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Phosphate Ester Fluids and Lubricants
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Phosphate Ester
Fluids and Lubricants
Supresta: At a Glance
• Leader in phosphorus based flame
retardants, fluids, and lubricants
• Headquartered in Ardsley, New York USA
• ~300 employees worldwide
• Formerly a business unit of Akzo Nobel
Chemicals
• Supresta worldwide includes
– Regional sales centers in America,
Europe, and Asia
– Two manufacturing facilities
– Advocacy and government affairs
expertise
– Two research and development
facilities
In addition to providing
fire resistance, our flame
retardant plasticizers assist in
processing and add malleability.
Supresta: A Global Presence
Headquarters and
Administrative Office
Regional Sales Center
Research and
Development Facility
Manufacturing Facility
Ardsley, New
York, USA
Gallipolis Ferry,
West Virginia, USA
Amersfoort,
The Netherlands
Bitterfeld,
Germany
Deventer,
The Netherlands
Shanghai,
China
Supresta’s Mission and Vision
• Mission: Phosphorus products for fire safety. We strive toward our mission by supplying
sustainable products for our key markets, including
– Fluids and Lubricants
– Polyurethane foams
– Engineering resins
• Vision: To be Operationally Excellent in sustainable phosphorus products and advocates of
fire safety
Our Products: Built-In Defense against Fire
• More than 80 products with several
more in development
• Product applications
– Flame retardants for rigid and flexible
polyurethane foams
– Flame retardants for engineering
resins for electronics and high-end
structural plastics
– Fire resistant hydraulic fluids,
lubricants, cleaners, and anti-wear
additives
– Flame retardant plasticizers that
assist in processing, add malleability,
and provide fire resistance
– Phosphorus organics, inorganics, and
wetting agents
Our flame retardant plasticizers are applied to
plastic casings for electronic goods.
Our FyrolflexTM products are commonly used in
electrical connectors and boxes.
Business Brands
Our flame retardant plasticizers are
applied to plastic casings.
Globally recognized brands
– FyrolTM flame retardants for rigid and
flexible foams
– FyrolflexTM flame retardant
engineering resins for electronics and
high-end structural plastics
– FyrquelTM fire resistant hydraulic fluids
– Syn-O-AdTM fire resistant anti-wear
additives
– PhosflexTM flame retardant plasticizers
– VictawetTM flame retardant wetting
agents
Product Families
AlcoholsAlcohols
Specialty PhosphatesSpecialty Phosphates
Phenol / AlcoholsPhenol / Alcohols
Specialty PlasticizersSpecialty Plasticizers
Polyurethane Flame Retardants
Polyurethane Flame Retardants
Alkyl Oxides/Chloroalkyl OxideAlkyl Oxides/
Chloroalkyl Oxide
Alkyl DiphenylPhosphates
Alkyl DiphenylPhosphates
TrialkylPhosphatesTrialkyl
Phosphates
AlkylchloridePhosphatesAlkylchloridePhosphates
Alkylated TriarylPhosphates
Alkylated TriarylPhosphates
TriphenylPhosphateTriphenylPhosphate
Tricresyl/TrixylenolPhosphate
Tricresyl/TrixylenolPhosphate
Engineering ResinsEngineering Resins
PhenolPhenol
Cellulose Flame Retardants
Cellulose Flame Retardants
Alkylated PhenolAlkylated Phenol
Functional Fluids & Plasticizers
Functional Fluids & Plasticizers
Functional FluidsFunctional Fluids
Cresylic Acid or Xylenol
Cresylic Acid or Xylenol
SalesSales
SalesSales
BisphosphatesBisphosphates
Resorcinol / BPAResorcinol / BPA Phenol / OthersPhenol / Others
POCl3POCl3
PCI3PCI3
POCl3POCl3
ChlorineChlorinePhosphorusPhosphorus
OxygenOxygen
Intermediate
Raw material
End product
Application
Phosphorous
Acid
Product Families
AlcoholsAlcohols
Specialty PhosphatesSpecialty Phosphates
Phenol / AlcoholsPhenol / Alcohols
Specialty PlasticizersSpecialty Plasticizers
Polyurethane Flame Retardants
Polyurethane Flame Retardants
Alkyl Oxides/Chloroalkyl OxideAlkyl Oxides/
Chloroalkyl Oxide
Alkyl DiphenylPhosphates
Alkyl DiphenylPhosphates
TrialkylPhosphatesTrialkyl
Phosphates
AlkylchloridePhosphatesAlkylchloridePhosphates
Alkylated TriarylPhosphates
Alkylated TriarylPhosphates
TriphenylPhosphateTriphenylPhosphate
Tricresyl/TrixylenolPhosphate
Tricresyl/TrixylenolPhosphate
Engineering ResinsEngineering Resins
PhenolPhenol
Cellulose Flame Retardants
Cellulose Flame Retardants
Alkylated PhenolAlkylated Phenol
Functional Fluids & Plasticizers
Functional Fluids & Plasticizers
Functional FluidsFunctional Fluids
Cresylic Acid or Xylenol
Cresylic Acid or Xylenol
SalesSales
SalesSales
BisphosphatesBisphosphates
Resorcinol / BPAResorcinol / BPA Phenol / OthersPhenol / Others
POCl3POCl3
PCI3PCI3
POCl3POCl3
ChlorineChlorinePhosphorusPhosphorus
OxygenOxygen
Intermediate
Raw material
End product
Application
Phosphorous
Acid
Fluids and Lubricants
Phosphate Esters: Which Ones Are You Talking About?
• Alkyl Acid Phosphates- These are acids
P2O5 reacted with any alcohol
Applications: metalworking; reacted with neutralizing amines
• POCl3 reactions with (these are not acids)
– Straight chain alcohols (n-butanol)-----�tri-alkyl phosphate (tributyl phosphate)
commercial aviation hydraulic fluid
– Natural based raw materials (xylenols; cresols)
• TCP- (not ToCP) – jet engine lubricant additive
• TXP- ISO 46 hydraulic fluid; lubricant additive
– Synthetic based raw materials (alkylated phenols)
• Butylated phenyl phosphates (ISO 32-100)
» Excellent oxidative stability-tertiary carbon
» Tox profile similar to conventional oils
» FR hydraulic fluids and oil additives
• Propylated phenyl phosphates - oil additives
Fire Resistant Hydraulic Fluids Demonstration
• DVD available; or at watch the demonstration at
www.supresta.com/MASTER2.wmf
FMRC Approved Products
Fire Resistant Hydraulic Fluids Demonstration
Fyrquel®Fluids
• Are difficult to ignite and flame spread is limited in hydraulics and lubricating applications
– Excellent application in critical high pressure applications or high temperature
applications
• Wide range of Fyrquel®products is available
– Fyrquel products: FR Hydraulic Fluids & Compressor Fluids
ISO 32-ISO 100
– Fyrquel EHC series: FR Electro-Hydraulic Control Fluid
– Fyrquel GT: Gas Turbine Bearing Lubricant ISO 32
– Fyrquel L: Turbine/Hydraulic Fluid
Syn-O-Ad®Lubricant Additives
Additives or basestocks used to promote fire resistance or anti-wear/mild EP properties in
lubricating fluids
– Forms solid boundary lubricant on surfaces following in high temperature lubricant
applications
– Improved film strength without chlorine or sulfur in fill for life applications
– Trialkyl Phosphates: Syn-O-Ad®8412 (Tributyl Phosphate)
– Triaryl Phosphates
– Syn-O-Ad®8484 (Tricresyl Phosphate)
– Syn-O-Ad®8475 (Trixylenyl Phosphate)
– Syn-O-Ad ®8485, 8478, 8477 (Butylated Triphenyl Phosphates)
– Syn-O-Ad®9578 (Propylated Triphenyl Phosphates)
– Next generation triaryl phosphate product
Headquarters and Regional Sales Office Locations
Supresta Headquarters
420 Saw Mill River Road
Ardsley, New York 10502 USA
914.269.5900 fax: 914.674.9736
Americas Sales Office
420 Saw Mill River Road
Ardsley, New York 10502 USA
914.269.5900 fax: 914.674.9735
Greater Europe Sales Office
Hoefseweg 1, PO Box 2501
3800 GB Amersfoort, The Netherlands
+31 33 4534580 fax: +31 33 4534578
Greater Asia Pacific Sales Office
Room 606, Pacheer Commercial Center
555 West NanJing Road
Shanghai, 200041 China
+86 21 62560853 fax: + 86 21 62535184
www. .com
Online at