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Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input...

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Multi-Stage Cascade Refrigeration System
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Page 1: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Multi-StageCascade Refrigeration System

Page 2: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Contents

Refrigeration Cycle and Input Condition of Natural Gas

Cascade Refrigeration

Three-Stage Refrigeration of methane

Two-Stage Refrigeration of ethylene

Three-Stage Refrigeration of propane

Multi-Stage Cascade Refrigeration Cycle & Results

02/33

Page 3: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Refrigeration Cycle and Input Condition of Natural Gas

03/33

Page 4: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

What is the refrigerator?

Ø By letting-down the pressure of chilled and highly compressed refrigerant, we can obtain a cold temperature of refrigerant. By adjusting the pressure letting-down level, we can obtain a wanted temperature level of refrigerant.

Ø By cooling after compressing a vapor stream, we can obtain a liquefied refrigerant.

04/33

Page 5: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Ideal refrigeration Cycle

Process Flow Diagram Pressure Enthalpy Diagram

Compressor

Condenser

ExpansionValve

Evaporator

D

AB

C

A

B C

D

△Hevap

TB=TC

TA TDPA, PD

PB, PC

P

H

By utilizing the Pressure-Enthalpy (P-H) diagram, the refrigeration cycle can be broken down into four distinct steps :

ExpansionEvaporationCompressionCondensation

A

B

C

D

05/33

Page 6: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Input Condition of Natural Gas

Component Mole%Nitrogen 0.22

Methane 91.33

Ethane 5.36

Propane 2.14

I-Butane 0.46

N-Butane 0.47

I-Pentane 0.01

N-Pentane 0.01

Total 100

Contents ValuePressure (bar) 53

Temperature (oC) 45

Flow Rate (kg/hr) 625,000

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Page 7: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Cascade Refrigeration

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Page 8: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Cascade Refrigeration

Stream01Pressure : 53bar

Temperature : 45 oCFlow Rate : 625,000 kg/hr

E01Pressure drop(Hot Side) : 0.5barMinimum of [Hot Out-Cold In] and [Hot In-Cold Out] : 3 oCRefrigerant Component : C3Refrigerant Temp. : 11.075 oC

E02Pressure drop(Hot Side) : 0.5barMinimum of [Hot Out-Cold In] and [Hot In-Cold Out] : 3 oCRefrigerant Component : C3

Refrigerant Temp. : -17.148 oC

E03Pressure drop(Hot Side) : 0.5bar

Hot Product Temp. : -37 oCRefrigerant Component : C3Refrigerant Temp. : -40 oC

E04Pressure drop(Hot Side) : 0.5barMinimum of [Hot Out-Cold In] and [Hot In-Cold Out] : 3 oCRefrigerant Component : C2-

Refrigerant Temp. : -69.74 oC

E05Pressure drop(Hot Side) : 0.5bar

Hot Product Temp. : -92 oCRefrigerant Component : C2-

Refrigerant Temp. : -95 oC

E06Pressure drop(Hot Side) : 0.5barMinimum of [Hot Out-Cold In] and [Hot In-Cold Out] : 3 oCRefrigerant Component : C1

Refrigerant Temp. : -118.78 oC

E07Pressure drop(Hot Side) : 0.5barMinimum of [Hot Out-Cold In] and [Hot In-Cold Out] : 3 oCRefrigerant Component : C1

Refrigerant Temp. : -139.29 oC

E08Pressure drop(Hot Side) : 0.5bar

Hot Product Temp. : -152 oCRefrigerant Component : C1Refrigerant Temp. : -155 oC

F01Adiabatic : duty 0

E01 E02 E03 E04 E05 E06 E07 E08CV01

F01

02

01

11

12

03 04 05 06 07 08 09 10

CV01Pressure Drop : 0

CN01

08/33

Page 9: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

CN1 Condition & Result

09/33

Rate of LNG Liquefaction=Stream12 Total Rate/Stream01 Total Rate X 100

= 32158.4636/35065.3581 X 100 = 91.71%

Page 10: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Heat duty(106 Kcal/hr)

0 20 40 60 80 100 120 140

Temperature(

℃)

-200

-150

-100

-50

0

50

Cascade Heating Curve

C3

C2-

C1

[1]

[2]

[3]

[4]

[5]

[6]

[7]

[8]

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Page 11: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Cascade Heating Curve

Temperature(℃)

Heat duty(*106 Kcal/hr)

Flowrate of refrigerator

(kg/hr)

[1] 11.08 11.7401 337452.036

[2] -17.15 11.2082 117796.037

[3] -40.00 10.6854 106008.027

[4] -69.74 25.8445 253708.024

[5] -95.00 33.0099 296820.610

[6] -118.78 14.0877 149153.654

[7] -139.29 10.5958 95617.043

[8] -155.00 7.6387 64009.514

Total 124.8103

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Page 12: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Multi-Stage Cascade Refrigeration Cycle

E01 E02 E03

E04 E05

E06 E07 E08

K01K02K03

Propane

Ethylene

Methane

K04K05

K06K07K08

M01M02M03

M04M05

M06M07M08

CV01F01

F02 F03 F04

F05 F06

F07 F08 F09

E09

E10

E11

E12

CV02 CV03 CV04

CV05

CV06

CV07 CV08 CV09

SP01 SP02

SP03 SP04

SP05 SP06 SP07

04 05

030201

09

10

11

12

06 07 08

21 22

22V

22L 22B

22A

2423

24L

24V

24B

24A

2625

26V

26L

27

2829

30

31

3233

61

62

62V

62L 62B

62A

6463

64L

64V

64B

64A

6665

66V

66L

67

6970

71

72

7374

66B

66A

68

41

42

42L

42V

42B

42A

4344

44V

44L44B

44A

45 46

4748

49

50

51

12/33

Page 13: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Three-Stage Refrigeration of methane

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Page 14: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Three-Stage Refrigeration System

Temperature of Refrigerator(E06)= Dew point temperature of propane

at 4.6250 bar= -118.78 oC

Temperature of Refrigerator(E07)= Dew point temperature of propane

at 12.6947 bar= -139.29 oC

First Stage Discharge Pressure(K01)= First Suction Pressure * Ratio per stage

= 1.685 * 2.7448= 4.6250 bar

Second Stage Discharge Pressure(K02)= Second Suction Pressure * Ratio per stage

= 4.6250 * 2.7448= 12.6947 bar

06 07 08 09

E09

CV02CV03 CV04

F02 F03 F04

SP01SP02

M01K01M02K02

E06 E07 E08

M03K03

21 22

22V

22L

23

22B

22A 24

24V

25

24L

24B

24A 26

26L

26V

27

2829

30

31

32

33

Ratio per stage

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Page 15: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Calculation of total flowrate of methane

CV02Outlet Pressure :

12.6947 bar

CV03Outlet Pressure :

4.6250 bar

CV04Outlet Pressure :

1.6850 bar

15/33

Page 16: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

CN1 Condition & Result

Total Flowrate of methane35431.4336 Kgmol/hr = 568419.403 kg/hr

16/33

Page 17: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Three-Stage Refrigeration Cycle

K01Outlet Pressure : 4.6250barAdiabatic Efficiency : 70%

E06/E07/E08Pressure drop(Hot Side) : 0.5 barCold Product Liquid Fraction : 0

F02/F03/F04Adiabatic : duty 0

Stream21Temperature : -92 ℃

Bubble PointComponent : Methane

Total Fluid Flowrate : 568420 kg/hr

K02Outlet Pressure : 12.6947barAdiabatic Efficiency : 70%

K03Outlet Pressure : 34.845barAdiabatic Efficiency : 70%

E09Pressure drop(Hot Side) : 0.5barHot Product Liquid Fraction : 1

CV02Outlet Pressure :

12.6947 bar

CV03Outlet Pressure :

4.6250 bar

CV04Outlet Pressure :

1.6850 bar

17/33

Page 18: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Two-Stage Refrigeration of ethylene

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Page 19: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

E04 E05

04 05 06

E09

E10

E11

CV05CV06

F05 F06

SP03SP04

M04M05 K04K05

41

42

42V

44L

42B

42A 44

43

44V

42L

44B

44A

45

46

4748

4950

51

Two-Stage Refrigeration System

Temperature of Refrigerator(E04)= Dew point temperature of propane

at 5.2239 bar= -69.74 oC

First Stage Discharge Pressure(K04)= Suction Pressure * Ratio per stage

= 1.665 * 3.1375= 5.2239 bar

Ratio per stage

Condenser Heat Duty of C1 Refrigeration Cycle(E09)

= 56.2055*106 Kcal/hr

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Page 20: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Calculation of total flowrate of ethylene

Stream Name 44A 46

Temperature (℃) -95.00 -95.00

Pressure (bar) 1.665 1.665

Flowrate(kgmole/hr)

18015.211 18015.211

Flowrate(kg/hr)

505395.121 505395.121

E09 Duty 56.2055*106 Kcal/hr

20/33

Page 21: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Calculation of total flowrate of ethylene

CV05Outlet Pressure :

5.2239 bar

CV06Outlet Pressure :

1.6650 bar

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Page 22: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

CN3 Condition & Result

Total Flowrate of ethylene53164.75 Kgmol/hr = 1491473.264 kg/hr

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Page 23: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Two-Stage Refrigeration CycleK04

Outlet Pressure : 5.2239barAdiabatic Efficiency : 70%

K05Outlet Pressure : 16.390barAdiabatic Efficiency : 70%

E09Pressure drop(Hot Side) : 0.5barHot Product Liquid Fraction : 1

CV05Outlet Pressure :

5.2239 bar

CV06Outlet Pressure :

1.6650 bar

E04/E05Pressure drop(Hot Side) : 0.5 barCold Product Liquid Fraction : 0

E10Pressure drop(Hot Side) : 0 barHot Product Temperature : 45℃

E11Pressure drop(Hot Side) : 0.5 barHot Product Liquid Fraction : 1

F05/F06Adiabatic : duty 0

Stream41Temperature : -37 ℃

Bubble PointComponent : Ethylene

Total Fluid Flowrate : 1491500 kg/hr

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Page 24: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Three-Stage Refrigerationof propane

24/33

Page 25: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Three-Stage Refrigeration System

Temperature of Refrigerator(E01)= Dew point temperature of propane

at 2.7013 bar= -17.148 oC

Ratio per stage

Temperature of Refrigerator(E02)= Dew point temperature of propane

at 6.5505 bar= 11.075 oC

First Stage Discharge Pressure(K06)= First Suction Pressure * Ratio per stage

= 1.114 * 2.4249= 2.7013 bar

Second Stage Discharge Pressure(K07)= Second Suction Pressure * Ratio per stage

= 2.7013 * 2.4249= 6.5505 bar

E01 E02 E03

E11

01 02 03 04

61

62

62V

62L

62B

62A 64

63

64V

64L

64B

64A 66

65

66L

66V

67

66B

66A

68

71

72 70 69

73

74

K08 K06K07 M06M07M08

CV07CV08 CV09

F07 F08 F09SP05 SP06 SP07

E12

Condenser Heat Duty of C2- Refrigeration Cycle(E11)

= 174.1497*106 Kcal/hr

25/33

Page 26: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Calculation of total flowrate of propane

Stream Name 66A 68

Temperature (℃) -40.00 -39.99

Pressure (bar) 1.114 1.114

Flowrate(kgmole/hr)

39180.305 39180.305

Flowrate(kg/hr)

1727714.258 1727714.258

E09 Duty 174.1497*106 Kcal/hr

26/33

Page 27: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Calculation of total flowrate of propane

CV07Outlet Pressure :

6.5505 bar

CV08Outlet Pressure :

2.7013 bar

CV09Outlet Pressure :

1.114 bar

27/33

Page 28: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

CN5 Condition & Result

Total Flowrate of propane87113.3668 Kgmol/hr = 3841394.579 kg/hr

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Page 29: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Three-Stage Refrigeration Cycle

K06Outlet Pressure : 2.7013barAdiabatic Efficiency : 70%

E01/E02/E03Pressure drop(Hot Side) : 0.5 barCold Product Liquid Fraction : 0

F07/F08/F09Adiabatic : duty 0

Stream61Temperature : 45 ℃

Bubble PointComponent : Propane

Total Fluid Flowrate : 3841400 kg/hr

K07Outlet Pressure : 6.5505barAdiabatic Efficiency : 70%

K08Outlet Pressure : 15.885barAdiabatic Efficiency : 70%

E12Pressure drop(Hot Side) : 0.5barHot Product Liquid Fraction : 1

CV07Outlet Pressure :

6.5505 bar

CV08Outlet Pressure :

2.7013 bar

CV09Outlet Pressure :

1.114 bar

E09Pressure drop(Hot Side) : 0.5barHot Product Liquid Fraction : 1

29/33

Page 30: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Multi-Stage Cascade Refrigeration Cycle

& Results

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Page 31: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Multi-Stage Cascade Refrigeration Cycle

31/33

Page 32: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Results of Calculator

Refrigerator Contents Actual Work (kW)

Propane

K08 6.97935E+04

K07 4.65535E+04

K06 3.26463E+04

EthyleneK05 4.93771E+04

K04 2.40789E+04

Methane

K03 1.94100E+04

K02 6.41777E+03

K01 1.91124E+03

Total 2.50188E+05

LNG Flowrate (kg/hr) 577679.6567

Specific Power for produced LNG [kWh/kg]= 0.433 kWh/kg LNG

32/33

Page 33: Multi-Stage Cascade Refrigeration System · PDF fileContents Refrigeration Cycle and Input Condition of Natural Gas Cascade Refrigeration Three-Stage Refrigeration of methane Two-Stage

Thank youfor your attention


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