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NETWORK PINCH ANALYSIS PART II
PROCESS OPTIMIZATION
Introducing Process Integration for Environmental Control in Engineering
Curricula
Created by:Ana Carolina Hortua
Texas A&M UniversityCollege Station, TX.
PURPOSE
The purpose of this module is to describe basic concepts and techniques necessary in the application of direct recycle as a strategy for the optimization of a process performance.
Direct recycle is considered a low-cost strategy since the companies are not required to invest a large amount of capital into equipment or technologies in order to reduce significantly their fresh resource consumption and/or waste production.
MODULE STRUCTURE
This module is made up of three tiers:
Tier I: Basic Concepts
Tier II: Application of Direct Recycle Concepts (Case Study)
Tier III: Open-Ended Problem
TIER IBASIC CONCEPTS
DEFINITIONS
Refers to the identification of performance benchmarks ahead of detailed design. In other words, targeting determines how far we can push the process performance without specifying how it may be reached.
TARGETING:
It is a holistic approach to process design and operation that emphasizes the unity of the process and optimizes its design and operation.
PROCESS INTEGRATION:
DEFINITIONS
Refers to avoiding mixing of streams. Segregation of streams with different compositions avoids unnecessary loss of driving force streams. Thus, improving the performance of process units and may allow the streams to be recycle directly into the units.
SEGREGATION:
RECYCLE:Refers to the utilization of a process stream (e.g. a waste or a low-value stream) in a process unit.
DEFINITIONS
Correspond to the load of the targeted species in streams designated as waste streams or point sources of pollution.
TERMINAL LOAD (T):
FRESH LOAD (F):
Correspond to the quantity of the targeted species in streams entering the process.
WholePlant (F)
WholePlant (T)
DEFINITIONS
An existing process unit/equipment such as reactors, separators, etc., which can accept a source.
SINK:
SOURCE:A stream which contains the targeted species.
RECYCLE STRATEGY
This is an important strategy in the optimization of a process because through this technique we can determine the target for minimum usage of fresh resource (Fmin), maximum material reuse and minimum discharge to waste (Tmin); as a result of the reutilization of process streams.
Whole Plant RecoveryNetwork
Total Fresh Load (F)
Process Streams
Maximum Recycle (R)
Total Terminal Load (T)
Fmin = F - R Tmin = T - R
IN OUT
DIRECT RECYCLE
DIRECT RECYCLE
This technique is based on the rerouting of process streams directly to process units without the addition of new equipment.
Direct recycle must respect the constrains such as feed flowrate, composition, etc., for each process units involved in the recycle analysis in order to keep the same level of product quality as well as the safety process operation.
Therefore, in order to fulfill with these constrains the process streams can be segregated, mixed and/or distributed in several ways depending on the specific case.
DIRECT RECYCLE REPRESENTATION
Sinks Constrains on feed flowrate and composition
Segregated Sources
Sources
?SINK
SINK
SINK
DIRECT RECYCLEThe next design questions should be answered in order to apply direct recycle strategy successfully :
Should a stream (source) be segregated and split? To how many fractions? What should be the flow rate of each split? Should streams or splits of streams be mixed? To what extent? What should be the optimum feed entering each sink? What should be its composition? What is the minimum amount of fresh resource used? What is the minimum discharge of unused process sources?
DIRECT RECYCLE
The previous design questions can be solved by the application of a graphical procedure called Source-Sink Mapping Diagram and Level-Arm Rules.
However, before describing the methods mentioned above, it is necessary to identify the bounds (limits) on flowrate and composition for the sink(s) that is/are going to accept the recycle stream(s).
The flow rate and composition bounds on sinks can be determined based on several considerations such as:
1. From physical limitations (e.g. flooding flowrate, weeping flowrate, channeling flowrate, saturation composition, etc.).
2. From manufacturer’s design data.3. From technical constrains (e.g., to avoid scaling, corrosion,
explosion, buildup, etc.)4. From historical data.
HOW TO IDENTIFY BOUNDS ON SINKS
By taking into account a process with a number of process sources that can be considered for possible recycle and replacement of the fresh material and/or reduction of waste discharge. Each source, i, has a given flowrate, W i, and a given composition of a targeted species, yi. Available for services is a fresh (external) resource that can be purchased to supplement the use of process sources in sinks. Each sink, j, requires a feed whose flowrate, Gin
j, and an inlet composition of a targeted species, zin
j, that must satisfy certain bounds.
Example:
Unit jFeedGin
j
zinj
Source iWi
yi
HOW TO IDENTIFY BOUNDS ON SINKS (continued)
As mentioned in the previous problem statement, there are bounds on flowrate and composition entering each sink. In this example, the bounds were set using historical data and they are described as follows :
Flow Rate Bounds:
Gminj < Gin
j < Gmaxj
Where: j=1,2,…,Nsinks Gmin
j and Gmaxj are the lower and upper
bounds on admissible flowrate to unit j
Gminj
Gmaxj
Time Composition Bounds:
zminj < zin
j < zmaxj
Where: j=1,2,…,Nsinks zmin
j and zmaxj are the lower and upper
bounds on admissible composition to unit j
zminj
zmaxj
Time
HOW TO IDENTIFY BOUNDS ON SINKS (continued)
HOW TO IDENTIFY BOUNDS ON SINKS (continued)5. Constrain propagation: In some cases, the constrains on a sink j are based on
critical constrains for another unit (j+1). Therefore, to determine the constrains for unit j, it is necessary to use a process model that relates the inlets for both sinks.
Example:
Unit j Unit j+1
Known ConstraintsUnknown Constraintszmin
j < zinj < zmax
jzmin
j+1 < zinj+1 < zmax
j+1
zinj zin
j +1
From process model: zinj = 3zin
j+1
0.03 < zinj < 0.04 0.09 < zin
j < 0.012
zminj < zin
j < zmaxj
Source-Sink Mapping Diagram
In order to determine if process streams can be direct recycle to a specific process unit or sink a graphic technique called Source-Sink Mapping Diagram was developed.
This diagram is constructed by plotting the flowrate versus composition for each targeted species. On the source-sink mapping diagram the sources are represented by shaded circles and sinks are represented by unshaded circles.
The constrains on flowrate and composition are respectively represented by horizontal and vertical bands and the intersection of this two bands provides a zone of acceptable load and composition for recycle. As shown in Fig. 1.
Source-Sink Mapping Diagram
sink
source
S
b
a
Composition
c
Flowrate
Figure 1: Source-Sink Mapping Diagram
Range of acceptable flowrates on sink “S”
Range of acceptable composition on sink “S”
Source “a” can be directly recycle to sink “S”
El-Halwagi, 1997
Lever-Arm RulesAs we can see from Fig. 1, just source “a” can be directly recycle to the sink (s) but we still have two more sources “b” and “c”, which contain the targeted specie. Therefore, to create a mixed stream that fulfills with the flowrate and composition constrains for sink (s), the sources “a” and “b” will be mixed using the Lever-Arm Rules as follows in Fig. 2:
Flowrate
Composition
Sourcea
Sourceb
ResultingMixture
ya ys yb
Wb
Wa
Wa+Wb
Figure 2: Mixing of sources “a” and “b”
El-Halwagi, 1997
Lever-Arm RulesAs seen in Fig. 2, the result of mixing the source “a” and “b”, which have a flowrate Wa and Wb and a composition ya and yb respectively, is a mixture with a flowrate Wa + Wb and a targeted composition ys. This resulting mixture fulfills with the constrains for sink (s).
Applying a material balance for the targeted species around the mixing operation we get the following equation:
ys(Wa + Wb) = yaWa + ybWb (1)
From equation (1), we obtained:
Similarly:
Wa yb - ys arm for aWb ys - ya arm for b
= =
Wa arm for a
Wa + Wb Total arm =
Arm for aArm for a = y= ybb - y - ys s
Arm for bArm for b = y= yss - y - yaa
Total ArmTotal Arm = yb - ya
Lever-Arm RulesThe lever-arm for the sources and resulting mixture are represented in Fig. 3.
Wb
Arm for aArm for b
Total Arm
Compositionya ys yb
Flowrate
Sourcea
Sourceb
ResultingMixture
Wa
Wa+Wb
Figure 3: Lever-Arm Rules for mixing
El-Halwagi, 1997
Lever-Arm Rules Applications Lever-Arm rules for fresh resource:
One effective method to reduce fresh resource consumption is by mixing the fresh resource stream with a process stream. But to determine what should be the appropriate composition of the feed entering the sink (s), the lever-arm rules should be applied as shown in Fig. 4:
Flo
wra
te
Sourcea
Fresh
Feed toSink j
Fresh Arm
Total Armyf yaZ feed to sink
Composition
Figure 4: Lever-Arm Rules for fresh resource
arm Total
armFresh
sink tofed flowrate Total
sink in used flowrateFresh
Fa
a
yy
zy
sinktoFeed
sink tofed flowrate Total
sink in used flowrateFresh
Lever-Arm Rules Applications
Sink Composition Rule:
When a fresh source is mixed with process sources (s), the composition of the mixture entering the sink should be set to a value that minimizes the fresh arm.
Example:To reduce the fresh resource consumption in sink (s), the fresh resource stream is mixed with a process stream “a” to obtain a mixture, which satisfies the composition and flowrate requirements for sink (s). The composition constrains for the sink (s) are zmin < zin
< zmax.
What should be the composition of the feed entering the sink?
Based on the equations showed in the previous slide, we can see that the flowrate of fresh resource is minimized when the feed composition (zfeed to sink) entering the sink (s) is maximized. This analysis leads us to the following rule:
Lever-Arm Rules Applications
Sourcea
Fresh
Sink S
???
Z min Z avgZ max
Flo
wra
te
What should be the composition of the feed entering the sink? Zmin, Zavg or Zmax?
Applying the sink composition rule, the composition of the inlet feed should be Zmax because with that value we have the shortest fresh arm.
Z max
Flo
wra
te
Sourcea
Fresh
Minimumfresh arm
Sink S
Figure 6: Sink Composition Rule
Lever-Arm Rules ApplicationsWhen there are two or more process sources that can be recycle to reduce the fresh usage, it is necessary to determine the order in which they should be used.
Example: Supposed we have three process sources (a, b and c) that can be mixed with the fresh source. Which source should be recycled first in order to minimize the use of fresh resource?
Z smax
Flo
wra
te
yF ya yb yc
Sourcea
Fresh
Sink SSource
bSource
c? ? ?
Lever-Arm Rules ApplicationsIn order to solve the problem previously mentioned, a prioritization rule was developed using the concept of fresh arm as follows:
Source Prioritization Rule: To minimize the usage of the fresh resource, recycle of the process sources should be prioritized in order of their fresh arms starting with the source having the shortest fresh arm.
Z smax
Flo
wra
te
yF ya yb yc
Sourcea (1st)
Fresh
Sink SSourceB (2nd)
SourceC(3rd)
Shortest Shortest Fresh Fresh ArmArm
According with the source prioritization rule, the source aa should be used first until it is completely recycled before using source b.
Recycle Alternatives
Using the concepts explained in direct recycle strategies, we can set the target performance of a process. However, depending on the process this target may be attain for more than one recycle alternative, as shown in the next example:
Example: To minimize the terminal load discharged of the process shown below, two different recycle alternatives could be applied.
Process Before RecycleAlternative 1
Alternative 2
Tk,2
Tk,12
3
1Fk,1
Fk,2
Tk,1
Tk,2
2
3
1Fk,1
Fk,2
Note: To generate an effective recycle strategy all the recycle streams should be rerouted to units process that employ fresh resources (In our case: S1 and S3).
Tk,1
Tk,2
2
3
1Fk,1
Fk,2
Material Recycle Pinch Diagram
Material Recycle Pinch DiagramReference: El-Halwagi, M. M., F. Gabriel, and D. Harell, “Rigorous Graphical Targeting for Resource
Conservation via Material Recycle/Reuse Networks”, Ind. Eng. Chem. Res., 42, 4319-4328 (2003)
Material Recycle Pinch Diagram is a method use to determine the target performance of a process as a result of direct recycle without detailing the recycle strategies.
Before describing the targeting procedure the following considerations should be taken into account:
Composition Constrain for Sink j: zmin
j < zinj < zmax
j Where: j=1,2,…,Nsinks
Impurities Entering the Sink j:
Msinkj = Gj zin
j
Where Gj is the feed flowrate entering to the sink j
Constrain on Load:
0 < Msinkj < Mmax
j Where: j=1,2,…,Nsinks
Material Recycle Pinch DiagramIn order to apply the Material Recycle Pinch Diagram the nextprocedure should be follow:
1. Rank the sinks in ascending order of maximum admissible composition of impurities.
zmax1 < zmax
2 < …. < zmaxj.... < zmax
NSINKS
1. Rank sources in ascending order of impurities composition. y1 < y2 < …. < yi.... < yNSINKS
2. Plot the sink composite curve. In order to generate this curve each sink is represented as an arrow by plotting the maximum load of impurities for each sink (Msink
j = Gj zinj ) versus its
flowrate, as shown in Fig. 7.
Material Recycle Pinch DiagramFigure 7: Sink Representation
S2
S3
G1 G2
S1
Msink,max1
Msink,max2
Msink,max3
LoadLoad
FlowrateFlowrateG3
Reference: El-Halwagi, M. M., F. Gabriel, and D. Harell, “Rigorous Graphical Targeting for Resource Conservation via Material Recycle/Reuse Networks”, Ind. Eng. Chem. Res., 42, 4319-4328 (2003)
Material Recycle Pinch Diagram
Figure 8: Sink Composite curve
Sink Composite Curve (Fig. 8) - is the outcome of superposing the sink arrows in ascending order starting with the sink, which has the lowest composition of impurities (zmax
j).
G1 +
G1
G3
S2
S1
S3
Msink,max1
Msink,max2
Msink,max3
G2 +
G1 + G2
LoadLoad
FlowrateFlowrateSourceCompositeCurve
Material Recycle Pinch Diagram4. Generate the source composition curve by plotting the load
of each source (Msourcei = Wj yi ) versus its flowrate. This curve
starts with the source that has the least composition and the rest of the sources will be plotted in ascending order using superposition, as shown in Fig.9:
Msource1
M source2
Msource3
W1 W2 W3 FlowrateFlowrate
LoadLoad
Figure 9: Source Composite Curve
Material Recycle Pinch Diagram
Figure 10 a : Sink and Source Composite Curves
5. Locating the pinch point. The pinch point is found by placing both composite curves in the same diagram (Fig. 10a), then the source composite stream is moved horizontally until it touches the sink composite stream. The point where both curves unite is called the pinch point (Fig. 10b).
FlowrateFlowrate
LoadLoad
Sink Sink Composite Composite CurveCurve
SourceSourceComposite Composite CurveCurve
Material Recycle Pinch Diagram
Figure 10 b : Material Recycle Pinch Diagram
FlowrateFlowrate
Material Recycle Material Recycle Pinch PointPinch Point
Sink Sink Composite Composite CurveCurve
SourceSourceComposite Composite CurveCurve
MinimumMinimumFreshFresh
MaximumMaximum RecycleRecycle
MinimumMinimumWasteWaste
LoadLoad
Reference: El-Halwagi, M. M., F. Gabriel, and D. Harell, “Rigorous Graphical Targeting for Resource Conservation via Material Recycle/Reuse Networks”, Ind. Eng. Chem. Res., 42, 4319-4328 (2003)
Material Recycle Pinch Diagram5. Identify the targets for Minimum Fresh Usage, Maximum
Direct Recycle and Minimum Waste Discharge. Those targets are determined using the Material Recycle Pinch Diagram as follows:
The target for Minimum Fresh Usage is the flowrate of sink below, which there are not sources (fig. 10b).
The target for Maximum Direct Recycle is the overlapped area region of process and sources (fig. 10b).
The target for Minimum Waste Discharge is the flowrate above the sources, which there are not sinks. (fig. 10b)
Design RulesIn order to attain the optimum target for minimum fresh usage and minimum waste discharge, the following three design rules are required:
FlowrateFlowrate
Sink Sink Composite Composite CurveCurve
SourceSourceComposite Composite CurveCurve
MinimumMinimumFreshFresh
RecycleRecycle WasteWaste
LoadLoad
FreshFresh
MinimumMinimumWasteWaste
Figure 11: Passing Flow through the Pinch.
1. No flowrate should be passed through the pinch.
Reference: El-Halwagi, M. M., F. Gabriel, and D. Harell, “Rigorous Graphical Targeting for Resource Conservation via Material Recycle/Reuse Networks”, Ind. Eng. Chem. Res., 42, 4319-4328 (2003)
Design Rules
As we can see in Fig. 11, the sink stream is not touching the source stream; this fact allows a flowrate (α) to pass through the pinch point, which will cause an increase in the consumption of fresh resource as well as in the waste discharge in the amount equal to the (α). Therefore, it will increase the cost operation twice since we are consuming more resource and producing more waste.
2. No waste should be discharged from sources below the pinch.
3. No fresh resource should be used in any sink above the pinch.
Targeting for Impure FreshIn the case where the fresh resource is not pure, the same targeting procedure explained previously applies. However, the main difference now is that the source composite curve will not be locus on the horizontal axis as was shown before, instead it will be locus on a straight line emanating from the origin. The slope of this line is the composition of impurities in the fresh (y fresh ) Fig.12.
FlowrateFlowrate
Material Recycle Material Recycle Pinch PointPinch Point
Sink Sink Composite Composite CurveCurve
SourceSourceComposite Composite CurveCurve
MinimumMinimumFreshFresh
Maximum RecycleMaximum Recycle MinimumMinimumWasteWaste
LoadLoad
Fresh Fresh LocusLocus
Figure 12: Material pinch Diagram when fresh resources is Impure
Reference: El-Halwagi et al., 2003
Material Recycle Pinch Diagram Based on
Properties
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
As we have seen so far, we have just considered the composition and flowrate constrains to evaluate the sink performance; however, there are many process units, specially those that work with solvents, which their performance are based in properties such as viscosity, solubility, density, volatility, etc. Therefore, in order to apply direct recycle as a process optimization strategy, a graphic property integration method was developed to track properties instead of compositions as was study previously.
Material Recycle Pinch Diagram Based on Properties
A number of sinks Nsinks, which require a feed with a given flowrate Gj and an inlet property, pin
j. The feed entering to each sink should satisfy the following constrain:
A number of sources Nsources, which have a given flowrate i, and a given property, pi. They can be considered for recycle to reduce fresh usage.
A fresh resource whose property value is pfresh, and it can supplement the use of process sources in sinks.
Property constrain:pmin
j < pinj < pmax
j Where: j=1,2,…,Nsinks (1)
Before describing the targeting procedure, consider the following process with:
Material Recycle Pinch Diagram Based on Properties
In order to develop a procedure that allows us to determine the optimum target performance of the process stated before, the following rules should be taken into account.
The resulting property of mixing two or more source streams will be evaluated according to the next equation:
F * Ψ ( p ) = ΣFi * Ψ( pi ) (2) i Where F is the total flowrate of the mixture, which is given by:
F = ΣFi (3) i And, Ψ( pi ) is the property-mixing operator, which can be evaluated from first principles or estimated through empirical or semi-empirical methods.
1. Mixing Rule:
Material Recycle Pinch Diagram Based on Properties
Example: Consider the mixing of two liquid sources whose flowrates are F1 and F2, volumetric flowrates are V1 and V2, and densities are ρ1 and ρ2. Suppose that the volumetric flowrate of the mixture is given by V = V1 + V2 (4).
Applying the definition of density and designating the total flowrate of the mixture by F, we obtain:
F = F1 + F2 (5) comparing with equation (2)
ρ ρ1 ρ2
We can define the density-mixing operator as:
Ψ( pi ) = 1 (6) ρ i
Material Recycle Pinch Diagram Based on Properties
After the mixing operator is defined, the sink property constrain (eq. 1) can be restated as follows:
And considering the special case where the fresh source has a property operator larger than all other streams, the sink constrain is rewritten as:
The equations shown above gives us the basis to derive optimality rules for maximum recycle of process to sinks, as explained in the following slide.
Ψminj < Ψin
j < Ψmaxj (7)
Ψfresh < Ψinj < Ψmax
j (8) Where: Ψfresh = Ψ( pfresh) (9)
Material Recycle Pinch Diagram Based on Properties
2. Sink Optimality Condition:
When a fresh source is mixed with a reused material, the inlet property operator to the sink should be assigned to its maximum feasible value, that is described in Fig. 13 using the lever-arm rules:
Ψ max
Sourcei
Fresh
Minimumfresh arm
Sink j
Ψ fresh
To minimize the consumption of fresh resource Ψin = Ψ max.
Appling the lever-arm rule:
Ffresh = Ψi - Ψ maxj
Gj Ψi - Ψ fresh
Ffresh = Fresh arm for 1 Gj Total arm from i to fresh
Figure 12: Sink Optimality Condition
Flowrate
Gj
Property Operator
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
3. Source Prioritization Rule:
The use of the process sources should be prioritized starting with the source having the last value of property operator and sequenced in increasing order of the property operator of the sources (Fig.13).
Ψ max
Source i
FreshFresh
arm for i
Sink j
Ψ fresh
Figure 13: Source Prioritization Rule
Gj
Flowrate
Property Operator
Source i +1
Fresh arm for i+1
Ψi Ψi +1
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
Based on the optimality conditions for sources and sinks, thenext graphical targeting procedure is developed:
Targeting Procedure:
1. Rank the sinks in ascending order of Ψmaxj,
Ψ max
1 < Ψ max2 < …. < Ψ max
j.... <Ψ maxNSINKS (10)
and calculate the maximum admissible property load (Uj), for each sink using the following equation:
Uj= Gj* Ψmaxj (11)
Where Gj is the required flowrate for each sink.
Material Recycle Pinch Diagram Based on Properties
2. Creating a sink composite curve using the required flowrate for each sink (Gj) and the calculated values of the maximum admissible loads (Uj), as shown in Fig.14.
Figure 14: Fresh Locus
S3
Source Composite
Curve
S2
Sink1
Sink2
Sink3
G1 G2 FlowrateFlowrateG3
U1
LoadLoad
U1 + U2
U1 + U2 + U3
SinkComposite
Curve
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
3. Evaluating the property operator of fresh (Ψfresh) using equation 9, then a locus of the fresh line is drawn starting from the origin with a slope of Ψfresh Fig.15.
Figure 15: Sink Composite Curve Based on Properties.
G1 G2 FlowrateFlowrateG3
U1
LoadLoad
U1 + U2
U1 + U2 + U3 SinkComposite
Curve
Fresh Line
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
4. Calculating the value of the property operator for each source (Ψi) and then ranking the sources in ascending order of (Ψi).
Ψ 1 <Ψ2 < …. < Ψ3.... <Ψi …. <Ψi NSources (12)
In addition, the property load of each source (Mi) is calculated using the next equation.
Mi = Fi * Ψ( pi ) (13)
Where Fi is the flowrate and Ψ( pi ) is the property operator for each source .
Material Recycle Pinch Diagram Based on Properties
5. Generating the source composite curve using the flowrate of each source and the calculated values of the property operator Ψi,, as seen in Fig. 16.
F1 FlowrateFlowrate
M1Lo
adL
oad
M1 + M2
Source1
Source2
F2
Source Composite
Curve
This curve starts with the source, which has the lowest property operator and the rest of the sources will be plotted in ascending order using superposition.
Figure 16: Sink Composite Curve Based on Properties
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
6. Placing both composite curves in the same diagram Fig. 17:
Figure 17: Sink and Source Composite Curves
G1 G2 FlowrateFlowrateG3
U1
LoadLoad
U1 + U2
U1 + U2 + U3 SinkComposite
Curve
Fresh Line
Source Composite
Curve
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
7. Locating the pinch point. The pinch point is found by placing the source composite curve onto the fresh line and then sliding it to the left until the source composite stream touches the sink composite stream. The point where both curves unite, is called the pinch point (Fig. 18).
Figure 18: Pinch Diagram
FlowrateFlowrate
LoadLoadProperty-BasedMaterial ReusePinch Point
SinkComposite
Curve
Source Composite
Curve
Fresh Line
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
7. Identifying the targets for Minimum Fresh Usage, Maximum Direct Recycle and Minimum Waste Discharge. Those targets are determined using the Material Recycle Pinch Diagram, as shown in Fig.19:
Figure 19: Pinch Diagram (Targeting)
FlowrateFlowrate
LoadLoad Property-BasedMaterial ReusePinch Point
SinkComposite
Curve
Source Composite
Curve
Fresh Line
MinimumMinimumFresh UsageFresh Usage
Maximum Maximum RecycleRecycle
Minimum Minimum WasteWaste
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Material Recycle Pinch Diagram Based on Properties
Design Rules:
The same three design rules explained in the Material RecyclePinch Diagram directly apply to the Material Recycle PinchDiagram Based on Properties, which are as follows:
1. No flowrate should be passed through the pinch.
2. No waste should be discharged from sources below the pinch.
3. No fresh resource should be used in any sink above the pinch.
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
TIER IICase Study
Suvit
Tapioca Starch Manufacturing
Case Study
1. Washing and peeling of the roots, rasping them and straining the pulp with addition of water.
2. Rapid removal of the fruit water and its soluble and replacing them with pure water to prevent deterioration of the pulp. This stage includes sedimentation and washing of the starch in tanks or settling tables.
3. The removal of water by draining, centrifuging and drying.
4. Grinding, bolting and other finishing operations.
Tapioca Starch is obtained from the processing of tuberous roots of the manioc or cassava plant. This process can be divided in four stages, which are:
Tapioca starch process is described in detailed in the following flowsheet Fig. 20.
Reference: Tia., Thongchai Srinophakun. Water-Waste Management of Tapioca Starch Manufacturing Using Optimization Technique. Science Asia, pp 57-67, February (2000)
Figure 20: Flowsheet for the Manufacturing of Tapioca Starch Plant.
Wash & Rasp
Grind
Screen 1
Screen 2
Separator 1
Screen 3
Separator 2
Fresh Roots32 ton/hr. (S=20.)
Clean Roots28 ton/hr. (S=22%)
Pulp100 ton/hr. (S=15%)
Starch Milk 114 ton/hr. (S=8%)
Starch Milk130 ton/hr. (S=7%)
Starch Milk130 ton/hr. (S=7%)
Starch Milk16 ton/hr. (S=33%)
Fiber21ton/hr. (S=15%)
Fiber28 ton/hr. (S=18%)
Water 160 ton/hr. (S=15%, COD=29)
Fiber41 ton/hr. (S=10%COD=205 )
Dewater
Final Screen
Press
Fiber21ton/hr. (S=15%) Water
38 ton/hr.
Wastewater 87 ton/hr.
Water 72 ton/hr. (S=0.06%, COD=29)
Water 86 ton/hr. (S=13%, COD=196)
Wastewater 75 ton/hr. (S=0.2%, COD=40)
Peels1.19 ton/hr.
(S=7.8%)
Fresh Water15 Ton/hr
Fresh Water25 Ton/hr
Fresh Water72 Ton/hr
Fresh Water8 Ton/hr
Fresh Water42 Ton/hr
Starch Milk15 ton/hr. (S=34%)Wastewater
5 ton/hr. (S=0.75%, COD=6.5)
DryingWater loss
0.31 ton/hr. (S=67%)Dry Starch 7.43 ton/hr. (S=67%)
Evaporated Water 4 ton/hr.
Wastewater 30 ton/hr. (S=0.07, COD=8)
Case StudyAs seen in Fig. 20, the processes of washing, rasping and grinding do not required the use of fresh water to operate because the water is used to wash the adhering dirt to the roots as they go through the mentioned processes. After that, the slurry is sent to the screening process in order to separate the fiber and other insoluble particles such as protein, fat, etc. Then the soluble particles are removed with water in the separating process.
On the other hand, the discharged water from screening and separating processes contain a high value of starch. Therefore, in order to recover this important component those streams are sent to the ‘final screen’. The stream resulting from the final screen process is rich with starch and is returned to the grinding process while the fiber is sent to the press process to recover water. Fresh pulp is sold as a cattle food.
Taking into account the information given for tapioca starch manufacturing process, determine the recycle strategies that minimize the usage of fresh water.
In order to solve the previously stated problem the next procedureis followed:
1. Identifying the sinks/process units which consume fresh water, and as we can see in Fig. 20 they are: Screen 1, Screen 2, Separator 1, Screen 3 and Separator 2.
2. Identifying the bounds in composition and flowrate for each one of the process units mentioned above. To determine these bounds a mathematical model was developed using the following assumptions:
Case StudySolution:
There are two main components in the manioc roots: starch and water. Only one single contaminant is considered: COD (Chemical Oxygen Demand) The composition of starch loss in drying is the same as they dry starch product.
As a result of the application of the mathematical model the following process constrains were determined (Table 1):
Case Study
Process Units
Flowrate Constrains
(Tons/hr)
Composition Constrains (Based on COD mg/l)
Screen 1 15≤ Flowrate of Feed to Screen 1 ≤ 20
0≤ Composition of COD in Feed to Screen 1 ≤ 5
Screen 2 25≤ Flowrate of Feed to Screen 2 ≤ 33
0≤ Composition of COD in Feed to Screen 2 ≤ 4
Separator 1 80≤ Flowrate of Feed to Separator 1 ≤ 72
0≤ Composition of COD in Feed to Separator 1 ≤ 0.00
Screen 3 8≤ Flowrate of Feed to Separator 1 ≤ 10
0≤ Composition of COD in Feed to Screen 3 ≤ 3.5
Separator 2 42≤ Flowrate of Feed to Separator 2 ≤ 50
0≤ Composition of COD in Feed to Separator 2 ≤ 0.00
Table 1: Process Constrains
Case Study3. Selecting the process streams (sources) that can be recycle
to the chosen process units. The criteria used to select the streams is based on the COD value, amount of starch and amount of protein. This criteria is applied to the four wastewater streams that are leaving the process as follows:
The stream leaving the washing and rasping units can not be reused in any unit due to its high content of COD.
The discharged water from Separator 1 can not be reused in any unit except in washing process since this water contains high protein.
The streams leaving the dewater and Separator 2 units can be consider for recycle.
Case Study4. Generating the Source-Sink Mapping Diagram Fig. 21:
30
50
60
70
80
40
15
10
0
20
1 2 3 4 5 6 7 8 9 10 11 12 13
8.0 Screen 3 (S4)
72
42
Screen 1 (S1)
Screen 2 (S2)
Separator 1 (S3)
Separator 2 (S4)
Separator 1 wastewater 1(R2)
Dewater wastewater (R1)
Flo
wra
te, t
ons/
hr
Concentration of Contaminant, mg/lt
Figure 21: Source-Sink Mapping Diagram for the Tapioca Starch Case Study
3.5
5.0
25
33
Case Study4. Applying Lever-Arm Rules.
30
50
60
70
80
40
15
10
0
20
8.0 Screen 3 (S4)
72
42
Flo
wra
te, t
ons/
hr
Concentration of Contaminant, mg/lt
3.5
5.0
For S1, R1 has the shortest water fresh arm
1 2 3 4 5 6 7 8 9 10 11 12 13
Screen 1 (S1)
Screen 2 (S2)
Separator 2 (S4)
Dewater wastewater (R1)
Separator 1 (S3)
Separator 1 wastewater 1(R2)
00.05.6
55.6
15
Sin er UsedFresh Wat 1
Fresh Water Used in S1 = 3.46 tons/hr
Flowrate to be recycled from R1 to S1 should be:
11 SRW 15 – 3.46 = 11.54 tons/hr
All of R1 is used in S1 (5 tons/hr)
Calculations for Screen 1
25
33
Case Study4. Applying Lever-Arm Rules.
30
50
60
70
80
40
15
10
0
20
Screen 3 (S4)
72
42
Flo
wra
te, t
ons/
hr
Concentration of Contaminant, mg/lt
3.5
For S2, After using all R1, R2 has the next shortest arm
1 2 3 4 5 6 7 8 9 10 11 12 13
Screen 1 (S1)
Screen 2 (S2)
Separator 2 (S4)
Dewater wastewater (R1)
Separator 1 (S3)
Separator 1 wastewater 1(R2)
Applying a water balance:
5.312 tons/hr
5*6.5 + *8 + Fresh Water in S1* 0.0
= 15*5
12 SRW
12 SRW
Fresh water in S1 = 15 – 5 – 5,312 = 4,68 ton/hr
Calculations for Screen 1 (continued)
25
33
8.05.0
Case Study4. Applying Lever Arm Rules.
30
50
60
70
80
40
15
10
0
20
72
42
Screen 3 (S4)
Flo
wra
te, t
ons/
hr
Concentration of Contaminant, mg/lt
3.51 2 3 4 5 6 7 8 9 10 11 12 13
Screen 1 (S1)
Screen 2 (S2)
Separator 2 (S4)
Dewater wastewater (R1)
Separator 1 (S3)
Separator 1 wastewater 1(R2)
Calculations for Screen 2
00.08
48
25
Sin er UsedFresh Wat 2
Flowrate to be recycled from R2 to S2 should be:
Fresh Water Used in S2 = 12.5 tons/hr
22 SRW 25 – 12.5 = 12.5 tons/hr
12.5 tons/hr of R2 are used in S2 33
25
8.05.0
Case Study4. Applying Lever Arm Rules.
30
50
60
70
80
40
15
10
0
20
Screen 3 (S4)
72
42
Flo
wra
te, t
ons/
hr
Concentration of Contaminant, mg/lt
3.51 2 3 4 5 6 7 8 9 10 11 12 13
Screen 1 (S1)
Screen 2 (S2)
Separator 2 (S4)
Dewater wastewater (R1)
Separator 1 (S3)
Separator 1 wastewater 1(R2)
Calculations for Screen 3
00.08
5.38
8
Sin er UsedFresh Wat 3
Flowrate to be recycled from R2 to S3 should be:
Fresh Water Used in S3 = 4.5 tons/hr
32 SRW 8 – 4.5 = 3.5 tons/hr
3.5 tons/hr of R2 are used in S3 8.7 tons/hr of R2 will go to waste since they can not be used in other sink,
33
25
8.05.0
Case Study4. Applying Lever Arm Rules.
Case StudyFor the process units Separator 1 and Separator 2 nothing can be done to reduce their consumption of fresh water since those sinks are not allowed to accept a feed flowrate with any concentration of contaminant.
Solution to the minimization of fresh water consumption
Screen 1
Screen 2
Screen 3
R1
5 tons/hr
30 tons/hrR2
5.312 tons/hr
12.5 tons/hr3.5 tons/hr
Waste8.7 tons/hr
Fresh Water21.7 tons/hr 4.68 t
ons/h
r
12.5 tons/h
r
4.5 tons/hr
Total Fresh Water Consumption = 21.7 + 72 + 42 = 135.7 tons/hr
Case Study4. Applying Lever Arm Rules.
Case StudyAlternate Solution:
Screen 1
Screen 3
R15 tons/hr
30 tons/hrR2
6.937 tons/hr
Waste8.7 tons/hr
Fresh Water21.7 tons/hr
The same target for minimum fresh usage is reached using a different recycle strategy.
5.06
3 to
ns/h
r
Screen 2
3 tons/hr
2 tons/hr
1.875 tons/hr4.125 tons/hr
12.5 tons/hr
12.5 tons/hr
Case Study4. Applying Lever Arm Rules.
Case StudyThe same problem is now solve using the Material-Recycle Pinch Diagram. The important data for sources and sinks are summarized in Tables 2 and 3.
Table 2 : Sources Data for the Tapioca Starch Case Study
Source Flowrate
(Tons/hr)
Inlet Composition (Based on COD mass
fraction)
Inlet
Load (Tons/hr)
R1
(Dewater 1)
5 0.065 0.325
R2
(Separator 1)
30 0.08 2.4
Case Study4. Applying Lever Arm Rules.
Case Study
Table 3 : Sink Data for the Tapioca Starch Case Study
Sinks Flowrate
(Tons/hr)
Maximum Inlet Composition (Based on
COD mass fraction)
Maximum Inlet
Load
(Tons/hr)
Separator 1 72 0 0
Separator 2 42 0 0
Screen 3 8 0.035 0.28
Screen 2 25 0.04 1.0
Screen1 15 0.05 0.75
Case Study4. Applying Lever Arm Rules.
Case StudyUsing the data given in the Tables 2 and 3, the sink and source composite curve are constructed as shown in Figures 22 and 23:
Figure 22: Source Composite Curve for the Tapioca Starch Case Study
Loa
d, t
ons/
hr
Flowrate, tons/hr
0.5
1
1.5
2.0
2.5
0 10 20 30 40 50 60 70 80
0.325
35
2.725
3.0
12010090 130 140 150 1605 170
Dewater
Separator 1
Source Composite
Curve
Dewater
Case Study4. Applying Lever Arm Rules.
Case StudyFigure 23: Sink Composite Curve for the Tapioca Starch Case Study
Loa
d, t
ons/
hr
Flowrate, tons/hr
0.5
1
1.5
2.0
2.5
0 10 20 30 40 50 60 70 80
0.28
42
3.0
12010090 130 140 150 160
1.28
147114
2.03
122170
162
Separator 2 Separator 1 Screen 3
Screen 1
Screen 2
SinkComposite
Curve
Case Study4. Applying Lever Arm Rules.
Case StudyL
oad
, ton
s/h
r
Flowrate, tons/hr
0.5
1
1.5
2.0
2.5
0 10 20 30 40 50 60 70 80
3.0
12010090 130 140 150 160
Next, both curves are placed in the same diagram and the source composite curve is slid horizontally to the right until it touches the sink composite curve as shown in Fig. 24:
Figure 24: Material Recycle Pinch Diagram for the Tapioca Starch Case Study
Fresh Water = 135.7
Material Recycle Material Recycle Pinch PointPinch Point
Waste = 8.7
170 180
SinkComposite
Curve
Source Composite
Curve
135.7 170.7162
Case Study4. Applying Lever Arm Rules.
Case StudyAs demonstrated by applying Direct Recycle Strategy, the maximum consumption of fresh water reduction that can be reached without the use of new equipment is from 162 tons/hr to 135.7 tons/hr. The same targeted value was reached by using the Material Recycle Pinch Diagram and Direct Recycle Strategy.
Case Study4. Applying Lever Arm Rules.
TIER IIIOpen Ended Problem
Case Study4. Applying Lever Arm Rules.
Open Ended ProblemProblem Statement: Consider the metal degreasing process shown in Fig.25:Figure 25: Microelectronics Manufacturing Flowsheet
Thermal Processing,Solvent Regeneration
& makeupT = 515 K
DegreaserMetal
Finishing
Absorber
To Flare
To Flare
OrganicAdditives
FreshSolvent
Degreased Metal
AbsorberBottoms(to boiler fuel)
Condensate II(to waste disposal)3.0 kg/s
5.0 kg/s
2.0 kg/s
Metal
Regenerated Solvent
Offgas
Condensate I(to waste disposal)4.0 kg/s
Reference: Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
Case Study4. Applying Lever Arm Rules.
Open Ended ProblemIn this process, a fresh organic solvent is used in the degreaser and the absorber. A reactive thermal processing and solvent regeneration system is used to decompose the grease and the organic additives and regenerate the solvent from the degreaser.
The liquid product of the solvent regeneration system is reused in the degreaser, while the gaseous product is passed through a condenser, an absorber and a flare. The process produces two condensate streams: Condensate I from the solvent regeneration unit and Condensate II from degreaser. The two streams are currently sent to hazardous waste disposal.
Since these two streams have many desirable properties that enable their possible use in the process, it is recommended their recycle/reuse to be considered. The absorber and the degreaser are the two process sinks. The two process sources satisfy many properties required for the feed of two sinks. An additional property should be examined; namely Reid Vapor Pressure (RVP), which is important in characterizing the volatility, makeup and regeneration of the solvent.
Case Study4. Applying Lever Arm Rules.
Open Ended Problem
The mixing rule for vapor pressure (RVP) is giving by the following expression:
sN
iii RVPxRVP
1
44.144.1
The pertinent information regarding the sinks in study can be seen in Table 5.
Table 5 : Flow Rates and Bounds on Properties of Sinks
Sink Flowrate
(kg/s)
Lower Bound on RVP (atm)
Upper Bound on RVP (atm)
Degreaser 5.0 2.0 3.0
Absorber 2.0 2.0 4.0
4. Applying Lever Arm Rules. Open Ended Problem
The RVP for Condensate I is a function of the thermal regeneration temperature as follows:
RVPCondensate I =
175
100
56.0T
e
Where RVP Condensate I is the RVP of Condensate I in atm and T is the temperature of thermal processing system in K. The acceptable range of this temperature is 430 to 520 K. At present, the thermal processing system operates at 515 K leading to an RVP of 6.0. The data for Condensate I and Condensate II are given in Table 6.
4. Applying Lever Arm Rules. Open Ended Problem
Table 6 : Properties of Process Sources and Fresh
Sources Flowrate (kg/s) RVP (atm)
Process Condensate I 4.0 6.0
Process Condensate II 3.0 2.5
Fresh Solvent To be determined 2.0
Using Direct Recycle Strategies, identify the target for minimum usage of fresh solvent and minimum waste discharge for this case study.
4. Applying Lever Arm Rules. END OF TIER III
CONGRATULATIONS
This is the end of Module 18.
Please submit your report to your professor for grading.
4. Applying Lever Arm Rules. REFERENCES
El-Halwagi, M.M. Pollution Prevention through Process Integration. Acadamic Press. 1997
Suvit Tia., Thongchai Srinophakun. Water-Waste Management of Tapioca Starch Manufacturing Using Optimization Technique. Science Asia, pp 57-67, February (2000)
Kazantzi, V. and M. M. El-Halwagi, “Targeting Material Reuse via Property Integration”, Chem. Eng. Prog., 101(8) 28-37(2005)
El-Halwagi, M. M., F. Gabriel, and D. Harell, “Rigorous Graphical Targeting for Resource Conservation via Material Recycle/Reuse Networks”, Ind. Eng. Chem. Res., 42, 4319-4328 (2003)