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45.2.1
* SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Trade name: VpCI®-396· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Coating
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
Cortec Corporation
4119 White Bear Parkway
St. Paul, MN 55110 USA
Phone (651) 429-1100
Fax (651) 429-1122
· Information department: [email protected]
· 1.4 Emergency telephone number:Spill, Leak, Fire, Exposure, or Accident24 hour CHEMTREC contact:USA and Canada 1-800-424-9300International +1-703-527-3887 (collect calls accepted)UK +(44)-870-8200418
* SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Carc. 2 H351 Suspected of causing cancer.
STOT RE 1 H372-H373 Causes damage to the respiratory system through prolonged or repeated exposure.
May cause damage to the central nervous system and the respiratory system throughprolonged or repeated exposure.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.(Contd. on page 2)
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45.2.1
· Hazard pictograms
GHS02 GHS07 GHS08
· Signal word Danger
· Hazard-determining components of labelling:Aromatic Polyisocyanate based on MDI
diphenylmethane-4,4'-di-isocyanante
diphenylmethane-2,4'-diisocyanate
aromatic polyisocyanate
p-toluenesulphonyl isocyanate
diphenylmethanediisocyanate,isomeres and homologuesdiphenylmethane-2,2'-diisocyanatemethylenediphenyl diisocyanate
· Hazard statementsH226 Flammable liquid and vapour.H332 Harmful if inhaled.H315 Causes skin irritation.H319 Causes serious eye irritation.H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.H317 May cause an allergic skin reaction.H351 Suspected of causing cancer.H335 May cause respiratory irritation.H372-H373 Causes damage to the respiratory system through prolonged or repeated exposure. May cause damage
to the central nervous system and the respiratory system through prolonged or repeated exposure.· Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P241 Use explosion-proof electrical/ventilating/lighting equipment.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/internationalregulations.
· Additional information:Contains isocyanates. May produce an allergic reaction.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
* SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Mixture of the substances listed below with nonhazardous additions.
(Contd. on page 3)
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45.2.1
· Ingredients:
CAS: 167883-19-4EC number: 642-370-1
Aromatic Polyisocyanate based on MDI
STOT RE 1, H372; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit.2, H319; Skin Sens. 1, H317; STOT SE 3, H335
10-25%
CAS: 7429-90-5
EINECS: 231-072-3
aluminium powder (stabilised)
Flam. Sol. 1, H228; Water-react. 2, H261
10-25%
CAS: 123-86-4
EINECS: 204-658-1
n-butyl acetate
Flam. Liq. 3, H226; STOT SE 3, H336
10-25%
CAS: 101-68-8
EINECS: 202-966-0
diphenylmethane-4,4'-di-isocyanante
Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4,H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE
3, H335
≥2.5-≤25%
CAS: 5873-54-1
EINECS: 227-534-9
diphenylmethane-2,4'-diisocyanate
Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4,H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE3, H335
2.5-10%
CAS: 67815-87-6EC number: 642-899-8
aromatic polyisocyanate
Resp. Sens. 1, H334; STOT RE 1, H372; Acute Tox. 4, H332; SkinIrrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
2.5-10%
CAS: 64742-95-6EINECS: 265-199-0
Solvent naphtha (petroleum), light arom. (Nota P, <0.1% benzene)
Flam. Liq. 3, H226; Asp. Tox. 1, H304; Acute Tox. 4, H332
>0-≤10%
CAS: 8052-41-3EINECS: 232-489-3
Stoddard solvent
Acute Tox. 3, H331; STOT RE 1, H372; Asp. Tox. 1, H304
>0-≤10%
CAS: 64742-88-7EINECS: 265-191-7
Solvent naphtha (petroleum), medium aliph.
STOT RE 1, H372; Asp. Tox. 1, H304; Acute Tox. 4, H332
≤2.5%
CAS: 57855-77-3EINECS: 260-991-2
Calcium Alkylnaphthalenesulfonate
Skin Irrit. 2, H315; Eye Irrit. 2, H319
≤2.5%
CAS: 4083-64-1EINECS: 223-810-8
p-toluenesulphonyl isocyanate
Resp. Sens. 1, H334; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE3, H335
≤2.5%
CAS: 9016-87-9EC number: 618-498-9
diphenylmethanediisocyanate,isomeres and homologues
Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4,H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE3, H335
≤2.5%
CAS: 2536-05-2EINECS: 219-799-4
diphenylmethane-2,2'-diisocyanate
Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4,H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE
3, H335
≤2.5%
CAS: 26447-40-5EINECS: 247-714-0
methylenediphenyl diisocyanate
Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4,H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE3, H335
≤2.5%
· Additional informationThe specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a tradesecret.The stoddard solvent (CAS 8052-41-3) contains <0.1% benzene, therefore the classification as a carcinogen/
mutagen does not apply.For the wording of the listed hazard phrases refer to section 16.
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45.2.1
* SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalationSupply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably on side position for transportation.
· After skin contactIf direct skin contact with isocyanates occurs, immediately remove contaminated clothing and shoes. Wipe
off the isocyanate product from the skin using dry towels or other similar absorbent fabric. If readily
available, apply a polyglycol-based cleanser or corn oil. Wash with soap and warm water and pat dry. If a
polyglycol-based cleanser is notavailable, wash with soap and warm water for 15 minutes. If available, use a wipe test pad to verifydecontamination is complete. Get medical attention if irritation develops. Discard orwash contaminated clothing before reuse.Immediately wash with water and soap and rinse thoroughly.If skin irritation continues, consult a doctor.
· After eye contactRinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowingIf swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
· 4.2 Most important symptoms and effects, both acute and delayedThe symptoms and effects are as expected from the hazards shown in section 2. No specific product relatedsymptoms are known.
· Information for doctor Show this safety data sheet to the doctor in attendance.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
* SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents
CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agentsWater.Water with full jet.
· 5.2 Special hazards arising from the substance or mixtureIn certain fire conditions, traces of other toxic gases cannot be excluded.
· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.
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45.2.1
* SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
· 6.2 Environmental precautions: Do not allow undiluted product to enter sewers/surface or ground water
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.Do not flush with water or aqueous cleansing agents
· 6.4 Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for disposal information.
* SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/exhaustion at the workplace.Open and handle receptacle with care.Prevent formation of aerosols.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect from heat.Protect against electrostatic charges.Keep respiratory protective device available.
Use explosion-proof apparatus / fittings and spark-proof tools.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage· Requirements to be met by storerooms and receptacles:
Use only receptacles specifically permitted for this substance/product.· Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidising agents.
· Further information about storage conditions:Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.
* SECTION 8: Exposure controls/personal protection
· Additional information about design of technical systems: No further data; see item 7.(Contd. on page 6)
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45.2.1
· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace:
7429-90-5 aluminium powder (stabilised) (10-25%)
WEL Long-term value: 10* 4** mg/m³
*inhalable dust **respirable dust
123-86-4 n-butyl acetate (10-25%)
WEL Short-term value: 966 mg/m³, 200 ppm
Long-term value: 724 mg/m³, 150 ppm
101-68-8 diphenylmethane-4,4'-di-isocyanante (10-25%)
WEL Short-term value: 0.07 mg/m³
Long-term value: 0.02 mg/m³
Sen; as -NCO
5873-54-1 diphenylmethane-2,4'-diisocyanate (2.5-10%)
WEL Short-term value: 0.07 mg/m³Long-term value: 0.02 mg/m³Sen; as -NCO
4083-64-1 p-toluenesulphonyl isocyanate (≤≤≤≤2.5%)
WEL Short-term value: 0.07 mg/m³Long-term value: 0.02 mg/m³Sen; as -NCO
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues (≤≤≤≤2.5%)
WEL Short-term value: 0.07 mg/m³Long-term value: 0.02 mg/m³Sen; as -NCO
2536-05-2 diphenylmethane-2,2'-diisocyanate (≤≤≤≤2.5%)
WEL Short-term value: 0.07 mg/m³Long-term value: 0.02 mg/m³Sen; as -NCO
· Additional information: The lists that were valid during the creation were used as basis.
· 8.2 Exposure controls Use local exhaust ventilation to control airborne concentrations below exposure limits.
· Personal protective equipment· General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.
Store protective clothing separately.Do not inhale gases / fumes / aerosols.Avoid contact with the eyes and skin.
· Breathing equipment:Suitable respiratory protective device recommended.Use respirators and components tested and approved under appropriate government standards such as NIOSH
(US) or CEN (EU). To determine the appropriate type of respiratory protection that should be used, and hazardassessment should be performed prior to using the product. Environmental conditions such as ventilation and other
contaminants may affect the type of respiratory protection that is chosen.· Protection of hands:
Protective gloves.The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
(Contd. on page 7)
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45.2.1
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to beobserved.
· Protective Gloves I.E., Nitrile, Viton, Neoprene
· Eye protection: Tightly sealed goggles.
· Body protection: Protective work clothing.
* SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Silver-coloured
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: undetermined
Initial boiling point and boiling range: 124°C
· Flash point: 25°C (*)
· Flammability (solid, gaseous) Not applicable.
· Ignition temperature: 370°C (*)
· Decomposition temperature: Not determined.
· Self igniting: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/vapourmixtures are possible.
· Explosion limits:Lower: 3.0 Vol % (*)
Upper: 10.4 Vol % (*)
· Vapour pressure at 20°C: 10.7 hPa (*)
· Density at 20°C: 1.1-1.2 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withWater: Not miscible or difficult to mix
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:dynamic: Not determined.
kinematic at 40°C: 247.79 mm²/s
· Solvent content:Organic solvents: 22.1-27.9 %
VOC (EC) 22.13-27.94 %
(Contd. on page 8)
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45.2.1
Solids content: 25.1-34.8 %
· 9.2 Other information The above data are typical values and do not constitute a specification.*Properties have been calculated.
* SECTION 10: Stability and reactivity
· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability Stable under recommended storage conditions
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known
· 10.4 Conditions to avoid High temperatures, sparks, and open flames.
· 10.5 Incompatible materials:Water.aminesalcoholscopper
· 10.6 Hazardous decomposition products: No dangerous decomposition products known
* SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity
Harmful if inhaled.
· LD/LC50 values that are relevant for classification:
123-86-4 n-butyl acetate
Oral LD50 14,000 mg/kg (rat)
Inhalative LC50/4 h >21 mg/l (rat)
64742-95-6 Solvent naphtha (petroleum), light arom. (Nota P, <0.1% benzene)
Oral LD50 >6,800 mg/kg (Rat)
Dermal LD50 >3,400 mg/kg (Rabbit)
Inhalative LC50/4 h >10.2 mg/l (Rat)
8052-41-3 Stoddard solvent
Oral LD50 >5,000 mg/kg (Rat)
Dermal LD50 >5,000 mg/kg (Rat)
Inhalative LC50/4 h >5.5 mg/l (Rat) (4 hours)
64742-88-7 Solvent naphtha (petroleum), medium aliph.
Oral LD50 >6,500 mg/kg (Rat)
Dermal LD50 >3,000 mg/kg (Rabbit)
Inhalative LC50/4 h >14 mg/l (Rat)
57855-77-3 Calcium Alkylnaphthalenesulfonate
Oral LD50 >2,500 mg/kg (Rat)
NOAEL 95 mg/kg (Rat)
Inhalative LC50/1 h >9,000 mg/l (Rat)
(Contd. on page 9)
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45.2.1
· Primary irritant effect:· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritationCauses serious eye irritation.
· Respiratory or skin sensitisationMay cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)Carc. 2
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· CarcinogenicitySuspected of causing cancer.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposureMay cause respiratory irritation.
· STOT-repeated exposureCauses damage to the respiratory system through prolonged or repeated exposure. May cause damage to thecentral nervous system and the respiratory system through prolonged or repeated exposure.
· Aspiration hazard Based on available data, the classification criteria are not met.
* SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
123-86-4 n-butyl acetate
LC50 18 mg/l (Pimephales Promelas (Fathead minnow)) (96 hours)
EC50 6,477 mg/l (Desmodesmus subspicatus) (72 Hours)
44 mg/l (Daphnia magna) (48 Hours)
IC50 356 mg/L (Tetrahymena pyriformis)
NOEC 200 mg/l (Desmodesmus subspicatus) (72 Hours)
8052-41-3 Stoddard solvent
EC50 1.4 mg/l (Daphnia magna) (48 Hours)
1.2 mg/l (Green algae) (72 Hours)
57855-77-3 Calcium Alkylnaphthalenesulfonate
LC50 >0.28 mg/l (Fish) (96 Hours)
EC50 >0.27 mg/l (Daphnia) (48 hours)
NOEC >0.27 mg/l (Algae) (3 days)
· 12.2 Persistence and degradability
123-86-4 n-butyl acetate
Biodegradability 83 % in 28 days
· 12.3 Bioaccumulative potential
123-86-4 n-butyl acetate
Bioaccumalative potential 2.3 LogPow
· 12.4 Mobility in soil No further relevant information available.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.(Contd. on page 10)
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45.2.1
· 12.6 Other adverse effects No further relevant information available.
* SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation Dispose of in accordance with local, state, and federal regulations.
· European waste catalogueThe European Waste Catalogue (EWC) waste codes do not refer to product but to origin. The
manufacturer is therefore unable to quote a waste code for products which are used in various
industries. Any codes shown should be regarded as a recommendation to the user.
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS
AND PRINTING INKS
08 01 00 wastes from MFSU and removal of paint and varnish
08 01 11* waste paint and varnish containing organic solvents or other hazardous substances
HP 3 Flammable
HP 4 Irritant - skin irritation and eye damage
HP 5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity
HP 7 Carcinogenic
HP 13 Sensitising
· Uncleaned packagings:· Recommendation: Disposal must be made according to official regulations.
* SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1263
· 14.2 UN proper shipping name· ADR 1263 PAINT
· IMDG, IATA PAINT
· 14.3 Transport hazard class(es)
· ADR, IMDG, IATA
· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group III
· ADR, IMDG, IATA III
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 30
· EMS Number: F-E,S-E
(Contd. on page 11)
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45.2.1
· Stowage Category A
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 3
· Tunnel restriction code D/E
· IMDG· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1Maximum net quantity per inner packaging: 30 mlMaximum net quantity per outer packaging: 1000 ml
· UN "Model Regulation": UN 1263 PAINT, 3, III
* SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category P5c
· Qualifying quantity (tonnes) for the application of lower-tier requirements 5,000 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50,000 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 56, 56a, 56b, 56c
· National regulations
· Information about limitation of use:Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
· Technical instructions (air):
Class Share in %
I 10-25
NK 25-50
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
* SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specificproduct features and shall not establish a legally valid contractual relationship.
Cortec Corporation does not warranty any translation of this SDS not created by Cortec Corporation.
· Relevant phrasesH226 Flammable liquid and vapour.
H228 Flammable solid.H261 In contact with water releases flammable gases.
(Contd. on page 12)
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45.2.1
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H372 Causes damage to the respiratory system through prolonged or repeated exposure.
H373 May cause damage to the central nervous system and the respiratory system through prolonged or repeated
exposure.
· Abbreviations and acronyms:ICAO: International Civil Aviation Organisation
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage
of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids – Category 3
Flam. Sol. 1: Flammable solids – Category 1
Water-react. 2: Substances and mixtures which in contact with water emit flammable gases – Category 2
Acute Tox. 3: Acute toxicity – Category 3
Acute Tox. 4: Acute toxicity – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Resp. Sens. 1: Respiratory sensitisation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Carc. 2: Carcinogenicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Asp. Tox. 1: Aspiration hazard – Category 1
· * Data compared to the previous version altered. GB