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PICKLINOX P2 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Date of issue: 14/10/2009 Revision date: 01/03/2018 Supersedes: 09/01/2014 Version: 2.0 17/07/2018 EN (English) SDS Ref.: WL-0044 1/14 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : PICKLINOX P2 Product code : WL-0044 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category : Acidic cleaner. Industrial/Professional use spec : For professional use only Function or use category : Welding and soldering agents 1.2.2. Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Lincoln Electric Europe S.L. Calle Balmes, 89 8th floor, 2a 08008 Barcelona - SPAIN T +34 93 492 20 00 [email protected] - www.lincolnelectric.eu 1.4. Emergency telephone number Emergency number : +33 1 45 42 59 59 (INRS) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 2 H310 Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 1A H314 Serious eye damage/eye irritation, Category 1 H318 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects No additional information available 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) : GHS05 GHS06 Signal word (CLP) : Danger Hazardous ingredients : ammonium bifluoride; hydrofluoric acid … % Hazard statements (CLP) : H301+H331 - Toxic if swallowed or if inhaled H310 - Fatal in contact with skin. H314 - Causes severe skin burns and eye damage. Precautionary statements (CLP) : P260 - Do not breathe dust, gas, fume, mist, spray, vapours. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water . P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P311 - IF exposed or concerned: Call a doctor. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Transcript
Page 1: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Date of issue: 14/10/2009 Revision date: 01/03/2018 Supersedes: 09/01/2014 Version: 2.0

17/07/2018 EN (English) SDS Ref.: WL-0044 1/14

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture

Product name : PICKLINOX P2

Product code : WL-0044

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Main use category : Acidic cleaner.

Industrial/Professional use spec : For professional use only

Function or use category : Welding and soldering agents

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Lincoln Electric Europe S.L. Calle Balmes, 89 8th floor, 2a 08008 Barcelona - SPAIN T +34 93 492 20 00 [email protected] - www.lincolnelectric.eu

1.4. Emergency telephone number

Emergency number : +33 1 45 42 59 59 (INRS)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II)

Acute toxicity (oral), Category 3 H301

Acute toxicity (dermal), Category 2 H310

Acute toxicity (inhal.), Category 3 H331

Skin corrosion/irritation, Category 1A H314

Serious eye damage/eye irritation, Category 1

H318

Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display

Hazard pictograms (CLP) :

GHS05

GHS06

Signal word (CLP) : Danger

Hazardous ingredients : ammonium bifluoride; hydrofluoric acid … %

Hazard statements (CLP) : H301+H331 - Toxic if swallowed or if inhaled H310 - Fatal in contact with skin. H314 - Causes severe skin burns and eye damage.

Precautionary statements (CLP) : P260 - Do not breathe dust, gas, fume, mist, spray, vapours. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water . P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P311 - IF exposed or concerned: Call a doctor. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Page 2: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 2/14

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]

nitric acid ... %

(CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23

13,75 - 20 Ox. Liq. 3, H272 Met. Corr. 1, H290 Acute Tox. 3 (Inhalation), H331 Skin Corr. 1A, H314

hydrofluoric acid … %

(CAS-No.) 7664-39-3 (EC-No.) 231-634-8 (EC Index-No.) 009-003-00-1 (REACH-no) 01-2119458860-33

7 - 9,5 Acute Tox. 2 (Oral), H300 Acute Tox. 1 (Dermal), H310 Acute Tox. 2 (Inhalation:dust,mist), H330 Skin Corr. 1A, H314

Bariumsulfate

(CAS-No.) 7727-43-7 (EC-No.) 231-784-4 (REACH-no) 01-2119491274-35

0,5 - 5 Not classified

ammonium bifluoride

(CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38

1 - 5 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314

Specific concentration limits:

Name Product identifier Specific concentration limits

nitric acid ... % (CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23

( 5 =<C < 20) Skin Corr. 1B, H314 (C >= 20) Skin Corr. 1A, H314 ( 65 =<C < 99) Ox. Liq. 3, H272 (C >= 99) Ox. Liq. 2, H272

hydrofluoric acid … % (CAS-No.) 7664-39-3 (EC-No.) 231-634-8 (EC Index-No.) 009-003-00-1 (REACH-no) 01-2119458860-33

( 0,1 =<C < 1) Eye Irrit. 2, H319 ( 1 =<C < 7) Skin Corr. 1B, H314 (C >= 7) Skin Corr. 1A, H314

ammonium bifluoride (CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38

( 0,1 =<C < 1) Eye Irrit. 2, H319 ( 0,1 =<C < 1) Skin Irrit. 2, H315 (C >= 1) Skin Corr. 1B, H314

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Give oxygen or artificial respiration if necessary.

First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention.

First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.

First-aid measures after ingestion : If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting because of corrosive effects.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Carbon dioxide. Dry powder.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : In case of fire and/or explosion do not breathe fumes. Not flammable.

Page 3: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 3/14

Hazardous decomposition products in case of fire

: Toxic fumes may be released.

5.3. Advice for firefighters

Precautionary measures fire : Keep container closed when not in use.

Firefighting instructions : Cool closed containers exposed to fire with water spray.

Protection during firefighting : Complete protective clothing. EN 469. EN 659. Self-contained breathing apparatus. EN137. Wear recommended personal protective equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Avoid contact with skin and eyes. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment.

6.2. Environmental precautions

Do not allow to enter drains or water courses.

6.3. Methods and material for containment and cleaning up

For containment : Do not touch or walk on the spilled product. Collect as much as possible in clean container for (preferably) re-use or disposal.

Methods for cleaning up : Absorb remaining liquid with sand or inert absorbent and remove to safe place. Avoid non protected metal containers.

Other information : Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Do not breathe vapours. Avoid contact with skin, eyes and clothing.

Hygiene measures : Do not eat, drink or smoke when using this product. Take off immediately all contaminated clothing and wash it before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in a well-ventilated place. Keep container tightly closed. Keep only in original container. Keep away from ignition sources.

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

PICKLINOX P2

EU Local name Hydrogen fluoride

EU IOELV TWA (mg/m³) 1,5 mg/m³

EU IOELV TWA (ppm) 1,8 ppm

EU IOELV STEL (mg/m³) 2,5 mg/m³

EU IOELV STEL (ppm) 3 ppm

EU Regulatory reference COMMISSION DIRECTIVE 2000/39/EC

Czech Republic Local name Fluorovodík

Czech Republic Expoziční limity (PEL) (mg/m³) 1,5 mg/m³

Czech Republic Expoziční limity (PEL) (ppm) 1835 ppm

Czech Republic Expoziční limity (NPK-P) (mg/m³) 2,5 mg/m³

Czech Republic Expoziční limity (NPK-P) (ppm) 3058 ppm

Czech Republic Remark (CZ) I (dráždí sliznice (oči, dýchací cesty) resp. kůži)

Czech Republic Regulatory reference Nařízení vlády č. 361/2007 Sb. (zapracovány změny č. 93/2012 Sb., 9/2013 Sb.)

France Local name Fluorure d’hydrogène (Acide fluorhydrique)

France VME (mg/m³) 1,5 mg/m³

France VME (ppm) 1,8 ppm

Page 4: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 4/14

PICKLINOX P2

France VLE (mg/m³) 2,5 mg/m³

France VLE (ppm) 3 ppm

France Note (FR) Valeurs règlementaires contraignantes

France Regulatory reference Article R4412-149 du Code du travail (réf.: INRS ED 984, 2016)

Germany Local name Fluorwasserstoff

Germany TRGS 900 Occupational exposure limit value (mg/m³) 0,83 mg/m³

Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm

Germany Remark (TRGS 900) DFG;EU;Y;H

Germany Regulatory reference (TRGS900) TRGS900

Italy Local name Acido fluoridrico

Italy OEL TWA (mg/m³) 1,5 mg/m³

Italy OEL TWA (ppm) 1,8 ppm

Italy OEL STEL (mg/m³) 2,5 mg/m³

Italy OEL STEL (ppm) 3 ppm

Italy Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.

Netherlands Local name Fluorwaterstof

Netherlands Grenswaarde TGG 15MIN (mg/m³) 1 mg/m³ (als F)

Netherlands Regulatory reference Arbeidsomstandighedenregeling 2017

Poland Local name Fluorowodór

Poland NDS (mg/m³) 0,5 mg/m³

Poland NDSCh (mg/m³) 2 mg/m³

Poland Regulatory reference Dz. U. 2017 poz. 1348

Portugal Local name Sulfato de bário

Portugal OEL TWA (mg/m³) 5 mg/m³ I (Fraçao inalável), E (O valor aplica-se a partículas sem amianto e contendo menos de 1 % de sílica cristalina)

Portugal OEL TWA (ppm) 0,5 ppm

Portugal OEL STEL (ppm) 4 ppm

Portugal OEL - Ceilings (mg/m³) 2 mg/m³

Portugal Regulatory reference Norma Portuguesa NP 1796:2014

Romania Local name Acid fluorhidric

Romania OEL TWA (mg/m³) 1,5 mg/m³

Romania OEL TWA (ppm) 1,8 ppm

Romania OEL STEL (mg/m³) 2,5 mg/m³

Romania OEL STEL (ppm) 3 ppm

Romania Regulatory reference Legea 319/2006 privind Securitatea şi sănătatea în muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006

Slovakia Local name Síran (sulfát) bárnatý

Slovakia NPHV (priemerná) (mg/m³) 4 mg/m³ inhalovateľná frakcia 1,5 mg/m³ respirabilná frakcia

Slovakia NPHV (priemerná) (ppm) 1,8 ppm

Slovakia OEL STEL (mg/m³) 2,5 mg/m³

Slovakia OEL STEL (ppm) 3 ppm

Slovakia Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (Zmena: 300/2007 Z.z.; Zmena: 471/2011 Z.z.)

Spain Local name Sulfato de bario

Spain VLA-ED (mg/m³) 10 mg/m³

Spain VLA-ED (ppm) 1,8 ppm

Spain VLA-EC (mg/m³) 2,5 mg/m³

Spain VLA-EC (ppm) 3 ppm

Spain Notes e (Este valor es para la materia particulada que no contenga amianto y menos de un 1% de sílice cristalina).

Page 5: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 5/14

PICKLINOX P2

Spain Spain - BLV 2 mg/l Parámetro: Fluoruros - Medio: Orina - Momento de muestreo: Antes de la jornada laboral - Notas: F (Fondo. El indicador está generalmente presente en cantidades detectables en personas no expuestas laboraboralmente. Estos niveles de fondo están considerados en el valor VLB), I (Significa que el indicador biológico es inespecífico puesto que puede encontrarse después de la exposición a otros agentes químicos) 3 mg/l Parámetro: Fluoruros - Medio: Orina - Momento de muestreo: Final de la jornada laboral - Notas: F (Fondo. El indicador está generalmente presente en cantidades detectables en personas no expuestas laboraboralmente. Estos niveles de fondo están considerados en el valor VLB), I (Significa que el indicador biológico es inespecífico puesto que puede encontrarse después de la exposición a otros agentes químicos)

Spain Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2018. INSHT

United Kingdom Local name Barium sulphate

United Kingdom WEL TWA (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust

United Kingdom WEL TWA (ppm) 1,8 ppm (as F)

United Kingdom WEL STEL (mg/m³) 2,5 mg/m³ (as F)

United Kingdom WEL STEL (ppm) 3 ppm (as F)

United Kingdom Regulatory reference EH40. HSE

USA - ACGIH Local name Barium sulfate

USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³

USA - ACGIH ACGIH TWA (ppm) 0,5 ppm

USA - ACGIH ACGIH STEL (ppm) 4 ppm

USA - ACGIH ACGIH Ceiling (ppm) 2 ppm

USA - ACGIH Remark (ACGIH) Pneumoconiosis

USA - ACGIH Regulatory reference ACGIH 2018

USA - OSHA Local name Hydrogen fluoride (as F)

USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³

USA - OSHA OSHA PEL (TWA) (ppm) 2 ppm

USA - OSHA Remark (OSHA) (2) See Table Z-2.

nitric acid ... % (7697-37-2)

EU Local name Nitric acid

EU IOELV STEL (mg/m³) 2,6 mg/m³

EU IOELV STEL (ppm) 1 ppm

EU Regulatory reference COMMISSION DIRECTIVE 2006/15/EC

Czech Republic Local name Kyselina dusičná

Czech Republic Expoziční limity (PEL) (mg/m³) 1 mg/m³

Czech Republic Expoziční limity (PEL) (ppm) 0,39 ppm

Czech Republic Expoziční limity (NPK-P) (mg/m³) 2,5 mg/m³

Czech Republic Expoziční limity (NPK-P) (ppm) 1 ppm

Czech Republic Remark (CZ) I (dráždí sliznice (oči, dýchací cesty) resp. kůži)

Czech Republic Regulatory reference Nařízení vlády č. 361/2007 Sb. (zapracovány změny č. 93/2012 Sb., 9/2013 Sb.)

France Local name Acide nitrique

France VLE (mg/m³) 2,6 mg/m³

France VLE (ppm) 1 ppm

France Note (FR) Valeurs règlementaires indicatives

France Regulatory reference Arrêté du 30 juin 2004 modifié (réf.: INRS ED 984, 2016)

Germany Local name Salpetersäure

Germany TRGS 900 Occupational exposure limit value (mg/m³) 2,6 mg/m³

Page 6: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 6/14

nitric acid ... % (7697-37-2)

Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm

Germany Remark (TRGS 900) EU;13;16

Germany Regulatory reference (TRGS900) TRGS900

Italy Local name Acido nitrico

Italy OEL STEL (mg/m³) 2,6 mg/m³

Italy OEL STEL (ppm) 1 ppm

Italy Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.

Netherlands Local name Salpeterzuur

Netherlands Grenswaarde TGG 15MIN (mg/m³) 1,3 mg/m³

Netherlands Regulatory reference Arbeidsomstandighedenregeling 2018

Poland Local name Kwas azotowy(V)

Poland NDS (mg/m³) 1,4 mg/m³

Poland NDSCh (mg/m³) 2,6 mg/m³

Poland Regulatory reference Dz. U. 2017 poz. 1348

Portugal Local name Ácido nítrico

Portugal OEL TWA (ppm) 2 ppm

Portugal OEL STEL (ppm) 4 ppm

Portugal Regulatory reference Norma Portuguesa NP 1796:2014

Romania Local name Acid nitric

Romania OEL STEL (mg/m³) 2,6 mg/m³

Romania OEL STEL (ppm) 1 ppm

Romania Regulatory reference Legea 319/2006 privind Securitatea şi sănătatea în muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006

Slovakia Local name Kyselina dusičná

Slovakia OEL STEL (mg/m³) 2,6 mg/m³

Slovakia OEL STEL (ppm) 1 ppm

Slovakia Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (Zmena: 300/2007 Z.z.; Zmena: 471/2011 Z.z.)

Spain Local name Ácido nítrico

Spain VLA-EC (mg/m³) 2,6 mg/m³

Spain VLA-EC (ppm) 1 ppm

Spain Notes VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo).

Spain Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2018. INSHT

United Kingdom Local name Nitric acid

United Kingdom WEL STEL (mg/m³) 2,6 mg/m³

United Kingdom WEL STEL (ppm) 1 ppm

United Kingdom Regulatory reference EH40. HSE

USA - ACGIH Local name Nitric acid

USA - ACGIH ACGIH TWA (ppm) 2 ppm

USA - ACGIH ACGIH STEL (ppm) 4 ppm

USA - ACGIH Remark (ACGIH) URT & eye irr; dental erosion

USA - ACGIH Regulatory reference ACGIH 2018

USA - OSHA Local name Nitric acid

USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³

USA - OSHA OSHA PEL (TWA) (ppm) 2 ppm

hydrofluoric acid … % (7664-39-3)

EU Local name Hydrogen fluoride

EU IOELV TWA (mg/m³) 1,5 mg/m³

EU IOELV TWA (ppm) 1,8 ppm

EU IOELV STEL (mg/m³) 2,5 mg/m³

EU IOELV STEL (ppm) 3 ppm

Page 7: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 7/14

hydrofluoric acid … % (7664-39-3)

Czech Republic Local name Fluorovodík

Czech Republic Expoziční limity (PEL) (mg/m³) 1,5 mg/m³

Czech Republic Expoziční limity (PEL) (ppm) 1835 ppm

Czech Republic Expoziční limity (NPK-P) (mg/m³) 2,5 mg/m³

Czech Republic Expoziční limity (NPK-P) (ppm) 3058 ppm

France Local name Fluorure d’hydrogène

France VME (mg/m³) 1,5 mg/m³

France VME (ppm) 1,8 ppm

France VLE (mg/m³) 2,5 mg/m³

France VLE (ppm) 3 ppm

Germany Local name Fluorwasserstoff

Germany TRGS 900 Occupational exposure limit value (mg/m³) 0,83 mg/m³

Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm

Germany Remark (TRGS 900) DFG,EU,Y,H

Italy Local name Acido fluoridrico

Italy OEL TWA (mg/m³) 1,5 mg/m³

Italy OEL TWA (ppm) 1,8 ppm

Italy OEL STEL (mg/m³) 2,5 mg/m³

Italy OEL STEL (ppm) 3 ppm

Netherlands Local name Fluorwaterstof (als F)

Netherlands Grenswaarde TGG 15MIN (mg/m³) 1 mg/m³

Poland Local name Fluorowodór

Poland NDS (mg/m³) 0,5 mg/m³

Poland NDSCh (mg/m³) 2 mg/m³

Portugal Local name Ácido fluorídrico , expresso em F

Portugal OEL TWA (ppm) 0,5 ppm

Portugal OEL - Ceilings (ppm) 2 ppm

Romania Local name Acid fluorhidric

Romania OEL TWA (mg/m³) 1,5 mg/m³

Romania OEL TWA (ppm) 1,8 ppm

Romania OEL STEL (mg/m³) 2,5 mg/m³

Romania OEL STEL (ppm) 3 ppm

Slovakia NPHV (priemerná) (mg/m³) 1,5 mg/m³

Slovakia NPHV (priemerná) (ppm) 1,8 ppm

Slovakia OEL STEL (mg/m³) 2,5 mg/m³

Spain Local name Fluoruro de hidrógeno

Spain VLA-ED (mg/m³) 1,5 mg/m³

Spain VLA-ED (ppm) 1,8 ppm

Spain VLA-EC (mg/m³) 2,5 mg/m³

Spain VLA-EC (ppm) 3 ppm

Spain Notes VLB® (Agente químico que tiene Valor Límite Biológico específico en este documento.), VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país.)

United Kingdom Local name Hydrogen fluoride

United Kingdom WEL TWA (mg/m³) 1,5 mg/m³ (as F)

United Kingdom WEL TWA (ppm) 1,8 ppm (as F)

United Kingdom WEL STEL (mg/m³) 2,5 mg/m³ (as F)

United Kingdom WEL STEL (ppm) 3 ppm (as F)

Page 8: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 8/14

hydrofluoric acid … % (7664-39-3)

USA - ACGIH Local name Hydrogen fluoride , as F

USA - ACGIH ACGIH TWA (ppm) 0,5 ppm

USA - ACGIH ACGIH Ceiling (ppm) 2 ppm

USA - ACGIH Remark (ACGIH) URT, LRT, skin, & eye irr

USA - OSHA Local name Hydrogen fluoride (as F)

USA - OSHA Remark (OSHA) (2) See Table Z-2.

Bariumsulfate (7727-43-7)

Portugal Local name Sulfato de bário

Portugal OEL TWA (mg/m³) 5 mg/m³ I (Fraçao inalável), E (O valor aplica-se a partículas sem amianto e contendo menos de 1 % de sílica cristalina)

Portugal Regulatory reference Norma Portuguesa NP 1796:2014

Slovakia Local name Síran (sulfát) bárnatý

Slovakia NPHV (priemerná) (mg/m³) 4 mg/m³ inhalovateľná frakcia 1,5 mg/m³ respirabilná frakcia

Slovakia Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (Zmena: 300/2007 Z.z.; Zmena: 471/2011 Z.z.)

Spain Local name Sulfato de bario

Spain VLA-ED (mg/m³) 10 mg/m³

Spain Notes e (Este valor es para la materia particulada que no contenga amianto y menos de un 1% de sílice cristalina).

Spain Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2018. INSHT

United Kingdom Local name Barium sulphate

United Kingdom WEL TWA (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust

United Kingdom Regulatory reference EH40. HSE

USA - ACGIH Local name Barium sulfate

USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³

USA - ACGIH Remark (ACGIH) Pneumoconiosis

USA - ACGIH Regulatory reference ACGIH 2018

8.2. Exposure controls

Appropriate engineering controls:

Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure that there is a suitable ventilation system. Measure concentrations regularly, and at the time of any change occuring in conditions likely to have consequences on workers exposure.

Materials for protective clothing:

Wear suitable protective clothing.

Hand protection:

Chemical resistant PVC gloves (to European standard EN 374 or equivalent). The breakthrough time of the selected gloves must be greater than the intended use period.

Eye protection:

Chemical goggles or face shield. Use eye protection according to EN 166, designed to protect against liquid splashes.

Skin and body protection:

Long sleeved protective clothing. Chemical resistant safety shoes

Respiratory protection:

Do not exceed the occupational exposure limits (OEL). This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Solid

Appearance : Paste.

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PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 9/14

Colour : white.

Odour : Pungent.

Odour threshold : No data available

pH : ≈ 1

Relative evaporation rate (butylacetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : No data available

Solubility : In water, material is partially soluble.

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : Not applicable.

Oxidising properties : No data available

Explosive limits : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

10.2. Chemical stability

No additional information available

10.3. Possibility of hazardous reactions

Reacts violently with water. Danger of explosion on contact with : Chlorine trifluoride. Bromine trifluoride. May react violently with acids.

10.4. Conditions to avoid

Do not allow contact with water. Overheating.

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Fluorine (F). Hydrogen fluoride. ammonia. Nitrogen.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Oral: Toxic if swallowed.

Acute toxicity (dermal) : Dermal: Fatal in contact with skin.

Acute toxicity (inhalation) : Inhalation: Toxic if inhaled.

PICKLINOX P2

LD50 oral ≈ 52 mg/kg

LD50 dermal ≈ 53 mg/kg

LC50 inhalation rat (Vapours - mg/l/4h) ≈ 3,81 mg/l/4h

ATE CLP (gases) 700 ppmv/4h

ATE CLP (dust,mist) 0,5 mg/l/4h

nitric acid ... % (7697-37-2)

LC50 inhalation rat (Vapours - mg/l/4h) > 2,65 mg/l/4h

ammonium bifluoride (1341-49-7)

LD50 oral 130 mg/kg OCDE 401

Page 10: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 10/14

hydrofluoric acid … % (7664-39-3)

LC50 inhalation rat (Vapours - mg/l/4h) > 1310 mg/l/4h ppm/1h

Skin corrosion/irritation : Causes severe skin burns and eye damage.

pH: ≈ 1

Serious eye damage/irritation : Causes serious eye damage.

pH: ≈ 1

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Acute aquatic toxicity : Not classified

Chronic aquatic toxicity : Not classified

hydrofluoric acid … % (7664-39-3)

LC50 fish 1 ≈ 51 mg/kg

NOEC chronic fish ≈ 4 mg/l 21 day

NOEC chronic crustacea ≈ 3,7 mg/l 21 day

NOEC chronic algae ≈ 50 mg/l 21 day

12.2. Persistence and degradability

hydrofluoric acid … % (7664-39-3)

Persistence and degradability Readily biodegradable.

12.3. Bioaccumulative potential

ammonium bifluoride (1341-49-7)

Bioconcentration factor (BCF REACH) ≈ 0,5

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number

UN-No. (ADR) : 2922

UN-No. (IMDG) : 2922

UN-No. (IATA) : 2922

UN-No. (ADN) : Not regulated

UN-No. (RID) : 2922

14.2. UN proper shipping name

Proper Shipping Name (ADR) : CORROSIVE LIQUID, TOXIC, N.O.S.

Proper Shipping Name (IMDG) : CORROSIVE LIQUID, TOXIC, N.O.S.

Proper Shipping Name (IATA) : Corrosive liquid, toxic, n.o.s.

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PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 11/14

Proper Shipping Name (ADN) : Not regulated

Proper Shipping Name (RID) : CORROSIVE LIQUID, TOXIC, N.O.S.

Transport document description (ADR) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II, (E)

Transport document description (IMDG) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II

Transport document description (IATA) : UN 2922 Corrosive liquid, toxic, n.o.s. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II

Transport document description (RID) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II

14.3. Transport hazard class(es)

ADR

Transport hazard class(es) (ADR) : 8 (6.1)

Danger labels (ADR) : 8, 6.1

:

IMDG

Transport hazard class(es) (IMDG) : 8 (6.1)

Danger labels (IMDG) : 8, 6.1

:

IATA

Transport hazard class(es) (IATA) : 8 (6.1)

Hazard labels (IATA) : 8, 6.1

:

ADN

Transport hazard class(es) (ADN) : Not regulated

RID

Transport hazard class(es) (RID) : 8 (6.1)

Danger labels (RID) : 8, 6.1

:

14.4. Packing group

Packing group (ADR) : II

Packing group (IMDG) : II

Packing group (IATA) : II

Packing group (ADN) : Not regulated

Packing group (RID) : II

14.5. Environmental hazards

Dangerous for the environment : No

Page 12: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 12/14

Marine pollutant : No

Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport

Classification code (ADR) : CT1

Special provisions (ADR) : 274

Limited quantities (ADR) : 1l

Excepted quantities (ADR) : E2

Packing instructions (ADR) : P001, IBC02

Mixed packing provisions (ADR) : MP15

Portable tank and bulk container instructions (ADR)

: T7

Portable tank and bulk container special provisions (ADR)

: TP2

Tank code (ADR) : L4BN

Vehicle for tank carriage : AT

Transport category (ADR) : 2

Special provisions for carriage - Loading, unloading and handling (ADR)

: CV13, CV28

Hazard identification number (Kemler No.) : 86

Orange plates :

Tunnel restriction code (ADR) : E

EAC code : 2X

APP code : B

- Transport by sea

Special provisions (IMDG) : 274

Limited quantities (IMDG) : 1 L

Excepted quantities (IMDG) : E2

Packing instructions (IMDG) : P001

IBC packing instructions (IMDG) : IBC02

Tank instructions (IMDG) : T7

Tank special provisions (IMDG) : TP2

EmS-No. (Fire) : F-A

EmS-No. (Spillage) : S-B

Stowage category (IMDG) : B

Stowage and handling (IMDG) : SW2

Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation.

MFAG-No : 154

- Air transport

PCA Excepted quantities (IATA) : E2

PCA Limited quantities (IATA) : Y840

PCA limited quantity max net quantity (IATA) : 0.5L

PCA packing instructions (IATA) : 851

PCA max net quantity (IATA) : 1L

CAO packing instructions (IATA) : 855

CAO max net quantity (IATA) : 30L

Special provisions (IATA) : A3

ERG code (IATA) : 8P

- Inland waterway transport

Not regulated

Page 13: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 13/14

- Rail transport

Classification code (RID) : CT1

Special provisions (RID) : 274

Limited quantities (RID) : 1L

Excepted quantities (RID) : E2

Packing instructions (RID) : P001, IBC02

Mixed packing provisions (RID) : MP15

Portable tank and bulk container instructions (RID)

: T7

Portable tank and bulk container special provisions (RID)

: TP2

Tank codes for RID tanks (RID) : L4BN

Transport category (RID) : 2

Special provisions for carriage - Loading, unloading and handling (RID)

: CW13, CW28

Colis express (express parcels) (RID) : CE6

Hazard identification number (RID) : 86

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances

15.1.2. National regulations

Germany

VwVwS Annex reference : Water hazard class (WGK) 2, significant hazard to waters (Classification according to VwVwS, Annex 4)

12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV

: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)

Netherlands

SZW-lijst van kankerverwekkende stoffen : None of the components are listed

SZW-lijst van mutagene stoffen : None of the components are listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding

: None of the components are listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid

: None of the components are listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling

: None of the components are listed

Denmark

Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

Pregnant/breastfeeding women working with the product must not be in direct contact with the product

15.2. Chemical safety assessment

No additional information available

SECTION 16: Other information

Indication of changes:

Composition/information on ingredients. Hazards identification. Identification of the substance/mixture and of the company/undertaking. Regulatory information.

Abbreviations and acronyms:

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate

Page 14: PICKLINOX P2 - market.varjenje.net · muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006 Slovakia Local name Síran (sulfát) bárnatý Slovakia NPHV (priemerná)

PICKLINOX P2 Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

17/07/2018 EN (English) SDS Ref.: WL-0044 14/14

BCF Bioconcentration factor

CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008

DMEL Derived Minimal Effect level

DNEL Derived-No Effect Level

EC50 Median effective concentration

IARC International Agency for Research on Cancer

IATA International Air Transport Association

IMDG International Maritime Dangerous Goods

LC50 Median lethal concentration

LD50 Median lethal dose

LOAEL Lowest Observed Adverse Effect Level

NOAEC No-Observed Adverse Effect Concentration

NOAEL No-Observed Adverse Effect Level

NOEC No-Observed Effect Concentration

OECD Organisation for Economic Co-operation and Development

PBT Persistent Bioaccumulative Toxic

PNEC Predicted No-Effect Concentration

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006

RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SDS Safety Data Sheet

STP Sewage treatment plant

TLM Median Tolerance Limit

vPvB Very Persistent and Very Bioaccumulative

Other information : The product must not be used for any application that is not allowed, in this case we will not be responsible for any damage caused. The user must respect current Safety, Health and Environmental legislation.

Full text of H- and EUH-statements:

Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1

Acute Tox. 2 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 2

Acute Tox. 2 (Oral) Acute toxicity (oral), Category 2

Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3

Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3

Met. Corr. 1 Corrosive to metals, Category 1

Ox. Liq. 3 Oxidising Liquids, Category 3

Skin Corr. 1A Skin corrosion/irritation, Category 1A

Skin Corr. 1B Skin corrosion/irritation, Category 1B

H272 May intensify fire; oxidiser.

H290 May be corrosive to metals.

H300 Fatal if swallowed.

H301 Toxic if swallowed.

H310 Fatal in contact with skin.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage

H330 Fatal if inhaled.

H331 Toxic if inhaled.

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product


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