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New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory,...

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New Neutron Absorbers Absorbers Industry Meeting with NRC Neutron Absorber Material Degradation October 4 2012
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Page 1: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

New

Neu

tron

Abs

orbe

rsA

bsor

bers

Indu

stry

Mee

ting

with

NR

CN

eutro

n A

bsor

ber M

ater

ial D

egra

datio

n

Oct

ober

4 2

012

Page 2: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Neu

tron

Abs

orbe

rsin

US

Spen

tFue

lPoo

lsN

eutr

on A

bsor

bers

in U

S Sp

ent F

uel P

ools

Supp

lier

Prod

uctN

ame

Mat

rixA

bsor

ber

Supp

lier

Prod

uct N

ame

Mat

rixA

bsor

ber

BIS

CO

*B

oraf

lex

Pol

y D

imet

hyl

Silo

xane

Bor

on

Cer

adyn

e/A

AR

*B

oral

Al1

100

Allo

yB

oron

Cer

adyn

e/A

AR

Bor

alA

l 110

0 A

lloy

Bor

onH

olte

c/M

etam

icLL

C*

Met

amic

Al 6

061

Allo

yB

oron

HLE

RB

lh

Nt

it30

4S

ti

lB

HLE

R B

lech

e N

eutro

nit

304

Sta

inle

ss

Bor

onC

arpe

nter

Neu

troS

orb

AS

TM A

887

Bor

onC

arbo

rund

um C

o.*

Cab

orun

dum

Phe

nolic

Res

inB

oron

ES

K*

Tetra

bor

Phe

nolic

Res

inB

oron

Alc

anW

1100

N.X

XB

Al 6

351

Allo

yB

oron

*For

mer

Sup

plie

r/Out

of B

usin

ess

Page 3: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Cha

nge

inA

bsor

berM

arke

tC

hang

e in

Abs

orbe

r Mar

ket

Av

aila

ble

neut

ron

abso

rber

sfo

rspe

ntfu

elpo

olar

eal

mos

t

Avai

labl

e ne

utro

n ab

sorb

ers

for s

pent

fuel

poo

l are

alm

ost

excl

usiv

ely

Alu

min

um a

nd S

tain

less

Ste

el b

ased

m

ater

ials

N

o po

lym

er o

r res

in b

ased

neu

tron

abso

rber

mat

eria

l cu

rrent

ly b

eing

mar

kete

d fo

r spe

nt fu

el p

ool u

se

Sta

inle

ssS

teel

base

dm

ater

ials

use

boro

nan

d/or

S

tain

less

Ste

el b

ased

mat

eria

ls u

se b

oron

and

/or

gado

linia

as th

e ne

utro

n ab

sorb

er

Alu

min

um b

ased

mat

eria

ls u

se b

oron

as

the

neut

ron

abso

rber

Page 4: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Neu

tron

Abs

orbe

rsAv

aila

ble

forS

FPo

ols

Neu

tron

Abs

orbe

rs A

vaila

ble

for S

F Po

ols

Supp

lier

Prod

uctN

ame

Mat

rixA

bsor

ber

Stai

nles

s St

eel B

ased

Mat

eria

ls

Supp

lier

Prod

uct N

ame

Mat

rixA

bsor

ber

Car

pent

er??

????

?S

tain

less

Ste

elB

oron

, Gad

olin

iaB

ÖH

LER

Ble

che

Neu

troni

tS

tain

less

Ste

elB

oron

Car

pent

erN

eutro

Sor

bS

tain

less

Ste

elB

oron

AT

I Nuc

lear

Ene

rgy

NU

SH

IELD

Sta

inle

ss S

teel

Bor

on

Page 5: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Neu

tron

Abs

orbe

rs A

vaila

ble

for S

F Po

ols

Alu

min

umB

ased

Mat

eria

lsA

lum

inum

Bas

ed M

ater

ials

Supp

lier

Prod

uct N

ame

Mat

rixA

bsor

ber

Cer

adyn

eB

OR

AL

Al1

100

Allo

yB

oron

Cer

adyn

eB

OR

AL

Al 1

100

Allo

yB

oron

Cer

adyn

eB

OR

TEC

Al 1

100,

609

0 A

lloy

Bor

on

Hol

tec

Met

amic

Al6

061

Allo

yB

oron

Hol

tec

Met

amic

Al 6

061

Allo

yB

oron

Alu

min

um C

ore

Tech

nolo

gyM

AX

US

1070

Al c

ore

5052

Al A

lloy

clad

Bor

on

Talo

nC

ompo

site

sTa

lbor

Al6

061

Allo

yB

oron

Talo

n C

ompo

site

sTa

lbor

Al 6

061

Allo

yB

oron

Alc

anW

1100

N.X

XB

Al 6

351

Allo

yB

oron

Page 6: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Neu

tron

Abs

orbi

ngFe

-Bas

eA

lloy

Neu

tron

Abs

orbi

ng F

eB

ase

Allo

y

C

arpe

nter

Tech

nolo

gyC

orpo

ratio

n

Bor

on, G

adol

inia

Stai

nles

s St

eel

C

arpe

nter

Tec

hnol

ogy

Cor

pora

tion

W

yom

issi

ng, P

A

w

ww

.car

tech

.com

/ssa

lloys

prod

–N

o da

ta o

n th

is p

rodu

ct

A

uste

nitic

pow

der m

etal

lurg

y

A

tlea

st0

25w

t%bo

ron

A

t lea

st 0

.25

wt.%

bor

on

A

t lea

st 0

.05

wt.%

gad

olin

ia

Av

aila

ble

assh

eeto

rpla

teAv

aila

ble

as s

heet

or p

late

P

rodu

ct is

in d

evel

opm

ent

Page 7: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Neu

tron

it®N

eutr

onit

B

ÖH

LER

Ble

che

Gm

bH&

Co

KG

Bor

ated

Sta

inle

ss S

teel

B

ÖH

LER

Ble

che

Gm

bH &

Co

KG

M

ürzz

usch

lag,

AU

STR

IA

w

ww

.boh

ler-

blec

he.c

om/e

nglis

h/sp

ecia

l_al

loys

A

STM

-A88

7 A

lloy

B

oron

cont

entu

pto

19

wt%

B

oron

con

tent

up

to 1

.9 w

t.%

Av

aila

ble

as p

late

, she

et o

r stri

p

In

ser

vice

at G

inna

Neu

troni

tA 9

78 w

/1%

Bor

on

C

orro

sion

per

form

ance

test

ing

data

Ref

. 1

Page 8: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Neu

troS

orb

PLU

S®N

eutr

oSor

bPL

US

C

arpe

nter

Tech

nolo

gy

Bor

ated

Sta

inle

ss S

teel

C

arpe

nter

Tec

hnol

ogy

Cor

pora

tion

W

yom

issi

ng, P

A

w

ww

.car

tech

.com

/ssa

lloys

prod

A

STM

A88

7-89

Gra

de A

Allo

y

B

oron

cont

entu

pto

25

wt%

B

oron

con

tent

up

to 2

.5 w

t.%

Av

aila

ble

as s

heet

or p

late

In

use

at t

he U

S M

OX

faci

lity

Neu

troS

orb

Plu

s 1.

17 w

t.% b

oron

y

In

use

in U

S c

omm

erci

al re

acto

r sp

ent f

uel p

ools

C

orro

sion

perfo

rman

cete

stin

g

Cor

rosi

on p

erfo

rman

ce te

stin

g da

ta –

Ref

. 1

Page 9: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

NU

SHIE

LD™

NU

SHIE

LD

A

llegh

eny

Tech

nolo

gies

Inco

rpor

ated

Bor

ated

Sta

inle

ss S

teel

A

llegh

eny

Tech

nolo

gies

Inco

rpor

ated

P

ittsb

urgh

, PA

w

ww

.ATI

met

als.

com

30

4 S

tain

less

Ste

el M

atrix

B

oron

con

tent

1.7

5-2.

25 w

/oFi

ldi

dh

bid

–Fi

nely

dis

pers

ed c

hrom

e-bo

rides

Av

aila

ble

as s

heet

or p

late

In

use

atth

eU

SM

OX

faci

lity

In u

se a

t the

US

MO

X fa

cilit

y

N

ot in

ser

vice

in U

S c

omm

erci

al re

acto

r sp

ent f

uel p

ools

Ci

ft

tid

t

Cor

rosi

on p

erfo

rman

ce te

stin

g da

ta –

Ref

. 2

Page 10: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

BO

RA

L®B

OR

AL

C

erad

yne,

Inc.

Alu

min

um B

oron

Car

bide

Cer

met

y,

Q

uebe

c, C

anad

a

w

ww

.cer

adyn

ebor

on.c

om/p

rodu

cts

11

00 A

lum

inum

Allo

y C

lad

A

lum

inum

, Bor

on C

arbi

de C

ore

BC

tt

t67

l%i

th

B4C

con

tent

up

to 6

7 vo

l.% in

the

core

Av

aila

ble

as s

heet

N

otin

serv

ice

inU

Sco

mm

erci

alN

ot in

ser

vice

in U

S c

omm

erci

al

reac

tor s

pent

fuel

poo

ls

C

orro

sion

per

form

ance

test

ing

data

–R

ef3

Ref

. 3–

EP

RI L

ong

Term

Cor

rosi

on P

erfo

rman

ce

Test

Page 11: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

BO

RTE

BO

RTE

C

C

erad

yne

Inc

Alu

min

um M

etal

Mat

rix C

ompo

site

C

erad

yne,

Inc.

Q

uebe

c, C

anad

a

w

ww

.cer

adyn

ebor

on.c

om/p

rodu

cts

10

00, 5

000

& 6

000

Alu

min

um A

lloy

Mat

rix

B

Cco

nten

tup

to45

vol%

B

4C c

onte

nt u

p to

45

vol.%

Av

aila

ble

as b

illet o

r she

et

N

ot in

ser

vice

in U

S c

omm

erci

al

reac

tor s

pent

fuel

poo

ls

C

orro

sion

per

form

ance

test

ing

data

–R

ef. 3

Page 12: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Met

amic

®M

etam

ic

H

olte

cIn

tern

atio

nal

Alu

min

um M

etal

Mat

rix C

ompo

site

–M

arlto

n, N

J

M

etam

icLL

CL

kl

dFL

–La

kela

nd, F

L

w

ww

.met

amic

.com

60

61 A

lum

inum

Allo

y M

atrix

606

uu

oyat

B

oron

con

tent

up

to 3

3 w

t.%

Av

aila

ble

as e

xtru

sion

, she

et,

fi

dd

forg

ings

and

dra

wn

In

use

in U

S c

omm

erci

al re

acto

r sp

ent f

uel p

ools

6061

+21%

Bor

on C

arbi

de

C

orro

sion

per

form

ance

test

ing

data

–R

ef. 3

Page 13: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

MA

XUS™

MA

XUS

A

lum

inum

Cor

e Te

chno

logy

C

lad

Met

al M

atrix

Com

posi

teH

ybrid

Alu

min

um M

etal

Mat

rix C

ompo

site

To

kyo,

Jap

an

w

ww

.nlm

etal

.com

/sol

utio

ns

–A

lum

inum

Cor

e –

5052

Alu

min

um A

lloy

Cla

d

N

ot in

ser

vice

in U

S c

omm

erci

al

B

4C in

cor

e 21

-40

wt.%

Av

aila

ble

as s

heet

reac

tor s

pent

fuel

poo

ls

80

00 h

our a

ccel

erat

ed

corr

osio

n te

st (p

ropr

ieta

ry)

(pp

y)

B4C

Aluminum

×100

×400

50μm

10μm

Page 14: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Talb

or®

Talb

or

Ta

lon

Com

posi

tes

LLC

Alu

min

um M

etal

Mat

rix C

ompo

site

Ta

lon

Com

posi

tes,

LLC

S

an J

uan

Cap

istra

no, C

A

w

ww

.talo

ncom

posi

tes.

com

Av

aila

ble

as 1

100

or 6

092

Alu

min

um

Allo

y M

atrix

for n

ucle

ar a

pplic

atio

ns

B

C1

40vo

l%

B4C

1-4

0 vo

l.%–

29.2

wt.%

B4C

@ 2

00x

Av

aila

ble

as s

heet

, ext

rude

d cr

oss

tilli

&f

ibl

kse

ctio

ns, r

ollin

g &

forg

ing

blan

ks

N

ot in

ser

vice

in U

S c

omm

erci

al

spen

t fue

l poo

ls

C

orro

sion

test

ing

to s

uppo

rt dr

y st

orag

e ap

plic

atio

n –

Ref

. 3

Page 15: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

W11

0NXX

BW

110N

.XXB

R

io T

into

Alc

an

Alu

min

um M

etal

Mat

rix C

ompo

site

Q

uebe

c, C

anad

a

w

ww

.rtap

ublic

sale

s.rio

tinto

.com

A

lum

inum

110

0 A

lloy

Mat

rix

B

oron

con

tent

Fo

rUS

spen

tfue

lpoo

lapp

licat

ions

:–

For U

S s

pent

fuel

poo

l app

licat

ions

: 16

-40

vol.%

Av

aila

ble

as b

illet o

r she

et

ItL

Sll

Uit

2

In u

se a

t LaS

alle

Uni

t 2 a

s S

NA

P-IN

®sp

ent f

uel p

ool i

nser

ts

C

orro

sion

per

form

ance

test

ing

dt

Rf

4da

ta –

Ref

. 4–

Sub

mitt

ed a

s pa

rt of

LaS

alle

& P

each

B

otto

m L

AR

Page 16: New Neutron AbsorbersAbsorber Materials,” Lister, T., et al, May 2007, Idaho National Laboratory, INL/EXT-06-11772, Rev. 1 2. “ATI 304B7 P/M™ Alloy Technical Data Sheet,” ATI

Cor

rosi

onPe

rfor

man

ceR

efer

ence

sC

orro

sion

Per

form

ance

Ref

eren

ces

1“E

lect

roch

emic

alC

orro

sion

Test

ing

ofN

eutro

nA

bsor

ber

Ope

n Li

tera

ture

1.E

lect

roch

emic

al C

orro

sion

Tes

ting

of N

eutro

n A

bsor

ber

Mat

eria

ls,”

List

er, T

., et

al,

May

200

7, Id

aho

Nat

iona

l La

bora

tory

, IN

L/E

XT-

06-1

1772

, Rev

. 12.

“ATI

304

B7

P/M

™ A

lloy

Tech

nica

l Dat

a S

heet

,” AT

I N

ucle

ar E

nerg

y, 1

2/2/

113

“Han

dboo

kof

Neu

tron

Abs

orbe

rMat

eria

lsfo

rSpe

nt3.

Han

dboo

k of

Neu

tron

Abs

orbe

r Mat

eria

ls fo

r Spe

nt

Nuc

lear

Fue

l Tra

nspo

rtatio

n an

d S

tora

ge A

pplic

atio

ns,

2009

Edi

tion,

” EP

RI,

TR 1

0191

10, N

ovem

ber 2

009

4.“M

ater

ial Q

ualif

icat

ion

of A

lcan

Com

posi

te fo

r Spe

nt

Fuel

Sto

rage

,” N

orth

east

Tec

hnol

ogy

Cor

p., N

ET-

259-

03, R

ev. 5

, Aug

ust 2

008


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