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New Insights into the Atmospheric Chemistry of Venus from
Venus Express
Yuk L. Yung
Caltech
GISS Seminar, Mar 24 2012
Earth VenusSurface P, bar 1 90Surface T, °C +15 +460
Composition , %N2
O2
Atmospheric H2O Total H2O, cm
CO2
SO2
Clouds
0.780.21< 0.03~3×105
0.0003~10-9
H2O
0.035~ 00.00005~30.965~10-4
H2SO4 + ? (Sx, FeCl3…)
Different Twins
“Firsts” by Venus Express (1)• First global monitoring of the composition of the lower atmosphere in the near IR spectral windows
from orbit;– This has been done very well by VIRTIS. Abundance of CO, SO2, COS, H2O at ~35 km and H2O at the
surface at all latitudes. Indeed pioneering results. • First coherent study of the atmospheric temperature and dynamics at different levels of the atmosphere
up to the top of the cloud layer;– We have now a survey of temperature structures in the 40-120 km altitude range. From this the
thermal wind field in 50-80km range has been derived. This is complemented by direct wind tracking (clouds) at 70 km, ~60 km, and 50 km.
• First measurements of global surface temperature distribution from orbit;– VIRTIS has almost completely covered the Southern hemisphere. VMC is building surface maps from
~20 S to ~50 N.• First study of the middle and upper atmosphere dynamics from O2, O, and NO emissions;
– These emissions originating around the mesopause (~90-110 km) have been observed and mapped. The regions of maximum brightness of NO and O2 airglow are slightly displaced, leading to new insights to the dynamics in this region.
Svedhem
“Firsts” by Venus Express (2) • First measurements of the non-thermal atmospheric escape
– Great results from ASPERA: escape of O+, H+, and He++ ions is measured as well as spatial distribution of fluxes. The escape of O and H corresponds to water.
• First coherent observations of Venus in the spectral range from UV to thermal infrared;– Accomplished, but thermal range is limited to λ< 5 µm due to the non operational PFS.
• First application of the solar/stellar occultation technique at Venus;– Yes, the technique implemented by SOIR and SPICAV has proven to be extremely effective in sounding
the mesosphere (70-120 km).• Firsts use of 3D ion mass analyzer, high energy resolution electron spectrometer, and energetic neutral
atom imager;– Very good results on characterization of the plasma environment. Comparative studies with both
ASPERA-3 on MEX and ASPERA-4 on VEX.• First complete monitoring of the electromagnetic environment of the planet.
– MAG is providing excellent data on the structure and variability of the induced magnetosphere as well as on lightning. Particularly impressive as VEX has only one field instrument
Svedhem
Global Circulation Regimes
Troposphere• Zonal superrotation (>100
m/s)• Poleward winds v ~ 10 m/s
Thermosphere• Zonal superrotation (~100
m/s) • Solar-antisolar circulation
(~200 m/s)
Titov et al., 2009
• A sulfur source is required to explain the SO2 inversion layer above 80 km.
• The evaporation of the aerosols composed of sulfuric acid or polysulfur above 90 km could provide the sulfur source.
• Measurements of SO3 and SO (a1∆→X3∑) emission at 1.7 μm may be the key to distinguish between the two models.
Summary
Conclusions (1)
• Recent observations of enhanced amounts of SO2 at 100 km by Venus Express suggest a hitherto unknown source of gaseous sulfur species in the upper atmosphere of Venus. Highly variable correlated with temperature.
• The photolysis of H2SO4 vapor derived from evaporation of H2SO4 aerosols provides a source of SO3, which upon photolysis yields SO2.
• The predicted concentrations of SO and SO3 could be detected by future measurements.
Conclusions (2)
• More experimental work is needed to investigate the molecular dynamics of the photolysis of H2SO4 and its hydrates, as well as the saturation vapor pressure of H2SO4 in the low temperature range (150-300 K).
• A more detailed microphysical aerosol coupled photochemical model is needed.
• The proposed mechanism may play an important role in the recycling of H2SO4 in the terrestrial stratosphere, where the Junge layer (composed of H2SO4 aerosols) is a regulator of climate and the abundance of O3.
Novel Chemistry
• SO3 + CO → CO2 + SO2
• SO3 + OCS → CO2 + (SO)2
• (SO)2 + OCS → CO + S2 + SO2
• CO + (1/n)Sn → OCS
• OCS + S → CO + S2
• Krasnopolsky, Pollack, Fegley, Yung
Carlson, R. W. Venus' Ultraviolet Absorber and Sulfuric Acid Droplets.International Venus Conference, Aussois, France, 44 (2010).
Conclusions
Novel Chemistry of OCS and CO via polysulfur photochemistry for converting CO to OCS
Integrated destruction rate of OCS is 23,000 Tg-S/yr [Earth Pinatubo = 10 Tg-S/yr]
Flux ~ 1012 cm-2s-1
Comparable production and flux for CO
Long term evolution of SO2
1970 1975 1980 1985 1990 1995 2000 2005
101
102
103
SO2 vs. Time
Anderson et al.Owen&Sagan
Balloon
Venera 15
HSTRocket
IUE
PV
SOIR (68 km)SOIR (70 km)
SPICAV UV(at 100 km)
SO
2 a
bu
nd
ance
at
leve
l 40
mb
ar (
~69
km
), p
pb
upper limit
YEAR
SPICAV UV NADIR(~70 km)
• Co-authors: Liang, M. C., Mills, F. P., Belyaev, D. A., Arthur Zhang
• Marcq, E., Parkinson, C., Bougher, S., Brecht, A., Ingersoll, A., Yang, D., Zeng, R., Gerstell, M., Line, M.
• NASA Grant • Venus Express Project
Acknowledgement