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OSHA Requires
That if there are chemicals at your work site…
You must be trained in Hazard Communications
Hazard Communication, Labeling, and the MSDS
OSHA Requires
• That when you use a chemical, the MSDS be readily available– Good rule of thumb:
• Within 50 feet indoors• Within 100 feet outdoors
– The custodial department has more MSDS’s than any other department
– Custodial has one book on each floor in each building
OSHA
Hazard Communication Training• Basic Orientation Level• Area-Specific Training• Job-Specific Training
OSHA Standards
CFR 29, Parts 1900-1910• Hazard Communication• Universal Precaution (HIV/Hep B)• Injury and Illness• Emergency Procedures• Hearing Conservation
OSHA Standards
CFR 29, Parts 1900-1910• Respirator• Industrial Truck (Fork Lift)• Confined Space• Fire Extinguisher• Lock Out Protection
OSHA Standards
CFR 29, Parts 1900-1910• Crane• Radiation Safety• There are also rules on:
– Asbestos, Indoor Air Quality (IAQ), Lead, Mercury, and Personal Protective Equipment (PPE)
Government Regulatory Acts
The College is responsible for compliance with many government regulations.
EPA
Environmental Protection Agency• Clean Air• Clean Water• TOSCA• RCRA (Hazardous Waste)• CERCLA (Superfund)• SARA (Title III)• EPCRA (Right to Know)• Endangered Species
EPA
Definition of Hazardous Waste• …any garbage, refuse, sludge from a waste treatment plant, or air
pollution control facility and other discarded material, including solid, liquid, semi-solid, or contained gaseous material resulting from industrial, commercial, mining, and agricultural operations, and from community activities…– Ignitable– Corrosive– Reactive– Toxic
OSHA
Definition of Hazardous Substance
“…a substance or material that presents a physical or health hazard.”
OSHA
Physical Hazards
Bodily harm can result from the physical properties of the substance.
OSHA
Physical Hazards• Compressed gases• Flammable materials• Explosives• Corrosives• Reactives
OSHA
Health Hazards
Exposure can adversely affect an individual’s health.
OSHA
Health Hazards• Irritation• Sensitization• Organ damage• Cancer
OSHA
Toxic Effects of Materials• Acute• Chronic
OSHA
Toxic Effects of Materials• Acute
– Sudden exposure– High concentration of toxic material– Rapid reaction with body tissue
OSHA
Toxic Effects of Materials• Chronic
– Repeated exposure to small concentrations– No immediate reaction to exposure– Effects appear long after exposure
OSHA
Routes of Entry
The four ways toxic materials can enter the body
OSHA
Routes of Entry• Inhalation• Most common route of entry
– Rapidly absorbed in lungs and passed to bloodstream
– Vapors and gases– Particulates– Aerosols and gases
OSHA
Routes of Entry• Absorption through the skin
• Reaction with surface skin• Skin penetrated—sensitization• Multiple skin layers penetrated and toxin enters
bloodstream and causes systemic poisoning
OSHA
Routes of Entry• Ingestion
– Usually not intentional• Keep food away from chemicals• Wash hands before eating, drinking, or smoking
OSHA
Routes of Entry• Injection
– Materials enter through broken skin• Cuts• Sores• Burns• Scratches
OSHA Requires
M aterialS afetyD ataS heet
Training
MATERIAL MSDS No. 259SAFETY Revision No. 006DATA Date: 01/31/98SHEET Page 1 of 2
SECTION I: GENERAL INFORMATION
HILTI, INC.: P.O. Box 21148, Tulsa, OK 74121; Ph: 1 800 879 6000; EmergencyNo.: 1 800-879444
PRODUCT: FS-ONE High Performance Intumescent Firestop Sealant
DESCRIPTION: One-part acrylic-based sealant
For: SALT LAKE COMM COLLEGE/+ P.O. No. P.O. BOX 30808 SALT LAKE CITY, UT 84130-0808
SECTION II: HAZARDOUS INGREDIENTS
INGREDIENTS AND EXPOSURE LIMITS
INGREDIENTS: CAS NUMBER: PEL: TLV: STEL:Vinyl acetate 000108-05-4 NE NE NEAmmonium polyphosphate 007722-76-1 NE NE NEExpandable graphite 012689-13-3 NA NA NAPolyisobutylene 009003-29-6 NE NE NE
PEL = OSHA Permissible Exposure Limit. TVL = ACGIH Threshold Limit Value. These are 8 hour time-weighted averages unless otherwise indicated “C” (Ceiling) or“STEL” (Short Term Exposure Limit). NA = Not Applicable. NE = None Established. ND = Not Determined.
SECTION III: PHYSICAL DATA
APPEARANCE AND ODOR: Red paste. Odorless pH: Not DeterminedBOILING POINT: Approx. 100o C/ 212o F MELTING POINT: Not DetVOC CONTENT: None VAPOR PRESSURE: Not DetEVAPORATION RATE: Not Determined VAPOR DENSITY: 1.5SOLUBILITY IN WATER: Slightly soluble SPECIFIC GRAVITY: Not Det
SECTION IV: FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: Non-Flammable FLAMMABLE LIMITS: Not ApplicableEXTINGUISHING MEDIA: Not applicable. Use extinguishing agent suitable for typeof surrounding fire.SPECIAL FIRE FIGHTING PROCEDURES: A self-contained breathing apparatus
should be worn when fighting fires involving chemicals.UNUSUAL FIRE AND EXPLOSION HAZARDS: None Known
SECTION V: HEALTH HAZARD DATA
KNOW HAZARDS: None Known. CARCINOGENICITY: No ingredients are considered by IARC, NTP, or OSHA PRIMARY ROUTES OF EXPOSURE: DermalSIGNS AND SYMPTOMS OF EXPOSURE: None expectedMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions
EMERGENCY AND FIRST AID PROCEDURESEYES: Immediately flush with plenty of water while holding eyelids apart. .SKIN: Wipe off material and wash with soap and water. INHALATION: Move victim to fresh air if discomfort develops. INGESTION: Give plenty of water to drink. OTHER: Referral to a physician is recommended
CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENTVENTILATION: General (natural or mechanically induced fresh air movements).EYE PROTECTION: Safety glasses or goggles are recommended SKIN PROTECTION: Gloves are recommended (cotton are sufficient).RESPIRATORY PROTECTION: None normally required.
PRECAUTIONS FOR SAFE HANDLING AND USEHANDLING AND STORING PRECAUTIONS: Avoid contact with the skin. SPILL PROCEDURES: Allow to cure.
SECTION VI: TOXICITY INFORMATION
REGULATORY INFORMATIONHAZARD COMMUNICATION: This MSDS has been prepared in accordance with the
federal OSHA Hazard Communication Standard.HMIS CODES: Health 1, Flammability 0, Reactivity0, PPE BDOT SHIPPING INFO: Non-regulatedTSCA INVENTORY STATUS: Chemical components listed on TSCA inventory.SARA TITLE III, SECTION 313: This product contains 1-4% ethylene glycol (CAS 107-
21-1) which is subject to reporting under Section 313 of SARA Title III (40 CFR Part372).
WASTE DISPOSAL METHODS: Consult with regulatory agencies or corporate personnelfor disposal methods that comply with local, state, and federal health andenvironmental regulations.
HEALTH/SAFETY CONTACTS: Steve Gerrard (x6309), Jerry Metcalf (x6704)
SECTION VII: REACTIVITY DATA
STABILITY: StableHAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can yield
carbon dioxide an/or carbon monoxide.INCOMPATIBILITY: Strong acids, peroxides and other oxidizing agentsHAZARDOUS POLYMERIZATION: Will not occurCONDITIONS TO AVOID: None Known
MATERIAL MSDS No. 259SAFETY Revision No. 006DATA Date: 01/31/98SHEET Page 1 of 2
SECTION I: GENERAL INFORMATION
HILTI, INC.: P.O. Box 21148, Tulsa, OK 74121; Ph: 1 800 879 6000;Emergency No.: 1 800-879444
PRODUCT: FS-ONE High Performance Intumescent Firestop Sealant
DESCRIPTION: One-part acrylic-based sealant
For: SALT LAKE COMM COLLEGE/+ P.O. No.P.O. BOX 30808SALT LAKE CITY, UT 84130-0808
Date of Issue
MATERIAL MSDS No. 259SAFETY Revision No. 006DATA Date: 01/31/98SHEET Page 1 of 2
SECTION I: GENERAL INFORMATION
HILTI, INC.: P.O. Box 21148, Tulsa, OK 74121; Ph: 1 800 879 6000;Emergency No.: 1 800-879444
PRODUCT: FS-ONE High Performance Intumescent Firestop Sealant
DESCRIPTION: One-part acrylic-based sealant
For: SALT LAKE COMM COLLEGE/+ P.O. No.P.O. BOX 30808SALT LAKE CITY, UT 84130-0808
Emergency Telephone #
MATERIAL MSDS No. 259SAFETY Revision No. 006DATA Date: 01/31/98SHEET Page 1 of 2
SECTION I: GENERAL INFORMATION
HILTI, INC.: P.O. Box 21148, Tulsa, OK 74121; Ph: 1 800 879 6000;Emergency No.: 1 800-879444
PRODUCT: FS-ONE High Performance Intumescent Firestop Sealant
DESCRIPTION: One-part acrylic-based sealant
For: SALT LAKE COMM COLLEGE/+ P.O. No.P.O. BOX 30808SALT LAKE CITY, UT 84130-0808
SECTION II: HAZARDOUS INGREDIENTS
INGREDIENTS AND EXPOSURE LIMITS
INGREDIENTS: CAS NUMBER: PEL: TLV: STEL:
Vinyl acetate 000108-05-4 NE NE NEAmmonium polyphosphate 007722-76-1 NE NE NEExpandable graphite 012689-13-3 NA NA NAPolyisobutylene 009003-29-6 NE NE NE
PEL = OSHA Permissible Exposure Limit. TVL = ACGIH Threshold LimitValue. These are 8 hour time-weighted averages unless otherwiseindicated “C” (Ceiling) or “STEL” (Short Term Exposure Limit). NA = NotApplicable. NE = None Established. ND = Not Determined.
SECTION III: PHYSICAL DATA
APPEARANCE AND ODOR: Red paste. OdorlessBOILING POINT: Approx. 100o C/ 212o FVOC CONTENT: NoneEVAPORATION RATE: Not DeterminedSOLUBILITY IN WATER: Slightly soluble (prior to curing) pH: Not DeterminedMELTING POINT: Not DeterminedVAPOR PRESSURE: Not DeterminedVAPOR DENSITY: 1.5SPECIFIC GRAVITY: Not Determined
VaporDensity
Air = 1.0
SECTION IV: FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: Non-Flammable
FLAMMABLE LIMITS: Not Applicable
EXTINGUISHING MEDIA: Not applicable. Use extinguishing agentsuitable for type of surrounding fire.
SPECIAL FIRE FIGHTING PROCEDURES: A self-contained breathingapparatus should be worn when fighting fires involving chemicals.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None Known
NFPA HAZARD RATING 3 <--Health 1 <--Flammability 0 <--Reactivity <--Special
SECTION VI: TOXICITY INFORMATION
REGULATORY INFORMATION
HAZARD COMMUNICATION: This MSDS has been prepared in accordance withthe federal OSHA Hazard Communication Standard.
HMIS CODES: Health 1, Flammability 0, Reactivity0, PPE B
DOT SHIPPING INFO: Non-regulated
TSCA INVENTORY STATUS: Chemical components listed on TSCA inventory.
SARA TITLE III, SECTION 313: This product contains 1-4% ethylene glycol (CAS107-21-1) which is subject to reporting under Section 313 of SARA Title III (40CFR Part 372).
WASTE DISPOSAL METHODS: Consult with regulatory agencies or corporatepersonnel for disposal methods that comply with local, state, and federal healthand environmental regulations.
HEALTH/SAFETY CONTACTS:Steve Gerrard (x6309), Jerry Metcalf (x6704)
The National Fire Protection Association has a hazardous materials labeling model.
HEALTH HAZARD4–Deadly3–Extreme Danger2–Hazardous1–Slightly Hazardous0–Normal Material
FIRE HAZARDFlash Points4–Below 73o F3–Below 100o F2–Below 200o F1–Above 200o F0–Will not burn
Hazardous MaterialsClassifications
HEALTH HAZARD4–Deadly3–Extreme Danger2–Hazardous1–Slightly Hazardous0–Normal Material
FIRE HAZARDFlash Points4–Below 73o F3–Below 100o F2–Below 200o F1–Above 200o F0–Will not burn
HEALTH HAZARD4–Deadly3–Extreme Danger2–Hazardous1–Slightly Hazardous0–Normal Material
FIRE HAZARDFlash Points4–Below 73o F3–Below 100o F2–Below 200o F1–Above 200o F0–Will not burn
HEALTH HAZARD4–Deadly3–Extreme Danger2–Hazardous1–Slightly Hazardous0–Normal Material
FIRE HAZARDFlash Points4–Below 73o F3–Below 100o F2–Below 200o F1–Above 200o F0–Will not burn
REACTIVITY 4–May detonate 3–Shock and heat may detonate2–Violent chemical change1–Unstable if heated0–Stable
HEALTH HAZARD4–Deadly3–Extreme Danger2–Hazardous1–Slightly Hazardous0–Normal Material
FIRE HAZARDFlash Points4–Below 73o F3–Below 100o F2–Below 200o F1–Above 200o F0–Will not burn
REACTIVITY 4–May detonate 3–Shock and heat may detonate2–Violent chemical change1–Unstable if heated0–Stable
SPECIFICHAZARDOxidizer OXAcid ACIDAlkali ALKCorrosive CORUse NO WATER WRadiation Hazard
• For more information, contact:• Rand Webb
GFSB 126 OfficeMail Stop FCE-mail: [email protected] (office)801-856-6458 (cell)
THANK YOU!For your attention!