PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 14/10/2009 Revision date: 01/03/2018 Supersedes: 09/01/2014 Version: 2.0
17/07/2018 EN (English) SDS Ref.: WL-0044 1/14
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Product name : PICKLINOX P2
Product code : WL-0044
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Acidic cleaner.
Industrial/Professional use spec : For professional use only
Function or use category : Welding and soldering agents
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Lincoln Electric Europe S.L. Calle Balmes, 89 8th floor, 2a 08008 Barcelona - SPAIN T +34 93 492 20 00 [email protected] - www.lincolnelectric.eu
1.4. Emergency telephone number
Emergency number : +33 1 45 42 59 59 (INRS)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II)
Acute toxicity (oral), Category 3 H301
Acute toxicity (dermal), Category 2 H310
Acute toxicity (inhal.), Category 3 H331
Skin corrosion/irritation, Category 1A H314
Serious eye damage/eye irritation, Category 1
H318
Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS05
GHS06
Signal word (CLP) : Danger
Hazardous ingredients : ammonium bifluoride; hydrofluoric acid … %
Hazard statements (CLP) : H301+H331 - Toxic if swallowed or if inhaled H310 - Fatal in contact with skin. H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P260 - Do not breathe dust, gas, fume, mist, spray, vapours. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water . P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P311 - IF exposed or concerned: Call a doctor. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 2/14
2.3. Other hazards
No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
nitric acid ... %
(CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23
13,75 - 20 Ox. Liq. 3, H272 Met. Corr. 1, H290 Acute Tox. 3 (Inhalation), H331 Skin Corr. 1A, H314
hydrofluoric acid … %
(CAS-No.) 7664-39-3 (EC-No.) 231-634-8 (EC Index-No.) 009-003-00-1 (REACH-no) 01-2119458860-33
7 - 9,5 Acute Tox. 2 (Oral), H300 Acute Tox. 1 (Dermal), H310 Acute Tox. 2 (Inhalation:dust,mist), H330 Skin Corr. 1A, H314
Bariumsulfate
(CAS-No.) 7727-43-7 (EC-No.) 231-784-4 (REACH-no) 01-2119491274-35
0,5 - 5 Not classified
ammonium bifluoride
(CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38
1 - 5 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314
Specific concentration limits:
Name Product identifier Specific concentration limits
nitric acid ... % (CAS-No.) 7697-37-2 (EC-No.) 231-714-2 (EC Index-No.) 007-004-00-1 (REACH-no) 01-2119487297-23
( 5 =<C < 20) Skin Corr. 1B, H314 (C >= 20) Skin Corr. 1A, H314 ( 65 =<C < 99) Ox. Liq. 3, H272 (C >= 99) Ox. Liq. 2, H272
hydrofluoric acid … % (CAS-No.) 7664-39-3 (EC-No.) 231-634-8 (EC Index-No.) 009-003-00-1 (REACH-no) 01-2119458860-33
( 0,1 =<C < 1) Eye Irrit. 2, H319 ( 1 =<C < 7) Skin Corr. 1B, H314 (C >= 7) Skin Corr. 1A, H314
ammonium bifluoride (CAS-No.) 1341-49-7 (EC-No.) 215-676-4 (EC Index-No.) 009-009-00-4 (REACH-no) 01-2119489180-38
( 0,1 =<C < 1) Eye Irrit. 2, H319 ( 0,1 =<C < 1) Skin Irrit. 2, H315 (C >= 1) Skin Corr. 1B, H314
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Give oxygen or artificial respiration if necessary.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention.
First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion : If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting because of corrosive effects.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : In case of fire and/or explosion do not breathe fumes. Not flammable.
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 3/14
Hazardous decomposition products in case of fire
: Toxic fumes may be released.
5.3. Advice for firefighters
Precautionary measures fire : Keep container closed when not in use.
Firefighting instructions : Cool closed containers exposed to fire with water spray.
Protection during firefighting : Complete protective clothing. EN 469. EN 659. Self-contained breathing apparatus. EN137. Wear recommended personal protective equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Avoid contact with skin and eyes. Stop leak if safe to do so.
6.1.1. For non-emergency personnel
No additional information available
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment.
6.2. Environmental precautions
Do not allow to enter drains or water courses.
6.3. Methods and material for containment and cleaning up
For containment : Do not touch or walk on the spilled product. Collect as much as possible in clean container for (preferably) re-use or disposal.
Methods for cleaning up : Absorb remaining liquid with sand or inert absorbent and remove to safe place. Avoid non protected metal containers.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Do not breathe vapours. Avoid contact with skin, eyes and clothing.
Hygiene measures : Do not eat, drink or smoke when using this product. Take off immediately all contaminated clothing and wash it before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed. Keep only in original container. Keep away from ignition sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
PICKLINOX P2
EU Local name Hydrogen fluoride
EU IOELV TWA (mg/m³) 1,5 mg/m³
EU IOELV TWA (ppm) 1,8 ppm
EU IOELV STEL (mg/m³) 2,5 mg/m³
EU IOELV STEL (ppm) 3 ppm
EU Regulatory reference COMMISSION DIRECTIVE 2000/39/EC
Czech Republic Local name Fluorovodík
Czech Republic Expoziční limity (PEL) (mg/m³) 1,5 mg/m³
Czech Republic Expoziční limity (PEL) (ppm) 1835 ppm
Czech Republic Expoziční limity (NPK-P) (mg/m³) 2,5 mg/m³
Czech Republic Expoziční limity (NPK-P) (ppm) 3058 ppm
Czech Republic Remark (CZ) I (dráždí sliznice (oči, dýchací cesty) resp. kůži)
Czech Republic Regulatory reference Nařízení vlády č. 361/2007 Sb. (zapracovány změny č. 93/2012 Sb., 9/2013 Sb.)
France Local name Fluorure d’hydrogène (Acide fluorhydrique)
France VME (mg/m³) 1,5 mg/m³
France VME (ppm) 1,8 ppm
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 4/14
PICKLINOX P2
France VLE (mg/m³) 2,5 mg/m³
France VLE (ppm) 3 ppm
France Note (FR) Valeurs règlementaires contraignantes
France Regulatory reference Article R4412-149 du Code du travail (réf.: INRS ED 984, 2016)
Germany Local name Fluorwasserstoff
Germany TRGS 900 Occupational exposure limit value (mg/m³) 0,83 mg/m³
Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm
Germany Remark (TRGS 900) DFG;EU;Y;H
Germany Regulatory reference (TRGS900) TRGS900
Italy Local name Acido fluoridrico
Italy OEL TWA (mg/m³) 1,5 mg/m³
Italy OEL TWA (ppm) 1,8 ppm
Italy OEL STEL (mg/m³) 2,5 mg/m³
Italy OEL STEL (ppm) 3 ppm
Italy Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.
Netherlands Local name Fluorwaterstof
Netherlands Grenswaarde TGG 15MIN (mg/m³) 1 mg/m³ (als F)
Netherlands Regulatory reference Arbeidsomstandighedenregeling 2017
Poland Local name Fluorowodór
Poland NDS (mg/m³) 0,5 mg/m³
Poland NDSCh (mg/m³) 2 mg/m³
Poland Regulatory reference Dz. U. 2017 poz. 1348
Portugal Local name Sulfato de bário
Portugal OEL TWA (mg/m³) 5 mg/m³ I (Fraçao inalável), E (O valor aplica-se a partículas sem amianto e contendo menos de 1 % de sílica cristalina)
Portugal OEL TWA (ppm) 0,5 ppm
Portugal OEL STEL (ppm) 4 ppm
Portugal OEL - Ceilings (mg/m³) 2 mg/m³
Portugal Regulatory reference Norma Portuguesa NP 1796:2014
Romania Local name Acid fluorhidric
Romania OEL TWA (mg/m³) 1,5 mg/m³
Romania OEL TWA (ppm) 1,8 ppm
Romania OEL STEL (mg/m³) 2,5 mg/m³
Romania OEL STEL (ppm) 3 ppm
Romania Regulatory reference Legea 319/2006 privind Securitatea şi sănătatea în muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006
Slovakia Local name Síran (sulfát) bárnatý
Slovakia NPHV (priemerná) (mg/m³) 4 mg/m³ inhalovateľná frakcia 1,5 mg/m³ respirabilná frakcia
Slovakia NPHV (priemerná) (ppm) 1,8 ppm
Slovakia OEL STEL (mg/m³) 2,5 mg/m³
Slovakia OEL STEL (ppm) 3 ppm
Slovakia Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (Zmena: 300/2007 Z.z.; Zmena: 471/2011 Z.z.)
Spain Local name Sulfato de bario
Spain VLA-ED (mg/m³) 10 mg/m³
Spain VLA-ED (ppm) 1,8 ppm
Spain VLA-EC (mg/m³) 2,5 mg/m³
Spain VLA-EC (ppm) 3 ppm
Spain Notes e (Este valor es para la materia particulada que no contenga amianto y menos de un 1% de sílice cristalina).
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 5/14
PICKLINOX P2
Spain Spain - BLV 2 mg/l Parámetro: Fluoruros - Medio: Orina - Momento de muestreo: Antes de la jornada laboral - Notas: F (Fondo. El indicador está generalmente presente en cantidades detectables en personas no expuestas laboraboralmente. Estos niveles de fondo están considerados en el valor VLB), I (Significa que el indicador biológico es inespecífico puesto que puede encontrarse después de la exposición a otros agentes químicos) 3 mg/l Parámetro: Fluoruros - Medio: Orina - Momento de muestreo: Final de la jornada laboral - Notas: F (Fondo. El indicador está generalmente presente en cantidades detectables en personas no expuestas laboraboralmente. Estos niveles de fondo están considerados en el valor VLB), I (Significa que el indicador biológico es inespecífico puesto que puede encontrarse después de la exposición a otros agentes químicos)
Spain Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2018. INSHT
United Kingdom Local name Barium sulphate
United Kingdom WEL TWA (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust
United Kingdom WEL TWA (ppm) 1,8 ppm (as F)
United Kingdom WEL STEL (mg/m³) 2,5 mg/m³ (as F)
United Kingdom WEL STEL (ppm) 3 ppm (as F)
United Kingdom Regulatory reference EH40. HSE
USA - ACGIH Local name Barium sulfate
USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³
USA - ACGIH ACGIH TWA (ppm) 0,5 ppm
USA - ACGIH ACGIH STEL (ppm) 4 ppm
USA - ACGIH ACGIH Ceiling (ppm) 2 ppm
USA - ACGIH Remark (ACGIH) Pneumoconiosis
USA - ACGIH Regulatory reference ACGIH 2018
USA - OSHA Local name Hydrogen fluoride (as F)
USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³
USA - OSHA OSHA PEL (TWA) (ppm) 2 ppm
USA - OSHA Remark (OSHA) (2) See Table Z-2.
nitric acid ... % (7697-37-2)
EU Local name Nitric acid
EU IOELV STEL (mg/m³) 2,6 mg/m³
EU IOELV STEL (ppm) 1 ppm
EU Regulatory reference COMMISSION DIRECTIVE 2006/15/EC
Czech Republic Local name Kyselina dusičná
Czech Republic Expoziční limity (PEL) (mg/m³) 1 mg/m³
Czech Republic Expoziční limity (PEL) (ppm) 0,39 ppm
Czech Republic Expoziční limity (NPK-P) (mg/m³) 2,5 mg/m³
Czech Republic Expoziční limity (NPK-P) (ppm) 1 ppm
Czech Republic Remark (CZ) I (dráždí sliznice (oči, dýchací cesty) resp. kůži)
Czech Republic Regulatory reference Nařízení vlády č. 361/2007 Sb. (zapracovány změny č. 93/2012 Sb., 9/2013 Sb.)
France Local name Acide nitrique
France VLE (mg/m³) 2,6 mg/m³
France VLE (ppm) 1 ppm
France Note (FR) Valeurs règlementaires indicatives
France Regulatory reference Arrêté du 30 juin 2004 modifié (réf.: INRS ED 984, 2016)
Germany Local name Salpetersäure
Germany TRGS 900 Occupational exposure limit value (mg/m³) 2,6 mg/m³
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 6/14
nitric acid ... % (7697-37-2)
Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm
Germany Remark (TRGS 900) EU;13;16
Germany Regulatory reference (TRGS900) TRGS900
Italy Local name Acido nitrico
Italy OEL STEL (mg/m³) 2,6 mg/m³
Italy OEL STEL (ppm) 1 ppm
Italy Regulatory reference Allegato XXXVIII del D.Lgs. 9 aprile 2008, n. 81 e s.m.i.
Netherlands Local name Salpeterzuur
Netherlands Grenswaarde TGG 15MIN (mg/m³) 1,3 mg/m³
Netherlands Regulatory reference Arbeidsomstandighedenregeling 2018
Poland Local name Kwas azotowy(V)
Poland NDS (mg/m³) 1,4 mg/m³
Poland NDSCh (mg/m³) 2,6 mg/m³
Poland Regulatory reference Dz. U. 2017 poz. 1348
Portugal Local name Ácido nítrico
Portugal OEL TWA (ppm) 2 ppm
Portugal OEL STEL (ppm) 4 ppm
Portugal Regulatory reference Norma Portuguesa NP 1796:2014
Romania Local name Acid nitric
Romania OEL STEL (mg/m³) 2,6 mg/m³
Romania OEL STEL (ppm) 1 ppm
Romania Regulatory reference Legea 319/2006 privind Securitatea şi sănătatea în muncă şi HG nr. 1/2012 de modificare şi completare a HG 1218/2006
Slovakia Local name Kyselina dusičná
Slovakia OEL STEL (mg/m³) 2,6 mg/m³
Slovakia OEL STEL (ppm) 1 ppm
Slovakia Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (Zmena: 300/2007 Z.z.; Zmena: 471/2011 Z.z.)
Spain Local name Ácido nítrico
Spain VLA-EC (mg/m³) 2,6 mg/m³
Spain VLA-EC (ppm) 1 ppm
Spain Notes VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo).
Spain Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2018. INSHT
United Kingdom Local name Nitric acid
United Kingdom WEL STEL (mg/m³) 2,6 mg/m³
United Kingdom WEL STEL (ppm) 1 ppm
United Kingdom Regulatory reference EH40. HSE
USA - ACGIH Local name Nitric acid
USA - ACGIH ACGIH TWA (ppm) 2 ppm
USA - ACGIH ACGIH STEL (ppm) 4 ppm
USA - ACGIH Remark (ACGIH) URT & eye irr; dental erosion
USA - ACGIH Regulatory reference ACGIH 2018
USA - OSHA Local name Nitric acid
USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³
USA - OSHA OSHA PEL (TWA) (ppm) 2 ppm
hydrofluoric acid … % (7664-39-3)
EU Local name Hydrogen fluoride
EU IOELV TWA (mg/m³) 1,5 mg/m³
EU IOELV TWA (ppm) 1,8 ppm
EU IOELV STEL (mg/m³) 2,5 mg/m³
EU IOELV STEL (ppm) 3 ppm
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 7/14
hydrofluoric acid … % (7664-39-3)
Czech Republic Local name Fluorovodík
Czech Republic Expoziční limity (PEL) (mg/m³) 1,5 mg/m³
Czech Republic Expoziční limity (PEL) (ppm) 1835 ppm
Czech Republic Expoziční limity (NPK-P) (mg/m³) 2,5 mg/m³
Czech Republic Expoziční limity (NPK-P) (ppm) 3058 ppm
France Local name Fluorure d’hydrogène
France VME (mg/m³) 1,5 mg/m³
France VME (ppm) 1,8 ppm
France VLE (mg/m³) 2,5 mg/m³
France VLE (ppm) 3 ppm
Germany Local name Fluorwasserstoff
Germany TRGS 900 Occupational exposure limit value (mg/m³) 0,83 mg/m³
Germany TRGS 900 Occupational exposure limit value (ppm) 1 ppm
Germany Remark (TRGS 900) DFG,EU,Y,H
Italy Local name Acido fluoridrico
Italy OEL TWA (mg/m³) 1,5 mg/m³
Italy OEL TWA (ppm) 1,8 ppm
Italy OEL STEL (mg/m³) 2,5 mg/m³
Italy OEL STEL (ppm) 3 ppm
Netherlands Local name Fluorwaterstof (als F)
Netherlands Grenswaarde TGG 15MIN (mg/m³) 1 mg/m³
Poland Local name Fluorowodór
Poland NDS (mg/m³) 0,5 mg/m³
Poland NDSCh (mg/m³) 2 mg/m³
Portugal Local name Ácido fluorídrico , expresso em F
Portugal OEL TWA (ppm) 0,5 ppm
Portugal OEL - Ceilings (ppm) 2 ppm
Romania Local name Acid fluorhidric
Romania OEL TWA (mg/m³) 1,5 mg/m³
Romania OEL TWA (ppm) 1,8 ppm
Romania OEL STEL (mg/m³) 2,5 mg/m³
Romania OEL STEL (ppm) 3 ppm
Slovakia NPHV (priemerná) (mg/m³) 1,5 mg/m³
Slovakia NPHV (priemerná) (ppm) 1,8 ppm
Slovakia OEL STEL (mg/m³) 2,5 mg/m³
Spain Local name Fluoruro de hidrógeno
Spain VLA-ED (mg/m³) 1,5 mg/m³
Spain VLA-ED (ppm) 1,8 ppm
Spain VLA-EC (mg/m³) 2,5 mg/m³
Spain VLA-EC (ppm) 3 ppm
Spain Notes VLB® (Agente químico que tiene Valor Límite Biológico específico en este documento.), VLI (Agente químico para el que la U.E. estableció en su día un valor límite indicativo. Todos estos agentes químicos figuran al menos en una de las directivas de valores límite indicativos publicadas hasta ahora (ver Anexo C. Bibliografía). Los estados miembros disponen de un tiempo fijado en dichas directivas para su transposición a los valores límites de cada país miembro. Una vez adoptados, estos valores tienen la misma validez que el resto de los valores adoptados por el país.)
United Kingdom Local name Hydrogen fluoride
United Kingdom WEL TWA (mg/m³) 1,5 mg/m³ (as F)
United Kingdom WEL TWA (ppm) 1,8 ppm (as F)
United Kingdom WEL STEL (mg/m³) 2,5 mg/m³ (as F)
United Kingdom WEL STEL (ppm) 3 ppm (as F)
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 8/14
hydrofluoric acid … % (7664-39-3)
USA - ACGIH Local name Hydrogen fluoride , as F
USA - ACGIH ACGIH TWA (ppm) 0,5 ppm
USA - ACGIH ACGIH Ceiling (ppm) 2 ppm
USA - ACGIH Remark (ACGIH) URT, LRT, skin, & eye irr
USA - OSHA Local name Hydrogen fluoride (as F)
USA - OSHA Remark (OSHA) (2) See Table Z-2.
Bariumsulfate (7727-43-7)
Portugal Local name Sulfato de bário
Portugal OEL TWA (mg/m³) 5 mg/m³ I (Fraçao inalável), E (O valor aplica-se a partículas sem amianto e contendo menos de 1 % de sílica cristalina)
Portugal Regulatory reference Norma Portuguesa NP 1796:2014
Slovakia Local name Síran (sulfát) bárnatý
Slovakia NPHV (priemerná) (mg/m³) 4 mg/m³ inhalovateľná frakcia 1,5 mg/m³ respirabilná frakcia
Slovakia Regulatory reference Nariadenie vlády č. 355/2006 Z. z. (Zmena: 300/2007 Z.z.; Zmena: 471/2011 Z.z.)
Spain Local name Sulfato de bario
Spain VLA-ED (mg/m³) 10 mg/m³
Spain Notes e (Este valor es para la materia particulada que no contenga amianto y menos de un 1% de sílice cristalina).
Spain Regulatory reference Límites de Exposición Profesional para Agentes Químicos en España 2018. INSHT
United Kingdom Local name Barium sulphate
United Kingdom WEL TWA (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust
United Kingdom Regulatory reference EH40. HSE
USA - ACGIH Local name Barium sulfate
USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³
USA - ACGIH Remark (ACGIH) Pneumoconiosis
USA - ACGIH Regulatory reference ACGIH 2018
8.2. Exposure controls
Appropriate engineering controls:
Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure that there is a suitable ventilation system. Measure concentrations regularly, and at the time of any change occuring in conditions likely to have consequences on workers exposure.
Materials for protective clothing:
Wear suitable protective clothing.
Hand protection:
Chemical resistant PVC gloves (to European standard EN 374 or equivalent). The breakthrough time of the selected gloves must be greater than the intended use period.
Eye protection:
Chemical goggles or face shield. Use eye protection according to EN 166, designed to protect against liquid splashes.
Skin and body protection:
Long sleeved protective clothing. Chemical resistant safety shoes
Respiratory protection:
Do not exceed the occupational exposure limits (OEL). This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Paste.
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 9/14
Colour : white.
Odour : Pungent.
Odour threshold : No data available
pH : ≈ 1
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : In water, material is partially soluble.
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : Not applicable.
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No additional information available
10.2. Chemical stability
No additional information available
10.3. Possibility of hazardous reactions
Reacts violently with water. Danger of explosion on contact with : Chlorine trifluoride. Bromine trifluoride. May react violently with acids.
10.4. Conditions to avoid
Do not allow contact with water. Overheating.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Fluorine (F). Hydrogen fluoride. ammonia. Nitrogen.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Oral: Toxic if swallowed.
Acute toxicity (dermal) : Dermal: Fatal in contact with skin.
Acute toxicity (inhalation) : Inhalation: Toxic if inhaled.
PICKLINOX P2
LD50 oral ≈ 52 mg/kg
LD50 dermal ≈ 53 mg/kg
LC50 inhalation rat (Vapours - mg/l/4h) ≈ 3,81 mg/l/4h
ATE CLP (gases) 700 ppmv/4h
ATE CLP (dust,mist) 0,5 mg/l/4h
nitric acid ... % (7697-37-2)
LC50 inhalation rat (Vapours - mg/l/4h) > 2,65 mg/l/4h
ammonium bifluoride (1341-49-7)
LD50 oral 130 mg/kg OCDE 401
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 10/14
hydrofluoric acid … % (7664-39-3)
LC50 inhalation rat (Vapours - mg/l/4h) > 1310 mg/l/4h ppm/1h
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: ≈ 1
Serious eye damage/irritation : Causes serious eye damage.
pH: ≈ 1
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
SECTION 12: Ecological information
12.1. Toxicity
Acute aquatic toxicity : Not classified
Chronic aquatic toxicity : Not classified
hydrofluoric acid … % (7664-39-3)
LC50 fish 1 ≈ 51 mg/kg
NOEC chronic fish ≈ 4 mg/l 21 day
NOEC chronic crustacea ≈ 3,7 mg/l 21 day
NOEC chronic algae ≈ 50 mg/l 21 day
12.2. Persistence and degradability
hydrofluoric acid … % (7664-39-3)
Persistence and degradability Readily biodegradable.
12.3. Bioaccumulative potential
ammonium bifluoride (1341-49-7)
Bioconcentration factor (BCF REACH) ≈ 0,5
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with licensed collector’s sorting instructions.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2922
UN-No. (IMDG) : 2922
UN-No. (IATA) : 2922
UN-No. (ADN) : Not regulated
UN-No. (RID) : 2922
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CORROSIVE LIQUID, TOXIC, N.O.S.
Proper Shipping Name (IMDG) : CORROSIVE LIQUID, TOXIC, N.O.S.
Proper Shipping Name (IATA) : Corrosive liquid, toxic, n.o.s.
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 11/14
Proper Shipping Name (ADN) : Not regulated
Proper Shipping Name (RID) : CORROSIVE LIQUID, TOXIC, N.O.S.
Transport document description (ADR) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II, (E)
Transport document description (IMDG) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II
Transport document description (IATA) : UN 2922 Corrosive liquid, toxic, n.o.s. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II
Transport document description (RID) : UN 2922 CORROSIVE LIQUID, TOXIC, N.O.S. ( NITRIC ACID; HYDROFLUORIC ACID), 8 (6.1), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 8 (6.1)
Danger labels (ADR) : 8, 6.1
:
IMDG
Transport hazard class(es) (IMDG) : 8 (6.1)
Danger labels (IMDG) : 8, 6.1
:
IATA
Transport hazard class(es) (IATA) : 8 (6.1)
Hazard labels (IATA) : 8, 6.1
:
ADN
Transport hazard class(es) (ADN) : Not regulated
RID
Transport hazard class(es) (RID) : 8 (6.1)
Danger labels (RID) : 8, 6.1
:
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not regulated
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 12/14
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CT1
Special provisions (ADR) : 274
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container instructions (ADR)
: T7
Portable tank and bulk container special provisions (ADR)
: TP2
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Loading, unloading and handling (ADR)
: CV13, CV28
Hazard identification number (Kemler No.) : 86
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
APP code : B
- Transport by sea
Special provisions (IMDG) : 274
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes. Toxic if swallowed, by skin contact or by inhalation.
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity (IATA) : 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
Special provisions (IATA) : A3
ERG code (IATA) : 8P
- Inland waterway transport
Not regulated
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 13/14
- Rail transport
Classification code (RID) : CT1
Special provisions (RID) : 274
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container instructions (RID)
: T7
Portable tank and bulk container special provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Special provisions for carriage - Loading, unloading and handling (RID)
: CW13, CW28
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 86
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
VwVwS Annex reference : Water hazard class (WGK) 2, significant hazard to waters (Classification according to VwVwS, Annex 4)
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling
: None of the components are listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2. Chemical safety assessment
No additional information available
SECTION 16: Other information
Indication of changes:
Composition/information on ingredients. Hazards identification. Identification of the substance/mixture and of the company/undertaking. Regulatory information.
Abbreviations and acronyms:
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE Acute Toxicity Estimate
PICKLINOX P2 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
17/07/2018 EN (English) SDS Ref.: WL-0044 14/14
BCF Bioconcentration factor
CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
DMEL Derived Minimal Effect level
DNEL Derived-No Effect Level
EC50 Median effective concentration
IARC International Agency for Research on Cancer
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Median lethal concentration
LD50 Median lethal dose
LOAEL Lowest Observed Adverse Effect Level
NOAEC No-Observed Adverse Effect Concentration
NOAEL No-Observed Adverse Effect Level
NOEC No-Observed Effect Concentration
OECD Organisation for Economic Co-operation and Development
PBT Persistent Bioaccumulative Toxic
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS Safety Data Sheet
STP Sewage treatment plant
TLM Median Tolerance Limit
vPvB Very Persistent and Very Bioaccumulative
Other information : The product must not be used for any application that is not allowed, in this case we will not be responsible for any damage caused. The user must respect current Safety, Health and Environmental legislation.
Full text of H- and EUH-statements:
Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1
Acute Tox. 2 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 2
Acute Tox. 2 (Oral) Acute toxicity (oral), Category 2
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Met. Corr. 1 Corrosive to metals, Category 1
Ox. Liq. 3 Oxidising Liquids, Category 3
Skin Corr. 1A Skin corrosion/irritation, Category 1A
Skin Corr. 1B Skin corrosion/irritation, Category 1B
H272 May intensify fire; oxidiser.
H290 May be corrosive to metals.
H300 Fatal if swallowed.
H301 Toxic if swallowed.
H310 Fatal in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage
H330 Fatal if inhaled.
H331 Toxic if inhaled.
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product