Norwater AS Safety Datasheets

35727 Date of issue: 2012.02.13NW Clean A

SAFETY DATA SHEET

NW Clean A

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

Product name NW Clean A

Applications For cleaning of components in drinking water systems.

Supplier Ambio Ingeniørtjenester AS

Godesetdalen 10, 4034 Stavanger

Norway

Tel: +47 51446400

Fax: +47 51446401

[email protected]

http://www.ambio.no

Contact person Bjørn Pedersen (E-mail: [email protected])

Emergency telephone number 112 / National Poisons Information Service (NPIS), phone 0844 892 0111. WEB:

http://www.toxbase.org

2. HAZARDS IDENTIFICATION

Symbol(s)

Contains sodium hydrogensulphite

propylene glycol

Risk phrases R-22 Harmful if swallowed.

R-31 Contact with acids liberates toxic gas.

Safety phrases S-25 Avoid contact with eyes.

S-45 In case of accident or if you feel unwell, seek medical advice immediately (show

the label where possible).

S-46 If swallowed seek medical advice immediately and show this container or label.

S-50 Do not mix with acids.

CLP

Hazard pictograms

1 / 5 Created by SafeProduction™ESSENTICON

http://www.essenticon.com


terese

Stamp


Signal word Warning

Hazard statements Acute Tox. 4: H302 Harmful if swallowed.

EUH031 Contact with acids liberates toxic gas.

Precautionary statements P262 Do not get in eyes, on skin, or on clothing.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or

doctor/physician.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P501 Dispose contents/container in accordance to local regulations.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients

Name EC No. CAS No. Content Symbol Classification

sodium hydrogensulphite 231-548-0 7631-90-5 2,5-40 % Xn R-22, R-31

propylene glycol 200-338-0 57-55-6 0-94 % -

CLP

Name CAS No. REACH No. Content Symbol Classification

sodium hydrogensulphite 7631-90-5 2,5-40 % GHS07, ,

Warning

Acute Tox. 4: H302,

EUH031

propylene glycol 57-55-6 0-94 %

Section 16 contains detailed classification phrases.

Composition comments Typical specification:

Sulphur dioxide SO2 mg/l 23,4-24,6

Arsene As ppm <1

Lead Pb ppm <5

Mercury Hg ppm <1

Cadmium Cd ppm <1

Krom Cr ppm <1

Copper Cu ppm <5

Iron Fe pm <5

Manganese Mn ppm <5

4. FIRST AID MEASURES

General Remove victim immediately from source of exposure. General first aid, rest, warmth

and fresh air. Secure open airways. If breathing stops, provide artificial respiration.

Inhalation Provide rest, warmth and fresh air. Get medical attention if any discomfort continues.

Ingestion Rinse nose, mouth and throat with water. Provide rest, warmth and fresh air. Contact

physician if larger quantity has been consumed.

Skin Wash skin with soap and water. Remove contaminated clothing. Get medical attention

if irritation persists after washing.

Eyes Immediately flush with plenty of water for up to 15 minutes. Remove any contact

lenses and open eyes wide apart. Get medical attention if any discomfort continues.

5. FIRE-FIGHTING MEASURES

Extinguishing media Water spray, fog or mist. Powder, foam or CO2. Do not use direct water flow, risk for

spreading the fire.

Special fire fighting procedures Move container from fire area if it can be done without risk.

Specific hazards Not flammable according to national regulations concerning flammable goods.

Hazardous combustion products Fire or high temperatures create: Sulphurous gases (SOx). Carbon monoxide (CO).

Carbon dioxide (CO2).





Protective measures in fire Wear self-contained breathing apparatus (SCBA) to prevent contact with thermal

decomposition products.

6. ACCIDENTAL RELEASE MEASURES

Personal protection Wear appropriate personal protective equipment - see Section 8. Avoid inhalation of

vapours and spray mist and contact with skin and eyes. Provide adequate ventilation.

Environmental protection Prevent liquid entering sewers, basements and work pits.

Spill cleanup methods Limit spread of spilled material. Absorb with sand, earth or an inert material. Collect

and reclaim or dispose in sealed containers in licensed waste. Waste treated in

accordance with section 13.

7. HANDLING AND STORAGE

Usage precautions Wear appropriate personal protective equipment - see Section 8. Avoid spilling, skin

and eye contact. Provide good ventilation. Eye wash station should be available at the

work place.

Storage precautions Keep in cool, dry, ventilated storage and closed containers. Keep in original container.

Avoid heating and sunlight. Store separated from: Acids. Oxidising material.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredient name CAS no. Reference LT Exp 8 Hrs ST Exp 15 Min Date

sodium hydrogensulphite 7631-90-5 WEL. 5 mg/m3

propylene glycol 57-55-6 WEL. 150 ppm No std.

Ingredient comments WEL = Workplace exposure limits. SK= Skin absorbance, Rep= Reproduction, Carc=

Carcinogenic Senz= Sensitisers, Mut= Carcinogenic

Protective equipment

Process conditions An eye wash bottle must be available at the work site.

Ventilation Provide adequate general and local exhaust ventilation.

Respirators If ventilation is insufficient, suitable respiratory protection must be provided. Gas

cartridge (acid gases). At work in confined or poorly ventilated spaces, respiratory

protection with air supply must be used.

Protective gloves Protective gloves must be used if there is a risk of direct contact or splash.

Use protective gloves made of: Butyl rubber. Break through time: 4 - 8 hours.

Eye protection Wear approved safety goggles.

Other Protection Protective clothing as needed.

Hygienic work practices Wash at the end of each work shift and before eating, smoking and using the toilet.

Promptly remove non-impervious clothing that becomes wet or contaminated.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Liquid.

Colour Clear. Light yellow.

Odour Sulphur.

Physical data comments Freeze point values:

Temp. Density g/cm3

0 °C 1,35





-5°C 1,05

-10 °C 1,03

-15 °C 1,03

-20 °C 1,02

The content of propylene glycol should be adjusted according to the exposure

temperature. The content of sodium bisulfite and water will vary as a function of the

propylene glycol addition.

Solubility description Very soluble in water.

Boiling point (°C, interval) ~98 Pressure

Melting/freezing point (°C, interval) <2

Vapour pressure ~27 mbar Temperature (°C) 20

pH-value, conc. solution 3,7 - 4,5

Viscosity (interval) ~4 mPas Temperature (°C) 20

10. STABILITY AND REACTIVITY

Stability Stable when used at recommended storage and handling conditions.

Conditions to avoid Generates toxic gas in contact with acid. Avoid exposure to high temperatures or direct

sunlight.

Hazardous polymerisation Will not polymerise.

Materials to avoid Acids. Oxidising substance.

Hazardous decomp. products No specific hazardous decomposition products noted.

11. TOXICOLOGICAL INFORMATION

Sensitization No allergic reaction is known.

Genotoxicity No known heritable or mutagenic effects.

Carcinogenicity This substance has no evidence of carcinogenic properties.

Reproduction toxicity No known hazardous effects on reproduction, fertility or to the unborn child.

Inhalation Gas or vapour in high concentrations may irritate respiratory system.

Ingestion Harmful if swallowed. Reaction with gastric acid releases sulphur dioxide, which may

give severe lung injury.

Skin May cause irritation.

Eyes May cause irritation to eyes.

Route of entry Skin and/or eye contact. Ingestion.

COMPONENT: sodium hydrogensulphite

Toxic dose - LD50: 1420 mg/kg (oral rat)

COMPONENT: propylene glycol


Toxic dose - LD50 (skin): 20800 mg/kg (skin rabbit)

12. ECOLOGICAL INFORMATION

Ecotoxicity Not regarded as dangerous to the environment. This does not, however, rule out the

possibility that large or frequent smaller emissions of the product may be harmful to

the environment.

Mobility The product is soluble in water. High mobility in soil and water.

Bioaccumulative potential The product is not bioaccumulating.

Persistence and degradability The product is biodegradable.

Other adverse effects Results of PBT and vPvB assessment: No data available.





COMPONENT: sodium hydrogensulphite

LC 50, 96 Hrs, Fish mg/l: 240 (Gambusia affinis)

EC 50, 48 Hrs, Daphnia, mg/l: 119 (Daphnia magna)

Component will not bio-accumulate.Bioaccumulative potential

COMPONENT: propylene glycol

LC 50, 96 Hrs, Fish mg/l: 45760 (Oncorhynchus mykiss)

EC 50, 48 Hrs, Daphnia, mg/l: 34400 (Daphnia magna)

IC 50, 72 Hrs, Algae, mg/l: 19000

BCF: 3Bioaccumulative potential

-0,30Partition coefficient (log Pow)

BOD5/COD:

70 % deg., Method: BOD5

Persistence and degradability

13. DISPOSAL CONSIDERATIONS

General/cleaning Waste is classified as hazardous waste.

Disposal methods Confirm disposal procedures with environmental engineer and local regulations.

Equipment and facilities to be cleaned using mild detergent.

Waste class 16 05 07* discarded inorganic chemicals consisting of or containing dangerous

substances

14. TRANSPORT INFORMATION

General No dangerous goods (ADR/RID, IMDG, IATA/ICAO)

15. REGULATORY INFORMATION

EU directives Regulation 1907/2006/EC (REACH), 1272/2008/EC (CLP), 790/2009/EC,

453/2010/EC. Workplace exposure limits (WEL), UK.

16. OTHER INFORMATION

Explanations to R-phrases in section 3 R-22 Harmful if swallowed.

R-31 Contact with acids liberates toxic gas.

Explanations to classification in section

3

EUH031 Contact with acids liberates toxic gas.

H302 Harmful if swallowed.

* Information revised since the previous version of the SDS

Issued by Essenticon AS, Leif Weldingsvei 10, N-3208 Sandefjord, Norge. Tlf.: +47 33 42 34 50 -

Fax: +47 33 42 34 59 www.essenticon.com

Date of issue 2012.02.13

Safety Data Sheet status CLP 01 ATP

Signature R. E. Lunde

Disclaimer The information in this data sheet is considered to be correct according to present

knowledge and experience, but there is no guarantee that it is complete. It is therefore

in the user´s interest to ensure that the information is sufficient for the area it is

intended for.




35728 Date of issue: 2012.02.13NW Clean B

SAFETY DATA SHEET

NW Clean B


COMPANY/UNDERTAKING

Product name NW Clean B




Norway

Tel: +47 51446400

Fax: +47 51446401

[email protected]

http://www.ambio.no





Symbol(s)

Contains pentasodium triphosphate

EDTA

benzenesulfonic acid, Sodium salts (C18H29NaO3S)

Risk phrases R-22 Harmful if swallowed.

R-41 Risk of serious damage to eye.

Safety phrases S-25 Avoid contact with eyes.

S-26 In case of contact with eyes, rinse immediately with plenty of water and seek

medical advice.

S-39 Wear eye/face protection.



S-46 If swallowed seek medical advice immediately and show this container or label.

CLP

Hazard pictograms




terese

Stamp


Signal word Danger

Hazard statements Acute Tox. 4: H302 Harmful if swallowed.

Eye Dam. 1: H318 Causes serious eye damage.




doctor/physician.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.



Ingredients


pentasodium triphosphate 231-838-7 7758-29-4 40-80 % -

EDTA 200-573-9 64-02-8 10-30 % Xi ,Xn R-22, R-41

benzenesulfonic acid, Sodium salts

(C18H29NaO3S)

270-115-0 68411-30-3 1-5 % Xn R-22, R-38, R-41

CLP


pentasodium triphosphate 7758-29-4 40-80 %

EDTA 64-02-8 10-30 % GHS07,

GHS05, ,

Danger

Acute Tox. 4: H302, Eye

Dam. 1: H318

benzenesulfonic acid, Sodium salts

(C18H29NaO3S)

68411-30-3 1-5 % GHS07,

GHS05, ,

Warning

Acute Tox. 4: H302, Skin

Irrit. 2: H315, Eye Dam. 1:

H318






Ingestion Rinse nose, mouth and throat with water. Provide rest, warmth and fresh air. Contact

physician if larger quantity has been consumed. Induce vomiting, if person is

conscious.

Skin Wash skin with soap and water. Remove contaminated clothing. Get medical attention

if irritation persists after washing.




Extinguishing media Use extinguishing media appropriate for surrounding fire.



Hazardous combustion products Fire or high temperatures create: Carbon monoxide (CO). Carbon dioxide (CO2).

Nitrous gases (NOx). Oxides of: Phosphorus.








Personal protection Wear appropriate personal protective equipment - see Section 8. Avoid inhalation of

vapours and spray mist and contact with skin and eyes. Provide adequate ventilation.

Environmental protection Prevent liquid entering sewers, basements and work pits.

Spill cleanup methods Limit spread of spilled material. Pick up mechanically or with a vacuum cleaner.

Collect and reclaim or dispose in sealed containers in licensed waste. Waste treated

in accordance with section 13.



and eye contact. Provide good ventilation. Eye wash station should be available at the

work place.

Storage precautions Keep in cool, dry, ventilated storage and closed containers. Keep in original container.

Avoid heating and sunlight. Store separated from: Acids.



Inert or nuisance dust, inhalable WEL. 10 mg/m3

Ingredient comments No exposure limits noted for ingredient(s).


Process conditions An eye wash bottle must be available at the work site.


Respirators In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory

equipment with particle filter (type P2).


Use protective gloves made of: Butyl rubber. Viton ® rubber (fluor rubber). Break

through time: 4 - 8 hours.






Appearance Crystalline powder

Colour Light yellow.

Odour Sulphur.


Density (g/cm3) 0,91 Temperature (°C) 20






Stability Stable when used at recommended storage and handling conditions.

Conditions to avoid Reacts with alloys as aluminium and magnesium with emission of Hydrogen gas.


Materials to avoid Acids. Oxidising substance.








Ingestion Harmful if swallowed.

Skin May cause irritation.

Eyes Risk of serious damage to eye. May cause chemical eye burns.


COMPONENT: pentasodium triphosphate



Toxic conc. - LC50: >0,39 mg/l/4h (inhalation rat)

COMPONENT: EDTA


COMPONENT: benzenesulfonic acid, Sodium salts (C18H29NaO3S)

Toxic dose - LD50: 1086 -1980 mg/kg (oral rat)

Toxic dose - LD50 (skin): >2000 mg/kg (skin rabbit)




the environment.



Persistence and degradability The product is biodegradable.






COMPONENT: pentasodium triphosphate

LC 50, 96 Hrs, Fish mg/l: 500 (Oncorhynchus mykiss)

EC 50, 48 Hrs, Daphnia, mg/l: >100 (Daphnia magna)

IC 50, 72 Hrs, Algae, mg/l: 160 (Scenedesmus subspicatus)

COMPONENT: EDTA

LC 50, 96 Hrs, Fish mg/l: 121 (Lepomis macrochirus)

EC 50, 48 Hrs, Daphnia, mg/l: <625 (Daphnia magna)

IC 50, 72 Hrs, Algae, mg/l: 11

BCF:1

Component will not bio-accumulate.

Bioaccumulative potential

<-3,86Partition coefficient (log Pow)

BOD5/COD: <0,004

5 % deg., 28d, Method: OECD 302B

The component is not readily biodegradable.

Persistence and degradability

COMPONENT: benzenesulfonic acid, Sodium salts (C18H29NaO3S)

LC 50, 96 Hrs, Fish mg/l: 19,8 - 39,6 (Pimephales promelas, C11-C10)

EC 50, 48 Hrs, Daphnia, mg/l: 16,7 (Daphnia magna, C10)

IC 50, 72 Hrs, Algae, mg/l: 11 (Selenastrum capricornutum, C11--C13)

3,32Partition coefficient (log Pow)

84 % deg., 21 days, Method: OECD 301EPersistence and degradability






substances







Explanations to R-phrases in section 3 R-22 Harmful if swallowed.

R-38 Irritating to skin.

R-41 Risk of serious damage to eye.


3


H315 Causes skin irritation.

H318 Causes serious eye damage.










intended for.




35732 Date of issue: 2012.02.13NW Clean C

SAFETY DATA SHEET

NW Clean C


COMPANY/UNDERTAKING

Product name NW Clean C




Norway

Tel: +47 51446400

Fax: +47 51446401

[email protected]

http://www.ambio.no




CAS No. 5949-29-1


Symbol(s)

Contains citric acid

Risk phrases R-36 Irritating to eyes.

Safety phrases S-23/24/25 Avoid inhalation and contact with skin and eyes.


medical advice.

CLP

Hazard pictograms

Signal word Warning

Hazard statements Eye Irrit. 2: H319 Causes serious eye irritation.




doctor/physician.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position




terese

Stamp


comfortable for breathing.





Ingredients


citric acid 201-069-1 5949-29-1 60-100 % -

CLP


citric acid 5949-29-1 60-100 % GHS07 Eye Irrit. 2: H319


Composition comments Typical specification:

Oxalic acid / oxalate < 100 mg/kg

Sulphate < 100 mg/kg

Heavy metals < 5 mg/kg

Arsenic < 1 mg/kg

Lead < 0.5 mg/kg

Mercury < 0.5 mg/kg

Calcium < 30 mg/kg

Iron < 3 mg/kg

Chloride < 5 mg/kg

Residue on ignition (USP / FCC) < 0.05 %

Sulphated ash < 0.05 %

Water < 0.50 %

Assay 99.7 - 100.3 %





Ingestion Do not induce vomiting. If vomiting occurs, the head should be kept low so that

stomach vomit doesn't enter the lungs. Rinse nose, mouth and throat with water. Give

lots of water, then 3-4 tablespoons of active carbon or paraffin emulsion. Get medical

attention immediately!

Skin Wash skin with soap and water. Get medical attention if irritation persists after

washing.




Extinguishing media Use extinguishing media appropriate for surrounding fire.



Hazardous combustion products Fire or high temperatures create: Corrosive gases/vapours/fumes.








Personal protection Wear appropriate personal protective equipment - see Section 8. Avoid skin-,

eyecontact and inhalation of steam. Provide adequate ventilation.

Environmental protection Contain spillages with sand, earth or any suitable adsorbent material. Prevent liquid

entering sewers, basements and work pits.

Spill cleanup methods Limit spread of spilled material. Pick up mechanically or with a vacuum cleaner.

Waste treated in accordance with section 13.



and eye contact. Provide good ventilation.

Storage precautions Keep in cool, dry, ventilated storage and closed containers. Store separated from:

Alkalis.


Ingredient comments No exposure limits noted for ingredient(s).


Process conditions Provide eyewash station.


Respirators In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory

equipment with particle filter (type P3).


Use protective gloves made of: Nitrile. Neoprene. 4H. Polyvinyl chloride (PVC). Break

through time 8 hours.






Appearance Powder. Granules.

Colour White.

Odour None. Taste: Acidic.


Solubility value (g/100g H2O 20°C) 60

Molecular weight 210.14

Melting/freezing point (°C, interval) 100


pH-value, diluted solution 2,2 Concentration %M 1 %

Decomposition temp. (°C) 153

Auto ignition temp. (°C) 500






Stability Stable under normal temperature conditions and recommended use.


Materials to avoid Bases and alkalies.








Ingestion Ingestion of great quantities may cause discomfort.

Skin Liquid or powder may irritate skin.

Eyes Irritating to eyes.


COMPONENT: citric acid





the environment. The product may affect the acidity (pH-factor) in water with risk of

harmful effects to aquatic organisms.



Persistence and degradability The product contains essential inorganic compounds and the biodegradability is

therefore not relevant.


COMPONENT: citric acid

Ecotoxicology data Acute toxicity. LC50 96 hours fish 440 - 760 mg/l (Leuciscus idus)

Acute toxicity. EC50 Pseudomona subspicata >10000 mg/l (Bakterie,

Method DIN 34812 T.8))

LC 50, 96 Hrs, Fish mg/l: 440 - 706 (Carassius auratas)

EC 50, 48 Hrs, Daphnia, mg/l: 80 -120 (72h)

IC 50, 72 Hrs, Algae, mg/l: 640 (Scenedesmus quadricauda)

<1Partition coefficient (log Pow)

Biodegradability: 98%, method OECD 302B.Persistence and degradability






substances











Explanations to R-phrases in section 3


3

H319 Causes serious eye irritation.










intended for.




35733 Date of issue: 2012.02.13NW Clean D

SAFETY DATA SHEET

NW Clean D


COMPANY/UNDERTAKING

Product name NW Clean D




Norway

Tel: +47 51446400

Fax: +47 51446401

[email protected]

http://www.ambio.no





Symbol(s)

Contains hydrogen peroxide solution

peracetic acid solution

acetic acid ... %

Risk phrases R-5 Heating may cause explosion.

R-7 May cause fire.

R-8 Contact with combustible material may cause fire.

R-20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R-34 Causes burns.

R-50 Very toxic to aquatic organisms.

Safety phrases S-1/2 Keep locked up and out of reach of children.


medical advice.

S-28 After contact with skin, wash immediately with plenty of water.



S-50 Do not mix with acids.

CLP

Hazard pictograms




terese

Stamp


Signal word Danger

Hazard statements Self-react. B: H241 Heating may cause a fire or explosion.

Ox. Liq. 3: H272 May intensify fire; oxidiser.

Acute Tox. 4: H302 Harmful if swallowed.

Acute Tox. 4: H312 Harmful in contact with skin.

Skin Corr. 1B: H314 Causes severe skin burns and eye damage.

Acute Tox. 4: H332 Harmful if inhaled.

Precautionary statements P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P273 Avoid release to the environment.



doctor/physician.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position

comfortable for breathing.





Ingredients


hydrogen peroxide solution 231-765-0 7722-84-1 5-15 % C ,O R-5, R-8, R-20/22, R-35

peracetic acid solution 201-186-8 79-21-0 10-30 % C ,O ,N R-7, R-10, R-20/21/22,

R-35, R-50

acetic acid ... % 200-580-7 64-19-7 20-40 % C R-10, R-35

CLP


hydrogen peroxide solution 7722-84-1 5-15 % GHS03,

GHS07,

GHS05, ,

Danger

Ox. Liq. 1: H271, Acute

Tox. 4: H302, Acute Tox.

4: H332, Skin Corr. 1A:

H314

peracetic acid solution 79-21-0 10-30 % GHS02,

GHS09,

GHS07,

GHS05, ,

Danger

Flam. Liq. 3: H226, Org.

Perox. CD: H242, Acute

Tox. 4: H302, Acute Tox.

4: H312, Acute Tox. 4:

H332, Skin Corr. 1A:

H314, Aquatic Acute 1:

H400

acetic acid ... % 64-19-7 20-40 % GHS05, GHS02 Flam. Liq. 3: H226, Skin

Corr. 1A: H314










Ingestion Do not induce vomiting. If vomiting occurs, the head should be kept low so that

stomach vomit doesn't enter the lungs. Rinse nose, mouth and throat with water. Give

lots of water, then 3-4 tablespoons of active carbon or paraffin emulsion. Get medical

attention immediately!

Skin Promptly flush contaminated skin with water. Promptly remove clothing if soaked

through and flush the skin with water. Important to remove the substance from the skin

immediately. Get medical attention if irritation persists after washing.

Chemical burns must be treated by a physician.



Chemical burns must be treated by a physician.


Extinguishing media Water spray, fog or mist. Powder, foam or CO2.


Specific hazards OXIDISING! Risk of explosion if heated.

Hazardous combustion products Fire or high temperatures create: Oxides of Chlorine. Corrosive gases/vapours/fumes.




Personal protection Wear appropriate personal protective equipment - see Section 8. Avoid skin-,

eyecontact and inhalation of steam. Provide adequate ventilation.

Environmental protection Contain spillages with sand, earth or any suitable adsorbent material. Prevent liquid

entering sewers, basements and work pits.

Spill cleanup methods Limit spread of spilled material. Absorb with inactive materials as vermikulite, sand,

dolomite, diatomene etc. Deliver to approved reception facility. Collect and reclaim or

dispose in sealed containers to licensed waste plant. DO NOT touch spilled material.

Waste treated in accordance with section 13.



and eye contact. Provide good ventilation. Eye wash facilities and emergency shower

must be available when handling this product.

Storage precautions Keep in cool, dry, ventilated storage and closed containers. Avoid heating and

sunlight. Oxidising material - Keep away from flammable and combustible materials.

Store away from oxidizing agents or combustible material.

Storage criteria Corrosive storage. Oxidiser storage.



hydrogen peroxide solution 7722-84-1 WEL. 1 / 1.4

ppm/mg/m³

2 / 2.8

ppm/mg/m3

Ingredient comments WEL = Workplace exposure limits. SK= Skin absorbance, Rep= Reproduction, Carc=

Carcinogenic Senz= Sensitisers, Mut= Carcinogenic






Process conditions Eyewash fountains and safety showers must be present on the workplace.


Respirators If ventilation is insufficient, suitable respiratory protection must be provided. Gas

cartridge (acid gases). At work in confined or poorly ventilated spaces, respiratory

protection with air supply must be used.


Use protective gloves made of: 4H. Viton ® rubber (fluor rubber). Butyl rubber. Break

through time: 4 - 8 hours.






Appearance Liquid.

Colour Clear.

Odour Pungent.


Boiling point (°C, interval) >100 Pressure


Vapour pressure 20 - 25 mmHg Temperature (°C) 25

pH-value, conc. solution ~1

Flash point (°C) >80 Method CC (Closed cup).


Stability Stable under normal temperature conditions and recommended use.

Conditions to avoid Avoid excessive heat, flames and other sources of ignition. Avoid contact with strong

acids and bases.


Materials to avoid Oxidising substance.







Inhalation Harmful by inhalation. Corrosive if inhalating aerosoles.

Ingestion Corrosive. Even small amounts may cause serious damage.

Skin Corrosive. Prolonged contact causes serious tissue damage.

Eyes Corrosive. Immediate first aid is necessary. Risk of serious damage to eye.






COMPONENT: hydrogen peroxide solution


Toxic dose - LD50 (skin): 3000 mg/kg (skin rat)

Toxic conc. - LC50: 2 mg/l/4h (inhalation rat)

COMPONENT: peracetic acid solution



OSHA Carcinogen Candidate List.Carcinogenicity

COMPONENT: acetic acid ... %



Toxic conc. - LC50: 11,4 mg/l/4h (inhalation rat)




the environment. The product may affect the acidity (pH-factor) in water with risk of

harmful effects to aquatic organisms.



Persistence and degradability The product contains essential inorganic compounds and the biodegradability is

therefore not relevant.


COMPONENT: hydrogen peroxide solution

LC 50, 96 Hrs, Fish mg/l: 16,4 (Pimephales promelas)

EC 50, 48 Hrs, Daphnia, mg/l: 2,8 (Daphnia pulex)

IC 50, 72 Hrs, Algae, mg/l: 2,5 (Chlorella vulgaris)

The product is not bioaccumulating.Bioaccumulative potential


The product is easily biodegradable.Persistence and degradability

COMPONENT: peracetic acid solution

EC 50, 48 Hrs, Daphnia, mg/l: 3,3 (Daphnia magna)

IC 50, 72 Hrs, Algae, mg/l: 0,18

BCF:1Bioaccumulative potential


COMPONENT: acetic acid ... %

LC 50, 96 Hrs, Fish mg/l: 79 (Pimephales promelas)

EC 50, 48 Hrs, Daphnia, mg/l: 65 (Daphnia magna) (24 h)

BCF: < 10Bioaccumulative potential


>60 % deg., 28 days, Method: OECD 301EPersistence and degradability






substances


Label for conveyance





Proper shipping name (national) HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE, STABILIZED

Proper shipping name (international) HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE, STABILIZED

ROAD TRANSPORT (ADR):

UN no. road 3149

ADR class no. 5.1

ADR Hazard labels 5.1+8

Classification code OC1

ADR packing group III

Hazard no. (ADR) 58

RAIL TRANSPORT (RID):

RID class no. 5.1

RID Hazard labels 5.1+8

RID packing group III

SEA TRANSPORT (IMDG):

UN no. sea 3149

IMDG class 5.1

IMDG subsidiary risk 8

IMDG packing group III

EmS no. F-H, S-Q

AIR TRANSPORT (IATA-DGR / ICAO-TI):

UN no., air 3149

IATA/ICAO class 5.1

IATA/ICAO Hazard label Oxidizer & Corrosive

IATA/ICAO subsidiary risk 8

IATA/ICAO packing group III





Explanations to R-phrases in section 3 R-10 Flammable.

R-20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R-20/22 Harmful by inhalation and if swallowed.

R-35 Causes severe burns.

R-5 Heating may cause explosion.

R-50 Very toxic to aquatic organisms.

R-7 May cause fire.

R-8 Contact with combustible material may cause fire.


3

H226 Flammable liquid and vapour.

H242 Heating may cause a fire.

H271 May cause fire or explosion; strong oxidiser.


H312 Harmful in contact with skin.





H314 Causes severe skin burns and eye damage.

H332 Harmful if inhaled.

H400 Very toxic to aquatic life.










intended for.




Date post:	14-Mar-2016
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Norwater AS Safety Datasheets

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