crystalline Silica, a known human carcinogen by inhalation. Flammability Hazards: These chalks are not flammable. Finely divided dusts from these products can form explosive mixtures in air. If involved in a fire, these products may decompose to form iron oxides, aluminum oxides, silicon dioxide, sulfur dioxide, magnesium oxides, carbon oxides and calcium oxides. Reactivity Hazards: These chalks are not reactive. Environmental Hazards: These products are not expected to pose significant harm to the environment, however all release to the environment should be avoided. Emergency Recommendations: Emergency responders must wear the personal protective equipment suitable for the situation to which they are responding.
3. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # EINECS # % w/w EU CLASSIFICATION FOR COMPONENTS
Limestone/Calcium Carbonate (CaCO3) 1317-65-3 215-279-6 70-100% Hazard Classification: Not Applicable Risk Phrases: Not Applicable / Safety Phrases: Not Applicable
Blue Chalk: Sodium Alumino Sulphosilicate/C.I. Pigment Blue 29
57455-37-5 Unlisted 20-30% Hazard Classification: Not Applicable Risk Phrases: Not Applicable / Safety Phrases: Not Applicable
Black Chalk: Carbon Black 1333-86-4 215-609-9 17-23% Hazard Classification: Not Applicable Risk Phrases: Not Applicable / Safety Phrases: Not Applicable
Red Chalk: Hematite/Iron Oxide (Fe2O3) 1317-60-8 215-275-4 20-30%^ Hazard Classification: Not Applicable Risk Phrases: Not Applicable / Safety Phrases: Not Applicable
White Chalk: Magnesium Carbonate (MgCo3)
546-93-0 208-915-6 0-2% Hazard Classification: Not Applicable Risk Phrases: Not Applicable / Safety Phrases: Not Applicable
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES Contaminated individuals must be taken for medical attention if any adverse effects occur. Rescuers should be taken for medical attention if necessary. Take a copy of label and MSDS to health professional with the contaminated individual.
STANLEY CHALKS MSDS
STANLEY CHALKS MSDS PAGE 2 OF 10
4. FIRST-AID MEASURES (Continued) SKIN EXPOSURE: If the product contaminates the skin, immediately begin decontamination with copious amounts of running water. Minimum flushing is for 20 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The contaminated individual must seek immediate medical attention if any adverse health effect continues after flushing. EYE EXPOSURE: If the product enters the eyes, open the contaminated individual's eyes while under gently running water. Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. Minimum flushing is for 20 minutes. Contact medial personnel if adverse effect persists after flushing. INHALATION: If dusts or particulates are inhaled, remove the contaminated individual to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers. The contaminated individual should seek immediate medical attention if any adverse effects occur. INGESTION: If product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Have victim rinse mouth with water or drink several cupfuls of water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting respiratory problems, dermatitis, and other skin disorders may be aggravated by exposure to this product. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.
5. FIRE-FIGHTING MEASURES FLASH POINT: Not applicable. AUTOIGNITION TEMPERATURE: Not applicable. FLAMMABLE LIMITS (in air by volume, %): Not applicable. FIRE EXTINGUISHING MATERIALS:
Water Spray: YES Carbon Dioxide: YES Foam: YES Dry Chemical: YES Halon: YES Other: Any "ABC" Class.
FIRE EXTINGUISHING MATERIALS NOT TO BE USED: None known. UNUSUAL FIRE AND EXPLOSION HAZARDS: Finely divided dusts from these products can form explosive mixtures in air. If involved in a fire, these products may decompose to form iron oxides, aluminum oxides, silicon dioxide, sulfur dioxide, magnesium oxides, carbon oxides and calcium oxides.
Explosion Sensitivity to Mechanical Impact: Not sensitive. Explosion Sensitivity to Static Discharge: Finely divided dusts from this material
pose a hazard of an air/dust explosion in presence of an ignition source.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move containers from fire area if it can be done without risk to personnel. Water fog or spray can also be used to cool fire-exposed containers. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. Rinse contaminated equipment thoroughly before returning such equipment to service.
6. ACCIDENTAL RELEASE MEASURES RELEASE RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Eliminate all sources of ignition before clean-up begins. Use non-sparking tools. The atmosphere must have levels of the components of this product lower than those listed in Section 8, (Exposure Limits and Personal Protection) and at least 19.5 percent oxygen before personnel can be allowed into the area without Self-Contained Breathing Apparatus (SCBA).
Small Spills: Wipe up spilled solid with damp sponge or sweep up spilled material or vacuum with explosion-proof vacuum, avoiding generation of dusts, wearing gloves, goggles and apron. Place spilled material in appropriate container for disposal, sealing tightly. Clean spill area with soap and water.
Large Spills: Trained personnel using pre-planned procedures should respond to uncontrolled releases. Proper protective equipment should be used. In case of a spill, clear the affected area, protect people, and respond with trained personnel. Minimum Personal Protective Equipment should be the following: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus. Monitor the surrounding area for oxygen levels. The atmosphere must have at least 19.5 % oxygen before personnel can be allowed in the area without Self-Contained Breathing Apparatus. Access to the spill area should be restricted. Spread should be limited by gently covering the spill with damp cloths or towels. Sweep up or vacuum spilled solid (an explosion-proof vacuum should be used), avoiding the generation of airborne dusts. The dispersal of particles into surrounding air must be avoided. Decontaminate the area thoroughly. All contaminated absorbents and other materials should be placed in an appropriate container and sealed.
Place all spill residue in a double plastic bag or other containment and seal. Decontaminate the area thoroughly. Do not mix with wastes from other materials. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). For spills on water, contain, minimize dispersion and collect. Dispose of recovered material and report spill per regulatory requirements.
1 HEALTH
FLAMMABILITY
INSTABILITY
OTHER
NFPA RATING
0
1
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
3 = Serious 4 = Severe
STANLEY CHALKS MSDS
STANLEY CHALKS MSDS PAGE 3 OF 10
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breathing airborne dusts generated by this product. Use in a well-ventilated location. Ensure this substance is used with adequate ventilation and personal protective equipment (see Section 8, Exposure Controls and Personal Protection). Avoid airborne dusts generated by this product. Clean work areas routinely to prevent accumulation of dust. Clean up spills promptly. STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Open containers slowly on a stable surface. Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Have appropriate extinguishing equipment in the storage area (e.g., sprinkler system, portable fire extinguishers). Keep container tightly closed when not in use. Refer to NFPA 654, Prevention of Fire and Dust Explosions from the Manufacturing, Processing and Handling of Combustible Particulate Solids for additional information on storage. SPECIFIC USE(S): These products are used in chalk line devices in construction. Follow all industry standards for use of this product. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely. Always use this product in areas where adequate ventilation is provided. Decontaminate equipment thoroughly, before maintenance begins. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures, or applicable federal, state, provincial and local standards.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section if applicable. Ensure eyewash/safety shower stations are available near areas where this product is used. EXPOSURE LIMITS/GUIDELINES:
CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR
ACGIH-TLVs OSHA-PELs NIOSH-RELs NIOSH OTHER
TWA STEL TWA STEL TWA STEL IDLH
mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3
Calcium Carbonate 1317-65-3 NE NE 15 (total dust); 5 (resp. fract.)
NE 10 (total dust); 5 (resp. fract.)
NE NE NE
Carbon Black 1333-86-4 3.5
NIC = 3 (inhal. fraction)
NE 3.5 NE 3.5 (0.1 in presence of
PAHs, as PAHs; 10-hr TWA)
NE 1750 DFG MAK: as Inhalable Dust Carcinogen: IARC-2B, MAK-
3B, NIOSH-Ca, TLV-A4; NIC = TLV-A3
C.I. Pigment Blue 29 57455-37-5 NE NE NE NE NE NE NE NE
Iron Oxide/Hematite 1317-60-8 NE NE NE NE NE NE NE Carcinogen: IARC-3
Magnesium Carbonate (talc, containing no asbestos fibers)
14807-96-6 2 (resp. fraction)
NE 20 mppcf (containing < 1% quartz)
NE 2 (respirable dust) NE NE Carcinogen: IARC-3, MAK-3B, TLV-A4 (respirable)
NE = Not Established. NIC = Notice of Intended Change See Section 16 for Definitions of Terms Used.
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: Currently, the following international exposure limits are established for some components of this product. CALCIUM CARBONATE: Belgium: TWA = 10 mg/m3, MAR 2002 Hungary: TWA = 10 mg/m3, SEP 2000 Japan: OEL = 1 mg/m3 (respirable), 4 mg/m3 (total), APR
2007 Korea: TWA = 10 mg/m3, 2006 Mexico: TWA = 10 mg/m3; STEL 20 mg/m3 (inhalable),
2004 The Netherlands: MAC-TGG = 10 mg/m3, 2003 New Zealand: TWA = 10 mg/m3 (inspirable dust), JAN 2002 Poland: MAC(TWA) dust = 10 mg/m3, JAN 1999 Russia: STEL = 6 mg/m3, JUN 2003 Switzerland: MAK-W = 3 mg/m3, DEC 2006 United Kingdom: TWA = 10 mg/m3 (inhalable), 2005 United Kingdom: TWA = 4 mg/m3 (respirable), 2005 In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV
CARBON BLACK: Australia: TWA = 3 mg/m3, JUL 2008 Belgium: TWA = 3.6 mg/m3, MAR 2002 Denmark: TWA = 3.5 mg/m3, OCT 2002 Finland: TWA = 3.5 mg/m3, STEL = 7 mg/m3, SEP 2009 France: VME = 3.5 mg/m3, FEB 2006 Japan: OEL = 1 mg/m3 (respirable), 4 mg/m3 (total), APR
2007 Korea: TWA = 3.5 mg/m3, 2006 Mexico: TWA = 3.5 mg/m3; STEL = 7 mg/m3, 2004 The Netherlands: MAC-TGG = 3.5 mg/m3, 2003 New Zealand: TWA = 3 mg/m3, JAN 2002 Norway: TWA = 3.5 mg/m3, JAN 1999 The Philippines: TWA = 3.5 mg/m3, JAN 1993 Russia: STEL = 4 mg/m3, JUN 2003 Sweden: TWA = 3 mg/m3, JUN 2005 United Kingdom: TWA = 3.5 mg/m3; STEL = 7 mg/m3, 2005
CARBON BLACK (continued): In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV CRYSTALLINE SILICA: Australia: TWA = 0.1 mg/m3, JUL 2008 Belgium: TWA = 0.1 mg/m3 (resp. dust), MAR 2002 Denmark: TWA = 0.1 mg/m3 (respirable), OCT 2002 Denmark: TWA = 0.3 mg/m3 (total), OCT 2002 Finland: TWA = 0.05 mg/m3, resp. dust, SEP 2009 France: VME = 0.1 mg/m3, (resp), FEB 2006 Japan: OEL-C = 0.03 mg/m3 (respirable), APR 2007 Korea: TWA = 0.1 mg/m3, 2006 Mexico: TWA = 0.1 mg/m3 (respirable), 2004 The Netherlands: MAC-TGG = 0.075 mg/m3, 2003 New Zealand: TWA = 0.2 mg/m3 (respirable dust), JAN
2002 Norway: TWA = 0.1 mg/m3 (resp. dust), JAN 1999
STANLEY CHALKS MSDS
STANLEY CHALKS MSDS PAGE 4 OF 10
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued) INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS (continued): CRYSTALLINE SILICA (continued): Norway: TWA = 0.3 mg/m3 (total dust), JAN 1999 Russia: TWA = 1 mg/m3, STEL = 3 mg/m3, JUN 2003 Sweden: TWA = 0.1 mg/m3 (resp. dust), JUN 2005 Switzerland: MAK-W = 0.15 mg/m3, DEC 2006 Thailand: TWA = 10 mg/m3 (resp. dust), JAN 1993 Thailand: TWA = 30 mg/m3 (total dust), JAN 1993 United Kingdom: TWA = 0.3 mg/m3 (respirable), 2005 In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV
IRON OXIDE: Russia: STEL = 4 mg/m3, JUN 2003 MAGNESIUM CARBONATE (TALC): Australia: TWA = 2.5 mg/m3, JUL 2008 Belgium: TWA = 2 mg/m3, MAR 2002 Finland: TWA = 0.5 f/cc, fibrous, SEP 2009 Finland: TWA = 5 mg/m3, granulated, SEP 2009 Japan: OEL = 0.5 mg/m3 (respirable), 2 mg/m3 (total), APR
2007 Korea: TWA = 2 mg/m3, 2006
MAGNESIUM CARBONATE (TALC): Mexico: TWA = 2 mg/m3 (respirable), 2004 The Netherlands: MAC-TGG = 1 mg/m3, 2003 New Zealand: TWA = 2 mg/m3 (respirable dust), JAN 2002 Sweden: TWA = 2 mg/cm3 (total dust); TWA = 1 mg/cm3
(resp. dust), JUN 2005 Switzerland: MAK-W = 2 mg/m3, DEC 2006 United Kingdom: TWA = 1 mg/m3 (respirable), 2005 In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132), equivalent standards of Canada (including CSA Standard Z94.4-02 and CSA Standard Z94.3-02), standards of EU member states (including EN 529:2005 for respiratory PPE, CEN/TR 15419:2006 for hand protection, and CR 13464:1999 for face/eye protection). Please reference applicable regulations and standards for relevant details.
RESPIRATORY PROTECTION: None needed under normal conditions of use and handling. Maintain airborne contaminant concentrations below exposure limits listed above if applicable. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian CSA Standard Z94.3-02, or the European Standard CR 13464:1999. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998). The following are NIOSH Respiratory Protection Equipment Guidelines for some components of these products:
CARBON BLACK CONCENTRATION RESPIRATORY PROTECTION Up to 17.5 mg/m3: Any Dust and Mist Respirator. Up to 35 mg/m3: Any Dust and Mist Respirator except single-use and quarter-mask respirators, or any Supplied-Air Respirator (SAR). Up to 87.5 mg/m3: Any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator (PAPR) with a dust and mist
filter. Up to 175 mg/m3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any PAPR with a tight-fitting
facepiece and a high-efficiency particulate filter, or any Self-Contained Breathing Apparatus (SCBA) with a full facepiece, or any SAR with a full facepiece.
Up to 1750 mg/m3: Any SAR operated in a pressure-demand or other positive-pressure mode. Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and is operated in a pressure-
demand or other positive-pressure mode, or any SAR that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any appropriate escape-type, SCBA.
In Presence of Polycyclicaromatic Hydrocarbons: Based on NIOSH REL at Concentrations Above the NIOSH REL, or Where There is No REL, at Any Detectable Concentration: Any SCBA that has a
full facepiece and is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any appropriate escape-type, SCBA.
CRYSTALLINE SILICA CONCENTRATION RESPIRATORY PROTECTION Up to 0.5 mg/m
3: Any Air-Purifying Respirator with a high-efficiency particulate filter.
Up to 1.25 mg/m3: Any Powered, Air-Purifying Respirator (PAPR) with a high-efficiency particulate filter, or any Supplied-Air Respirator
(SAR) operated in a continuous-flow mode. Up to 2.5 mg/m
3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any PAPR with a tight-fitting
facepiece and a high-efficiency particulate filter. Up to 25 mg/m
3: Any SAR operated in a pressure-demand or other positive-pressure mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any appropriate escape-type, SCBA.
EYE PROTECTION: None needed under normal use and handling. Wear safety goggles if dusts or other particulates are present. If necessary refer to U.S. OSHA 29 CFR 1910.133, Canadian CSA Standard Z94.3-02, or the European Standard CR 13464:1999. HAND PROTECTION: None needed under normal conditions of use and handling. Wear appropriate glove for work being done. Resistance of specific materials can vary from product to product. Evaluate resistance under conditions of use and maintain gloves carefully. Use triple gloves for spill response, as stated in Section 6 (Accidental Release Measures) of this MSDS. If necessary, refer to U.S. OSHA 29 CFR 1910.138, appropriate Standards of Canada and the European Standard CEN/TR 15419:2006. BODY PROTECTION: Use body protection appropriate for task. Full-body chemical protective clothing is recommended for emergency response procedures. If necessary, refer to the OSHA Technical Manual (Section VII: Personal Protective Equipment) appropriate Standards of Canada, or the European Standard CEN/TR 15419:2006. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136 and the Canadian CSA Standard Z195-02, Protective Footwear.
STANLEY CHALKS MSDS
STANLEY CHALKS MSDS PAGE 5 OF 10
9. PHYSICAL and CHEMICAL PROPERTIES SOLUBILITY IN ORGANIC SOLVENTS: Not known. SOLUBILITY IN WATER: Black and Blue Chalks: Insoluble. Red Chalk: 0.1%; White Chalk: Insoluble. RELATIVE VAPOR DENSITY (air = 1): Not established. EVAPORATION RATE (n-BuAc = 1): Not established. MELTING/FREEZING POINT: Not established. BOILING POINT: Not established. VAPOR PRESSURE: Not established. pH: Not available. ODOR THRESHOLD: Not applicable. DECOMPOSITION TEMPERATURE: 120°C (248°F) SPECIFIC GRAVITY (water = 1): Black Chalk: 2.49-2.52; Blue Chalk: 2.60-2.62; Red Chalk: 3.1-3.3; White Chalk: 2.71
APPEARANCE, ODOR AND COLOR: These products are colored (black, red, white or blue), finely divided, odorless powdered solids. HOW TO DETECT THIS SUBSTANCE IN EVENT OF ACCIDENTAL SPILL (warning properties): The color of these products may be a method to identify them in event of an accidental spill.
10. STABILITY and REACTIVITY STABILITY: Normally stable. DECOMPOSITION PRODUCTS: Thermal: Thermal decomposition of this product can produce iron oxides, aluminum oxides, silicon dioxide, sulfur dioxide, magnesium oxides, carbon oxides and calcium oxides. The Blue Chalk may release hydrogen sulfide in contact with acids. Hydrolysis: None known. MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Calcium carbonate ignites on contact with fluorine. It is incompatible with acids, aluminum, and ammonium salts and mercury/hydrogen mixtures. Due to other components, these products may also be incompatible with formaldehyde, strong oxidizing agents, hydrofluoric acid, manganese trifluoride, sodium, and xenon hexafluoride. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid exposure to or contact with light, extreme temperatures, and incompatible chemicals.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of industrial exposure to this product are by skin or eye contact and inhalation. INHALATION: If dusts or particulates from these products are inhaled, irritation of the nose, throat, and lungs can occur. Symptoms may include sneezing, coughing, nasal congestion, and difficulty breathing. Symptoms are generally alleviated upon exposure to fresh air. If heated, chronic exposure to concentrations of silicon dioxide fume may cause chronic obstructive lung disease. Inhalation of iron oxide fume or dust is cause of pulmonary roentgenographic appearance called siderosis, or an accumulation of iron that leads to reduced lung capacity. These products contain Crystalline Silica, which is a known human carcinogen. Chronic inhalation exposure to this material may cause silicosis, pulmonary fibrosis, bronchitis or present a hazard of cancer, due to the presence of Crystalline Silica. CONTACT WITH SKIN or EYES: Skin contact may cause abrasion, redness, and discomfort. Prolonged or repeated skin overexposure may cause dermatitis (dry, red skin). Direct eye contact with these products may cause stinging, tearing, and redness. Dust can cause mechanical irritation to the eye. Repeated contact of iron dusts with the eyes can cause conjunctivitis, or can cause discoloration of the eyes. SKIN ABSORPTION: This product does not pose a hazard of skin absorption. INGESTION: Ingestion is an unlikely route of occupational exposure to this product. In the unlikely event that dusts from the product are ingested nausea, vomiting, and diarrhea may result. Repeated ingestion of iron compounds can cause vomiting, diarrhea, pink urine, black stool, and liver or kidney damage. Repeated ingestion of iron compounds can also cause siderosis, which is an accumulation of iron in tissues. INJECTION: These products do not pose a hazard of injection. HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. In the event of overexposure, the following symptoms may be observed: ACUTE: Acute exposure to the skin and eyes can cause mechanical irritation. Inhalation of dusts can cause pulmonary irritation. CHRONIC: Repeated inhalation exposure may cause adverse effects to the respiratory system. Chronic inhalation may result in pulmonary fibrosis. This product contains crystalline silica, which is a known human carcinogen.
HEALTH HAZARD
FLAMMABILITY HAZARD
PHYSICAL HAZARD
PROTECTIVE EQUIPMENT
1
EYES RESPIRATORY HANDS BODY
(BLUE)
(RED)
For Routine Industrial Use and Handling Applications
SEE SECTION 8
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
(ORANGE)
1
0
SEE SECTION 8
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
3 = Serious 4 = Severe * = Chronic hazard
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11. TOXICOLOGICAL INFORMATION (Continued) HEALTH EFFECTS OR RISKS FROM EXPOSURE (continued): TARGET ORGANS: ACUTE: Skin, eyes, respiratory system. CHRONIC: Skin, respiratory system. TOXICITY DATA: Currently, toxicity data are available for the following components of these products:
changes in liver weight; Blood: changes in spleen TDLo (Intravenous-Rat) 10 mg/kg/2 minutes: Biochemical;
Enzyme inhibition, induction, or change in blood or tissue levels: hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.)
TDLo (Skin-Rat) 11 gm/kg/4 weeks-intermittent: Blood: pigmented or nucleated red blood cells; Liver: changes in liver weight; Nutritional and Gross Metabolic: weight loss or decreased weight gain
TDLo (Intratracheal-Rat) 16 mg/kg: Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TDLo (Intratracheal-Rat) 15 mg/kg: Lungs, Thorax, or Respiration: other changes; Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: cytochrome oxidases (including oxidative phosphorylation)
TDLo (Intratracheal-Rat) 10 mg/kg: Lungs, Thorax, or Respiration: sputum; Biochemical: Metabolism (Intermediary): other proteins, effect on inflammation or mediation of inflammation
TDLo (Intratracheal-Mouse) 20 mg/kg: Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TDLo (Intratracheal-Mouse) 20 mg/kg/4 days-intermittent: Lungs, Thorax, or Respiration: sputum; Immunological Including Allergic: increase in cellular immune response; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TDLo (Parenteral-Mouse) 36 µg/kg/3 days-intermittent: Immunological Including Allergic: increase in humoral immune response
TCLo (Inhalation-Rat) 7 mg/m3: Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Rat) 1.66 mg/m3/7 hours: Lungs, Thorax, or Respiration: sputum; Blood: changes in leukocyte (WBC) count; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Rat) 50 mg/m3: Sense Organs and Special Senses (Olfaction): effect, not otherwise specified; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Rat) 50 mg/m3/6 hours/90 days-intermittent: Lungs, Thorax, or Respiration: other changes
TCLo (Inhalation-Rat) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Rat) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: other changes, changes in lung weight; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
CARBON BLACK (continued): TCLo (Inhalation-Rat) 50 mg/m3/13 weeks-intermittent:
Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): other
TCLo (Inhalation-Rat) 50 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): other, effect on inflammation or mediation of inflammation
TCLo (Inhalation-Rat) 7 mg/m3/6 hours/13 weeks-intermittent: Sense Organs and Special Senses (Olfaction): effect, not otherwise specified; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Mouse) 50 mg/m3/6 hours: Sense Organs and Special Senses (Olfaction): effect, not otherwise specified
TCLo (Inhalation-Mouse) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Mouse) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: other changes; Lungs, Thorax, or Respiration: changes in lung weight; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Mouse) 7 mg/m3/6 hours/13 weeks-intermittent: Sense Organs and Special Senses (Olfaction): effect, not otherwise specified; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Hamster) 7 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of inflammation
TCLo (Inhalation-Hamster) 50 mg/m3/6 hours/13 weeks-intermittent: Sense Organs and Special Senses (Olfaction): effect, not otherwise specified
Lungs, Thorax, or Respiration: fibrosis, focal (pneumoconiosis); Blood: changes in spleen; Immunological Including Allergic: decrease in cellular immune
TCLo (Inhalation-Rat) 108 mg/m3/6 hours/3 days-intermittent: Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: phosphatases, Enzyme inhibition, induction, or change in blood or tissue levels: other oxidoreductases, Metabolism (Intermediary): other proteins
TCLo (Inhalation-Rat) 58 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: other changes; Endocrine: changes in thymus weight; Blood: changes in leukocyte (WBC) count
TCLo (Inhalation-Mouse) 1475 µg/m3/8 hours/21 weeks-intermittent: Lungs, Thorax, or Respiration: other changes
TCLo (Inhalation-Mouse) 4932 µg/m3/24 hours/39 weeks-continuous: Endocrine: changes in spleen weight; Immunological Including Allergic: decrease in humoral immune response
TCLo (Inhalation-Guinea Pig) 28 mg/m3/3 weeks-continuous: Lungs, Thorax, or Respiration: other changes, changes in lung weight; Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: other
rate increase, without fall in BP; Liver: liver function tests impaired; Kidney/Ureter/Bladder: other changes in urine composition
TCLo (Inhalation-Rat) 76 mg/m3/4 hours: Blood: changes in serum composition (e.g. TP, bilirubin, cholesterol); Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: phosphatases
TDLo (Unreported-Mammal-Species Unspecified) 18,000 mg/kg/7 days-intermittent: Gastrointestinal: other changes; Related to Chronic Data: death
CARCINOGENIC POTENTIAL OF COMPONENTS: The components of these products are listed by agencies tracking the carcinogenic potential of chemical compounds, as follows:
CARBON BLACK: ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen); Notice of Intended Change: ACGIH TLV-A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans); IARC-2B (Possibly Carcinogenic to Humans), MAK-3B (Substances for Which in vitro Tests or Animal Studies Have Yielded Evidence of Carcinogenic Effects that is Not Sufficient for Classification of the Substance in One of the Other Categories), NIOSH-Ca (Potential Occupational Carcinogen, with No Further Categorization)
CRYSTALLINE SILICA: ACGIH TLV-A2 (Suspected Human Carcinogen); IARC-1 (Carcinogenic to Humans); MAK-1 (Substances that Cause Cancer in Man and Can Be Assumed to Make a Significant Contribution to Cancer Risk); NIOSH-Ca (Potential Occupational Carcinogen, with No Further Categorization); NTP-K (Known to Be a Human Carcinogen)
IRON OXIDE/HEMATITE: IARC-3 (Unclassifiable as to Carcinogenicity in Humans) MAGNESIUM CARBONATE (TALC containing no asbestos fibers): ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen); IARC-3 (Unclassifiable as to Carcinogenicity in Humans);
MAK-3B (Substances for Which in vitro Tests or Animal Studies Have Yielded Evidence of Carcinogenic Effects that is Not Sufficient for Classification of the Substance in One of the Other Categories)
The remaining components of this product are not found on the following lists: U.S. EPA, U.S. NTP, U.S. OSHA, U.S. NIOSH, GERMAN MAK, IARC, or ACGIH and therefore are neither considered to be nor suspected to be cancer-causing agents by these agencies.
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11. TOXICOLOGICAL INFORMATION (Continued) IRRITANCY OF PRODUCT: These products may cause skin, eye and respiratory irritation. SENSITIZATION TO THE PRODUCT: Components of these products are not known to cause human skin or respiratory sensitization. REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this these products and their components on the human reproductive system.
Mutagenicity: The components of these products are not reported to cause mutagenic effects in humans. Embryotoxicity: The components of these products are not reported to cause embryotoxic effects in humans. Teratogenicity: The components of these products are not reported to cause teratogenic effects in humans. Reproductive Toxicity: The components of these products are not reported to cause reproductive effects in humans.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process.
ACGIH BIOLOGICAL EXPOSURE INDICES: Currently, there are no ACGIH Biological Exposure Indices (BEIs) determined for the components of these products.
12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
MOBILITY: These products have not been tested for mobility in soil; due to form they are not expected to be mobile. PERSISTENCE AND BIODEGRADABILITY: These products have not been tested for persistence or biodegradability. BIO-ACCUMULATION POTENTIAL: These products have not been tested for bio-accumulation potential. ECOTOXICITY: These products have not been tested for aquatic or animal toxicity. All release to terrestrial, atmospheric and aquatic environments should be avoided. OTHER ADVERSE EFFECTS: The components of these products are not listed as having ozone depletion potential. EFFECT OF CHEMICAL ON AQUATIC LIFE: These products have not been tested for aquatic toxicity. Releases of large quantities of this material may be detrimental to an aquatic environment.
13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with regulations of Canada. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. U.S. EPA WASTE NUMBER: Not applicable. EUROPEAN EWC CODE: Wastes Not Otherwise Specified: 16 10 99
14. TRANSPORTATION INFORMATION U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS: These products are NOT classified as dangerous goods,
per U.S. DOT regulations, under 49 CFR 172.101. TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: These products are NOT
classified as Dangerous Goods, per regulations of Transport Canada. INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): These products are NOT classified as Dangerous Goods, per
rules of IATA. INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION: These products are NOT classified as Dangerous
Goods, per rules of IMO. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): These products are NOT classified by the United Nations Economic Commission for Europe to be dangerous goods.
15. REGULATORY INFORMATION ADDITIONAL U.S. REGULATIONS: U.S. SARA REPORTING REQUIREMENTS: The components of these products are not subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act. U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for the components of these products. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) therefore applies, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
U.S. TSCA INVENTORY STATUS: Components of these products are on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): Crystalline Silica is on the California Proposition 65 lists. Carbon Black, with particles of respirable size, is on the Proposition 65 Lists as well. WARNING! These products contain compounds known to the State of California to cause cancer.
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15. REGULATORY INFORMATION (Continued) ADDITIONAL U.S. REGULATIONS (continued): LABELING (Precautionary Statements) ANSI LABELING (Z129.1): CAUTION! MAY CAUSE EYE AND RESPIRATORY TRACT IRRITATION. CONTAINS CRYSTALLINE SILICA, WHICH IS A KNOWN HUMAN CARCINOGEN; CONTAINS CARBON BLACK, WHICH IS A KNOWN ANIMAL CARCINOGEN. INGESTION MAY BE HARMFUL. Avoid breathing dusts. Avoid contact with skin, eyes, and clothing. Keep container closed. Use with adequate ventilation. Prevent dust accumulation. Wash thoroughly after handling. Wear gloves, goggles, dust mask, and appropriate body protection during operations that can generate dust. FIRST-AID: In case of contact, flush skin or eyes with plenty of water. If inhaled, remove to fresh air. If ingested do not induce vomiting. Get medical attention if adverse effects continue after overexposure ends. IN CASE OF FIRE: Use water fog, dry chemical, CO2, or “alcohol” foam. IN CASE OF SPILL: Sweep up spill, avoiding the generation of airborne dusts. Place residual in appropriate container and seal. Consult Material Safety Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: The components of these products are on the DSL Inventory. OTHER CANADIAN REGULATIONS: Not applicable. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of these products are not on the CEPA Priority Substances Lists. CANADIAN WHMIS CLASSIFICATION and SYMBOLS: Class D2A-Chronic Toxic Effects
EUROPEAN UNION INFORMATION:
EU LABELING/CLASSIFICATION: These products do meet the definition of any hazard class, as defined by the European Union Council Directive 67/548/EEC or subsequent Directives.
EU Classification: Not applicable. EU Risk Phrases: Not applicable. EU Safety Phrases: Not applicable.
CLASSIFICATION INFORMATION FOR COMPONENTS: Crystalline Silica:
The following is a self-classification per requirements in Commission Directives. Classification: These components are not classified in the European Union Annex I of Directive 67/548/EEC or subsequent Directives. EU Classification: [Xn] Harmful EU Risk Phrases: [R: 68/20]: Harmful: possible risk of irreversible effects through inhalation. EU Safety Phrases: [S: 22]: Do not breathe dust. [S: 38]: In case of insufficient ventilation wear suitable respiratory equipment.
All Other Components: Classification: Official classifications have not been published under EU Directives for these compounds.
16. OTHER INFORMATION PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 1961, Hilo, HI 96721 •(800) 441-3365 DATE OF PRINTING: October 13, 2010
REVISION INFORMATION: July 2010: Review of MSDS and up-date. Format up-dated. Section 3 EU Crystalline Silica self-classification added. Section 8 Exposure limits up-dated. Section 11 Cancer ratings up-dated. Section 15 EU component classification added.
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Stanley Works assumes no responsibility for injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Stanley Works assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.
DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on an MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each constituent.
EXPOSURE LIMITS IN AIR: CEILING LEVEL: The concentration that shall not be exceeded during any part of the working exposure. DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens which have been shown to increase the mutant frequency in the progeny of exposed humans. 2: Germ cell mutagens which have been shown to increase the mutant frequency in the progeny of exposed mammals. 3A: Substances which have been shown to induce genetic damage in germ cells of human of animals, or which produce mutagenic effects in somatic cells of mammals in vivo and have been shown to reach the germ cells in an active form. 3B: Substances which are suspected of being germ cell mutagens because of their genotoxic effects in mammalian somatic cell in vivo; in exceptional cases, substances for which there are no in vivo data, but which are clearly mutagenic in vitro and structurally related to known in vivo mutagens. 4: Not applicable (Category 4 carcinogenic substances are those with non-genotoxic mechanisms of action. By definition, germ cell mutagens are genotoxic. Therefore, a Category 4 for germ cell mutagens cannot apply. At some time in the future, it is conceivable that a Category 4 could be established for genotoxic substances with primary targets other than DNA [e.g. purely aneugenic substances] if research results make this seem sensible.) 5: Germ cell mutagens, the potency of which is considered to be so low that, provided the MAK value is observed, their contribution to genetic risk for humans is expected not to be significant. DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the developing embryo or fetus has been unequivocally demonstrated. Exposure of pregnant women can lead to damage of the developing organism, even when MAK and BAT (Biological Tolerance Value for Working Materials) values are observed.
EXPOSURE LIMITS IN AIR (continued): DFG MAK Pregnancy Risk Group Classification (continued): Group B: Currently available information indicates a risk of damage to the developing embryo or fetus must be considered to be probable. Damage to the developing organism cannot be excluded when pregnant women are exposed, even when MAK and BAT values are observed. Group C: There is no reason to fear a risk of damage to the developing embryo or fetus when MAK and BAT values are observed. Group D: Classification in one of the groups A-C is not yet possible because, although the data available may indicate a trend, they are not sufficient for final evaluation. IDLH-Immediately Dangerous to Life and Health: This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. LOQ: Limit of Quantitation. MAK: Federal Republic of Germany Maximum Concentration Values in the workplace. NE: Not Established. When no exposure guidelines are established, an entry of NE is made for reference. NIC: Notice of Intended Change. NIOSH CEILING: The exposure that shall not be exceeded during any part of the workday. If instantaneous monitoring is not feasible, the ceiling shall be assumed as a 15-minute TWA exposure (unless otherwise specified) that shall not be exceeded at any time during a workday.
NIOSH RELs: NIOSH’s Recommended Exposure Limits.
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DEFINITIONS OF TERMS (Continued)
EXPOSURE LIMITS IN AIR (continued): PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits. This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, “Vacated 1989 PEL,” is placed next to the PEL that was vacated by Court Order. SKIN: Used when a there is a danger of cutaneous absorption. STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-minute time-weighted average (TWA) exposure that should not be exceeded at any time during a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-TWA or REL-TWA. TLV-Threshold Limit Value: An airborne concentration of a substance that represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour. TWA-Time Weighted Average: Time Weighted Average exposure concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek.
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS: This rating system was developed by the National Paint and Coating
Association and has been adopted by industry to identify the degree of chemical hazards. HEALTH HAZARD: 0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = “0”. Eye Irritation: Essentially non-irritating, or minimal effects which clear in < 24 hours [e.g. mechanical irritation]. Draize = “0”. Oral Toxicity LD50 Rat: < 5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LD50 Rat: > 500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L);2 (Moderate Hazard: Temporary or transitory injury may occur. Skin Irritation: Moderately irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation: Moderately to severely irritating and/or corrosive; reversible corneal opacity; corneal involvement or irritation clearing in 8-21 days. Draize > 0, < 25. Oral Toxicity LD50 Rat: > 50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.); 3 (Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given; high level of toxicity; corrosive. Skin Irritation: Severely irritating and/or corrosive; may destroy dermal tissue, cause skin burns, dermal necrosis. PII or Draize > 5-8 with destruction of tissue. Eye Irritation: Corrosive, irreversible destruction of ocular tissue; corneal involvement or irritation persisting for more than 21 days. Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD50 Rat: > 1-50 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-threatening; major or permanent damage may result from single or repeated exposure. Skin Irritation: Not appropriate. Do not rate as a “4”, based on skin irritation alone. Eye Irritation: Not appropriate. Do not rate as a “4”, based on eye irritation alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L). FLAMMABILITY HAZARD: 0 (Minimal Hazard-Materials that will not burn in air when
exposure to a temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight Hazard-Materials that must be pre-heated before ignition can occur. Material require considerable pre-heating, under all ambient temperature conditions before ignition and combustion can
occur, Including: Materials that will burn in air when exposed to a temperature of 815.5°C
(1500°F) for a period of 5 minutes or less; Liquids, solids and semisolids having a flash point at
or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most ordinary combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not, under normal conditions, form hazardous atmospheres in air, but under high ambient temperatures or moderate heating may release vapor in sufficient quantities to produce hazardous atmospheres in air, Including: Liquids having a flash-point at or above
37.8°C [100°F]; Solid materials in the form of course dusts that may burn rapidly but that generally do not form explosive atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly and create flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that readily give off flammable vapors.); 3 (Serious Hazard- Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures, or, unaffected by ambient temperature, are readily ignited under almost all conditions, including:
Liquids having a flash point below 22.8°C [73°F] and having a boiling point at or above 38°C
[100°F] and below 37.8°C [100°F] [e.g. OSHA Class IB and IC]; Materials that on account of their physical form or environmental conditions can form explosive mixtures with air and are readily dispersed in air [e.g., dusts of combustible solids, mists or droplets of flammable liquids]; Materials that burn extremely rapidly, usually by reason of self-contained oxygen [e.g. dry nitrocellulose and many organic peroxides]); 4 (Severe Hazard-Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air, and which will burn readily, including: Flammable gases; Flammable cryogenic materials; Any liquid or gaseous material that is liquid while under pressure and has
a flash point below 22.8°C [73°F] and a boiling point below 37.8°C [100°F] [e.g. OSHA Class
IA; Material that ignite spontaneously when exposed to air at a temperature of 54.4°C [130°F] or below [e.g. pyrophoric]). PHYSICAL HAZARD: 0 (Water Reactivity: Materials that do not react with water. Organic Peroxides: Materials that are normally stable, even under fire conditions and will not react with water. Explosives: Substances that are Non-Explosive. Unstable Compressed Gases: No Rating. Pyrophorics: No Rating. Oxidizers: No “0” rating allowed. Unstable Reactives: Substances that will not polymerize, decompose, condense or self-react.); 1 (Water Reactivity: Materials that change or decompose upon exposure to moisture. Organic Peroxides: Materials that are normally stable, but can become unstable at high temperatures and pressures. These materials may react with water, but will not release energy. Explosives: Division 1.5 & 1.6 substances that are very insensitive explosives or that do not have a mass explosion hazard. Compressed Gases: Pressure below OSHA definition. Pyrophorics: No Rating. Oxidizers: Packaging Group III; Solids: any material that in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing Group I and II are not met.
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS (continued): PHYSICAL HAZARD (continued): 1 (continued): Unstable Reactives: Substances that may decompose, condense or self-react, but only under conditions of high temperature and/or pressure and have little or no potential to cause significant heat generation or explosive hazard. Substances that readily undergo hazardous polymerization in the absence of inhibitors.); 2 (Water Reactivity: Materials that may react violently with water. Organic Peroxides: Materials that, in themselves, are normally unstable and will readily undergo violent chemical change, but will not detonate. These materials may also react violently with water. Explosives: Division 1.4 – Explosive substances where the explosive effect are largely confined to the package and no projection of fragments of appreciable size or range are expected. An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package. Compressed Gases: Pressurized and meet OSHA definition
but < 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II Solids: any material that, either in concentration tested, exhibits a mean burning time of less than or equal to the mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for Packing Group I are not met. Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure, but have a low potential for significant heat generation or explosion. Substances that readily form peroxides upon exposure to air or oxygen at room temperature);3 (Water Reactivity: Materials that may form explosive reactions with water. Organic Peroxides: Materials that are capable of detonation or explosive reaction, but require a strong initiating source, or must be heated under confinement before initiation; or materials that react explosively with water. Explosives: Division 1.2 – Explosive substances that have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but do not have a mass explosion hazard. Compressed Gases: Pressure > 514.7 psi
absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group I Solids: any material that, in either concentration tested, exhibits a mean burning time less than the mean burning time of a 3.:2 potassium bromate/cellulose mixture. Liquids: Any material that spontaneously ignites when mixed with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize, decompose, condense or self-react at ambient temperature and/or pressure and have a moderate potential to cause significant heat generation or explosion.); 4 (Water Reactivity: Materials that react explosively with water without requiring heat or confinement. Organic Peroxides: Materials that are readily capable of detonation or explosive decomposition at normal temperature and pressures. Explosives: Division 1.1 & 1.2-explosive substances that have a mass explosion hazard or have a projection hazard. A mass explosion is one that affects almost the entire load instantaneously. Compressed Gases: No Rating. Pyrophorics: Add to the definition of Flammability “4”. Oxidizers: No “4” rating. Unstable Reactives: Substances that may polymerize, decompose, condense or self-react at ambient temperature and/or pressure and have a high potential to cause significant heat generation or explosion.).
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS: HEALTH HAZARD: 0 (materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials): Gases and vapors whose LC50 for acute inhalation toxicity is greater than 10,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than 200 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 2000 mg/kg. Materials whose LD50 for acute oral toxicity is greater than 2000 mg/kg. Materials that are essentially non-irritating to the respiratory tract, eyes and skin. 1 (materials that, under emergency conditions, can cause significant irritation): Gases and vapors whose LC50 for acute inhalation toxicity is greater than 5,000 ppm but less than or equal to 10,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than 10 mg/L but less than or equal to 200 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 1000 mg/kg but less than or equal to 2000 mg/kg. Materials whose LD50 for acute oral toxicity is greater than 500 mg/kg but less than or equal to 2000 mg/kg. Materials that cause slight to moderate irritation to the respiratory tract, eyes and skin. 2 (materials that, under emergency conditions, can cause temporary incapacitation or residual injury): Gases and vapors whose LC50 for acute inhalation toxicity is greater than 3,000 ppm but less than or equal to 5,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than 2 mg/L but less than or equal to 10 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 200 mg/kg but less than or equal to 1000 mg/kg. Materials whose LD50 for acute oral toxicity is greater than 50 mg/kg but less than or equal
to 500 mg/kg. Any liquid whose saturated vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute inhalation toxicity, if its LC50 is less than or equal to 5000 ppm and that does not meet the criteria for either degree of hazard 3 or degree of
hazard 4. Compressed liquefied gases with boiling points between -30°C (-22°F) and -
55°C (-66.5°F) that cause severe tissue damage, depending on duration of exposure. Materials that are respiratory irritants. Materials that cause severe, but reversible irritation to the eyes or are lachrymators. Materials that are primary skin irritants or sensitizers. 3 (materials that, under emergency conditions, can cause serious or permanent injury): Gases and vapors whose LC50 for acute inhalation toxicity is greater than 1,000 ppm but less than or equal to 3,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than 0.5 mg/L but less than or equal to 2 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 40 mg/kg but less than or equal to 200 mg/kg. Materials whose LD50 for acute oral toxicity is greater than 5 mg/kg but less than or equal to 50 mg/kg. Any liquid
whose saturated vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute inhalation toxicity, if its LC50 is less than or equal to 3000 ppm and that does not meet the criteria for degree of hazard 4. Compressed liquefied gases with boiling
points between -30°C (-22°F) and -55°C (-66.5°F) that cause frostbite and irreversible tissue damage. Materials that are respiratory irritants. Cryogenic gases that cause frostbite and irreversible tissue damage. Materials that are corrosive to the respiratory tract. Materials that are corrosive to the eyes or cause irreversible corneal opacity. Materials that are corrosive to the skin. 4 (materials that, under emergency conditions, can be lethal): Gases and vapors whose LC50 for acute inhalation toxicity less than or equal to 1,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is less than or equal to 0.5 mg/L. Materials whose LD50 for acute dermal toxicity is less than or equal to 40 mg/kg. Materials whose LD50 for acute oral toxicity is less than or equal to 5 mg/kg. Any liquid
whose saturated vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute inhalation toxicity, if its LC50 is less than or equal to 1000 ppm.
STANLEY CHALKS MSDS
STANLEY CHALKS MSDS PAGE 10 OF 10
DEFINITIONS OF TERMS (Continued) NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS (continued): FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand:
Materials that will not burn in air when exposed to a temperature of 816°C (1500°F) for a period of 5 minutes in according with Annex D. 1 Materials that must be preheated before ignition can occur. Materials in this degree require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur: Materials that
will burn in air when exposed to a temperature of 816°C (1500°F) for a period of 5 minutes in accordance with Annex D. Liquids, solids and semisolids having a flash point at or
above 93.4°C (200°F) (i.e. Class IIIB liquids). Liquids with a flash point greater than 35°C
(95°F) that do not sustain combustion when tested using the Method of Testing for Sustained Combustibility, per 49 CFR 173, Appendix H or the UN Recommendation on the Transport of Dangerous Goods, Model Regulations (current edition) and the related Manual
of Tests and Criteria (current edition). Liquids with a flash point greater than 35°C (95°F) in a water-miscible solution or dispersion with a water non-combustible liquid/solid content of more than 85 percent by weight. Liquids that have no fire point when tested by ASTM D 92 Standard Test Method for Flash and Fire Points by Cleveland Open Cup, up to a boiling point of the liquid or up to a temperature at which the sample being tested shows an obvious physical change. Combustible pellets with a representative diameter of greater than 2 mm (10 mesh). Solids containing greater than 0.5 percent by weight of a flammable or combustible solvent are rated by the closed up flash point of the solvent. Most ordinary combustible materials. 2 Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to
produce hazardous atmospheres with air: Liquids having a flash point at or above 37.8°C
(100°F) and below 93.4°C (200°F) (i.e. Class II and Class IIIA liquids.) Solid materials in the form of powders or coarse dusts of representative diameter between 420 microns (40 mesh) and 2 mm (10 mesh) that burn rapidly but that generally do not form explosive mixtures in air. Solid materials in fibrous or shredded form that burn rapidly and create flash fire hazards, such as cotton, sisal and hemp. Solids and semisolids that readily give off flammable vapors. Solids containing greater than 0.5 percent by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. 3 Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by ambient temperatures, are readily ignited under almost all conditions:
Liquids having a flash point below 22.8°C (73°F) and having a boiling point at or above
37.8°C (100°F) and those liquids having a flash point at or above 22.8°C (73°F) and below
37.8°C (73°F) and below 37.8°C (100°F) (i.e. Class IB and IC liquids). Materials that, on account of their physical form or environmental conditions, can form explosive mixtures with air and are readily dispersed in air. Flammable or combustible dusts with a representative diameter less than 420 microns (40 mesh). Materials that burn with extreme rapidity, usually by reason of self-contained oxygen (e.g. dry nitrocellulose and many organic peroxides). Solids containing greater than 0.5 percent by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. 4 Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air and will burn readily: Flammable gases. Flammable cryogenic materials. Any liquid or gaseous materials that is liquid while under
pressure and has a flash point below 22.8°C (73°F) and a boiling point below 37.8°C
(100°F) (i.e. Class IA liquids). Materials that ignite when exposed to air, Solids containing greater than 0.5 percent by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire conditions: Materials that have an estimated instantaneous power density (product of heat of
reaction and reaction rate) at 250°C (482°F) below 0.01 W/mL. Materials that do not exhibit
an exotherm at temperatures less than or equal to 500°C (932°F) when tested by differential scanning calorimetry. 1 Materials that in themselves are normally stable, but that can become unstable at elevated temperatures and pressures: Materials that have an estimated
instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above 0.01 W/mL and below 10 W/mL. 2 Materials that readily undergo violent chemical change at elevated temperatures and pressures: Materials that have an estimated
instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above 10 W/mL and below 100W/mL.
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS (continued): INSTABILITY HAZARD (continued): 3 Materials that in themselves are capable of detonation or explosive decomposition or explosive reaction, but that require a strong initiating source or that must be heated under confinement before initiation: Materials that have an estimated instantaneous power density (product of heat of reaction and reaction rate)
at 250°C (482°F) at or above 100 W/mL and below 1000 W/mL. Materials that are sensitive to thermal or mechanical shock at elevated temperatures and pressures. 4 Materials that in themselves are readily capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures: Materials that have an estimated
instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F) of 1000 W/mL or greater. Materials that are sensitive to localized thermal or mechanical shock at normal temperatures and pressures.
FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source.
ECOLOGICAL INFORMATION: EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a substance will concentrate in lifeforms which consume contaminated plant or animal matter. TLm = median threshold limit; Coefficient of Oil/Water Distribution is represented by log Kow or log Koc and is used to assess a substance’s behavior in the environment.
TOXICOLOGICAL INFORMATION: Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m3 concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: The sources are: IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV.
REGULATORY INFORMATION: U.S. and CANADA:
ACGIH: American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits.
This section explains the impact of various laws and regulations on the material. EPA is the U.S. Environmental Protection Agency. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). WHMIS is the Canadian Workplace Hazardous Materials Information System. DOT and TC are the U.S. Department of Transportation and the Transport Canada, respectively. Superfund Amendments and Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status according to the DOT; the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund); and various state regulations. This section also includes information on the precautionary warnings which appear on the material’s package label. OSHA - U.S. Occupational Safety and Health Administration.
Protective Clothing OSHA Classification WHMIS (Canada) Transport
Not Required for Normal Use Not classified as a hazardous chemical Not Controlled Not Regulated
Emergency Overview:
Exposure to hazardous substances is not expected when handling this article for its intended use. Hot, molten product can cause thermal burns.
Appearance, Color and Odor: Solid, tangerine stick in a labeled holder, odorless.
While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product.
USA: This product is not a hazardous chemical as defined by 29 CFR1910.1200, OSHA Hazard Communication Standard. This product meets the definition of an “article”.
Canada: This is not a controlled product under WHMIS. This product meets the definition of a “manufactured article” and is not subject to the regulations of the Hazardous Products Act.
European Union (EU): This product is not classified as hazardous according to Regulation (EC) No 1272/2008.
Potential Health Effects ACUTE (short term):
Relevant Route(s) of Exposure: Skin contact.
Inhalation: Exposure to hazardous substances by inhalation is not expected with normal use of the product. Fumes generated from overheating the material may cause irritation to the respiratory tract.
Ingestion: Not an expected route of occupational exposure. Components of the product have low oral toxicity. May cause nausea, vomiting and diarrhea if swallowed.
Skin: Normal use of the stick will not result in harmful effects. Molten product can cause thermal burns.
Eye: Not an expected route of occupational exposure. Fumes generated from overheating the material may cause eye irritation.
CHRONIC (long term): see Section 11 for additional toxicological data
Long-term health effects are not expected with normal use of the product.
Section 3: Composition / Information on Ingredients
Mixture containing non-hazardous substances in a non-hazardous hydrocarbon resin.
Section 4: First Aid Measures
Inhalation: If symptoms are experienced remove source of contamination or move victim to fresh air and obtain medical advice.
Eye Contact:
No effects expected. If irritation occurs, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes. If irritation persists, obtain medical advice.
Skin Contact:
If irritation does occur, flush with lukewarm, gently flowing water for 5 minutes. If irritation persists, obtain medical advice. For thermal burns: cool affected area with cold water; do not remove solidified material from the skin; seek medical attention.
Ingestion: If swallowed, call a Poison Control Centre or obtain medical advice immediately.
Section 5: Fire Fighting Measures
Flammable Properties:
Product will burn if involved in a fire.
Suitable extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam. For large fires, use carbon dioxide, dry chemical powder, alcohol-resistant foam or polymer foam. Use water spray to cool fire-exposed containers.
Unsuitable extinguishing Media:
Do not use water jet on hot, molten product.
Explosion Data: Sensitivity to Mechanical Impact:
Not applicable
Sensitivity to Static Discharge: Not applicable
Specific Hazards arising from the Chemical:
If involved in a fire, combustion may produce toxic and irritating fumes and gases including oxides of sulfur, potassium and carbon.
Protective Equipment and precautions for firefighters:
Self-contained breathing apparatus and protective clothing should be worn. Remove all unprotected personnel.
Section 6: Accidental Release Measures
Personal Precautions: Wear thermal protective gloves if needed to prevent skin contact with hot, molten material.
Environmental Precautions: Prevent the product from entering sewers or waterways.
Methods for Containment: Not applicable
Methods for Clean-up:
Pick up spilled product and collect for re-use or proper disposal. Dispose of any contaminated, unusable product as described in Section 13 of this SDS.
Section 7: Handling and Storage
Handling:
Keep out of reach of children. Avoid breathing any fumes from thermal decomposition. Do not ingest. Do not use on foods. Do not touch heated, molten product.
Storage: Store out of direct sunlight and away from heat, flames and ignition sources.
Measurable airborne concentrations of the component substances are not expected when the product is used for its intended purpose. Exposure Controls Engineering Controls:
Not required for normal use.
Personal Protection:
Eye/Face Protection:
No special requirements. Wear protective equipment appropriate for the workplace conditions where this product is used.
Skin Protection: Wear thermal protective gloves when needed to prevent burns.
Respiratory Protection: No special requirements Wear protective equipment appropriate for the workplace conditions where this product is used.
General Hygiene Measures: Avoid breathing fumes. Do not ingest. Avoid contact with the skin. Keep out of reach of children. Wash hands at the end of every work shift and before eating, drinking, smoking or using the toilet.
Section 9: Physical and Chemical Properties
Physical State:
Solid.
Flash Point & method:
Not available
Appearance, Color and Odor:
Tangerine stick in a labeled holder, odorless.
Autoignition Temperature: Not available
Odor Threshold:
Not available Flammability Limits in Air: Not available
pH:
Not applicable Vapor Pressure: Not available
Relative density:
>1 (estimated) Vapor Density: Not applicable
Partition coefficient:
Not available Evaporation Rate: Not applicable
Solubility:
Insoluble in cold water. Boiling Point/Range: Not available
Viscosity:
Not applicable Melting Point: Approximately 650°F/343°C
Decomposition Temperature:
Not available VOC Content: 0% (w/w)
Section 10: Stability and Reactivity Chemical Stability:
Stable
Conditions to Avoid:
Do not use in conditions of extreme heat or near open flames. Avoid contact with other substances; contamination of product may affect its melting point.
Incompatible Materials:
Incompatible with strong acids, strong bases and oxidizing agents.
Hazardous Decomposition Products:
Heating to decomposition may release highly toxic fumes including low molecular weight hydrocarbons and volatile acidic vapors.
Acute toxicity data is not available for the marking preparations inside the sticks. Worker exposure to toxic and harmful substances is not expected when the stick is used for its intended purpose.
Other Toxicity Data
Carcinogenicity: Normal use of this product will not result in exposure to any component that is considered a human carcinogen by IARC (International Agency for Research on Cancer), ACGIH (American Conference of Governmental Industrial Hygienists, OSHA or NTP (National Toxicology Program).
Irritation: Direct contact with the eyes may cause irritation. May cause irritation if in prolonged or repeated contact with skin.
Corrosivity: Not applicable
Sensitization: Not applicable
Neurological Effects: Not applicable
Genetic Effects: Not applicable
Reproductive Effects: Not applicable
Developmental Effects: Not applicable
Target Organ Effects: Not applicable
Section 12: Ecological Information
Ecotoxicity: Not available
Persistence/Degradability: Not available
Bioaccumulation/Accumulation: Not available
Mobility: Not available
Section 13: Disposal Considerations
Waste Disposal Method:
Do NOT dump into any sewers, on the ground or into any body of water. Store material for disposal as indicated in Section 7 Handling and Storage. The conditions of use, storage and disposal of this product are beyond our control and may be beyond our knowledge. For this and other reasons, LA-CO Industries, Inc. does not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this product.
Waste must be disposed of in accordance with relevant EU Directives and national, regional and local environmental control regulations.
TSCA Status: All component substances are listed on the TSCA inventory.
SARA Title III Sec. 302/304: Sec: 311/312:
Sec. 313: CERCLA RQ:
None None Not applicable Not applicable
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
WHMIS Classification: (for workplace exposures)
Not controlled. Product meets the definition of a “manufactured article” and is not subject to the regulations of the Hazardous Products Act.
New Substance Notification Regulations:
All substances are listed on Canada’s Domestic Substances List (DSL).
NPRI Substances: Not applicable
EU Classification for the Substance/Preparation
European Inventories: All component substances are listed in EINECS.
Symbol: This product is not classified as dangerous according to Regulation (EC) No 1272/2008.
Section 16: Other Information
Preparation Information:
Revision Date:
September 6, 2012
Manufacturer Disclaimer: The information contained herein is based on data available to us and is accurate and reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc. makes no representations as to its completeness or accuracy. Information is supplied on condition that persons receiving such information will make their own determination as to its suitability for their purposes prior to use. In no event will LA-CO Industries, Inc. be responsible for damages of any nature whatsoever resulting from the use of or reliance upon the information contained herein.
While LEHDER Environmental Services Limited believes that the data set forth herein is accurate, as of the date hereof, LEHDER makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data is offered solely for your consideration, investigation and verification.
Material Safety Data Sheet
TREMSTOP FYRE-SIL S/L RUST RED-4.5 GAL Version 3. Print Date 11/27/2010 REVISION DATE: 11/26/2010
1/5 939874 805
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information Trade name : TREMSTOP FYRE-SIL S/L RUST RED-4.5 GAL Product code : 939874 805 Supplier : Tremco Canada division
Rust Red. Paste. May cause slight irritation to the respiratory system. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention. Acute Potential Health Effects/ Routes of Entry
Inhalation : May cause slight irritation to the respiratory system. Eyes : Direct contact may cause moderate irritation. Ingestion : May cause irritation to the mouth, throat and stomach. Skin : May cause mild irritation.
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure. Chronic Health Effects
Possible skin sensitization. As a by-product of curing up to 4% Methyl Ethyl Ketoxime (MEKO) may be released within product. Repeated and prolonged exposure to MEKO can cause allergic skin reaction. It may adversely affect the blood, (methemoglobinemia and anemia). Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free silica. Organosilane may cause liver injury with fibrosis after repeated and prolonged overexposure. Fillers are encapsulated and not expected to be released from product under normal conditions of use. Target Organs: Skin, Blood, Lung, Liver, Kidney
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range Oximino Silane 22984-54-9 1.0 - 5.0 Titanium dioxide 13463-67-7 0.1 - 1.0
Material Safety Data Sheet
TREMSTOP FYRE-SIL S/L RUST RED-4.5 GAL Version 3. Print Date 11/27/2010 REVISION DATE: 11/26/2010
2/5 939874 805
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 0.1 - 1.0 The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure. Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : Not available. Method : Not available.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion products
: Smoke, fumes.Carbon monoxide and carbon dioxide can form.Silicon oxides and trace amounts of MEKO.
Protective equipment for firefighters
: Use accepted fire fighting techniques. Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : This product not expected to ignite under normal conditions of use.
Use appropriate protective equipment. Avoid contact with material. Keep out of water courses. Scrape up and transfer to appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
Personal protective equipment must be worn during maintenance or repair of contaminated mixer, reactor, or other equipment. Do not use in confined or poorly ventilated areas. Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when not in use. Precautions also apply to emptied containers. Change soiled work clothes frequently. Clean hands thoroughly after handling. Store in sealed containers in a cool, dry, ventilated warehouse location.
Material Safety Data Sheet
TREMSTOP FYRE-SIL S/L RUST RED-4.5 GAL Version 3. Print Date 11/27/2010 REVISION DATE: 11/26/2010
Substances to avoid : Strong acids.Strong bases.Alcohols.Water or moisture and oxidizing agents.
Material Safety Data Sheet
TREMSTOP FYRE-SIL S/L RUST RED-4.5 GAL Version 3. Print Date 11/27/2010 REVISION DATE: 11/26/2010
4/5 939874 805
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
No Data Available
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED SECTION 15 - REGULATORY INFORMATION
North American Inventories: All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
Canadian Regulations: WHMIS Classification : D2A, D2B This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System (WHMIS). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. Other Regulations: Regulatory VOC (less water and exempt solvent)
: 26 g/l
Material Safety Data Sheet
TREMSTOP FYRE-SIL S/L RUST RED-4.5 GAL Version 3. Print Date 11/27/2010 REVISION DATE: 11/26/2010
5/5 939874 805
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammability 1 Reactivity 0 PPE
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration DOT - Department of Transportation PEL - Permissible Exposure Limit DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act EPA - Environmental Protection Agency STEL - Short Term Exposure Limit HMIS - Hazardous Materials Information System TLV - Threshold Limit Value IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act MSHA - Mine Safety Health Administration TWA - Time Weighted Average NDSL - Non-Domestic Substance List V - Volume NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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Material Safety Data SheetUltramarine blue MSDS
Section 1: Chemical Product and Company Identification
Product Name: Ultramarine blue
Catalog Codes: SLU1114
CAS#: 57455-37-5
RTECS: Not available.
TSCA: TSCA 8(b) inventory: Ultramarine blue
CI#: 77007
Synonym: Pigment Blue 29; Sodium AluminoSulfosilicate
Chemical Name: Ultramarine Blue
Chemical Formula: Na6-Al6-Si6-O24-S4
Contact Information:
Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396
US Sales: 1-800-901-7247International Sales: 1-281-441-4400
For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Ultramarine blue 57455-37-5 100
Toxicological Data on Ingredients: Ultramarine blue: ORAL (LD50): Acute: 5000 mg/kg [Rat].
Section 3: Hazards Identification
Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Slightly hazardous in case of inhalation.
Potential Chronic Health Effects:Slightly hazardous in case of ingestion. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available.
Section 4: First Aid Measures
Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention.
Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.
Serious Inhalation: Not available.
Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on thecontaminated surface and allow to evacuate through the sanitary system.
Section 7: Handling and Storage
Precautions:Do not ingest. Do not breathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
p. 3
Section 8: Exposure Controls/Personal Protection
Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.
Personal Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.
Exposure Limits: Not available.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid. (Powdered solid.)
Odor: Odorless.
Taste: Not available.
Molecular Weight: Not available.
Color: Blue.
pH (1% soln/water): Not applicable.
Boiling Point: Not available.
Melting Point: Decomposes.
Critical Temperature: Not available.
Specific Gravity: 2.3 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility: Insoluble in cold water.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
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Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Eye contact. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 5000 mg/kg [Rat].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion. Slightly hazardous in case of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Section 14: Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
Section 15: Other Regulatory Information
Federal and State Regulations: TSCA 8(b) inventory: Ultramarine blue
Other Regulations: Not available.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC): R36/38- Irritating to eyes and skin.
p. 5
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/10/2005 12:13 AM
Last Updated: 11/01/2010 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.
