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8/11/2019 Nanotechnology and Maya Blue
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Mystery Image
High magnification micrograph of a grain of intergrown palygorskite fibers.
Note the presence of poorly crystalline smectitic clays on the lower left of the micrograph (x 80,000) Source : www.attaclay.co.za/pix/atta3.gif
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So rce: www.pict resofrecor!.com/"onampak#$%.htm
http://en.wikipe!ia.org/wiki/Maya&"l e'
"erke' Heinz ($##)* +,he in-ention of bl e an! p rple pigments in ancient times hem. Soc. 0e-.' $##)' 3%' 12 3#' 45I: 1#.1#36/b%#%$%7g
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5
Maya "l e8hy se it9
; H $5 $ < ; H $5
$H $5 ; 5 $ H $5 $
Source : http://www.mi!seasonreplacements.com (San!ra' =merica>s Next ,op Mo!el*
hy!rogen peroxi!e
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8/11/2019 Nanotechnology and Maya Blue
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Maya "l eHow !oes it work9
(Mg'=l* $Si @5 1# (5H*A@H$5Source : http://rr ff.geo.arizona.e! /!oclib/hom/palygorskite.p!f
Mineral Han!book
1%H1# N$5 $Source : http://en.wikipe!ia.org/wiki/In!igo&!ye
Mg' =l grey' Si !ark green' 5 re!' N light bl e' carbon colorlessSource : "erke' Heinz ($##)* +,he in-ention of bl e an! p rple pigments in ancient times
hem. Soc. 0e-.' $##)' 3%' 12 3#' 45I: 1#.1#36/b%#%$%7gSources : http://backreaction.blogspot.com/$##7/#3/cookies<palygorskite<an!<maya<bl e.html (science blog*
H bbar!' "asil ($##3* +Str ct ral St !y of Maya "l e: ,ext ral' ,hermal an! Soli!state M ltin clear Magnetic 0esonanceharacterization of the Balygorskite<in!igo an! Sepiolite<in!igo =!! cts lays an! lay Minerals' Col. 21' No. 3' 317 3$%.
lattice perio!icity 1.@ nmSource : 4 tta' Doy!eep an! Hofmann'
Heinrich ($##3* +Self<5rganization of olloi!alNanoparticles Encyclope!ia of Nanosciencean! Nanotechnology E!ite! by H. S. Nalwa
Col me F: Bages (1 $3*
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Maya "l eHow !oes it work9 8here !oes the in!igo
lo!ge91. +8ithin the channels of palygorskite'
$. at the openings of its nanot nnels'
3. or in open channels on grain s rfaces
Gare some of the proposals fo n! in theliterat re. =ll of them in-ol-e !yemolec les strongly hy!rogen<bon!e!'isolate! an! protecte! by theinorganic lattice.
Source : mez<0omeroa' Be!ro ($##2* +Hybri! materials.J nctional properties. Jrom Maya "l e to $1 st cent rymaterials New Do rnal of hemistry' $##2' $6' 2) 27
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Maya "l eHow !oes it work9
In!igo nestles on openchannels or groo-es on theBalygorskite' bon!ingthro gh $ hy!rogen bon!s.Source : hiari' . ($##7* +Bre<col mbian nanotechnology:reconciling the mysteries of the maya bl e pigment =ppl.Bhys. = 6#' 3 ) 45I: 1#.1##)/s##336<##)<@$7)<z
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Maya "l eHow !oes it work9
1%H1# N$5 $
Source : "erke' Heinz ($##)* +,he in-ention of bl e an! p rple pigments in ancient times
hem. Soc. 0e-.' $##)' 3%' 12 3#' 45I: 1#.1#36/b%#%$%7g
Source : ht tp://en.wikipe!ia.org/wiki/In!igo&!ye
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Maya "l eHow !oes it work9
Sources : 0onan' olin =. (1663* Science Explaine!' 13%
Nassa ' K rt ($##1* ,he Bhysics an! hemistry of olor: ,he Jifteen a ses of olor' 1$$
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Maya "l eHow !oes it work9
Sources : 0onan' olin =. (1663* Science Explaine!' 137
1 Cause of Color
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Maya "l eHow !oes it work9
Source : Nassa ' K rt ($##1* ,he Bhysicsan! hemistry of olor: ,he Jifteen a ses
of olor' $6$<$62' 3#%<3#)' 3@7<323
15 Causes of Color
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earth ; air ; fire ; water H ; 5 ; ; N ; G
0e! ctionism
protons ; electrons ; photons ; GL arks ; leptons ; !ark matter ; Ggra-ity ; electromagnetism ;weak ; strong ; G
Explain
the s rf
Explain
the win!
onser-ation laws
E ler eL ations (fl i! !ynamics*
4arcy s law
4ynamic press re
Jl i! statics
Helmholtz s theorems
Kirchhoff eL ations
Manning eL ation
Mil!<slope eL ation
Morison eL ation
Na-ier Stokes eL ations
5seen flowBascal s law
Boise ille s law
Botential flow
Bress re
Static press re
Bress re hea!
0elati-istic E ler eL ations
0eynol!s !ecomposition
Stokes flow
Stokes stream f nction
Stream f nction
Streamlines' streaklines an! pathlines
Source : htt ://en.wiki e!ia.or /wiki/Jl i! ! namics
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Emergent Broperties(aka emergence *
Source : http://s.ws .net/p blic/reso rces/images/5"< =361ˇph&$##7#711###3$7. pg
Let’s see…hydrogen, just aproton and electron. A gas.
Oxygen, 8 protons, 8 neutrons,and 8 electrons. Also a gas.
Bond a couple hydrogen witheach oxygen to ma e a li!uid. "x #$ %& ' %Os in each liter. % x #$ (
liters in an Olympic pool. And)*oil+)# gold medals-
Source : http://en.wikipe!ia.org/wiki/ eorge& abriel&Stokes
4ear Mr. Bhelps' itappears yo r brain h rts
from !eri-ing the Na-ier<Stokes eL ation for motion
of fl i! s bstances:
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Emergent Broperties(aka emergence *
Source : =n!erson' B.8. (16)$*' OMore is 4ifferent:"roken Symmetry an! the Nat re of the HierarchicalStr ct re of ScienceO' Science 1)) (@#@)*: 363 36%
,he ability to re! ce e-erythingto simple f n!amental laws !oesnot imply the ability to start from
those laws an! reconstr ct theni-erse..,he constr ctionisthypothesis breaks !own when
confronte! with the twin!iffic lties of scale an!
complexity. =t each le-el ofcomplexity entirely new
properties appear.
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Broperties of Matter P Nanoscale
Q ,o n!erstan! R createnanotechnology' we rely onproperties of matter at the nanoscale
Q "etween b lk materials (mg' kg;* at
+the topan! elements or simple compo n!sat +the bottom
Q Mo!els of emergent properties areapproximations ' enable! by scale
an! force! by complexityQ 8hen yo !esign molec les an!
sim late with molec lar !ynamicsan! L ant m chemistry' yo will not
st see b t feel why we approximateSource : http://en.wikipe!ia.org/wiki/Jile:34&mo!el&hy!rogen&bon!s&in&water. pg