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Bronwyn Jones Queensland University of Technology School of Natural Resource Sciences OCCURRENCE AND CHEMICAL CHARACTER OF GROUNDWATER WITHIN SAMFORD VALLEY, SOUTHEAST QUEENSLAND by Bronwyn Ursula Patricia Jones B.App.Sc.Dist.(QUT) 2007 SUPERVISOR Associate Professor Malcolm E. Cox Queensland University of Technology A thesis submitted in partial fulfilment of the requirements for the degree of Bachelor of Applied Science (Honours) at the Queensland University of Technology. Further reproduction prohibited without permission from the author. CRICOS No. 00213J
Transcript

Bronwyn Jones

Queensland University of Technology

School of Natural Resource Sciences

OCCURRENCE AND CHEMICAL CHARACTER OF

GROUNDWATER WITHIN SAMFORD VALLEY,

SOUTHEAST QUEENSLAND

by

Bronwyn Ursula Patricia Jones

B.App.Sc.Dist.(QUT)

2007

SUPERVISOR

Associate Professor Malcolm E. Cox

Queensland University of Technology

A thesis submitted in partial fulfilment of the requirements for the degree of Bachelor of

Applied Science (Honours) at the Queensland University of Technology. Further reproduction

prohibited without permission from the author.

CRICOS No. 00213J

Bronwyn Jones

ABSTRACT

Samford Valley, southeast Queensland, is a granitic catchment essentially formed

from a granodiorite intrusion of Middle Triassic age that has been weathered and

differentially eroded. The weathered and fractured granitic rocks of the valley floor have

formed aquifers that contain an important water supply for the area; however, there has

never been a comprehensive groundwater study to assess the quality, occurrence,

productivity or potential of the groundwater resources of the valley. This current study was

carried out to determine the occurrence and chemical character of the groundwater within the

valley and the hydrogeological controls on it. Field measurements and a water sample were

taken from existing groundwater bores; an experienced drilling contractor with extensive local

knowledge provided drilling records with bore yields and stratigraphic data.

Hydrochemical analyses and electrical conductivity measurements indicate that

groundwater quality is fresh and potable towards the margins of the valley and that there is a

central brackish-saline zone. Maps and graphs generated from the software programs

SURFER and AquaChem have also revealed that groundwater central to the valley is mature

and more evolved than around the edges, as evidenced by Na-Cl type groundwater, more

total dissolved solids, elevated pH, and higher Cl–/HCO3– ratios. Furthermore, shallow

permeability and bore yields are highest around the valley edges and lowest in the central

zone, however the thickest weathered zone is in the centre of the valley.

The results suggested that the fresh groundwater around the edges of the valley is

from recharging rainwater that has filled fracture systems and is extracted early in its

migration. The more saline groundwater in the central zone is from the accumulation of salts

as the groundwater evolved. These salts are products of rock-water interactions and ion

exchanges within the deeply weathered granodioritic aquifers as the groundwater flowed

from the higher-elevation recharge areas at the edges of the valley to the low lying discharge

area. Low precipitation and high evaporation conditions have also enhanced salinity over

time. The prolonged in situ weathering history of the granodiorite and the formation of clays

as remnant material have reduced shallow permeability and yields in the centre of the valley;

however, networks of connected fractures draining porous weathered rocks have contributed

to the high permeability and bore yields around the northern and southern edges of Samford

Valley.

KEY WORDS

Samford Valley · Southeast Queensland · Groundwater occurrence · Chemical character ·

Granitic aquifers · Weathered and Fractured Granodiorite · AquaChem · SURFER.

CRICOS No. 00213J

Bronwyn Jones

TABLE OF CONTENTS

Page

ABSTRACT i

KEYWORDS i

TABLE OF CONTENTS ii

LIST OF FIGURES iv

LIST OF TABLES v

LIST OF APPENDICES v

STATEMENT OF ORIGINAL WORK vi

ACKNOWLEDGMENTS vii

INTRODUCTION 1

Aim 1

Objectives 1

Significance 2

BACKGROUND 3

Description of Location 3

Topography 5

Rainfall 7

Landuse 9

Geological Setting 11

Hydrogeology 13

Porosity and Permeability of Granitic Rocks 13

Strata Log 14

Bore Construction 16

METHODS 17

Collection of Data for Groundwater Bores 17

Groundwater Field Investigations 19

Laboratory Water Analyses 20

Acid Titration for Bicarbonates 20

Inductively Coupled Plasma – Optical Emission Spectroscopy 20

Ion Chromatography 20

Data Interpretation and Modelling 20

SURFER 20

AquaChem 21

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Bronwyn Jones

RESULTS 22

Physico-Chemical Parameters 22

Groundwater pH 22

Electrical conductivity 24

Bore Yield 27

Watertable 28

Hydrochemistry 32

Piper Trilinear Diagram 32

Bicarbonate and Chloride 33

Schoeller Diagram 34

Calcium and Sulphate 35

Calcium, Magnesium and Chloride 36

Sodium, Calcium and Total Dissolved Solids 37

DISCUSSION 38

Bore Yield and Permeability 38

Watertable 39

Groundwater pH 41

Groundwater Chemistry 42

Piper Trilinear Diagram 42

Bicarbonate and Chloride 43

Schoeller Diagram 43

Calcium and Sulphate 44

Calcium, Magnesium and Chloride 46

Sodium, Calcium and Total Dissolved Solids 46

Distribution of Salinity 47

CONCLUSIONS 48

REFERENCES 49

APPENDICES 53

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LIST OF FIGURES

Figure 1. Location map of Samford Valley 4

Figure 2. Map of the localities in Samford Valley 5

Figure 3. Topographic map of Samford Valley 6

Figure 4. Topographic profile of Samford Valley from north to south 6

Figure 5. Topography and average annual rainfall (mm) isohyetal map 8

Figure 6. Graph of mean monthly rainfall and temperature 8

Figure 7. The methods used to provide water for properties not connected to town water 10

Figure 8. Geological map of Samford Valley 12

Figure 9. Generalised weathering profile for granitic rocks 14

Figure 10. Typical strata log from Samford Valley 15

Figure 11. A groundwater bore being drilled in Samford Valley 16

Figure 12. Mapped location of groundwater bores in Samford Valley 18

Figure 13. Piper classification diagram 21

Figure 14. Scatter plot of the relationship between electrical conductivity and pH 22

Figure 15. Scatter plot of the influence of bicarbonate on pH 23

Figure 16. Graph of the frequency of electrical conductivity in Samford Valley 24

Figure 17. Contour map of the electrical conductivity of groundwater in Samford Valley 25

Figure 18. Scatter plot of the influence of water level on EC, Samford Valley 26

Figure 19. Contour map of bore yields and distribution of permeability in Samford Valley 27

Figure 20. Contour map of the watertable in Samford Valley 28

Figure 21. Transect of the watertable from the southwest to northeast 29

Figure 22. Contour map of the watertable and groundwater flow vectors, Samford Valley 29

Figure 23. Groundwater flow net of Samford Valley 31

Figure 24. Trilinear classification of groundwater, Samford Valley 32

Figure 25. Scatter plot of the trend between bicarbonate and chloride ions 33

Figure 26. Schoeller diagram of fresh and brackish-saline sample pairs 34

Figure 27. Scatter plot of the relationship between calcium and sulphate ions 35

Figure 28. Scatter plot comparing calcium plus magnesium to chloride ions 36

Figure 29. Scatter plot of the dependence of sodium to calcium on TDS 37

Figure 30. Scatter plot confirming the influence of topography on the water level 40

Figure 31. Summary of groundwater composition trend, Samford Valley 42

Figure 32. The degraded upper reaches of Samford Creek, Samford Valley 45

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Bronwyn Jones

LIST OF TABLES

Table 1. Samford climatic statistics 9

LIST OF APPENDICES

Appendix 1. Explanation of the Groundwater Inventory 53

Appendix 2. Groundwater Inventory 87

Registration Table 88

Field Water Quality Measurement Table 100

Strata Log Table 102

Casing Table 109

Aquifer Table 114

Water Analysis Table 120

Elevation and Co-ordinate Table 126

Drilling Contractor Remarks Table 130

Other Bores in Samford Valley Table 133

Appendix 3. Groundwater Analytical Procedures 135

Acid Titration 136

Inductively Coupled Plasma – Optical Emission Spectroscopy 137

Ion Chromatography 139

Appendix 4. Samford Valley Maps 143

Ortho-photo map of Samford Valley 144

Topographic map of Samford Valley (metres above sea level) 145

Mapped location of groundwater bores in Samford Valley 146

Electrical conductivity of groundwater, Samford Valley 147

DEM topographic map with surface drainage systems 148

Generalised distribution of shallow permeability, Samford Valley 149

Photographs looking NE across the valley from Jolly’s Lookout 150

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Bronwyn Jones

STATEMENT OF ORIGINAL WORK

The work contained within this thesis has not been submitted for a degree or diploma

at any other higher education institution. To the best of my knowledge and belief, this thesis

contains no material previously published or written by another person except where due

reference is made.

Signed ……………………………………………….

Date ...………………………………………………..

CRICOS No. 00213J

Bronwyn Jones

ACKNOWLEDGMENTS

A special thank-you is expressed towards Associate Professor Malcolm Cox for his

supervision, helpful comments and guidance throughout the year. They were greatly

appreciated.

I acknowledge Wathsala Kumar for her assistance with laboratory work, Dr Micaela

Preda for her assistance with DEM data and maps, and to NRS PhD student Qing Wang for

providing me with some of her data.

I have appreciated the Honours scholarship, jointly funded by the QUT Institute for

Sustainable Resources (ISR) and QUT School of Natural Resource Sciences (NRS) and I

thank Professor Peter Grace and Associate Professor Mal Cox for this support. I also thank

Peter Loose and Dr Rainer Hasse of Pine Rivers Shire Council for information and DEM

contour data, and the Department of Natural Resources and Water (NRW) for use of the

groundwater database.

Thanks is given to drilling contractor Mr Neville Scells and his colleague Glen from

S. H. Scells Water Well Drilling Business for sharing their knowledge of the area, access to

well-organised logbooks, and the invitations to observe them drill groundwater bores. I also

gratefully thank Mr Geoff Ward for sharing his general and groundwater knowledge of the

area. Finally, I thank the many friendly and helpful landholders of Samford Valley for

providing me with access to their private bores.

CRICOS No. 00213J

Bronwyn Jones

INTRODUCTION

Weathered and fractured zones of granitic rocks can form aquifers which, in many

parts of the world, contain important groundwater resources locally, particularly for rural

populations. Samford Valley is an area where such groundwater is important as two-thirds of

the valley is not connected to townwater and on-going dry conditions have reduced rainwater

tank supplies. The valley has formed from the differential weathering of a granodiorite

intrusion and the weathered and fractured granitic rocks contain the important water supply

for the area. The potential of the aquifer system to supply groundwater is governed by such

factors as the distribution of permeability, the quality of the water, and the depth to the

watertable. However, despite the fact that domestic bores have been drilled in the valley for

over 60 years, there has not been a previous comprehensive groundwater study to

determine the occurrence and chemical character of the groundwater resource in Samford

Valley.

An overall understanding of the groundwater movements throughout the valley was

required to assess the potential groundwater resource. A map and conceptual model of the

watertable have been developed to explain the groundwater flow, and a bore yield map was

used to determine the generalised spatial distribution of shallow permeability.

It was also essential to ascertain the evolution of the chemical character of the

groundwater and the water quality variations throughout the valley. These parameters have

been determined by the collection and analysis of groundwater samples from different

aquifer materials throughout the whole valley, and by the production of a salinity distribution

map. In addition, the comprehensive compilation of groundwater and bore data has enabled

the production of a groundwater bore inventory that will be a useful record or reference to

support future management of this valuable local resource.

Aim

The overall aim of this study was to determine the occurrence and chemical character

of groundwater within Samford Valley and the hydrogeological controls on it.

Objectives

To achieve the aim, the objectives were to:

• Compile a comprehensive groundwater bore inventory for Samford Valley as a useful

record or reference for future studies and management of the resource.

CRICOS No. 00213J

Bronwyn Jones

• Investigate the chemical variations of the groundwater by analysing for chemical ions

in groundwater samples collected from existing bores throughout Samford Valley.

This also involved physico-chemical measurements such as electrical conductivity

(EC) and pH.

• Examine the groundwater resource potential and controls on the occurrence and

movement of groundwater by establishing the depth to groundwater within different

aquifers and their water-bearing characteristics (e.g. bore yields).

• Determine the distribution of salinity and shallow permeability to produce groundwater

resource maps for the valley.

• Determine the groundwater flow direction and link between groundwater and surface

waters (i.e. South Pine River) by the development of a watertable contour map and

flow net for the valley.

Significance

There has not been a previous comprehensive study of the hydrogeology or

groundwater of the valley. Thus, this study is significant in that it provides an understanding

of how groundwater occurs within this weathered granodioritic catchment. The study also

provides some understanding of groundwater/surface water interactions in Samford Valley

and the chemical variations of the groundwater throughout the whole valley. In addition,

useful information, with respect to resource management and land use, can be gained from

the comprehensive groundwater bore inventory and maps.

CRICOS No. 00213J

Bronwyn Jones

BACKGROUND

Description of Location

The groundwater study was conducted in Samford Valley, in the Pine Rivers Shire,

~20 km northwest of Brisbane, southeast Queensland (Figure 1a, b). Samford Valley

occupies an area of approximately 50 km2 and encompasses the localities of Camp

Mountain, Highvale, Wights Mountain, Samford Village and Samford (Figure 2). It is

surrounded by a prominent “horseshoe” of mountains to the north, west and south (Figure

1b). To the south and west are the Brisbane Forest Park and D’Aguilar Ranges including

Mount Nebo and Jolly’s Lookout. To the north is the House Mountain Range and Mount

O’Reilly. Thus, the boundary for the study area was clearly defined on three sides, and the

eastern limit was taken as the elevated area immediately east of Samford Village.

South Pine River forms the main drainage system. It enters the valley in the west

(just north of Mount Nebo) and flows east within the northern half of the valley, while Samford

Creek flows along the southern half of the valley (Figure 2). The valley has a dendritic

drainage pattern and the rivers have incised into the granodiorite, depositing very limited

amounts of floodplain alluvium. The streams and creeks have an ephemeral flow and during

dry periods of the year flow usually ceases over much of their length. This is especially the

case under the current dry conditions and with continued extraction of groundwater. At

present, the water quality of Samford Creek and South Pine River are “satisfactory to poor”

and degraded with nutrients and coliform bacteria (Nolte and Loose, 2004). Locals have also

observed that there is a tendency to get saline borewater near Samford Village. Many

residents near the village have therefore followed “conventional wisdom” and have not had a

bore drilled because of the known elevated salinity.

CRICOS No. 00213J

Bronwyn Jones

Figure 1. Location map of Samford Valley. (a) Regional setting of Samford Valley in southeast Queensland. (b) Ortho-photo map of Samford Valley. The valley occupies an area of ~50 km2, and is surrounded by mountains to the north, west and south. The ortho-photo image is from aerial photographs flown in March 2002 and was produced by the Department of Natural Resources and Water, 2007 (an A3-size ortho-photo map is in the Appendix).

(a)

(b)

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Bronwyn Jones

Topography

Mount Nebo to the west has an elevation of 617 m and Mount O’Reilly in the north is

503 m high, but the undulating terrain of Samford Valley only has an average elevation of 60-

100 m Above Sea Level (ASL) (Samford 1:50 000 Map, 1974). The ranges have an average

elevation over 400 m ASL. After heavy rain the streams around the edges of the valley can

get flash floods as the rainwater comes directly from the very steep slopes. The valley floor

slopes less than 10 % towards the northeast (Figure 3). Furthermore, the streams in the

valley have gradients of approximately 6 m km–1, although the upper reaches of South Pine

River are typically more than 40 m km–1 (Cosser, 1989).

In addition, the northern section of the valley appears more eroded than the southern

section (Figure 4); the southern section of the valley has more colluvium and rounded hills.

The elevation of the highest bore in this study is 165 m ASL (bore F2); while the lowest bore

has an elevation of 44 m ASL (bore G3).

South Pine River

Samford Creek

Dawson Creek

Mount Glorious Road

CSIRO site

0 3 km

SCALE

Figure 2. Map of the localities in Samford Valley. Samford Valley encompasses the suburbs of Highvale (green), Wights Mountain (blue), Camp Mountain (yellow), Samford (pinky-red) and Samford Village (light orange). South Pine River flows east within the northern half of the valley and Samford Creek flows along the southern half of the valley. Mount Glorious Road is the main road.

CRICOS No. 00213J

Bronwyn Jones

Figure 3. Topographic map of Samford Valley. Samford Valley has an undulating terrain with an average elevation of 60 – 100 m ASL. The gradient of the valley floor is less than 10 % towards the northeast. The red line is the location of the topographic profile for Figure 4. The contour data is from Pine Rivers Shire Council (an A3-size topographic map is in the Appendix).

Figure 4. Topographic profile of Samford Valley from north to south (A – A’ [Figure 3]). The northern section of the valley is more eroded than the southern half. Note: vertical exaggeration of ×10.

A

A’

A A’

0 3km

SCALE

South Pine River Samford Creek

CONTOUR INTERVAL 5 metres

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Bronwyn Jones

Rainfall

Due to the orographic effect in Samford Valley, rainfall is higher in the west of the

catchment. This is evident in average annual rainfall (mm) isohyetal maps of the area

(based on 5 m DEM contours and processed by ArcGIS) whereby the rainfall varies from an

average 1100 mm to 1300 mm (Figure 5; M. Preda, unpublished 2007). A linear relationship

between the elevation and rainfall in the valley can be expressed as: y = 0.7302x + 1074.6,

where x is the elevation and y demotes the average annual rainfall. Furthermore, due to

both the rainfall distribution and the steepness of the surrounding highlands, streams in the

valley can have rapid flow and response to high rainfall events, resulting in flash flooding.

The rainfall is highly seasonal as evidenced by a pronounced December to March

summer wet season on a graph of monthly mean rainfall and temperature (Figure 6).

Between 1912 to 2003 the average rainfall was highest in February (161 mm) and lowest in

August (34 mm) with a yearly average of 1122 mm (Table 1), but the area has received less

rainfall in the last few years because of the current dry (drought) conditions affecting

southeast Queensland. Rainfall since 2002 has been well below-average for the vast

majority of the state and is reflected in the area that has been drought declared (EPA, 2003).

In December 2002, 50% of Queensland was drought declared; by 2007, this percentage had

significantly increased (EPA, 2003). Furthermore, with on-going use of the groundwater the

watertable has been lowered, as evidenced by the local driller who has stated that shallow

bores have tended to deplete, or “dry-up”. It is therefore likely that many of the deep bores in

the fractured granodiorite (rather than the weathered zone) in the study area have mostly

been drilled after the drought started.

Rainfall may be the main source of groundwater recharge for groundwater in the

valley, and it is a paramount factor in chemical weathering as it controls the supply of

moisture for chemical reactions and the removal of soluble constituents of the minerals

(Sreedevi et al., 2006). Rainwater is weakly acidic due to carbon dioxide (CO2 [gas]) in the

atmosphere, and in the Brisbane area it typically has a pH in the range 4.5 – 5.5 (Cox et al.,

1996). Other ionic species in rain derived from terrestrial sources can be bicarbonate

(HCO3–), carbonate (CO3

2–), hydroxide (OH–), calcium (Ca2+), potassium (K+), ammonium

(NH4+ ) and nitrate (NO3

–) (Hiscock, 2005), but the ions vary depending on the particular area

and climate.

CRICOS No. 00213J

Bronwyn Jones

Figure 6. Graph of mean monthly rainfall and temperature. The data is from 1912 – 2003 at the Samford CSIRO site (Figure 2 [site was closed December 2003]). The rainfall is highly seasonal as evidenced by a pronounced summer wet season.

Month

Samford Valley

Figure 5. Topography and average annual rainfall (mm) isohyetal map. Due to an orographic effect, rainfall is higher in the west of the catchment and varies from an average 1100 mm to 1300 mm. The DEM was based on 5 m contours and processed by ArcGIS (M. Preda, unpublished 2007).

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Land Use

Samford Valley can be classified as a ‘peri-urban’ area and townwater is currently

only supplied to the new estates built north of Mount Glorious Road, the main road that runs

east-west near South Pine River and links to Mount Nebo (Figure 2). The new estates

receive water from North Pine Dam (located at Lake Samsonvale), that has been treated by

Brisbane Water and distributed to the Pine Rivers Shire. The two-thirds of the valley south of

the main road, mostly acreage properties, are not connected to town water and must

therefore provide their own water supply. The property owners use borewater and rainwater

tanks and most have ponds or small dams. However, during long dry periods (e.g. the

present drought conditions) many residents have resorted to having water tanked in by water

carriers, while others buy bottled springwater (Figure 7). Thus, two-thirds of the valley is

reliant or heavily dependent on the groundwater. In addition, only Samford Village is

connected to a sewerage system. The remainder of the valley uses some form of septic

system.

In this peri-urban environment, land use is made up of new residential estates and a

golf course (north of the main road), a showground, farms, horse studs, urban blocks, and

bushland areas. Native forest covers the steep perimeter of the valley, and there are some

small plantations. Furthermore, there has generally been a change from rural to rural-

residential blocks in the valley. Altogether, the five local suburbs now have a combined

population of about 6700 (year 2006) (PIFU, 2004).

Table 1. Samford climatic statistics.

The main climatic statistics are summarised for Samford for the period 1912 – 2003. The average rainfall has been highest in February (typically 161 mm) and lowest in August (typically 34 mm) with a yearly average of 1122 mm. Data is from the Bureau of Meteorology (2007).

CRICOS No. 00213J

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Figure 7. The methods used to provide water for properties not connected to town water. Two-thirds of the valley must provide their own water supply. The property owners use: A) borewater, B) rainwater tanks, C) water tanked in by water carriers, D) bottled springwater.

A

C

D

B

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Bronwyn Jones

Geological Setting

The pronounced basin-shape of Samford Valley is essentially the result of a granitic

intrusion that has been weathered and eroded differentially. The Samford Granodiorite (K/Ar

age 221 ± 8 m.y.) intruded Palaeozoic Bunya Phyllite and Neranleigh-Fernvale beds in the

Middle Triassic (Cranfield et al., 1976). The intrusion is largely granodiorite but has some

dioritic rocks in the western part (near Mount Nebo), and minor trondhjemite (a leucotonalite)

occurs along the valley margins (Stevens, 1984).

In sections of the contact metamorphic zone between the granodiorite and the

metasediments, hornfels developed because of the heat of the molten Samford Granodiorite

magma, i.e. the surrounding metasediments were recrystallised (Figure 8) (Willmott and

Trezise, 1984). Thus, the steep slopes of the metasediments are exaggerated around

Samford Valley because the alteration to hornfels has made those rocks more resistant to

weathering than the relatively “weak” or more susceptible granitic rocks (Phillips, 1959;

Stevens, 1973).

The grey-white, coarse-grained Samford Valley Granodiorite has the composition of a

typical granodiorite and consists of andesine laths (3 – 10 mm), microperthitic feldspar,

quartz, mafics (Fe + Mg minerals), accessories and numerous rounded xenoliths (Gradwell,

1955). Biotite is the dominant mafic mineral, but others include hornblende and rare

pyroxene (non-pleochroic diopsidic augite) (Cranfield et al., 1976). Accessories include

apatite, magnetite, sphene, and rare zircon (Cranfield et al., 1976). The xenoliths in the

granodiorite are derived from both the surrounding country rock and igneous rocks

(Gradwell, 1966). The country rocks are Bunya Phyllite in the east and Neranleigh-Fernvale

beds in the west; the boundary between these runs north-westerly and is intruded by the

Samford pluton (Figure 8) (Willmott, 2004; Hodgkinson et al., 2006).

Although the valley is primarily formed of granodiorite, there are also some colluvium

deposits around the valley edges. This material contains unsorted masses of clay and sand

mixed with boulders and stone layers that can be traced upslope to the surrounding hills

(Van Genderen, 1966). Holocene unconsolidated alluvium is only found along very small

sections of Samford Creek and South Pine River and ranges in texture from sandy to heavy

clays (Van Genderen, 1966).

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Bronwyn Jones

Figure 8. Geological map of Samford Valley. Hornfels have developed in the contact metamorphic zone between the Samford Granodiorite and the metasediments. The country rocks are Bunya Phyllite and Neranleigh-Fernvale beds; the boundary between these runs northwest and is intruded by the Samford pluton (Willmott, 2004).

0 1 2 3 km

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Hydrogeology

Porosity and Permeability of Granitic Rocks

The granodioritic rocks are porous and permeable due to secondary porosity by

fracturing and weathering. The weathering and removal of both biotite and plagioclase from

weathered granodiorite results in significant amounts of silica (quartz), kaolinite and other

clay minerals left as remnant material, which may reduce the available secondary porosity

(e.g. by kaolinisation) (Dewandel et al., 2006). On the other hand, it is possible that the

swelling of certain minerals (the most sensitive mineral is biotite) can result in a local

increase in volume that favours cracking and fissuring, increasing secondary porosity

(Dewandel et al., 2006). The deeper granodiorite has only fracture porosity, with the porosity

(the volume of voids to the total volume [n = Vv/Vt]), typically ranging between 0 – 0.10. In

comparison, the porosity in alluvial tracts (up to 0.35) is higher than those of the granitic

formations (Stober and Bucher, 2007).

The hydraulic conductivity (K) or permeability of fractured granitic rocks typically

ranges from 10–13 – 10–4 m s–1 (Stober and Bucher, 2007). Hornfels at the valley margins in

the contact metamorphic zone of the Neranleigh-Fernvale metasediments would have no or

very low permeability (Davis and DeWiest, 1991). In Samford Valley, permeability and

groundwater yield is low with maximum bore yields at 1 L/sec. However, the local drilling

contractor has recommended to many people in the valley to use a pumping rate of 0.25

L/sec, which provides a good supply for domestic use. The likely aquifers or water-bearing materials in Samford Valley are:

i) Alluvium in the active drainage systems, peripheral to streams, and on floodplains;

colluvium at the edges of the valley. Both of these materials are very limited in volume.

ii) Weathered upper granodiorite, which is probably the primary aquifer of the valley.

However, over much of the valley, the weathered zone has become unsaturated as the

watertable has lowered, and some bores that were once productive are now dry because

of the current dry (drought) conditions. Whereas previously bores only needed to be

drilled into the weathered zone to reach water, a lot of new bores registered on the NRW

database are being drilled into fractured granodiorite.

iii) Deeper fresh, fractured granodiorite. Some of the bores in the fractured granodiorite in

Samford Valley are to depths of 60 metres.

Some of these aquifers may overlap and be hydrogeologically continuous.

From drillers’ logbooks (N. Scells, unpublished data 2007), the depth to the water-

bearing zone varies from 1 m (bore F11) to 44 m (bore A22); in some bores the water level

rose from this depth. The aquifers are primarily unconfined, and generally only occupy the

first tens of metres below the ground surface. However, the rise in the water level in some

bores could indicate (a) hydraulic head related to recharge, or (b) semi confining conditions.

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Strata Log

A typical weathering profile for granitic rocks includes overlying sediments (usually

structureless sands and clays), weathered rock, a weathered-fractured zone, and fractured

bedrock (Figure 9, Huggett, 2003). Based on data from driller logbooks, a strata log was

created for the Samford Valley bores (Figure 10). The brown sandy soil cover (typically

sandy loam) derived from the weathering of the Samford Granodiorite is typically less than a

metre deep and underlain by light brown stiff clay, highly weathered granodiorite and grey

fractured granodiorite.

The light brown stiff clay material and deeply weathered zone have formed because

of the prolonged in situ weathering of the granodiorite. The thickness of the weathered zone

varies from 1 m (bore E7) to about 29 m thick (bore D4) and is referred to as “deco”

(decomposed) by the drillers. The highly weathered granodiorite is then underlain by

fractured grey granodiorite. The deepest layer is the fresh, unweathered, light grey, very

hard granodiorite bedrock, which has no or negligible fracturing.

Figure 9. Generalised weathering profile for granitic rocks. Layers include overlying sediments, weathered rock, the weathered-fissured zone, and fractured bedrock (Huggett, 2003).

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17

18

Figure 10. Typical strata log from Samford Valley. It is based on data from driller logbooks. Brown sandy soil cover (or sandy loam) is typically less than a metre deep and underlain by light brown stiff clay, highly weathered granodiorite, grey fractured granodiorite and light grey, very hard granodiorite bedrock. The depths are in a typical range that is representative of most of the bores in the valley.

Depth (m)

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Bore Construction

Most of the groundwater bores in the valley have been drilled by the S. H. SCELLS

Water Well Drilling Business, a business that has been drilling bores in the area for over 60

years. The current operator is an experienced drilling contractor with extensive local

knowledge of the area. Boreholes have mostly been drilled using cable tool and air rotary

methods and range in depth from 9 m (e.g. bore E13, Samford) to 49 m (e.g. bore A22,

Highvale), with an unsuccessful (dry) bore down to 60 m (e.g. bore A7, Highvale).

Based on data from driller logbooks, casing for the bores are predominantly 125 mm

diameter PVC (Polyvinyl Chloride) and steel of 200 mm diameter (Figure 11 and Appendix 2

Casing Table). Using bore F13 as an example of how bores in Samford Valley have typically

been constructed, it was drilled to a depth of 14.5 m and has PVC casing from 0 – 14.5 m

with perforations in the PVC from 9 – 14.5 m. The upper 7.5 m below the surface (0 – 7.5 m)

also has a solid steel casing. Around the outside of the PVC casing there is cement grout

from 0 – 5 m, fill from 5 – 6 m and gravel pack from 6 – 14.5 m. The slotted or perforated

section of the PVC casing allows groundwater to flow from the surrounding aquifer into the

casing, the gravel allows water but not finer sediments to flow into the bore, and the cement

is set around the casing at the surface to prevent surface water from seeping down the

outside of the casing. Most of the completed bores in the valley have been sealed up.

Figure 11. A groundwater bore being drilled in Samford Valley. The bore was drilled into granodiorite using cable tool and air rotary methods in Highvale (bore A8) by S. H. SCELLS Water Well Drilling Business. Casing for bores in Samford Valley are predominantly 125 mm diameter PVC and 200 mm diameter steel.

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METHODS

Collection of Data for Groundwater Bores

A total of 122 existing groundwater bores were located in Samford Valley (Figure 12

and Appendix 2). Although there was an attempt to locate a relatively even spread of bores,

they are distributed throughout the whole valley with clusters in some areas, and in other

areas the bores are widely spread. Nevertheless, the main focus was to establish where

bores were, so that a complete groundwater bore inventory could be generated. In addition,

there does not appear to be any spatial significance to the location of the dry bores.

Forty-nine bores were originally identified from the Queensland State Government’s

Department of Natural Resources and Water (NRW) Register, as prior to several years ago

there were no requirements for bores to be registered. However, a local ex-driller identified

where other bores were (G. Ward, pers. comm., 2007), and the location of other non-

registered private bores (including dry bores) was established in this study by visiting

properties. The challenge of locating new bores was increased as some landowners were

nervous about providing access (especially considering there has long been talk of the

council metering bores).

Co-ordinate locations of the bores were confirmed by handheld GPS (Global

Positioning System), and each bore position was later converted to easting and northing,

latitude and longitude in decimals, and latitude and longitude in degrees, minutes and

seconds (Appendix 2 Elevation and Co-ordinate Table).

An experienced drilling contractor with extensive local knowledge also provided

access to drill logs (N. Scells, unpublished data 2007); data such as bore yield (supply in

L/sec), stratigraphy, casing data and drilling methods for a lot of bores were obtained. The

full details for each bore are listed in the groundwater inventory (Appendix 2) and the

mapped locations of the 122 bores are shown in Figure 12.

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Figure 12 . Mapped location of groundwater bores in Samford Valley. A total of 122 existing groundwater bores were located and confirmed in Samford Valley. The details for each bore are listed in the groundwater inventory (Appendix 2) and an A3-size bore location map is also in the Appendix.

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Groundwater Field Investigations

Field measurements and a groundwater water sample were taken from existing

groundwater bores (no new bores were drilled specifically to measure and collect

information). Both the in situ field measurements and sample collection were made over

three months at various bore locations throughout the area. If there was a tap connected to

the bore, this was run before tests were carried out. A few of the bores with no tap or pump

were bailed (such as bore F16 which had equivalent to 30 L of water bailed out); otherwise,

shallow water or water sitting in the pipe (e.g. rainwater) would have been tested instead of

the main groundwater source.

Various physico-chemical parameters of the groundwater were measured in the field

including the potential hydrogen ion activity (pH), electrical conductivity (EC in µS/cm) and

redox potential (Eh in millivolts). The pH and EC’s of the groundwater were measured by

means of pH and conductivity meters. The electrode probes were placed into a bucket of the

groundwater and the measurement values were allowed to stabilise before a reading was

recorded. Sixty-six EC values, 51 pH values and 26 redox potential values have been

obtained (See Appendix 2).

The depth to the watertable was determined by placing a dipmeter* down the bore.

This was only possible with bores that were not sealed up, although most of the 45 standing

water levels were available from the NRW database and drill log reports. The government

records, mostly from the period 2003 – 2007, and field measurements in this current study

were taken to indicate the current water table conditions. The yields of the aquifers (supply

in L/sec) from 51 bores were also available from drill logs.

The groundwater samples from 42 existing bores were collected in clean 250 mL

plastic bottles for hydrochemical analysis in the QUT geochemistry laboratory. Each

container was filled completely, so as to be free of air. Two sample bottles, one each for

cations and anions, were required for each site. Before going into the field 2 mL of

concentrated nitric acid (HNO3–) was added to the cation sample bottles, to give a pH<2 in

the final sample, to stabilise metal ions in solution.

* A dipmeter or dipper has a probe on the end of a long tape. The inner electrode on the probe ‘beeps’ when it comes into contact with water.

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Laboratory Water Analyses

Groundwater samples collected from bores in the field were chemically analysed for

major and minor cations and anions in the QUT geochemistry laboratory by various methods,

to determine the chemical components, character and variation. The water analyses were

performed by the ion chromatography (IC) and inductively coupled plasma (ICP – OES)

machines, as well as manually by acid titration (for bicarbonates). The full laboratory

groundwater analytical procedure is included in Appendix 3.

Acid Titration for Bicarbonates

The concentration of bicarbonate anions (HCO3–) in each groundwater sample was

determined by titrating hydrochloric acid (HCl) with each sample. Calculations were made

using the amount (volume) and concentration of titrate used to reach the endpoint, so as to

convert the bicarbonate expressed as alkalinity (mg/L CaCO3) to the concentration of the

bicarbonate species (HCO3–). The full acid titration procedure is in Appendix 3.

Inductively Coupled Plasma – Optical Emission Spectroscopy

The Inductively Coupled Plasma – Optical Emission Spectroscopy (ICP – OES)

machine was used to analyse for major and minor cations in the groundwater samples that

had been filtered and acidified with nitric acid. The concentrations of sodium, calcium,

potassium, magnesium, iron, aluminium, manganese, strontium, zinc and copper (Na, Ca, K,

Mg, total Fe, Al, Mn, Sr, Zn, and Cu respectively) were determined. The full ICP procedure is

in Appendix 3.

Ion Chromatography

The Ion Chromatography (IC) machine analysed the groundwater samples for the

important anions of chloride, fluoride, bromide, nitrate, phosphate and sulphate (Cl, F, Br,

NO3, PO4 and SO4 respectively). These anion samples were not acidified. The full IC

procedure is in Appendix 3.

Data Interpretation and Modelling

SURFER

SURFER for Windows by Golden Software, Inc. was used to generate groundwater

resource maps of Samford Valley. Contour maps (2D and 3D) were developed to show the

electrical conductivity, watertable, bore yields, and generalised distribution of shallow

permeability in the valley. Maps of the watertable (metres above sea level) were constructed

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by subtracting the standing water level values from bore elevations. The bore elevations and

topographic data had been extrapolated from a 1 m and 5 m contour digital elevation model

(DEM) of the area. Groundwater flow was identified through the direction and magnitude of

vector arrows overlaid on the watertable map. The arrow symbol points in the “downhill”

direction and the length (magnitude) of the arrow depends on the steepness, or gradient, of

the watertable (SURFER 8, 2002). A bore yield and generalised permeability distribution

map was prepared from the driller logbook data on the yield in litres/second; while an

electrical conductivity map was prepared from EC data to determine the distribution of

salinity in the valley.

AquaChem

Various graphs and diagrams in the aqueous geochemistry package AquaChem were

used to plot the chemical character of the groundwater samples, to determine mixing and

major trends visually and to also show clustering of data points that indicate samples (water

bodies) that have similar compositions.

Scatter plots were produced to determine the major trends, patterns and relationships

between different combinations of parameters in the groundwater samples. A schoeller

diagram provided a comparison of the logarithmic concentrations of the major ions.

A trilinear diagram was used to plot together the relative percent abundance of major

ions to classify different watertypes, to interpret the chemical evolution, and to reveal

relationships or groupings of all the samples. Samples were classified by dividing the main

diamond field into nine distinct categories based upon chemical composition (Figure 13).

Figure 13. Piper classification diagram. The diamond field is divided into nine groundwater types based upon chemical composition (after Sujatha and Reddy, 2003).

Groundwater Types

1. Ca-Cl 2. Ca-HCO3,Cl 3. Ca,Na-Cl 4. Ca-HCO3 5. Ca,Na-HCO3,Cl 6. Na-Cl 7. Ca,Na-HCO3 8. Na-HCO3,Cl 9. Na-HCO3

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RESULTS

Physico-Chemical Parameters

Groundwater pH

The groundwater pH values in the study area range between pH 5.8 (bore B4 in

Highvale) to pH 8.5 (bore H2 in Draper). The highest pH value measured within the valley

itself was pH 8.0 (bores F16 and D5) but the average pH was calculated to be 6.86. The pH

was low in samples collected from around the periphery of the valley, including at Mount

Nebo (bore H3, pH 6.4). The pH was higher in samples from the middle of the valley (e.g.

D5 and D6).

A scatter plot was produced to determine whether there is a relationship between pH

and the electrical conductivity (Figure 14). The electrical conductivity axis of the graph was

given a logarithmic scale to better discriminate the distribution of samples. It is apparent that

the pH of the groundwater generally increases with increasing electrical conductivity. The

samples with lower EC and pH are mainly from recharge areas towards the valley edges.

The groundwater samples with the highest electrical conductivity and pH are mainly from

Samford or in the central area of the valley. Furthermore, seven of the ten highest electrical

conductivities are from Samford.

B4

C11

F5

G1

F9 F15

F16 D5

H2

D2

E15

B3

D6 C15

B6

Electrical Conductivity (µS/cm)

pH

Figure 1 4. Scatter plot of the relationship between electrical conductivity and pH. The pH increases with increasing EC.

H3

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A scatter plot was created to determine whether pH is influenced by the amount of

bicarbonate (Figure 15). It is evident that the pH of the groundwater generally increases with

increasing bicarbonate (HCO3). The groundwater samples with the highest bicarbonate

content are from Samford in the middle of the valley (e.g. D5, D6, D2) and they are at some

of the highest pH’s in the valley. Conversely, groundwater samples from Highvale near the

western edge of the valley have some of the lowest pH’s and bicarbonate contents (e.g. B4,

B3). All the Highvale samples have a pH of less than 7.31, and less than 365 mg/L HCO3–.

H2

F16 D5

F9 F31

B4 G1

D6

C1

D2

F5

H3 F15

Figure 15. Scatter plot of the influence of bicarbonate on pH. The pH increases with increasing bicarbonate. Samford samples (red) D5, D6 and D2 have some of the highest pH’s and bicarbonate contents.

B3

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Electrical conductivity

The quality of water from the bores in the study area varies from potable to fresh to

brackish and saline. Electrical conductivity values of the groundwater (which is a measure of

total dissolved solids – TDS) range between 142 µS/cm (bore F5, Camp Mountain) and 5980

µS/cm (bore D2, Samford). In this study, the “quality” of the groundwater is classified on the

basis of the electrical conductivity (rather than TDS content), as follows:

Of the 66 EC measurements of groundwater from throughout the whole valley, 35 are

less than 750 µS/cm, 17 values are between 750 – 2000 µS/cm, 12 are between 2000 –

5000 µS/cm, and two are greater than 5000 µS/cm (Figure 16), indicating dominantly fresh

and potable quality groundwater.

Figure 1 6. Graph of the frequency of electrical conductivity in Samford Valley. Of the 66 EC measurements of groundwater, most are less than 2000 µS/cm, indicating dominantly fresh and potable quality groundwater.

Frequency (counts) of EC values

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The contour map of the electrical conductivity of groundwater shows the spatial

distribution of salinity in Samford Valley (Figure 17). Although the contours have been

slightly skewed by a few individual bores, the electrical conductivity map of the groundwater

displays a central brackish-saline zone with values above 2000 µS/cm. Values of electrical

conductivity <2000 µS/cm are towards the edges of the valley, reflecting more direct

recharge. The distinctively brackish-saline central zone occurs mainly between South Pine

River and Samford Creek, and also extends out of the mouth of the valley.

Figure 17. Contour map of the electrical conductivity of groundwater in Samford Valley. There is a central brackish and saline quality zone above the 2000 µS/cm contours. Values of electrical conductivity <2000 µS/cm are towards the edges of the valley. An A3-size EC contour map is in the Appendix.

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To determine whether electrical conductivity is influenced by the elevation of the

water table (m ASL), a scatter plot was generated (Figure 18). The graph suggests that, in

general, higher elevations of groundwater are fresher, due to more direct recharge. For

example, the two highest EC values on the graph (bore E15 [5778 µS/cm] and E3 [3800

µS/cm], from Samford) occurred at some of the lowest relative water levels in the valley (51.2

m and 61.6 m respectively). In contrast, two of the lowest EC values (bore B2 [380 µS/cm]

and B4 [296 µS/cm], from Highvale) had some of the highest relative water levels in the

valley (133.6 m and 133.1 m respectively).

E3

E15

B4

B2

G3

G2

E8

F23

A4

C2 C4

Figure 18. Scatter plot of the influence of water level on EC, Samford Valley. The graph suggests that higher elevations of groundwater are fresher.

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Bore Yield

A contour map of the bore yields (supply in L/sec) reflects the generalised distribution

of shallow permeability in the valley (Figure 19). These values are estimates of bore

production with pumping and are conducted by drillers after the hole has been drilled. It is

apparent that the highest yields are generally obtained around the northern and southeastern

edges of the valley (at up to 1 L/sec). The lowest yield values (<0.25 L/sec) are central to the

valley between South Pine River and Samford Creek, and extend to the valley mouth. Yields

are also low along the south-southwestern margins of the valley where contact

metamorphism is well developed. Using the bore yield map to infer the generalised

distribution of shallow permeability, it is evident that shallow permeability is highest towards

the margins of the valley. However, it should be noted that there is local variability, both

laterally and with depth.

Figure 19. Contour map of bore yields and distribution of permeability in Samford Valley. Yield is highest around the northern and southern edges (at up to 1 L/sec). The lowest yields (<0.25 L/sec) are in a central zone of the valley. An A3-size generalised distribution of shallow permeability map is in the Appendix.

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Watertable

A watertable map, based on standing water levels measurements (for the period

2003 – 2007, and taken to indicate current conditions) subtracted from bore elevations (m

ASL), was developed to contour the groundwater and determine the elevation of the water

level throughout Samford Valley (Figure 20). Considering a southwest to northeast transect

through the valley, the water table has an overall mean gradient of ~10 m/km (Figure 21),

although an area in the centre of the valley (between 60 – 70 m) is of comparatively low

gradient (Figure 20). Steeper gradients of the watertable (i.e. closely spaced contour lines)

are in the west, south-southwest and in a section of the north-northeastern edge of the valley

near bore E16. It is also evident that contour lines from the northern and southern edges of

the valley (e.g. 80 m and 70 m) wrap around the central lower-watertable gradient zone.

Furthermore, it is apparent from flow arrows overlaid over the contour water map that

groundwater flows out of the valley and discharges into South Pine River north of bore G3

(Figure 22).

Figure 20. Contour map of the watertable in Samford Valley. The watertable slopes at ~10 % towards the northeast. A central area of the valley has a comparatively low gradient, and contour lines from the northern and southern edges (e.g. 80 m and 70 m) wrap around the central zone. The red line is the location of the watertable transect for Figure 21.

B

B’

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Figure 22. Contour map of the watertable and groundwater flow vectors, Samford Valley. Groundwater flows out of the valley and discharges into South Pine River north of bore G3.

Figure 2 1. Transect of the watertable from the southwest to northeast (B – B’ [Figure 20]). The water table has a mean gradient of ~10 m/km. Note: vertical exaggeration of ×50.

B B’

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A wireframe and contour map of the watertable (m ASL) and vector map were

combined to produce a groundwater flow net (Figure 23). Together they give a visual view of

the water surface in three-dimensions. The magnitude of groundwater flow is greatest from

the northern edge, as shown by the length of the arrows, determined by the computer

software from the gradient or steepness of the watertable.

The arrow symbols originate from high elevations and point “downhill” towards lower

elevations, and thus, it is evident that overall the groundwater flows from the margins of the

valley, towards and through the central lower-watertable-elevation area, and out of the valley

mouth. Figure 22 showed that the groundwater then discharges into South Pine River in the

northeast.

It is also evident that the groundwater flows below South Pine River into the central

area, as evidenced by the position of the river with respect to the relative elevation of the

water table and vector arrows (Figure 23).

LEGEND

N

(a)

Watertable Contour Line

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N

N

LEGEND

LEGEND

South Pine River

(b)

(c)

Figure 23. Groundwater flow net of Samford Valley. (a) Vector arrow symbols originate from high water table elevations and point “downhill” towards lower elevations. (b) Surface drainage systems are overlaid over the water table. (c) Groundwater flows below South Pine River, as evidenced by the position of the river with respect to the relative elevation of the water table and vector arrows. Flow is from the valley margins, through the central area, and out of the valley mouth.

Surface drainage systems

Surface drainage systems

Watertable Contour Line

Watertable Contour Line

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Hydrochemistry

Piper Trilinear Diagram

A trilinear diagram was created to classify the groundwater from different areas of the

valley, and to reveal any similarities, groupings or trends of the samples (Figure 24). The

HCO3-Cl-SO4 anion triangle shows groundwater samples have plotted between the

bicarbonate-type (HCO3) and chloride-type (Cl) end members, and sulphate (SO4) is not

present in any significant proportion. The Ca-Mg-Na cation triangle has samples clustered

off-centre towards sodium-type groundwater. These two triangles projected onto the main

diamond field account for a number of hydrochemical groupings, and the chemical character

of groundwater in Samford Valley is mainly Ca,Na-HCO3,Cl-type as evidenced by the

clustering of samples in the centre of the diamond (see Piper classification [Figure 13]). The

groundwater samples from Wights Mountain and Highvale are Ca,Na-HCO3-type to Ca,Na-

HCO3,Cl-type. Draper and Mount Nebo also have Ca,Na-HCO3,Cl-type groundwater. Camp

Mountain samples have a composition of Ca,Na-HCO3,Cl-type to Ca,Na-Cl-type except for

outlier sample F15 which is Na-HCO3,Cl-type. The Samford samples are spread over

several groundwater-types, ranging from Ca,Na-HCO3-type to Na-Cl-type, however, only the

Samford samples from the centre of the valley (D2, D5, D7) are Na-Cl-type.

Figure 24. Trilinear classification of groundwater, Samford Valley. The clustering of groundwater samples around the centre of the diamond indicates mainly Ca,Na-HCO3,Cl-type groundwater. The blue oval groups Wights Mountain samples, green rectangle is Highvale, yellow diamond is Camp Mountain and the purple oval is Draper and Mount Nebo.

D5

F15

D7 D2

G1

Cl

SO4

Ca

Mg A13

Na HCO3

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Bicarbonate and Chloride

As it was quite apparent from the anion triangle in the Piper trilinear diagram that the

groundwater samples had plotted between the bicarbonate (HCO3–) and chloride (Cl–) end

members rather than up to sulphate (Figure 24), a 1:1 scatter plot was created to examine

the trend between the HCO3 and Cl ions (Figure 25). The results showed that, overall, most

samples have a distinct enrichment of bicarbonate relative to chloride (i.e. a high ratio of

HCO3 to Cl); however, several samples have an enrichment of chloride (e.g. D2, E15, F9,

F31, F16). In the graph, sample E15 from Samford in the central zone of the valley, for

example, has a ratio of Cl/HCO3 of 2.97 (rather than 1:1) which indicates a high chloride

(salty, low bicarbonate) content, whereas F15 from near an edge of the valley has a Cl/HCO3

ratio of 0.5 which indicates a low chloride (potable, high bicarbonate) content. Furthermore, it

is evident that groundwater samples collected from the centre of the valley in the brackish-

saline quality zones (Figure 17) mostly have more chloride ions than bicarbonate ions.

F15

D5

E15, Cl/HCO3 ratio 2.97

D2

F9

F16

F31

C1 D6

B4

A3

H2

Samples from areas with salty or brackish quality groundwater

Old, evolved, mature, salty groundwater

Young, fresh, immature groundwater

B6

Figure 25. Scatter plot of the trend between bicarbonate and chloride ions. Most samples have a distinct enrichment of bicarbonate relative to chloride. The inset plot has enlarged the sample cluster to distinguish the samples.

G2

A18

B3

C15

F5

C11

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Schoeller Diagram

A Schoeller diagram is used to provide a comparison of the logarithmic

concentrations of major ions in groundwater sample pairs of different water types (Figure 27).

The results show that the concentrations of certain ions in samples from “fresh” groundwater

areas are different to the ion concentrations in “brackish-saline” samples from the middle of

the valley. The groundwater samples from the centre of the valley (D5, F9) have high

sodium and chloride, some elevation of magnesium, but low calcium. In contrast, the two

samples from fresh quality areas (A21, A22) have much lower sodium and chloride, no

elevation in magnesium, and no depletion in calcium. It is thus apparent that while there is

originally a similar proportion of calcium, sodium and magnesium ions in the fresh

groundwater (A21, A22), the calcium ion concentrations decrease and sodium ion

concentrations increase in the brackish-saline groundwater (F9, D5). The chloride ions also

have a substantial increase, however the bicarbonate ions do not.

Figure 26. Schoeller diagram of fresh and brackish-saline sample pairs. F9 (yellow) and D5 (pink) have high sodium and chloride, some elevation of magnesium, but low calcium. A21 (green) and A22 (green) have much lower sodium and chloride, no elevation in magnesium, and no depletion in calcium.

Major Ions

Recharge areas

Central zone of valley

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Calcium and Sulphate

To confirm whether there is a relationship between calcium and sulphate ions a

scatter plot was generated (Figure 27). The results show three distinct groupings. Group ‘A’

has comparatively lower calcium and sulphate, group ‘B’ has higher sulphate but low

calcium, and group ‘C’ has higher calcium and a spread of sulphate. Samples from the lower

calcium and sulphate group are predominantly from the Wights Mountain, Highvale and

Camp Mountain areas around the valley edges or recharge areas. The comparatively high

calcium samples are mainly from the Samford areas of the middle of the valley. The high

sulphate group ‘B’ groundwater samples are spread throughout the valley, but include

samples such as B6 from the Samford Showgrounds.

Figure 27. Scatter plot of the relationship between calcium and sulphate ions. Group A has comparatively lower calcium and sulphate, group B has higher sulphate but low calcium, and group C has higher calcium than the others.

E15

D2

F31

F9

A4

E12

B6

C1 A22

C20

E13

F5

E1 D5

G1

H2 F2

Recharge area

More evolved waters

C

A B

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Calcium, Magnesium and Chloride

A scatter plot was used to make a comparison of calcium and magnesium ions to

chloride ions (Figure 28). The results showed a positive relationship between calcium plus

magnesium concentrations (Ca + Mg) and chloride ion concentrations (Cl). Groundwater

samples from Highvale, Draper and Mount Nebo are grouped below 140 ppm chloride and

80 ppm Ca + Mg (except B6 [with 170 ppm Cl]). Most of the samples with high chloride and

high Ca + Mg are from Samford, and the highest values (e.g. E15 and D2) are from the

central zone of the valley.

F15

F31

D2

E15

F16 D5

F9

Figure 28. Scatter plot comparing calcium plus magnesium to chloride ions, Samford Valley. Ca + Mg increases with increasing chloride.

Recharge area

B6

C1

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Sodium, Calcium and Total Dissolved Solids

To determine whether the proportion of sodium to calcium is dependent on total

dissolved solids (TDS, a measure of EC) a scatter plot was developed (Figure 29). Around

three-quarters of the samples are below 1000 mg/L TDS indicating that these groundwater

samples waters have a low content of soluble salts. There is also a low Na/Ca ratio below

~1000 mg/L TDS. Above ~1000 mg/L TDS there is scatter; however, Na/Ca generally

increases with increasing TDS. In particular, Samford samples collected from the central

part of the valley are mainly scattered above 1000 mg/L TDS, and have an increasing Na/Ca

ratio as TDS increases.

Figure 29. Scatter plot of the dependence of sodium to calcium on TDS. Around three-quarters of the samples are below 1000 mg/L TDS indicating a low content of soluble salts. Samford samples (red) are mainly scattered above 1000 mg/L TDS and have an increasing Na/Ca ratio as TDS increases.

Total Dissolved Solids (mg/L)

Fresh

D5

H2

D2

E15

C1

F5

F9 F16

B4

A13

B6

A21 A22

D6

D7 E12

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DISCUSSION

Bore Yield and Permeability

The contour map of estimated bore yield indicates higher permeability and flow (>0.5

L/sec) towards the margins of the valley floor (Figure 19). Areas of higher yield in the valley

imply greater shallow permeability produced by the fractured or weathered granodiorite

(Dewandel et al., 2006). These areas are also likely to contain groundwater under a higher

hydraulic head (Stober and Bucher, 2007). Central to the valley and extending to its mouth

in the northeast is a lower permeability zone with yields of <0.25 L/sec. A reason may be

that large fractures that drain the porous weathered rock are connected to the high yielding

bores at the valley edges, whereas the central zone may have deeper permeability, or

possibly reduced permeability as a result of the long weathering history of the granodiorite

(Davis and DeWiest, 1991). Bore D4, for example, is found in the central zone and has the

thickest weathering zone of the valley (29 m thick). The prolonged weathering and removal

of both biotite and plagioclase must have resulted in significant amounts of silica (quartz),

kaolinite and other clay minerals left as remnant material, which would have reduced the

available permeability (e.g. by kaolinisation) (Dewandel et al., 2006). There may also be fine

clays deposited into fracture systems. Furthermore, the bores in the permeable zones will be

more likely to provide less-mineralised groundwater than less-permeable zones, due to a

shorter period of groundwater contact with the aquifer materials (Al-Khashman, 2007). In

addition, the less-permeable zone in the south-southwest can be related to hornfels in the

contact metamorphic zone (Figure 8).

Interestingly, Davis and DeWiest (1991) found topography is an important indication

of bore yield, whereby bores in flat areas and in gullies tend to produce larger amounts of

water than bores on hill tops, because groundwater drains to points of discharge in low lying

areas. The local drillers in Samford Valley also tend to drill groundwater bores in gullies and

in the weathered zone to <20 m, and have stated that hard granite, and high elevations up-

gully tend to provide limited amounts of water. However, the bore yield maps have shown

that the elevated areas (e.g. in the north of the valley) do not produce limited amounts of

water, possibly due to a higher hydraulic head of the water table with higher elevations in the

valley. Furthermore, there may not be a significant influence of topography on bore yield in

Samford Valley because granitic terrains have extreme spatial variability in hydraulic

conductivity (Cook, 2003). For example, extensive networks of connected fractures around

the edges of the valley may be draining weathered rock to provide the high yields (Davis and

DeWiest, 1991). Hence, high bore productivity in most granitic terrains may simply depend

on the luck of drilling into a fracture or highly weathered zone, rather than any influence of

topography. Nevertheless, on smaller scale areas of the valley floor, it is possible the

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Bronwyn Jones

topography (bore elevation) may influence the yield or performance of some bores (as Davis

and DeWiest [1991] suggested), because Van Genderen (1966) noted in his soil, slope and

landuse study of the area that the depressions and concave slopes of the valley tend to

accumulate water, while the mounds and convex surfaces shed water.

Watertable

The watertable surface has an overall mean gradient of ~10 m/km towards the

northeast (Figure 21), which follows the overall mean slope of the topography in the valley (of

~10 m/km towards the northeast). Therefore, the differences in the surface topography are

mirrored in the changes of the watertable, and the groundwater flow system has developed

driven by a watertable surface that is a subdued replica of the land surface (Umar, 2006;

Huggett, 2003; Sophocleous, 2002). A scatter plot also confirms that topography (based on

bore elevations in m ASL) does influence the watertable as evidenced by the increasing

linear trend (Figure 30 below).

A very steep watertable gradient often reflects low permeability (Stober and Bucher,

2007). The steep gradient of the watertable in the south-southwest therefore reflects the low

permeability of the hornfels in the contact metamorphic zone. The lower watertable

gradients in the south-southeast and north reflect the highest bore yields and greatest

shallow permeability of the valley. However, the low watertable gradient in the centre of the

valley reflects a reduced permeability zone, possibly as a result of the long weathering

history of the granodiorite, formation of clay material and kaolinisation (Dewandel et al.,

2006). Furthermore, the north-northeastern edge of the valley has a steep watertable

gradient, high watertable elevations and higher magnitude of flow than other areas of the

valley (Figure 22, Figure 23); however, high bore yields and shallow permeability are in the

northern section (Figure 19). The higher elevations of the watertable in the north-northeast

of the valley may indicate a high hydraulic head related to recharge, possibly with networks

of connected fractures, which would provide the higher bore yields and high permeability

(Davis and DeWiest, 1991).

Besides topography, other major factors controlling the water level may be the

amount of rainfall, evaporation and pumping of bores. For example, during drought the water

table tends to flatten out (ADITC, 1992). The main sources of recharge for groundwater in

the area are direct precipitation, groundwater flow, infiltration, and seepage from South Pine

River. Recharge in the west of the valley would be rainfall, especially since rainfall is higher

due to an orographic effect. The east would mainly be receiving infiltration and groundwater

flow.

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The flow net shows that groundwater flows below South Pine River (i.e. the river is

above the watertable), indicating that the river is influent (losing in nature) (Sophocleous,

2002). This is consistent with the knowledge that South Pine River has an ephemeral flow

and that during dry periods of the year (when there is low precipitation) flow ceases over

much of the length of the river; otherwise, it would flow all year round. However, during high

rainfall around the northern ranges and with an increase in the groundwater level, South Pine

River may receive baseflow (Sophocleous, 2002). It is also possible that groundwater

flowing into the central lower-watertable area of the valley may be “ponding”.

Figure 30. Scatter plot confirming the influence of topography on the water level. The increasing linear trend confirms that the topography (bore elevation in m ASL) influences the watertable.

This side of linear trend bore elevation is dominant

C18

A4

B2

A22 A20

G3

F9

A19

E3 D6

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Groundwater pH

Rainfall in the Brisbane region is acidic from CO2 and typically has a pH of 4.5 to 5.5

(Cox et al., 1996). The groundwaters with more direct recharge and low electrical

conductivity (such as at Mount Nebo) typically have a slightly acid pH of 5.8 to 6.7 (Figure

14); the migration of groundwater towards the centre of the valley has produced more

alkaline-natured water with a pH of up to ~8 (Figure 15).

The low EC of the recharging rainwater reflects the low content of total dissolved

solids or soluble salts (Water Commission, 1988). The increase in alkalinity of the measured

pH values in groundwater samples distributed towards the centre of the valley is attributed to

an increase in the amount of bicarbonate in the groundwater (as evidenced by the correlation

between pH and bicarbonate [Figure 15]). Bicarbonate is derived from carbon dioxide (CO2)

dissolved in rainwater in the atmosphere or extracted from the air through natural weathering

(Al-Khashman, 2007). Hiscock (2005) also states that dissolved carbon dioxide (CO2) in the

groundwater produces a weakly acidic solution of carbonic acid (H2CO3), which promotes the

weathering of silicate minerals. Thus, the weathering of silicate minerals such as augite in

the granodiorite over time may have released Ca2+ and HCO3– ions to the groundwater,

resulting in an increase in pH (Locsey and Cox, 2003). It is also possible that the cement

grout used during construction of the bore, which is composed of a limestone-clay mixture

(that forms concrete when mixed with water, sand and aggregate), may have leached and

raised the pH and alkalinity for a few bores (ADITC, 1992).

Elevated pH and alkalinity is an indication of mature groundwater (Banks et al.,

1998), thus this initially indicates that the groundwaters in the centre of the valley may be

more mature or evolved than around the edges.

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0

50

100

150

200

250

300

350

400

450

0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 8000 8500

Length (m)

Ele

vatio

n (m

AS

L)

Groundwater Chemistry

Piper Trilinear Diagram

Stober and Bucher (2007) studied the relationship between groundwater chemistry

and groundwater flow and concluded that groundwater evolves naturally from a bicarbonate-

type water in recharge areas to chloride-dominated water in discharge areas. The overall

chemical character of groundwater in Samford Valley is mainly Ca,Na-HCO3,Cl-type (Figure

24), indicating the groundwaters are at different stages of evolution between the young, fresh

Ca-HCO3-type water in recharge areas to more mature Na-Cl-type waters in discharge areas

such as Samford in the middle of the valley (Gascoyne, 1997) (e.g. Figure 31).

The Ca,Na-HCO3-type to Ca,Na-HCO3,Cl-type encompassing the groundwater from

Wights Mountain and Highvale are at an earlier stage of travelling along a recharge-to-

discharge flow path in the valley than Samford, because they contain more bicarbonate than

the Na-Cl-type groundwaters.

Furthermore, Hiscock (2005) states that dissolved carbon dioxide (CO2) in the

groundwater produces a weakly acidic solution of carbonic acid (H2CO3), which itself

dissociates and promotes the dissolution of calcium and sodium giving a Ca,Na-HCO3 water

type. Thus, the chemistry of the groundwaters and especially of the major cations is

controlled by local rock compositions, whereby substitution or ion exchanges occur during

the rock-water interactions as the groundwater is migrating along the flow path from recharge

to discharge areas (Frape et al., 1984).

Figure 31. Summary of groundwater composition trend, Samford Valley. The freshly recharged groundwaters are mostly Ca,Na-HCO3 type, while the central zone has evolved to Na-Cl type.

Recharge from rain

Na-Cl type pH: 8.0 EC: >5000 µS/cm

Ca,Na-HCO3 type EC: <750 µS/cm pH: 5.8

Ca,Na-HCO3,Cl type EC: ~ 2000 µS/cm pH: 7.1

Increasing distance from recharge area over time

NORTH SOUTH

South Pine River

Note: vertical exaggeration of ×10

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Bicarbonate and Chloride

Bicarbonate is typically the dominant chemical constituent in young, freshly recharged

groundwater (Stober and Bucher, 2007). The low chloride, high bicarbonate (potable)

Cl/HCO3 ratios of ~0.5 near the periphery of the valley confirms that those groundwaters are

in recharge zones (e.g. recharged more directly by rainwater) (Figure 25).

In contrast, high chloride values are associated with more mature, brackish-saline

quality groundwater indicating that the high chloride (salty, low bicarbonate) Cl/HCO3 ratios

of ~2.97 (rather than 1:1) from the central area of the valley are more evolved (Gascoyne,

1997). However, as a comparison to the groundwaters of Samford Valley that are ~25 km

inland, the seawater off southeast Queensland is very highly enriched with chloride and has

a Cl/HCO3 ratio of 140 (e.g. chloride ions are dominant in seawater with 150 mg/L HCO3–

and 21 000 mg/L Cl– [Cox et al., 2006]).

Chloride is a conservative ion that is not elevated in concentration by ion-exchange

with rocks in the aquifers. Thus, groundwater in the middle of the valley receives

groundwater that has percolated or flowed from surrounding recharge areas and evolved and

matured over time, with the chloride ions only accumulating through concentration

processes, and possibly evaporation (Wen et al., 2005)

Schoeller Diagram

Cox et al. (1996) noted that chemical reactions between groundwater and aquifer

materials can be established by comparing groundwater from recharge and discharge areas.

Considering the Samford Granodiorite is very deeply weathered, rock-water interactions in

the aquifers can explain the increase and decrease in ion concentrations as the groundwater

evolves from the fresh to brackish-saline quality areas (Figure 26). The likely water-rock

reactions controlling the hydrochemistry of the granodioritic aquifers are predominantly the

dissociation weathering of silicate minerals, with the subsequent released of ions into the

groundwater (Locsey and Cox, 2003).

Calcium ions (Ca2+) are exchanged or substituted for sodium ions (Na+ + K+, or 2Na+)

in the groundwater because of their similar ionic-exchange capacity (2+ ionic charge). The

feldspars in the Samford Granodiorite are the main source contributing to the increased

amount of sodium in the groundwater, derived directly from the solution of minerals such as

andesine (50 – 70 % albite [NaAlSi3O8]) (Al-Khashman, 2007). McMahon (1995) also noted

in his groundwater study that recharge waters have approximately equal proportions of

calcium, sodium and magnesium, but then calcium ions precipitate out as salts as the EC

increases. The magnesium ions may be produced from the weathering of the mafic minerals

in the granodiorite including biotite, hornblende, and pyroxene (e.g. the diopsidic augite).

The chloride content increases from the fresh to brackish-saline quality areas through

processes of accumulation and concentration, and possibly evaporation, because, as

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mentioned in the previous section, chloride ions are not elevated in concentration by ion-

exchange in rocks (Wen et al., 2005).

In addition to the rock-water ionic-exchanges as groundwater migrates, the

composition or quality of the source (recharge) water may also influence the hydrochemistry

(Misra and Mishra, 2006). Considering a rainfall source in Samford Valley (Figure 5), a

prevailing wind and rain from the coming from the southeast direction of the coast may be

depositing slightly more sodium and chloride than rain falling in the northwestern ranges

(where rainfall is ~1400 mm/year). The minute quantities of Cl–, Na+ and other salts

dissolved in the rainwater from the coast would be added to the groundwater in the southeast

and east of the valley, thus influencing the groundwater chemistry to a degree (Misra and

Mishra, 2006). Conversely, the concentration of salts in the northwestern ranges rainfall may

be negligible and the recharge source would contain a higher proportion of bicarbonate.

Calcium and Sulphate

Highvale, Wights Mountain and Camp Mountain around the valley edges

predominantly have relatively lower calcium and sulphate than central areas of the valley

(Figure 27). These are recharge areas because fresh, geochemically immature recharge

waters are calcium-bicarbonate-type but increase in calcium and accumulate more sulphate

only as the groundwaters evolve as they flow from recharge to discharge areas (Ophori and

Toth, 1989).

The much higher calcium groundwaters in the centre of the valley are largely due to

an accumulation of calcium ions over time. The groundwater has flowed slowly from the

recharge areas and calcium has become concentrated due to the long residence times, and

possibly by evaporation of the shallow groundwater. It is also possible that the high calcium

is artificial, and that cement grout (a limestone-clay mixture) used during construction of the

bore, may have leached minor amounts of calcium ions to the groundwater in a few bores

(ADITC, 1992).

The comparatively high sulphate in the groundwater from the Samford areas of the

middle of the valley is either from a lithological source (e.g. pyrite-derived sulphate), or

possibly due to anthropogenic activities (Al-Khashman, 2007). Hiscock (2005) and Ophori

and Toth (1989) have stated that groundwaters tend to have higher sulphate the further they

have travelled long a flow path, and in the valley, groundwater flows from peripheral recharge

areas towards higher sulphate areas around the central zone and Samford. The oxidation of

sulphide minerals during groundwater migration can serve as a lithological source of

sulphate (SO42–). Pyrite (FeS2) is commonly a minor accessory mineral in igneous rocks and

its oxidation in the aquifers may have contributed to the higher sulphate levels in some areas

(Al-Khashman, 2007). Gradwell (1955) also suggested that there may be minor pyrrhotite

(Fe1–xS [x = 0 – 0.2]) in association with the magnetite in the Samford Granodiorite.

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Some groundwaters in the area may have suffered sulphate contamination,

especially considering horses or livestock are allowed in the immediate vicinity of the

boreholes on many properties. The Samford showgrounds is one such location where

sulphate is relatively high and horses regularly train. Thus, in these areas the horses are

generating manure, which contains sulphur (a portion of which is readily available as

sulphate) that may be washed into the groundwater. However, considering only Samford

Village is connected to a sewerage system and the remainder of the valley uses some form

of septic system, the elevated sulphate ions are most likely due to percolation from septic

tanks or domestic effluents. It is known that the surface waters of Samford Creek and South

Pine River are degraded with nutrients and coliform bacteria (Figure 32; Nolte and Loose,

2004), and human faecal material contains large numbers of coliform bacteria and sulphur,

which supports the conclusion that the higher sulphate content in some groundwaters may

be non-lithological, from leaking septic tanks.

Figure 32. The degraded upper reaches of Samford Creek, Samford Valley. The creek is of poor water quality and degraded with nutrients and coliform bacteria. Blue-green algae (cyanobacteria) such as Nostoc sp. are abundant (Nolte and Loose, 2004).

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Calcium, Magnesium and Chloride

Calcium and magnesium ions increased in concentration in the groundwater with

increasing chloride (Figure 28), reflecting that as the groundwater evolves towards the centre

of the valley, Ca2+ and Mg2+ ions in the groundwater may be derived from secondary

sources, such as rock-water interactions (Wen et al., 2005). The chloride ions concentrate in

groundwater along flowpaths over time, and the feldspars, calcic-magnesium silicates, and

clay minerals within the deeply weathered granodiorite are substituting or exchanging ions to

account for the increase in Ca2+ and Mg2+ as the groundwater migrates (Trainer, 1988).

Calcium and magnesium salts would also be precipitating as the groundwater becomes

saturated with the ions (Stober and Bucher, 2007).

In addition, Misra and Mishra (2006) found from their study in India that the

concentrations of some chemical constituents can escalate in an aquifer with time, especially

with low precipitation and high evaporation. The high calcium and magnesium “hard”

groundwaters at the lower topographic elevations in the centre of the valley may be reflecting

the effect of evaporation.

Sodium, Calcium and Total Dissolved Solids

The recharge groundwaters around the margins of the valley have a lower amount of

total dissolved solids and are less hard than groundwaters further down flow (Figure 29). As

flow towards the low-lying areas may be slow (e.g. compared to surface water), the

groundwater is in contact with the weathered granodioritic material for a long time, and

soluble salts in the weathered granodiorite are dissolved and carried in the groundwater in

solution (Wen et al., 2005). Thus, groundwater carries more total dissolved solids (TDS)

over time, which results in brackish-saline and “hard” waters (high in calcium and magnesium

carbonates) (ADITC, 1992). Higher amounts of TDS in the central zone of the valley may

also be from salts concentrated in the shallow groundwater by evaporation.

Therefore, at the early stages of groundwater evolution, the fresh, geochemically

immature Ca-HCO3-type water from around the edges of the valley has a low content of

soluble salts (Rao et al., 1997). During migration downslope along flow paths towards the

middle of the valley, the initial low mineralisation gradually increases as Na+ replaces Ca2+ in

solution, evolving the groundwater to a more highly Na-HCO3 and Na-Cl-type (high Na/Ca

ratio) water (Hiscock, 2005; Stober and Bucher, 2007).

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Distribution of Salinity

Electrical conductivity (EC) reflects the amount of soluble salts in a water sample, and

is one way of measuring salinity (Water Commission, 1988). About two-thirds of

groundwater in the valley has an EC below 2000 µS/cm, predominantly at higher water table

elevations towards the margins of the valley (Figure 17, Figure 18), indicating that these

waters have a low content of soluble salts, supporting more direct recharge (Rao et al.,

1997). The low EC recharging rainwater groundwater has filled fracture systems around the

edges of the valley and is being extracted before it has been allowed to percolate to any

great depth or distance (Sukhija et al., 2006). In contrast, the groundwater in the centre of

the valley has flowed there over time and evolved to be more geochemically mature and

hence more saline than the young, fresh, immature and generally good quality recharge

groundwaters around the margins of the valley.

There are several further explanations for the elevated EC central to the valley.

Dissolved salts occur naturally in groundwater, and although the conductivity test does not

identify the particular salts involved, the major ions responsible for the salinity are usually

Na+, K+, Ca2+, Mg2+ and Cl– (Misra and Mishra, 2006). The origin of the salinity (high EC) is

also the result of rock-water interactions, and ion exchanges due to a long period of contact

with rocks and minerals (Al-Khashman, 2007). The results from the hydrogeology of

Samford Valley revealed that, in general, the areas in the centre of the valley (with the

highest EC values), such as around bore D4 have the thickest weathered zone (29 m thick).

Thus, the abundant silicate minerals, feldspars and clay minerals within the deeply

weathered granodiorite have undergone ion-exchange and weathered to solution. In

particular, the amount of sodium ions has been elevated as the groundwater travels along

the flow paths to the low lying area. Thus, the salinity of the groundwater in the central part

of the valley is mainly due to the accumulation of the salts, as a result of rock-water

interactions, by the continual movement of groundwater flowing towards and through the

central lower-elevation area and concentrating dissolved ions (Rao et al., 1997).

Low precipitation and high evaporation are also dominant processes determining the

water composition and enhancing salinity (Wen et al., 2005). Misra and Mishra (2006)

determined in their hydrochemical study in India that salinity and some chemical constituents

(namely Na, Cl, TDS, K, F) can escalate with time in the aquifer, especially with low

precipitation and high evaporation. This is because when moisture is evaporated from the

shallow unsaturated zone, the remaining water is concentrated with dissolved ions from

chemical weathering, leading to the precipitation of salts and enhanced salinity (Sreedevi et

al., 2006). The low precipitation and slow groundwater flow in the present study area may

have therefore made the groundwater more prone to enhanced evaporation and salinisation

(Misra and Mishra, 2006).

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CONCLUSIONS

In Samford Valley, groundwater occurs under unconfined or semi-confined conditions

and the aquifers are mainly in highly weathered or fractured granodiorite. There is a central

zone of salinity, with associated Na-Cl-type groundwater, elevated pH, high amount of total

dissolved solids (TDS), comparatively higher sulphate content, and high Cl–/HCO3– ratios, all

indicative of mature and evolved groundwater. The central zone of mature, saline

groundwater is attributed to the accumulation of salts as the groundwater evolved along

flowpaths from the higher-elevation recharge areas at the edges of the valley to the low lying

central discharge area. The salts are a product of rock-water interactions and ion exchanges

within the feldspars, silicate minerals and clay minerals of the deeply weathered granodioritic

aquifers, which have concentrated in the centre of the valley over time. It has also been

concluded that the low rainfall and high evaporation climatic conditions have enhanced

salinity over time.

The results also suggested that the low EC, fresh, bicarbonate-type groundwater in

fracture systems around the edges of the valley is recharging more directly from rainwater

and is extracted early in its migration. Thus, the Ca,Na-HCO3-type to Ca,Na-HCO3-Cl-type

groundwaters have not evolved far from the fresh rainwater that recharged them.

The groundwater flow is driven by a gently sloping watertable that is influenced by the

surface topography, whereby groundwater flows from the margins of the valley, towards and

through the central area, out of the valley mouth, and discharges into South Pine River in the

northeast. It is possible that the central low-watertable area may be ponding groundwater.

Shallow permeability and bore yields are highest around the valley edges and lowest

in the central zone, however the thickest weathered zone is in the centre of the valley. The

prolonged in situ weathering history of the granodiorite and the formation of silica, kaolinite

and clays as remnant material may have reduced shallow permeability in the centre of

Samford Valley. Connective fracture systems draining the porous weathered rock have

contributed to the high permeability and high yield of the bores around the northern and

southern valley edges.

Overall, useful information was gained with respect to the chemical quality, chemical

variations, bore yields and occurrence of the groundwater in the valley. This groundwater

study has provided important groundwater resource maps, including maps of the generalised

distribution of shallow permeability and salinity, which will allow a better assessment of the

potential groundwater resources of the valley. Most importantly, a comprehensive

groundwater bore inventory for Samford Valley was compiled, and it will be a useful record or

reference for future studies. Further studies may be needed in order to assess the relative

importance of the findings of this groundwater study, so that the local resource can be

managed for the future.

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TRAINER, F. W. 1988. Plutonic and Metamorphic Rocks. In: BACK, W., ROSENHEIM, J.

S., & SEABER, P. R. Eds. 1988. The Geology of North America: Hydrogeology.

The Geological Society of America.

UMAR, R. 2006. Hydrogeological environment and groundwater occurrences of the

alluvial aquifers in parts of the Central Ganga Plain, Uttar Pradesh, India.

Hydrogeology Journal. 14, 969 – 978.

VAN GENDEREN, J. L. 1966. The Relationship between Soils, Slopes & Land Use in the

Samford Basin. Unpublished BA(Geography) Honours Thesis. University of

Queensland.

WARD, G. 2007. General information about Samford Valley. Personal comments to B Jones.

WATER COMMISSION. 1988. Water Analysis for Irrigation: Information Bulletin.

Queensland State Government Water Resources Commission Office, Australia.

WEN, X., WU, Y., SU, J., ZHANG, Y., & LIU, F. 2005. Hydrochemical characteristics and

salinity of groundwater in the Ejina Basin, Northwestern China. Environmental

Geology. 48, 665 – 675.

WILLMOTT, W. 2004. Rocks and Landscapes of the National Parks of Southern

Queensland. Geological Society of Australia, Queensland Division.

WILLMOTT, W., & TREZISE, D. 1984. Rocks and Landscapes of Brisbane Forest Park.

Brisbane Forest Park Authority Administration Authority, Brisbane.

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APPENDICES 1 – 4

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APPENDIX 1

Explanation of the Groundwater Inventory

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Explanation of the

Groundwater Database

for the bores of

Samford Valley, Southeast Queensland

Modified from: Queensland Government Department of Natural

Resources and Mines. 2005. Groundwater Database: Data

Dictionary & Standards. Version 6.

BRONWYN JONES

2007

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GROUNDWATER DATABASE

The groundwater database has tables that hold data relating to groundwater bores in Samford Valley.

The main data tables are:

Page

Registration Table……………………………………………………………………………………………………………….49

Field Water Quality Measurement Table……………………………………………………..…………………….57

Strata Log Table……………………………………………………………………………………………………………….…60

Casing Table………………………………………………………………………………………………………..………………62

Aquifer Table…………………………………………………………………………………………………………..………….65

Water Analysis Table……………………………………………………………………………………………………………69

Elevation & Co-ordinate Table………………………………………………………………………………………..….73

Drilling Contractor Remarks Table………………………………………………………………………………………76

Other Possible Bores in Samford Valley Table……………….………………………………………………….77

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REGISTRATION TABLE

INTRODUCTION

The records in the registration table give general registration details of the bore.

Column Names

Bore

Government Registered Number (RN)

Property Name

Field Location

Lot

Office

Shire Code

Parish

Post Code

County

Basin

Facility Type

Facility Status

District Office File Number

Regional Office File Number

Head Office File Number

File ID

Object ID

Map Scale

Map Series

Map Number

Registered Plan (RP)

Original Description

Driller Name

Drilling Company

Driller Licence Number

Drilled Date

Log Rec Date

Method of Construction

Present Equipment

Original Bore Name

Bore Role

Confidential

Data Owner

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Formation Name

Created By

Created Date

Updated By

Updated Date

Elevation

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

Government Registered Number (RN)

The government registered number is unique. Each bore, even those on the same property, are all

allocated a five or six number Registration Number (RN).

E.g.

The following list shows the Registered Number block for a few offices (30/10/2003):

Brisbane 120000 - 120999

Gatton 106000 - 106999

Oil Bores 100000 - 101999

Toowoomba 119000 - 119999

Property Name

This stores the name of the person/people who are at the property on which the bore is situated. It

can prove useful in finding all bores located on the one property. The name is either of the

person/people living at the property where the bore is located, the name of the person who owns the

property, or the person who was originally living at that address when the bore was drilled.

Field Location

The field location is used to help locate the bore in the field. It may be the residential address of the

land or property on which the bore is located, or a landmark that the bore is near.

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Lot

The lot is the number of the lot on a registered plan on which the bore is located.

Office

The office bore data is administered by each regional office. This column is a compulsory field in the

database. E.g. BNE = Brisbane

Shire

A shire represents an area of Local Government in Queensland. Each shire is named and given a

number.

Parish

The parish is required to define the location of a bore. It is necessary to code parish because there is

a number of parishes in Queensland with the same name.

E.g. 3749 = Parker,

4150 = Samford

Post Code

The post code is of the region where the bore is located.

County

The county is required to define the location of a bore. The county will be recorded by name and not

coded because county names are unique.

Basin

The basin is a four-digit number that is consistent with those numbers used by the Department to

define the surface water drainage sub-basins in Queensland. For definition of these drainage sub-

basins you should refer to the Department’s WRC plans, V38883 to V38900, or to Water Resources

basin maps.

Facility Type

This column is required to describe the type of bore about which we are recording data. The break-up

is relatively simple in that the basic distinction is between surface water and groundwater bores. A

further break-up of the groundwater bores is whether they are artesian in various conditions or sub-

artesian. This column is a compulsory field in the database.

E.g.

SF = Sub-artesian Bore

AU = Artesian Bore, Uncontrolled Flow

AC = Artesian Bore, Ceased to Flow

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AS = Artesian Bore, Seasonal Flow

Facility Status

The facility status defines whether the bore is proposed, existing, abandoned and destroyed or

abandoned but still useable. The ‘proposed’ status refers mainly to private bores that have not been

constructed. The ‘existing’ status is important for both private and Commission bores. The two states

of abandonment shown in the codes are mainly required for observation bores that are not in use but

could be re-activated easily.

Private bores that are constructed but not equipped are recorded as existing, if the intention is to use

the bore in the future. If the bore is useable but temporarily abandoned such as a stand-by bore or a

replacement bore the facility status should be recorded as abandoned but useable i.e. code ‘AU’. If it

has been destroyed it is coded ‘AD’, abandoned and destroyed.

E.g.

EX = Existing

AD = Abandoned and Destroyed

AU = Abandoned but still useable

PR = Proposed

District Office File Number

The identification of the District Office paper file in which details about the bore are contained is

entered here.

Regional Office File Number

The identification of the Regional Office paper file in which details about the bore are contained is

entered here.

Head Office File Number

The head office file number referring to the bore should be stored here.

File Number

All correspondence regarding the bore should be stored on file and the file number entered into the

GWDB for reference.

Object ID

The object ID is given by the Department of NR&W when the bore from each driller’s logbook is put

on the file, and I haven’t added any new data into this column.

Map Scale

The map scale code is a three-digit number defined in such a way that it will tell you what the actual

scale is. Consider the following examples:

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1. 1:2 500 Scale

The first two digits of the 2 500 are recorded as the first and second digit of the 3 digit number. The

number of trailing zeros after the first two digits is then recorded. i.e. 2 for the above scale. Thus the

code for 1:2 500 is 252.

2. 1:100 00 Scale

The first two digits are 10 and there are three trailing zeros therefore the code will be 103.

For the old ‘Imperial’ type maps that were used to record groundwater details the approach is simply

to use 4ML for four mile.

E.g.

1:2 500 = 252

1:5 000 = 502

1:10 000 = 103

1:25 000 = 253

1:50 000 = 503

1:100 000 = 104

4 Mile Series = 4ML

Map Series

Use this column to record the series the map used to locate the bore belongs.

E.g. M = Metric Series: These are all metric scale maps produced on the

National Mapping System.

Map Number

This is a character field, i.e. accepts both alphabetic and numeric characters. All maps have or should

have a unique identifying formatting of the numbers in this column as required for subsequent

retrieval and grouping of all the bores on a map or plan. Some maps also have names. These names

must not be entered in this column.

E.g.

The smallest scale maps are 1:250 000 and these numbers are 2 letters, 2 digits, a dash and

digits 1 to 16 e.g. SP54-8. All other maps are divisions of the 1:100000 map, which are 4

digits only. The 1:50 000 maps (e.g. 5286-2) are 4 digits, a dash and a number 1, 2, 3 or 4

where the 4 digit number is the 1:100 000 sheet and the numbers 1 to 4 are NE, SE, SW and

NW quarters respectively. Thus a 1:50 000 number looks like 5286-2. 1:25 000 maps are an

extension of the same quartering system. Thus a 1:25 000 number looks like 9443-23. 1:10

000 maps are the next breakdown and would look like 9443-224 and so forth down to the

largest scale produced.

Registered Plan

The plan or registered plan is the number of the plan that contains the lot on which the bore is

located.

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Description

This column is for the Real Property Description of the land on which the bore is located, other than a

lot and registered plan number which is provided for separately. If a lot and registered plan have been

entered in their designated columns, this column may be used to record the original portion number.

It should be noted that it is not a property description of all the land owned; it simply describes the

land on which the bore is located.

Driller Name

This column records the licence number and name of the driller who drilled the initial bore at the site.

The standard format for entering a drillers name is Lastname, Firstname Secondname (eg. Scells,

Neville Graham).

Drilling Company

The drilling company is the name of the company who drilled the initial bore at the site.

Driller Licence

This column records the licence number of the Driller who drilled the initial bore at the site.

Date Drilled

The date drilled is the date on which the drilling of the bore was completed. It stores the initial

completion date and not the date of subsequent deepening’s. The drilled date must not be greater

than the Log Rec Date.

Log Rec Date

This column records the date the drillers log has been received by the departmental office. The format

for the date must be DD/MM/YYYY (eg. 01/01/2005).

Method of Construction

The method used to construct the bore is recorded in this column.

E.g. CABLE TOOL, ROTARY AIR, PICK AND SHOVEL.

Present Equipment

This coded column is to describe the equipment on a bore. Generally it applies to the type of pump.

Allowance has also been made for automatic recorders on observation bores. A code is available for

staff gauges used to record surface water levels in groundwater investigations.

E.g.

SP = Submersible

NE = No equipment/headworks

CL = Centrifugal Pump

JP = Jet or Pressure Pump

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WL = Windmill and Cylinder Pump

WA = Windmill and Cylinder Pump, additional power

OR = Other Pump

AR = Automatic Recorder

HW = Headworks (Artesian Bores)

Original Bore Name

This column mentions the original owner of the bore, if known.

Bore Role

The bore role column stores a comment about the bore role.

E.g. WS = Water Supply

SI = Stratigraphic Investigation

PE = Petroleum or Gas Exploration

ME = Mineral or Coal Exploration

OE = Other Exploration/Investigation

Confidential

A bore which contains details that must not be released to the public is confidential. Any details on

unlicensed bores which have been collected by PWF surveys, or Groundwater Advisory jobs, or

obtained from mining companies (not on open file) fall into the category of confidential. This

information cannot be released, without the owners consent.

Data Owner

The data owner is the organisation that owns all of the data that relates to the bore and is usually

responsible for the collection of that data. Only data belonging to DNR should be released to the

public. E.g. DNR = Department of Natural Resources

Formation Name

Formation Name is the name of the geological unit containing the aquifer being recorded. The source

of data to be entered in this column is the formation name on published maps or in published

documents from either the Bureau of Mineral Resources or the Department of Mines and Energy.

Alluvium is to be treated as a lithological formation. The formation name is to consist of the name of

the river, creek or geographic feature commonly used to describe the alluvium of an area. All

formation names entered into this column are to be validated.

Created By

This column is simply from the original Department of NR&W database and includes the original

entries such ‘GW_LOAD’ and ‘BLS’, no new data has been added into this column.

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Created Date

This column has not been edited or modified from the original Department NR&W database.

Updated By

This column is simply from the original Department NR&W database and includes the original entries

such ‘GW’, and I haven’t added any new data into this column.

Updated Date

This column is simply from the original Department NR&W database and includes the original entries,

and I haven’t added any new data into this column.

Elevation

The elevation value is the elevation of the natural ground surface immediately surrounding the

borehole, either taken by a handheld GPS unit or extracted from a raster Digital Elevation Model

(DEM) of the valley using the bore co-ordinates.

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FIELD WATER QUALITY MEASUREMENT TABLE

INTRODUCTION

This table records water quality measurements that have been taken in the field. This will commonly

be from groundwater pumped straight out of the bore, or from a tap at the bore.

Column Names

Bore

Pipe

Date

Sampling Method

Source

pH

Redox Potential

Conductivity

Quality Remark

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

Pipe

There can be single or multiple pipe bores. A single pipe refers to one that operates as if it has a

single length of casing. However, by definition in the Groundwater Database, a bore with several

different diameter casings joined concentrically to effectively form a single pipe will be called a single

pipe bore. The single pipe bore is filled in with an ‘A’.

E.g. A = Single Pipe (Operates as, or effectively forms, a single pipe bore)

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Date

The date to be entered is the date on which the field measurement was taken.

Sampling Method

This column describes the method used to collect the sample.

E.g.

PU = Pump - Other or Flowing Bore

PF = Pump – Air Forced

BT = Bailer – Teflon

BA = Bailer – Other

DH = Downhole Probe

XX = Unknown

NR = Not Recorded

Source

This column describes the source of the sample. The available codes are:

GB = Groundwater - Sample from bore

GS = Groundwater - Sample from stream or spring

GR = Groundwater - Sample from remote source eg. Tank, dam

pH

The pH of the groundwater/borewater measured in the field is stored as a number.

Redox Potential (Eh)

The Eh of the groundwater taken in the field is entered here. The data must be entered in the unit of

millivolts (MV).

Conductivity

The conductivity measurement must always be converted to the correct units. The unit is

microSiemens per centimetre (µS/cm) at 25 degrees Celsius (°C).

For conversion of the conductivity measurements to µS/cm at 25 degrees Celsius (°C) from different

temperatures, the conductivity conversion multipliers are as follows:

DEGREES CELSIUS MULTIPLIERS

15 Multiply reported conductivity by 1.2

16 Multiply reported conductivity by 1.18

17 Multiply reported conductivity by 1.16

18 Multiply reported conductivity by 1.14

19 Multiply reported conductivity by 1.12

20 Multiply reported conductivity by 1.10

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21 Multiply reported conductivity by 1.08

22 Multiply reported conductivity by 1.06

23 Multiply reported conductivity by 1.04

24 Multiply reported conductivity by 1.02

25 No conversion required

26 Multiply reported conductivity by 0.98

27 Multiply reported conductivity by 0.96

28 Multiply reported conductivity by 0.94

29 Multiply reported conductivity by 0.92

30 Multiply reported conductivity by 0.90

Quality Remark

This column is used to indicate the quality of water in the aquifer. A simple comment regarding the

quality of the water is made. E.g. SALTY, POTABLE, BRACKISH, FRESH, etc.

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STRATA LOG TABLE

INTRODUCTION

The records in this table are a transcription of the strata encountered in a bore as described on the

strata log sheet completed by the driller, geologist, etc. This table must not be used for storing notes

(notes or remarks can be stored in the Drilling Contractor Remarks Table).

Column Names

Bore

Government Registered Number (RN)

Record

Strata Description or Notes

Top of Strata

Bottom of Strata

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

Government Registered Number (RN)

The government registered number is unique. Each bore, even those on the same property, are all

allocated a five or six number Registration Number (RN).

E.g.

The following list shows the Registered Number block for a few offices (30/10/2003):

Brisbane 120000 - 120999

Gatton 106000 - 106999

Oil Bores 100000 - 101999

Toowoomba 119000 - 119999

Record

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The record is the next highest level of unique identification after date. E.g. In the example below,

the records in examples 1 and 2 can be the same because they are distinguished by date. Records in

examples 2 and 3 must be different because they are on the same date.

RN Date Record No.

Example 1 100 01/01/1980 1

Example 2 100 02/01/1980 1

Example 3 100 02/01/1980 2

Strata Description

The description of strata in the interval defined by top of strata and bottom of strata fields is entered

here. If the description requires more than one record, the required records can be added without top

of strata and bottom of strata fields being repeated.

When entering strata log details into the database, the whole log, as recorded by the driller or

hydrologist is entered. Do not abbreviate the logs, i.e. do not leave out colour, granularity, or any

descriptive terms.

Top of Strata

The depth from the natural surface to the top of the strata described is recorded in this column. The

top of the strata log value must not be greater than the bottom value. Values are stored in metres

(m) to two decimal places.

Bottom of Strata

The depth from the natural surface to the bottom of the strata described is recorded in this column.

The bottom of the strata log value must not be marked with a minus sign eg. -6.00. Values are stored

in metres (m) to two decimal places.

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CASING TABLE

INTRODUCTION

This table records the bore's casing details, as detailed by the drilling contractor.

Column Names

Bore

Pipe

Date

Record

Material Description

Material Size

Material Size Description

Outside Diameter

Top of Material

Bottom of Material

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

Pipe

There can be single or multiple pipe bores. A single pipe refers to one that operates as if it has a

single length of casing. However, by definition in the Groundwater Database, a bore with several

different diameter casings joined concentrically to effectively form a single pipe will be called a single

pipe bore. The single pipe bore is filled in with an ‘A’.

E.g. A = Single Pipe (Operates as, or effectively forms, a single pipe bore)

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Date

The date to be entered is the date on which the bore was completed.

Record

The record is the next highest level of unique identification after date. E.g. In the example below,

the records in examples 1 and 2 can be the same because they are distinguished by date. Records in

examples 2 and 3 must be different because they are on the same date.

RN Date Record No.

Example 1 100 01/01/1980 1

Example 2 100 02/01/1980 1

Example 3 100 02/01/1980 2

Material Description

Material description defines the type of material described in the record. It could be steel casing, PVC

casing, etc. Some of the coded values for material description include:

E.g.

PVC = Polyvinyl Chloride

PERF = Perforated or Slotted Casing Section

GRAV = Gravel Pack

FILL = Cuttings or other fill between casing

GROU = Cement Grout

STEL = Steel Casing (unspecified)

BNSL = Bentonite Seal

PLAS = Plastic Casing (unspecified)

SCRN = Screen

OPEN = Open Hole (Section of bore uncased)

SSL = Stainless Steel

FRP = Fibreglass Reinforced Plastic

Material Size

The material size describes the wall thickness of a length of casing or aperture of a screen, etc. For a

gravel pack, the nominal gravel size (i.e. sieve size that all gravel passes) is entered. Values are

stored in millimetres (mm) to three decimal places.

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Material Size Description

The material size description identifies what attribute the material size field is measuring. It must have

one of the following three codes.

E.g. WT = Wall Thickness of casing (e.g. PVC casing is WT)

AP = Aperture Size for Screens, Slots, Perforations (eg Perforated sections are AP)

GR = Gravel Packs; Nominal gravel size (e.g. Gravel Packing is GR)

Note: If you have a material description of GRAV (gravel) you can not have a size description of AP or

WT. Also if you have a material description of PERF or SCRN you can not have a size description of GR

or WT.

Outside Diameter

The outside diameter of the material is entered in this column. The term diameter has been chosen

because the majority of the bores are circular in shape. Values are stored in mm’s.

Top of Material

This column defines the depth from the natural surface to the top of the material being described in

the record. The top of the casing value must not be greater than the bottom value. For a string of

casing with slots/perforations the total length of the string is entered as one record (perforated

section included). A further record/s is then entered identifying where the slots/perforations occur.

Values are stored in metres (m) to one decimal place.

Bottom of Material

This column defines the depth from the natural surface to the bottom of the material being described

in the record. The bottom of the casing value must not be marked with a minus sign eg. -6.00. For a

string of casing with slots/perforations the total length of the string is entered as one record

(perforated section included). A further record/s is then entered identifying where the

slots/perforations occur. Values are stored in metres (m) to one decimal place.

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AQUIFER TABLE

INTRODUCTION

The purpose of this table is to record information about the permeable water bearing beds

encountered by a bore penetrating a single geological unit or a number of geological units.

Column Names

Bore

Date

Record

Condition

Total Bore Depth

Water Struck At

Standing Water Level

Yield

Top of Aquifer

Bottom of Aquifer

Contributing Aquifer

Flow Indicator

Water Table (ASL)

General Aquifer Material

Other Notes

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

Date

The date is the date on which the drilling of the bore was completed. It stores the initial completion

date and not the date of subsequent deepening’s.

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Record

The record is the next highest level of unique identification after date. E.g. In the example below,

the records in examples 1 and 2 can be the same because they are distinguished by date. Records in

examples 2 and 3 must be different because they are on the same date.

RN Date Record No.

Example 1 100 01/01/1980 1

Example 2 100 02/01/1980 1

Example 3 100 02/01/1980 2

Condition

Condition refers to the hydrological and physical condition of the material in the bed. However, the

hydrological aspect is dominant. Basically, the condition is determined by the mechanism by which

water is transmitted in the rock mass, i.e. is the water transmitted via pores, between grains or via

fractures in the rock mass?

E.g.

Porous Rocks

UC = Unconsolidated

PS = Consolidated

SC = Semi-Consolidated

Fractured Rocks

FR = Fractured

VS = Vesicular

CV = Cavernous

WZ = Weathered Zone

Total Bore Depth

This column gives the total depth of the bore in metres (m) below the ground when the bore was

drilled.

Water Struck At

This column states the depth/s that water was struck at in metres below ground level (m bgl) when

the bore was drilled.

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Standing Water Level

The standing water level (SWL) of the aquifer when drilled is used to record the water level or static

head measured from the natural surface for each aquifer when the bore was drilled. Water levels

below ground level must be entered as a negative. If the bore is flowing the static head is entered as

a positive measurement above ground level. Values are stored in metres (m) to two decimal places.

Yield

The yield from an aquifer is stored as an estimate of the yield from the aquifer. The estimate may be

obtained by bailing, air test, pump test, flow test, etc. Values are stored in litres/second (L/sec) to

two decimal places.

Top of Aquifer

The depth from the natural surface to the top of the aquifer described is recorded in this column. The

top of the aquifer value must not be greater than the bottom value. Values are stored in metres (m)

to two decimal places.

Bottom of Aquifer

The depth from the natural surface to the bottom of the aquifer described is recorded in this column.

The bottom of the aquifer value must not be marked with a minus sign, e.g. -6.00. Values are stored

in metres (m) to two decimal places.

Contributing Aquifer

The contributing aquifer column is completed with ‘Y’ (Yes) if the Aquifer contributes to the supply in

the completed bore. If the aquifer is not contributing to the supply of the completed bore then it is

completed with ‘N’ (No).

Flow Indicator

In many cases it is known that an aquifer has yielded a flowing water supply, however there are no

details of the static head. This column indicates whether or not the water level of the aquifer rose

above ground level, i.e. whether or not a flow was encountered. If a flow is encountered in the

aquifer specified, ‘Y’ is entered. If the water level is below ground level ‘N’ is entered.

Water Table (ASL)

This column provides the elevation of the water table above sea level. It has been calculated from

the standing water level (SWL) and elevation data.

CRICOS No. 00213J

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General Aquifer Material

The material the water is in is simply the aquifer material. E.g. Deco or Weathered granite, Fresh

granite, Fractured granite, Alluvium, Metamorphic Rock, etc.

Other Notes

In this column a brief comment can be made about the bore or aquifer, etc. E.g. the location of the

bore such as in a natural gully; or in backyard, a flat area with all trees; etc.

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Bronwyn Jones

WATER ANALYSIS TABLE

INTRODUCTION

The water analysis table stores the results of chemical analyses performed on the

groundwater/borewater samples by an analyst.

Column Names

Bore

Pipe

Date Tested

Record

Analyst

Analysis Number

Sampling Method

Source

Depth

Figure of Merit (Ratio) *

Sodium Adsorption Ratio *

Residual Alkalinity Hazard *

Total Dissolved Ions *

Total Dissolved Solids *

Hardness

Alkalinity

Silica (SiO2)

Aluminium (Al)

Strontium (Sr)

Manganese (Mn)

Iron (Fe)

Magnesium (Mg)

Sodium (Na)

Calcium (Ca)

Zinc (Zn)

Copper (Cu)

Potassium (K)

Bicarbonate (HCO3-)

Carbonate (CO32-)

Chloride (Cl-)

Fluoride (F-)

Bromide (Br-)

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Bronwyn Jones

Nitrate (NO3-)

Phosphate (PO43-)

Sulphate (SO42-)

* Note: These values are calculated (See ‘Chemical Data – IONS’ below)

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

Pipe

There can be single or multiple pipe bores. A single pipe refers to one that operates as if it has a

single length of casing. However, by definition in the Groundwater Database, a bore with several

different diameter casings joined concentrically to effectively form a single pipe will be called a single

pipe bore. The single pipe bore is filled in with an ‘A’.

E.g. A = Single Pipe (Operates as, or effectively forms, a single pipe bore)

Date Tested

The date to be entered is the date on which the water sample was analysed in the lab.

Record

The record is the next highest level of unique identification after date. E.g. In the example below,

the records in examples 1 and 2 can be the same because they are distinguished by date. Records in

examples 2 and 3 must be different because they are on the same date.

RN Date Record No.

Example 1 100 01/01/1980 1

Example 2 100 02/01/1980 1

Example 3 100 02/01/1980 2

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Bronwyn Jones

Analyst

The analyst column defines who performed the chemical analysis of the water sample.

E.g.

GCL = Government Chemical Laboratory

DPI = Qld Department of Primary Industries Agricultural Chemist

B Jones@QUT = QUT NRS Honours Student (2007) Miss Bronwyn Jones

PRSC = Pine Rivers Shire Council

Analysis Number

Insert the DNR Analysis Number quoted on the certificate. Where an analyst leaves the DNR Analysis

Number field blank, a DNR Analysis Number should be issued. A new number should also be issued

when an old analysis is located with no DNR Analysis Number.

Sampling Method

This column describes the method used to collect the sample.

E.g.

PU = Pump - Other or Flowing Bore

PF = Pump – Air Forced

BT = Bailer – Teflon

BA = Bailer – Other

DH = Downhole Probe

XX = Unknown

NR = Not Recorded

Source

This column describes the source of the sample. The available codes are:

GB = Groundwater - Sample from bore

GS = Groundwater - Sample from stream or spring

GR = Groundwater - Sample from remote source eg. Tank, dam

Depth

The depth column is the depth in metres from the reference point to the point at which the sample

was taken. The only unit allowed is metres (m). It should be noted that only GCL (Government

Chemical Laboratory) has measured the depth at which the sample was taken; in the other cases, the

samples may have been taken from the groundwater pumped out by the bore or from a tap at the

bore.

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Bronwyn Jones

Chemical Data – MAJOR IONS

Chemical data is directly from the laboratory chemical analysis results. Where an analysis is

presented partly in milligrams per litre (mg/L) and partly in some other unit such as parts per million

(ppm), all data is converted to the one set of units. The data is stored as either milligrams per litre or

parts per million for all quantities except:

1. Residual Alkalinity stored as milli-equivalents per litre.

2. Sodium Adsorption Ratio stored as a number.

3. Figure of Merit stored as a number.

4. For Fluoride, only values between zero and 30 milligrams per litre are valid.

For the calculated values, the following notes are given by QUEENSLAND HEALTH SCIENTIFIC

SERVICES and apply to their analyses:

• Total Dissolved Ions = Total Cations + Total Anions.

• Total Dissolved Solid = 1. Silica + Total Cations + Total Anions - (HCO3- x

0.583); i.e. Bicarbonate is expressed as Carbonate.

= 2. Electrical Conductivity (EC) x 0.583

• Hardness is (Ca++ + Mg++) as CaCO3.

• Residual Alkalinity = meq (HCO3- + CO3

--) -meq (Ca++ + Mg++).

• Sodium Adsorption Ratio = meqNa+/vmeq(Ca++ + Mg++)/2.

• Figure of Merit (Ratio) = meq (Ca++ + Mg++)/meqNa+.

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ELEVATION & CO-ORDINATE TABLE

INTRODUCTION

The coordinate information recorded in this table is vital for locating the bore geographically. This

table also records the elevation of the ground immediately surrounding the borehole.

Column Names

Bore

Elevation

GIS_ Latitude

GIS_ Longitude

NR&W Checked

Easting

Northing

Zone

Co-ordinate System

Latitude

Longitude

Accuracy

GPS Accuracy

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

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Bronwyn Jones

Elevation

The elevation value is the elevation of the natural ground surface immediately surrounding the

borehole, either taken by a handheld GPS unit or extracted from a raster Digital Elevation Model

(DEM) of the valley using the bore co-ordinates.

GIS_Latitude

Latitude is derived from the bore location system. It is the location with respect to the boundaries

stored in the Departmental Digital Cadastral Database (DCDB). It gives the Latitude as a decimal.

GIS_Longitude

Longitude is derived from the bore location system. It is the location with respect to the boundaries

stored in the Departmental Digital Cadastral Database (DCDB). It gives the Longitude as a decimal.

NR&W Checked

This column indicates whether or not the location of the bore has been validated by the NR&W Bore

Location System. The column can only be updated by the Bore Location System.

Easting

The easting is required to define the Map Grid of Australia (MGA) co-ordinates.

Northing

The northing is required to define the Map Grid of Australia (MGA) co-ordinates. The northing must

be a 7-digit number.

Zone Number

The zone number is required to define the Map Grid of Australia (MGA) coordinates. The zone must

be a 2-digit number and be between zone 53 and zone 56. E.g. 56J.

Co-ordinate System

The co-ordinate system is that given by the hand-held GPS unit when taking easting and northing co-

ordinates.

E.g. UTM = Universal Transverse Mercator, is the most widely used plane

coordinate system and is based on the transverse Mercator projection.

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Latitude

Latitude is used to describe the position of the bore on the earth's surface. Enter as degrees, minutes

and seconds, e.g. 27°23'33'' S. Fractions of a second are not allowed. All latitudes are stored as

South.

Longitude

Latitude is used to describe the position of the bore on the earth's surface. Enter as degrees, minutes

and seconds, e.g. 152°51'02'' E. Fractions of a second are not allowed. All longitudes are stored as

East.

Accuracy

This column records how accurately the bore has been located. There are 6 accuracy codes.

E.g.

GPS = Global Positioning System: The bores location has been determined by a global

positioning system (GPS).

UNKN = Unknown: It is unknown how the bore’s position has been determined.

GPS Accuracy

The GPS Accuracy column is the accuracy of the global positioning system. E.g. 100 means a GPS

with an accuracy of +100 metres has been used.

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DRILLING CONTRACTOR REMARKS TABLE

INTRODUCTION

This table provides the short notes or remarks that the drilling contractor has made in his logbook.

They are predominantly those remarks written in the logbook of N. Scells from the drilling company S.

H. Scells, because the logbooks of other drilling contractors who drilled in the area were unable to be

obtained.

Column Names

Bore

Government Registered Number (RN)

Driller Remarks

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together. The bore values were determined as follows:

A1 - An = Bores in Highvale South of Mount Glorious Road

B1 - Bn = Bores in Highvale North of Mount Glorious Road

C1 - Cn = Bores in Wights Mountain

D1 - Dn = Bores in Samford Valley South of Mount Glorious Road

E1 - En = Bores in Samford Valley North of Mount Glorious Road

F1 - Fn = Bores in Camp Mountain

G1 - Gn = Bores in Samford Village & bores in Samford Valley to the East of

Samford Road/Main Street

H1 - Hn = Other Bores, e.g. in Draper, Mt Nebo.

Government Registered Number (RN)

The government registered number is unique. Each bore, even those on the same property, are all

allocated a five or six number Registration Number (RN).

E.g.

The following list shows the Registered Number block for a few offices (30/10/2003):

Brisbane 120000 - 120999

Gatton 106000 - 106999

Oil Bores 100000 - 101999

Toowoomba 119000 - 119999

Driller Remarks

The remark is simply a short note made by the drilling contractor in his logbook.

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Bronwyn Jones

OTHER POSSIBLE BORES IN SAMFORD VALLEY TABLE

This table lists the location of other probable groundwater bores. I have provided co-ordinates for

them but no data, because they haven’t been confirmed/checked to be bores.

Column Names

Bore

Latitude

Longitude

Field Location

Bore

The bore column is the identifier common to all the tables and maps. It allows the rows in different

tables for a particular bore to be linked together.

Latitude

Latitude is used to describe the position of the bore on the earth's surface. Enter as degrees, minutes

and seconds, e.g. 27°23'33'' S. Fractions of a second are not allowed. All latitudes are stored as

South.

Longitude

Latitude is used to describe the position of the bore on the earth's surface. Enter as degrees, minutes

and seconds, e.g. 152°51'02'' E. Fractions of a second are not allowed. All longitudes are stored as

East.

Field Location

The field location is used to help locate the bore in the field. It may be the residential address of the

land or property on which the bore is located, or a landmark that the bore is near.

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Bronwyn Jones

REFERENCE

• Queensland Government Department of Natural Resources and Mines. 2005. Groundwater

Database: Data Dictionary & Standards. Version 6.

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APPENDIX 2

Groundwater Inventory

CRICOS No. 00213J

Field Water Quality Measurement Table

BORE PIPE RDATE SAMP METHOD SOURCE pH Eh (in MV) EC (µS/cm ) QUALITYF1F2 A 30/07/2007 PU GB 7.15 .+ 21 871 FRESHF3F4F5 A 26/06/2007 PU GB 6.78 142 POTABLEF6 A 15/08/2005 PU GB 2200 BRACKISHF7F8F9 A 20/05/2003 PU GB 6.45 3100 BRACKISHF10 7.40 1100 FRESHF11 A 13/10/2004 PU GB 1300 FRESHF12 A 28/06/2006 PU GB 6.30 .+ 71 572 POTABLEF13 A 25/01/2004 PU GB 620 POTABLEF14 A 23/03/2006 GB - - -F15 A 18/06/2007 PU GB 6.56 .+ 57 215 POTABLEF16 A 1/06/1993 GB 8.00 .+ 46 3250 (1826*) BRACKISHF17 A 16/10/2006 GB - - -F18 POTABLEF19 A 5/09/2006 GB - - -F20F21 A 13/09/2004 PU GB 650 POTABLEF22F23 A 26/06/2007 PU GB 6.54 .+ 23 435 POTABLEF24 - - -F25 A 15/06/2006 PU GB 520 POTABLEF26F27F28 A 18/05/2007 PU GB 6.63 .+ 29 886 FRESHF29F30 POTABLEF31 A 26/06/2006 GB 6.40 869 FRESHF32F33F34 A 29/08/2003 PU GB 550 POTABLEF35F36 A 1/12/2005 PU GB 520 POTABLEF37 POTABLEF38H1 A 2/02/2004 PU GB 2600 BRACKISHH2 8.50 890 FRESHA1A2 A 5/10/2004 PU GB 620 POTABLE

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CRICOS No. 00213J

Field Water Quality Measurement Table

A3 A 15/07/2004 PU GB 7.13 .+ 23 550 POTABLEA4 A 10/01/2005 PU GB 6.58 .+ 54 661 POTABLEB1 A 15/08/2006 PU GB 660 POTABLEA5A6A7 A 8/07/2005 GB - - -A8 A 16/07/2007 PU GBA9 A 19/05/2007 PU GB 7.14 1011 FRESHA10 A 11/08/2006 GB - - -B2 A 4/11/2003 PU GB 380 POTABLEA11A12A13 A 29/07/2007 PU GB 7.25 .+ 14 692 POTABLEA14B3 A 18/06/2007 PU GB 6.10 .+ 69 602 POTABLEB4 A 18/06/2007 PU GB 5.80 .+ 96 296 POTABLEB5 7.31 752 FRESHA15A16A17A18 A 18/06/2007 PU GB 6.54 .+ 55 1018 FRESHB6 A 26/06/2006 GB 6.64 317 POTABLEA19 A 4/06/2004 PU GB 440 POTABLEA20 A 21/08/2006 PU GB 700 POTABLEA21 A 19/05/2007 PU GB 6.58 .+ 45 444 POTABLEA22 A 12/11/2003 PU GB 7.02 .+ 7 1210 FRESHA23A24A25A26H3 A 1/01/1950 GB 6.40G1 A 1/01/1990 GB 6.00 1260 FRESHE1 A 6/05/2006 PU GB 6.62 .+ 51 720 POTABLEG2A A 20/02/1988 GB 7.10 570 POTABLEG2B A 20/02/1988 GB 7.00 540 POTABLEE2 A 29/07/2007 PU GB 6.67 .+ 50 2177 BRACKISHE3 A 7/07/2006 PU GB 3800 BRACKISHE4 A 23/10/2006 GB 2200 BRACKISHE5 A 13/06/2006 PU GB 340 POTABLE SOAKE6 A 24/10/2006 GB - - -E7 A 26/10/2006 GB - - -D1D2 A 29/07/2007 PU GB 7.25 .+ 15 5980 SALTYE8 A 29/06/2006 GB 420 POTABLE

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CRICOS No. 00213J

Field Water Quality Measurement Table

E9 A 18/05/2007 PU GB 6.49 .+ 35 896 FRESHE10E11 A 16/08/2005 PU GB 2900 BRACKISHD3E12 A 5/01/2006 PU GB 6.77 .+ 43 960 FRESHD4 - -D5 A 1/01/1991 GB 8.00 4000 BRACKISHE13 A 1/11/2006 GB 7.05 .+ 26 1010 FRESHG3 A 24/11/2006 GB 360 POTABLED6 A 29/07/2007 PU GB 7.49 2031 BRACKISHE14E15 A 25/10/2006 GB 7.07 .+ 26 5778 SALTYD7 6.70 1950 FRESHE16 A 25/01/2006 PU GB 420 POTABLE SOAKG4 A 13/08/2007 PU GBG5C1 A 29/07/2007 PU GB 7.11 .+ 25 2605 BRACKISHC2 A 2/05/2003 PU GB 1800 FRESHC3C4 A 2/05/2003 GB 1800 FRESHC5 A 9/05/2003 GB - -C6C7C8C9C10C11 A 9/07/2007 PU GB 6.20 .+ 44 162 POTABLEC12 A 3/03/2004 PU GB 350 POTABLEC13 A 20/05/2003 PU GB 440 POTABLEC14 A 18/10/2006 PU GB 560 POTABLEC15 A 20/03/2006 PU GB 7.40 .– 6 598 POTABLEC16 A 20/05/2003 GB 7.04 .+ 29 506 POTABLEC17C18 A 20/06/2005 PU GB 3700 BRACKISHC19C20 A 9/07/2007 PU GB 6.28 .+ 39C21

* After bailing ~30 Litres of water

Bronwyn Jones Page 102

CRICOS No. 00213J

Strata Log Table

BORE RN REC DESCRIPTION TOP BOTTOMF1F2F3F4F5F6 124853 1 LIGHT BROWN TIGHTLY COMPACTED STIFF CLAY 0 2.5

2 LIGHT BROWN VERY SANDY DECOMPOSED GRANITE (ALLUVIUM) 2.5 43 BROWN DECOMPOSED GRANITE WITH HEAVY TRACES OF GRAVEL * 4 5.254 DARK GREY & BLACK MODERATELY HARD SOLID GRANITE * 5.25 11.55 BLACK & GREY VERY HARD GRANITE 11.5 20

F7F8F9 120458 1 BROWN SANDY SOIL 0 0.25

2 LIGHT BROWN COMPACTED STIFF CLAY 0.25 1.53 LIGHT BROWN CLAYEY DECOMPOSED GRANITE 1.5 64 LIGHT & DARK BROWN DECOMPOSED GRANITE WITH SOME SEAMS 6 19

OF DARK BLUE ROCK ALTERNATING BETWEEN HARD & SOFT5 LIGHT & DARK BROWN MODERATELY HARD DECOMPOSED GRANITE 19 22.5

(BREAKING UP INTO CEMENTED PIECES)6 DARK BLUE & BROWN DECOMPOSED GRANITE ALTERNATING WITH 22.5 24.5

LIGHT BLUE GREY ROCK ADHERING TO LIGHT BROWN ROCK WITH GRAIN STRUCTURE (VERY UNUSUAL FOR THIS AREA) *

F10 79159

F11 124206 1 TOP SOIL 0 12 SAND AND GRAVEL * 1 53 DECOMPOSED GRANITE * 5 124 SPOTTED D & G GRANITE 12 25

F12 133877 1 GREY SANDY SOIL 0 0.52 BROWN "COMPACTED" STIFF CLAY, TRACES OF COARSE SAND 0.5 7.53 BROWN MODERATELY CLAYEY M & C DECOMPOSED GRANITE 7.5 94 GREY & WHITE HARD GRANITE 9 135 BROWN HARD DECOMPOSED GRANITE 13 13.56 GREY & WHITE HARD GRANITE 13.5 167 BROWN HARD COARSE DECOMPOSED/WEATHERED GRANITE * 16 18.58 GREY & WHITE HARD GRANITE 18.5 24

F13 120217 1 LIGHT BROWN VERY SANDY CLAY WITH SEAMS OF CLAYEY SAND 0 32 DARK BROWN VERY SANDY CLAY WITH LAYERS OF FINE GRAVEL 3 6.53 BROWN GRAVELY CLAY 6.5 7.54 HARD BLACK AND WHITE GRANITE BOULDER) 7.5 95 LIGHT BROWN SOFT COARSE DECOMPOSED GRANITE WITH SEAMS 9 12.5

OF HARD BLACK & WHITE FRACTURED GRANITE *

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CRICOS No. 00213J

Strata Log Table

6 VERY HARD BLACK AND WHITE GRANITE 12.5 14.5F14 133792 1 SANDY SOIL OVERLYING BROWN MODERATELY STIFF CLAY 0 0.5

2 LIGHT BROWN CLAYEY DECOMPOSED GRANITE WITH SEAMS OF 0.5 6HARD DECOMPOSED GRANITE

3 DARK BROWN MEDIUM GRAINED GRANITE DECOMPOSED GRANITE 6 124 BLACK & WHITE HARD GRANITE (BOULDER) 12 13.55 BROWN MODERATELY SOFT FINE GRAINED DECOMPOSED GRANITE 13.5 176 HARD BLACK & WHITE GRANITE 17 187 BROWN MODERATELY HARD DECOMPOSED GRANITE 18 198 HARD BLACK & WHITE GRANITE 19 219 BLACK & WHITE SOFT GRANITE 21 21.510 BLACK & WHITE HARD TO VERY HARD GRANITE, NO FRACTURING 21.5 32

F15F16 79713 1 SANDY LOAM 0 2.44

2 DECOMPOSED GRANITE 2.44 13.413 GRANITE 13.41 16.764 FRACTURED GRANITE 16.76 28.955 SOFTER GRANITE 28.95 29.566 SOFTER GRANITE, NO FRACTURES * 29.56 42.677 HARD GRANITE, NO FRACTURES 42.67 45.72

903 WATER STRUCK AT 30m;TOTAL DEPTH 46mF17 134255 1 DARK BROWN SANDY SOIL 0 0.5

2 LIGHT BROWN COMPACTED SANDY CLAY 0.5 23 LIGHT BROWN VERY SANDY DECOMPOSED GRANITE 2 4.754 LIGHT GREY & BLACK HARD GRANITE 4.75 45

F18F19 134182 1 BROWN SAND SLIGHTLY CLAYBOUND GRAVEL & COBBLE 0 2

2 LIGHT BROWN CLAYBOUND DECOMPOSED GRANITE 2 53 BROWN VERY SANDY 5 114 SEAM OF BROWN FRACTURED ROCK IN DECOMPOSED GRANITE 11 11.55 RED-BROWN FINE & MEDIUM GRAINED VERY SANDY DECO GRANITE 11.5 15.56 GREY & WHITE VERY HARD GRANITE 15.5 227 GREY & WHITE SLIGHTLY SOFTER GRANITE 22 22.58 GREY & WHITE VERY HARD GRANITE 22.5 23.5

F20F21 124005 1 DARK BROWN SANDY CLAY 0 4

2 DARK BLUE & BROWN MODERATELY STIFF CLAY 4 5.53 BROWN CLAYBOUND DECOMPOSED GRANITE 5.5 84 COARSE CLAYBOUND "BASALTIC" GRAVEL 8 8.55 LIGHT BROWN CLAYBOUND DECOMPOSED GRANITE * 8.5 116 DARK BROWN V COARSE DECO GRANITE (V LITTLE CLAYBINDING) * 11 157 HARD GRANITE 15 15

F22F23 120587 1 HARD BROWN CLAY 0 1

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CRICOS No. 00213J

Strata Log Table

2 HARD BROWN CLAY 1 23 HARD BROWN CLAY 2 64 HARD BROWN CLAY WITH SMALL STONE 6 115 RED & BROWN STONE WET 11 126 RIVER GRAVEL 8-20mm AQUIFER * 12 187 RIVER GRAVEL 3-20mm (STABLE) 18 26.15

F24F25 133875 1 GREY SANDY SOIL 0 0.5

2 DARK GREY TO BLACK VERY STIFF CLAY 0.5 5.53 BROWN SLIGHTLY CLAYEY M & C GRAINED DECOMPOSED GRANITE 5.5 8

WITH BOULDERS & TRACES OF GRAVEL *4 GREY & WHITE VERY HARD GRANITE WITH FRACTURING @ 10.5m * 8 13.75

F26

F27F28F29F30 120589 1 BLACK SOIL 0 1

2 BROWN CLAY 1 33 DECOMPOSED GRANITE * 3 114 HARD BLUE GRANITE FRACTURED 11 21.5

F31F32F33F34 120465 1 BLACK SANDY SOIL 0 1

2 DARK GREY MODERATELY STIFF CLAY 1 4.53 BROWN F TO M GRAINED CLAYBOUND DECOMPOSED GRANITE 4.5 84 LIGHT BROWN VERY PERMEABLE M TO C GRAINED DECO GRANITE * 8 9.55 LIGHT BROWN VERY PERMEABLE DECOMPOSED GRANITE * 9.5 10.56 VERY HARD BROKEN GRANITE * 10.5 10.75

F35F36 133516 1 BROWN MODERATELY SANDY ALLUVIAL CLAYS 0 3

2 BROWN (FRETTING) ALLUVIAL CLAYS WITH COARSE GRAVEL & 3 4SMALL BOULDERS

3 BROWN VERY CLAYBOUND DECOMPOSED GRANITE 4 94 DARK BROWN PERMEABLE COARSE DECOMPOSED GRANITE WITH 9 13

THIN SEAMS OF FINE & MEDIUM GRAINED GRAVEL *5 BLACK & WHITE HARD GRANITE (BOULDER) 13 13.756 BROWN COARSE DECOMPOSED GRANITE * 13.75 14.57 BLACK & WHITE BASEMENT GRANITE, VERY HARD 14.5 16.5

F37F38H1 120216 1 BROWN GRAVELY SOIL & MODERATELY STIFF CLAY 0 1.5

2 DK GREY TO BLACK CLAYBOUND MOD SOFT WEATHERED SCHIST * 1.5 13

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CRICOS No. 00213J

Strata Log Table

3 DARK BLUE GREY MODERATELY HARD TO HARD SCHIST, SLIGHT 13 24TRACES OF WHITE QUARTZ *

H2 79216

A1A2 124012 1 LIGHT BROWN SANDY SOIL/CLAY 0 0.5

2 LIGHT BROWN STIFF CLAY 0.5 1.53 BROWN CLAYEY DECOMPOSED GRANITE 1.5 34 DARK BROWN SLIGHTLY CLAYEY MEDIUM GRAINED DECO GRANITE 3 65 DARK BROWN HARD DECOMPOSED GRANITE * 6 7.56 GREY & WHITE VERY HARD GRANITE 7.5 127 GREY FRACTURED GRANITE * 12 12.58 GREY & WHITE VERY HARD GRANITE 12.5 17.5

A3 120508 1 LIGHT BROWN STIFF & COMPACTED CLAY 0 22 DARK & LIGHT BROWN FINE GRAINED SL CLAYEY DECO GRANITE 2 123 LIGHT GREY & WHITE HARD GRANITE, SLIGHT FRACTURING @ 20m * 12 32

A4 124245 1 BROWN VERY SANDY ALLUVIAL SOIL 0 1.252 LARGE BOULDERS BOUND WITH SANDY SOIL & SILT 1.25 2.753 LIGHT BROWN CLAYBOUND DECOMPOSED GRANITE (WITH 2.75 7

INTERMITTENT BOULDERS)4 DARK BROWN LESS CLAYBOUND DECO GRANITE * 7 8.55 GREY & WHITE SOLID GRANITE 8.5 10

B1 134096 1 GREY SANDY SOIL 0 0.252 GREY VERY STIFF CLAY 0.25 1.53 BROWN STIFF CLAY 1.5 2.54 BROWN CLAYBOUND DECOMPOSED GRANITE 2.5 65 DARK BROWN MEDIUM & COARSE-GRAINED DECOMPOSED GRANITE* 6 7.56 LIGHT BROWN VERY HARD DECOMPOSED GRANITE 7.5 87 LIGHT BROWN & WHITE SOFT DECO GRANITE (TRACES OF GRAVEL) * 8 98 GREY & WHITE VERY HARD GRANITE 9 11

A5A6A7 124665 1 LIGHT GREY SANDY SOIL 0 0.5

2 BROWN CLAYBOUND DECOMPOSED GRANITE 0.5 3.53 BROWN MODERATELY HARD DECOMPOSED GRANITE 3.5 74 HARD LIGHT GREY & BLACK SOLID GRANITE WITH NO FRACTURING 7 60

A8A9 ~17.68A10 1 GREY SANDY SOIL 0 0.5

2 ORANGE-BROWN VERY COMPACTED SLIGHTLY SANDY CLAY 0.5 23 LIGHT BROWN VERY SANDY DECOMPOSED GRANITE 2 84 BROWN HARD DECOMPOSED GRANITE 8 95 GREY & WHITE HARD GRANITE, NO FRACTURING 9 126 GREY & WHITE HARD GRANITE, NO FRACTURING 12 38

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CRICOS No. 00213J

Strata Log Table

7 GREY & WHITE & BROWN HARD GRANITE, NO FRACTURING 38 53.5B2 120466 1 LIGHT BROWN STIFF CLAY 0 1.5

2 DARK MODERATELY CLAYEY DECOMPOSED GRANITE 1.5 43 LIGHT GREY & BLACK HARD GRANITE 4 5.54 LIGHT GREY & LIGHT BROWN FRACTURED SOFT GRANITE * 5.5 6.55 LIGHT GREY & BLACK HARD GRANITE, NO FRACTURING 6.5 11.5

A11A12A13 79880

A14B3B4 15.9B5 13A15A16A17A18B6A19 120163 1 DARK BROWN CLAYBOUND DECOMPOSED GRANITE 0 7.5

2 LIGHT BROWN VERY CLAYEY DECOMPOSED GRANITE 7.5 8.75 3 HARD BROWN GRANITE (PROBABLY BOULDER) 8.75 9.25

4 LIGHT BROWN CLAYEY FINE & MEDIUM GRAINED DECO GRANITE 9.25 185 DARK BROWN & GREY MEDIUM GRAINED DECOMPOSED GRANITE* 18 206 LIGHT GREY & BLACK HARD GRANITE 20 24

A20 134181 1 DARK GREY SANDY CLAY & CLAYEY SAND 0 3.52 DARK BROWN CLAYEY DECOMPOSED GRANITE 3.5 5.53 LIGHT BROWN VERY SANDY DECOMPOSED GRANITE 5.5 8.754 LIGHT GREY & WHITE HARD GRANITE, SLIGHT FRACTURING @ 35m * 8.75 415 GREY & WHITE VERY HARD GRANITE 41 44

A21A22 120467 1 DARK BROWN VERY COMPACTED CLAYEY DECOMPOSED GRANITE 0 5.5

2 MID BROWN LESS CLAYEY "SANDY" DECOMPOSED GRANITE 5.5 13.53 LIGHT GREY MODERATELY HARD BLACK & WHITE GRANITE 13.5 144 BROWN MODERATELY HARD DECOMPOSED GRANITE 14 15.5

5 LIGHT GREY & BLACK HARD GRANITE 15.5 176 BROWN & BLACK & WHITE HARD GRANITE * 17 17.57 LIGHT GREY & BLACK MODERATELY HARD GRANITE 17.5 448 LIGHT GREY & BLACK GRANITE WITH SEAMS OF BLACK ROCK * 44 459 LIGHT GREY & BLACK MODERATELY HARD TO HARD GRANITE 45 49

A23 ~36.57A24A25A26

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CRICOS No. 00213J

Strata Log Table

H3 79699

G1 79861 903 BORE 4m DEEP YIELD 800gall/hr 905 DRILLER NEVILLE SCELLS 902 ADDRESS: LOT 7, 5 BENJAMIN CLOSE, SAMFORD VALLEY

E1 133950 1 BLACK CLAY AND SOIL 0 0.52 BROWN STIFF CLAY, VERY GRAVELY AT INTERVALS 0.5 2.53 BROWN CLAYBOUND MEDIUM-GRAINED DECOMPOSED GRANITE 2.5 64 DARK BROWN FINE-GRAINED DECOMPOSED GRANITE 6 85 DARK & LIGHT BROWN COARSE PERMEABLE DECOMPOSED GRANITE 8 11.5

WITH MODERATE TRACES OFGRAVEL* 6 BLACK & WHITE VERY HARD GRANITE 11.5 13.75

G2 73232 1 STIFF GREY CLAY 0 6.71 2 BROWN DECOMPOSED CLAY 6.71 9.14 3 DECOMPOSED GRANITE & GRAVEL (MAIN WATER BED) * 9.14 10.97 4 DARK GREY SCHIST(WATER BED 12.8-15.9) 10.97 18.59 902 SWL=1.66 BELOW TOP OF CASING 29-02-1988

E2E3 134223 1 SANDY LOAM 0 1

2 DECOMPOSED ROCK 1 83 GRANITE * 8 26.6

E4 1 BROWN SANDY SOIL 0 0.252 ORANGE-BROWN COMPACTED SANDY CLAY 0.25 13 LIGHT BROWN VERY STIFF CLAY 1 24 BROWN CLAYEY MEDIUM GRAINED DECOMPOSED GRANITE 2 5.55 DARK GREY & BROWN MODERATELY HARD DECOMPOSED GRANITE 5.5 7.56 DARK GREY & WHITE HARD TO VERY HARD GRANITE WITH 7.5 33.5

VIRTUALLY NO FRACTURING *E5 133874 1 GREY SANDY SOIL 0 1

2 BROWN STIFF CLAY 1 1.53 BROWN CLAYEY FINE & MEDIUM GRAINED DECOMPOSED GRANITE 1.5 4.54 BLACK & WHITE GREY VERY HARD GRANITE WITH NO FRACTURING 4.5 34

E6 1 GREY SANDY SOIL 0 0.252 ORANGE-BROWN COMPACTED SANDY CLAY 0.25 1.253 LIGHT BROWN STIFF CLAY 1.25 24 BROWN CLAYEY DECOMPOSED GRANITE 2 5.55 DARK BROWN & GREY MODERATELY HARD DECOMPOSED GRANITE 5.5 7.56 DARK & LIGHT GREY HARD GRANITE, NO FRACTURING 7.5 33.5

E7 1 GREY SANDY SOIL 0 0.252 ORANGE-BROWN COMPACTED SANDY CLAY 0.25 23 LIGHT BROWN STIFF CLAY 2 2.54 LIGHT BROWN CLAYBOUND DECOMPOSED GRANITE 2.5 3.55 DARK & LIGHT GREY HARD GRANITE, NO FRACTURING 3.5 316 DARK & LIGHT GREY HARD GRANITE, NO FRACTURING 31 33

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CRICOS No. 00213J

Strata Log Table

7 DARK & LIGHT GREY HARD GRANITE, NO FRACTURING 33 36.5D1D2 ~37.8E8 1 ORANGE-BROWN SLIGHTLY SANDY SANDY CLAY (FILL) 0 1

2 DARK BROWN COMPACTED STIFF CLAY WITH DECO ROCK SEAMS 1 3.53 LIGHT BROWN VERY DECOMPOSED ROCK (VIRTUALLY POWDERY), 3.5 14.5

CLAY WITH LAYERS OF VERY WEATHERED DARK BLUE ROCK4 DARK BLUE MODERATELY HARD VERY FRACTURED ROCK * 14.5 175 DARK BLUE HARD ROCK WITH NO FRACTURING, TRACES OF 17 23

QUARTZ & GREY ROCK @ 21mE9 ~20E10 120397 1 BROWN CLAY WITH SMALL 5mm STONE 0 1

2 BROWN CLAY WITH SMALL 5mm STONE 1 23 LIGHT BROWN CLAY WITH SMALL 5mm STONE 2 34 LIGHT GRAY CLAY WITH SMALL 5mm STONE 3 45 GREY CLAY WITH SMALL BROWN STONE FRAC 4 56 GRANITE - QUARTZ WITH BLACK STONE 5 67 GRANITE - QUARTZ WITH BLACK STONE 6 128 GRANITE - QUARTZ WITH BLACK STONE 12 189 FRACTURED RED STONE WITH MOISTURE * 18 2410 GRANITE - QUARTZ WITH BLACK STONE 24 30

E11 124861 1 LIGHT GREY SOIL 0 0.52 BROWN STIFF CLAY 0.5 33 LIGHT & DARK BROWN VERY "SANDY" DECOMPOSED GRANITE 3 64 LIGHT GREY & BLACK HARD GRANITE 6 8.55 LIGHT GREY & BLACK GRANITE WITH SEAMS OF BROWN 8.5 10

DECOMPOSED GRANITE *6 LIGHT GREY & BLACK HARD GRANITE 10 17.57 MAROON-BROWN LIGHT GREY & BLACK MOD HARD GRANITE 17.5 218 BLACK & WHITE HARD GRANITE 21 24

D3E12 133595 1 LIGHT BROWN CLAYBOUND MODERATELY SOFT DECO GRANITE 0 3

2 LIGHT BROWN MODERATELY HARD DECOMPOSED GRANITE 3 63 BROWN DECO GRANITE WITH SEAMS OF HARD BLACK ROCK * 6 8.54 BLACK & WHITE FRESH GRANITE, VERY HARD, NO FRACTURING 8.5 15.25

D4 79690 1 CLAY TOPSOIL 0 1.52 2 DECOMPOSED GRANITE 1.52 30.48 3 SOLID GRANITE 30.48 38.1 903 DRY HOLE

D5 79407

E13 1 GREY SANDY SOIL 0 0.252 LIGHT GREY & BROWN COBBLE OVERLYING CLAYBOUND GRAVEL 0.25 3.53 BROWN VERY CLAYEY COARSE DECOMPOSED GRANITE 3.5 6.5

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CRICOS No. 00213J

Strata Log Table

4 DARK BROWN COARSE TO VERY COARSE VERY PERMEABLE DECO 6.5 7.25GRANITE, WITH MODERATE TRACES OF F & M GRAINED GRAVEL *

5 LIGHT GREY & WHITE HARD GRANITE 8.75 9G3 1 BROWN MOTTLED CLAY, SEAM OF COMPACTED GRAVEL @ 2m 0 2

2 LIGHT BROWN & LIGHT GREY STIFF CLAY 2 43 LIGHT BROWN CLAYBOUND DECOMPOSED GRANITE 4 7.54 DARK GREY F & M GRAINED SLIGHTLY CLAYEY DECO GRANITE * 7.5 115 BLUE-GREY ROCK WITH GRAIN STRUCTURE SIMILAR TO GRANITE 11 20

BUT NOT TYPICAL OF GRANITE IN AREA. MINOR FRACTURING UP TO 13.5m *

D6 120676 1 TOPSOIL 0 12 WEATHERED GRANITE 1 93 HARD GRANITE 9 124 LIGHT FRACTURED GRANITE 12 135 GRANITE 13 176 FRACTURED GRANITE * 17 187 HARD GRANITE 18 308 FRACTURED GRANITE * 30 319 HARD GRANIITE 31 36

E14E15 1 GREY SANDY SOIL 0 0.25

2 LIGHT BROWN STIFF CLAY 0.25 13 BROWN CLAYEY DECOMPOSED GRANITE WITH SEAMS OF COARSE 1 4

GRAVEL & COBBLE4 GREY MEDIUM GRAINED DECOMPOSED GRANITE 4 55 GREY & WHITE MODERATELY HARD SOLID GRANITE, LESS HARD 5 28

THAN MUCH OF SOLID GRANITE IN AREA6 MOD HARD GREY & WHITE GRANITE, HIGHER PROPORTION OF QTZ 28 367 SLIGHTLY HARDER GREY & WHITE GRANITE * 36 39

D7 79000E16 133670 1 BROWN SOIL & COARSE COBBLE 0 1

2 LIGHT GREY VERY DECOMPOSED ROCK 1 3.53 BROWN & GREY VERY WEATHERED ROCK 3.5 64 STEEL GREY MODERATELY HARD SCHIST-TYPE-OF-ROCK WITH 6 17

SEAMS OF SLIGHTLY DECOMPOSED ROCK *5 BLUE GREY TO BLACK HARD ROCK, NO FRACTURING 17 21.5

G4G5C1C2 120451 1 BROWN SOIL/CLAY COARSE GRAVEL/BOULDER 0 4

2 HARD DARK BLUE TO BLACK ROCK 4 93 WHITE AND BLACK VERY HARD GRANITE 9 174 WHITE TO BLACK MOD HARD GRANITE * 17 215 VERY HARD WHITE TO BLACK GRANITE 21 25

Bronwyn Jones Page 109

CRICOS No. 00213J

Strata Log Table

C3 120455 1 DARK BROWN SANDY SOIL AND CLAY 0 1.52 LIGHT BROWN CLAYBOUND DECOMPOSED GRANITE 1.5 33 BLACK & WHITE HARD GRANITE NO FRACTURING 3 31

C4 1 BROWN SOIL & CLAYBOUND COARSE GRAVEL & BOULDERS 0 42 HARD DARK BLUE TO BLACK ROCK (Typical of MT NEBO - HORNFELS) 4 9

VERY FINE GRAIN STRUCTURE, SOME MINOR FRACTURING3 WHITE & BLACK VERY HARD GRANITE 9 174 WHITE & BLACK MODERATELY HARD GRANITE, CUTTINGS TENDING 17 21

TO BE "SANDY" *5 WHITE & BLACK VERY HARD GRANITE 21 25

C5 1 DARK BROWN SANDY SOIL & CLAY 0 1.52 LIGHT BROWN CLAYBOUND DECOMPOSED GRANITE WITH 1.5 3

ALTERNATING LAYERS OF LESS DECO GRANITE (HARDER SEAMS)3 BLACK & WHITE HARD TO VERY HARD GRANITE 3 31

C6C7C8C9C10C11C12 120224 1 BLACK SANDY ALLUVIAL SOIL 0 1.5

2 LIGHT GREY & BROWN MODERATELY STIFF CLAY 1.5 43 LIGHT BROWN CLAYBOUND SOFT DECOMPOSED GRANITE 4 64 LIGHT BROWN HARD DECOMPOSED GRANITE 6 75 BROWN SLIGHTLY CLAYBOUND DECOMPOSED GRANITE WITH VERY 7 10.5

SOFT SEAMS & HEAVY TRACES OF RED/BROWN ROCK *6 BLUE-GREY & WHITE HARD GRANITE (SL FRACTURED @ 11.5m) 10.5 14

C13 120459 1 DARK BROWN SOIL & FINE, MEDIUM & COARSE SAND/CLAY 0 42 LIGHT BROWN CLAYEY DECO GRANITE 4 73 MED GRAINED DECOMPOSED GRANITE * 7 94 BLUE DARK & WHITE HARD GRANITE FRAC * 9 125 BLACK & WHITE HARD GRANITE NO FRAC 12 14

C14 134256 1 DK BROWN VERY SANDY CLAY & CLAYEY SAND (FRETTING @ 3m) 0 32 BROWN MOIST VERY CLAYEY DECOMPOSED GRANITE 3 4.53 BROWN DECO GRANITE WITH SEAMS OF F & M GRAINED GRAVEL * 4.5 5.754 GREY & WHITE HARD GRANITE 5.75 8.55 GREY, WHITE & BROWN SOFT GRANITE * 8.5 96 GREY & WHITE HARD GRANITE (& TRACES OF BROWN) 9 107 GREY & WHITE HARD GRANITE 10 14

C15 133791 1 DARK BROWN VERY SANDY SOIL & VERY CLAYEY SAND 0 3.52 LIGHT BROWN MODERATELY CLAYBOUND DECOMPOSED GRANITE, 3.5 7.5

VERY PERMEABLE @ 6 - 7.5m *3 DARK GREY MOD HARD FINE GRAINED DECOMPOSED GRANITE * 7.5 10.54 BLACK & WHITE VERY HARD GRANITE, TRACES OF BROWN @ 10.5 15.5

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CRICOS No. 00213J

Strata Log Table

INTERVALS, NO FRACTURESC16 1 DARK BROWN SOIL & CLAYBOUND F M & C SAND & SANDY CLAY 0 4

2 LIGHT BROWN VERY CLAYEY DECOMPOSED GRANITE 4 73 MEDIUM GRAINED DECOMPOSED GRANITE * 7 94 BLUE (DARK) & WHITE HARD GRANITE FRACTURED ALTERNATING 9 12

WITH BROWN & WHITE SOFTER DECOMPOSED GRANITE *5 BLACK & WHITE HARD GRANITE, NO FRACTURES 12 14

C17C18 124664 1 LIGHT GREY SANDY SOIL 0 0.5

2 BROWN STIFF CLAY 0.5 1.53 BROWN CLAYBOUND COARSE GRAINED DECOMPOSED GRANITE 1.5 10.54 BROWN MODERATELY HARD DECOMPOSED GRANITE 10.5 135 BROWN & DARK GREY MODERATELY HARD SOLID GRANITE * 13 256 GREY-PINK & BROWN MODERATELY HARD SOLID GRANITE WITH 25 40

LENS OF LIGHT GREY SOLUBLE CLAYC19C20C21

* Water found

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CRICOS No. 00213J

Casing Table

BORE PIPE RDATE REC MATERIAL DESC MATERIAL SIZE SIZE DESC OUT DIAMETER TOP BOTTOMF1F2F3F4F5F6 A 15/08/2005 1 PVC 125 0 8.25

A 15/08/2005 2 STEL 200 0 5.25A 15/08/2005 3 PERF 6 AP 4 8.25A 15/08/2005 4 GRAV 5 GR 3.5 8.25A 15/08/2005 5 FILL 8.25 20A 15/08/2005 6 FILL 3 3.5A 15/08/2005 7 FILL 3.5 4A 15/08/2005 8 GROU 225 0 3

F7F8F9 A 20/05/2003 1 PVC 9 WT 0 24.5

A 20/05/2003 2 PERF 6 AP 21.5 24.5A 20/05/2003 3 FILL 6 24.5A 20/05/2003 4 GROU 175 0 6

F10F11 A 13/10/2004 1 PVC 5.9 WT 125 0 25

A 13/10/2004 2 PERF 6 13A 13/10/2004 3 PERF 13 19A 13/10/2004 4 GRAV 5 GR 2 25A 13/10/2004 5 GROU 173 0 2

F12 A 28/06/2006 1 PVC 9 WT 125 0 23A 28/06/2006 2 PERF 4 AP 15 23A 28/06/2006 3 GRAV 5 GR 8 23A 28/06/2006 4 FILL 5 8A 28/06/2006 5 GROU 225 0 5

F13 A 25/01/2004 1 STEL 200 0 7.5A 25/01/2004 2 PVC 9 WT 125 0 14.5A 25/01/2004 3 PERF 4 AP 9 14.5A 25/01/2004 4 GRAV 5 GR 6 14.5A 25/01/2004 5 FILL 5 6A 25/01/2004 6 GROU 225 0 5

F14 A 23/03/2006 1 FILL 3.2 6A 23/03/2006 2 BNSL 5.5 6A 23/03/2006 3 GROU 225 0 5.5

F15F16 A 1/06/1993 1 PLAS 100 0 45.7F17 A 16/10/2006 1 STEL 200 0 4.75

A 16/10/2006 2 PVC 9 WT 125 0 6A 16/10/2006 3 GROU 225 0 5

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CRICOS No. 00213J

Casing Table

F18F19 A 5/09/2006 1 STEL 200 0 3.5

A 5/09/2006 2 FILL 7 23.5A 5/09/2006 3 GROU 225 1 3.5A 5/09/2006 4 GROU 168 3.5 7A 5/09/2006 5 FILL 0 13

F20F21 A 13/09/2004 1 PVC 9 WT 125 0 15

A 13/09/2004 2 PERF 6 AP 9 15A 13/09/2004 3 GRAV 5 GR 8 15A 13/09/2004 4 FILL 5 8A 13/09/2004 5 GROU 225 0 5

F22F23 A 29/07/2004 1 PVC 5 WT 125 0 26

A 29/07/2004 2 PERF 2 AP 14 26A 29/07/2004 3 GRAV 5 GR 5 26A 29/07/2004 4 GROU 200 0 5

F24F25 A 15/06/2006 1 STEL 200 0 5.75

A 15/06/2006 2 PVC 9 WT 125 0 13.75A 15/06/2006 3 PERF 6 AP 6 13.75A 15/06/2006 4 GRAV 5 GR 6 13.75A 15/06/2006 5 FILL 5 6A 15/06/2006 6 GROU 200 0 5

F26F27F28F29F30 A 11/06/2004 1 PVC 5.9 WT 125 0 21.5

A 11/06/2004 2 PERF 9.5 21.5A 11/06/2004 3 GRAV 5 GR 6 21.5A 11/06/2004 4 GROU 200 0 1A 11/06/2004 5 GROU 173 1 6

F31F32F33F34 A 29/08/2003 1 PVC 9 WT 125 0 10.5

A 29/08/2003 2 PERF 6 AP 7.5 10.5A 29/08/2003 3 GRAV 5 GR 6.5 10.5A 29/08/2003 4 FILL 5 6.5A 29/08/2003 5 GROU 225 0 5

F35F36 A 1/12/2005 1 STEL 200 0 5.5

A 1/12/2005 2 PVC 9 WT 125 0 15A 1/12/2005 3 PERF 4 AP 7.5 15

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CRICOS No. 00213J

Casing Table

A 1/12/2005 4 GRAV 5 GR 6.5 15A 1/12/2005 5 FILL 5 6.5A 1/12/2005 6 GROU 225 0 5

F37F38H1 A 2/02/2004 1 PVC 9 WT 125 0 24

A 2/02/2004 2 PERF 4 AP 18 24A 2/02/2004 3 GRAV 5 GR 8 24A 2/02/2004 4 FILL 5 8A 2/02/2004 5 GROU 175 0 5

H2A1A2 A 5/10/2004 1 PVC 9 WT 125 0 17.5

A 5/10/2004 2 PERF 4 AP 6.5 17.5A 5/10/2004 3 GRAV 5 GR 6 17.5A 5/10/2004 4 FILL 5 6.5A 5/10/2004 5 GROU 225 0 5

A3 A 15/07/2004 1 PVC 9 WT 125 0 13.5A 15/07/2004 2 GRAV 5 GR 12 13.5A 15/07/2004 3 FILL 6 12A 15/07/2004 4 GROU 225 0 6

A4 A 10/01/2005 1 STEL 200 0 6A 10/01/2005 2 PVC 9 WT 125 0 8.5A 10/01/2005 3 PERF 6 AP 6.25 8.5A 10/01/2005 4 GRAV 5 GR 6 8.5A 10/01/2005 5 FILL 5.5 6.25A 10/01/2005 6 FILL 1.25 2.75A 10/01/2005 7 GROU 225 3 5.5A 10/01/2005 8 GROU 225 0 1.25

B1 A 15/08/2006 1 STEL 200 0 7.5A 15/08/2006 2 STEL 150 0 9A 15/08/2006 3 PVC 9 WT 100 0 11A 15/08/2006 4 PERF 6 AP 8 11A 15/08/2006 5 GRAV 5 GR 6 11A 15/08/2006 6 FILL 5 6A 15/08/2006 7 GROU 225 0 5

A5A6A7 A 8/07/2005 1 PVC 9 WT 125 0 5.5

A 8/07/2005 2 GROU 180 0 5A8 A 16/07/2007A9A10 A 11/08/2006 1 PVC 8.25 WT 125 0 8.25

A 11/08/2006 2 FILL 5 8.25A 11/08/2006 3 GROU 225 0 5

Bronwyn Jones Page 111

CRICOS No. 00213J

Casing Table

B2 A 4/11/2003 1 PVC 9 WT 125 0 11.5A 4/11/2003 2 PERF 4 AP 5.5 11.5A 4/11/2003 3 GRAV 5 GR 5 11.5A 4/11/2003 4 GROU 225 0 2.5

A11A12A13A14B3B4B5A15A16A17A18B6A19 A 4/06/2004 1 PVC 9 WT 125 0 24

A 4/06/2004 2 PERF 4 AP 18 24A 4/06/2004 3 GRAV 5 GR 8 24A 4/06/2004 4 FILL 5 8A 4/06/2004 5 GROU 225 0 5

A20 A 21/08/2006 1 STEL 200 0 3.5A 21/08/2006 2 PVC 9 WT 125 0 9A 21/08/2006 3 FILL 6 9A 21/08/2006 4 GROU 225 0 3.5A 21/08/2006 5 GROU 168 3.5 6

A21A22 A 12/11/2003 1 PVC 9 WT 125 0 49

A 12/11/2003 2 PERF 6 AP 43 49A 12/11/2003 3 FILL 6 49A 12/11/2003 4 FILL 5 6A 12/11/2003 5 GROU 225 0 5

A23A24A25A26H3 A 1/01/1950G1 A 1/01/1990E1 A 6/05/2006 1 STEL 200 0 3.5

A 6/05/2006 2 PVC 9 WT 125 0 12A 6/05/2006 3 PERF 4 AP 6.5 12A 6/05/2006 4 GRAV 5 GR 6 12A 6/05/2006 5 BNSL 5 6A 6/05/2006 6 GROU 225 0 5

G2 A 20/02/1988 1 PLAS 102 0 9.1

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CRICOS No. 00213J

Casing Table

A 20/02/1988 2 PERF 102 9.1 10.9A 20/02/1988 3 PLAS 102 10.9 12.8A 20/02/1988 4 PERF 102 12.8 15.8A 20/02/1988 5 PLAS 102 15.8 18.5A 20/02/1988 6 GR 9.1 18.5

E2E3 A 7/07/2006 1 FILL 5 26.6

A 7/07/2006 2 GROU 200 0 5E4 A 23/10/2006 1 STEL 200 0 7.5

A 23/10/2006 2 FILL 5.5 30.5A 23/10/2006 3 GROU 225 0 5.5

E5 A 13/06/2006 1 PVC 9 WT 125 0 6A 13/06/2006 2 FILL 5 5.25A 13/06/2006 3 GROU 225 0 5

E6 A 24/10/2006 1 STEL 200 0 7.5A 24/10/2006 2 FILL 5 33.5A 24/10/2006 3 GROU 225 0 5

E7 A 26/10/2006 1 STEL 200 0 3.5A 26/10/2006 2 FILL 5 36.5A 26/10/2006 3 GROU 225 0 3.5A 26/10/2006 4 GROU 168 3.5 5

D1D2E8 A 29/06/2006 1 STEL 200 0 3.5

A 29/06/2006 2 PVC 9 WT 125 0 23A 29/06/2006 3 PERF 4 AP 14.5 23A 29/06/2006 4 GRAV 5 GR 7 23A 29/06/2006 5 FILL 5 7A 29/06/2006 6 GROU 225 0 3.5A 29/06/2006 7 GROU 180 3.5 5

E9E10 A 22/09/2003 1 FILL 1 30

A 22/09/2003 2 GROU 200 0 1E11 A 16/08/2005 1 PVC 9 WT 125 0 24

A 16/08/2005 2 PERF 4 AP 9 24A 16/08/2005 3 GRAV 5 GR 6 24A 16/08/2005 4 FILL 5 6A 16/08/2005 5 GROU 225 0 5

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CRICOS No. 00213J

Casing Table

D3E12 A 5/01/2006 1 PVC 9 WT 125 0 15.5

A 5/01/2006 2 PERF 4 AP 7.5 15.25A 5/01/2006 3 GRAV 5 GR 6 15.25A 5/01/2006 4 BNSL 5 6A 5/01/2006 5 GROU 225 0 3A 5/01/2006 6 GROU 168 3 5

D4 A 3/03/1993D5 A 1/01/1991E13 A 1/11/2006 1 STEL 200 0 4.5

A 1/11/2006 2 PVC 9 WT 125 0 8.75A 1/11/2006 3 PERF 8 AP 6.75 8.75A 1/11/2006 4 GRAV 5 GR 6 8.75A 1/11/2006 5 FILL 5 6A 1/11/2006 6 GROU 225 0 4.25A 1/11/2006 7 GROU 168 4.5 5

G3 A 24/11/2006 1 STEL 0 11A 24/11/2006 2 PVC 9 WT 125 0 20A 24/11/2006 3 PERF 4 AP 8 20A 24/11/2006 4 GRAV 5 GR 7 20A 24/11/2006 5 FILL 6 7A 24/11/2006 6 FILL 5 6A 24/11/2006 7 GROU 225 0 5

D6 A 27/07/2004 1 PVC 9 WT 125 0 36A 27/07/2004 2 PERF 3 AP 12 18A 27/07/2004 3 PERF 3 AP 30 36A 27/07/2004 4 GRAV 5 GR 10 36A 27/07/2004 5 BNSL 9 10A 27/07/2004 6 GROU 170 1 9

E14E15 A 25/10/2006 1 PVC 9 WT 125 0 39

A 25/10/2006 2 PERF 6 AP 35.5 39A 25/10/2006 3 GRAV 6 39A 25/10/2006 4 FILL 5 6A 25/10/2006 5 GROU 125 0 5

D7E16 A 25/01/2006 1 PVC 9 WT 125 0 6

A 25/01/2006 2 BNSL 5 5.5A 25/01/2006 3 GROU 225 0 5

G4 A 13/08/2007G5C1C2 A 2/05/2003 1 STEL 0 4C3 A 9/05/2003C4 A 2/05/2003 1 STEL 200 0 4

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CRICOS No. 00213J

Casing Table

C5 A 9/05/2003 .-C6C7C8C9C10C11C12 A 3/03/2004 1 PVC 9 WT 125 0 14

A 3/03/2004 2 PERF 4 AP 8 14A 3/03/2004 3 GRAV 5 GR 6 14A 3/03/2004 4 FILL 5 6A 3/03/2004 5 GROU 225 0 5

C13 A 20/05/2003 1 PVC 9 WT 125 0 14A 20/05/2003 2 STEL 200 0 9A 20/05/2003 3 PERF 7 14A 20/05/2003 4 GRAV 5 GR 6 14A 20/05/2003 5 GROU 0 6

C14 A 18/10/2006 1 STEL 200 0 5.75A 18/10/2006 2 STEL 150 0 6.25A 18/10/2006 3 PVC 9 WT 100 0 13.5A 18/10/2006 4 PERF 6 AP 4.5 6.5A 18/10/2006 5 PERF 4 AP 6.5 13.5A 18/10/2006 6 GRAV 5 GR 4 13.5A 18/10/2006 7 FILL 3 4A 18/10/2006 8 GROU 225 0 3

C15 A 20/03/2006 1 STEL 200 0 7.5A 20/03/2006 2 PVC 9 WT 125 0 15.5A 20/03/2006 3 PERF 4 AP 9.5 15.5A 20/03/2006 4 PERF 6 AP 6.5 9.5A 20/03/2006 5 GRAV 5 GR 6 15.5A 20/03/2006 6 BNSL 5 6A 20/03/2006 7 GROU 225 0 5

C16 A 20/05/2003 1 PVC 9 WT 125 0 14A 20/05/2003 2 STEL 0 9A 20/05/2003 3 PERF 4 AP 7 14A 20/05/2003 4 GRAV 5 GR 6 14A 20/05/2003 5 GROU 0 6

C17C18 A 20/06/2005 1 PVC 9 WT 125 0 40

A 20/06/2005 2 GRAV 5 GR 8 40A 20/06/2005 3 FILL 6 8A 20/06/2005 4 GROU 225 0 6

C19C20 C21

Bronwyn Jones Page 115

CRICOS No. 00213J

Aquifer Table

BORE RDATE REC CONDITION TOTAL BORE DEPTH WATER STRUCK AT SWL YIELD (L/sec) TOP OF AQ BOTTOM CONTRIB AQ FLOW WATER TABLE (ASL) GENERAL AQUIFER MATERIAL OTHER NOTES

F1F2 metamorphic rockF3F4F5F6 15/08/2005 1 UC 20 4 & 11.5 -3 0.0625 4 Y N 50.67713928000F7F8F9 20/05/2003 1 UC 24.5 22.5 -17.5 0.687 22.5 Y N 69.80635071000F10F11 13/10/2004 1 UC 25 1 -0.2 0.7 1 7 Y N 64.29034119000F12 28/06/2006 1 UC 24 16 -13 0.225 16 Y N 76.88522339000 Bore located in backyard, a flat area with all trees; H2S rotten egg smellF13 25/01/2004 1 14.5 (9 - 12.5) -5.5 0.312 9 95.74707031000F14 23/03/2006 1 32 - .- .- (NIL) .- .- Says he doesn't have a bore (but is on the Gov register)F15 Bore located in corner of front yard in garden bed, under metal cover; Pump is all closed upF16 1/06/1993 1 46 4.5 & 30 -4.5 0.25 4.5 85.99937439000 Bore located down backyard; Very Salty, Never used; Approx flow rate of a garden hose, ~180 gall/hrF17 16/10/2006 1 45 - .- .- (NIL) .- .-F18F19 5/09/2006 1 23.5 - .- .- (NIL) .- .- fresh granite New bore located down yard near/beside gully; Very close to mountain; no sign of finding any waterF20 fresh granite Old bore is located left of front gate/driveway; ~50 gallons/hr ~20 yrs ago; Now only a trickle (none)F21 13/09/2004 1 UC 15 9 -4.5 0.75 9 Y N 88.92050171000 Neighbours have boresF22F23 29/07/2004 1 UC 26.15 18 -10 0.31 18 Y N 61.82234955000F24 - .- .- (NIL) .- No water, but area does some bores with waterF25 15/06/2006 1 UC 13.75 6.5 & 10.5 -4.5 0.75 6.5 10.5 Y N 79.71795654000F26F27F28 weathered granite Bore located down the backyard in natural shallow drainage gully; High iron content, neighbours have boresF29 -5.52 91.67663270000 weathered granite Bore located down the backyard in natural shallow drainage gully; High iron content, neighbours have boresF30 11/06/2004 1 UC 21.5 11 -0.5 1 11 Y N 85.29429626000F31 weathered granite Bore located in front corner of yard, beside driveway (opposite QUT farm slab hut gate); bore damaged/run over by husbandF32F33F34 29/08/2003 1 UC 10.75 8 -1.75 0.75 8 Y N 81.93528748000F35F36 1/12/2005 1 UC 16.5 9.5 -3.25 0.75 9.5 14.5 Y 104.00304413000 metamorphic rockF37 metamorphic rock Bore located in gully way down front yard; Highly Fe stained, Not used in yearsF38H1 2/02/2004 1 UC 24 9 & 18.5 -6.5 0.187 (SOAK) 9 18.5 Y 65.86338806000H2A1A2 5/10/2004 1 UC 17.5 6.8 & 12 -5.75 0.625 6.8 Y N 89.42948914000A3 15/07/2004 1 FR 32 20 -7 0.062 20 Y N 93.23847198000A4 10/01/2005 1 UC 10 7 -1.75 0.187 7 Y N 154.33226013000 Bore located in large natural gully down front of yard/houseB1 15/08/2006 1 UC 11 6 & 9 -3 1 6 Y N 83.79467773000A5A6A7 8/07/2005 1 60 .- .- .- (NIL) .- .-A8 16/07/2007 1A9 ~17.68 Originally 400gallons/hr; Now 160 gallons/hrA10 11/08/2006 1 53.5 .- .- .- (NIL) .- .-B2 4/11/2003 1 FR 11.5 5.5 -2 0.25 5.5 Y N 133.64080811000A11A12A13 1/02/1993 1A14B3 -9.88 123.67584717000B4 15.9 -9.1 * 113.06873932000 Deco Bore located down sloping backyard, under windmill; Neighbours have boresB5 13 8 -4.16 8 76.27265533000 Bore located in front yard, flat area; Depth to water table 4.16m after 2 inches rain; originally 8m & 440 gallons/hrA15

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Aquifer Table

A16A17A18B6 Bore located on flat ground near front steps of building; Originally 100's gallons/hrA19 4/06/2004 1 UC 24 18 -14.5 0.625 18 Y N 119.70706177000A20 21/08/2006 1 PS 44 35 -13 0.0625 35 Y N 112.18003845000 Fractured granite Bore located in natural gully; Casing has no screen, just slots; originally ~30 gall/hrA21 Bore located down in flat bottom gully; old ones in paddock all run dryA22 12/11/2003 1 UC 49 44 -21 0.25 44 Y N 116.83697510000Hard rock (20-30ft decayed then hit rock)Bore located in front, flat yard; Flow rate of normal garden hose A23 ~36.57 ~27.13 fractures Bore located in natural gully; Up-gully from 44 Smalls Rd bore in gullyA24A25A26 H3 1/01/1950 1G1 1/01/1990 1E1 6/05/2006 1 UC 13.75 8 -2.5 1 8 Y N 87.46067810000 weathered granite Bore located down front yard, next to damG2A 29/02/1988 1 WZ 9.1 -1.66 9.1 10.9 47.19353851000G2B 29/02/1988 2 FR 18.59 12.8 -1.66 12.8 15.8 47.19353851000E2E3 7/07/2006 1 UC 26.6 22.7 -20 0.05 22.7 Y N 61.58985901000E4 23/10/2006 1 33.5 9 NA 0.006 9E5 13/06/2006 1 UC 34 5 (SOAK) NA .- (V. LOW) 5 No water out of it, Not usedE6 24/10/2006 1 33.5 .- .- .- (NIL) .- .-E7 26/10/2006 1 36.5 .- .- .- (NIL) .- .-D1D2 ~37.8 They used a Water DivinerE8 29/06/2006 1 23 16 -15 0.187 16 65.64530945000E9 20 metamorphic rock Bore located in a small, flat bottom drainage gully; Bore within the contact zone of silicified metamorphic schistsE10 22/09/2003 1 30E11 16/08/2005 1 UC 24 8.5 -6.25 0.075 8.5 Y N 51.27365875000D3E12 5/01/2006 1 UC 15.25 7.5 -5.5 0.31 7.5 Y N 82.39140320000D4 3/03/1993 1 38.1 .- .- .- (NIL) .- .- fractured? granite Dry boreD5 1/01/1991 1E13 1/11/2006 1 9 6.5 -1.25 1 6.5 76.53344727000G3 24/11/2006 1 20 9 & 13 -5 0.225 9 39.08166885000D6 27/07/2004 1 FR 36 17 -12.5 0.08 17 Y N 56.03141785000E14E15 25/10/2006 1 39 36 -2.5 0.25 36 51.22098160000D7E16 25/01/2006 1 UC 21.5 12 -1.5 - 12 N 107.60725403000 Only a trickle, not usedG4 13/08/2007 1G5C1C2 2/05/2003 1 UC 25 17 -4 0.02 17 Y N 127.57356262000C3 9/05/2003 1 31C4 2/05/2003 1 25 17 -4 0.025 17 90.87135315000C5 9/05/2003 1 31 .- .- .- (NIL) .- Nil water, bore abandonedC6C7C8C9C10C11 -1.8 80.17336578000 alluvium Bore located near former (now dry) Dam; in paddock; The bore was NOT put in by her (last 5 yrs) or the previous ownerC12 3/03/2004 1 UC 14 9 -5.5 0.437 9 Y N 102.25466156000C13 20/05/2003 1 FR 14 7 0.5 7 12 YC14 18/10/2006 1 UC 14 5 & 9 -3 0.43 5 N 97.18775177000C15 20/03/2006 1 UC 15.5 6 & 10 -5.5 0.162 6 10 Y N 93.51816559000 Bore located in gully down sloping backyardC16 20/05/2006 1 14 7 & 9 -1.75 0.5 7 105.73023987000 Bore located in gully down sloping backyardC17C18 20/06/2005 1 UC 40 25 -18 0.018 25 N 79.03181458000 She reckons bore is only a trickle, or practically none, but it is 0.018L/secC19C20 Bore located near dam in paddock with horses; No pump, just PVC pipe; they only use rainwater tanksC21

* -9.1 in 2007, originally -7.3

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CRICOS No. 00213J

Water Analysis Table

BORE PIPE TEST DATE REC ANALYST ANALYSIS NO SAMP METHOD S OURCE DEPTH FIG MERIT NA ADS RATIOF1F2 A 31/07/2007 1 B Jones@QUT GBF3F4F5 A 28/06/2007 1 B Jones@QUT GBF6F7F8F9 A 28/06/2007 1 B Jones@QUT GBF10 A 16/12/1982 1 GCL 95968 GB 20 1.8 2.1F11F12 A 21/06/2007 1 B Jones@QUT GBF13F14 - DRY BORE - - - - - - - -F15 A 21/06/2007 1 B Jones@QUT GBF16 A 18/06/1993 1 DPI 93 6 809 PU GB 1 5.5F17 - DRY BORE - - - - - - - -F18F19 - DRY BORE - - - - - - - -F20F21F22F23 A 28/06/2007 1 B Jones@QUT GBF24 - DRY BORE - - - - - - - -F25F26F27F28 A 28/06/2007 1 B Jones@QUT GBF29F30F31 A 28/06/2007 1 B Jones@QUT GBF32F33F34F35F36F37F38H1H2 A 8/09/1988 1 GCL 126647 PU GB 5 0.7 3.8A1A2A3 A 31/07/2007 1 B Jones@QUT GBA4 A 21/06/2007 1 B Jones@QUT GBB1A5A6A7 - DRY BORE - - - - - - - -A8A9 A 5/06/2007 1 B Jones@QUT GBA10 - DRY BORE - - - - - - - -B2A11A12A13 A 31/07/2007 1 B Jones@QUT GBA14B3 A 21/06/2007 1 B Jones@QUT GBB4 A 21/06/2007 1 B Jones@QUT GBB5 A 6/03/2007 1 PRSC HD07NA1696 GB 1.1 2.7A15A16A17A18 A 21/06/2007 1 B Jones@QUT GBB6 A 28/06/2007 1 B Jones@QUT GBA19

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CRICOS No. 00213J

Water Analysis Table

A20A21 A 5/06/2007 1 B Jones@QUT GBA22 A 5/06/2007 1 B Jones@QUT GBA23A24A25A26H3 A 1/01/1950 1 GCL 1 GB 5G1 A 2/08/1993 1 DPI PU GB 1.1 3.2E1 A 31/07/2007 1 B Jones@QUTG2A A 29/02/1988 1 GCL 123686 PU GB 19 1.1 2.2G2B A 1/03/1988 1 GCL 123688 PU GB 19 1.2 1.9G2C A 21/04/1988 1 GCL 123852 GB 19E2 A 31/07/2007 1 B Jones@QUT GBE3E4E5E6 - DRY BORE - - - - - - - -E7 - DRY BORE - - - - - - - -D1D2 A 31/07/2007 1 B Jones@QUT GBE8E9 A 5/06/2007 1 B Jones@QUT GBE10E11D3E12 A 31/07/2007 1 B Jones@QUT GBD4 - DRY BORE - - - - - - - -D5 A 1/10/1991 1 GCL 140851 BA GB 30 0.4 12.2E13 31/07/2007G3D6 A 31/07/2007 1 B Jones@QUT GBE14E15 A 31/07/2007 1 B Jones@QUTD7 A 1/10/1979 1 GCL 82698 GB 0.5 6.5E16G4G5C1 A 31/07/2007 1 B Jones@QUT GBC2C3C4C5 - DRY BORE - - - - - - - -C6C7C8C9C10C11 A 10/07/2007 1 B Jones@QUT GBC12C13C14C15 A 21/06/2007 1 B Jones@QUT GBC16 A 21/06/2007 1 B Jones@QUT GBC17C18C19C20 A 10/07/2007 1 B Jones@QUT GBC21

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CRICOS No. 00213J

Water Analysis Table

RES ALK TOTAL IONS TOTAL SOLIDS HARD ALK SiO2 Al Sr Mn Fe Mg

507.79 0.01732 0.09226 0.10690 22.17000

82.79 0.02396 0.10980 0.03247 0.04496 21.790001282.6

1807.3 0.12210 0.18630 0.18750 0.03308 117.10000757.1 623.57 347 300 52 63

757.9333.48 0.05017 0.07046 0.30380 20.04000361.46

- - - - - - - - - - -125.35 0.02085 0.00576 0.00716 0.09654 1.80000

0.00 1995.9 1707.69 774 495 165- - - - - - - - - - -

- - - - - - - - - - -

378.95

253.61 0.01899 0.09124 0.00690 0.00233 9.12300- - - - - - - - - - -

303.16

516.54 0.09100 0.15810 0.14200 4.17400 33.59000

506.63 0.47710 0.49280 0.09142 3.82800 114.70000

320.65

303.16

1515.80.73 633.02 547.78 194 230 52 0.01 0.01 27

361.46320.65 0.09332 0.00317 13.47000385.36 0.12520 0.62340 0.02699 16.23000384.78

- - - - - - - - - - -

589.41 0.13100 0.23520 0.00310 0.00436 34.98000- - - - - - - - - - -

221.54

403.44 0.03422 0.09219 0.00344 0.26180 26.60000

350.97 0.09307 0.00290 0.01682 16.64000172.57 0.04083 0.00385 0.00345 5.01500

1.0 560 474 203 251 69 0.05 0.11 0.01 29.00

593.49 0.01765 0.10710 0.02845 3.23600 25.84000184.81 0.00066 0.16420 0.02006 0.24160 39.34000256.52

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CRICOS No. 00213J

Water Analysis Table

408.1258.85 0.14720 0.08643 0.00618 0.29280 17.30000705.43 0.09520 0.21670 0.00213 0.02363 25.54000

68 122 11728.5 669.54 321 95 0 44

419.76 0.04396 0.18840 0.01205 29.13000340.77 326.77 135 99 47 2.9 0.07 23326.84 315.39 133 94 47 3.2 0.04 22

3.2 411269.19 0.08914 4.59800 0.08909 1.63800 100.800002215.41282.6198.22

- - - - - - - - - - -- - - - - - - - - - -

3486.34 0.06269 0.17370 0.00916 141.60000244.86522.37 0.05504 0.10170 0.00444 0.24540 18.04000

1690.7

559.68 0.00209 0.29170 0.00746 0.04903 12.94000- - - - - - - - - - -

4.42 2030.2 1529.49 656 878 33 130588.83 0.20630 0.58090 0.00486 54.80000209.88

1184.07 0.07612 0.09192 47.34000

3368.57 0.23610 1.58900 0.09052 1.77500 154.100001073.1 973.78 295 180 12 48

244.86

1518.72 0.676 0.367 0.0704 0.04524 98.441049.4

1049.4- - - - - - - - - - -

94.45 0.02595 0.09699 0.01749 16.13204.05256.52326.48348.63 0.07524 0.00261 0.01797 15.34000295.00 0.05686 0.01739 0.61330 10.86000

2157.1

0.1294 0.07115 0.2201 0.8 7.578

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CRICOS No. 00213J

Water Analysis Table

Na Ca Zn Cu K HCO3– CO3

2– Cl– F– Br– NO3–

87.98000 31.44000 1.54000 256.81 76.19 0.14 8.08

54.62000 24.08000 0.13440 0.00167 1.71100 125.0 68.82 0.44

467.90000 49.02000 0.01728 0.02172 12.60000 643.5 759.40 1.40 1.6390 35 5 333.5 0.7 185.00 0.40 1.00

75.05000 25.42000 0.00732 0.00577 3.75400 175.0 74.72 0.19 0.06

- - - - - - - - - - -39.64000 2.26600 0.03272 0.02171 0.59440 42.0 21.01 0.51 6.10 1.75

352 38 10.3 500 18 795.00 0.60- - - - - - - - - - -

- - - - - - - - - - -

39.69000 14.25000 1.42400 0.62740 1.15000 81.0 49.25 0.22 1.80- - - - - - - - - - -

98.49000 46.80000 0.00908 0.06924 3.69700 297.5 121.84 0.48 0.86

367.70000 159.50000 0.46890 0.15600 13.61000 478.5 770.55 0.03 9.27

120 33 1.5 269 5.2 140.00 0.30 0.50

40.91000 17.68000 0.38770 0.01625 7.77400 130.98000 37.14 0.31 1.6460.67000 31.93000 3.34700 0.03609 1.42600 167.5 57.42 0.05 0.05

- - - - - - - - - - -

105.70000 43.82000 0.18340 0.15350 3.53700 365.0 61.22 1.28 0.03 1.81- - - - - - - - - - -

123.40000 16.40000 2.75200 0.26800 1.37800 338.6 60.24 0.70

59.73000 22.09000 0.03384 0.14550 2.76800 98.5 93.49 13.3939.93000 9.21200 0.08608 0.01840 1.62000 47.3 42.50 0.15 11.65

87.00 34.00 0.01 0.03 2.80 305.0 0.3 92.00 0.54 2.00

92.81000 31.73000 0.04975 0.05923 4.11000 169.0 139.43 0.03 0.38139.60000 38.54000 2.56600 0.00135 2.53300 262.0 169.47 1.04

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CRICOS No. 00213J

Water Analysis Table

31.43000 27.84000 0.07713 0.00884 3.66900 187.0 27.80 0.28 0.20 5.2075.27000 49.14000 0.03846 0.01434 3.65900 258.0 70.27 0.51 0.37 0.77

52.5 9 100 60.00133 56 3.1 116 0 333.00 0.00 0.40

116.40000 41.26000 0.00428 2.55800 355.02 66.81 0.6658 16 1.7 120 0.1 115.00 0.30 0.5051 17 1.1 115 0.1 110.00 0.20 5.20

328.20000 41.31000 0.00513 0.01769 1.66900 529.79 473.11 0.25 1.15

- - - - - - - - - - -- - - - - - - - - - -

828.80000 119.40000 0.11450 0.01022 6.62500 728.0 1155.86 0.17

40.97000 27.63000 0.08322 0.01457 2.57000 163.1 48.36 0.15 0.39 3.80

108.90000 18.99000 3.62000 1.41000 2.26200 244.3 68.59 1.07 4.28- - - - - - - - - - -

720 48.5 26.5 1050 9.9 950.00 1.80172.60000 58.42000 0.01429 3.22600 429.4 155.69 0.13

286.10000 33.78000 0.01469 7.03600 686.56 170.19 0.70

572.80000 145.70000 8.64400 428.83 1273.73 0.27 2.74255 39 3 219 0 470.00 0.20 4.90

340 56.96 0.06741 0.04722 5.839 675.88 360.24 0.14

- - - - - - - - - - -

87.38 17.20 0.05847 0.1131 190.15 56.25 0.50

65.18000 42.36000 0.04202 0.00891 2.32700 278.0 23.48 0.14 0.6661.50000 25.01000 0.05474 0.02372 1.86200 195.5 29.35 0.14 0.05 6.85

61.18 7.751 1.31 13.94 1.605 89.365 64.08 0.20 10.43

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CRICOS No. 00213J

Water Analysis Table

PO43– SO4

2–

34.16

22.00

34.2912.00

0.03 19.93

- -12.6919.00

- -

- -

16.04- -

7.69

35.82

35.50

8.2359.13

- -

10.05- -

7.71

8.442.437.40

4.9248.20

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CRICOS No. 00213J

Water Analysis Table

7.6718.56

14.0043.0053.663.202.00

14.69

- -- -

4.12

14.13

37.75- -

43.5046.21

4.05

17.674.00

2.56

- -

11.15

11.9115.60

2.11

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CRICOS No. 00213J

Elevation and Co-ordinate Table

BORE ELEVATION GIS LATITUDE (y) GIS LONGITUDE (x) NR&W CHECKED EASTING (x) NORTHING (y) CO-ORDINATE SYSTEM ZONE LATITUDE (y) LONGITUDE (x) ACCURACY GPS ACCURACYF1 142.36392212 -27.41305600 152.8627780 486435.58 6967806.18 UTM 56J 27°24'47'' S 152°51'46'' EF2 165.04042053 -27.41250000 152.8658330 486737.50 6967868.10 UTM 56J 27°24'45'' S 152°51'57'' EF3 119.10253906 -27.41194400 152.8594440 486105.88 6967928.99 UTM 56J 27°24'43'' S 152°51'34'' EF4 109.17855072 -27.40972200 152.8577780 485940.91 6968174.92 UTM 56J 27°24'35'' S 152°51'28'' EF5 111.58896637 -27.40861100 152.8513890 485309.19 6968297.24 UTM 56J 27°24'31'' S 152°51'05'' EF6 53.67713928 -27.37913750 152.8884241 Y 488967.34 6971565.72 UTM 56J 27°22'45'' S 152°53'18'' E GPS 10F7 73.63883209 -27.38472200 152.8816670 488299.78 6970946.53 UTM 56J 27°23'05'' S 152°52'54'' EF8 65.48519897 -27.38527800 152.8811110 488244.87 6970884.89 UTM 56J 27°23'07'' S 152°52'52'' EF9 87.30635071 -27.39222367 152.8842007 Y 488551.08 6970115.84 UTM 56J 27°23'32'' S 152°53'03'' EF10 79.80293274 -27.39381601 152.8883375 Y 488960.23 6969939.84 UTM 56J 27°23'38'' S 152°53'18'' E UNKNF11 64.49034119 -27.39160781 152.8928324 Y 489404.42 6970184.82 UTM 56J 27°23'30'' S 152°53'34'' E GPS 10F12 89.88522339 -27.40027780 152.8594444 Y 486104.46 6969221.20 UTM 56J 27°24'01'' S 152°51'34'' E GPS 10F13 101.24707031 -27.40261435 152.8682307 Y 486973.36 6968963.34 UTM 56J 27°24'09'' S 152°52'06'' EF14 112.52137756 -27.40416670 152.8658333 Y 486736.54 6968791.14 UTM 56J 27°24'15'' S 152°51'57'' E GPS 10F15 112.89778137 -27.40472200 152.8661110 486764.06 6968729.66 UTM 56J 27°24'17'' S 152°51'58'' EF16 90.49937439 -27.39515227 152.8823082 Y 488364.27 6969791.28 UTM 56J 27°23'43'' S 152°52'56'' E UNKNF17 84.16453552 -27.39388890 152.8852778 Y 488657.74 6969931.49 UTM 56J 27°23'38'' S 152°53'07'' E GPS 10F18 86.40231323 -27.39638900 152.8811110 488246.04 6969654.18 UTM 56J 27°23'47'' S 152°52'52'' EF19 106.22076416 -27.40277780 152.8738889 Y 487532.74 6968945.82 UTM 56J 27°24'10'' S 152°52'26'' E GPS 10F20 96.89158630 -27.40083300 152.8747220 487614.89 6969161.32 UTM 56J 27°24'03'' S 152°52'29'' EF21 93.42050171 -27.40039083 152.8758780 Y 487729.12 6969210.41 UTM 56J 27°24'01'' S 152°52'33'' E GPS 10F22 98.28659058 -27.40111100 152.8744440 487587.43 6969130.50 UTM 56J 27°24'04'' S 152°52'28'' EF23 71.82234955 -27.39363542 152.8946185 Y 489581.20 6969960.38 UTM 56J 27°23'37'' S 152°53'41'' E UNKNF24 102.15243530 -27.39861100 152.8827780 488411.08 6969408.21 UTM 56J 27°23'55'' S 152°52'58'' EF25 84.21795654 -27.39722220 152.8761111 Y 487751.82 6969561.41 UTM 56J 27°23'50'' S 152°52'34'' E GPS 10F26 90.41406250 -27.39972200 152.8705560 487202.90 6969283.96 UTM 56J 27°23'59'' S 152°52'14'' EF27 83.84493256 -27.39750000 152.8713890 487285.00 6969530.16 UTM 56J 27°23'51'' S 152°52'17'' EF28 90.58262634 -27.40027800 152.8708330 487230.35 6969222.40 UTM 56J 27°24'01'' S 152°52'15'' EF29 97.48766327 -27.40111100 152.8705560 487203.06 6969130.10 UTM 56J 27°24'04'' S 152°52'14'' EF30 85.79429626 -27.39747386 152.8751584 Y 487657.66 6969533.44 UTM 56J 27°23'51'' S 152°52'31'' E UNKNF31 80.80998230 -27.39333300 152.8758330 487723.89 6969992.17 UTM 56J 27°23'36'' S 152°52'33'' EF32 79.34068298 -27.39472200 152.8744440 487586.72 6969838.18 UTM 56J 27°23'41'' S 152°52'28'' EF33 83.55152130 -27.39666700 152.8744440 487586.94 6969622.74 UTM 56J 27°23'48'' S 152°52'28'' EF34 83.68528748 -27.39675183 152.8732549 Y 487469.39 6969613.22 UTM 56J 27°23'48'' S 152°52'24'' EF35 85.52229309 -27.39722200 152.8722220 487367.32 6969561.04 UTM 56J 27°23'50'' S 152°52'20'' EF36 107.25304413 -27.40567560 152.8589181 Y 486053.10 6968623.25 UTM 56J 27°24'34'' S 152°51'59'' E UNKNF37 87.31219482 -27.39972200 152.8891670 489042.83 6969285.73 UTM 56J 27°23'59'' S 152°53'21'' EF38 89.66113281 -27.40027800 152.8891670 489042.88 6969224.15 UTM 56J 27°24'01'' S 152°53'21'' EH1 72.36338806 -27.36038403 152.9119257 Y 491289.72 6973644.81 UTM 56J 27°21'37'' S 152°54'43'' EH2 47.55944061 -27.35242886 152.9009456 Y 490203.12 6974525.15 UTM 56J 27°21'09'' S 152°54'03'' E UNKNA1 120.54857635 -27.39000000 152.8197220 482175.78 6970354.57 UTM 56J 27°23'24'' S 152°49'11'' EA2 95.17948914 -27.39070154 152.8273396 Y 482929.05 6970277.93 UTM 56J 27°23'27'' S 152°49'38'' E UNKNA3 100.23847198 -27.39196533 152.8285430 Y 483048.22 6970138.11 UTM 56J 27°23'31'' S 152°49'43'' EA4 156.08226013 -27.38705505 152.7959657 Y 479826.44 6970677.15 UTM 56J 27°23'13'' S 152°47'45'' E GPS 10B1 86.79467773 -27.36651130 152.8273612 Y 482927.47 6972957.38 UTM 56J 27°21'59'' S 152°49'39'' E GPS 10A5 148.58627319 -27.39444400 152.8250000 482698.32 6969863.07 UTM 56J 27°23'40'' S 152°49'30'' EA6 83.06827545 -27.37944400 152.8275000 482943.18 6971524.90 UTM 56J 27°22'46'' S 152°49'39'' EA7 122.32004547 -27.39311702 152.8251959 Y 482717.48 6970010.08 UTM 56J 27°23'35'' S 152°49'31'' E GPS 10A8 114.98994446 -27.39500000 152.8272220 482918.08 6969801.79 UTM 56J 27°23'42'' S 152°49'38'' EA9 101.16764832 -27.38305600 152.8275000 482943.74 6971124.82 UTM 56J 27°22'59'' S 152°49'39'' EA10 96.10183716 -27.38555600 152.8291670 483108.94 6970848.13 UTM 56J 27°23'08'' S 152°49'45'' EB2 135.64080811 -27.37500088 152.8054755 Y 480764.63 6972013.84 UTM 56J 27°22'30'' S 152°48'20'' EA11 108.83288574 -27.37555600 152.8094440 481157.14 6971952.96 UTM 56J 27°22'32'' S 152°48'34'' EA12 104.75450134 -27.37944400 152.8125000 481459.98 6971522.76 UTM 56J 27°22'46'' S 152°48'45'' EA13 93.86954498 -27.37997927 152.8305874 Y 483248.55 6971466.03 UTM 56J 27°22'48'' S 152°49'50'' E GPS 10A14 90.30949402 -27.37888900 152.8202780 482228.98 6971585.37 UTM 56J 27°22'44'' S 152°49'13'' EB3 133.55584717 -27.37388900 152.8030560 480525.18 6972136.62 UTM 56J 27°22'26'' S 152°48'11'' EB4 122.16873932 -27.37194400 152.8047220 480689.59 6972352.32 UTM 56J 27°22'19'' S 152°48'17'' EB5 80.43265533 -27.36694400 152.8308330 483270.87 6972909.92 UTM 56J 27°22'01'' S 152°49'43'' EA15 101.83810425 -27.37972200 152.8141670 481624.86 6971492.21 UTM 56J 27°22'47'' S 152°48'51'' EA16 94.39411926 -27.37972200 152.8175000 481954.43 6971492.70 UTM 56J 27°22'47'' S 152°49'03'' E

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CRICOS No. 00213J

Elevation and Co-ordinate Table

A17 99.49576569 -27.38222200 152.8166670 481872.47 6971215.66 UTM 56J 27°22'56'' S 152°49'00'' EA18 109.03340149 -27.38750000 152.8191670 482120.51 6970631.40 UTM 56J 27°23'15'' S 152°49'09'' EB6 96.14372253 -27.37055600 152.8183330 482035.31 6972508.10 UTM 56J 27°22'14'' S 152°49'06'' EA19 134.20706177 -27.39305657 152.8195650 Y 482160.75 6970015.98 UTM 56J 27°23'35'' S 152°49'10'' EA20 125.18003845 -27.39250000 152.8200000 Y 482203.67 6970077.70 UTM 56J 27°23'33'' S 152°49'12'' E GPS 10A21 124.76037598 -27.39333300 152.8222220 482423.49 6969985.74 UTM 56J 27°23'36'' S 152°49'20'' EA22 137.83697510 -27.39453865 152.8208687 Y 482289.88 6969852.01 UTM 56J 27°23'40'' S 152°49'15'' EA23 134.77268982 -27.39333300 152.8191670 482121.45 6969985.31 UTM 56J 27°23'36'' S 152°49'09'' EA24 114.98713684 -27.38194400 152.8091670 481130.83 6971245.34 UTM 56J 27°22'55'' S 152°48'33'' EA25 112.98178101 -27.38083300 152.8094440 481158.04 6971368.45 UTM 56J 27°22'51'' S 152°48'34'' EA26 108.11836243 -27.38250000 152.8113890 481350.63 6971184.09 UTM 56J 27°22'57'' S 152°48'41'' EH3 482.23327637 -27.38453230 152.7788305 Y 478131.73 6970953.69 UTM 56J 27°23'04'' S 152°46'44'' E GPS 10G1 59.01585388 -27.35767372 152.9009557 Y 490204.58 6973944.20 UTM 56J 27°21'28'' S 152°54'03'' E UNKNE1 89.96067810 -27.36224950 152.8485885 Y 485026.11 6973432.16 UTM 56J 27°21'44'' S 152°50'55'' E GPS 10G2 48.85353851 -27.36766476 152.8964461 Y 489759.50 6972837.18 UTM 56J 27°22'04'' S 152°53'47'' EE2 55.01645279 -27.35472200 152.8786110 487994.38 6974269.20 UTM 56J 27°21'17'' S 152°52'43'' EE3 81.58985901 -27.37083260 152.8448341 Y 484656.00 6972481.00 UTM 56J 27°22'15'' S 152°50'41'' E GPS 10E4 74.76452637 -27.36861100 152.8550000 485660.99 6972728.29 UTM 56J 27°22'07'' S 152°51'18'' EE5 92.91610718 -27.36505270 152.8591500 Y 486070.94 6973122.89 UTM 56J 27°21'54'' S 152°51'33'' E UNKNE6 79.75423431 -27.36694400 152.8652780 486677.18 6972914.07 UTM 56J 27°22'01'' S 152°51'55'' EE7 72.32447815 -27.36722200 152.8650000 486649.72 6972883.25 UTM 56J 27°22'02'' S 152°51'54'' ED1 69.10216522 -27.38055600 152.8616670 486321.76 6971405.94 UTM 56J 27°22'50'' S 152°51'42'' ED2 72.72537994 -27.37972200 152.8611110 486266.68 6971498.26 UTM 56J 27°22'47'' S 152°51'40'' EE8 80.64530945 -27.36444400 152.8675000 486896.63 6973191.22 UTM 56J 27°21'52'' S 152°52'03'' EE9 85.74143219 -27.36333300 152.8680560 486951.48 6973314.34 UTM 56J 27°21'48'' S 152°52'05'' EE10 97.60636902 -27.36300932 152.8677115 Y 486917.37 6973350.15 UTM 56J 27°21'47'' S 152°52'04'' EE11 57.52365875 -27.37200070 152.8679958 Y 486946.54 6972354.25 UTM 56J 27°22'19'' S 152°52'48'' E GPS 10D3 60.64148331 -27.36972200 152.8561110 485771.00 6972605.35 UTM 56J 27°22'11'' S 152°51'22'' EE12 87.89140320 -27.36555560 152.8425000 Y 484424.44 6973065.22 UTM 56J 27°21'56'' S 152°50'33'' E GPS 10D4 79.81034088 -27.37971330 152.8663284 Y 486782.58 6971499.79 UTM 56J 27°22'47'' S 152°51'59'' E UNKND5 68.79301453 -27.37773219 152.8659266 Y 486742.61 6971719.18 UTM 56J 27°22'40'' S 152°51'57'' E UNKNE13 77.78344727 -27.36583300 152.8519440 485358.42 6973035.64 UTM 56J 27°21'57'' S 152°51'07'' EG3 44.08166885 -27.35944400 152.8947220 489588.24 6973747.61 UTM 56J 27°21'34'' S 152°53'41'' ED6 68.53141785 -27.37694878 152.8694672 Y 487092.62 6971806.33 UTM 56J 27°22'37'' S 152°52'10'' E UNKNE14 66.16719818 -27.37111100 152.8736110 487501.71 6972453.38 UTM 56J 27°22'16'' S 152°52'25'' EE15 53.72098160 -27.37083300 152.8716670 487309.44 6972483.97 UTM 56J 27°22'15'' S 152°52'18'' ED7 76.47724915 -27.38524012 152.8607056 Y 486227.28 6970887.00 UTM 56J 27°23'07'' S 152°51'39'' E UNKNE16 109.10725403 -27.36206620 152.8619071 Y 486343.23 6973454.00 UTM 56J 27°21'43'' S 152°51'43'' E GPS 10G4 52.19744873 -27.37222200 152.8836110 488490.70 6972331.28 UTM 56J 27°22'20'' S 152°53'01'' EG5 49.99047852 -27.37083300 152.8833330 488463.07 6972485.11 UTM 56J 27°22'15'' S 152°53'00'' EC1 81.77803040 -27.39083300 152.8594440 486103.24 6970267.36 UTM 56J 27°23'27'' S 152°51'34'' EC2 131.57356262 -27.41190338 152.8445037 Y 484629.00 6967931.73 UTM 56J 27°24'43'' S 152°50'40'' EC3 135.57180786 -27.41187462 152.8450790 Y 484685.87 6967934.98 UTM 56J 27°24'43'' S 152°50'42'' EC4 94.87135315 -27.40444400 152.8558330 485747.96 6968759.32 UTM 56J 27°24'16'' S 152°51'21'' EC5 94.87135315 -27.40444400 152.8558330 485747.96 6968759.32 UTM 56J 27°24'16'' S 152°51'21'' EC6 81.04022217 -27.39222200 152.8597220 486130.90 6970113.54 UTM 56J 27°23'32'' S 152°51'35'' EC7 104.36602783 -27.39888900 152.8433330 484511.46 6969373.13 UTM 56J 27°23'56'' S 152°50'36'' EC8 88.29090881 -27.39666700 152.8638890 486543.42 6969621.64 UTM 56J 27°23'48'' S 152°51'50'' EC9 76.76413727 -27.39111100 152.8636110 486515.26 6970237.03 UTM 56J 27°23'28'' S 152°51'49'' EC10 79.37996674 -27.38416700 152.8388890 484070.01 6971003.26 UTM 56J 27°23'03'' S 152°50'20'' EC11 81.97336578 -27.38500000 152.8386110 484042.64 6970910.96 UTM 56J 27°23'06'' S 152°50'19'' EC12 107.75466156 -27.39819940 152.8332395 Y 483513.49 6969448.22 UTM 56J 27°23'54'' S 152°50'00'' EC13 102.37355042 -27.39687555 152.8372712 Y 483911.88 6969595.38 UTM 56J 27°23'49'' S 152°50'14'' EC14 100.18775177 -27.39676030 152.8376986 Y 483954.12 6969608.20 UTM 56J 27°23'48'' S 152°50'16'' E GPS 10C15 99.01816559 -27.39766870 152.8365585 Y 483841.54 6969507.44 UTM 56J 27°23'52'' S 152°50'12'' E GPS 10C16 107.48023987 -27.39777800 152.8358330 483769.83 6969495.24 UTM 56J 27°23'52'' S 152°50'09'' EC17 99.44569397 -27.39500000 152.8430560 484483.54 6969803.86 UTM 56J 27°23'42'' S 152°50'35'' EC18 97.03181458 -27.39253496 152.8505610 Y 485225.20 6970077.82 UTM 56J 27°23'33'' S 152°51'02'' E GPS 10C19 89.68402863 -27.39666700 152.8558330 485746.96 6969620.75 UTM 56J 27°23'48'' S 152°51'21'' EC20 78.20840454 -27.38916700 152.8566670 485828.46 6970451.58 UTM 56J 27°23'21'' S 152°51'24'' EC21 75.72455597 -27.38694400 152.8586110 486020.39 6970698.03 UTM 56J 27°23'13'' S 152°51'31'' E

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CRICOS No. 00213J

Drilling Contractor's Remarks Table

BORE RN DRILLER REMARKS

F1F2F3F4F5F6 124853 BORE IS LOCATED IN AREA RENOWNED FOR SALT WATER IN GRANITE. BORE WAS COMPLETED IN VERY SHALLOW ALLUVIUM

AS A VERY LOW YIELD SUITABLE FOR TANK FILLING BY INTERMITTENT PUMPING. NOTE: DUE TO VERY SHALLOW DEPTH OF

ALLUVIUM CEMENTING FROM 3m WAS ONLY POSSIBLE.

F7F8F9 120458 DESPITE HIGH SALT CONTENT OWNER HAS USE FOR WATER.

F10 79159F11 124206F12 133877 RECOMMENDED PUMPING RATE FOR TANK FILLING, INTERMITTENT PUMPING @ 0.187 LPS

F13 120217 RECOMMENDED PUMPING RATE FOR TANK FILLING @ 0.225 LPS. EXTENSIVE EXPERIENCE IN THIS AREA HAS SHOWN THAT

DRILLING UP TO 70 - 80 m IN SOLID GRANITE RARELY PRODUCES RESULTS.

F14 133792 THIS PARTICULAR BORE IS SURROUNDED MAINLY BY USEFUL BORES IN GRANITE. GRANITE ON THIS SITE NOT PERMEABLE.

F15F16 79713F17 134255 NO FRACTURING & NO WATER. ALTHOUGH IT IS NOT RECOMMENDED PRACTICE TO DRILL INTO SOLID GRANITE FOR WATER

THERE WAS NO ALTERNATIVE ON THIS PROPERTY AS DECOMPOSED GRANITE OF ANY DEPTH WAS UNAVAILABLE.

F18F19 134182 IN NORMAL SEASONS USEFUL WATER MAY HAVE OCCURRED IN THE LOWER DECOMPOSED GRANITE. THIS PROPERTY IS

LOCATED CLOSE TO BASE OF MOUNTAIN. INSUFFICIENT DEPTH OF DECOMPOSED GRANITE TO PRODUCE USEFUL WATER.

EXPERIENCE HAS SHOWN THAT DRILLING MORE THAN SEVERAL METRES INTO SOLID GRANITE IN THIS AREA IS RARELY

SUCCESSFUL.

F20F21 124005 RECOMMENDED PUMPING RATE 0.56 LPM. NOTE: AT LEAST 6 BORES IN CLOSE PROXIMITY IN SAME FORMATION HAVE PUMPED

RELIABLY FOR MANY YEARS.

F22F23 120587F24F25 133875 RECOMMENDED PUMPING RATE 0.56 LPS (450 GALL/HR). NOTE: EXTENSIVE FRETTING OF FORMATION BETWEEN BASEMENT

OF STIFF CLAY & TOP OF SOLID GRANITE.

F26F27F28F29F30 120589F31F32F33F34 120465 RECOMMENDED PUMPING RATE 0.5 LPS (400 GALL/HR). NOTE: EXTENSIVE DRILLING CARRIED OUT IN THIS AREA HAS PROVEN

THAT IN ALMOST EVERY BORE WHERE DRILLING HAS CONTINUED INTO HARD GRANITE NO FURTHER WATER HAS BEEN

ENCOUNTERED.

F35F36 133516 BORE COMPLETED @ 15.25m. RECOMMENDED PUMPING RATE 0.5 LPS.

F37F38H1 120216 VIRTUALLY NO VARIATION IN THIS FORMATION VERY SLIGHT FRACTURING @ 18.5m YIELDING A TANK FILLING SUPPLY.

DRILLING TO 24m ONLY DUE TO FINANCIAL RESTRAINTS. NOTE: BORE DRILLED IN THE BOTTOM OF THE ONLY GULLY

(ACCESSIBLE) ON PROPERTY. "TANK FILLING" SUPPLY ACQUIRED.

H2 79216A1A2 124012 RECOMMENDED PUMPING RATE 0.437 LPS. NOTE: THIS PARTICULAR PART OF HIGHVALE GENERALLY PRODUCES LESSER YIELDS

SO REC. P.R. KEPT TO 0.437 LPS.

A3 120508 TEST BORE EMPTIED & ALLOWED TO REFILL OVER A FEW HOURS, OWNER DECIDED A VERY LOW YIELD SUITABLE FOR TANK

FILLING BETTER THAN ABANDONING BORE.

A4 124245 LOW YIELD BORE TO PROVIDE TANK FILLING SUPPLY. BORE DRILLED CLOSE TO HEAD OF DAWSON CREEK IN AREA

SURROUNDED BY BOULDERS.

B1 134096 RECOMMENDED PUMPING RATE MAXIMUM 0.625 LPS.

A5A6A7 124665 SITE DIVINED BY OPTIMISTIC DIVINER. OWNER DECIDED TO DRILL INTO HARD GRANITE AS BORE POSITION WAS A LOGICAL SITE.

RARELY OBTAIN WATER IN HARD GRANITE. NOTE: SURFACE CASING CEMENTED & CAPPED TO ALLOW FUTURE DEEPENING IF

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CRICOS No. 00213J

Drilling Contractor's Remarks Table

DECISION MADE.

A8A9A10 I NORMALLY DO NOT RECOMMEND DRILLING INTO SOLID GRANITE BECAUSE OF MINIMAL CHANCE OF SUCCESS, BUT DUE TO THE

FACT THAT A SUCCESSFUL BORE EXISTED IN SOLID GRANITE WITHIN APPROX 200m IT WAS DECIDED TO DRILL INTO SOLID

GRANITE WITH A CHANCE OF ACQUIRING A USEFUL SUPPLY.

B2 120466 TO MINIMISE CHANCES OF CEMENT GROUT INFILTRATING WATER BED BORE WAS BACKFILLED TO 2.5m. NOTE: BORE LOCATED

IN NARROW GULLY NEIGHBOURING BORE IN SIMILAR LOCATION (150m DISTANCE) HAS PRODUCED RELIABLE WATER FROM

SIMILAR DEPTH. EXTENSIVE LOCAL EXPERIENCE HAS SHOWN THAT DRILLING DEEP IN VERY HARD GRANITE IS A WASTE OF TIME.

A11A12A13 79880A14B3B4B5A15A16A17A18B6A19 120163 DRILLING DEEP INTO SOLID GRANITE IN THIS AREA HAS RARELY PROVEN WORTHWHILE.

A20 134181 SURFACE CASING SEALED & CEMENTED TO ALLOW FOR FUTURE DEEPENING OF BORE IF & WHEN REQUIRED.

A21A22 120467 THIS PROPERTY HAS HAD 3 PREVIOUS BORES DRILLED 2 UNSUCCESSFUL. 1 APPROX. 20 YRS AGO PRODUCED 0.625 LPS @

APPROX. 20m BUT DEPLETED OVER TIME. NOTE: THE FACT THAT THE SOLID GRANITE WAS SLIGHTLY SOFTER THAN NORMAL

ENCOURAGED DEEPER DRILLING THAN USUSAL IN THIS FORMATION IN THE AREA. AS WELL THE PROPERTY IS CLOSE TO THE

EDGE OF THE GRANITE BOUNDERED BY THE BLACK ROCK IN THE ADJACENT RANGE.

A23A24A25A26H3 79699G1 79861E1 133950 RECOMMENDED PUMPING RATE 0.5 LPS. NOTE: SEVERE FRETTING OF DECOMPOSED GRANITE PARTICULARLY @ 6.8m REQUIRED

EXTENSIVE GRAVEL PACKING.

G2 73232E2E3 134223E4 DRILLING DEEPER THAN SEVERAL METRES INTO SOLID GRANITE IN THIS AREA IS ONLY SUCCESSFUL IN ISOLATED INSTANCES.

BECAUSE NO ACTUAL GULLIES ON THIS PROPERTY DRILLING WAS CONTINUED WITH THE POSSIBILITY OF ENCOUNTERING A

FRACTURE.

E5 133874 FROM 5m DRILLING WAS THROUGH SOLID BLACK & WHITE GRANITE WITH NO FRACTURING, FAIRLY TYPICAL OF THIS

FORMATION IN ELEVATED AREAS OF SAMFORD . NOTE: PVC CASING SEALED AT 5m & CEMENT GROUTED TO ALLOW FOR ANY

FUTURE DEEPENING OF BORE.

E6 DRILLING INTO SOLID GRANITE IN THIS AREA IS ONLY SUCCESSFUL IN ISOLATED INSTANCES. GENERALLY WATER OCCURS IN

LOWER DECOMPOSED GRANITE OR IN INITIAL FRACTURED HARD GRANITE.

E7 NO FRACTURING IN HARD GRANITES FROM 3.5 - 36.5m. NOTE: THIS BORE NO.2 WAS DRILLED ALSO INTO HARD GRANITE WITH

THE SLIM CHANCE THAT SOME FRACTURING MIGHT OCCUR.

D1D2E8 THIS LOW YIELD BORE IS TO BE USED FOR TANK FILLING, BORE IS LOCATED ON EDGE OF VALLEY IN AN ELEVATED AREA.

NEIGHBOURING BORE ON OPPOSITE SIDE OF NARROW GULLY DID PRODUCE A BETTER YIELD WHEN DRILLED APPROX 10 YEARS

AGO.

E9E10 120397E11 124861 THIS VERY LOW YIELD BORE TO BE EQUIPED WITH SUB PUMP. PROBES TO ALLOW INTERMITTENT PUMPING FOR TANK FILLING -

NO OTHER OPTIONS AVAILABLE ON SITE.

D3E12 133595 RECOMMENDED PUMPING RATE 0.25 LPS, INTERMITTENT PUMPING. NOTE: BORE LOCATED IN NARROW VALLEY AT BASE OF

HIGH HILLS. ONLY VIABLE DRILL SITE.

D4 79690D5 79407E13 BORE LOCATED ON FLAT SLIGHTLY SLOPING (DOWNHILL) ALLUVIAL VALLEY BETWEEN GRANITE HILLS & EXTENDING A

CONSIDERABLE DISTANCE, SIMILAR VALLEYS IN AREA ARE QUITE PRODUCTIVE. AS HARD GRANITE IN AREA RARELY

PRODUCES USEFUL WATER DRILLING WAS TERMINATED @ 9m.

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Drilling Contractor's Remarks Table

G3 RECOMMENDED PUMPING RATE 0.193 FOR TANK FILLING (150 - 160 GALL/HR).

D6 120676E14E15 BORE HAS AN UNACCEPTABLE SALT CONTANT BUT OWNER INTENDS MIXING WITH DAM WATER TO DILUTE. NOTE: . . .

D7 79000E16 133670 BORE LOCATED CLOSE TO FRINGE OF GRANITES. PREVIOUS DRILLING IN AREA HAS ENCOUNTERED WATER IN SCHIST-TYPE

OF ROCK @ SHALLOW DEPTHS IN DECOMPOSED OR FRACTURED ROCK. NOTE: SURFACE CASING SEALED & GROUTED TO

ALLOW ANY FUTURE OF DEEPENING OF BORE.

G4G5C1C2 120451C3 120455C4 BORE ABANDONED. TOTAL DEPTH 25m.

C5 NIL WATER, BORE ABANDONED. TEST BORE NO.2 DRILLED APPROX 150m FROM NO.1 ON A HIGHER PORTION OF PROPERTY.

GENERALLY DRILLING INTO HARD GRANITE IN THIS AREA RARELY PRODUCES WATER.

C6C7C8C9C10C11C12 120224 BORE DRILLED IN GULLY AT BASE OF STEEP HILL. RECOMMENDED PUMPING RATE 0.25 LPS.

C13 120459C14 134256 RECOMMENDED PUMPING RATE 0.31LPS. NOTE: BORE IS LOCATED IN SHALLOW ALLUVIAL VALLEY. LIMITED CEMENTING DEPTH

DUE TO VERY SHALLOW ALLUVIAL AQUIFER.

C15 133791 RECOMMENDED PUMPING RATE @ 0.25 LPS, INTERMITTENT PUMPING WITH PROBES & LLP.

C16 DRILLING CARRIED OUT IN SMALL ALLUVIAL FLAT APPROX. 50m WIDE.

C17C18 124664 THIS PARTICULAR PART OF WIGHTS MT HAS A PROVEN HISTORY OF SALTY WATER. OWNER WAS PREPARED TO DILUTE BY

PUMPING TO HIS DAM. WATER USED FOR GARDEN PURPOSES. OWNER DECIDED TO SUPPLY SUITABLE CASING & CASE BORE

FOR FUTURE DEEPENING IF EVER DECIDED.

C19C20C21

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CRICOS No. 00213J

Other Bores in Samford Valley Table

BORE LATITUDE LONGITUDE FIELD LOCATION

1 27'24',39" S 152"5 14" E North side of BETTS ROAD, CAMP MOUNTAINa 27'24',41" S 152"5'21 " E South side of BETTS ROAD, CAMP MOUNTAIN3 27"24',39" S 152"5'26" E North side of BETTS ROAD. CAMP MOUNTAIN4 27"24'46" S 152"5'42" E South side of BETTS ROAD, CAMP MOUNTAIN5 27"24'47" S 152"5'46" E South side of BETTS ROAD. CAMP MOUNTAIN

6 27"24'38" S 152"5'53" E West side of BETTS ROAD. CAMP MOUNTAIN7 27"24'37" S 152'5 '57" E West side of BETTS ROAD (Near Mitchell Park). CAMP MOUNTAIN

27"23'46" 5 152"5 '58" E 9? DAVISON ROAD (Behind 7 Richards Road). CAMP MOUNTAIi\

9 27"24',17" S 152"5'54" E 86 DOMROW ROAD, CAMP MOUNTAIN

0 27"24',21" S 152"5'5 '1" E North side of DOMROW ROAD on corner of UPPER CAMP MOUNTAIN ROAD, CAMP MOUNTAINI 27"24'24" S 152"5'53" E South side of corner of UPPER CAMP MOUNTAIN ROAD & DOMROW ROAD. CAMP MOUNTAIN2 27"24'24" S 152"5 48" E UPPER CAMP MOUNTAIN ROAD (Opp DOMROW ROAD), CAMP MOUNTAIN

27"24'19" S 152"5'47" E UPPER CAMP MOUNTAIN ROAD (Near DOMROW ROAD). CAMP MOUNTAIN4 27'24'18" S 152"5 46" E UPPER CAMP MOUNTAIN ROAD (Near DOMROW ROAD), CAMP MOUNTAIN

27'24'12" S 152"5 '43" E South side of UPPER CAMP MOUNTAIN ROAD. CAMP MOUNTAIh27"24"t1" S 152"5 46" E South side of bend in UPPER CAMP MOUNTAIN ROAD, CAMP MOUNTAIN

7 27"24',09" S 152"5 41" E North side of bend in UPPER CAMP MOUNTAIN ROAD, CAMP MOUNTAIN

8 27"24'42" S 152"5'52" E North side of bend in UPPER CAMP MOUNTAIN ROAD, CAMP MOUNTAIN

I 27"23',59" S 152"5'58', E North side of bend in UPPER CAMP MOUNTAIN ROAD, CAMP MOUNTAIi\20 27'23',27" S 152"52',48" E South side of UPPER CAMP MOUNTAIN ROAD (Near QUT Farm), CAMP MOUNTAIN21 27'23'41" S 152"52'23" E LES-DOUGLAS COURT "Auchen Eden" (Yellow Post 108), CAMP MOUNTAII22 27"23'47" S 152"52',10" E RICHARDS ROAD (NE corner of UPPER CAMP MOUNTAIN ROAD). CAMP MOUNTAIA23 27'23'55" S 152"52'02" E 172 UPPER CAMP MOUNTAIN ROAD "Greenvale", CAMP MOUNTAIT\

24 27'23'56" S 152"52',01" E UPPER CAMP MOUNTAIN ROAD (Yellow Post 178), CAMP MOUNTAIh

25 27'23'13" S 152'53'09" E McCOMBE ROAD, CAMP MOUNTAIT\zo 27"23'48" 5 152"53'32" E McLEAN ROAD SOUTH, CAMP MOUNTAIT\

1 2 7 27'22'55" S 152'53'28" E End of PETERSON ROAD, CAMP MOUNTAIil28 27"22'.51" S 152'53 '31" E Between PETERSON ROAD & SAMFORD ROAD, CAMP MOUNTAIN29 27"23'58" S 152"53',14" E 4 VONNE COURT, CAMP MOUNTAII\?n 27"23'55" S 152"53',17" E 3 VONNE COURT, CAMP MOUNTAII\

1 3 1 27'24',04" S 152"53'.17" E 9 VONNE COURT, CAMP MOUNTAII\

2 1 27'21'09" S 152'53',02" E Next to (North ofl South Pine River & Near Yuqar Park, DRAPEF3 1 27"22'.49" S 152"48',29" E DAWSON CREEK ROAD, HIGHVALE

R 2 27'23'00" S 152"48'16" E West side of DAWSON CREEK ROAD, HIGHVALE

R 3 27"23'05" S 152"48',24" E West side of DAWSON CREEK ROAD, HIGHVALE

3 4 27"23',01" S 152'48'26" E East side of DAWSON CREEK ROAD, HIGHVALE

3 5 27'23',17" S 152"48',13" E South side of DAWSON CREEK ROAD, HIGHVALE

J O 27"23',16" S 152"48'09" E South side of DAWSON CREEK ROAD, HIGHVALE

i 7 27"23',02" S 152"48'30" E 61 DAWSON CREEK ROAD, HIGHVALE

3 7 27"23',17" S 152'47'37" E 242 DAWSON CREEK ROAD, HIGHVALE

3 B 27'22'53" S 152"47'53" E GOAT TRACK, HIGHVALE

J J 27"22',40" S 'r s2'48'09" E Cnr GOAT TRACK & MOUNT GLORIOUS ROAD. HIGHVALE

3 27'21',45" S 152"49',32" E North of HOUSEWOOD COURT. HIGHVALE

1 27"21'47" S 152"49'28" E NOrth Of HOUSEWOOD COURT. HIGHVALE4 2 27"23'08" S 152'49'33" E HULCOMBE ROAD, HIGHVALE3 27"23'31" S 152'49'25" E HULCOMBE ROAD (Oop PACKER LANE). HIGHVALE

4 27"2339'" S 152'49'41" E East side of southern end of HULCOMBE ROAD. HIGHVALE' l 5 27"23'29" S 152"49',54" E Southern end of HULCOMBE ROAD, HIGHVALE

B 27"23'.12" S 152"49',26" E KAREELA DRIVE (Near Cnr HULCOMBE ROAD), HIGHVALE

7 27"23',00" S 152"49'44" E 3 MESSMATE COURT. HIGHVALE

B 8 27"23',01" S 152"49',44" E 5 MESSMATE COURT, HIGHVALE

J 9 27'22',37" S 152'48'09" E MOUNT GLORIOUS ROAD (Ooo GOAT TRACK), HIGHVALE320 27"22',39" S 152"48'39" E MOUNT GLORIOUS ROAD, HIGHVALE

321 27"22',34" S 152"48'09" E East side of bend in MOUNT GLORIOUS ROAD, HIGHVALE

3 2 2 27"22',43" S 152'48',12" E Near bend. south side of MOUNT GLORIOUS ROAD, HIGHVALE

5 t J 27'22'40" S 't52"48'24" E North side of bend in MOUNT GLORIOUS ROAD. HIGHVALE

3 2 4 27"22'39" 5 152"48',32" E North side of bend in MOUNT GLORIOUS ROAD, HIGHVALE

s t J 27"22'24" S 152"48'05" E West side of bend in MOUNT GLORIOUS ROAD, HIGHVALE

326 27'23'35" S 152"49',22" E PACKER LANE, HIGHVALE

3 2 7 27"21'49" S 152"50'03" E REINERS ROAD, HIGHVALE

27"22'14" S 152'48'57" E Next to huqe dam to the west of the SHOWGROUNDS, HIGHVALE

: Z J 27'22'36" S 152"49'35" E Either 10 NORWOOD COURT or house behind i t in 5 SHOWGROUNDS DRIVE, HIGHVALE

: 3 0 27'23',20" S 152"49',14" E Cnr SMALLS ROAD & RYDER ROAD, HIGHVALE

2 3 1 27"23'22" S 152"49',14" E SMALLS ROAD (Opp CHAROLAIS PLACE), HIGHVALE

: J Z 27'2328 5 152"49 '15" E East side of SMALLS ROAD, HIGHVALE

Bronwyn Jones Page 133

CRICOS No. 00213J

Other Bores in Samford Valley Table

13 33 27"23'.28" S 152"49',11" E West side of SMALLS ROAD, HIGHVALE)4 1 27"21'38" 5 152'54'03" E BURTON LANE. SAMFORD VALLE\) 4 2 27"21',42" S 152'54'00" E BURTON LANE, SAMFORD VALLEI) 4 3 27"22',03" S 152'53',34" E CORELLA AVENUE (Opp SERENDIPITY DRIVE), SAMFORD VALLEY) 4 4 27'21'51" S 152"52'01" E End of MAMGANI COURT (Either 31 or 33), SAMFORD VALLE\) 4 5 27"22'27" S 1 52'50'53" E South of MOUNT GLORIOUS ROAD (Between Reqoli Ct & Parkwood Dr), SAMFORD VALLE\1 4 6 27'22',28" S '1 52"50'52" E South of MOUNT GLORIOUS ROAD (Between Reqoli Ct & Parkwood Dr). SAMFORD VALLEY) 4 7 27'22'22" S 152"52',02" E South side of MOUNT GLORIOUS ROAD (Opp 22OMT GLORIOUS ROAD), SAMFORD VALLE\) 4 8 27"21',30" S 152'49'56" E Cnr MAYFIELD & MOUNT O'REILLY ROAD "Jualbren". SAMFORD VALLE\) 4 9 27"23'26" 5 152'51'54" E RICHARDS ROAD (Yellow Post 24?) Opp PONY CLUB & SOCCER CLUB, SAMFORD VALLEY1 4 1 0 27"22',04" S 1 5 2 " 5 1 ' 4 9 " E RIVERINE COURT, SAMFORD VALLE\) 4 1 1 27"22'03" S 152"54'03" E SYLVATERRE COURT, SAMFORD VALLEY)4 12 27"22',44" S 152 ' '5210 'E WIGHTS MOUNTAIN ROAD (Between Furlonqer Road & Sheppard Street), SAMFORD VALLE\) 4 1 3 27"22',4s" S 152"52'.16" E WIGHTS MOUNTAIN ROAD (Between Furlonger Road & Sheppard Street), SAMFORD VALLE\)5 1 27"23',42" S 152'50'05" E 3 JANLEY COURT, WIGHTS MOUNTAIN) 5 2 27"24',00" S 152'50',39" E Bend in OATLANDS ROAD (Near No.68), WIGHTS MOUNTAIN

27'23'55" S 152"50 '39" E Bend in OATLANDS ROAD (Near No.68 & Further up driveway), WIGHTS MOUNTAIN) 5 4 27"23',37" S 152'50'20" E Bend in SMITHS ROAD (Near RIVE COURT). WIGHTS MOUNTAIh1 5 5 27"23',55" 5 152'51'22" E West side of UPPER WIGHTS MOUNTAIN ROAD, WIGHTS MOUNTAIN) 5 6 27'23',48" 5 1 5 2 " 5 1 ' 1 3 " E East side of corner of UPPER WIGHTS MOUNTAIN ROAD. WIGHTS MOUNTAIil

3ronwyn Jones Page 134

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Bronwyn Jones

APPENDIX 3

Groundwater Analytical Procedures

CRICOS No. 00213J

Bronwyn Jones

Analysis of ALKALINITY (BICARBONATES) in the ground water samples by:

ACID TITRATION

The alkalinity of a sample is due to the presence of hydroxide, carbonate or

bicarbonate ions. No carbonate or hydroxide alkalinity is recorded for this study since

phenolphthalein alkalinity equals zero (i.e. pH <8.3).

Detection limit

0.25 ppm CaCO3 (mg/L)

Apparatus

• 250 mL conical flasks or beakers

• Calibrated pH meter

• 50 mL pipette and burette

• Spin bar magnet and magnetic stirrer plate

• Reagent: 0.01N Standard HCl (or 0.1N HCl if pH>8.3)

Procedure

1) Pipette 100mL of groundwater sample into a 250 mL beaker. Measure the pH of the

sample. If pH is less than 8.3 then titrate the sample with 0.01N HCl to pH 4.7 (If pH

is >8.3 use 0.1N HCl). All the while, use a magnetic stirrer and leave pH probe in

sample while titrating. Record total volume of HCl used/titrated.

2) Then, continue to titrate the solution further to reduce the pH exactly 0.30 pH units to

pH 4.3 and record the final volume.

NOTE: As the end point is approached make smaller additions of acid and be sure that pH

equilibrium is reached before adding more titrant.

Calculation of Bicarbonate Alkalinity as CaCO 3

T mg/L CaCO 3 = (2B – C) ×××× N ×××× 50 000 / volume of sample

where B = mL of titrant to first recorded pH (e.g. 56 mL HCl to pH 4.7)

C = total mL of titrant to reach pH 0.3 unit lower (e.g. 58.5mL HCl to pH 4.4)

N = normality of acid (e.g. 0.01N HCl)

E.g. (2 × 56 – 58.5) × 0.01 × 50 000 / 100 mL

= (112 – 58.5) × 5

= 267.5 mg/L CaCO3

To convert bicarbonate expressed as alkalinity to concentration of own species to be used in

a mass balance (only if pH >8.3) multiply by the following factor:

Bicarbonate in mg/L HCO 3– = ………mg/L CaCO 3 x 1.22

CRICOS No. 00213J

Bronwyn Jones

Analysis of CATIONS in the groundwater samples by:

INDUCTIVELY COUPLED PLASMA – OPTICAL EMISSION SPECT ROSCOPY (ICP-OES)

Cations commonly analysed in water samples by ICP – OES are:

• Major Cations: Na, K, Mg, Ca

• Minor Cations: Al, Sr, Mn, Fe, Zn, Cu

Detection Limits

Theory of Operation

The cation and sulphur concentrations are measured using inductively coupled

plasma – optical emission spectroscopy (ICP-OES). This technique involves the water

sample being aspirated into plasma. The intensity of characteristic wavelengths emitted by

the excited analyte ions in the plasma are measured by a spectrophotometer. The measured

intensity is proportional to concentration, thus concentration of ions in the sample can be

determined.

Sample Preparation

Little sample preparation is required for analysis of aqueous samples by ICP-OES,

except for filtering samples through a 0.45 µm membrane filter, with the filtrate collected

(then diluted if necessary) and analysed. Samples of high electrical conductivity (EC) are

diluted to <4000 µS/cm before analysis. The determined concentrations of elements must

also be within the detection limits of the ICP-OES for the results to have analytical meaning.

It is possible for cations other than those listed above to be analysed, e.g. Si (that has a

detection limit of 0.011 – 75 mg/L), however it may not be feasible if the selected analyte ions

are present only in trace amounts, i.e. at levels below the limits of ICP-OS detection.

Appropriate standards and blanks are used to calibrate the machine during use.

CRICOS No. 00213J

Bronwyn Jones

Results

All data should be within the detection limits set out above. Any results out of this

range should be recorded as being out of detection limits. Data out of detection limits has no

real meaning, inclusion this data in a report or thesis is completely inaccurate.

Below is an example of an ICP-OES results print-out:

CRICOS No. 00213J

Bronwyn Jones

Analysis of ANIONS in the groundwater samples by:

ION CHROMATOGRAPHY (IC)

Anions commonly analysed in groundwater samples by IC are:

• Cl–, NO3–, SO4

2–, F–, Br–, PO43–

• NO2– and SO3

2– can also be analysed but are not included in the routine analysis

Detection Limits

A working range has been given below. This range is based on a combination of

standard concentration range and instrument working range.

Theory of operation

The Ion Chromatographic Process:

Ion chromatography is a useful technique for the measurement of various ionic

species in solution. It is based on the principles of chromatographic separation, and

detection methods, the most common being conductivity suppression.

The sample is introduced in the flowing stream and carried into the anion exchange

column. Ions interact with the ion exchange sites on the stationary phase in the column.

Mobile phase ions (or eluent ions) compete with the sample ions for ion exchange sites on

the column. Separation depends upon the different ions having different affinities for both

phases. In the case of anion separations, the differing affinities for stationary and mobile

phases are due to the ionic charge and ion size (ionic radius) of each anion species. Once

anions are separated the concentration of each species present in the sample is measured

using a conductivity detector. Each anionic species is identifies by its retention time which

remains constant throughout successive runs. A chromatogram displays peaks in

conductivity at various retention times.

A suppressor column is used in many ion chromatographs in ion detection. Here the

ion suppressors neutralise the mobile phase, reducing its conductivity, while simultaneously

increasing the sample’s conductivity. This combination offers the quietest baselines and

highest sensitivity.

CRICOS No. 00213J

Bronwyn Jones

Stationary Phase: The column packing material containing functionalised active sites.

Mobile Phase (or Eluent): The liquid flowing through the column that contains competing

ions for the active sites.

Apparatus

• DIONEX Bio LC Ion Chromatograph

• Anions analysed using Ion Pac AS9 HC analytical column with an Ion Pac AG9 HC

guard column. Both these columns are filled with polymer anion exchange resin.

• Anion Self-Regenerating Suppressor (ASRS-ULTRA II) 4mm is used in the “Auto

Suppression Recycle Mode”. In this mode of operation, eluent flows from the eluent

outlet of the suppressor into the conductivity cell and is then recycled through the ASRS-

ULTRA regenerant chambers. This eliminates the need for an external source of water

but restricts the regenerant flow rate to the eluent flow rate.

• Eluent: 9mM NaHCO3. The flow rate of the eluent is 1.2mL/min. typical background

pump pressure is 2250psi

• Regenerate Solution

Software

Data acquisition and control of the instrument is achieved using the PEAKNET

software package.

Sample Preparation

Little or no sample preparation is required for analysis of aqueous groundwater

samples by ion chromatography. However, highly turbid samples must be filtered before

analysis (most groundwater samples are not highly turbid) and samples of high conductivity

require diluting before analysis. Samples analysed must have a conductivity of less than 700

µS/cm, if not diluting is required. Samples can be filtered through a 0.45µm membrane filter,

with the filtrate collected and analysed, or diluted if necessary. These anion samples are not

acidified.

Sample Analysis

All samples and standards are transferred into the small clean IC vials. Samples are

injected into the column using an autosampler. This automates injection of multiple samples

to the column using a schedule prepared by the user from PEAKNET software package.

A single sample (each vial) will take about 20 minutes to run through the column.

CRICOS No. 00213J

Bronwyn Jones

Results

Ion chromatography is an excellent method of anion species determination in

groundwater samples. It has an extremely good precision with a %RSD of <2%. However, it

is important that results obtained are not taken on face value but are checked to assure data

is reasonable. This is particularly important as peaks can be misnamed due to small shifts in

retention time. The retention can change due to a variety of reasons, most commonly due to

problems with the eluent pump, blockages and inaccurate preparation of eluent. Always

check with the previous days’ data to determine if retention times have not changed (refer to

daily log, located next to instrument for this information). Data should also be within the

working range of each species listed above, if not then dilution may be required before

rerunning samples or an alternative method of analysis may be required. In particular, high

chloride data should be checked by titration as concentrations over 150 – 200ppm may not

be linear, giving inaccurate results.

Reference

DIONEX CORPORATION. 2001. Dionex Manuals and Literature CD, Revision 12. Dionex

Corporation, USA

Below is an example of an IC chromatogram print-out:

CRICOS No. 00213J

Sample Analysis Report

Data File Narne : C:\PEAKNET\DATA\BRONWYN\2007 06 05 BRONW\N_B0Ot.DXDMethod File Name : C:\Pealaret\METHOD ACI\as9-hc mar 06.metDate Tinre Collected . 6106107 4'.01'.29 PMSt'stem Ouerator :

Peah # Component Name

Peali Infomtation

Retention Time

Forurd Components

Concentration

Sample Name : 32

I2aJ

AT

5

5 0 0

@ 40.0f,

1 0 . 0

0

FluorideChlorideBromideNitrateSulfate

3 . 1 35 .02/ . o L

8 6 816 .47

0 . l 6I 00.07

0 3 93 8 2

1 4 . l 9

24443261396402222

149 I 89619452206

119669364

80.01

+I

70.0+II

60.01

2 - Chloride

I

c n n

20.0

PerkNel 5.01

8.00 10.00 12.00 14.00 16.00 18.00Minutes

Current Date : 6,/0Current Tine : 16:3

Bronwyn Jones

P r o e I n f l

Page I42

CRICOS No. 00213J

Bronwyn Jones

APPENDIX 4

Samford Valley Maps

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Bronwyn Jones

Topographic map of Samford Valley (metres above sea level)

0 3km

SCALE

CONTOUR INTERVAL 5 metres

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Bronwyn Jones

Mapped location of groundwater bores in Samford Valley

See also Appendix 2 Registration Table

0 3km

SCALE

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Bronwyn Jones

Electrical conductivity of groundwater, Samford Valley

0 3km

CONTOUR INTERVAL 250 microSiemens

SCALE

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Bronwyn Jones

Generalised distribution of shallow permeability, Samford Valley

0 3 km

CONTOUR INTERVAL 0.25 L/sec

SCALE

CRICOS No. 00213J

Bronwyn Jones

(b)

Photographs looking northeast across Samford Valley from Jolly’s Lookout. (a) The valley in 2007 and (b) in 1966 (Van Genderen, 1966).

(a)

2007

1966

CRICOS No. 00213J


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