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NEKTOR™ 4G - Grace Catalysts...1G 2G 3G NEKTOR™N EKTOR-ULCC NaceR NOMUS™ NOMUS-DMAX DieseliseR...

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Fig. 1. NEKTORis the leading technology in EMEA for low delta coke applications. Fig. 2. New functionalities utilized in NEKTOR4G. Fig. 3. NEKTOR™ 4G enabled heavier feed processing through lower delta coke. Table 1. NEKTOR4G improved unit profitability by $5/ton feed by allowing greater flexibility to process heavier feed in Refinery A. NEKTOR4G incorporates new technologies that were developed during the extensive Grace R&D program that was initiated as a result of the tight oil boom in North America and the new challenges faced by European refineries. This R&D program resulted in advances to the following five functionalities: Higher Diffusivity Matrices Flexible Hydrogen Transfer Higher Activity Advanced Metals Tolerance Dual Zeolite Functionality. 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 NEKTOR™ 4G Case Study NEKTOR4G was successfully used in a coke-burn limited FCC unit. NEKTOR4G’s lower delta coke relieved the regenerator bed temperature constraint. Cat/oil increased by +0.5 and the unit conversion by +0.7wt%. The refinery was able to use the improved delta coke to process heavier feeds, which in turn boosted profitability by approximately $5/MT. NEKTOR™ 4G Higher Diffusivity Matrices Dual Zeolite Technology Flexible Hydrogen Transfer Higher Activity Advanced Metals Tolerance Normalised shifts vs base Conversion +0.7 wt% C1+C2 -0.5 wt% C3+C4 +1.3 wt% Gasoline -0.1 wt% LCO (wt%) -0.5 wt% Slurry -0.2 wt% Regenerator T(°C) -16°C Cat/Oil +0.5 Unit profitability + $5/MT feed # of EnhanceR™ applications NEKTOR™4G is the latest generation of Grace’s market- leading low coke NEKTOR™ for residue FCC feed applications. NEKTOR™ 4G is manufactured using the Grace EnhanceRTechnology Platform, and is an extension of the NEKTORcatalyst family, which is the market leader in the EMEA region (Fig. 1). Ni equivalent (Ni+V/4-0.4/0.33 Sb) (ppm) Delta coke Base catalyst NEKTOR -4G 0.6 2,000 2,500 3,000 3,500 4,000 0.7 0.8 0.9 1.0
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Page 1: NEKTOR™ 4G - Grace Catalysts...1G 2G 3G NEKTOR™N EKTOR-ULCC NaceR NOMUS™ NOMUS-DMAX DieseliseR ... NEKTOR™ 4G catalysts result from Grace’s innovation in FCC catalyst technology.

Fig. 1. NEKTOR™ is the leading technology in EMEA for low delta coke applications.

Fig. 2. New functionalities utilized in NEKTOR™ 4G.

Fig. 3. NEKTOR™ 4G enabled heavier feed processing through lower delta coke.

Table 1. NEKTOR™ 4G improved unit profitability by $5/ton feed by allowing greater flexibility to process heavier feed in Refinery A.

NEKTOR™ 4G incorporates new technologies that were developed during the extensive Grace R&D program that was initiated as a result of the tight oil boom in North America and the new challenges faced by European refineries.

This R&D program resulted in advances to the following five functionalities:• Higher Diffusivity Matrices• Flexible Hydrogen Transfer• Higher Activity• Advanced Metals Tolerance• Dual Zeolite Functionality.

2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

# of EnhanceR applications

NEKTOR™ 4G Case Study

NEKTOR™ 4G was successfully used in a coke-burn limited FCC unit. NEKTOR™ 4G’s lower delta coke relieved the regenerator bed temperature constraint. Cat/oil increased by +0.5 and the unit conversion by +0.7wt%. The refinery was able to use the improved delta coke to process heavier feeds, which in turn boosted profitability by approximately $5/MT.

NEKTOR™ 4G

Higher Diffusivity Matrices

Dual Zeolite Technology

Flexible Hydrogen Transfer

Higher Activity

Advanced Metals Tolerance

Normalised shifts vs baseConversion +0.7 wt%

C1+C2 -0.5 wt%C3+C4 +1.3 wt%

Gasoline -0.1 wt%LCO (wt%) -0.5 wt%

Slurry -0.2 wt%Regenerator T(°C) -16°C

Cat/Oil +0.5Unit profitability + $5/MT feed

# of EnhanceR™ applications

NEKTOR™4G is the latest generation of Grace’s market- leading low coke NEKTOR™ for residue FCC feed applications.

NEKTOR™ 4G is manufactured using the Grace EnhanceR™ Technology Platform, and is an extension of the NEKTOR™ catalyst family, which is the market leader in the EMEA region (Fig. 1).

Ni equivalent (Ni+V/4-0.4/0.33 Sb) (ppm)

Del

ta c

oke

Base catalyst

NEKTOR™ -4G

0.62,000 2,500 3,000 3,500 4,000

0.7

0.8

0.9

1.0

Page 2: NEKTOR™ 4G - Grace Catalysts...1G 2G 3G NEKTOR™N EKTOR-ULCC NaceR NOMUS™ NOMUS-DMAX DieseliseR ... NEKTOR™ 4G catalysts result from Grace’s innovation in FCC catalyst technology.

The information contained herein is based upon our testing and experience and is believed to be accurate. Since operating conditions may vary and since we do not control such conditions, we must disclaim any warranty, express or implied, with regard to results to be obtained from the use of our products or with regard to application of GRACE techniques. January 2015

W. R. Grace & Co.-Conn. | 7500 Grace Drive | Columbia, MD 21044 | USA | +1.410.531.4000 | www.grace.com

Grace Refining Technologies

NEKTOR™ 4G catalysts bring the following performance benefits to unit operations:

• lowest delta coke for heavy metal feeds • excellent coke to bottoms performance • high intrinsic activity and stability• excellent attrition resistance.

NEKTOR™ 4G catalysts are fully compatible with all Grace additives.

Technical ServiceAn equally critical component associated with processing challenging feeds is solid technical service support. Grace has been providing industry-leading technical service to the refining industry since 1947.

Grace’s experienced engineers support FCC customers with:

• Application and operations expertise • Start-up and optimization assistance • Industry benchmarking • Feed characterization and pilot plant studies

Understanding feed impacts earlier allows opportunity to optimize the operating parameters and catalyst management strategies, enabling a more stable and profitable operation.

Innovation

NEKTOR™ 4G is the latest in a long line of Grace’s innovation in catalyst technology, and is the product of Grace’s global team of research scientists.

Our sales representatives in your region

W.R. Grace & Co. Refining Technologies7500 Grace Drive Columbia, MD 21044 USA Phone: +1 (410) 531-4000

Grace GmbH & Co. KGIn der Hollerhecke 1, 67547 Worms, GermanyPhone: +49 (6241) 403-00

W.R. Grace Singapore PTE Ltd.230 Orchard RoadFaber House#09-232Singapore 238854Phone: (65) 6265 3033

MIDAS® Gold

Highest activity, deep conversion resid catalyst

Used in 7 FCC’s globally

2014

pre

20032003 2003

2003-2009

REsolution™REactoR™REduceR™ProgREss™

MIDAS®

Gold

EnhanceR™

New holistic approach to catalyst design

Used in over 100 FCC’s in EMEA

2013

ACHIEVE ® 400

1G 2G 3G

NEKTOR™ NEKTOR-ULCC NaceR

NOMUS™ NOMUS-DMAX DieseliseR

NADIUS™ ProtAgon™ ResidCrackeR

2015

EnhanceR 4G

ACHIEVE® Series

2013

MIDAS® in EMEA

High matrix bottoms cracking catalyst

Used in over 120 FCC’s globally

ACHIEVE® 400

Maximum octane and butylene selectivity

Used in 3 FCC’s in N. America

MIDAS®

REpLaCeR® Rare-earth free FCC catalysts

Used in over 170 FCC’s

2011

NEKTOR™ 4GResidCrackeR™ 4GNADIUS™ 4G ProtAgon™ 4G

™ 4G

Platform

Fig. 4. NEKTOR™ 4G catalysts result from Grace’s innovation in FCC catalyst technology.


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